US3514391A - Sputtering apparatus with finned anode - Google Patents
Sputtering apparatus with finned anode Download PDFInfo
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- US3514391A US3514391A US636423A US3514391DA US3514391A US 3514391 A US3514391 A US 3514391A US 636423 A US636423 A US 636423A US 3514391D A US3514391D A US 3514391DA US 3514391 A US3514391 A US 3514391A
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- anode
- target
- sputtering
- sputtering apparatus
- fins
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/35—Sputtering by application of a magnetic field, e.g. magnetron sputtering
- C23C14/354—Introduction of auxiliary energy into the plasma
- C23C14/355—Introduction of auxiliary energy into the plasma using electrons, e.g. triode sputtering
Definitions
- This application relates to sputtering equipment and particularly to low energy sputtering equipment used for sputter coating of insulator materials.
- This object s achieved, in general, by a new construction of anode comprising fins on the anode extending inwardly towards the plasma to define troughs therebetween which are open to and substantially facing the electron source and partially masked from the target so that there is no clear line of sight path from the target to these masked areas.
- a new construction of anode comprising fins on the anode extending inwardly towards the plasma to define troughs therebetween which are open to and substantially facing the electron source and partially masked from the target so that there is no clear line of sight path from the target to these masked areas.
- secondary collisions lead to eventual coating of the troughs by the target material and eventual extinguishment of the plasma.
- FIG. 1 is a diagram of the apparatus arranged according to a preferred embodiment of the invention and FIGS. 2-3 are drawings of modified anodes for use in the arrangement of FIG. l.
- an electron source assembly 10 including a thermionic filament 12 enclosed by a grounded enclosure 14 having an exit port 16.
- p ICC Adjacent to the exit port is an auxiliary anode (or grid) electrode 18.
- An anode electrode is provided at 20. Electrons are emitted at the filament and drawn to anode 20 along an electron path coinciding approximately with the axis 22. A plasma is produced along the electron path consisting of the electrons and ions produced by collision of the electrons With gas molecules.
- a sputtering target 24 of insulating material, such as quartz, is mounted on a supporting electrode 26 connected to a radio frequency power source 28.
- a grounded Paschen shield 27 is provided for the target electrode.
- a substrate to be coated with sputtered target material may be located at 29.
- the apparatus may be used without the substrate, for instance for etching the target material, or with the vacuum vessel as a substrate for use as a getter ion pump.
- All of the electrodesanode 20, target 26, grid 18 and enclosure 14 are cooled by appropriate cooling means not shown.
- the anode is biased to about 40 volts by a power supply (not shown), the grid is biased to about 39 volts by a power supply (not shown).
- the filament 12 is powered by standard industrial house power. All the above apparatus is contained in an hermetically sealed vacuum vessel (not shown) evacuated to about 2 l0-4 torr as indicated in the drawing.
- a magnetic field is produced in the direction HA by a magnet (not shown) to focus the electrons.
- fins 30 are added to the anode 20.
- the fins are steel or copper plates l inch wide, 5 inches lon-g, 1/16 inch thick and spaced about -1/2 inch apart, or with spacing at least equal to or greater than the width of the fins or, in other terms, the spacing being at least equal to or greater than the depth of the troughs 31 formed between iins and opening toward the plasma.
- the target 24 is a 6 inch long sheet and typical line of sight paths for material sputtered from the target are indicated by lines 32 with the lins providing very effective masking provided in certain regions of the anode structure, e.g. at 33.
- the masked regions will eventually be coated with sputtered insulator material due to secondary collisions of sputtered material in flight. But this coating of masked areas will occur later and at a slower rate than the directly exposed anode structure.
- FIG. 2 shows a second embodiment of the invention wherein the fins 30 on anode 20 are inclined away from the target 24 at an angle l equal to 45 degrees to enhance masking.
- FIG. 3 shows a third embodiment of the invention wherein the masking is provided by a wire mesh 30" spot welded to the anode 20.
- the target 24, 26 is a solid or transparent (helix or cage) cylinder instead of the iiat plate structure of FIG. l concentric ring fins would be more appropriate than the flat plate fin structure of FIG. 1.
- the fins could be made of different widths to provide troughs 31 of different depths or the fins might be bent for more effective masking and made non-conductive to minimize disturbance of the electrical field of the apparatus.
- the troughs 31 could be formed of grooves milled out of a block anode structure.
- a sputtering device comprising an anode, an electron source and a sputter-target disposed in a vacuum zone
- the electron source producing electrons moving along an electron path from said source to the anode and the target being essentially parallel to and offset from said path and biased to attract, to a face thereof opening toward the electron path, ions formed in a plasma in the region of said path by collison between the electrons and residual gas molecules of said vacuum
- said anode extending in cross-section transversely to the electron path, and having a surface facing the electron path, said surface being per se in line-of-sight relation to said sputter target face
- the improvement comprising projections on said anode surface extending away from said surface to at least partially block said line-of-sight relation to said target surface.
- anode has the form of a plate extending transversely to the electron path and the masking is provided by troughs opening towards the plasma.
- troughs are formed by fins attached to an anode member and extending parallel to said target.
Description
May 26,1970 3,514,391
M. H. HABLANIAN ETAL SPUTTERING APPARATUS WITH FINNED ANODE Filed May 5, 19,67
FIG. 3
United States Patent O 3,514,391 SPUI'I'ERING APPARATUS WITH FINNED ANODE Marsbed H. Hablanian, Wellesley, Calvin H. Hemeon, East Boston, and Emil C. Muly, Jr., Needham, Mass., assignors to National Research Corporation, Newton Highlands, Mass., a corporation of Massachusetts Filed May 5, 1967, Ser. No. 636,423 Int. Cl. C23c 15/00 U.S. Cl. 204-298 4 Claims ABSTRACT F THE DISCLOSURE A low energy sputtering apparatus is provided with a finned anode to mask parts of the anode from sputtered target material.
'This application relates to sputtering equipment and particularly to low energy sputtering equipment used for sputter coating of insulator materials.
It is already known in the art from the publications of Wehner and co-workers to sputter materials in vacuum by using a separate anode, cathode and target electrodes wherein a plasma is formed by electrons moving from cathode to anode and colliding with residual gas molecules in the vacuum to form positive ions. The target electrode is biased to attract the ions which impinge into the target and sputter particles off the target surface. The particles may be intercepted and collected on a substrate to build up as a coating. This prior art also teaches the necessity of applying a high frequency alternating voltage as the target bias when the target is made of insulating material to periodically neutralize a build-up of positive charge on the target surface.
We have discovered that the sputtering of insulators leads to a problem wherein the sputtering is dificult to maintain continuously. The source of this problem is that sputtered insulator material from the target collects on the anode as well as the substrate and as this process goes on, the voltage at the anode rises while anode current drops. In a short time, the plasma extinguishes.
It is the object of the invention to provide an improved sputtering apparatus which substantially solves this problem allowing continuous sputtering of insulators at low anode voltage.
This object s achieved, in general, by a new construction of anode comprising fins on the anode extending inwardly towards the plasma to define troughs therebetween which are open to and substantially facing the electron source and partially masked from the target so that there is no clear line of sight path from the target to these masked areas. Of course, secondary collisions lead to eventual coating of the troughs by the target material and eventual extinguishment of the plasma.
But using this anode we have demonstrated the ability to run in a low energy sputtering of quartz for over an hour, and substantially more, without the onset of drastic voltage rise. This is sufiicient for many practical purposes and we have established the feasibility of this concept for tailoring other anodes to other insulator sputtering tasks.
Other objects, features and advantages of the invention will in part be obvious and will in part appear hereinafter.
The invention is now specifically described with reference to the accompanying drawings in which FIG. 1 is a diagram of the apparatus arranged according to a preferred embodiment of the invention and FIGS. 2-3 are drawings of modified anodes for use in the arrangement of FIG. l.
Referring to FIG. 1 there is shown an electron source assembly 10 including a thermionic filament 12 enclosed by a grounded enclosure 14 having an exit port 16.
p ICC Adjacent to the exit port is an auxiliary anode (or grid) electrode 18. An anode electrode is provided at 20. Electrons are emitted at the filament and drawn to anode 20 along an electron path coinciding approximately with the axis 22. A plasma is produced along the electron path consisting of the electrons and ions produced by collision of the electrons With gas molecules. A sputtering target 24 of insulating material, such as quartz, is mounted on a supporting electrode 26 connected to a radio frequency power source 28. A grounded Paschen shield 27 is provided for the target electrode. A substrate to be coated with sputtered target material may be located at 29. Of course, the apparatus may be used without the substrate, for instance for etching the target material, or with the vacuum vessel as a substrate for use as a getter ion pump. All of the electrodesanode 20, target 26, grid 18 and enclosure 14are cooled by appropriate cooling means not shown. The anode is biased to about 40 volts by a power supply (not shown), the grid is biased to about 39 volts by a power supply (not shown). The filament 12 is powered by standard industrial house power. All the above apparatus is contained in an hermetically sealed vacuum vessel (not shown) evacuated to about 2 l0-4 torr as indicated in the drawing. A magnetic field is produced in the direction HA by a magnet (not shown) to focus the electrons.
All the above described apparatus is prior art with respect to the present invention.
According to a distinct preferred embodiment of the present invention, fins 30 are added to the anode 20. Typically, in a 6- inch diameter anode 20, made of 1A; inch thick steel of copper disk, the fins are steel or copper plates l inch wide, 5 inches lon-g, 1/16 inch thick and spaced about -1/2 inch apart, or with spacing at least equal to or greater than the width of the fins or, in other terms, the spacing being at least equal to or greater than the depth of the troughs 31 formed between iins and opening toward the plasma.
Typically the target 24 is a 6 inch long sheet and typical line of sight paths for material sputtered from the target are indicated by lines 32 with the lins providing very effective masking provided in certain regions of the anode structure, e.g. at 33. Of course, the masked regions will eventually be coated with sputtered insulator material due to secondary collisions of sputtered material in flight. But this coating of masked areas will occur later and at a slower rate than the directly exposed anode structure.
FIG. 2 shows a second embodiment of the invention wherein the fins 30 on anode 20 are inclined away from the target 24 at an angle l equal to 45 degrees to enhance masking.
FIG. 3 shows a third embodiment of the invention wherein the masking is provided by a wire mesh 30" spot welded to the anode 20.
Still other embodiments may be made within the scope of the invention. For instance, where the target 24, 26 is a solid or transparent (helix or cage) cylinder instead of the iiat plate structure of FIG. l concentric ring fins would be more appropriate than the flat plate fin structure of FIG. 1. Also, the fins could be made of different widths to provide troughs 31 of different depths or the fins might be bent for more effective masking and made non-conductive to minimize disturbance of the electrical field of the apparatus.
As another variation the troughs 31 could be formed of grooves milled out of a block anode structure.
Still other variations within the scope of the invention will occur to those skilled in the art. It is therefore intended that the above disclosure shall be read as illustrative and not in a limiting sense.
What is claimed is:
1. In a sputtering device comprising an anode, an electron source and a sputter-target disposed in a vacuum zone With the electron source producing electrons moving along an electron path from said source to the anode and the target being essentially parallel to and offset from said path and biased to attract, to a face thereof opening toward the electron path, ions formed in a plasma in the region of said path by collison between the electrons and residual gas molecules of said vacuum, said anode extending in cross-section transversely to the electron path, and having a surface facing the electron path, said surface being per se in line-of-sight relation to said sputter target face, the improvement comprising projections on said anode surface extending away from said surface to at least partially block said line-of-sight relation to said target surface.
2. The apparatus of claim 1 wherein the anode has the form of a plate extending transversely to the electron path and the masking is provided by troughs opening towards the plasma.
3. The apparatus of claim 2 wherein the troughs are formed by fins attached to an anode member and extending parallel to said target.
4. The apparatus of claim 2 wherein the troughs are deeper than they are wide.
References Cited UNITED STATES PATENTS 7/ 1968 Moseson 204--298
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US63642367A | 1967-05-05 | 1967-05-05 |
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US3514391A true US3514391A (en) | 1970-05-26 |
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US636423A Expired - Lifetime US3514391A (en) | 1967-05-05 | 1967-05-05 | Sputtering apparatus with finned anode |
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Cited By (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3617463A (en) * | 1969-06-18 | 1971-11-02 | Ibm | Apparatus and method for sputter etching |
US4038171A (en) * | 1976-03-31 | 1977-07-26 | Battelle Memorial Institute | Supported plasma sputtering apparatus for high deposition rate over large area |
US4322277A (en) * | 1980-11-17 | 1982-03-30 | Rca Corporation | Step mask for substrate sputtering |
FR2568269A1 (en) * | 1984-07-26 | 1986-01-31 | Leybold Heraeus Gmbh & Co Kg | SPRAYING DEVICE FOR CATHODE SPRAYING INSTALLATIONS |
DE3612721A1 (en) * | 1986-04-16 | 1987-10-22 | Ver Glaswerke Gmbh | Apparatus for coating panes of glass using reactive cathode sputtering |
US5080774A (en) * | 1986-10-11 | 1992-01-14 | Saint-Gobain Vitrage | Surface configuration means for vacuum coating device |
EP0632142A1 (en) * | 1993-07-01 | 1995-01-04 | The Boc Group, Inc. | Magnetron sputtering apparatus and systems |
US5527439A (en) * | 1995-01-23 | 1996-06-18 | The Boc Group, Inc. | Cylindrical magnetron shield structure |
US5733419A (en) * | 1995-11-16 | 1998-03-31 | Balzers Aktiengesellschaft | Vacuum treatment chamber |
US5837057A (en) * | 1992-12-21 | 1998-11-17 | Canon Kabushiki Kaisha | Film forming apparatus with particle prevention plate |
US6006694A (en) * | 1997-12-05 | 1999-12-28 | Tegal Corporation | Plasma reactor with a deposition shield |
US6162297A (en) * | 1997-09-05 | 2000-12-19 | Applied Materials, Inc. | Embossed semiconductor fabrication parts |
US6390019B1 (en) | 1998-06-11 | 2002-05-21 | Applied Materials, Inc. | Chamber having improved process monitoring window |
US6495000B1 (en) * | 2001-07-16 | 2002-12-17 | Sharp Laboratories Of America, Inc. | System and method for DC sputtering oxide films with a finned anode |
US6673199B1 (en) | 2001-03-07 | 2004-01-06 | Applied Materials, Inc. | Shaping a plasma with a magnetic field to control etch rate uniformity |
US20040056211A1 (en) * | 2002-03-13 | 2004-03-25 | Applied Materials, Inc. | Method of surface texturizing |
US6933508B2 (en) | 2002-03-13 | 2005-08-23 | Applied Materials, Inc. | Method of surface texturizing |
US20050257742A1 (en) * | 2000-06-07 | 2005-11-24 | Tue Nguyen | Replaceable shielding apparatus |
US20060049042A1 (en) * | 2004-08-20 | 2006-03-09 | Jds Uniphase Corporation | Cathode for sputter coating |
US20060049041A1 (en) * | 2004-08-20 | 2006-03-09 | Jds Uniphase Corporation | Anode for sputter coating |
US20060081188A1 (en) * | 2004-10-14 | 2006-04-20 | Mitsubishi Denki Kabushiki Kaisha | Deposition system |
US20060292310A1 (en) * | 2005-06-27 | 2006-12-28 | Applied Materials, Inc. | Process kit design to reduce particle generation |
US20080081128A1 (en) * | 2006-09-28 | 2008-04-03 | Fujifilm Corporation | Film-forming system, film-forming method, insulating film, dielectric film, piezoelectric film, ferroelectric film, piezoelectric element and liquid discharge system |
US7439188B2 (en) | 1999-12-02 | 2008-10-21 | Tegal Corporation | Reactor with heated and textured electrodes and surfaces |
US20090194414A1 (en) * | 2008-01-31 | 2009-08-06 | Nolander Ira G | Modified sputtering target and deposition components, methods of production and uses thereof |
US20090250341A1 (en) * | 2004-08-20 | 2009-10-08 | Ockenfuss Georg J | Anode for sputter coating |
US20100155238A1 (en) * | 2008-12-23 | 2010-06-24 | Oc Oerlikon Balzers Ag | Rf sputtering arrangement |
EP2325350A1 (en) * | 2009-11-24 | 2011-05-25 | Applied Materials, Inc. | Anode rod for a sputtering system |
US20170316924A1 (en) * | 2016-04-27 | 2017-11-02 | Applied Materials, Inc. | Non-disappearing anode for use with dielectric deposition |
US10224188B2 (en) * | 2008-11-24 | 2019-03-05 | Evatec Ag | RF sputtering arrangement |
US11072852B2 (en) * | 2018-07-23 | 2021-07-27 | Applied Materials, Inc. | Pre-conditioned chamber components |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3393142A (en) * | 1964-08-20 | 1968-07-16 | Cons Vacuum Corp | Cathode sputtering apparatus with plasma confining means |
-
1967
- 1967-05-05 US US636423A patent/US3514391A/en not_active Expired - Lifetime
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3393142A (en) * | 1964-08-20 | 1968-07-16 | Cons Vacuum Corp | Cathode sputtering apparatus with plasma confining means |
Cited By (48)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3617463A (en) * | 1969-06-18 | 1971-11-02 | Ibm | Apparatus and method for sputter etching |
US4038171A (en) * | 1976-03-31 | 1977-07-26 | Battelle Memorial Institute | Supported plasma sputtering apparatus for high deposition rate over large area |
US4322277A (en) * | 1980-11-17 | 1982-03-30 | Rca Corporation | Step mask for substrate sputtering |
FR2568269A1 (en) * | 1984-07-26 | 1986-01-31 | Leybold Heraeus Gmbh & Co Kg | SPRAYING DEVICE FOR CATHODE SPRAYING INSTALLATIONS |
US4619755A (en) * | 1984-07-26 | 1986-10-28 | Hans Zapfe | Sputtering system for cathode sputtering apparatus |
DE3612721A1 (en) * | 1986-04-16 | 1987-10-22 | Ver Glaswerke Gmbh | Apparatus for coating panes of glass using reactive cathode sputtering |
US5080774A (en) * | 1986-10-11 | 1992-01-14 | Saint-Gobain Vitrage | Surface configuration means for vacuum coating device |
US5837057A (en) * | 1992-12-21 | 1998-11-17 | Canon Kabushiki Kaisha | Film forming apparatus with particle prevention plate |
US5683558A (en) * | 1993-07-01 | 1997-11-04 | The Boc Group, Inc. | Anode structure for magnetron sputtering systems |
US5487821A (en) * | 1993-07-01 | 1996-01-30 | The Boc Group, Inc. | Anode structure for magnetron sputtering systems |
EP0632142A1 (en) * | 1993-07-01 | 1995-01-04 | The Boc Group, Inc. | Magnetron sputtering apparatus and systems |
US5527439A (en) * | 1995-01-23 | 1996-06-18 | The Boc Group, Inc. | Cylindrical magnetron shield structure |
US5733419A (en) * | 1995-11-16 | 1998-03-31 | Balzers Aktiengesellschaft | Vacuum treatment chamber |
US6162297A (en) * | 1997-09-05 | 2000-12-19 | Applied Materials, Inc. | Embossed semiconductor fabrication parts |
US6006694A (en) * | 1997-12-05 | 1999-12-28 | Tegal Corporation | Plasma reactor with a deposition shield |
US6170431B1 (en) * | 1997-12-05 | 2001-01-09 | Tegal Corporation | Plasma reactor with a deposition shield |
US6360686B1 (en) * | 1997-12-05 | 2002-03-26 | Tegal Corporation | Plasma reactor with a deposition shield |
US6712927B1 (en) | 1998-06-11 | 2004-03-30 | Applied Materials Inc. | Chamber having process monitoring window |
US6390019B1 (en) | 1998-06-11 | 2002-05-21 | Applied Materials, Inc. | Chamber having improved process monitoring window |
US20080318432A1 (en) * | 1999-12-02 | 2008-12-25 | Tegal Corporation | Reactor with heated and textured electrodes and surfaces |
US7439188B2 (en) | 1999-12-02 | 2008-10-21 | Tegal Corporation | Reactor with heated and textured electrodes and surfaces |
US20050257742A1 (en) * | 2000-06-07 | 2005-11-24 | Tue Nguyen | Replaceable shielding apparatus |
US7115169B2 (en) | 2000-06-07 | 2006-10-03 | Tegal Corporation | Replaceable shielding apparatus |
US6673199B1 (en) | 2001-03-07 | 2004-01-06 | Applied Materials, Inc. | Shaping a plasma with a magnetic field to control etch rate uniformity |
US6495000B1 (en) * | 2001-07-16 | 2002-12-17 | Sharp Laboratories Of America, Inc. | System and method for DC sputtering oxide films with a finned anode |
US6933508B2 (en) | 2002-03-13 | 2005-08-23 | Applied Materials, Inc. | Method of surface texturizing |
US20040056211A1 (en) * | 2002-03-13 | 2004-03-25 | Applied Materials, Inc. | Method of surface texturizing |
US6812471B2 (en) | 2002-03-13 | 2004-11-02 | Applied Materials, Inc. | Method of surface texturizing |
US20060049042A1 (en) * | 2004-08-20 | 2006-03-09 | Jds Uniphase Corporation | Cathode for sputter coating |
US20060049041A1 (en) * | 2004-08-20 | 2006-03-09 | Jds Uniphase Corporation | Anode for sputter coating |
US7879209B2 (en) | 2004-08-20 | 2011-02-01 | Jds Uniphase Corporation | Cathode for sputter coating |
US20090250341A1 (en) * | 2004-08-20 | 2009-10-08 | Ockenfuss Georg J | Anode for sputter coating |
US8500973B2 (en) | 2004-08-20 | 2013-08-06 | Jds Uniphase Corporation | Anode for sputter coating |
US20070022957A1 (en) * | 2004-10-14 | 2007-02-01 | Mitsubishi Denki Kabushiki Kaisha | Deposition system |
US20060081188A1 (en) * | 2004-10-14 | 2006-04-20 | Mitsubishi Denki Kabushiki Kaisha | Deposition system |
US20060292310A1 (en) * | 2005-06-27 | 2006-12-28 | Applied Materials, Inc. | Process kit design to reduce particle generation |
US20080081128A1 (en) * | 2006-09-28 | 2008-04-03 | Fujifilm Corporation | Film-forming system, film-forming method, insulating film, dielectric film, piezoelectric film, ferroelectric film, piezoelectric element and liquid discharge system |
US20090194414A1 (en) * | 2008-01-31 | 2009-08-06 | Nolander Ira G | Modified sputtering target and deposition components, methods of production and uses thereof |
US10224188B2 (en) * | 2008-11-24 | 2019-03-05 | Evatec Ag | RF sputtering arrangement |
CN102265375A (en) * | 2008-12-23 | 2011-11-30 | 欧瑞康巴尔查斯股份有限公司 | RF sputtering arrangement |
US8268142B2 (en) * | 2008-12-23 | 2012-09-18 | Oc Oerlikon Balzers Ag | RF sputtering arrangement |
US20100155238A1 (en) * | 2008-12-23 | 2010-06-24 | Oc Oerlikon Balzers Ag | Rf sputtering arrangement |
CN102265375B (en) * | 2008-12-23 | 2014-12-24 | 欧瑞康先进科技股份有限公司 | RF sputtering arrangement |
EP2325350A1 (en) * | 2009-11-24 | 2011-05-25 | Applied Materials, Inc. | Anode rod for a sputtering system |
US20110120862A1 (en) * | 2009-11-24 | 2011-05-26 | Applied Materials, Inc. | Anode rod for a sputtering system |
US20170316924A1 (en) * | 2016-04-27 | 2017-11-02 | Applied Materials, Inc. | Non-disappearing anode for use with dielectric deposition |
US11114289B2 (en) * | 2016-04-27 | 2021-09-07 | Applied Materials, Inc. | Non-disappearing anode for use with dielectric deposition |
US11072852B2 (en) * | 2018-07-23 | 2021-07-27 | Applied Materials, Inc. | Pre-conditioned chamber components |
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