US3600327A - Lubricating oil compositions having improved sludge dispersancy - Google Patents

Lubricating oil compositions having improved sludge dispersancy

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Publication number
US3600327A
US3600327A US802639*A US3600327DA US3600327A US 3600327 A US3600327 A US 3600327A US 3600327D A US3600327D A US 3600327DA US 3600327 A US3600327 A US 3600327A
Authority
US
United States
Prior art keywords
lubricating oil
oil compositions
additives
oil
reacting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US802639*A
Inventor
Shih-En Hu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Application granted granted Critical
Publication of US3600327A publication Critical patent/US3600327A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12—Reaction products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026—Butene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/22—Alkylation reaction products with aromatic type compounds, e.g. Friedel-crafts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/287—Partial esters
    • C10M2207/289—Partial esters containing free hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C10M2215/065—Phenyl-Naphthyl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/046—Overbasedsulfonic acid salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/086—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing sulfur atoms bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2221/00—Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2221/00—Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2221/04—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives

Abstract

MINERAL LUBRICATING OIL COMPOSITIONS ARE PREPARED CONTAINING OIL-SOLUBLE ADDITIVES HAVING IMPROVED SLUDGE INHIBITION AND DISPERSION, ANTIWEAR ACTIVITY, AND ANTIOXIDANT PROPERTIES UNDER HIGH TEMPERATURE CONDITIONS. THE NOVEL ADDITIVES ARE PREPARED BY REACTING, AT BETWEEN ABOUT 215* AND ABOUT 255*C., ELEMENTAL SULFUR WITH OIL-SOLUBLE HYDROCARBONS CONTAINING ALIPHATIC RADICALS AND REACTING THE SULFURIZED PRODUCT WITH PRIMARY, SECONDARY, OR TERTIARY MONO, DI OR POLY ALIPHATIC AMINES OR AMINO ALCOHOLS. SLUDGE DISPERSING AMOUNTS OF THE ADDITIVES ARE EMPLOYED IN THE OIL COMPOSITIONS AND USUALLY RANGE BETWEEN ABOUT 0.05 AND ABOUT 10.0 WT. PRECENT OF THE TOTAL COMPOSITION. THEY ARE PARTICULARLY USEFUL IN LUBRICATING OIL WHICH ALSO CONTAINS AN ANTIWEAR AGENT, I.E., THE ZINC SALT OF A DIALKYL DITHIOPHOSPAHTE.
US802639*A 1969-02-26 1969-02-26 Lubricating oil compositions having improved sludge dispersancy Expired - Lifetime US3600327A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US80263969A 1969-02-26 1969-02-26

Publications (1)

Publication Number Publication Date
US3600327A true US3600327A (en) 1971-08-17

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4025451A (en) * 1973-09-14 1977-05-24 Ethyl Corporation Sulfurized mannich bases as lubricating oil dispersant
US4059534A (en) * 1976-04-07 1977-11-22 Union Carbide Canada Limited Hydrocarbon/silicon oil lubricating compositions for low temperature use
US4263153A (en) * 1979-10-11 1981-04-21 Exxon Research & Engineering Co. Oxazoline containing dispersants stabilized against oxidation with sulfur and fuels and lubricants containing same
US4283293A (en) * 1978-08-07 1981-08-11 Mobil Oil Corporation Metal working lubricant compositions
US4317738A (en) * 1980-10-10 1982-03-02 Standard Oil Company (Indiana) Dispersants and dispersant viscosity modifiers from oxidized-sulfurized olefins
US4317739A (en) * 1980-10-10 1982-03-02 Standard Oil Company (Indiana) Aminated sulfurized olefin funtionalized with a boron compound and formaldehyde
US4317772A (en) * 1980-10-10 1982-03-02 Standard Oil Company (Indiana) Process for preparation of aminated sulfurized olefins using alkaline earth metal compounds
US4654156A (en) * 1985-09-12 1987-03-31 Mobil Oil Corporation Sulfurized olefins as antiwear additives and compositions thereof
US4661274A (en) * 1986-01-13 1987-04-28 Mobil Oil Corporation Additive for lubricants and hydrocarbon fuels comprising reaction products of olefins, sulfur, hydrogen sulfide and nitrogen containing polymeric compounds
US4711736A (en) * 1986-02-24 1987-12-08 Mobil Oil Corporation Sulfurized olefins as antiwear/extreme pressure additives for lubricants and fuels and compositions thereof
US4786425A (en) * 1986-01-13 1988-11-22 Mobil Oil Corporation Additive for lubricants and hydrocarbon fuels comprising reaction products of olefins, sulfur, hydrogen sulfide and polymeric succinimide compounds
WO1989012670A1 (en) * 1988-06-23 1989-12-28 Mobil Oil Corporation Sulfide adducts of high viscosity index polyalpha-olefins
US5028345A (en) * 1988-12-07 1991-07-02 Ethyl Petroleum Additives, Inc. Lubricating oil composition
US5403960A (en) * 1991-08-01 1995-04-04 Ethyl Petroleum Additives, Inc. Process for sulfurized olefinic product
US5410088A (en) * 1991-08-01 1995-04-25 Ethyl Petroleum Additives, Inc. Process for sulfurized olefinic product

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4025451A (en) * 1973-09-14 1977-05-24 Ethyl Corporation Sulfurized mannich bases as lubricating oil dispersant
US4059534A (en) * 1976-04-07 1977-11-22 Union Carbide Canada Limited Hydrocarbon/silicon oil lubricating compositions for low temperature use
US4283293A (en) * 1978-08-07 1981-08-11 Mobil Oil Corporation Metal working lubricant compositions
US4263153A (en) * 1979-10-11 1981-04-21 Exxon Research & Engineering Co. Oxazoline containing dispersants stabilized against oxidation with sulfur and fuels and lubricants containing same
US4317772A (en) * 1980-10-10 1982-03-02 Standard Oil Company (Indiana) Process for preparation of aminated sulfurized olefins using alkaline earth metal compounds
US4317739A (en) * 1980-10-10 1982-03-02 Standard Oil Company (Indiana) Aminated sulfurized olefin funtionalized with a boron compound and formaldehyde
US4317738A (en) * 1980-10-10 1982-03-02 Standard Oil Company (Indiana) Dispersants and dispersant viscosity modifiers from oxidized-sulfurized olefins
US4654156A (en) * 1985-09-12 1987-03-31 Mobil Oil Corporation Sulfurized olefins as antiwear additives and compositions thereof
US4661274A (en) * 1986-01-13 1987-04-28 Mobil Oil Corporation Additive for lubricants and hydrocarbon fuels comprising reaction products of olefins, sulfur, hydrogen sulfide and nitrogen containing polymeric compounds
US4786425A (en) * 1986-01-13 1988-11-22 Mobil Oil Corporation Additive for lubricants and hydrocarbon fuels comprising reaction products of olefins, sulfur, hydrogen sulfide and polymeric succinimide compounds
US4711736A (en) * 1986-02-24 1987-12-08 Mobil Oil Corporation Sulfurized olefins as antiwear/extreme pressure additives for lubricants and fuels and compositions thereof
WO1989012670A1 (en) * 1988-06-23 1989-12-28 Mobil Oil Corporation Sulfide adducts of high viscosity index polyalpha-olefins
US5028345A (en) * 1988-12-07 1991-07-02 Ethyl Petroleum Additives, Inc. Lubricating oil composition
US5403960A (en) * 1991-08-01 1995-04-04 Ethyl Petroleum Additives, Inc. Process for sulfurized olefinic product
US5410088A (en) * 1991-08-01 1995-04-25 Ethyl Petroleum Additives, Inc. Process for sulfurized olefinic product

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