US3716359A - Cyclic recording system by the use of an elastomer in an electric field - Google Patents

Cyclic recording system by the use of an elastomer in an electric field Download PDF

Info

Publication number
US3716359A
US3716359A US00101729A US3716359DA US3716359A US 3716359 A US3716359 A US 3716359A US 00101729 A US00101729 A US 00101729A US 3716359D A US3716359D A US 3716359DA US 3716359 A US3716359 A US 3716359A
Authority
US
United States
Prior art keywords
layer
imaging member
elastomer
electric field
elastomer layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US00101729A
Inventor
N Sheridon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xerox Corp
Original Assignee
Xerox Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xerox Corp filed Critical Xerox Corp
Application granted granted Critical
Publication of US3716359A publication Critical patent/US3716359A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14Metallic material, boron or silicon
    • C23C14/20Metallic material, boron or silicon on organic substrates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D39/00Application of procedures in order to connect objects or parts, e.g. coating with sheet metal otherwise than by plating; Tube expanders
    • B21D39/02Application of procedures in order to connect objects or parts, e.g. coating with sheet metal otherwise than by plating; Tube expanders of sheet metal by folding, e.g. connecting edges of a sheet to form a cylinder
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G16/00Electrographic processes using deformation of thermoplastic layers; Apparatus therefor
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02Charge-receiving layers
    • G03G5/022Layers for surface-deformation imaging, e.g. frost imaging
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/10Bases for charge-receiving or other layers
    • G03G5/102Bases for charge-receiving or other layers consisting of or comprising metals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S101/00Printing
    • Y10S101/37Printing employing electrostatic force

Definitions

  • ABSTRACT The applications of elastomers to various imaging techniques are described which may be used for the cyclic recording, storage and subsequent erasure of optical information.
  • Several embodiments of the invention are described, all of which form images by the elastic deformation of a thin elastomer layer.
  • the pattern of the surface deformation in general, follows the light distribution of the optical image being recorded. This image is formed on a photoconductive layer which is adjacent to, or integral with, the elastomer layer.
  • An electric field is placed across the elastomer and the photoconductor layers, the field being modulated by the action of the image light on the conductivity of the photoconductor and provides the mechanical force necessary to deform the elastomer.
  • thermoplastic surface relief imaging taught the recording of images by means of deformations in an otherwise smooth thermoplastic surface.
  • the image information is recorded as a hill and valley structure on this surface. Light reflected or transmitted through this surface may be used to make the recorded image visible because such light will be scattered or diffracted by this structure.
  • Three basic types of thermoplastic surface relief imaging may be distinguished.
  • frost imaging which may be seen in U.S. Pat. Nos. 3,196,009, 3,196,011, 3,258,336 and 3,196,008 as a few of many examples.
  • Frost imaging has been practiced in the past by creating a voltage pattern across a thin layer of insulating thermoplastic. This voltage pattern is usually established by means of an adjacent layer of photoconductor material although the thermoplastic itself may be made photoconductive. In use, the electric field is placed across the thermoplastic/photoconductor sandwich or across the photoconductive thermoplastic. The light intensity pattern of the image formed on the photoconductor now creates a varying electrostatic field.
  • the third type of surface relief imaging is actually a variant of the first two, but because of its importance of l/2T and being referred to as frost.
  • images having spatial frequencies within the region of the resonant frequency of the deformable surface will be faithfully reproduced by deformations of this surface.
  • images, on the other hand, having spatial frequencies much lower than this resonant frequency will tend to form frost in the regions of greater illumination.
  • good quality images may be reconstructed from frost deformations.
  • the inherent noise strucdeserves to be treated separately.
  • a hologram is a recording of the interference pattern between two coherent light beams.
  • One light beam usually contains information about an object and the other is a reference beam, generally of simple structure.
  • the interference pattern generally resembles a somewhat garbled image of a screen. If the spatial frequency of the screen approximates the resonant frequency of the thin liquid layer, the surface would deform along the structure of the interference pattern and little noise would be generated.
  • Applicant has invented improved apparatus and methods for a fully cyclycable imaging device on which images may be recorded, stored for short periods of time and erased at will.
  • the inventor provides an imaging member which comprises a substrate that is conductive or has a conductive surface. Coated on this surface is a photoconductive layer whose conductivity is dependent upon illumination, and coated above this is an elastomer layer. In another embodiment a separate photoconductor layer is not used, but rather the elastomer layer is photoconductive.
  • a deformable conductive layer including either a flexible conductive member, a conductive liquid, a conductive gas or a layer of electrostatic charge is placed contiguous to the surface of the elastomer.
  • An electric field established between the deformable conductive layer and the conductive substrate increases in those regions where the photoconductive layer is exposed to electromagnetic radiation (hereafter referred to as light) causing the elastomer to deform in those regions.
  • electromagnetic radiation hereafter referred to as light
  • Two types of imaging behavior have been observed. In the case of very compliant elastomers and large electric fields theelastomer remains deformed while the electric field is maintained. This deformation is not substantially affected by subsequent illumination of the photoconductor, and thus may be said to be electrically locked.
  • the recorded image information may now be read out at leisure with any brightness illumination.
  • the deformation is removed by removing the field, allowing the elastomer to relax.
  • the image may be erased much more quickly.
  • a new image may now be formed.
  • the electrical locking property of the elastomer exists only above a certain value of the electric field. Below this field threshold value the image erases slowly especially upon exposure of the photoconductor to thermoplastic imaging device, is capable of forming three types of image: frost images, screened frost frequency bandwidth.
  • frost images screened frost frequency bandwidth.
  • the greatest response is in the neighborhood of the resonant frequency, usually equal to approximately l/2T as in the case of therrnoplastics.
  • the third type of surface relief image called screened frost is suitable for recording images having spatial frequencies substantially lower than the resonant deformation frequency of the elastomer layer. This is formed by placing an absorption type line grating between the projected image light and the photoconductor upon which it is imaged. The elastomer will now deform along the pattern of this high spatial frequency screen in those areas where it is illuminated and, therelight. This constitutes the second type of imaging fore, will not form frost.
  • the screened surface relief image will then consist of segments of the shadow of the screen. The image obtained by illuminating the elastomer will, thus, have a fine structure of lines superimposed upon the original image that was recorded. If this line structure is objectionable, it may be removed by suitable optical filtering techniques well known in the art.
  • the preferred location of the screen e.g., a line grating, is immediately adjacent to a photoconductive layer in the imaging structure.
  • Other types of screens that may be similarly located are described in two copending applications, both titled Methods of Organized Thermoplastic Xerography and Photoreceptor Structure Therefor, one in the name of Lloyd F. Bean and the other in the name of John C. Heurtley, filed Sept. 18, I970, and Sept. I8, 1970, Ser. Nos. 73,406 and 73,317, respectively.
  • FIG. I is a side sectional view of the elastomer imaging apparatus of a first embodiment of the present invention', I
  • FIG. 2 is a side sectional view of the elastomer imaging apparatus of a second embodiment of the present invention
  • FIG. 3 is a side sectional view of the elastomer imag-' ing apparatus of a third embodiment of the present invention.
  • FIG. 4 is a side sectional view of the elastomer imaging apparatus of a fourth embodiment of the present invention. I I
  • FIG. 5 is a side sectional view of a multilayered elastomer in accordance with the principles of the present invention.
  • FIGS. 6 to 10 are partly schematic, partly side sectional view of various physical applications of the principles of the present invention.
  • FIG. 11 is a schematic, perspective view of a computer print-out systems using the imaging structures and methods of the present invention.
  • elastomer in the various forms used herein is defined as a usually amorphous material which exhibits a restoring force in response to a deformation; that is, an amorphous material which deforms under a force, and, because of volume and surface forces, tends to return to the form it had before the force was applied.
  • the first embodiment of the present application shown in FIG. 1 is an elastomeric imaging device in which charges are placed on the surface of the elastomer by means of a corona discharge.
  • Modified I forms of a corona discharge device are well known in light.
  • Such a photoconductor is often a mixture of polyn-vinyl carbazole and a sensitizing dye.
  • the thicknessv of the photoconductor will probably range from 0.l microns to 200 microns, depending largely upon the spatial frequency of the information to be recorded.
  • the elastomer layer 4 may be of a class of elastomeric soft solid materials for use in this application including both natural, such as natural rubbers and synthetic polymers which have rubber like characteristics, i.e., are elastic and include materials such as styrene-butadiene, poly-butadiene, neoprene, butyl, polyisoprene, nitrile and ethylene propylene rubbers.
  • Preferred elastomers for use in this application include: water based gelatin gels and dimethylpolysiloxane based silicone gels.
  • These materials may be coated on the photoconductor as monomers and polymerized in place or they may be coated on the surface from solutions in volatile solvents which will evaporate and leave a thin uniform layer. In general, these materials should be reasonably good insulators, having volume resistivities in excess of IOohm-centimeters.
  • the preferred elastomer is a transparent composition comprising an elastomeric dimethylpolysiloxane silicone gel made by steps including combining about one part of Dow Corning No. I82, silicone resin potting compound and anywhere from about zero to about 30 parts of Dow Corning No. 200 dimethylpolysiloxane silicone oil.
  • Suitable resins include transparent flexible organosilonane resins of the type described in US. Pat. No. 3,284,406 in which a major portion of the organic groups attached to silicon are methyl radicals.
  • the thickness of the elastomer layer will range from approximately 0.] microns to approximately 2,000 microns, depending upon the spatial frequency of the information required.
  • Various optical properties of the device may be enhanced by a suitable selection of the reflective mirror finish so that reconstruction light will pass through the elastomer, reflect from it and pass through the elastomer once again; thereby obtaining twice the modulation that a transmissive device will impart.
  • the substrate is to be transparent, commonly available NESA glass could be used. This is a tin oxide coated glass conductive on the surface corresponding to layer 2 in FIG. 1. Alternatively, it could be a piece of transparent glass with a metallic conductive layer on the surface, a layer thin enough to be transparent.
  • a metallic substrate may be used.
  • the substrate could be a plastic material such as Mylar or acetate, if flexibility were desired.
  • layer 2 which is a conductive layer must be added. This is normally a transparent, or partially transparent layer.
  • the photoconductive layer 3 is a material which will allow the passage of more electric charge in those regions which are exposed to light.
  • This definition of a photoconductor may be extended to any materials in which the conductivity is inhibited by the presence of elastic modulus of the material used. For example, a stiffer elastomer will recover more rapidly from an image when the electric field is removed, that is, may be erased more quickly. 0n the other hand, a material having a low elastic modulus will be capable of greater deformations and hence greater optical modulation for a given value of electric field.
  • the corona charging apparatus 5 may be a stationary charging unit provided such a unit provides enough uniformity of charge deposition, or it may be a scanning system.
  • This device places positive or negative charges on the surface of the elastomer.
  • the voltage drop across the elastomer photoconductive sandwich will lie in the range of 1 to 25,000 volts depending on the modulus of elasticity of the elastomer and its thickness, as well as certain properties of the photoconductor.
  • Particular types of scoratron devices which have been found useful in corona charging are disclosed in the Vyverberg US. Pat. No. 2,836,725 and ability of the elastomer to hold charge on its surface, to
  • thermoplastic deformations assume a definite limit for a given electric field because elastic forces oppose the deformation.
  • the thermoplastic deformations do not encounter such a definite limit for a given field as long as the thermoplastic is maintained in a softened condition. To erase this image, the field across the elastomer is removed; to erase more quickly the field across the elastomer is reversed. Now the device is ready to accept another image.
  • FIG. 2 is a second embodiment wherein an electric field is created across the elastomer 9 and photoconductor layer 8 by means of a thin continuous conducpropagating from the right may be used to reconstruct the image.
  • the light sources used may be of different wavelengths and/or intensities and/or one light source may be coherent and the other noncoherent.
  • this device may be used to convert an image formed in one wavelength into an equivalent image formed in a different wavelength.
  • the apparatus shown in H0. 2 will provide great amplification of an input image, such amplified light being used, for example, for large panel displays.
  • the reconstruction light may be coherent, e.g., that produced by a laser, so that image processing steps may be performed on the surface deformation image which is formed with noncoherent light propagating from the left.
  • the light giving rise to the surface deformation image may be coherent light while the reconstruction light may be non-coherent. This latter case is desirable because non-coherent light is more pleasing to the human eye and current coherent light generators are limited to production of light within narrow wavelength bands, i.e., one color such as red.
  • a reason for having coherent light for forming the surface deformation image arises when his the reconstruction light for forming images with holograms. Therefore, the present device may have a holographically reconstructed image projected onto it forming a surface deformation image that is viewed with non-coherent light of substantially greater intensity as suited for large panel displays.
  • substrate 6 may be transparent or opaque depending upon use.
  • Conductive layer 7 is optional and is used if substrate 6 is not conductive. If substrate 6 is transparent then the conductive layer 7 would generally also be transparent.
  • the photoconductive layer 8 Over the photoconductive layer 8 is the elastomer layer 9.
  • the thin conductive layer 10 must be flexible enough to follow the deformations of the elastomer layer 9. if the conductive layer 10 is opaque, for example, a thin metal film, the substrate 6 and conductive layer 7 must be transparent to allow image information to reach the photoconductive layer 8. In this case, image information can be read out continuously if the readout light is incident from the right.
  • the conductive layer 10 is transparent, light may be reflected from its surface or the device may be used in transillumination, provided I also be used, such as Dow Corning resin ECR 34 may be coated on the surface of the elastomer 9.
  • Other conductive layers such as may occur to one skilled in the art, may also be used within the principles of the present invention. To form and lock the deformation image, the values of voltage between substrate 6 and conductive layer 10 would be approximately between i and 25,000 volts, depending on the thickness, and other characteristics of elastomer 9.
  • the requirements for conductive layer 10 include: sufiicient conductivity to become an equipotental surface when connected to an electrical energy source; sufficient flexibility to follow the deformations of the elastomer; sufficient fatigue resistance to withstand numerous and rapid formations and erasures of surface deformations; and, in some cases, high opacity and reflectivity as when being read out by a high intensity light source to which the photoconductive layer is sensitive.
  • the preferred materials for conductive layer 10 include gold and indium.
  • the layer is formed by steps including vapor depositing the materials onto the elastomer which involves heating a material to or above its melting point and condensing the vapors on the desired surface. This technique is well understood in the art and conventional practices are followed in evaporating and condensing the materials. However, a problem associated with shrinkage of a condensed l
  • suitable high melting point materials besides gold include aluminum, silver, magnesium, copper,
  • Aluminum metal layer is overcome by novel techniques in order to fabricate a conductive layer l0.meeting the above requirements. Vapor deposited metals tend to shrink, i.e., contract, as they cool and at some thermo-energy state the metal layer tends to break up or crack making the layer discontinuous. This break up of a metal layer is referred to herein as mud-cracking" since mud cracks are broadly descriptive of the appearance of the layer after shrinkage.
  • the instant novel technique includes vapor depositing a second metal over the first before the first has mudcracked. The two materials may be vapor deposited simultaneously. The second metal is selected so as to have a lower melting point than the first deposited metal.
  • the final product is a continuous layer meeting the above requirements which yet does not experience mud cracking over a wide range of temperatures.
  • the described layer may include portions where the two metals (or other suitable materials) are coated one over the other, portions where the two metals are intermixed macroscopically as well as microscopically (e.g., to form an alloy) and portions where they reside side by side.
  • additional materials may be added to the layer to enhance or suppress particular characteristics.
  • the preferred materials of gold and indium have high and low melting points respectively. Mud cracking is usually observed in vapor deposited gold layers within minutes after cooling to room temperatures. This usually provides ample time to vapor deposit the indium onto the gold layer.
  • An example of a highly successful coating is one formed by depositing from 50 to several thousand angstroms of gold followed by depositing onto this gold layer from 50 to several thousand angstroms of indium.
  • the resultant layer is continuous and exhibits no mud cracking over a wide range of temperatures.
  • the indium is particularly advantageous because it increases the opacity of the resultant layer and, because of its silver appearance, enhances the reflectivity of the layer.
  • indium by itself is not a highly efficient material for layer 10 because of poor conductivity.
  • the poor conductivity is peculiar to low melting point materials because they tend to form islands during condensation which do not join together into a continuous layer of a reasonable thickness. Accordingly, it is observed that vapor deposition of single materials (or alloys thereof), whether high or low melting point materials, yields layers that are less satisfactory than the layer comprised of high and low melting point materials.
  • the foregoing problems of mud cracking and island forming may not arise if the conductive layer 10 is formed by chemical reaction, precipitation out of a solution, electrophoresis, electrolysis and/or other techniques.
  • Over the conductive layer 10 in FIG. 2 may also be an optional transparent insulating layer of oil. lts purpose is to make less stringent the fabrication requirements for this apparatus.
  • the presence of pin holes in the elastomer layer 9 may cause the apparatus in FIG. 2 to short circuit, possibly destroying its performance.
  • the addition of the layer 12 prevents such short circuits from disrupting the performance of the device by allowing insulating oil to flow into such pin holes.
  • Layer 12 serves another important function when it has an index of refraction different than air.
  • the presence of oil 12 over the conductive layer 10 means light propagating from the right will be modulated more than it would be if only air was present. The reason being is that for the same magnitude of surface deformation the optical path changes are proportional to the refraction index of the medium adjacent to the surface.
  • Power supply 11 of FIG. 2 provides DC voltage of one polarity to form a deformation image on the surface of the elastomer.
  • the polarity required depends upon the nature of the photoconductor. Power supply 11 must be capable of being turned off to erase the image, or, undergo a shift in polarity to more rapidly erase the image. For a television type of picture wherein approximately 30 images per second are formed, stored and erased, the power supply must be capable of undergoing such cycles with appropriate speed.
  • the extent of the deformation and the rapidity with which information may be erased is dependent upon the voltages supplied by the power supply.
  • the stability of the voltage output of the power supply must be great enough to prevent unwanted erasure of the image.
  • An alternate scheme for erasing the surface deformation image is to position a strobe light at the left in FIG. 2 to flood the photoconductive layer 8 with light thereby erasing the modulated field pattern across the structure set up by the imagewise light. This operation is appropriate as long as the fields across the elastomer layer 9 are below a level causing the surface deformations to be locked.
  • the embodiment in FIG. 3 employs a very thick conductive liquid 16 in contact with elastomer 15 to provide the necessary electric field across the elastomer/photoconductor sandwich.
  • substrate 12 may be transparent or opaque and in turn may or may not be conductive.
  • Conductive layer 13 must be present if substrate layer 12 is not conductive. if substrate 12 is transparent then conductive layer 13 will normally also be transparent. Coated on the conductive layer 13 are 'not be transparent.
  • Non-transparent conductive fluids include mercury, room-temperature molten gallium-indium alloys, etc.
  • Transparent fluids include water to which conductive impurities have been added.
  • the fluid 16 should have a substantially dif ferent refractive index than the elastomer in order that defonnations of the elastomer surface will phase modulate the illuminating light.
  • a transparent fluid may also be used for reflection, which may be enhanced by placing a thin flexible transparent layer on the elastomer 15 having a substantially different refractive index than either the elastomer or the transparent conducting fluid.
  • Window layer 18 could be of normal optical property glass which contains the conductive fluid against the elastomer layer 15.
  • Power supply 17 supplies the necessary operating potential to the apparatus in FIG. 3. It is noted that most conducting .transparentfluids will undergo electrolysis in a DC electric field. This is undesirable because it leads to a deterioration of the operating components of the apparatus, as well as the evolution of gas. Thus, operation with conductive transparent fluids would normally require the use of an AC field across the elastomer/photoconductor sandwich.
  • the fourth embodiment is illustrated in'F-lG. 4.
  • This embodiment is essentially identical to the embodiment illustrated in FIG. 3, except that the thick conductive layer 16 in FIG. 3 is replaced by a conductive gas 22 and requires an electrode 23 which may be a transparent conducting window.
  • the conductive gas in cavity 22 may be obtained by means of a glow discharge through a low pressure gas of a few millimeters of mercury pressure, or by means of. a low pressure arc discharge which commonly takes place at a few microns of mercury pressure.
  • the gas may also be ionized by means of intense radioactivity in or near a low pressure gas 22 or radio frequency excitation of the gas in cavity 22 or other techniques for producing a conductive gaseous plasma well known in the art.
  • Charging of the elastomer surface 21 may also take place if gas 22 is at a sufficiently high vacuum and contains a source of thermally excited electrons, such as a heated tungsten filament, which is directed against the elastomer surface.
  • a source of thermally excited electrons such as a heated tungsten filament
  • This may be a scanned beam as from an electron gun, or an unscanned beam, or from a multiplicity of electron emitting sources.
  • a reflective layer may also be placed over layer 21 on the surface interface between layers 21 and 22.
  • conductive gas 22 in FIG. 4 Apart from the conductive gas 22 in FIG. 4, the components thereof are similar to that as shown in FIG. 3. That is, substrate 18 would have a conducting layer 19 thereon with transparency or not as set forth above. Photoconductive layer 20 and elastomer layer 21 are placed over the conductive layer 19. Here, however, the conductive gas 22 may be between 0.1 microns thick to an indefinite thickness. As set forth above, electrode 23 may be a separate electrode or may be coupled to a transparent conducting window to contain the conductive gas against the elastomer layer 21. The
  • FIG. 4 is particularly suited for holographic interferometry because the input light can be transmitted through it to form a composite image with the output light. Therefore, a holographically reconstructed image of an object may be superimposed upon the actual image .of the object to obtain interference fringes as a result of dimensional changes.
  • the embodiment in FIG. 4 teaches a novel technique for charging a surface without the use of the prior art corona discharging devicessuch as a corotron or a scorotron.
  • the limitations of the corotron and the scorotron are that the power requirement is high in relation to the density of charge placed I on the receptive layer. Further, corotrons and scorotrons being corona discharge devices must normally have a relative motion between the corona discharge device and the receptive layer.
  • an electrophotographic drum such as an aluminum drum overcoated with selenium
  • a corona discharge device such as the corotron or scorotron hereinabove set forth.
  • the corona discharge device could be advanced past a receptive layer, for example, in a situation where the receptive layer is flat with respect to the path ,of movement of the corona discharge device.
  • the fact that the prior art corona discharge devices operate in a normal room environment, that is, with normal air of varying humidities, the charge laid upon a receptive layer is not as accurate as could be desired.
  • the conductive gas in a predetermined vacuum, the level of charge placed upon a receptive layer can be precisely determined. If the conductive gas is coupled to a vacuum pump, the evacuated pressure and/or the potential applied to the electrode 23 may be controlled to specifically predetermine the charge generated on the receiving layer.
  • Adjacent photoconductor and elastomer layers may be replaced by a single layer of a photoconductive elastomer under some circumstances, in all embodiments hereinabove set forth.
  • the photoconductive elastomer under some circumstances, in all embodiments hereinabove set forth.
  • a thin elastomer layer is capable of undergoing appreciable elastic deformation for only a limited bandwidth of spatial frequencies. Its response outside this bandwidth is quite limited.
  • the spatial frequency response of the elastomer may be broadened or made multiply peaked by replacing the single elastomer layer with a multiply layered apparatus as illustrated in FIG. 5.
  • Each of these layers 25, 26, 27 and 28 will have a different limited spatial frequency response, but the combination of layers will have a broad or multiply peaked spatial frequency response.
  • the thickest layer 25 will-be placed closest to the photoconductor and the thinnest layer 28 will have the deformable surface. Two or more of such layers may be used as desired.
  • each of these layers may also be photoconductive, eliminating the need for a separate photoconductor and in some instances enhancing the resolution of the device.
  • the elastomer surfaces as described. herein may be used for the recording, storage and erasure of image information over a great many cycles, provided that the electric fields across the elastomer are not allowed to become excessively great. When these fields do become great enough that the deformations of the elastomer surface exceed the elastic limit of the elastomer, it has been observed that the image is permanently recorded on the elastomer.
  • the upper limit on the electric field applied to the previously mentioned dimethylpolysiloxane silicone gel is observed to be about 100 volts per micron. While for many systems this is regarded as undesirable, there are those in which it is also desired to record a permanent image.
  • the cyclic properties of the elastomer may be used in an attempt to obtain a satisfactory image, which is then permanently recorded by an over voltage application.
  • FIGS. 6 through I show actual physical'er'nbodb sandwich, the reflected light from which would be reflected away from the elastomer surface in the unfrosted areas, while the light impinging thereon would be scattered when reflected by the frosted area of the image.
  • Such scattered light from the frosted areas would enter the lens and would form an image at the image plane.
  • frosted areas would appear bright, unfrosted areas dark, yielding a positive image having bright and dark areas corresponding to those of the original object.
  • the system set forth in FIG. 6 cou'd be utilized to record a hologram. That is, the light source in FIG. 621 would be extended to impinge directly upon the imaging sandwich as a reference beam to coact with the object modulated beam from the objectto form a holographic image at the imaging sandwich. Upon reconstruction, the light source would be a similar light source which would impinge upon the imaging sandwich as indicated in FIG. 6b. In FIG. 6b, however, the lens would be unnecessary to form the reconstructed image.
  • FIGS. 6a and 6b are pertinent to the embodiments shown in FIGS. 1 to 4.
  • the readout light may be incident from either the left or the rightflf the layer 10 is opaque, the readout light may be incident from the left. In this latter case, the image may be readout at the same time the image is being recorded.
  • the readout light may be incident from either the right or the left. If the fluid is opaque, the readout light must be incident from the left.
  • FIG. 7 of the present application shows another structure which utilizes the principles of the present invention.
  • the light source impinges upon the object, the reflection from which is imaged by the lens onto the imaging device.
  • the elastomer in the presence of the electrical field records the image impinged thereon.
  • the light source now illuminates the recorded image on the elastomer layer.
  • the reflection from the elastomer layer is gathered by the lens which images the reflected image onto a plane. Between the plane and the lens is a focus point for the lens which,by the Y use of a spatial filter, causes a positive or negative image to be generated-at the image plane.
  • a frost image reflects high frequency spatial frequencies while the unfrosted areas reflect very low frequency spatial frequencies.
  • a solid spatial frequency filter placed at the focal point for the lens filters the low frequency spatial signals while allowing the high frequency spatial signals to be passed and imaged on the image plane as a positive image.
  • an annular spatial filter is utilized which filters the high frequency spatial signals while passing the low frequency spatial frequency signals.
  • FIG. 8 shows an additional embodiment utilizing the principles of the present invention, the image thereof being recorded in a manner similar to that set forth in FIG. 6a.
  • the light source would be transmitted through the elastomer layer rather than reflecting from it as set forth in FIGS. 6 and 7.
  • the particular spatial filter is required.
  • This embodiment is pertinent to FIGS. 1 through 4 as were the embodiments in FIGS. 6 and 7.
  • the embodiment therein is to be utilized only if the conductive layer 10 is transparent.
  • the embodiment therein can be utilized only if the conductive fluid 16 is transparent.
  • FIG. 9 shows apparatus utilizing the principles of the present invention wherein the construction and reconstruction steps occur simultaneously with similar or different light sources. That is, light from an object illuminated with light of a given wavelength and intensity is focused on the photoconductor of the imaging sandwich. Simultaneously, light of a possibly different wavelength and/or intensity is reflected from the coated surface of the elastomer. This image is converted to an intensity image at the image plane as was set forth above in conjunction with FIG. 6.
  • the apparatus of FIG. 9 can be extended as was the apparatus of FIGS. 6 and 7 for the construction of a hologram. That is, in FIG.
  • the illumination light source would not only be impinged upon the object to generate an object modulated wavefront, but would be impinged upon the imaging sandwich as a reference beam. Then, at the surface of the elastomer, a hologram would be constructed in accordance with the object and reference wavefronts.
  • the illumination light source must now be coherent as from a laser source, for example. Upon readout, a coherent light source would impinge upon the other side of the imaging sandwich, the light diffracted therefrom forming the reconstructed image.
  • the lens system would not be necessary.
  • FIG. 9 is pertinent to the embodiment set forth in FIG.
  • FIG. 9 is pertinent to the embodiment set forth in FIG. 2 primarily if the image is first formed and subsequently read out. That is, readout light would not be present duringimage forming in sufficient intensity to interfere with image forming.
  • FIG. 9 is also pertinent to the embodiments shown in FIGS. 1, 3 and 4 for simultaneous image recording and readout. It is also pertinent to the use of high and low pass spatial filters, depending upon the generation of a positive or negative image.
  • FIG. I0 utilizes the imaging sandwich for holographic recording.
  • a laser source would impinge upon the object by means of reflection from a mirror, for example, while an unobstructed reference beam would impinge upon the imaging sandwich.
  • the modulated beam from the object would coact with the reference beam within the photoconductor layer forming a holographic image therein.
  • the laser source can be used to reconstruct the image for an observer as shown in FIG. 10b.
  • FIG. 10 shows the use of the imaging sandwich to record a holographic interference pattern instead of a focused image.
  • the system illustrated schematically in FIG. 11 employs a cyclic imaging member 51 according to the present invention and preferably the embodiment represented by FIG. 2.
  • the portion 52 represents the transparent substrate, conductive layer and photoconductor while portion 53 represents an elastomer layer overcoated with an opaque, reflective, electrically conductive layer which deforms with the elastomer.
  • the system utilizes the imaging member 51 as a buffer storage device between devices such as a digital and/or analog computer, the output of which is represented by the arrow 54, and the xerographic reproduction apparatus 55.
  • the buffer storage device permits asynchronous operation of the computer and xerographic apparatus.
  • Digital information is converted to analog information by the analog to digital converter 57 which develops appropriate signals for driving the cathode ray tube (CRT) 58.
  • CRT cathode ray tube
  • electron beam position information is fed to the CRT through appropriate vertical and horizontal deflection circuits 59 and 60, respectively, and beam intensity information is fed to the CRT through an appropriate brightness circuit 61.
  • the CRT normally includes a phosphor screen 62, or the like, which remains illuminated sufficiently long after the scanning beam has passed to form a full frame image over its face. Alternately, the screen may be illuminated 'substantially only at areas at which the scanning beam currently resides.
  • the member 51 is able to record the loci of the beam and retains the information for a comparatively long period of time as long as an electric field is applied across the elastomer. Consequently, a two dimensional image may be formed on the surface of the CRT by any scanning or raster pattern and be simultaneously or subsequently recorded as a surface deformation image on member 5!.
  • Appropriate lens elements 63 are interposed between the photoconductor on member 51 and the screen 62 to create the surface deformation image.
  • the photoconductor in the member 51 must be sufficiently sensitive to respond to the relatively low levels of light available from CRT displays.
  • Seleniumand selenium arsenic alloys are examples of photoconductors having sensitivities in the order of l erg/cm which are capable of rapid response to the light levels associated with CRT displays.
  • the surface deformation image created on portion 53 of member 51 is simultaneously or subsequently read out by appropriate means such as that including lamp 65 and lens 66.
  • the lamp is a non-coherent light source of high intensity.
  • the light is diffracted by the surface deformation image, is collected by appropriate lens elements 66 and focused onto a plane tangent to drum 71.
  • the image temporarily recorded on member 51 is permanently recorded by I special consideration is given in an actual machine to compensate for changing distances between lens 66 and image point 72.
  • the focal length of lens 66 may be that distance between the lens and point 72 when the lens is at the midpoint in its scanning path as shown.
  • the amount of out-of-focus when the lens is at other points in the scan path indicated by the phantom lines of a lens is minimized by techniques known in the art.
  • the xerographic drum includes a photoreceptor coated onto a grounded conductive drum.
  • the photoreceptor is charged by a corotron 73 and a latent electrostatic image is created on this charged surface as the drum moves past the shield 70.
  • the latent image is developed by appropriate apparatus such as a cascade developer 74 that pours microscopic toner particles onto the drum that adhere in the image areas.
  • the developed latent image i.e., the toner image, is transferred to web 75 by electrostatics when corotron 76 deposits charge of appropriate polarity on the back side of the web.
  • the toner image is permanently fixed to the web by heating the toner as with fuser 77.
  • the drum surface is cleaned by means 78, e.g., a brush, flooded with light by lamp 79 and recharged bycorotron 73 to prepare for the formation of another toner image.
  • imaging members 51 When two or more imaging members 51 are arranged in parallel, one can be used to record information generated on the CRT while other imaging members are being read out by having their recorded information projected onto a recording medium such as the xerographic apparatus.
  • the above described systems are highly advantageous because analog and digital computers often generate information in irregular time intervals whereas xerographic and other recording apparatus operate on highly organized information and employ fixed operating cycles.
  • the image device 51 bridges the gap because it is able to: record irregularly'generated information; hold the information in a highly organized state for getting into phase with the reproduction cycle of xerographic or other imaging device; rapidly erase the recorded information; and immediately record new information.
  • the xerographic apparatus 55 may be replaced by other recording materials and/or apparatus.
  • photographic type films having sensitivities far too insensitive to respond to the light levels generated by a CRT display may be used because the necessary energy levels can be supplied by lamp 65.
  • Vesicular duplicating films available from the Kalvar Corp. of New La. are examples of such films.
  • An imaging method comprising the steps of: providing an imaging member comprising a layer of photoconductive material, an electric field deformable elastomer layer having a volume resistivity above about 10 ohm-cm. adjacent said photoconductive material layer and a deformable layer of a conductive gas adjacent said deformable elastomer layer, said conductive gas layer including means for ionizing said conductive gas; subjecting said imaging member to an electric field; and exposing said imaging member to information modulated electromagnetic radiation to which the photoconductive material is responsive to deform said elastomer layer corresponding to changes in the electric field caused by the exposure.
  • said imaging member further includes a substrate for supporting the layers of said imaging member.
  • said imaging member includes a plurality of electric field deformable elastomer layers, each said elastomer layer having different thickness and modulus of elasticity from said other elastomer layers.
  • step of erasing includes removing the electric field to which said imaging member is subjected.
  • step of erasing includes reversing the polarity of the field to which said imaging member is subjected.
  • said elastomer layer has a predetermined elastic modulus such that a deformation created therein by an electric field of sufficient strength can be locked in and said electric field is of sufficient strength to lock in said deformation, wherein said deformation remains while said electric field is maintained and is not substantially affected by subsequent exposure to illumination to which said photoconductive material is responsive.
  • An imaging method comprising the steps of:
  • an imaging member comprising an electric field deformable elastomer layer having a volume resistivity above about 10 ohm-cm., said elastomer layer including photoconductive material, and a deformable layer of a conductive gas adjacent said deformable elastomer layer, said conductive gas layer including means for ionizing said conductive gas;
  • imaging member further includes a substrate adjacent the side of the elastomer layer opposite from that to which the deformable conductive gas layer is adjacent.
  • step of erasing includes removing the electric field to which said imaging member is subjected.
  • step of erasing includes reversing the polarity of the field to which said imaging member is subjected.
  • said conductive gas layer including means for ionizing said conductive gas
  • said elastomer layer being capable of deforming to correspond to an electric field pattern created by altering an electrical field across said elastomer layer by exposing the photoconductive material to electromagnetic radiation to which it is responsive.
  • the imaging member as defined in claim 22 further including a substrate for supporting the layers of said imaging member.
  • the imaging member as defined in claim 22 further including means for spatially modulating an electric field across said elastomer layer at a frequency within the spatial frequency deformation capability. of the elastomer layer.
  • An imaging member comprising an electric field deformable elastomer layer having a volume resistivity above about 10 ohm-cm., said elastomer layer including photoconductive material, and a deformable layer of a conductive gas adjacent said deformable elastomer layer, said conductive gas layer including means for ionizing said conductive gas, and said elastomer layer being capable of deforming to correspond to an electric field pattern created by altering an electrical field across said elastomer layer by exposing said member to electromagnetic radiation to which said photoconductive material is responsive.
  • the imaging member as defined in claim 29 further including a substrate adjacent the side of the elastomer layer opposite from that to which the deformable conductive gas layer is adjacent.
  • the imaging member as defined in claim 29 further including means for spatially modulating an electric field across said elastomer layerat a frequency within the spatial frequency deformation capability of the elastomer layer.
  • an imaging member comprising a layer of photoconductive material and a plurality of electric field deformable elastomer layers overlying said photoconductive material layer, each said elastomer layer having a volumeresistivity above l ohm-cm. and each said elastomer layer having a different thickness and elastic modulus from said other elastomer layers;
  • said imaging member further includes a substrate for supporting the layers of said imaging member.
  • said imaging member further includes a deformable conductive layer adjacent the surface of said elastomer layer remote from said photoconductive material layer.
  • said deformable conductive layer comprises a layer of conductive gas, said conductive gas layer including means for ionizing said conductive gas.
  • An imaging member comprising a layer of photoconductive material and a plurality of electric field deformable elastomer layers overlying said photoconductive material layer, each said elastomer layer having a volume resistivity above about ohmcm. and each said elastomer layer having a different thickness and elastic modulus from said other .member.
  • imaging member further includes a substrate for sup- 22- elastomer layers, said elastomer layers being capable of deforming to correspond to an electric field pattern created by altering an electrical field across said elastomer layer by exposing the photoconductive materialto electromagnetic radiation to which it is responsive.
  • the imaging member as defined in claim 46 further including a substrate for supporting the layers of said imaging member.
  • said deformable conductive layer comprises a layer of conductive gas, said conductive gas layer including means for ionizing said gas.
  • An imaging member comprising a plurality of electric field deformable elastomer layers, each said elastomer layer having a volume resistivity above about i 10 ohm-cm., each said elastomer layer having a different thickness and elastic modulus from said other elastomer layers, and at least one of said elastomer layers including photoconductive material wherein said elastomer layers are capable of deforming to correspond to an electric field pattern created by altering an electrical field across said elastomer layers by exposing the member to electromagnetic radiation to which the photoconductive member is responsive.
  • An imaging method comprising the steps of: providing an imaging member comprising a layer of photoconductive material, an electric field deformable elastomer layer having a volume resistivity above about 10 ohm-cm. adjacent said photoconductive material layer and a deformable conductive layer adjacent said elastomer layer, said deformable conductive layer comprising gold and indium; subjecting said imaging member to an electric field;
  • one of said information modulated and readout radiation includes coherent radiation and the other non-coherent radiation.
  • said information modulated radiation includes the interference pattern formed by superpositioning of reference coherent radiation and object modulated coherent radiation.
  • said imaging member includes a plurality of electric field deformable elastomer layers, each said elastomer layer having different thickness and elastic modulus from said other elastomer layers.
  • step of erasing includes removing the electric field to which said imaging member is subjected.
  • step of erasing includes reversing the polarity of the field to which said imaging member is subjected.
  • An imaging method comprising the steps of:
  • an imaging member comprising an electric field deformable elastomer layer having a volume resistivity above about 10 ohm-cm., said elastomer layer including photoconductive material, and a deformable conductive layer adjacent said elastomer layer.
  • said deformable conductive imaging member further includes a substrate adjacent.
  • step of erasing includes removing the electric field to which said imaging member is subjected.
  • step of erasing includes reversing the polarity of the field to which said imaging member is subjected.
  • An imaging member comprising a layer of photoconductive material, an electric field deformable elastomer layer having a volume resistivity above about l0 ohm-cm. adjacent said photoconductive material layer and a deformable conductive layer adjacent said elastomer layer; said deformable conductive layer comprising gold and indium, said elastomer layer being capable of deforming to correspond to an electric field pattern created by altering an electrical field across said elastomer layer by exposing the photoconductive material to electromagnetic radiation to which it is responsive.
  • the imaging member as defined in claim 84 further including a substrate for supporting the layers of said imaging member.
  • said member includes a pluralityof said electric field deformable elastomer layers, each said elastomer layer having different thickness and elastic modulus from said other elastomer layers.
  • the imaging member as defined in claim 84 further including an insulating liquid layer adjacent the side of the deformable conductive layer opposite from that to which the elastomer layer is adjacent.
  • the imaging member as defined in claim 84 further including means for spatially modulating an electric field across said elastomer layer at a frequency within the spatial frequency deformation capability of the elastomer layer.
  • the imaging member as defined in claim 91 wherein said means for spatially modulating includes a line grating adjacent said photoconductive material layer.
  • An imaging member comprising an electric field deformable elastomer layer having a volume resistivity above about ohm-cm., said elastomer layer including photoconductive material, and a deformable eonductive layer adjacent said elastomer layer, said deformable conductive layer comprising gold and indium, said elastomer layer being capable of deforming to correspond to an electric field pattern created by altering an electrical field across said elastomer layer by exposing the photoconductive material to electromagnetic radiation to which it is responsive.
  • the imaging member as defined in claim 94 further including a substrate for supporting said layers of said imaging member.
  • the imaging member as defined in claim 94 further including an insulating liquid layer adjacent the side of the deformable conductive layer opposite from that to which the elastomer layer is adjacent.
  • the imaging member as defined in claim 94 further including means for spatially modulating an electric field across said elastomer layer at a frequency within the spatial frequency deformation capability of the elastomer layer.
  • An imaging member comprising a layer 'of photoconductive material,an electric field deformable elastomer layer having a volume resistivity above about 10 ohm-cm. adjacent said photoconductive material layer and a deformable conductive layer adjacent said elastomer layer, said deformable conducting layer comprising first and second metal materials, wherein said first metal material is chosen from the group consisting of gold, aluminum, silver, magnesium copper, cobalt, iron, chromium and nickel, said second metal material is chosen from the group consisting of indium, gallium, cadmium, mercury and lead, and said elastomer layer being capable of deforming to correspond to an electric field pattern created by altering an electrical field across said elastomer layer by exposing the photoconductive material to electromagnetic radiation to which it is responsive.
  • first metal material is chosen from the group consisting of gold, aluminum, silver, magnesium copper, cobalt, iron, chromium and nickel
  • said second metal material is chosen from the group consisting of indium, gallium, cadmium
  • An imaging member comprising an electric field deformable elastomer layer having a volume resistivity above about 10 ohm-cm., said elastomer layer including photoconductive material, and a deformable conductive layer adjacent said elastomer layer, said deformable conductive layer comprising first and second metal materials, wherein said first metal material is chosen from the group consisting of gold, aluminum, silver, magnesium, copper, cobalt, iron, chromium and nickel, said second metal material is chosen from the group consisting of indium, gallium, cadmium, mercury and lead, and said elastomer layer being capable of deforming to correspond to an electric field pattern created by altering an electric field across said elastomer layer by exposing the photoconductive material to electromagnetic radiation to which it is responsive.

Abstract

The applications of elastomers to various imaging techniques are described which may be used for the cyclic recording, storage and subsequent erasure of optical information. Several embodiments of the invention are described, all of which form images by the elastic deformation of a thin elastomer layer. The pattern of the surface deformation, in general, follows the light distribution of the optical image being recorded. This image is formed on a photoconductive layer which is adjacent to, or integral with, the elastomer layer. An electric field is placed across the elastomer and the photoconductor layers, the field being modulated by the action of the image light on the conductivity of the photoconductor and provides the mechanical force necessary to deform the elastomer. Once the elastomer surface has deformed, it will in general remain deformed as long as the field across it is maintained; the image recorded, accordingly, being stored. Removing the electric field allows the elastomer to relax and the image is consequently erased. Reversing the field increases the rate at which the image is erased. A new image may now be formed, and the cycle started over again. Such an elastomer material is capable of a great many recording/storage/erasure cycles.

Description

p) XR 307160359 EX United States Patent 1B1 Sheridon 11] 3,716,359 [451 Feb. 13, 1973 1 CYCLIC RECORDING SYSTEM BY THE 4 USE OF AN ELASTOMER IN AN ELECTRIC FIELD [75] Inventor: Nicholas K. Sheridon, Fairport,
I [73] Assignee: Xerox Corporation, Rochester, N.Y..
[22] Filed: Dec. 28, I970 ,[21] Appll No; 101,729.
Related Application Data [63] Continuation of Ser. No. 23,649, March 30, I970,
abandoned.
521 US. Cl ..96/1.1, 96/15, 96/27 H, 340/173 TP, 346/74 TP, l78/6.6 TP, 346/77 51 1m. 01. ..G03g 13/22 58 Field OI Search.96/l.l; 340/173 TP; 346/74 1?, 346/77 E; 178/6.6 TP
Wright ..340/173 Primary Examiner-John c Cooper, 111 Attorney-James J. Ralabate, David C. Petre an Michael H. Shanahan [57] ABSTRACT The applications of elastomers to various imaging techniques are described which may be used for the cyclic recording, storage and subsequent erasure of optical information. Several embodiments of the invention are described, all of which form images by the elastic deformation of a thin elastomer layer. The pattern of the surface deformation, in general, follows the light distribution of the optical image being recorded. This image is formed on a photoconductive layer which is adjacent to, or integral with, the elastomer layer. An electric field is placed across the elastomer and the photoconductor layers, the field being modulated by the action of the image light on the conductivity of the photoconductor and provides the mechanical force necessary to deform the elastomer. Once the elastomer surface has deformed,'it will in general remain deformed as long as the field across it is maintained; the image recorded, accordingly, being stored. Removing the electric field allows the elastomer to relax and the image is consequently erased. Reversing the field increases the rate at which the image is erased. A new image may now be formed, and the cycle started over again. Such an elastomer material is capable of a great man recording/storage/erasure cycles.
102 Claims, 13 Drawing Figures PAT N 3; 7 1 6.359
' sum 1 OF 5 I 4 L i 5 2 zgzrza I I2 u l5 l6 l0 I8 1920 2/ y 22 J i f n5, a-2f, Has 1 F G- mvsmon. NICHOLAS K. SHERIDON SHEET 2 OF 5 LIGHT SOURCE IMAGING SANDWICH OBJECT RECORDING IMAGE LIGHT SOURCE IMAGE PLANE mAeme BANDWICH READING-OUT IMAGE LIGHT SOURCE PATENTED Fun 3191s SHEET 3 OF 5 PATENTED 31913 3.716.359
SHEET '4 OF 5 BEAM SPLITTER MIRROR -0=== LASER I 1 x Ru I IMAGING SANDWICH fi LASER OBSERVER VIRTUAL IMAGE IMAGING SANDWICH F/GJOb PATENTED FEB] 75 SHEET 5 OF '5 CYCLIC RECORDING SYSTEM BY THE USE OF AN ELASTOMER IN AN ELECTRIC FIELD CROSS REFERENCE This application is a continuing application of my copending application under the same title filed Mar. 30, 1970, Ser. No. 23,649, now abandoned.
BACKGROUND OF THE INVENTION Prior art thermoplastic surface relief imaging taught the recording of images by means of deformations in an otherwise smooth thermoplastic surface. The image information is recorded as a hill and valley structure on this surface. Light reflected or transmitted through this surface may be used to make the recorded image visible because such light will be scattered or diffracted by this structure. Three basic types of thermoplastic surface relief imaging may be distinguished.
Historically, the first of these is frost imaging" which may be seen in U.S. Pat. Nos. 3,196,009, 3,196,011, 3,258,336 and 3,196,008 as a few of many examples. Frost imaging has been practiced in the past by creating a voltage pattern across a thin layer of insulating thermoplastic. This voltage pattern is usually established by means of an adjacent layer of photoconductor material although the thermoplastic itself may be made photoconductive. In use, the electric field is placed across the thermoplastic/photoconductor sandwich or across the photoconductive thermoplastic. The light intensity pattern of the image formed on the photoconductor now creates a varying electrostatic field.
It has been observed by this inventor and others that a thin liquid layer, across which a high electric field has been placed, will preferentially deform in a pattern exactly matching the spatial frequency variations in this field; provided these variations are predominately composed of spatial frequencies in the neighborhood of the characteristic or resonant frequency of the layer. For moderate values of the electric field this resonant frequency commonly has the value l/2T, where T is the thickness of the liquid layer. Where the field pattern varies much more slowly than this, the surface will tend to wrinkle or randomly deform; such wrinkles having characteristic spatial frequencies in the neighborhood between the image being projected on ,the photoconductor and the photoconductor itself, the surface will deform r without frost in those regions where the photoconductor is eliminated. The solid areas, i.e., low spatial frequency areas, of this screened frost image are now filled, not with frost, but with remnants of the screen. If these screen remnants are objectionable, they can be removed by subsequent spatial filtering or by techniques further taught by Urbach. I
The third type of surface relief imaging is actually a variant of the first two, but because of its importance of l/2T and being referred to as frost. Hence, images having spatial frequencies within the region of the resonant frequency of the deformable surface will be faithfully reproduced by deformations of this surface. Images, on the other hand, having spatial frequencies much lower than this resonant frequency will tend to form frost in the regions of greater illumination. In conjunction with a Schlieren optical or other suitable system, good quality images may be reconstructed from frost deformations. However, the inherent noise strucdeserves to be treated separately. This relates tothe recording of holograms on a deformable surface structure and has been taught by Cathey, for bleached gelatin emulsions and later by Urbach for thermoplastic/photoconductor sandwich structures. Ser. U.S. Pat. No. 3,560,205, Imaging System, Ser. No. 521,982, filed on Jan. 20, 1966. A hologram is a recording of the interference pattern between two coherent light beams. One light beam usually contains information about an object and the other is a reference beam, generally of simple structure. The interference pattern generally resembles a somewhat garbled image of a screen. If the spatial frequency of the screen approximates the resonant frequency of the thin liquid layer, the surface would deform along the structure of the interference pattern and little noise would be generated.
All of the above imaging techniques involve the deformation of a thin heat or solvent vapor softenable plastic layer to record image deformation. They may, in principle, be recycled by applying heat or solvent vapors to soften the plastic and allow the recorded image to erase. Ordinarily, the surface would be allowed to solidify again by cooling or vapor ventilation and another image could be formed on it as before. However, these systems cannot be cycled very rapidly or very conveniently. Moreover, cycling requires the expenditure of solvents, or large amounts of power. Further, it has been repeatedly observed that state of the art plastics do not erase completely, due to chemical changes associated with the development process; and, hence, only a limited number of imaging cycles can be obtained with these materials. Accordingly, there is a continuing need for surface deformation imaging systems that will store information and can be repeatedly cycled rapidly and conveniently, with low power consumption.
OBJECTS OF THE INVENTION It is, therefore, an object of the present invention to provide an optical imaging system which overcomes the above noted deficiencies and satisfies the abovenoted wants. 1 I
It is another object of the present invention to provide an optical imaging system that will record optical information, store it, erase it and do these things many times.
It is another object of this invention to provide an optical imaging system capable of recording the high spatial frequency optical interference patterns characteristic of holograms, as well as the lower spatial frequency images commonly characteristic of noncoherent light images.
It is another object of this invention to provide an optical imaging system which records a surface relief image with light incident from one side of the imaging member and to simultaneously allow light of the same or different wave length or the same or different intensity incident from the opposite side of the member to form a similar optical image for purposes of wavelength change, image projection, image intensification and other optical transformations.
It is another object of this invention to provide an optical imaging system which records a surface relief image on an essentially transparent imaging member, such that images may be recorded and reformed by transillumination.
It is another object of this invention to provide an optical imaging system which will be capable of recording images most efficiently within a narrow range of spatial frequencies, or within several narrow ranges of spatial frequencies.
BRIEF SUMMARY OF THE INVENTION In accomplishing the above and other desired aspects of the present invention, Applicant has invented improved apparatus and methods for a fully cyclycable imaging device on which images may be recorded, stored for short periods of time and erased at will. The inventor provides an imaging member which comprises a substrate that is conductive or has a conductive surface. Coated on this surface is a photoconductive layer whose conductivity is dependent upon illumination, and coated above this is an elastomer layer. In another embodiment a separate photoconductor layer is not used, but rather the elastomer layer is photoconductive. A deformable conductive layer including either a flexible conductive member, a conductive liquid, a conductive gas or a layer of electrostatic charge is placed contiguous to the surface of the elastomer. An electric field established between the deformable conductive layer and the conductive substrate increases in those regions where the photoconductive layer is exposed to electromagnetic radiation (hereafter referred to as light) causing the elastomer to deform in those regions. Two types of imaging behavior have been observed. In the case of very compliant elastomers and large electric fields theelastomer remains deformed while the electric field is maintained. This deformation is not substantially affected by subsequent illumination of the photoconductor, and thus may be said to be electrically locked. The recorded image information may now be read out at leisure with any brightness illumination. The deformation is removed by removing the field, allowing the elastomer to relax. By reversing the field across the elastomer instead of removing the field, the image may be erased much more quickly. A new image may now be formed. It is to be noted, however, that the electrical locking property of the elastomer exists only above a certain value of the electric field. Below this field threshold value the image erases slowly especially upon exposure of the photoconductor to thermoplastic imaging device, is capable of forming three types of image: frost images, screened frost frequency bandwidth. The greatest response is in the neighborhood of the resonant frequency, usually equal to approximately l/2T as in the case of therrnoplastics. When an elastomer is exposed to an image having the bulk of its information within the spatial frequency response of the elastomer, the elastomer will record that image very well. Such images are of great interest primarily for holography and for recording printed, written or numeric information of high contrast. When such an elastomer layer is exposed to an image composed of spatial frequencies lower than the recording band of the elastomer, the brightly illuminated areas of the elastomer will deform into a random deformation pattern similar to the frost of the thermoplastic recording. The spatial frequency of the frost deformation lies within the recording bandwidth of the elastomer, and the frost will randomly scatter incident light. Less brightly illuminated areas will not frost and hence will not scatter. Such an image is called a frost image and, as in the thermoplastic case, is sometimes objectionable for some applications because of its inherently noisy structure.
The third type of surface relief image called screened frost is suitable for recording images having spatial frequencies substantially lower than the resonant deformation frequency of the elastomer layer. This is formed by placing an absorption type line grating between the projected image light and the photoconductor upon which it is imaged. The elastomer will now deform along the pattern of this high spatial frequency screen in those areas where it is illuminated and, therelight. This constitutes the second type of imaging fore, will not form frost. The screened surface relief image will then consist of segments of the shadow of the screen. The image obtained by illuminating the elastomer will, thus, have a fine structure of lines superimposed upon the original image that was recorded. If this line structure is objectionable, it may be removed by suitable optical filtering techniques well known in the art.
For the imaging structures described herein, the preferred location of the screen, e.g., a line grating, is immediately adjacent to a photoconductive layer in the imaging structure. Other types of screens that may be similarly located are described in two copending applications, both titled Methods of Organized Thermoplastic Xerography and Photoreceptor Structure Therefor, one in the name of Lloyd F. Bean and the other in the name of John C. Heurtley, filed Sept. 18, I970, and Sept. I8, 1970, Ser. Nos. 73,406 and 73,317, respectively.
BRIEF DESCRlPTlON OF THE DRAWINGS For a better understanding of the invention as well as other objects and further features thereof, reference is made to the following detailed description taken in conjunction with the accompanying drawings wherein:
FIG. I is a side sectional view of the elastomer imaging apparatus of a first embodiment of the present invention', I
FIG. 2 is a side sectional view of the elastomer imaging apparatus of a second embodiment of the present invention;
FIG. 3 is a side sectional view of the elastomer imag-' ing apparatus of a third embodiment of the present invention;
FIG. 4 is a side sectional view of the elastomer imaging apparatus of a fourth embodiment of the present invention; I I
FIG. 5 is a side sectional view of a multilayered elastomer in accordance with the principles of the present invention; I
FIGS. 6 to 10 are partly schematic, partly side sectional view of various physical applications of the principles of the present invention; I
FIG. 11 is a schematic, perspective view of a computer print-out systems using the imaging structures and methods of the present invention.
DETAILED DESCRIPTION OF THE INVENTION The term elastomer in the various forms used herein is defined as a usually amorphous material which exhibits a restoring force in response to a deformation; that is, an amorphous material which deforms under a force, and, because of volume and surface forces, tends to return to the form it had before the force was applied.
The first embodiment of the present application shown in FIG. 1 is an elastomeric imaging device in which charges are placed on the surface of the elastomer by means of a corona discharge. Modified I forms of a corona discharge device are well known in light. Such a photoconductor is often a mixture of polyn-vinyl carbazole and a sensitizing dye. The thicknessv of the photoconductor will probably range from 0.l microns to 200 microns, depending largely upon the spatial frequency of the information to be recorded.
The elastomer layer 4 may be of a class of elastomeric soft solid materials for use in this application including both natural, such as natural rubbers and synthetic polymers which have rubber like characteristics, i.e., are elastic and include materials such as styrene-butadiene, poly-butadiene, neoprene, butyl, polyisoprene, nitrile and ethylene propylene rubbers. Preferred elastomers for use in this application include: water based gelatin gels and dimethylpolysiloxane based silicone gels. These materials may be coated on the photoconductor as monomers and polymerized in place or they may be coated on the surface from solutions in volatile solvents which will evaporate and leave a thin uniform layer. In general, these materials should be reasonably good insulators, having volume resistivities in excess of IOohm-centimeters.
The preferred elastomer is a transparent composition comprising an elastomeric dimethylpolysiloxane silicone gel made by steps including combining about one part of Dow Corning No. I82, silicone resin potting compound and anywhere from about zero to about 30 parts of Dow Corning No. 200 dimethylpolysiloxane silicone oil. Suitable resins include transparent flexible organosilonane resins of the type described in US. Pat. No. 3,284,406 in which a major portion of the organic groups attached to silicon are methyl radicals.
The thickness of the elastomer layer will range from approximately 0.] microns to approximately 2,000 microns, depending upon the spatial frequency of the information required. Various optical properties of the device may be enhanced by a suitable selection of the reflective mirror finish so that reconstruction light will pass through the elastomer, reflect from it and pass through the elastomer once again; thereby obtaining twice the modulation that a transmissive device will impart. If the substrate is to be transparent, commonly available NESA glass could be used. This is a tin oxide coated glass conductive on the surface corresponding to layer 2 in FIG. 1. Alternatively, it could be a piece of transparent glass with a metallic conductive layer on the surface, a layer thin enough to be transparent. If transparency of the substrate is not important, a metallic substrate may be used. The substrate could be a plastic material such as Mylar or acetate, if flexibility were desired. If substrate 1 is not conductive, layer 2 which is a conductive layer must be added. This is normally a transparent, or partially transparent layer.
The photoconductive layer 3 is a material which will allow the passage of more electric charge in those regions which are exposed to light. This definition of a photoconductor may be extended to any materials in which the conductivity is inhibited by the presence of elastic modulus of the material used. For example, a stiffer elastomer will recover more rapidly from an image when the electric field is removed, that is, may be erased more quickly. 0n the other hand, a material having a low elastic modulus will be capable of greater deformations and hence greater optical modulation for a given value of electric field.
The corona charging apparatus 5 may be a stationary charging unit provided such a unit provides enough uniformity of charge deposition, or it may be a scanning system. This device places positive or negative charges on the surface of the elastomer. The voltage drop across the elastomer photoconductive sandwich will lie in the range of 1 to 25,000 volts depending on the modulus of elasticity of the elastomer and its thickness, as well as certain properties of the photoconductor. Particular types of scoratron devices which have been found useful in corona charging are disclosed in the Vyverberg US. Pat. No. 2,836,725 and ability of the elastomer to hold charge on its surface, to
a light field which must come from the right if substrate 1 is opaque. If substrate 1 is transparent, the light may propagate from either the right or the left. Substrate l,
or the alternate layer 2, are grounded thereby creating an electric field across the photoconductor and elastomer combination. This electric field induces a flow of charge in those regions of the photoconductor which are exposed to light, varying the electric field across the elastomer. The mechanical force of the electric field across the elastomer causes it to deform. This deformation will proceed until the forces of the electric field are balanced'by the surface tension and elastic forces of the elastomer. At this point, the deformation stops and becomes stable as long as the electric fields across the elastomer are maintained. This deformation is different from that occurring in thermoplastic materials in that the elastomer deformations are independent of any developing step such as heat and/or solvent softening steps employed with thermoplastic materials. Another difference between elastomer and thermoplastics is that the elastomer deformations assume a definite limit for a given electric field because elastic forces oppose the deformation. The thermoplastic deformations do not encounter such a definite limit for a given field as long as the thermoplastic is maintained in a softened condition. To erase this image, the field across the elastomer is removed; to erase more quickly the field across the elastomer is reversed. Now the device is ready to accept another image.
In FIG. 2 is a second embodiment wherein an electric field is created across the elastomer 9 and photoconductor layer 8 by means of a thin continuous conducpropagating from the right may be used to reconstruct the image. The light sources used may be of different wavelengths and/or intensities and/or one light source may be coherent and the other noncoherent. Hence, this device may be used to convert an image formed in one wavelength into an equivalent image formed in a different wavelength. Also, if the readout light incident from the right is very much more intense than the imaging light incident from the left, the apparatus shown in H0. 2 will provide great amplification of an input image, such amplified light being used, for example, for large panel displays. Furthermore, the reconstruction light may be coherent, e.g., that produced by a laser, so that image processing steps may be performed on the surface deformation image which is formed with noncoherent light propagating from the left. On the other hand, the light giving rise to the surface deformation image may be coherent light while the reconstruction light may be non-coherent. This latter case is desirable because non-coherent light is more pleasing to the human eye and current coherent light generators are limited to production of light within narrow wavelength bands, i.e., one color such as red. A reason for having coherent light for forming the surface deformation image arises when his the reconstruction light for forming images with holograms. Therefore, the present device may have a holographically reconstructed image projected onto it forming a surface deformation image that is viewed with non-coherent light of substantially greater intensity as suited for large panel displays.
In HO. 2, as it was for the embodiment shown in FIG. 1, substrate 6 may be transparent or opaque depending upon use. Conductive layer 7 is optional and is used if substrate 6 is not conductive. If substrate 6 is transparent then the conductive layer 7 would generally also be transparent. Over the conductive layer 7 is coated the photoconductive layer 8. Over the photoconductive layer 8 is the elastomer layer 9. The thin conductive layer 10 must be flexible enough to follow the deformations of the elastomer layer 9. if the conductive layer 10 is opaque, for example, a thin metal film, the substrate 6 and conductive layer 7 must be transparent to allow image information to reach the photoconductive layer 8. In this case, image information can be read out continuously if the readout light is incident from the right. If the conductive layer 10 is transparent, light may be reflected from its surface or the device may be used in transillumination, provided I also be used, such as Dow Corning resin ECR 34 may be coated on the surface of the elastomer 9. Other conductive layers, such as may occur to one skilled in the art, may also be used within the principles of the present invention. To form and lock the deformation image, the values of voltage between substrate 6 and conductive layer 10 would be approximately between i and 25,000 volts, depending on the thickness, and other characteristics of elastomer 9.
The requirements for conductive layer 10 include: sufiicient conductivity to become an equipotental surface when connected to an electrical energy source; sufficient flexibility to follow the deformations of the elastomer; sufficient fatigue resistance to withstand numerous and rapid formations and erasures of surface deformations; and, in some cases, high opacity and reflectivity as when being read out by a high intensity light source to which the photoconductive layer is sensitive.
The preferred materials for conductive layer 10 include gold and indium. The layer is formed by steps including vapor depositing the materials onto the elastomer which involves heating a material to or above its melting point and condensing the vapors on the desired surface. This technique is well understood in the art and conventional practices are followed in evaporating and condensing the materials. However, a problem associated with shrinkage of a condensed l Other suitable high melting point materials besides gold include aluminum, silver, magnesium, copper,
cobalt, iron, chromium, nickel and others. Aluminum metal layer is overcome by novel techniques in order to fabricate a conductive layer l0.meeting the above requirements. Vapor deposited metals tend to shrink, i.e., contract, as they cool and at some thermo-energy state the metal layer tends to break up or crack making the layer discontinuous. This break up of a metal layer is referred to herein as mud-cracking" since mud cracks are broadly descriptive of the appearance of the layer after shrinkage. The instant novel technique includes vapor depositing a second metal over the first before the first has mudcracked. The two materials may be vapor deposited simultaneously. The second metal is selected so as to have a lower melting point than the first deposited metal. The final product is a continuous layer meeting the above requirements which yet does not experience mud cracking over a wide range of temperatures. The described layer may include portions where the two metals (or other suitable materials) are coated one over the other, portions where the two metals are intermixed macroscopically as well as microscopically (e.g., to form an alloy) and portions where they reside side by side. Naturally, additional materials may be added to the layer to enhance or suppress particular characteristics.
One theory, to which this invention is not limited, that explains why mud cracking is suppressed in the above multiple component layer, is connected with the relative mobility of atoms at the surfaces of the different materials. The atoms of high melting point materials normally exhibit low surface mobility which gives rise to the mud cracking when the metals are coated over an elastomer. The atoms of lower melting point materials exhibit by comparison much greater surface mobility and their presence enables the stresses developed in the high melting point material to be relieved.
The preferred materials of gold and indium have high and low melting points respectively. Mud cracking is usually observed in vapor deposited gold layers within minutes after cooling to room temperatures. This usually provides ample time to vapor deposit the indium onto the gold layer. An example of a highly successful coating is one formed by depositing from 50 to several thousand angstroms of gold followed by depositing onto this gold layer from 50 to several thousand angstroms of indium. The resultant layer is continuous and exhibits no mud cracking over a wide range of temperatures. The indium is particularly advantageous because it increases the opacity of the resultant layer and, because of its silver appearance, enhances the reflectivity of the layer.
It is noted that indium by itself is not a highly efficient material for layer 10 because of poor conductivity. The poor conductivity is peculiar to low melting point materials because they tend to form islands during condensation which do not join together into a continuous layer of a reasonable thickness. Accordingly, it is observed that vapor deposition of single materials (or alloys thereof), whether high or low melting point materials, yields layers that are less satisfactory than the layer comprised of high and low melting point materials.
has the further desirable property of being highly corrosion resistant. Other suitable low melting point materials besides indium include gallium, cadmium, mercury, lead and others. Cadmium by itself exhibits a low tendency to mud cracking.
Of course, the foregoing problems of mud cracking and island forming may not arise if the conductive layer 10 is formed by chemical reaction, precipitation out of a solution, electrophoresis, electrolysis and/or other techniques.
Over the conductive layer 10 in FIG. 2 may also be an optional transparent insulating layer of oil. lts purpose is to make less stringent the fabrication requirements for this apparatus. The presence of pin holes in the elastomer layer 9 may cause the apparatus in FIG. 2 to short circuit, possibly destroying its performance. The addition of the layer 12 prevents such short circuits from disrupting the performance of the device by allowing insulating oil to flow into such pin holes.
Layer 12 serves another important function when it has an index of refraction different than air. The presence of oil 12 over the conductive layer 10 means light propagating from the right will be modulated more than it would be if only air was present. The reason being is that for the same magnitude of surface deformation the optical path changes are proportional to the refraction index of the medium adjacent to the surface.
Power supply 11 of FIG. 2 provides DC voltage of one polarity to form a deformation image on the surface of the elastomer. The polarity required depends upon the nature of the photoconductor. Power supply 11 must be capable of being turned off to erase the image, or, undergo a shift in polarity to more rapidly erase the image. For a television type of picture wherein approximately 30 images per second are formed, stored and erased, the power supply must be capable of undergoing such cycles with appropriate speed. The extent of the deformation and the rapidity with which information may be erased is dependent upon the voltages supplied by the power supply. The stability of the voltage output of the power supply must be great enough to prevent unwanted erasure of the image. An alternate scheme for erasing the surface deformation image is to position a strobe light at the left in FIG. 2 to flood the photoconductive layer 8 with light thereby erasing the modulated field pattern across the structure set up by the imagewise light. This operation is appropriate as long as the fields across the elastomer layer 9 are below a level causing the surface deformations to be locked.
The embodiment in FIG. 3 employs a very thick conductive liquid 16 in contact with elastomer 15 to provide the necessary electric field across the elastomer/photoconductor sandwich. The other components of the apparatus of FIG. 3 are similar to those in FIGS. 1 and 2. That is, substrate 12 may be transparent or opaque and in turn may or may not be conductive. Conductive layer 13 must be present if substrate layer 12 is not conductive. if substrate 12 is transparent then conductive layer 13 will normally also be transparent. Coated on the conductive layer 13 are 'not be transparent.Non-transparent conductive fluids include mercury, room-temperature molten gallium-indium alloys, etc. Transparent fluids include water to which conductive impurities have been added. If transparent, the fluid 16 should have a substantially dif ferent refractive index than the elastomer in order that defonnations of the elastomer surface will phase modulate the illuminating light. A transparent fluid may also be used for reflection, which may be enhanced by placing a thin flexible transparent layer on the elastomer 15 having a substantially different refractive index than either the elastomer or the transparent conducting fluid. Window layer 18 could be of normal optical property glass which contains the conductive fluid against the elastomer layer 15. Power supply 17 supplies the necessary operating potential to the apparatus in FIG. 3. It is noted that most conducting .transparentfluids will undergo electrolysis in a DC electric field. This is undesirable because it leads to a deterioration of the operating components of the apparatus, as well as the evolution of gas. Thus, operation with conductive transparent fluids would normally require the use of an AC field across the elastomer/photoconductor sandwich.
The fourth embodiment is illustrated in'F-lG. 4. This embodiment is essentially identical to the embodiment illustrated in FIG. 3, except that the thick conductive layer 16 in FIG. 3 is replaced by a conductive gas 22 and requires an electrode 23 which may be a transparent conducting window. The conductive gas in cavity 22 may be obtained by means of a glow discharge through a low pressure gas of a few millimeters of mercury pressure, or by means of. a low pressure arc discharge which commonly takes place at a few microns of mercury pressure. The gas may also be ionized by means of intense radioactivity in or near a low pressure gas 22 or radio frequency excitation of the gas in cavity 22 or other techniques for producing a conductive gaseous plasma well known in the art. Charging of the elastomer surface 21 may also take place if gas 22 is at a sufficiently high vacuum and contains a source of thermally excited electrons, such as a heated tungsten filament, which is directed against the elastomer surface. This may be a scanned beam as from an electron gun, or an unscanned beam, or from a multiplicity of electron emitting sources. A reflective layer may also be placed over layer 21 on the surface interface between layers 21 and 22.
Apart from the conductive gas 22 in FIG. 4, the components thereof are similar to that as shown in FIG. 3. That is, substrate 18 would have a conducting layer 19 thereon with transparency or not as set forth above. Photoconductive layer 20 and elastomer layer 21 are placed over the conductive layer 19. Here, however, the conductive gas 22 may be between 0.1 microns thick to an indefinite thickness. As set forth above, electrode 23 may be a separate electrode or may be coupled to a transparent conducting window to contain the conductive gas against the elastomer layer 21. The
' container for withholding the conductive gas 22 from escaping would, of course, have to be airtight to contain the gas at the necessary level of vacuum.
The embodiment of FIG. 4 is particularly suited for holographic interferometry because the input light can be transmitted through it to form a composite image with the output light. Therefore, a holographically reconstructed image of an object may be superimposed upon the actual image .of the object to obtain interference fringes as a result of dimensional changes.
Apart from comprising a novel imaging technique for imaging on an elastomer layer, the embodiment in FIG. 4 teaches a novel technique for charging a surface without the use of the prior art corona discharging devicessuch as a corotron or a scorotron. The limitations of the corotron and the scorotron are that the power requirement is high in relation to the density of charge placed I on the receptive layer. Further, corotrons and scorotrons being corona discharge devices must normally have a relative motion between the corona discharge device and the receptive layer. in prior art devices such as normally utilized in xerographic machines, an electrophotographic drum such as an aluminum drum overcoated with selenium, is rotated about a central axis past a corona discharge device such as the corotron or scorotron hereinabove set forth. Additionally, the corona discharge device could be advanced past a receptive layer, for example, in a situation where the receptive layer is flat with respect to the path ,of movement of the corona discharge device. Further, the fact that the prior art corona discharge devices operate in a normal room environment, that is, with normal air of varying humidities, the charge laid upon a receptive layer is not as accurate as could be desired. The embodiment set forth in FIG. 4, however, overcomes these disadvantages by utilizing -the conductive gas in a predetermined vacuum, the level of charge placed upon a receptive layer can be precisely determined. If the conductive gas is coupled to a vacuum pump, the evacuated pressure and/or the potential applied to the electrode 23 may be controlled to specifically predetermine the charge generated on the receiving layer.
A number of variations of the various elements may be substituted for those used in the imaging devices set forth above in the embodiments disclosed in F108. '1 to 4. Thus, any one of any combination of the elements hereinafter described may be substituted for a corresponding element hereinabove described.
With respect to the photoconductive layers hereinabove described, in addition to the brilliant green dye produced by the J. T. Baker Chemical Company which is added to the poly-n-vinyl carbazole photoconductor to sensitize it for red light, other dyes may also be used for sensitization, such as trinitro-9- fluorene for blue light sensitivity. Finely ground pigments such as phthalocyanine may also be added to the poly-n-vinyl carbazole to obtain visible light sensitivity. Other organic photoconductors known in the art may also be utilized effectively. In addition, non-organic photoconductors, such as selenium and selenium alloys, may also be used.
Adjacent photoconductor and elastomer layers may be replaced by a single layer of a photoconductive elastomer under some circumstances, in all embodiments hereinabove set forth. For example, the
tive for blue or ultraviolet light by adding p-phenylenediamine, indoform and Calco oil orange dye manufactured by the American Cyanamid Company prior to the curing thereof.
With respect to the elastomer layers, a thin elastomer layer is capable of undergoing appreciable elastic deformation for only a limited bandwidth of spatial frequencies. Its response outside this bandwidth is quite limited. The spatial frequency response of the elastomer may be broadened or made multiply peaked by replacing the single elastomer layer with a multiply layered apparatus as illustrated in FIG. 5. Each of these layers 25, 26, 27 and 28 will have a different limited spatial frequency response, but the combination of layers will have a broad or multiply peaked spatial frequency response. In general, it will be noted that the thickest layer 25 will-be placed closest to the photoconductor and the thinnest layer 28 will have the deformable surface. Two or more of such layers may be used as desired. As described previously, each of these layers may also be photoconductive, eliminating the need for a separate photoconductor and in some instances enhancing the resolution of the device.
It should also be noted that in addition to controlling the thickness of the elastomer layer to peak its spatial frequency response for a given spatial frequency bandwidth, its elastic modulus will also be controlled to obtain deformations commensurate with that spatial frequency bandwidth. Materials of lower elastic modulus are capable of greater elastic deformations. On the other hand, materials of higher elastic modulus may be more quickly erased. Such factors must be taken into account when designing the apparatus for speed or greater deformation.
In several of the above embodiments, there is described the reflection of light from the elastomer surface. Numerous methods known in the art are available for enhancing such reflection. In addition to these, the previously mentioned thin layers of gold or indium, and/or other suitable metals, vacuum deposited on the surface of the elastomer provide a highly reflective surface that is sufficiently smooth to cause little optical noise. These metal depositions do not appear to appreciably change the elastic behavior or the electrical insulating properties of the elastomer surface, but it greatly enhances the reflective power of such surfaces.
It has hereinabove been set forth that the elastomer surfaces as described. herein may be used for the recording, storage and erasure of image information over a great many cycles, provided that the electric fields across the elastomer are not allowed to become excessively great. When these fields do become great enough that the deformations of the elastomer surface exceed the elastic limit of the elastomer, it has been observed that the image is permanently recorded on the elastomer. The upper limit on the electric field applied to the previously mentioned dimethylpolysiloxane silicone gel is observed to be about 100 volts per micron. While for many systems this is regarded as undesirable, there are those in which it is also desired to record a permanent image. Thus, the cyclic properties of the elastomer may be used in an attempt to obtain a satisfactory image, which is then permanently recorded by an over voltage application.
FIGS. 6 through I show actual physical'er'nbodb sandwich, the reflected light from which would be reflected away from the elastomer surface in the unfrosted areas, while the light impinging thereon would be scattered when reflected by the frosted area of the image. Such scattered light from the frosted areas would enter the lens and would form an image at the image plane. For this image, frosted areas would appear bright, unfrosted areas dark, yielding a positive image having bright and dark areas corresponding to those of the original object.
If the light source were a coherent light source as from a laser, the system set forth in FIG. 6 cou'd be utilized to record a hologram. That is, the light source in FIG. 621 would be extended to impinge directly upon the imaging sandwich as a reference beam to coact with the object modulated beam from the objectto form a holographic image at the imaging sandwich. Upon reconstruction, the light source would be a similar light source which would impinge upon the imaging sandwich as indicated in FIG. 6b. In FIG. 6b, however, the lens would be unnecessary to form the reconstructed image.
The apparatus in FIGS. 6a and 6b are pertinent to the embodiments shown in FIGS. 1 to 4. With regard to the embodiment shown in FIG. 2, if conductor 10 is transparent, the readout light may be incident from either the left or the rightflf the layer 10 is opaque, the readout light may be incident from the left. In this latter case, the image may be readout at the same time the image is being recorded. With regard to the embodiment shown in FIG. 3, if fluid I6 is transparent, the readout light may be incident from either the right or the left. If the fluid is opaque, the readout light must be incident from the left.
FIG. 7 of the present application shows another structure which utilizes the principles of the present invention. In a manner similar to that for FIG. 6a, the light source impinges upon the object, the reflection from which is imaged by the lens onto the imaging device. With the technique utilized in FIGS. 1 to 4, the elastomer in the presence of the electrical field records the image impinged thereon. Upon reconstruction, in FIG. 7, the light source now illuminates the recorded image on the elastomer layer. The reflection from the elastomer layer is gathered by the lens which images the reflected image onto a plane. Between the plane and the lens is a focus point for the lens which,by the Y use of a spatial filter, causes a positive or negative image to be generated-at the image plane. That is, a frost image reflects high frequency spatial frequencies while the unfrosted areas reflect very low frequency spatial frequencies. Thus, a solid spatial frequency filter placed at the focal point for the lens filters the low frequency spatial signals while allowing the high frequency spatial signals to be passed and imaged on the image plane as a positive image. For a negative image, an annular spatial filter is utilized which filters the high frequency spatial signals while passing the low frequency spatial frequency signals. The embodiments shown in FIG. 7 are applicable to the embodiments set forth in FIGS. 1 to 4 and are additionally applicable in the production of a hologram as set forth above.
FIG. 8 shows an additional embodiment utilizing the principles of the present invention, the image thereof being recorded in a manner similar to that set forth in FIG. 6a. Upon reconstruction, however, the light source would be transmitted through the elastomer layer rather than reflecting from it as set forth in FIGS. 6 and 7. Again, for either a positive or negative image, the particular spatial filter is required. This embodiment is pertinent to FIGS. 1 through 4 as were the embodiments in FIGS. 6 and 7. With respect to FIG. 2, the embodiment therein is to be utilized only if the conductive layer 10 is transparent. With respect to the embodiment in FIG. 3, the embodiment therein can be utilized only if the conductive fluid 16 is transparent.
FIG. 9 shows apparatus utilizing the principles of the present invention wherein the construction and reconstruction steps occur simultaneously with similar or different light sources. That is, light from an object illuminated with light of a given wavelength and intensity is focused on the photoconductor of the imaging sandwich. Simultaneously, light of a possibly different wavelength and/or intensity is reflected from the coated surface of the elastomer. This image is converted to an intensity image at the image plane as was set forth above in conjunction with FIG. 6. The apparatus of FIG. 9 can be extended as was the apparatus of FIGS. 6 and 7 for the construction of a hologram. That is, in FIG. 9 the illumination light source would not only be impinged upon the object to generate an object modulated wavefront, but would be impinged upon the imaging sandwich as a reference beam. Then, at the surface of the elastomer, a hologram would be constructed in accordance with the object and reference wavefronts. Of course, the illumination light source must now be coherent as from a laser source, for example. Upon readout, a coherent light source would impinge upon the other side of the imaging sandwich, the light diffracted therefrom forming the reconstructed image. Here, of course, the lens system would not be necessary. FIG. 9 is pertinent to the embodiment set forth in FIG. 2 for simultaneous image recording and readout primarily if a reasonably opaque metal is used for layer 10, or if the readout wavelength is nonactinic for the photoconductor. That is, the photoconductive layer of the imaging sandwich cannot be sensitive'to the readout light source or else the readout light source will affect the generation of the image on the elastomer surface. If these conditions do not hold, FIG. 9 is pertinent to the embodiment set forth in FIG. 2 primarily if the image is first formed and subsequently read out. That is, readout light would not be present duringimage forming in sufficient intensity to interfere with image forming. FIG. 9 is also pertinent to the embodiments shown in FIGS. 1, 3 and 4 for simultaneous image recording and readout. It is also pertinent to the use of high and low pass spatial filters, depending upon the generation of a positive or negative image.
FIG. I0 utilizes the imaging sandwich for holographic recording. In FIG. l0a, a laser source would impinge upon the object by means of reflection from a mirror, for example, while an unobstructed reference beam would impinge upon the imaging sandwich. The modulated beam from the object would coact with the reference beam within the photoconductor layer forming a holographic image therein. By deleting the mirror and the object itself, the laser source can be used to reconstruct the image for an observer as shown in FIG. 10b. Thus, FIG. 10 shows the use of the imaging sandwich to record a holographic interference pattern instead of a focused image. Those comments set forth above for FIG. 8 would apply here except it is noted that for readout the impinging wavefront must be coherent.
The system illustrated schematically in FIG. 11 employs a cyclic imaging member 51 according to the present invention and preferably the embodiment represented by FIG. 2. The portion 52 represents the transparent substrate, conductive layer and photoconductor while portion 53 represents an elastomer layer overcoated with an opaque, reflective, electrically conductive layer which deforms with the elastomer. The system utilizes the imaging member 51 as a buffer storage device between devices such as a digital and/or analog computer, the output of which is represented by the arrow 54, and the xerographic reproduction apparatus 55. The buffer storage device permits asynchronous operation of the computer and xerographic apparatus.
Digital information is converted to analog information by the analog to digital converter 57 which develops appropriate signals for driving the cathode ray tube (CRT) 58. Conventionally, electron beam position information is fed to the CRT through appropriate vertical and horizontal deflection circuits 59 and 60, respectively, and beam intensity information is fed to the CRT through an appropriate brightness circuit 61. The CRT normally includes a phosphor screen 62, or the like, which remains illuminated sufficiently long after the scanning beam has passed to form a full frame image over its face. Alternately, the screen may be illuminated 'substantially only at areas at which the scanning beam currently resides. In either case, the member 51 is able to record the loci of the beam and retains the information for a comparatively long period of time as long as an electric field is applied across the elastomer. Consequently, a two dimensional image may be formed on the surface of the CRT by any scanning or raster pattern and be simultaneously or subsequently recorded as a surface deformation image on member 5!. Appropriate lens elements 63 are interposed between the photoconductor on member 51 and the screen 62 to create the surface deformation image. The photoconductor in the member 51 must be sufficiently sensitive to respond to the relatively low levels of light available from CRT displays. Seleniumand selenium arsenic alloys are examples of photoconductors having sensitivities in the order of l erg/cm which are capable of rapid response to the light levels associated with CRT displays.
The surface deformation image created on portion 53 of member 51 is simultaneously or subsequently read out by appropriate means such as that including lamp 65 and lens 66. The lamp is a non-coherent light source of high intensity. As explained earlier, the light is diffracted by the surface deformation image, is collected by appropriate lens elements 66 and focused onto a plane tangent to drum 71. The image temporarily recorded on member 51 is permanently recorded by I special consideration is given in an actual machine to compensate for changing distances between lens 66 and image point 72. For example, the focal length of lens 66 may be that distance between the lens and point 72 when the lens is at the midpoint in its scanning path as shown. The amount of out-of-focus when the lens is at other points in the scan path indicated by the phantom lines of a lens is minimized by techniques known in the art.
The xerographic drum includes a photoreceptor coated onto a grounded conductive drum. The photoreceptor is charged by a corotron 73 and a latent electrostatic image is created on this charged surface as the drum moves past the shield 70. The latent image is developed by appropriate apparatus such as a cascade developer 74 that pours microscopic toner particles onto the drum that adhere in the image areas. The developed latent image, i.e., the toner image, is transferred to web 75 by electrostatics when corotron 76 deposits charge of appropriate polarity on the back side of the web. The toner image is permanently fixed to the web by heating the toner as with fuser 77. The drum surface is cleaned by means 78, e.g., a brush, flooded with light by lamp 79 and recharged bycorotron 73 to prepare for the formation of another toner image.
When two or more imaging members 51 are arranged in parallel, one can be used to record information generated on the CRT while other imaging members are being read out by having their recorded information projected onto a recording medium such as the xerographic apparatus.
The above described systems are highly advantageous because analog and digital computers often generate information in irregular time intervals whereas xerographic and other recording apparatus operate on highly organized information and employ fixed operating cycles. The image device 51 bridges the gap because it is able to: record irregularly'generated information; hold the information in a highly organized state for getting into phase with the reproduction cycle of xerographic or other imaging device; rapidly erase the recorded information; and immediately record new information.
The xerographic apparatus 55 may be replaced by other recording materials and/or apparatus. For example, photographic type films having sensitivities far too insensitive to respond to the light levels generated by a CRT display may be used because the necessary energy levels can be supplied by lamp 65. Vesicular duplicating films available from the Kalvar Corp. of New Orleans, La. are examples of such films.
In the foregoing there has been disclosed methods and apparatus indicating the application of elastomers to various imaging apparatus as described herein. By-
the use of an elastomer material, there is obtained a fully cyclical imaging apparatus on which images may be recorded, stored for short periods of time and erased at will. in the specification herein, specific materials and construction have been discussed with regard to the makeup of the imaging sandwich, but it is obvious that other construction may be available utilizing the elastomer material without deviating from the principles of the present invention. Therefore, while the invention has been described with reference to specific embodiments, it will be understood by those skilled in the art that various changes may be made and' equivalents may be substituted for elements thereof without departing from the true spirit and scope of the invention. In addition, many modifications may be made to adapt to a particular situation without departing from the essential teachings of the invention.
What is claimed is: 1. An imaging method comprising the steps of: providing an imaging member comprising a layer of photoconductive material, an electric field deformable elastomer layer having a volume resistivity above about 10 ohm-cm. adjacent said photoconductive material layer and a deformable layer of a conductive gas adjacent said deformable elastomer layer, said conductive gas layer including means for ionizing said conductive gas; subjecting said imaging member to an electric field; and exposing said imaging member to information modulated electromagnetic radiation to which the photoconductive material is responsive to deform said elastomer layer corresponding to changes in the electric field caused by the exposure.
2. The method as defined in claim 1 wherein said exposing includes projecting a radiation image pattern onto said imaging member.
3. The method as defined in claim 1 wherein said imaging member further includes a substrate for supporting the layers of said imaging member.
4. The method as defined in claim 1 wherein said imaging member includes a plurality of electric field deformable elastomer layers, each said elastomer layer having different thickness and modulus of elasticity from said other elastomer layers.
5. The method as defined in claim 1 further including the step of erasing deformations created on said elastomer layer.
6. The method as defined in claim 5 wherein said step of erasing includes removing the electric field to which said imaging member is subjected.
7. The method as defined in claim 5 wherein said step of erasing includes reversing the polarity of the field to which said imaging member is subjected.
8. The method as defined in claim 1 further including illuminating said imaging member with electromagnetic radiation to optically constructan image of the surface deformation on said elastomer layer.
9. The method as defined in claim 1 wherein said electric field to which said imaging member is subjected is spatially modulated at a frequency within the spatial frequency deformation capability of the elastomer layer.
10. The method as defined in claim 1 wherein said radiation to which said imaging member is exposed includes radiation generated by a cathode ray tube.
11. The method as defined in claim 1 wherein said elastomer layer has a predetermined elastic modulus such that a deformation created therein by an electric field of sufficient strength can be locked in and said electric field is of sufficient strength to lock in said deformation, wherein said deformation remains while said electric field is maintained and is not substantially affected by subsequent exposure to illumination to which said photoconductive material is responsive.
12. An imaging method comprising the steps of:
providing an imaging member comprising an electric field deformable elastomer layer having a volume resistivity above about 10 ohm-cm., said elastomer layer including photoconductive material, and a deformable layer of a conductive gas adjacent said deformable elastomer layer, said conductive gas layer including means for ionizing said conductive gas;
subjecting said imaging member to an electric field;
. and exposing said imagingmember to information modulated electromagnetic radiation to which the photoconductive material is responsive to deform said elastomer layer corresponding to changes in the electric field caused by the exposure.
13. The method as defined in claim 12 wherein said exposing includes projecting a radiation image pattern onto said imaging member. l
14. The method as defined infclaim 12 wherein said imaging member further includes a substrate adjacent the side of the elastomer layer opposite from that to which the deformable conductive gas layer is adjacent.
15. The method as defined in claim 12 further including the step of erasing deformations created on said elastomer layer.
16. The method as defined in claim 15 wherein said step of erasing includes removing the electric field to which said imaging member is subjected.
17. The method as defined in claim 15 wherein said step of erasing includes reversing the polarity of the field to which said imaging member is subjected.
18. The method as defined in claim 12 further ineluding illuminating said imaging member with electromagnetic radiation to optically construct an image of the surface deformation on said elastomer layer.
19. The method as defined in claim 12 wherein said electric field to which said imaging member is subjected is spatially modulated at a frequency'within the spatial frequency deformation capability of the elastomer layer. I
20. The method as defined in claim 12 wherein said radiation to which said imaging member is exposed includes radiation generated by a cathode ray tube.
21. The method as defined in claim 12 wherein said elastomer layer has a predetermined elastic modulus such that a deformation created therein by an electric field of sufficient strength can be locked in and said electric field is of sufficient strength to lock in said deformation, wherein said deformation remains while said electric field is maintained and is not substantially affected by subsequent exposure to illumination to I elastomer layer having a volume resistivity above about 10 ohm-cm. adjacent said photoconductive material layer and a deformable layer of conductive gas adjacent said deformable elastomer layer, said conductive gas layer including means for ionizing said conductive gas, and said elastomer layer being capable of deforming to correspond to an electric field pattern created by altering an electrical field across said elastomer layer by exposing the photoconductive material to electromagnetic radiation to which it is responsive.
23. The imaging member as defined in claim 22 further including a substrate for supporting the layers of said imaging member.
24. The imaging member as defined in claim 23 wherein said substrate is a transparent conductive member.
25. The imaging member as defined in claim 22 wherein said member includes a plurality of said electric field deformable elastomer layers, each said elastomer layer having different thickness and elastic modulus from said other elastomer layers.
26. The imaging member as defined in claim 22 further including means for spatially modulating an electric field across said elastomer layer at a frequency within the spatial frequency deformation capability. of the elastomer layer.
27. The imaging member as defined in claim 26 wherein said means for spatially modulating includes a line grating adjacent said photoconductive material layer.
28. The imaging member as defined in claim 22 wherein said elastomer layer has a predetermined elastic modulus wherein said elastomer layer is capable or deforming and locking in said deformation under the I influence of an electric field of sufficient strength and wherein said deformation remains while said electric field is maintained and is not substantially affected by subsequent exposure to illumination to which said photoconductive material is responsive.
29. An imaging member comprising an electric field deformable elastomer layer having a volume resistivity above about 10 ohm-cm., said elastomer layer including photoconductive material, and a deformable layer of a conductive gas adjacent said deformable elastomer layer, said conductive gas layer including means for ionizing said conductive gas, and said elastomer layer being capable of deforming to correspond to an electric field pattern created by altering an electrical field across said elastomer layer by exposing said member to electromagnetic radiation to which said photoconductive material is responsive.
30. The imaging member as defined in claim 29 further including a substrate adjacent the side of the elastomer layer opposite from that to which the deformable conductive gas layer is adjacent.
'31. The imaging member as defined in claim 30 wherein said substrate is a transparent conductive member.
32. The imaging member as defined in claim 29 further including means for spatially modulating an electric field across said elastomer layerat a frequency within the spatial frequency deformation capability of the elastomer layer.
33. The imaging member as defined in claim 32 wherein said means for spatially modulating includes line grating adjacent said elastomer layer.
34. The imaging member as defined in claim 29 wherein said elastomer layer has a predetermined elastic modulus wherein said elastomer layer is capable of deforming and locking in said deformation under the influence of an electric field of sufficient strength and wherein said deformation remains while said electric field is maintained and is not substantially affected by subsequent exposure to illumination to which said photoconductive material is responsive.
35. An imaging method comprising the steps of:
providing an imaging member comprising a layer of photoconductive material and a plurality of electric field deformable elastomer layers overlying said photoconductive material layer, each said elastomer layer having a volumeresistivity above l ohm-cm. and each said elastomer layer having a different thickness and elastic modulus from said other elastomer layers;
subjecting said imaging member to an electric field;
and
exposing said imaging member to information modulated electromagnetic radiation to which the photoconductive material is responsive to deform said elastomer layers corresponding to changes in the electric field caused by the exposure.
36. The method as defined in claim 35 wherein said exposing includes projecting a radiation image pattern onto said imaging member.
. 37. The method as defined in claim 35 wherein said imaging member further includes a substrate for supporting the layers of said imaging member.
38. The method as defined in claim 37 wherein said substrate is a transparent conductive member.
39. The method as defined in claim 35 wherein said step of subjecting said imaging member to an electric field includes depositing electrostatic charge adjacent said elastomer layer.
40. The method as defined in claim 35 wherein said imaging member further includes a deformable conductive layer adjacent the surface of said elastomer layer remote from said photoconductive material layer.
41. The method as defined in claim 40 wherein said deformable conductive layer comprises a layer of conductive liquid.
42. The method as defined in claim 40 wherein said deformable conductive layer comprises a layer of conductive gas, said conductive gas layer including means for ionizing said conductive gas.
43. The method as defined in claim 40 wherein said deformable conductive layer comprises a flexible conductive metal layer.
44. The method as defined in claim 35 further including the step of erasing deformations created on the elastomer layers.
45. The method as defined in claim 35 further including illuminating said imaging member with electromagnetic radiation to optically construct an image of the surface deformations on said elastomer layer.
46. An imaging member comprising a layer of photoconductive material and a plurality of electric field deformable elastomer layers overlying said photoconductive material layer, each said elastomer layer having a volume resistivity above about ohmcm. and each said elastomer layer having a different thickness and elastic modulus from said other .member.
' imaging member further includes a substrate for sup- 22- elastomer layers, said elastomer layers being capable of deforming to correspond to an electric field pattern created by altering an electrical field across said elastomer layer by exposing the photoconductive materialto electromagnetic radiation to which it is responsive.
47. The imaging member as defined in claim 46 further including a substrate for supporting the layers of said imaging member.
48. The imaging member as defined in claim 47 I wherein said substrate 'is a transparent conductive 49. The imaging member as defined in claim 46 further including a deformable conductive layer adjacent the surface of said elastomer layerremote from said photoconductive material layer.
50. The imaging member as defined in claim 49 wherein said deformable conductive layer comprises a layer of conductive liquid.
51. The imaging member as defined in claim 49 wherein said deformable conductive layer comprises a layer of conductive gas, said conductive gas layer including means for ionizing said gas.
52. The imaging member as defined in claim 49 wherein said deformable conductive layer comprises a flexible conductive metal layer.
53. An imaging member comprising a plurality of electric field deformable elastomer layers, each said elastomer layer having a volume resistivity above about i 10 ohm-cm., each said elastomer layer having a different thickness and elastic modulus from said other elastomer layers, and at least one of said elastomer layers including photoconductive material wherein said elastomer layers are capable of deforming to correspond to an electric field pattern created by altering an electrical field across said elastomer layers by exposing the member to electromagnetic radiation to which the photoconductive member is responsive.
54. An imaging method comprising the steps of: providing an imaging member comprising a layer of photoconductive material, an electric field deformable elastomer layer having a volume resistivity above about 10 ohm-cm. adjacent said photoconductive material layer and a deformable conductive layer adjacent said elastomer layer, said deformable conductive layer comprising gold and indium; subjecting said imaging member to an electric field;
and
exposing said imaging member to information modulated electromagnetic radiation to which the photoconductive material is responsive to deform said elastomer layer corresponding to changes in the electric field caused by the exposure.
55. The method as defined in claim 54 wherein said exposing includes projecting a radiation image pattern onto said imaging member.
56. The method as defined in claim 54 wherein said porting the layers of said imaging member.
57. The method as defined in claim 56 wherein said substrate is a transparent conductive member. I
58. The method as defined in claim 57 further including illuminating said imaging member with readout electromagnetic radiation to optically construct an image of the surface deformation on said elastomer layer. 7
59. The method as defined in claim 58 wherein said information modulated and readout radiation include radiation of different wavelengths.
60. The method as defined in claim 58 wherein said readout radiation is radiation to which the photoconductive layer is substantially not responsive.
61. The method as defined in claim 58 wherein said readout radiation includes radiation of substantially higher intensity than said information modulated radiation for amplifying the image represented by said modulated radiation.
62. The method as defined in claim 58 wherein one of said information modulated and readout radiation includes coherent radiation and the other non-coherent radiation.'
63. The method as defined in claim 62 wherein said information modulated radiation includes coherent radiation and said readout radiation includes noncoherent radiation.
64. The method as defined in claim 62 wherein said information modulated radiation includes noncoherent radiation and said readout radiation includes coherent radiation.
65. The method as defined in claim 58 wherein said information modulated radiation includes the interference pattern formed by superpositioning of reference coherent radiation and object modulated coherent radiation.
66. The method as defined in claim 54 wherein said imaging member includes a plurality of electric field deformable elastomer layers, each said elastomer layer having different thickness and elastic modulus from said other elastomer layers.
67. The method as defined in claim 58 further including the step of erasing deformations created on the elastomer layer. a
68. The method as defined in claim 67 wherein said step of erasing includes removing the electric field to which said imaging member is subjected.
69. The method as defined in claim 67 wherein said step of erasing includes reversing the polarity of the field to which said imaging member is subjected.
70. The method as defined in claim 54 wherein said electric field to which said imaging member is subjected is spatially modulated at a frequency within the spatial frequency deformation capability of the elastomer layer.
71. The method as defined in claim 54 wherein said radiation to which said imaging member is exposed includes radiation generated by a cathode ray tube.
72. The method as-defined in claim 54 wherein said elastomer layer has a predetermined elastic modulus such that a deformation created therein by an electric field of sufficient strength can be locked in and said electric field is of sufficient strength to lock in said deformation, wherein said deformation remains while said electric field is maintained and is not substantially affected by subsequent exposure to illumination to which said photoconductive material is responsive.
73. An imaging method comprising the steps of:
providing an imaging member comprising an electric field deformable elastomer layer having a volume resistivity above about 10 ohm-cm., said elastomer layer including photoconductive material, and a deformable conductive layer adjacent said elastomer layer. said deformable conductive imaging member further includes a substrate adjacent.
the side of the elastomer layer opposite from that to which the deformable conductive layer is adjacent.
76. The method as defined in claim 75 wherein said substrate is a transparent conductive member.
77. The method as defined in claim 76 further including illuminating said imaging member with readout electromagnetic radiation to optically construct an image of the surface deformation on said elastomer layer.
78. The method as defined in claim 77 further including the step of erasing deformations created on the elastomer layer.
79. The method as defined in claim 78 wherein said step of erasing includes removing the electric field to which said imaging member is subjected.
80. The method as defined in claim 78 wherein said step of erasing includes reversing the polarity of the field to which said imaging member is subjected.
81. The method as defined in claim 73 wherein said electric field to which said imaging member is subjected is spatially modulated at a frequency within the spatial frequency deformation capability of the elastomer layer.
82. The method as defined in claim 73 wherein said I radiation to which said imaging member is exposed includes radiation generated by a cathode ray tube.
83. The method as defined in claim 73 wherein said elastomer layer has a predetermined elastic modulus such that a deformation created therein by an electric field of sufficient strength can be locked in and said electric field is of sufficient strength to lock in said deformation, wherein said deformation remains while said electric field is maintained and is not substantially affected by subsequent exposure to illumination to which said photoconductive material is responsive.
84. An imaging member comprising a layer of photoconductive material, an electric field deformable elastomer layer having a volume resistivity above about l0 ohm-cm. adjacent said photoconductive material layer and a deformable conductive layer adjacent said elastomer layer; said deformable conductive layer comprising gold and indium, said elastomer layer being capable of deforming to correspond to an electric field pattern created by altering an electrical field across said elastomer layer by exposing the photoconductive material to electromagnetic radiation to which it is responsive.
85. The imaging member as defined in claim 84 further including a substrate for supporting the layers of said imaging member.
' wherein said member includes a pluralityof said electric field deformable elastomer layers, each said elastomer layer having different thickness and elastic modulus from said other elastomer layers.
88. The imaging member as defined in claim 84 wherein said elastomer layer comprises a dimethylpolysiloxane gel.
89. The imaging member as defined in claim 84 further including an insulating liquid layer adjacent the side of the deformable conductive layer opposite from that to which the elastomer layer is adjacent.
90. The imaging member as defined in claim 84 wherein said photoconductive material is chosen from the group consisting of selenium, selenium alloys and mixtures of poly-n-vinyl carbazole and a sensitizing dye.
91. The imaging member as defined in claim 84 further including means for spatially modulating an electric field across said elastomer layer at a frequency within the spatial frequency deformation capability of the elastomer layer.
92. The imaging member as defined in claim 91 wherein said means for spatially modulating includes a line grating adjacent said photoconductive material layer.
93. The imaging member as defined in claim 84 wherein said elastomer layer has a predetermined elastic modulus such that said elastomer layer is capable of deforming and locking in said deformation under the influence of an electric field of sufficient strength and wherein saiddeformation remains while said electric field is maintained and is not substantially affected by subsequent exposure to illumination to which said photoconductive material is responsive.
94. An imaging member comprising an electric field deformable elastomer layer having a volume resistivity above about ohm-cm., said elastomer layer including photoconductive material, and a deformable eonductive layer adjacent said elastomer layer, said deformable conductive layer comprising gold and indium, said elastomer layer being capable of deforming to correspond to an electric field pattern created by altering an electrical field across said elastomer layer by exposing the photoconductive material to electromagnetic radiation to which it is responsive. v 95. The imaging member as defined in claim 94 further including a substrate for supporting said layers of said imaging member.
96. The imaging member as defined in claim 95 wherein said substrate is a transparent conductive member.
97. The imaging member as defined in claim 94 further including an insulating liquid layer adjacent the side of the deformable conductive layer opposite from that to which the elastomer layer is adjacent.
98. The imaging member as defined in claim 94 further including means for spatially modulating an electric field across said elastomer layer at a frequency within the spatial frequency deformation capability of the elastomer layer.
99. The imaging member as defined in claim 98 wherein said means for spatially modulating includes a line gating adjacent said elastomer latyer.
l The imaging member as de med in claim 94 wherein said elastomer layer has a predetermined elastic modulus such that said elastomer layer is capable of deforming and locking in said deformation under the influence of an electric field of sufficient strength and wherein said deformation remains while said electric field is maintained and is not substantially affected by subsequent exposure to illumination to which said photoconductive material is responsive.
101. An imaging member comprising a layer 'of photoconductive material,an electric field deformable elastomer layer having a volume resistivity above about 10 ohm-cm. adjacent said photoconductive material layer and a deformable conductive layer adjacent said elastomer layer, said deformable conducting layer comprising first and second metal materials, wherein said first metal material is chosen from the group consisting of gold, aluminum, silver, magnesium copper, cobalt, iron, chromium and nickel, said second metal material is chosen from the group consisting of indium, gallium, cadmium, mercury and lead, and said elastomer layer being capable of deforming to correspond to an electric field pattern created by altering an electrical field across said elastomer layer by exposing the photoconductive material to electromagnetic radiation to which it is responsive.
102. An imaging member comprising an electric field deformable elastomer layer having a volume resistivity above about 10 ohm-cm., said elastomer layer including photoconductive material, and a deformable conductive layer adjacent said elastomer layer, said deformable conductive layer comprising first and second metal materials, wherein said first metal material is chosen from the group consisting of gold, aluminum, silver, magnesium, copper, cobalt, iron, chromium and nickel, said second metal material is chosen from the group consisting of indium, gallium, cadmium, mercury and lead, and said elastomer layer being capable of deforming to correspond to an electric field pattern created by altering an electric field across said elastomer layer by exposing the photoconductive material to electromagnetic radiation to which it is responsive.
a e e a:

Claims (101)

1. An imaging method comprising the steps of: providing an imaging member comprising a layer of photoconductive material, an electric field deformable elastomer layer having a volume resistivity above about 104 ohm-cm. adjacent said photoconductive material layer and a deformable layer of a conductive gas adjacent said deformable elastomer layer, said conductive gas layer including means for ionizing said conductive gas; subjecting said imaging member to an electric field; and exposing said imaging member to information modulated electromagnetic radiation to which the photoconductive material is responsive to deform said elastomer layer corresponding to changes in the electric field caused by the exposure.
2. The method as defined in claim 1 wherein said exposing includes projecting a radiation image pattern onto said imaging member.
3. The method as defined in claim 1 wherein said imaging member further includes a substrate for supporting the layers of said imaging member.
4. The method as defined in claim 1 wherein said imaging member includes a plurality of electric field deformable elastomer layers, each said elastomer layer having different thickness and modulus of elasticity from said other elastomer layers.
5. The method as defined in claim 1 further including the step of erasing deformations created on said elastomer layer.
6. The method as defined in claim 5 wherein said step of erasing includes removing the electric field to which said imaging member is subjected.
7. The method as defined in claim 5 wherein said step of erasing includes reversing the polarity of the field to which said imaging member is subjected.
8. The method as defined in claim 1 further including illuminating said imaging member with electromagnetic radiation to optically construct an image of the surface deformation on said elastomer layer.
9. The method as defined in claim 1 wherein said electric field to which said imaging member is subjected is spatially modulated at a frequency within the spatial frequency deformation capability of the elastomer layer.
10. The method as defined in claim 1 wherein said radiation to which said imaging member is exposed includes radiation generated by a cathode ray tube.
11. The method as defined in claim 1 wherein said elastomer layer has a predetermined elastic modulus such that a deformation created therein by an electric field of sufficient strength can be locked in and said electric field is of sufficient strength to lock in said deformation, wherein said deformation remains while said electric field is maintained and is not substantially affected by subsequent exposure to illumination to which said photoconductive material is responsive.
12. An imaging method comprising the steps of: providing an imaging member comprising an electric field deformable elastomer layer having a volume resistivity above about 104 ohm-cm., said elastomer layer including photoconductive material, and a deformable layer of a conductive gas adjacent said deformable elastomer layer, said conductive gas layer including means for ionizing said conductive gas; subjecting said imaging member to an electric field; and exposing said imaging member to information modulated electromagnetic radiation to which the photoconductive material is responsive to deform said elastomer layer corresponding to changes in the electric field caused by the exposure.
13. The method as defined in claim 12 wherein said exposing includes projecting a radiation image pattern onto said imaging member.
14. The method as defined in claim 12 wherein said imaging member further includes a substrate adJacent the side of the elastomer layer opposite from that to which the deformable conductive gas layer is adjacent.
15. The method as defined in claim 12 further including the step of erasing deformations created on said elastomer layer.
16. The method as defined in claim 15 wherein said step of erasing includes removing the electric field to which said imaging member is subjected.
17. The method as defined in claim 15 wherein said step of erasing includes reversing the polarity of the field to which said imaging member is subjected.
18. The method as defined in claim 12 further including illuminating said imaging member with electromagnetic radiation to optically construct an image of the surface deformation on said elastomer layer.
19. The method as defined in claim 12 wherein said electric field to which said imaging member is subjected is spatially modulated at a frequency within the spatial frequency deformation capability of the elastomer layer.
20. The method as defined in claim 12 wherein said radiation to which said imaging member is exposed includes radiation generated by a cathode ray tube.
21. The method as defined in claim 12 wherein said elastomer layer has a predetermined elastic modulus such that a deformation created therein by an electric field of sufficient strength can be locked in and said electric field is of sufficient strength to lock in said deformation, wherein said deformation remains while said electric field is maintained and is not substantially affected by subsequent exposure to illumination to which said photoconductive material is responsive.
22. An imaging member comprising a layer of photoconductive material, an electric field deformable elastomer layer having a volume resistivity above about 104 ohm-cm. adjacent said photoconductive material layer and a deformable layer of conductive gas adjacent said deformable elastomer layer, said conductive gas layer including means for ionizing said conductive gas, and said elastomer layer being capable of deforming to correspond to an electric field pattern created by altering an electrical field across said elastomer layer by exposing the photoconductive material to electromagnetic radiation to which it is responsive.
23. The imaging member as defined in claim 22 further including a substrate for supporting the layers of said imaging member.
24. The imaging member as defined in claim 23 wherein said substrate is a transparent conductive member.
25. The imaging member as defined in claim 22 wherein said member includes a plurality of said electric field deformable elastomer layers, each said elastomer layer having different thickness and elastic modulus from said other elastomer layers.
26. The imaging member as defined in claim 22 further including means for spatially modulating an electric field across said elastomer layer at a frequency within the spatial frequency deformation capability of the elastomer layer.
27. The imaging member as defined in claim 26 wherein said means for spatially modulating includes a line grating adjacent said photoconductive material layer.
28. The imaging member as defined in claim 22 wherein said elastomer layer has a predetermined elastic modulus wherein said elastomer layer is capable of deforming and locking in said deformation under the influence of an electric field of sufficient strength and wherein said deformation remains while said electric field is maintained and is not substantially affected by subsequent exposure to illumination to which said photoconductive material is responsive.
29. An imaging member comprising an electric field deformable elastomer layer having a volume resistivity above about 104 ohm-cm., said elastomer layer including photoconductive material, and a deformable layer of a conductive gas adjacent said deformable elastomer layer, said conductive gas layer including means for ionizing said conductive gas, and said elastomer layer being capable of deforming to correspond to An electric field pattern created by altering an electrical field across said elastomer layer by exposing said member to electromagnetic radiation to which said photoconductive material is responsive.
30. The imaging member as defined in claim 29 further including a substrate adjacent the side of the elastomer layer opposite from that to which the deformable conductive gas layer is adjacent.
31. The imaging member as defined in claim 30 wherein said substrate is a transparent conductive member.
32. The imaging member as defined in claim 29 further including means for spatially modulating an electric field across said elastomer layer at a frequency within the spatial frequency deformation capability of the elastomer layer.
33. The imaging member as defined in claim 32 wherein said means for spatially modulating includes a line grating adjacent said elastomer layer.
34. The imaging member as defined in claim 29 wherein said elastomer layer has a predetermined elastic modulus wherein said elastomer layer is capable of deforming and locking in said deformation under the influence of an electric field of sufficient strength and wherein said deformation remains while said electric field is maintained and is not substantially affected by subsequent exposure to illumination to which said photoconductive material is responsive.
35. An imaging method comprising the steps of: providing an imaging member comprising a layer of photoconductive material and a plurality of electric field deformable elastomer layers overlying said photoconductive material layer, each said elastomer layer having a volume resistivity above 104 ohm-cm. and each said elastomer layer having a different thickness and elastic modulus from said other elastomer layers; subjecting said imaging member to an electric field; and exposing said imaging member to information modulated electromagnetic radiation to which the photoconductive material is responsive to deform said elastomer layers corresponding to changes in the electric field caused by the exposure.
36. The method as defined in claim 35 wherein said exposing includes projecting a radiation image pattern onto said imaging member.
37. The method as defined in claim 35 wherein said imaging member further includes a substrate for supporting the layers of said imaging member.
38. The method as defined in claim 37 wherein said substrate is a transparent conductive member.
39. The method as defined in claim 35 wherein said step of subjecting said imaging member to an electric field includes depositing electrostatic charge adjacent said elastomer layer.
40. The method as defined in claim 35 wherein said imaging member further includes a deformable conductive layer adjacent the surface of said elastomer layer remote from said photoconductive material layer.
41. The method as defined in claim 40 wherein said deformable conductive layer comprises a layer of conductive liquid.
42. The method as defined in claim 40 wherein said deformable conductive layer comprises a layer of conductive gas, said conductive gas layer including means for ionizing said conductive gas.
43. The method as defined in claim 40 wherein said deformable conductive layer comprises a flexible conductive metal layer.
44. The method as defined in claim 35 further including the step of erasing deformations created on the elastomer layers.
45. The method as defined in claim 35 further including illuminating said imaging member with electromagnetic radiation to optically construct an image of the surface deformations on said elastomer layer.
46. An imaging member comprising a layer of photoconductive material and a plurality of electric field deformable elastomer layers overlying said photoconductive material layer, each said elastomer layer having a volume resistivity above about 104 ohm-cm. and each said elastomer layer having a different thickness and elastic modulus from said other elastomer layers, said elastomer layeRs being capable of deforming to correspond to an electric field pattern created by altering an electrical field across said elastomer layer by exposing the photoconductive material to electromagnetic radiation to which it is responsive.
47. The imaging member as defined in claim 46 further including a substrate for supporting the layers of said imaging member.
48. The imaging member as defined in claim 47 wherein said substrate is a transparent conductive member.
49. The imaging member as defined in claim 46 further including a deformable conductive layer adjacent the surface of said elastomer layer remote from said photoconductive material layer.
50. The imaging member as defined in claim 49 wherein said deformable conductive layer comprises a layer of conductive liquid.
51. The imaging member as defined in claim 49 wherein said deformable conductive layer comprises a layer of conductive gas, said conductive gas layer including means for ionizing said gas.
52. The imaging member as defined in claim 49 wherein said deformable conductive layer comprises a flexible conductive metal layer.
53. An imaging member comprising a plurality of electric field deformable elastomer layers, each said elastomer layer having a volume resistivity above about 104 ohm-cm., each said elastomer layer having a different thickness and elastic modulus from said other elastomer layers, and at least one of said elastomer layers including photoconductive material wherein said elastomer layers are capable of deforming to correspond to an electric field pattern created by altering an electrical field across said elastomer layers by exposing the member to electromagnetic radiation to which the photoconductive member is responsive.
54. An imaging method comprising the steps of: providing an imaging member comprising a layer of photoconductive material, an electric field deformable elastomer layer having a volume resistivity above about 104 ohm-cm. adjacent said photoconductive material layer and a deformable conductive layer adjacent said elastomer layer, said deformable conductive layer comprising gold and indium; subjecting said imaging member to an electric field; and exposing said imaging member to information modulated electromagnetic radiation to which the photoconductive material is responsive to deform said elastomer layer corresponding to changes in the electric field caused by the exposure.
55. The method as defined in claim 54 wherein said exposing includes projecting a radiation image pattern onto said imaging member.
56. The method as defined in claim 54 wherein said imaging member further includes a substrate for supporting the layers of said imaging member.
57. The method as defined in claim 56 wherein said substrate is a transparent conductive member.
58. The method as defined in claim 57 further including illuminating said imaging member with readout electromagnetic radiation to optically construct an image of the surface deformation on said elastomer layer.
59. The method as defined in claim 58 wherein said information modulated and readout radiation include radiation of different wavelengths.
60. The method as defined in claim 58 wherein said readout radiation is radiation to which the photoconductive layer is substantially not responsive.
61. The method as defined in claim 58 wherein said readout radiation includes radiation of substantially higher intensity than said information modulated radiation for amplifying the image represented by said modulated radiation.
62. The method as defined in claim 58 wherein one of said information modulated and readout radiation includes coherent radiation and the other non-coherent radiation.
63. The method as defined in claim 62 wherein said information modulated radiation includes coherent radiation and said readout radiation includes non-coherent radiation.
64. The method as defined in claim 62 wherein said information modulated radiation includes non-cohereNt radiation and said readout radiation includes coherent radiation.
65. The method as defined in claim 58 wherein said information modulated radiation includes the interference pattern formed by superpositioning of reference coherent radiation and object modulated coherent radiation.
66. The method as defined in claim 54 wherein said imaging member includes a plurality of electric field deformable elastomer layers, each said elastomer layer having different thickness and elastic modulus from said other elastomer layers.
67. The method as defined in claim 58 further including the step of erasing deformations created on the elastomer layer.
68. The method as defined in claim 67 wherein said step of erasing includes removing the electric field to which said imaging member is subjected.
69. The method as defined in claim 67 wherein said step of erasing includes reversing the polarity of the field to which said imaging member is subjected.
70. The method as defined in claim 54 wherein said electric field to which said imaging member is subjected is spatially modulated at a frequency within the spatial frequency deformation capability of the elastomer layer.
71. The method as defined in claim 54 wherein said radiation to which said imaging member is exposed includes radiation generated by a cathode ray tube.
72. The method as defined in claim 54 wherein said elastomer layer has a predetermined elastic modulus such that a deformation created therein by an electric field of sufficient strength can be locked in and said electric field is of sufficient strength to lock in said deformation, wherein said deformation remains while said electric field is maintained and is not substantially affected by subsequent exposure to illumination to which said photoconductive material is responsive.
73. An imaging method comprising the steps of: providing an imaging member comprising an electric field deformable elastomer layer having a volume resistivity above about 104 ohm-cm., said elastomer layer including photoconductive material, and a deformable conductive layer adjacent said elastomer layer, said deformable conductive layer comprising gold and indium; subjecting said imaging member to an electric field; and exposing said imaging member to information modulated electromagnetic radiation to which the photoconductive material is responsive to deform said elastomer layer corresponding to changes in the electric field caused by the exposure.
74. The method as defined in claim 73 wherein said exposing includes projecting a radiation image pattern onto said imaging member.
75. The method as defined in claim 73 wherein said imaging member further includes a substrate adjacent the side of the elastomer layer opposite from that to which the deformable conductive layer is adjacent.
76. The method as defined in claim 75 wherein said substrate is a transparent conductive member.
77. The method as defined in claim 76 further including illuminating said imaging member with readout electromagnetic radiation to optically construct an image of the surface deformation on said elastomer layer.
78. The method as defined in claim 77 further including the step of erasing deformations created on the elastomer layer.
79. The method as defined in claim 78 wherein said step of erasing includes removing the electric field to which said imaging member is subjected.
80. The method as defined in claim 78 wherein said step of erasing includes reversing the polarity of the field to which said imaging member is subjected.
81. The method as defined in claim 73 wherein said electric field to which said imaging member is subjected is spatially modulated at a frequency within the spatial frequency deformation capability of the elastomer layer.
82. The method as defined in claim 73 wherein said radiation to which said imaging member is exposed includes radiation generated by a cathode ray tube.
83. The method as defined in claim 73 wherein Said elastomer layer has a predetermined elastic modulus such that a deformation created therein by an electric field of sufficient strength can be locked in and said electric field is of sufficient strength to lock in said deformation, wherein said deformation remains while said electric field is maintained and is not substantially affected by subsequent exposure to illumination to which said photoconductive material is responsive.
84. An imaging member comprising a layer of photoconductive material, an electric field deformable elastomer layer having a volume resistivity above about 104 ohm-cm. adjacent said photoconductive material layer and a deformable conductive layer adjacent said elastomer layer; said deformable conductive layer comprising gold and indium, said elastomer layer being capable of deforming to correspond to an electric field pattern created by altering an electrical field across said elastomer layer by exposing the photoconductive material to electromagnetic radiation to which it is responsive.
85. The imaging member as defined in claim 84 further including a substrate for supporting the layers of said imaging member.
86. The imaging member as defined in claim 85 wherein said substrate is a transparent conductive member.
87. The imaging member as defined in claim 84 wherein said member includes a plurality of said electric field deformable elastomer layers, each said elastomer layer having different thickness and elastic modulus from said other elastomer layers.
88. The imaging member as defined in claim 84 wherein said elastomer layer comprises a dimethylpolysiloxane gel.
89. The imaging member as defined in claim 84 further including an insulating liquid layer adjacent the side of the deformable conductive layer opposite from that to which the elastomer layer is adjacent.
90. The imaging member as defined in claim 84 wherein said photoconductive material is chosen from the group consisting of selenium, selenium alloys and mixtures of poly-n-vinyl carbazole and a sensitizing dye.
91. The imaging member as defined in claim 84 further including means for spatially modulating an electric field across said elastomer layer at a frequency within the spatial frequency deformation capability of the elastomer layer.
92. The imaging member as defined in claim 91 wherein said means for spatially modulating includes a line grating adjacent said photoconductive material layer.
93. The imaging member as defined in claim 84 wherein said elastomer layer has a predetermined elastic modulus such that said elastomer layer is capable of deforming and locking in said deformation under the influence of an electric field of sufficient strength and wherein said deformation remains while said electric field is maintained and is not substantially affected by subsequent exposure to illumination to which said photoconductive material is responsive.
94. An imaging member comprising an electric field deformable elastomer layer having a volume resistivity above about 104 ohm-cm., said elastomer layer including photoconductive material, and a deformable conductive layer adjacent said elastomer layer, said deformable conductive layer comprising gold and indium, said elastomer layer being capable of deforming to correspond to an electric field pattern created by altering an electrical field across said elastomer layer by exposing the photoconductive material to electromagnetic radiation to which it is responsive.
95. The imaging member as defined in claim 94 further including a substrate for supporting said layers of said imaging member.
96. The imaging member as defined in claim 95 wherein said substrate is a transparent conductive member.
97. The imaging member as defined in claim 94 further including an insulating liquid layer adjacent the side of the deformable conductive layer opposite from that to which the elastomer layer is adjacent.
98. The imaging member as defined in claim 94 further including means for spatiallY modulating an electric field across said elastomer layer at a frequency within the spatial frequency deformation capability of the elastomer layer.
99. The imaging member as defined in claim 98 wherein said means for spatially modulating includes a line grating adjacent said elastomer layer.
100. The imaging member as defined in claim 94 wherein said elastomer layer has a predetermined elastic modulus such that said elastomer layer is capable of deforming and locking in said deformation under the influence of an electric field of sufficient strength and wherein said deformation remains while said electric field is maintained and is not substantially affected by subsequent exposure to illumination to which said photoconductive material is responsive.
101. An imaging member comprising a layer of photoconductive material, an electric field deformable elastomer layer having a volume resistivity above about 104 ohm-cm. adjacent said photoconductive material layer and a deformable conductive layer adjacent said elastomer layer, said deformable conducting layer comprising first and second metal materials, wherein said first metal material is chosen from the group consisting of gold, aluminum, silver, magnesium copper, cobalt, iron, chromium and nickel, said second metal material is chosen from the group consisting of indium, gallium, cadmium, mercury and lead, and said elastomer layer being capable of deforming to correspond to an electric field pattern created by altering an electrical field across said elastomer layer by exposing the photoconductive material to electromagnetic radiation to which it is responsive.
US00101729A 1970-12-28 1970-12-28 Cyclic recording system by the use of an elastomer in an electric field Expired - Lifetime US3716359A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10172970A 1970-12-28 1970-12-28

Publications (1)

Publication Number Publication Date
US3716359A true US3716359A (en) 1973-02-13

Family

ID=22286094

Family Applications (1)

Application Number Title Priority Date Filing Date
US00101729A Expired - Lifetime US3716359A (en) 1970-12-28 1970-12-28 Cyclic recording system by the use of an elastomer in an electric field

Country Status (12)

Country Link
US (1) US3716359A (en)
JP (1) JPS532061B1 (en)
AR (1) AR196734A1 (en)
AU (2) AU461213B2 (en)
BE (1) BE777320A (en)
BR (1) BR7107946D0 (en)
CA (1) CA953990A (en)
DE (1) DE2164340C3 (en)
FR (1) FR2120174B1 (en)
GB (1) GB1380057A (en)
IT (1) IT944392B (en)
NL (1) NL7117812A (en)

Cited By (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3842406A (en) * 1970-12-28 1974-10-15 Xerox Corp Cyclic recording system by the use of an elastomer in an electric field
US3861914A (en) * 1973-01-15 1975-01-21 Rca Corp Permanent holographic recording medium
US3877791A (en) * 1974-02-20 1975-04-15 Rca Corp Deformable mirror light valve and method of making the same
US3888591A (en) * 1974-01-21 1975-06-10 Xerox Corp Image subtraction apparatus
US3944358A (en) * 1974-09-20 1976-03-16 Xerox Corporation Color image reproduction system
US3951533A (en) * 1974-09-20 1976-04-20 Xerox Corporation Color image reproduction system
US3961950A (en) * 1975-01-10 1976-06-08 Xerox Corporation Imaging system
US3973958A (en) * 1973-12-28 1976-08-10 Xerox Corporation Method including exposure of deformation imaging member through lenticular lens element
US3973957A (en) * 1973-12-28 1976-08-10 Xerox Corporation Imaging method including exposure of deformation imaging member through lenticular lens element
US3980476A (en) * 1975-01-27 1976-09-14 Xerox Corporation Imaging system
FR2304948A1 (en) * 1975-03-17 1976-10-15 Hoechst Ag PROCESS FOR RECORDING RELIEF IMAGES ON A PHOTOCONDUCTIVE THERMOPLASTIC MATERIAL
US3994726A (en) * 1974-04-25 1976-11-30 Xerox Corporation Method of forming a resilient photoconductive element
US3999988A (en) * 1974-07-29 1976-12-28 Xerox Corporation Method for real-time color masking
US4002476A (en) * 1975-05-23 1977-01-11 Xerox Corporation Method of developing resilient photoconductive element
US4018603A (en) * 1975-04-24 1977-04-19 Xerox Corporation Deformation imaging system using thermoplastic and elastomeric layers
US4021236A (en) * 1975-04-24 1977-05-03 Xerox Corporation Imaging system
US4023969A (en) * 1975-01-03 1977-05-17 Xerox Corporation Deformable elastomer imaging member employing an internal opaque deformable metallic layer
FR2339195A1 (en) * 1976-01-21 1977-08-19 Xerox Corp METHOD AND DEVICE FOR SELECTIVE ERASING ON IMAGE RECORDING DEVICES
FR2339196A1 (en) * 1976-01-21 1977-08-19 Xerox Corp METHOD AND DEVICE FOR SELECTIVE PROJECTION OF POSITIVE OR NEGATIVE IMAGES FROM IMAGE RECORDING DEVICES
US4065308A (en) * 1975-04-24 1977-12-27 Xerox Corporation Deformation imaging element
US4076371A (en) * 1973-07-02 1978-02-28 Max-Planck-Gesellschaft Zur Forderung Der Wissenschaften E.V. Holographic recording material for infrared radiation
US4080897A (en) * 1977-01-07 1978-03-28 Xerox Corporation Selective tack imaging and printing
US4109316A (en) * 1976-01-21 1978-08-22 Xerox Corporation Method and apparatus for inverting the polarity of an input image formed on a surface of an image recording device
US4111538A (en) * 1976-02-25 1978-09-05 Xerox Corporation Projection system of high efficiency
US4163667A (en) * 1973-10-11 1979-08-07 Xerox Corporation Deformable imaging member used in electro-optic imaging system
US4174881A (en) * 1976-03-05 1979-11-20 Rca Corporation Recording a synthetic focused-image hologram on a thermally deformable plastic
US4242433A (en) * 1977-11-16 1980-12-30 Coulter Systems Corp. High speed electrophotographic medium
US4252400A (en) * 1978-08-09 1981-02-24 Honeywell Inc. Nondestructive dynamic controller for thermoplastic development
US4299450A (en) * 1978-08-18 1981-11-10 Sharp Kabushiki Kaisha Elastomer display
US4358677A (en) * 1980-05-22 1982-11-09 Siemens Corporation Transducer for fingerprints and apparatus for analyzing fingerprints
US4494826A (en) * 1979-12-31 1985-01-22 Smith James L Surface deformation image device
US4757472A (en) * 1986-12-31 1988-07-12 Tecon Memory, Inc. Electrophotographic optical memory system
US5291330A (en) * 1989-11-03 1994-03-01 Joseph Daniels Method and apparatus for enhancing image resolution by means of a multiplicity of phase objects and an optional external radiant flux
US5338653A (en) * 1993-02-22 1994-08-16 Ocg Microelectronic Materials, Inc. Phenolic novolak resin compositions containing 5-indanol and their use a process for forming positive resist patterns
US5900160A (en) * 1993-10-04 1999-05-04 President And Fellows Of Harvard College Methods of etching articles via microcontact printing
US6020047A (en) * 1996-09-04 2000-02-01 Kimberly-Clark Worldwide, Inc. Polymer films having a printed self-assembling monolayer
US6048623A (en) * 1996-12-18 2000-04-11 Kimberly-Clark Worldwide, Inc. Method of contact printing on gold coated films
US6180239B1 (en) 1993-10-04 2001-01-30 President And Fellows Of Harvard College Microcontact printing on surfaces and derivative articles
US6304364B1 (en) 1997-06-11 2001-10-16 President & Fellows Of Harvard College Elastomeric light valves
US6352337B1 (en) 2000-11-08 2002-03-05 Eastman Kodak Company Assisted drop-on-demand inkjet printer using deformable micro-acuator
US20020094572A1 (en) * 1993-10-04 2002-07-18 Rahul Singhvi Method of formation of microstamped patterns of plates for adhesion of cells and other biological materials, devices and uses therefor
US6428146B1 (en) 2000-11-08 2002-08-06 Eastman Kodak Company Fluid pump, ink jet print head utilizing the same, and method of pumping fluid
US6435840B1 (en) 2000-12-21 2002-08-20 Eastman Kodak Company Electrostrictive micro-pump
US6467605B1 (en) 1971-04-16 2002-10-22 Texas Instruments Incorporated Process of manufacturing
US6477029B1 (en) 2000-09-27 2002-11-05 Eastman Kodak Company Deformable micro-actuator
US6498711B1 (en) 2000-11-08 2002-12-24 Eastman Kodak Company Deformable micro-actuator with grid electrode
US20030107740A1 (en) * 2001-12-11 2003-06-12 Kaylor Rosann Marie Systems to view and analyze the results from diffraction-based diagnostics
US6626416B2 (en) 2000-12-12 2003-09-30 Eastman Kodak Company Electrostrictive valve for modulating a fluid flow
US6776094B1 (en) 1993-10-04 2004-08-17 President & Fellows Of Harvard College Kit For Microcontact Printing
US6858287B2 (en) * 2001-08-10 2005-02-22 Soliant Llc Formable bright film having discontinuous metallic layers
US7098041B2 (en) 2001-12-11 2006-08-29 Kimberly-Clark Worldwide, Inc. Methods to view and analyze the results from diffraction-based diagnostics
EP2322957A1 (en) 2009-11-12 2011-05-18 poLight AS A method, device and system for reducing speckle contrast
US9081190B2 (en) 2012-04-26 2015-07-14 Qualcomm Mems Technologies, Inc. Voltage controlled microlens sheet
CN107430162A (en) * 2015-03-23 2017-12-01 国立研究开发法人情报通信研究机构 Electric field imaging method

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4510208A (en) * 1983-07-01 1985-04-09 The Dow Chemical Company Duplex metal alloy/polymer compositions
DE102018133168B4 (en) 2018-12-20 2021-02-18 Papierfabrik August Koehler Se Thermosensitive recording material

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2896507A (en) * 1952-04-16 1959-07-28 Foerderung Forschung Gmbh Arrangement for amplifying the light intensity of an optically projected image
US3196011A (en) * 1962-05-08 1965-07-20 Xerox Corp Electrostatic frosting
US3196010A (en) * 1962-05-08 1965-07-20 Xerox Corp Electrophotographic process for formation of deformation images in deformable interference films
US3274565A (en) * 1961-05-01 1966-09-20 Rca Corp Optical-photoconductive reproducer utilizing insulative liquids
US3283309A (en) * 1962-08-20 1966-11-01 Gen Electric Information thermoplastic recording
US3436216A (en) * 1965-08-02 1969-04-01 Xerox Corp Image storage comprising a thermoplastic deformation pattern
US3441939A (en) * 1964-09-02 1969-04-29 Ibm Thermoplastic recording technique

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2896507A (en) * 1952-04-16 1959-07-28 Foerderung Forschung Gmbh Arrangement for amplifying the light intensity of an optically projected image
US3274565A (en) * 1961-05-01 1966-09-20 Rca Corp Optical-photoconductive reproducer utilizing insulative liquids
US3196011A (en) * 1962-05-08 1965-07-20 Xerox Corp Electrostatic frosting
US3196010A (en) * 1962-05-08 1965-07-20 Xerox Corp Electrophotographic process for formation of deformation images in deformable interference films
US3283309A (en) * 1962-08-20 1966-11-01 Gen Electric Information thermoplastic recording
US3441939A (en) * 1964-09-02 1969-04-29 Ibm Thermoplastic recording technique
US3436216A (en) * 1965-08-02 1969-04-01 Xerox Corp Image storage comprising a thermoplastic deformation pattern

Cited By (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3842406A (en) * 1970-12-28 1974-10-15 Xerox Corp Cyclic recording system by the use of an elastomer in an electric field
US6467605B1 (en) 1971-04-16 2002-10-22 Texas Instruments Incorporated Process of manufacturing
US3861914A (en) * 1973-01-15 1975-01-21 Rca Corp Permanent holographic recording medium
US4076371A (en) * 1973-07-02 1978-02-28 Max-Planck-Gesellschaft Zur Forderung Der Wissenschaften E.V. Holographic recording material for infrared radiation
US4163667A (en) * 1973-10-11 1979-08-07 Xerox Corporation Deformable imaging member used in electro-optic imaging system
US3973958A (en) * 1973-12-28 1976-08-10 Xerox Corporation Method including exposure of deformation imaging member through lenticular lens element
US3973957A (en) * 1973-12-28 1976-08-10 Xerox Corporation Imaging method including exposure of deformation imaging member through lenticular lens element
US3888591A (en) * 1974-01-21 1975-06-10 Xerox Corp Image subtraction apparatus
US3877791A (en) * 1974-02-20 1975-04-15 Rca Corp Deformable mirror light valve and method of making the same
US3994726A (en) * 1974-04-25 1976-11-30 Xerox Corporation Method of forming a resilient photoconductive element
US3999988A (en) * 1974-07-29 1976-12-28 Xerox Corporation Method for real-time color masking
US3951533A (en) * 1974-09-20 1976-04-20 Xerox Corporation Color image reproduction system
US3944358A (en) * 1974-09-20 1976-03-16 Xerox Corporation Color image reproduction system
US4023969A (en) * 1975-01-03 1977-05-17 Xerox Corporation Deformable elastomer imaging member employing an internal opaque deformable metallic layer
US3961950A (en) * 1975-01-10 1976-06-08 Xerox Corporation Imaging system
US3980476A (en) * 1975-01-27 1976-09-14 Xerox Corporation Imaging system
FR2304948A1 (en) * 1975-03-17 1976-10-15 Hoechst Ag PROCESS FOR RECORDING RELIEF IMAGES ON A PHOTOCONDUCTIVE THERMOPLASTIC MATERIAL
US4018603A (en) * 1975-04-24 1977-04-19 Xerox Corporation Deformation imaging system using thermoplastic and elastomeric layers
US4065308A (en) * 1975-04-24 1977-12-27 Xerox Corporation Deformation imaging element
US4021236A (en) * 1975-04-24 1977-05-03 Xerox Corporation Imaging system
US4002476A (en) * 1975-05-23 1977-01-11 Xerox Corporation Method of developing resilient photoconductive element
FR2339195A1 (en) * 1976-01-21 1977-08-19 Xerox Corp METHOD AND DEVICE FOR SELECTIVE ERASING ON IMAGE RECORDING DEVICES
FR2339196A1 (en) * 1976-01-21 1977-08-19 Xerox Corp METHOD AND DEVICE FOR SELECTIVE PROJECTION OF POSITIVE OR NEGATIVE IMAGES FROM IMAGE RECORDING DEVICES
US4109316A (en) * 1976-01-21 1978-08-22 Xerox Corporation Method and apparatus for inverting the polarity of an input image formed on a surface of an image recording device
US4111538A (en) * 1976-02-25 1978-09-05 Xerox Corporation Projection system of high efficiency
US4174881A (en) * 1976-03-05 1979-11-20 Rca Corporation Recording a synthetic focused-image hologram on a thermally deformable plastic
US4080897A (en) * 1977-01-07 1978-03-28 Xerox Corporation Selective tack imaging and printing
US4242433A (en) * 1977-11-16 1980-12-30 Coulter Systems Corp. High speed electrophotographic medium
US4252400A (en) * 1978-08-09 1981-02-24 Honeywell Inc. Nondestructive dynamic controller for thermoplastic development
US4299450A (en) * 1978-08-18 1981-11-10 Sharp Kabushiki Kaisha Elastomer display
US4494826A (en) * 1979-12-31 1985-01-22 Smith James L Surface deformation image device
US4358677A (en) * 1980-05-22 1982-11-09 Siemens Corporation Transducer for fingerprints and apparatus for analyzing fingerprints
US4757472A (en) * 1986-12-31 1988-07-12 Tecon Memory, Inc. Electrophotographic optical memory system
US5291330A (en) * 1989-11-03 1994-03-01 Joseph Daniels Method and apparatus for enhancing image resolution by means of a multiplicity of phase objects and an optional external radiant flux
US5338653A (en) * 1993-02-22 1994-08-16 Ocg Microelectronic Materials, Inc. Phenolic novolak resin compositions containing 5-indanol and their use a process for forming positive resist patterns
US6776094B1 (en) 1993-10-04 2004-08-17 President & Fellows Of Harvard College Kit For Microcontact Printing
US7067306B2 (en) 1993-10-04 2006-06-27 President & Fellows Of Harvard College Device containing cytophilic islands that adhere cells separated by cytophobic regions
US6180239B1 (en) 1993-10-04 2001-01-30 President And Fellows Of Harvard College Microcontact printing on surfaces and derivative articles
US7993905B2 (en) 1993-10-04 2011-08-09 President And Fellows Of Harvard College Device containing cytophilic islands that adhere cells separated by cytophobic regions
US20040159633A1 (en) * 1993-10-04 2004-08-19 President & Fellows Of Harvard University Methods of etching articles via micro contact printing
US20020094572A1 (en) * 1993-10-04 2002-07-18 Rahul Singhvi Method of formation of microstamped patterns of plates for adhesion of cells and other biological materials, devices and uses therefor
US7875197B2 (en) 1993-10-04 2011-01-25 President And Fellows Of Harvard College Methods of etching articles via microcontact printing
US5900160A (en) * 1993-10-04 1999-05-04 President And Fellows Of Harvard College Methods of etching articles via microcontact printing
US20090001049A1 (en) * 1993-10-04 2009-01-01 President And Fellows Of Harvard College Methods of etching articles via microcontact printing
US6020047A (en) * 1996-09-04 2000-02-01 Kimberly-Clark Worldwide, Inc. Polymer films having a printed self-assembling monolayer
US6048623A (en) * 1996-12-18 2000-04-11 Kimberly-Clark Worldwide, Inc. Method of contact printing on gold coated films
US6304364B1 (en) 1997-06-11 2001-10-16 President & Fellows Of Harvard College Elastomeric light valves
US6477029B1 (en) 2000-09-27 2002-11-05 Eastman Kodak Company Deformable micro-actuator
US6498711B1 (en) 2000-11-08 2002-12-24 Eastman Kodak Company Deformable micro-actuator with grid electrode
US6428146B1 (en) 2000-11-08 2002-08-06 Eastman Kodak Company Fluid pump, ink jet print head utilizing the same, and method of pumping fluid
US6352337B1 (en) 2000-11-08 2002-03-05 Eastman Kodak Company Assisted drop-on-demand inkjet printer using deformable micro-acuator
US6626416B2 (en) 2000-12-12 2003-09-30 Eastman Kodak Company Electrostrictive valve for modulating a fluid flow
US6435840B1 (en) 2000-12-21 2002-08-20 Eastman Kodak Company Electrostrictive micro-pump
US6858287B2 (en) * 2001-08-10 2005-02-22 Soliant Llc Formable bright film having discontinuous metallic layers
US20030107740A1 (en) * 2001-12-11 2003-06-12 Kaylor Rosann Marie Systems to view and analyze the results from diffraction-based diagnostics
US7102752B2 (en) 2001-12-11 2006-09-05 Kimberly-Clark Worldwide, Inc. Systems to view and analyze the results from diffraction-based diagnostics
US7098041B2 (en) 2001-12-11 2006-08-29 Kimberly-Clark Worldwide, Inc. Methods to view and analyze the results from diffraction-based diagnostics
EP2322957A1 (en) 2009-11-12 2011-05-18 poLight AS A method, device and system for reducing speckle contrast
US9081190B2 (en) 2012-04-26 2015-07-14 Qualcomm Mems Technologies, Inc. Voltage controlled microlens sheet
CN107430162A (en) * 2015-03-23 2017-12-01 国立研究开发法人情报通信研究机构 Electric field imaging method
EP3276361A4 (en) * 2015-03-23 2018-12-12 National Institute of Information and Communications Technology Electric field imaging method

Also Published As

Publication number Publication date
DE2164340A1 (en) 1972-07-27
DE2164340B2 (en) 1978-05-18
AU461213B2 (en) 1975-05-22
DE2164340C3 (en) 1979-01-25
AU3725271A (en) 1973-06-28
JPS532061B1 (en) 1978-01-25
AR196734A1 (en) 1974-02-19
FR2120174A1 (en) 1972-08-11
BE777320A (en) 1972-06-27
BR7107946D0 (en) 1973-06-07
CA953990A (en) 1974-09-03
IT944392B (en) 1973-04-20
AU6853674A (en) 1974-07-11
GB1380057A (en) 1975-01-08
NL7117812A (en) 1972-06-30
FR2120174B1 (en) 1974-09-27

Similar Documents

Publication Publication Date Title
US3716359A (en) Cyclic recording system by the use of an elastomer in an electric field
US3980476A (en) Imaging system
Pai et al. Physics of electrophotography
US5650247A (en) Preparation and reproduction of filters and preparation of filter photographic materials
US3542545A (en) Frost or relief wrinkling of an imaging article comprising an electrically photosensitive layer and a deformable layer
US2917385A (en) Reflex xerography
Sheridon The Ruticon family of erasable image recording devices
US3973958A (en) Method including exposure of deformation imaging member through lenticular lens element
US3752572A (en) Apparatus for making electrographs
US3719483A (en) Methods of organized thermoplastic xerography and photoreceptor structure therefor
US3653064A (en) Electrostatic image-forming apparatus and process
US3560205A (en) Method of forming a phase modulating hologram on a deformable thermoplastic
US3436216A (en) Image storage comprising a thermoplastic deformation pattern
US3519344A (en) Image projection
US4065308A (en) Deformation imaging element
US3083623A (en) Transferred image apparatus
US3853614A (en) Cyclic recording system by the use of an elastomer in an electric field
US3842406A (en) Cyclic recording system by the use of an elastomer in an electric field
US4298669A (en) Electrophotographic process and apparatus
US3764315A (en) Ambipolar electrophotographic plate
US3965461A (en) Thermoplastic image recording system
US3655257A (en) Apparatus for forming a phase hologram on a deformable thermoplastic
US3982936A (en) Deformation imaging system
US3687535A (en) Optical demodulation system
US4018603A (en) Deformation imaging system using thermoplastic and elastomeric layers