US3764796A - Chemical lighting device - Google Patents
Chemical lighting device Download PDFInfo
- Publication number
- US3764796A US3764796A US00295335A US3764796DA US3764796A US 3764796 A US3764796 A US 3764796A US 00295335 A US00295335 A US 00295335A US 3764796D A US3764796D A US 3764796DA US 3764796 A US3764796 A US 3764796A
- Authority
- US
- United States
- Prior art keywords
- ampoules
- chemiluminescent
- cylindrical sleeve
- ampoule
- frangible
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000126 substance Substances 0.000 title abstract description 10
- 239000003708 ampul Substances 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 20
- 239000012190 activator Substances 0.000 claims abstract description 10
- 239000012530 fluid Substances 0.000 claims description 8
- 239000011521 glass Substances 0.000 claims description 4
- 238000005452 bending Methods 0.000 abstract 1
- 210000003739 neck Anatomy 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- CBXRMKZFYQISIV-UHFFFAOYSA-N 1-n,1-n,1-n',1-n',2-n,2-n,2-n',2-n'-octamethylethene-1,1,2,2-tetramine Chemical group CN(C)C(N(C)C)=C(N(C)C)N(C)C CBXRMKZFYQISIV-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000003550 marker Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- MCJCREGWRMCHIM-UHFFFAOYSA-N bis(2-butoxycarbonyl-3,4,6-trichlorophenyl) oxalate Chemical compound CCCCOC(=O)C1=C(Cl)C(Cl)=CC(Cl)=C1OC(=O)C(=O)OC1=C(Cl)C=C(Cl)C(Cl)=C1C(=O)OCCCC MCJCREGWRMCHIM-UHFFFAOYSA-N 0.000 description 1
- TZZLVFUOAYMTHA-UHFFFAOYSA-N bis-(2,4,5-trichloro-6-(pentyloxycarbonyl)phenyl)oxalate Chemical compound CCCCCOC(=O)C1=C(Cl)C(Cl)=CC(Cl)=C1OC(=O)C(=O)OC1=C(Cl)C=C(Cl)C(Cl)=C1C(=O)OCCCCC TZZLVFUOAYMTHA-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 1
- 229960001826 dimethylphthalate Drugs 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000002654 heat shrinkable material Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000000422 nocturnal effect Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21K—NON-ELECTRIC LIGHT SOURCES USING LUMINESCENCE; LIGHT SOURCES USING ELECTROCHEMILUMINESCENCE; LIGHT SOURCES USING CHARGES OF COMBUSTIBLE MATERIAL; LIGHT SOURCES USING SEMICONDUCTOR DEVICES AS LIGHT-GENERATING ELEMENTS; LIGHT SOURCES NOT OTHERWISE PROVIDED FOR
- F21K2/00—Non-electric light sources using luminescence; Light sources using electrochemiluminescence
- F21K2/06—Non-electric light sources using luminescence; Light sources using electrochemiluminescence using chemiluminescence
Definitions
- the ampoules can be bro- 56] References Cited kin lay sensing the oiliterlcylindrical sleeve anld liglht is o tame w en t e c emi uminescent materia an ac- UNITED STATES PATENTS tivator are mixed 3,584,211 6/1971 Rauhut 240/225 3,539,794 3 Claims, 2 Drawing Figures ll/l970 Rauhut et al. 240/225 CHEMICAL LIGHTING DEVICE BACKGROUND OF THE INVENTION
- the present invention relates to a chemical lighting device and more particularly to a chemical lighting device which can be held in a hand and readily activated.
- chemiluminescent compounds are made by adding a fluorescer to an oxalate-ester compound and then activating the mixture with an oxidizing material.
- U. S. Pat. 3,612,857 entitled, Location Marker For Producing Luminous Display," which issued Oct. l2, 1971, to Dave Beatty and James Reinhart, describes a location marker which is a cloth streamer saturated with a mixture of bis(2,4,5 Trichloro-6-carbobutoxyphenyl) oxalate, anthracene cyanacryl terpolymer, and bis(2-ethylhexyl) phthalate in benzene.
- the activator fluid used to activate the chemiluminescent mixture is hydrogen peroxide in dimethyl phthalate.
- the present invention relates to a chemical lighting device which can be held in the hand and'which can be readily activated.
- An outer cylindrical sleeve of light transmitting material contains first and second ampoules which are kept separated in the cylindrical sleeve.
- One ampoule contains a chemiluminescent material and the second ampoule contains a activator fluid.
- Each ampoule is provided with a reduced neck portion which facilitates breaking the ampoule.
- the chemiluminescent material and activator fluid are mixed and light is obtained and transmitted through the cylindrical sleeve.
- the sealing of the chemiluminescent material in a glass ampoule prevents such deterioration and permits long shelf life.
- FIG. 1 is a longitudinal sectional view of a preferred embodiment of the present invention.
- FIG. 2 is a longitudinal sectional view of another. embodiment of the present invention.
- a tubular outer sleeve 11 having glass ampoules 12 and 13 positioned therein.
- Sleeve 11 is made of material which will transmit light such as clear radiation-crossedlinked polyolefinic plastic tube.
- the ends of sleeve 12 have been flattened by applying heat and pressure to form flat ends 14 and 15 that serve to retain ampoules l2 and 13 within sleeve 11.
- FIG. 1 of the drawing it can be seen that sleeve 11 is provided with a reduced diameter portion 16 which prevents ampoules l2 and 13 from moving together and be susceptible to breaking.
- Ampoule 12 is retained between flat end 14 and reduced diameter portion 16 and ampoule 13 is retained between flat end 15 and reduced diameter portion 16.
- sleeve 11 might be of a heat shrinkable material and reduced diameter portion 16 can be formed by applying heat to sleeve 11.
- two reduced diameter portions 17 and 18 are provided to retain ampoules 12 and 13 in position.
- the space 21 inside reduced diameter portion 16 and the space 22 between reduced diameter portions 17 and 18 serves as a mixing area when ampoules l2 and 13 are broken and the fluids therein are released.
- Ampoules 12 and 13 are provided with necks 23 that facilitate breaking the ampoules.
- Ampoule 12 contains a chemiluminescent material 7 which, by way of example, might be a mixture of an oxalate ester, such as bis(2,4,5-trichloro-6-carbopentoxyphenyl) oxalate, and a fluorescer, such as 9,10,- bis(phenylethynl) anthracene.
- Ampoule 13 contains an activator, such as hydrogen peroxide.
- sleeve 11 When it is desired to activate the chemical lighting system described herein, sleeve 11 is bent first in the region of the neck 23 of ampoule 12 to break ampoule 12 and then in the region of the neck of ampoule 13 to break ampoule 13. Mixing of the chemiluminescent material and the activator produces light that passes through sleeve 11.
- a chemiluminescent light device comprising,
- an outer cylindrical sleeve of light transmitting material having flat end portions and first and second reduced diameter portions between said flat end portions
- first and second frangible ampoules positioned in said outer cylindrical sleeve, one of said ampoules being positioned between one flat end portion and said first reduced diameter portion and the other of said ampoules being positioned between the other flat end portion and said second reduced diameter portion,
Abstract
A chemical lighting device having an outer cylindrical sleeve of light transmitting material and first and second frangible ampoules positioned within said outer cylindrical sleeve. Indentions are provided in the outer cylindrical sleeve for keeping the ampoules separated in the cylindrical sleeve. One ampoule contains a chemiluminescent material and the other ampoule contains an activator material. The ampoules can be broken by bending the outer cylindrical sleeve and light is obtained when the chemiluminescent material and activator are mixed.
Description
I United States Patent 1 [111 Gilliam et al. Oct. 9, 1973 [54] CHEMICAL LIGHTING DEVICE 3,068,154 12/1962 Majors 222/94 UX Inventors: Clarence w G l iam, Blo m g on, 3,397,819 8/1968 Hodge 222/94 X Ind.; Thomas N. Hall, Adelphi, Md.
Przmary Exammer-Fred L. Braun [73] Assignee: The United States of Americaas An0mey R, s S i i et 1 represented by the Secretary of the Navy, Washington, DC. [57] ABSTRACT [22] Ffled' Oct. 1972 A chemical lighting device having an outer cylindrical PP No.1 295,335 sleeve of light transmitting material and first and second frangible ampoules positioned within said outer [52] Cl H 240/225 222/94 222/541 cylindrical sleeve. lndentions are provided in the outer [51] Int. Cl. F21v 9/16 cylindrical sleeve for keeping the ampoules Separated 58 Field of Search 240/225; 222/94, in the cylindrical sleeveone ampwle a 222/541 miluminescent material and the other ampoule contains an activator material. The ampoules can be bro- 56] References Cited kin lay sensing the oiliterlcylindrical sleeve anld liglht is o tame w en t e c emi uminescent materia an ac- UNITED STATES PATENTS tivator are mixed 3,584,211 6/1971 Rauhut 240/225 3,539,794 3 Claims, 2 Drawing Figures ll/l970 Rauhut et al. 240/225 CHEMICAL LIGHTING DEVICE BACKGROUND OF THE INVENTION The present invention relates to a chemical lighting device and more particularly to a chemical lighting device which can be held in a hand and readily activated.
Various chemiluminescent peraminoethylene compounds have been used for lighting and marking purposes. One such use is described in U. S. Pat. 3,239,406, entitled, Chemiluminescent Structures And Their Preparation, which issued Mar. 8, 1966, to Donald D. Coffman and Hilmer E. Winberg. This patent teaches the coating of flexible material, such as plastic strips, with tetrakis (dimethylamino) ethylene to provide a nocturnal marking tape. As tetrakis (dimethylamino) ethylene becomes luminescent upon exposure to air, the preparation of the tape is made under nitrogen and the saturated material is protected from air by covering with polyethylene film.
Another group of chemiluminescent compounds are made by adding a fluorescer to an oxalate-ester compound and then activating the mixture with an oxidizing material. U. S. Pat. 3,612,857, entitled, Location Marker For Producing Luminous Display," which issued Oct. l2, 1971, to Dave Beatty and James Reinhart, describes a location marker which is a cloth streamer saturated with a mixture of bis(2,4,5 Trichloro-6-carbobutoxyphenyl) oxalate, anthracene cyanacryl terpolymer, and bis(2-ethylhexyl) phthalate in benzene. The activator fluid used to activate the chemiluminescent mixture is hydrogen peroxide in dimethyl phthalate.
SUMMARY OF THE INVENTION The present invention relates to a chemical lighting device which can be held in the hand and'which can be readily activated. An outer cylindrical sleeve of light transmitting material contains first and second ampoules which are kept separated in the cylindrical sleeve. One ampoule contains a chemiluminescent material and the second ampoule contains a activator fluid. Each ampoule is provided with a reduced neck portion which facilitates breaking the ampoule. When both ampoules are broken, the chemiluminescent material and activator fluid are mixed and light is obtained and transmitted through the cylindrical sleeve. As chemiluminescent material deterioates when even very small amounts of moisture are present, the sealing of the chemiluminescent material in a glass ampoule prevents such deterioration and permits long shelf life.
It is therefore a general object of the present invention to provide a chemical lighting device which can be readily activated.
BRIEF DESCRIPTION OF THE DRAWING FIG. 1 is a longitudinal sectional view of a preferred embodiment of the present invention; and
FIG. 2 is a longitudinal sectional view of another. embodiment of the present invention.
DESCRIPTION OF THE PREFERRED EMBODIMENTS Referring now to the drawing, there is shown a tubular outer sleeve 11 having glass ampoules 12 and 13 positioned therein. Sleeve 11 is made of material which will transmit light such as clear radiation-crossedlinked polyolefinic plastic tube. The ends of sleeve 12 have been flattened by applying heat and pressure to form flat ends 14 and 15 that serve to retain ampoules l2 and 13 within sleeve 11. Referring now to FIG. 1 of the drawing, it can be seen that sleeve 11 is provided with a reduced diameter portion 16 which prevents ampoules l2 and 13 from moving together and be susceptible to breaking. Ampoule 12 is retained between flat end 14 and reduced diameter portion 16 and ampoule 13 is retained between flat end 15 and reduced diameter portion 16. By way of example, sleeve 11 might be of a heat shrinkable material and reduced diameter portion 16 can be formed by applying heat to sleeve 11. In FIG. 2 of the drawing, two reduced diameter portions 17 and 18 are provided to retain ampoules 12 and 13 in position. The space 21 inside reduced diameter portion 16 and the space 22 between reduced diameter portions 17 and 18 serves as a mixing area when ampoules l2 and 13 are broken and the fluids therein are released. Ampoules 12 and 13 are provided with necks 23 that facilitate breaking the ampoules.
When it is desired to activate the chemical lighting system described herein, sleeve 11 is bent first in the region of the neck 23 of ampoule 12 to break ampoule 12 and then in the region of the neck of ampoule 13 to break ampoule 13. Mixing of the chemiluminescent material and the activator produces light that passes through sleeve 11.
We claim:
1. A chemiluminescent light device comprising,
an outer cylindrical sleeve of light transmitting material having flat end portions and first and second reduced diameter portions between said flat end portions,
first and second frangible ampoules positioned in said outer cylindrical sleeve, one of said ampoules being positioned between one flat end portion and said first reduced diameter portion and the other of said ampoules being positioned between the other flat end portion and said second reduced diameter portion,
a chemiluminescent fluid in said one frangible ampoule, and
activator fluid in said other frangible ampoule. v
2.' A chemiluminescent light device as set forth in claim 1 wherein said'frangible ampoules are glass.
3. A chemiluminescent light device as set forth in claim 1 wherein said frangible ampoules have a neck portion to facilitate breakage.
a a n 1:
Claims (3)
1. A chemiluminescent light device comprising, an outer cylindrical sleeve of light transmitting material having flat end portions and first and second reduced diameter portions between said flat end portions, first and second frangible ampoules positioned in said outer cylindrical sleeve, one of said ampoules being positioned between one flat end portion and said first reduced diameter portion and the other of said ampoules being positioned between the other flat end portion and said second reduced diameter portion, a chemiluminescent fluid in said one frangible ampoule, and activator fluid in said other frangible ampoule.
2. A chemiluminescent light device as set forth in claim 1 wherein said frangible ampoules are glass.
3. A chemiluminescent light device as set forth in claim 1 wherein said frangible ampoules have a neck portion to facilitate breakage.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US29533572A | 1972-10-05 | 1972-10-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3764796A true US3764796A (en) | 1973-10-09 |
Family
ID=23137253
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US00295335A Expired - Lifetime US3764796A (en) | 1972-10-05 | 1972-10-05 | Chemical lighting device |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US3764796A (en) |
Cited By (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3813534A (en) * | 1973-09-14 | 1974-05-28 | Us Navy | Chemical lighting device having interlocking ampoules |
| US3819925A (en) * | 1973-03-12 | 1974-06-25 | Us Navy | Chemiluminescent device |
| DE2461617A1 (en) * | 1973-12-27 | 1975-07-10 | Oreal | PRESSURELESS CONTAINER TO STORE SEPARATELY AND DISPOSE OF AT LEAST TWO MEDIA AT THE SAME TIME |
| US3934539A (en) * | 1974-03-26 | 1976-01-27 | The United States Of America As Represented By The Secretary Of The Navy | Chemiluminescent foldable signal device |
| DE2853411A1 (en) * | 1977-12-19 | 1979-08-23 | American Cyanamid Co | CHEMICAL LIGHT STICK |
| US4265280A (en) * | 1979-01-23 | 1981-05-05 | Baxter Travenol Laboratories, Inc. | Connector member for sealed conduits |
| US4299185A (en) * | 1979-11-21 | 1981-11-10 | American Cyanamid Company | Device for warning of impending roof-fall in underground excavations |
| US5018450A (en) * | 1990-04-25 | 1991-05-28 | Smith Henry J | Luminescent paintball for marking nighttime impacts |
| US5043851A (en) * | 1990-09-13 | 1991-08-27 | Omniglow Corporation | Polygonal chemiluminescent lighting device |
| US5222797A (en) * | 1991-10-31 | 1993-06-29 | Lexington & Associates | Multi-chamber chemiluminescent optical display device |
| US5508893A (en) * | 1994-02-08 | 1996-04-16 | Rhode Island Novelty Company, Inc. | Multi-color chemiluminescent lighting device and method of making same |
| US5595223A (en) * | 1994-10-21 | 1997-01-21 | Mitsubishi Pencil Corporation Of America | Ink refilling assembly |
| US5699936A (en) * | 1995-09-08 | 1997-12-23 | Sercomp Corporation | Liquid dispensing system |
| US6299441B1 (en) | 2000-07-05 | 2001-10-09 | Unique Industries, Inc. | Chemiluminescent mouthpiece |
| US20030168072A1 (en) * | 2002-03-06 | 2003-09-11 | Valdez Michael Dean | Hair holding device adapted for a removeably mounted chemical light stick |
| US6619211B1 (en) * | 1999-06-02 | 2003-09-16 | Nico-Pyrotechnik Hanns-Juergen Diederichs Gmbh & Co. Kg | Practice ammunition |
| US6685331B1 (en) | 1999-11-12 | 2004-02-03 | Edward T. Rockwell | Chemiluminescent device |
| US20040027227A1 (en) * | 2002-08-12 | 2004-02-12 | Byung Cheon Lee | Apparatus diagnosing a breaking of a fuse for a vehicle |
| US6758572B2 (en) | 2000-03-01 | 2004-07-06 | Omniglow Corporation | Chemiluminescent lighting element |
| US6802277B1 (en) | 2002-04-11 | 2004-10-12 | Durell Clay | Fire escape light and alarm |
| US20050123339A1 (en) * | 2003-12-05 | 2005-06-09 | Tawei Tsao | Enclosed opening means |
| US20050155269A1 (en) * | 2003-12-19 | 2005-07-21 | Heraeus Kulzer Gmbh | Multi-component cartridge and its application |
| WO2005065966A1 (en) * | 2003-12-05 | 2005-07-21 | Garry Tsaur | Enclosed opening means |
| US20060067783A1 (en) * | 2004-09-25 | 2006-03-30 | Garry Tsaur | Dual chamber applicator |
| US20060240739A1 (en) * | 2005-04-21 | 2006-10-26 | Matthew Kennedy | Illuminable noisemaker and associated methods |
| US20070079722A1 (en) * | 2003-10-21 | 2007-04-12 | The Sepron Company, L.C. | Chemiluminescent paint projectiles and method and preparation |
| US20120230009A1 (en) * | 2011-03-09 | 2012-09-13 | Omiglow, Llc | Multi-color chemiluminescent device with blended color effect |
| WO2013030270A1 (en) * | 2011-08-31 | 2013-03-07 | Sika Technology Ag | Stick applicator |
| US10220194B2 (en) | 2012-11-28 | 2019-03-05 | Advanced Resin Therapeutics, Inc. | Dual chamber applicator |
| CN109469254A (en) * | 2018-11-15 | 2019-03-15 | 重庆成维轻质墙板有限公司 | A kind of antidetonation ceramsite concrete light-weight wall boards |
| US11148142B2 (en) | 2019-06-23 | 2021-10-19 | Nano 2.0 Business Press, Llc | System and method for visual verification of secure closure of collection bottle through chemiluminescence |
| US11399914B2 (en) | 2017-08-09 | 2022-08-02 | Alcon Inc. | Self-illuminating microsurgical cannula device |
| US11844725B2 (en) | 2019-10-16 | 2023-12-19 | Alcon Inc. | Visually traceable vitrectomy probe cap |
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| US3068154A (en) * | 1959-11-04 | 1962-12-11 | Hill Top Res Inst Inc | Apparatus for preparing a fresh culture of microorganisms |
| US3397819A (en) * | 1967-07-19 | 1968-08-20 | Hughes Aircraft Co | Gas replenishment device |
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| US3584211A (en) * | 1968-10-07 | 1971-06-08 | American Cyanamid Co | Chemiluminescent liquid dispensing or display container |
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- 1972-10-05 US US00295335A patent/US3764796A/en not_active Expired - Lifetime
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| US3068154A (en) * | 1959-11-04 | 1962-12-11 | Hill Top Res Inst Inc | Apparatus for preparing a fresh culture of microorganisms |
| US3397819A (en) * | 1967-07-19 | 1968-08-20 | Hughes Aircraft Co | Gas replenishment device |
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| US3584211A (en) * | 1968-10-07 | 1971-06-08 | American Cyanamid Co | Chemiluminescent liquid dispensing or display container |
Cited By (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3819925A (en) * | 1973-03-12 | 1974-06-25 | Us Navy | Chemiluminescent device |
| US3813534A (en) * | 1973-09-14 | 1974-05-28 | Us Navy | Chemical lighting device having interlocking ampoules |
| DE2461617A1 (en) * | 1973-12-27 | 1975-07-10 | Oreal | PRESSURELESS CONTAINER TO STORE SEPARATELY AND DISPOSE OF AT LEAST TWO MEDIA AT THE SAME TIME |
| US3934539A (en) * | 1974-03-26 | 1976-01-27 | The United States Of America As Represented By The Secretary Of The Navy | Chemiluminescent foldable signal device |
| DE2853411A1 (en) * | 1977-12-19 | 1979-08-23 | American Cyanamid Co | CHEMICAL LIGHT STICK |
| US4340097A (en) * | 1979-01-23 | 1982-07-20 | Baxter Travenol Laboratories, Inc. | Connector member for sealed conduits |
| US4265280A (en) * | 1979-01-23 | 1981-05-05 | Baxter Travenol Laboratories, Inc. | Connector member for sealed conduits |
| US4299185A (en) * | 1979-11-21 | 1981-11-10 | American Cyanamid Company | Device for warning of impending roof-fall in underground excavations |
| US5018450A (en) * | 1990-04-25 | 1991-05-28 | Smith Henry J | Luminescent paintball for marking nighttime impacts |
| US5043851A (en) * | 1990-09-13 | 1991-08-27 | Omniglow Corporation | Polygonal chemiluminescent lighting device |
| US5222797A (en) * | 1991-10-31 | 1993-06-29 | Lexington & Associates | Multi-chamber chemiluminescent optical display device |
| US5508893A (en) * | 1994-02-08 | 1996-04-16 | Rhode Island Novelty Company, Inc. | Multi-color chemiluminescent lighting device and method of making same |
| US5595223A (en) * | 1994-10-21 | 1997-01-21 | Mitsubishi Pencil Corporation Of America | Ink refilling assembly |
| US5699936A (en) * | 1995-09-08 | 1997-12-23 | Sercomp Corporation | Liquid dispensing system |
| USRE40482E1 (en) * | 1999-06-02 | 2008-09-09 | Nico-Pyrotechnik Hanns-Juergen Diederichs Gmbh & Co. Kg | Practice ammunition |
| US6619211B1 (en) * | 1999-06-02 | 2003-09-16 | Nico-Pyrotechnik Hanns-Juergen Diederichs Gmbh & Co. Kg | Practice ammunition |
| US6685331B1 (en) | 1999-11-12 | 2004-02-03 | Edward T. Rockwell | Chemiluminescent device |
| US6758572B2 (en) | 2000-03-01 | 2004-07-06 | Omniglow Corporation | Chemiluminescent lighting element |
| US6299441B1 (en) | 2000-07-05 | 2001-10-09 | Unique Industries, Inc. | Chemiluminescent mouthpiece |
| US20030168072A1 (en) * | 2002-03-06 | 2003-09-11 | Valdez Michael Dean | Hair holding device adapted for a removeably mounted chemical light stick |
| US6802277B1 (en) | 2002-04-11 | 2004-10-12 | Durell Clay | Fire escape light and alarm |
| US20040027227A1 (en) * | 2002-08-12 | 2004-02-12 | Byung Cheon Lee | Apparatus diagnosing a breaking of a fuse for a vehicle |
| US6836206B2 (en) * | 2002-08-12 | 2004-12-28 | Hyundai Motor Company | Apparatus diagnosing a breaking of a fuse for a vehicle |
| US20070079722A1 (en) * | 2003-10-21 | 2007-04-12 | The Sepron Company, L.C. | Chemiluminescent paint projectiles and method and preparation |
| US7198421B2 (en) * | 2003-12-05 | 2007-04-03 | Garry Tsaur | Enclosed opening means |
| JP2007524493A (en) * | 2003-12-05 | 2007-08-30 | ゲィリー ツァワー | Enclosed breakthrough means |
| CN100567027C (en) * | 2003-12-05 | 2009-12-09 | 曹荣华 | The hermetic type shedding motion |
| WO2005065966A1 (en) * | 2003-12-05 | 2005-07-21 | Garry Tsaur | Enclosed opening means |
| US20050123339A1 (en) * | 2003-12-05 | 2005-06-09 | Tawei Tsao | Enclosed opening means |
| US20050155269A1 (en) * | 2003-12-19 | 2005-07-21 | Heraeus Kulzer Gmbh | Multi-component cartridge and its application |
| US20060067783A1 (en) * | 2004-09-25 | 2006-03-30 | Garry Tsaur | Dual chamber applicator |
| US20060240739A1 (en) * | 2005-04-21 | 2006-10-26 | Matthew Kennedy | Illuminable noisemaker and associated methods |
| US20120230009A1 (en) * | 2011-03-09 | 2012-09-13 | Omiglow, Llc | Multi-color chemiluminescent device with blended color effect |
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