US3796652A - Thermal dehydration of bitumen froth - Google Patents
Thermal dehydration of bitumen froth Download PDFInfo
- Publication number
- US3796652A US3796652A US00323454A US3796652DA US3796652A US 3796652 A US3796652 A US 3796652A US 00323454 A US00323454 A US 00323454A US 3796652D A US3796652D A US 3796652DA US 3796652 A US3796652 A US 3796652A
- Authority
- US
- United States
- Prior art keywords
- bitumen
- water
- froth
- mixer
- product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000010426 asphalt Substances 0.000 title abstract description 61
- 230000018044 dehydration Effects 0.000 title description 4
- 238000006297 dehydration reaction Methods 0.000 title description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 42
- 239000000203 mixture Substances 0.000 abstract description 9
- XLYOFNOQVPJJNP-PWCQTSIFSA-N Tritiated water Chemical compound [3H]O[3H] XLYOFNOQVPJJNP-PWCQTSIFSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 description 20
- 238000010438 heat treatment Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 239000002002 slurry Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 5
- 239000011275 tar sand Substances 0.000 description 5
- 239000004576 sand Substances 0.000 description 4
- 238000009834 vaporization Methods 0.000 description 3
- 230000008016 vaporization Effects 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
- C10C3/00—Working-up pitch, asphalt, bitumen
- C10C3/007—Working-up pitch, asphalt, bitumen winning and separation of asphalt from mixtures with aggregates, fillers and other products, e.g. winning from natural asphalt and regeneration of waste asphalt
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/04—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by extraction
- C10G1/047—Hot water or cold water extraction processes
Definitions
- This invention relates to a process for thermally dehydrating bitumen froth. It finds application as one of the operations in the combination of operations by which bitumen is extracted from tar sand.
- tar sand A large proportion of the worlds known hydrocarbon reserves exists in the form of tar sand. One large deposit of this material is found along the banks of the Athabasca River in Alberta.
- the tar sand comprises water-Wet grains of sand sheathed in films of bitumen. In treating the tar sand to recover commercially saleable products, it is first necessary to separate the bitumen from the water and sand.
- the extraction method commonly applied is known as the hot water method.
- this method involves contacting the tar sand in a tumbler with hot water and steam.
- the Water is supplied at a temperature of about 180 F. and in a amount suflicient to produce a slurry containing about 20 to 25% by weight water.
- the steam is supplied in an amount sufficient to ensure that the slurry temperature is about 180 F.
- the bitumen films are ruptured and a preliminary separation of the sand grains and bitumen flecks takes place.
- air bubbles are entrained in the slurry.
- More hot water is added to the slurry after it leaves the tumbler--typical1y this might raise the slurry water content to about 50%.
- the diluted slurry is then introduced into a separator cell containing a body of hot water.
- the contents of the cell are commonly maintained at about 180 F.
- the bitumen particles which have become attached to air bubbles, tend to rise to the surface of the water body and form an oily primary froth. This froth is recovered in a launder running around the rim of the cell.
- the coarse sand particles tend to sink to the bottom of the cell and are drawn oif as tailings.
- a middlings stream comprising water, fine solids (minus 325 mesh) and some bitumen, is continuously withdrawn from the cell at a point intermediate its ends.
- This middlings stream is treated in a sub-aerated flotation cell to recover the contained bitumen in the form of secondary froth.
- the primary and secondary froths are combined and transferred into a holding tank to remove some of the contained solids and water by gravity settling.
- the present invention is concerned with that type of thermal dehydration process wherein the bitumen froth is heated, to vaporize contained water, and is then flashed to separate the water vapor from the bitumen.
- the process has been developed with the objects of (l) avoiding the use of heat exchangers; (2) minimizing foaming and keeping it within predictable limits; and (3) keeping equipment costs low.
- dry bitumen is used as the vehicle for heating the froth.
- the bitumen is preheated to at least 300 F., preferably to a temperature in the range 600-700 F. It is mixed with the froth in a co-current flow mixer.
- the bitumen temperature, the amount of bitumen used, and the mixer residence time are selected having regard to the requirement that the desired amount of vaporization must be completed within the mixer.
- the mixer product is flashed in a flash zone of sufiicient volume and reduced pressure to produce water 'as overhead product and dry or substantially dry bitumen as the bottom product. Pa-rt of this bottom product may be recycled to the pre-heating step mentioned above.
- the mixer itself may be a downflow vessel having staggered, vertically spaced plates which blank off the vessel cross section to restrict the flow area to about 20%.
- the mixer may be of the cyclone type, as was used in the example following hereinbelow.
- the process is operated so that substantially all Water vaporization is carried out in the mixer. This is achieved by maintaining the temperature (Tm) of the mixer product stream about the same as the temperature (Tf) of the flash vessel bitumen stream. Preferably the temperature difference is maintained at less than 10 F.
- Tm temperature of the mixer product stream
- Tf temperature of the flash vessel bitumen stream
- Tm temperature of the mixer product stream
- Tf temperature of the flash vessel bitumen stream
- the process is characterized by several advantages.
- the capital cost of the mixer and flash vessel is less than that of the equipment used in prior art processes.
- the bitumen product contains only a small amount of water and this content is reasonably consistent over a prolonged period of operation.
- the invention comprises a thermal dehydration process for treating bitumen froth containing water, which process comprises: (a) heating substantially dry bitumen to a temperature greater than 300 F.; (b) mixing bitumen froth with a sufficient amount of the hot, dry bitumen of step (a) for a sufficiently long period of time to vaporize a predetermined amount of the water contained in the froth; and (c) flashing the product mixture to separate substantially all the vaporized water from the bitumen.
- FIG. 1 is a flow diagram illustrating the steps of the process.
- the mixer 1 comprised a series of six cyclone mixers. within the range 600 F. to 700 F.;
- Each cyclone had a cylindrical top section, provided with (b) co-currently mixing bitumen froth with a sufficient a tangential inlet, and a conical bottom section.
- the top 5 amount of the hot, dry bitumen of step (a) for a section had a diameter of 4 inches and length of 6 inches. sufficiently long period of time to vaporize substan- The bottom section reduced over a length of 4 inches to tially all of the Water Contained in the froth;
Abstract
Description
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US32345473A | 1973-01-15 | 1973-01-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3796652A true US3796652A (en) | 1974-03-12 |
Family
ID=23259269
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00323454A Expired - Lifetime US3796652A (en) | 1973-01-15 | 1973-01-15 | Thermal dehydration of bitumen froth |
Country Status (2)
Country | Link |
---|---|
US (1) | US3796652A (en) |
CA (1) | CA1010389A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4514305A (en) * | 1982-12-01 | 1985-04-30 | Petro-Canada Exploration, Inc. | Azeotropic dehydration process for treating bituminous froth |
US6372123B1 (en) * | 2000-06-26 | 2002-04-16 | Colt Engineering Corporation | Method of removing water and contaminants from crude oil containing same |
US6787027B1 (en) * | 1999-07-26 | 2004-09-07 | Shell Oil Company | Breaking of oil/water emulsion |
US6849175B2 (en) * | 2000-06-27 | 2005-02-01 | Colt Engineering Corporation | Method of removing water and contaminants from crude oil containing same |
-
1973
- 1973-01-15 US US00323454A patent/US3796652A/en not_active Expired - Lifetime
- 1973-11-16 CA CA186,026A patent/CA1010389A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4514305A (en) * | 1982-12-01 | 1985-04-30 | Petro-Canada Exploration, Inc. | Azeotropic dehydration process for treating bituminous froth |
US6787027B1 (en) * | 1999-07-26 | 2004-09-07 | Shell Oil Company | Breaking of oil/water emulsion |
US6372123B1 (en) * | 2000-06-26 | 2002-04-16 | Colt Engineering Corporation | Method of removing water and contaminants from crude oil containing same |
US6849175B2 (en) * | 2000-06-27 | 2005-02-01 | Colt Engineering Corporation | Method of removing water and contaminants from crude oil containing same |
Also Published As
Publication number | Publication date |
---|---|
CA1010389A (en) | 1977-05-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: GULF CANADA LIMITED Free format text: CHANGE OF NAME;ASSIGNOR:GULF OIL CANADA LIMITED;REEL/FRAME:003962/0723 Effective date: 19780508 |
|
AS | Assignment |
Owner name: PETRO-CANADA EXPLORATION, INC., STATELESS Free format text: CHANGE OF NAME;ASSIGNOR:ATLANTIC RICHFIELD CANADA LTD.;REEL/FRAME:004063/0175 Effective date: 19821103 Owner name: PETRO-CANADA EXPLORATION, INC. Free format text: CHANGE OF NAME;ASSIGNOR:ATLANTIC RICHFIELD CANADA LTD.;REEL/FRAME:004063/0175 Effective date: 19821103 |