US3824052A - Apparatus to produce nonwoven fabric - Google Patents

Apparatus to produce nonwoven fabric Download PDF

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US3824052A
US3824052A US00423332A US42333273A US3824052A US 3824052 A US3824052 A US 3824052A US 00423332 A US00423332 A US 00423332A US 42333273 A US42333273 A US 42333273A US 3824052 A US3824052 A US 3824052A
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nozzle
air
stream
fibers
air nozzle
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J Fowler
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Milliken Research Corp
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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/56Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving in association with fibre formation, e.g. immediately following extrusion of staple fibres
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D4/00Spinnerette packs; Cleaning thereof
    • D01D4/02Spinnerettes
    • D01D4/025Melt-blowing or solution-blowing dies

Definitions

  • fiber forming polymeric material is extruded from a suitable extrusion orifice or die and subjected, while in liquid moldable form, to the action of a pressurized stream of gas which attenuates the polymeric stream and breaks it generally traversely to form a plurality of discrete particles or fibers. Since the physical characteristics of the fibers produced de-' pend greatly upon the velocity and particular position of the pressurized gas stream relative to the moving flow of polymeric material, it has been quite difficult to control the size and uniformity of the fibrous particles produced due to the inherent wandering, erratic movement of the polymeric flow stream under influence of the pressurized attenuating gas.
  • lt is therefore an object of the present invention to provide an improved process and apparatus for producing fibrous particles for use in the formation-of nonwoven products by contacting a liquid flow of fiber formin g material with a pressurized fluid stream to attenuate the same while accurately controlling the position of the flow of fiber forming material relative to the pressurized fluid stream to control the physical characteristics of the fibrous particles produced.
  • FIG. 1 is a schematic representation of the new and improved process and apparatus
  • FIG. 2 is a cross-section view through the extruder head and air nozzle apparatus
  • FIG. 3 is a top view of the air nozzle
  • FIG. 4 is a top view of the air nozzle traverse linkage.
  • the invention is directed to shattering of a liquid stream which has a high di-electric constant and good electrical conductivity in the molten state.
  • a liquid stream with a di-electric constant above 20 is one which has a high di-electric constant.
  • a fiber forming polymeric material such as nylon 6 or nylon 6-6 is employed to form the shattered fibers and consequentially a nonwoven fabric.
  • a polymer such as nylon 6 is supplied in suitable form, such as pellets or discrete particles, into the hopper 10 of a conventional extruder 12.
  • the polymer is brought to the molten state and extruded downwardly under pressure in a substantially vertical direction through a single orifice spinnerette 14.
  • Located adjacent the downward path of flow of the extruded polymer 16 is a plurality of air nozzles 18 supplied with air under pressure from an air manifold 20 through a non-conductive air hose22.
  • the number of air nozzles 18 and spinnerettes 14 is dependent upon the width of nonwoven material to be'made.
  • the air nozzles 18 are of a highly conductive material such as copper and are connected to a high voltage d.c. source through the cable 24 to provide the air nozzles 18 with a high electrical potential.
  • a non-conductive air nozzle support 26 is provided to electrically isolate the charged air nozzles 18 from the support 25 .
  • the high velocity air from the air nozzles 18 will shatter thepolymer stream 16 into individual fibers and blow these individual fibers onto the continuously driven endless collection belt 28.
  • the high electrical potential of the air nozzles 18 initially attracts the highly conductive polymer toward the nozzle and tends to maintain the stream a predetermined horizontal distance from the air nozzle opening 30 which aids in controlling the effective use of the air velocity to control the length and diameter of the shattered fibers. Also, since the electrical potential of the air nozzles 18 is high enough to create a corona discharge, the polymer' stream and shattered fibers adjacent the nozzle rapidly take a charge which causes the fibers to repel one another as they travel to and impinge on the collection belt 28. The nonwoven web formedon the collection belt 28 is automatically employed is dependent on the width of the nonwoven web material desired.
  • two air nozzles 18 are shown and are mounted so that they can pivot back and forth to cover a certain preselected width of the conveyor belt 28 with shattered fibers.
  • the air nozzle 18 will pivot about a ro-' tary path so that the horizontal distance between the end of the air nozzle and the polymer stream remains constant to maintain uniformity of the fibers being made and as much as possible the uniformity of the nonwoven web being made from such fibers.
  • the T-shaped member 31 is rigidly secured to a suitable frame support (not shown) andsupports a cross-bar 32 mounted on an upstanding portion 34 of the member 31.
  • Pivotally connected to the crossbar 32 at 36 and 38 are lever arms 40 and 42 which are pivotally connected to the long arms 44 and 46 of the parallelogram linkage at 48 and 50.
  • Also pivotally connected to the ends of the arms 44 and 46 at 47 and 49 are the short arms 52 and 54'of the parallelogram linkage which are integral with the air nozzle support plates 56 and 58.
  • Mounted to the upstanding portion 34 of the T-shaped member 31 is a pair of pulleys 60.
  • each pivot point 49 Connected to each pivot point 49 is a wire or chain 62 wrapped around one of the pulleys 60 and then directed 'to a source of drive (not shown) which alternately pulls on one of the wires or chains 62 to cause the arms 44, 46, 52 and 54 to pivot about their pivot points to move the air nozzles 18 in an arc around the polymer scream 16 to blow shattered fibers across a predetermined width of the collection belt 28.
  • the air nozzle opening 30 is rectangular shaped to provide the most efficient use of the air on the polymer stream 16.
  • a rectangular shaped nozzle opening 30 it is preferred to have a rectangular shaped nozzle opening 30. It is found that this shape of nozzle in conjunction with the proper air pressure provides the mostconsistent and efficient breaking of the fibers from the polymer stream.
  • the selected air pressure normally will be one that will provide super sonic air velocities at the nozzle opening 30.
  • the proper air velocity or as normally expressed, the mass flow rate, in conjunction with the viscosity of the polymer stream 16 is important in controlling the diameter of the fibers being produced. Normally, as the air pressure is lowered, the diameter of the fiber being produced, increases. It is preferred to provide smaller diameter fibers since the nonwoven web produced therefrom tends to be stronger, have better cover and much better cohesion between the fibers.
  • Nylon 6 polymer manufactured by Allied Chemical Company is processed through an extruder in a normal manner and expelled at a rate of 3.8 pounds per hour through a spinnerette consisting of a single 0.040 inch diameter orifice.
  • the fluid nozzle used is this example consists of a copper tube fitted with a throat section of 0.065 inch diameter, and a general configuration of an elliptical hyperboloid.
  • the expanding gases are at least sonic at the nozzle exit.
  • This particular nozzle had a flow rate of 6.6 scfm when operating at a pressure of 60 psig.
  • Placement of the fluid nozzle exit was 1 /2 inches below the spinnerette orifice and approximately onequarter inch away from and generally perpendicular to the molten polymer stream.
  • Apparatus to produce a nonwoven sheet of material comprising an extruder providing a flow of molten liquid, an air nozzle supported below and substantially perpendicular to the flow of molten liquid from said extruder, a high voltage potential means operably associated with said air nozzle to maintain substantially constant the horizontal distance between said air nozzle and the path of flow of molten liquid from said extruder, means supplying air under pressure to said air nozzle and means operably associated with said air nozzle to collect fibers formed by the action of air from said air nozzle on a stream of molten liquid from said extruder.
  • porting said air nozzle includes a means to rotate said 4.

Abstract

Process and apparatus to produce nonwoven fabric from a stream of liquid material having a high di-electric constant. The stream of liquid material is delivered past an air nozzle having a high electrical potential which attracts the liquid stream and shatters it into fine fibrous particles.

Description

United States Patent Fowler July 16, 1974 APPARATUS T0 PRODUCE NONWOVEN 2,336,745 12/1943 Manning 425/81 x FABRIC 2,382,290 8/1945 Callander 425/81 X 2,466,906 4/1949 Miller 264/24 Inventor: James E. Fowler, Spartanburg, 8.0 3,020,585 2/1962 Berthon et a1... 65/4 3,158,668 11/1964 Johnson 425/83 X [73] Ass'gnee' g M Research 3,276,928 /1966 Pearson et a1, 425/83 x Spartanburg, 5- 3,338,992 8/1967 Kinney 264/24 22 Filed; 0 1973 3,442,633 5/1969 Perry 425/80 X 3,461,943 8/1969 Schile 264/24 X [21] Appl. No.: 423,332
Related U.S. Application D t Primary Examiner-Robert L. Spicer, Jr. Continuation of Ser. No. 134,131, April 15, 1971, Agent l Armltage;
abandoned, which is a division of Ser. No, 11,725, wllham Petry; Earle R- Marden Feb. 16, 1970. 1
57 ABSTRACT [52] U.S. C1 425/83, 264/22, /4 1 v 51 Int. Cl. B296 13/00, B29d 7/00 Process and apparatus 19 produce'nonwoven fabric [58] F1610 61 Search 425/-83, from a Stream of liquid material having a high 425/224; 264/10, 12, 22, 24 electric constant. The stream of liquid material is delivered past an air nozzle having a high electrical po- 5 References Cited tential which attracts the liquid stream and shatters it UNITED STATES PATENTS into fine fibrous particles. I
2,048,651 7/1936 Norton 264/10 4 Claims, 4 Drawing Figures PAIENIE JUL 1 a mu SHEET 1 OF 2 FIG. l--
FIG. -4-
INVENTOR. JAMES E. FOWLER M ra.
ATTORNEY PATENTED JUL 1 81874 SHEET 2 [IF 2 INVENTOR. 1 JAMES E. FOWLER mum;
Fl (H 30.
FIG. 3-
.MR.W
ATTORNEY 1 APPARATUS TO PRODUCE NONWOVEN FABRIC This is a continuation of application Ser. No. 134,131, now abandoned, filed Apr. 15, 1971 which is a divisional application of pending prior application Ser. No. 11,725, filed Feb. 16, 1970, of James E. Fowler for Process and Apparatus to Produce Nonwoven Fabric.
It is known to subject a liquid flow of polymeric material, such as a molten flow of thermoplastic polymer, to a high velocity fluid stream, such as air, to shatter the material into a plurality of discrete fibers or fibrils which may be suitably collected, such as on a moving screen or the like, to form a nonwoven web.
In such prior art processes, fiber forming polymeric material is extruded from a suitable extrusion orifice or die and subjected, while in liquid moldable form, to the action of a pressurized stream of gas which attenuates the polymeric stream and breaks it generally traversely to form a plurality of discrete particles or fibers. Since the physical characteristics of the fibers produced de-' pend greatly upon the velocity and particular position of the pressurized gas stream relative to the moving flow of polymeric material, it has been quite difficult to control the size and uniformity of the fibrous particles produced due to the inherent wandering, erratic movement of the polymeric flow stream under influence of the pressurized attenuating gas.
lt is therefore an object of the present invention to provide an improved process and apparatus for producing fibrous particles for use in the formation-of nonwoven products by contacting a liquid flow of fiber formin g material with a pressurized fluid stream to attenuate the same while accurately controlling the position of the flow of fiber forming material relative to the pressurized fluid stream to control the physical characteristics of the fibrous particles produced.
Other objects and advantages of the invention will become clearly apparent as the specification proceeds to describe the invention with reference to the accompanying drawings, in which:
FIG. 1 is a schematic representation of the new and improved process and apparatus;
FIG. 2 is a cross-section view through the extruder head and air nozzle apparatus;
FIG. 3 is a top view of the air nozzle; and
FIG. 4 is a top view of the air nozzle traverse linkage.
As discussed briefly, the invention is directed to shattering of a liquid stream which has a high di-electric constant and good electrical conductivity in the molten state. For purposes of this specification a liquid stream with a di-electric constant above 20 is one which has a high di-electric constant. In the preferred form of the invention a fiber forming polymeric material such as nylon 6 or nylon 6-6 is employed to form the shattered fibers and consequentially a nonwoven fabric.
Looking now to the drawings and especially to FIG. 1, the new and improved process and'apparatus will be described. Briefly, a polymer suchas nylon 6 is supplied in suitable form, such as pellets or discrete particles, into the hopper 10 of a conventional extruder 12. The polymer is brought to the molten state and extruded downwardly under pressure in a substantially vertical direction through a single orifice spinnerette 14. Located adjacent the downward path of flow of the extruded polymer 16 is a plurality of air nozzles 18 supplied with air under pressure from an air manifold 20 through a non-conductive air hose22. The number of air nozzles 18 and spinnerettes 14 is dependent upon the width of nonwoven material to be'made. Preferably, the air nozzles 18 are of a highly conductive material such as copper and are connected to a high voltage d.c. source through the cable 24 to provide the air nozzles 18 with a high electrical potential. To electrically isolate the charged air nozzles 18 from the support 25 a non-conductive air nozzle support 26 is provided. As is known in the prior art, the high velocity air from the air nozzles 18 will shatter thepolymer stream 16 into individual fibers and blow these individual fibers onto the continuously driven endless collection belt 28. The high electrical potential of the air nozzles 18 initially attracts the highly conductive polymer toward the nozzle and tends to maintain the stream a predetermined horizontal distance from the air nozzle opening 30 which aids in controlling the effective use of the air velocity to control the length and diameter of the shattered fibers. Also, since the electrical potential of the air nozzles 18 is high enough to create a corona discharge, the polymer' stream and shattered fibers adjacent the nozzle rapidly take a charge which causes the fibers to repel one another as they travel to and impinge on the collection belt 28. The nonwoven web formedon the collection belt 28 is automatically employed is dependent on the width of the nonwoven web material desired. mule embodiment described, two air nozzles 18 are shown and are mounted so that they can pivot back and forth to cover a certain preselected width of the conveyor belt 28 with shattered fibers. Preferably, the air nozzle 18 will pivot about a ro-' tary path so that the horizontal distance between the end of the air nozzle and the polymer stream remains constant to maintain uniformity of the fibers being made and as much as possible the uniformity of the nonwoven web being made from such fibers.
To control the pivotal movement of the air nozzles 18 the linkage arrangement shown in a top view in FIG. 4 isemployed. The T-shaped member 31 is rigidly secured to a suitable frame support (not shown) andsupports a cross-bar 32 mounted on an upstanding portion 34 of the member 31. Pivotally connected to the crossbar 32 at 36 and 38 are lever arms 40 and 42 which are pivotally connected to the long arms 44 and 46 of the parallelogram linkage at 48 and 50. Also pivotally connected to the ends of the arms 44 and 46 at 47 and 49 are the short arms 52 and 54'of the parallelogram linkage which are integral with the air nozzle support plates 56 and 58. Mounted to the upstanding portion 34 of the T-shaped member 31 is a pair of pulleys 60. Connected to each pivot point 49 is a wire or chain 62 wrapped around one of the pulleys 60 and then directed 'to a source of drive (not shown) which alternately pulls on one of the wires or chains 62 to cause the arms 44, 46, 52 and 54 to pivot about their pivot points to move the air nozzles 18 in an arc around the polymer scream 16 to blow shattered fibers across a predetermined width of the collection belt 28. Preferably, the air nozzle opening 30 is rectangular shaped to provide the most efficient use of the air on the polymer stream 16.
As set forth above, it is preferred to have a rectangular shaped nozzle opening 30. It is found that this shape of nozzle in conjunction with the proper air pressure provides the mostconsistent and efficient breaking of the fibers from the polymer stream. The selected air pressure normally will be one that will provide super sonic air velocities at the nozzle opening 30. The proper air velocity or as normally expressed, the mass flow rate, in conjunction with the viscosity of the polymer stream 16 is important in controlling the diameter of the fibers being produced. Normally, as the air pressure is lowered, the diameter of the fiber being produced, increases. It is preferred to provide smaller diameter fibers since the nonwoven web produced therefrom tends to be stronger, have better cover and much better cohesion between the fibers.
The following examples will illustrate the benefits obtained by applying a high electrical potential to the fluid nozzle used in shattering a molten polymer stream consisting of a material with generally a good' dielectric constant and electrical conductivity in the mol ten state.
EXAMPLE 1 Nylon 6 polymer manufactured by Allied Chemical Company is processed through an extruder in a normal manner and expelled at a rate of 3.8 pounds per hour through a spinnerette consisting of a single 0.040 inch diameter orifice.
The fluid nozzle used is this example consists of a copper tube fitted with a throat section of 0.065 inch diameter, and a general configuration of an elliptical hyperboloid. The expanding gases are at least sonic at the nozzle exit. This particular nozzle had a flow rate of 6.6 scfm when operating at a pressure of 60 psig.
Placement of the fluid nozzle exit was 1 /2 inches below the spinnerette orifice and approximately onequarter inch away from and generally perpendicular to the molten polymer stream.
The following data is obtained from conditions where the only variable is the level of electrical charge applied to the fluid nozzle.
Average Fiber Diameter No electric charge applied to fluid nozzle 18,000 volts d.c. negative potential applied to nozzle I 25.2 microns l 1.8 microns EXAMPLE 2 A nylon 6 polymer spun in a manner similar to that outlined in Example 1 was processed at a rate of 2.6
pounds per hour through a 0.040 inch diameter spin-' nerette orifice. The nozzle was operated with compressed air at 47 psig. It was found again that whenever a charge was applied to the fluid nozzle smaller diameter filaments were obtained.
Average Fiber Diameter No electrical charge applied 17.5 microns 10,000 volts electrical potential applied to nozzle 1 1.8 microns EXAMPLE 3 A nylon 6 polymer spun in a manner similar to Example l was shattered with a nozzle consisting of a rectangular throat section with an exit area of 0.0029 square inches. Placement of the nozzle was i% inches below the spinnerette orifice with the nozzle exit approximately one-half inch from the molten polymer stream, and generally perpendicular to the stream. The following table will illustrate the average fiber diameters obtained for several polymer flow rates, and the effect of a charged nozzle versus no electrical charge. The nozzle was operated at 50 'psig.
Voltage Applied Polymer Flow Average Fiber to Nozzle Rate Diameter 0 3.05 brn/hr 32.1 microns 20,000 3.05 bm/hr 14.9 microns 0 4.30 bm/hr 27.2 microns 20,000 4.30 bm/hr 20.3 microns 0 5.75 bm/hr 19.8 microns 20,000 5.75 bm/hr 16.3 microns 0 8.0 bm/hr. 32.4 microns 20,000 8.0 brn/hr. 24.2 microns tered fibers to readily pick up the charge of the air nozzle causing the fibers to repel one another to provide a better distribution of fibers on the collection belt.
Although l have described in detail the preferred embodiment of my invention, 1 contemplate that many changes may be made without departing from the scope or spirit of the invention and I desire to be limited only by the claims.
That which will be claimed is:
1. Apparatus to produce a nonwoven sheet of material comprising an extruder providing a flow of molten liquid, an air nozzle supported below and substantially perpendicular to the flow of molten liquid from said extruder, a high voltage potential means operably associated with said air nozzle to maintain substantially constant the horizontal distance between said air nozzle and the path of flow of molten liquid from said extruder, means supplying air under pressure to said air nozzle and means operably associated with said air nozzle to collect fibers formed by the action of air from said air nozzle on a stream of molten liquid from said extruder. a
3,824,052 5 6 2. The structure of claim 1 wherein said means suptate said air nozzle includes a parallelogramlinkage.
porting said air nozzle includes a means to rotate said 4. The structure of claim 3 wherein said fiber colleca1r nozzle partlally around the path of flow of said an nozzle, t1on means 18 an endless belt.
3. The structure of claim 2 wherein said means to r-

Claims (3)

  1. 2. The structure of claim 1 wherein said means supporting said air nozzle includes a means to rotate said air nozzle partially around the path of flow of said air nozzle.
  2. 3. The structure of claim 2 wherein said means to rotate said air nozzle includes a parallelogram linkage.
  3. 4. The structure of claim 3 wherein said fiber collection means is an endless belt.
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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4168138A (en) * 1977-06-01 1979-09-18 Celanese Corporation Spray spinning nozzle using parallel jet flow
US4173443A (en) * 1977-06-01 1979-11-06 Celanese Corporation Spray spinning nozzle having convergent gaseous jets
US4215682A (en) * 1978-02-06 1980-08-05 Minnesota Mining And Manufacturing Company Melt-blown fibrous electrets
WO1992005305A1 (en) * 1990-09-24 1992-04-02 Exxon Chemical Patents Inc. Charging apparatus and method for meltblown webs
US6086813A (en) * 1997-09-23 2000-07-11 Brunswick Corporation Method for making self-supporting thermoplastic structures
US6516126B1 (en) * 1999-02-25 2003-02-04 Nexans Element with extruded sheathing
US20030233735A1 (en) * 2002-06-15 2003-12-25 Kimberly-Clark Worldwide, Inc. Use of a pulsating power supply for electrostatic charging of nonwovens
US6709623B2 (en) 2000-12-22 2004-03-23 Kimberly-Clark Worldwide, Inc. Process of and apparatus for making a nonwoven web
US20050087288A1 (en) * 2003-10-27 2005-04-28 Haynes Bryan D. Method and apparatus for production of nonwoven webs
US20070040305A1 (en) * 2005-08-17 2007-02-22 Armantrout Jack E Electroblowing fiber spinning process
US7504060B2 (en) 2003-10-16 2009-03-17 Kimberly-Clark Worldwide, Inc. Method and apparatus for the production of nonwoven web materials

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2048651A (en) * 1933-06-23 1936-07-21 Massachusetts Inst Technology Method of and apparatus for producing fibrous or filamentary material
US2336745A (en) * 1941-12-20 1943-12-14 Fred W Manning Method and apparatus for making unwoven and composite fabrics
US2382290A (en) * 1940-11-22 1945-08-14 Marshall E Callander Manufacture of mineral wool
US2466906A (en) * 1946-11-23 1949-04-12 Ransburg Electro Coating Corp Method and apparatus for forming fibrous webs
US3020585A (en) * 1956-05-15 1962-02-13 Saint Gobain Process and apparatus for the manufacture of fiber linings or mats
US3158668A (en) * 1960-12-19 1964-11-24 Earl A N Johnson Method and apparatus for mat forming
US3276928A (en) * 1956-03-12 1966-10-04 Owens Corning Fiberglass Corp Reinforced mat construction and method of forming same
US3338992A (en) * 1959-12-15 1967-08-29 Du Pont Process for forming non-woven filamentary structures from fiber-forming synthetic organic polymers
US3442633A (en) * 1964-01-02 1969-05-06 Walter Merton Perry Method and apparatus for conveying and for treating glass fibers
US3461943A (en) * 1966-10-17 1969-08-19 United Aircraft Corp Process for making filamentary materials

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2048651A (en) * 1933-06-23 1936-07-21 Massachusetts Inst Technology Method of and apparatus for producing fibrous or filamentary material
US2382290A (en) * 1940-11-22 1945-08-14 Marshall E Callander Manufacture of mineral wool
US2336745A (en) * 1941-12-20 1943-12-14 Fred W Manning Method and apparatus for making unwoven and composite fabrics
US2466906A (en) * 1946-11-23 1949-04-12 Ransburg Electro Coating Corp Method and apparatus for forming fibrous webs
US3276928A (en) * 1956-03-12 1966-10-04 Owens Corning Fiberglass Corp Reinforced mat construction and method of forming same
US3020585A (en) * 1956-05-15 1962-02-13 Saint Gobain Process and apparatus for the manufacture of fiber linings or mats
US3338992A (en) * 1959-12-15 1967-08-29 Du Pont Process for forming non-woven filamentary structures from fiber-forming synthetic organic polymers
US3158668A (en) * 1960-12-19 1964-11-24 Earl A N Johnson Method and apparatus for mat forming
US3442633A (en) * 1964-01-02 1969-05-06 Walter Merton Perry Method and apparatus for conveying and for treating glass fibers
US3461943A (en) * 1966-10-17 1969-08-19 United Aircraft Corp Process for making filamentary materials

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4168138A (en) * 1977-06-01 1979-09-18 Celanese Corporation Spray spinning nozzle using parallel jet flow
US4173443A (en) * 1977-06-01 1979-11-06 Celanese Corporation Spray spinning nozzle having convergent gaseous jets
US4215682A (en) * 1978-02-06 1980-08-05 Minnesota Mining And Manufacturing Company Melt-blown fibrous electrets
DK157286B (en) * 1978-02-06 1989-12-04 Minnesota Mining & Mfg FACIAL MASK AND PROCEDURE FOR PREPARING A FIBER COVER ELECTRIC FOR USE AS FILTER LAYER IN THE FACE MASK
WO1992005305A1 (en) * 1990-09-24 1992-04-02 Exxon Chemical Patents Inc. Charging apparatus and method for meltblown webs
US6086813A (en) * 1997-09-23 2000-07-11 Brunswick Corporation Method for making self-supporting thermoplastic structures
US6516126B1 (en) * 1999-02-25 2003-02-04 Nexans Element with extruded sheathing
US6709623B2 (en) 2000-12-22 2004-03-23 Kimberly-Clark Worldwide, Inc. Process of and apparatus for making a nonwoven web
US20030233735A1 (en) * 2002-06-15 2003-12-25 Kimberly-Clark Worldwide, Inc. Use of a pulsating power supply for electrostatic charging of nonwovens
US7488441B2 (en) 2002-06-15 2009-02-10 Kimberly-Clark Worldwide, Inc. Use of a pulsating power supply for electrostatic charging of nonwovens
US7504060B2 (en) 2003-10-16 2009-03-17 Kimberly-Clark Worldwide, Inc. Method and apparatus for the production of nonwoven web materials
US20050087288A1 (en) * 2003-10-27 2005-04-28 Haynes Bryan D. Method and apparatus for production of nonwoven webs
US20070040305A1 (en) * 2005-08-17 2007-02-22 Armantrout Jack E Electroblowing fiber spinning process
US7582247B2 (en) * 2005-08-17 2009-09-01 E. I. Du Pont De Nemours And Company Electroblowing fiber spinning process

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