US3919447A - Spectral differential coded card - Google Patents
Spectral differential coded card Download PDFInfo
- Publication number
- US3919447A US3919447A US453138A US45313874A US3919447A US 3919447 A US3919447 A US 3919447A US 453138 A US453138 A US 453138A US 45313874 A US45313874 A US 45313874A US 3919447 A US3919447 A US 3919447A
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- US
- United States
- Prior art keywords
- film
- visible light
- light wave
- card
- wave region
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 230000003595 spectral effect Effects 0.000 title claims description 15
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 25
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 23
- 230000005540 biological transmission Effects 0.000 claims abstract description 15
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 8
- 229920000642 polymer Polymers 0.000 claims abstract description 5
- 238000010521 absorption reaction Methods 0.000 claims description 27
- 230000003287 optical effect Effects 0.000 claims description 12
- 230000001747 exhibiting effect Effects 0.000 claims description 11
- 238000002329 infrared spectrum Methods 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 2
- 125000004185 ester group Chemical group 0.000 claims description 2
- QGEOKXWFGANCJL-UHFFFAOYSA-N ethenyl acetate;hydrochloride Chemical compound Cl.CC(=O)OC=C QGEOKXWFGANCJL-UHFFFAOYSA-N 0.000 claims description 2
- 125000003636 chemical group Chemical group 0.000 claims 3
- 150000002148 esters Chemical class 0.000 claims 1
- 229920001756 Polyvinyl chloride acetate Polymers 0.000 description 6
- 229920002689 polyvinyl acetate Polymers 0.000 description 6
- 238000003475 lamination Methods 0.000 description 5
- 238000001514 detection method Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000004566 IR spectroscopy Methods 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000976 ink Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- -1 polyethylene terephthalate Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- JBRZTFJDHDCESZ-UHFFFAOYSA-N AsGa Chemical compound [As]#[Ga] JBRZTFJDHDCESZ-UHFFFAOYSA-N 0.000 description 1
- 238000005773 Enders reaction Methods 0.000 description 1
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 1
- 241000078511 Microtome Species 0.000 description 1
- 241000428199 Mustelinae Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012612 commercial material Substances 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000002648 laminated material Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 238000012667 polymer degradation Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/21—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose for multiple purposes
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06K—GRAPHICAL DATA READING; PRESENTATION OF DATA; RECORD CARRIERS; HANDLING RECORD CARRIERS
- G06K19/00—Record carriers for use with machines and with at least a part designed to carry digital markings
- G06K19/06—Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code
- G06K19/08—Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code using markings of different kinds or more than one marking of the same kind in the same record carrier, e.g. one marking being sensed by optical and the other by magnetic means
- G06K19/10—Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code using markings of different kinds or more than one marking of the same kind in the same record carrier, e.g. one marking being sensed by optical and the other by magnetic means at least one kind of marking being used for authentication, e.g. of credit or identity cards
- G06K19/14—Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code using markings of different kinds or more than one marking of the same kind in the same record carrier, e.g. one marking being sensed by optical and the other by magnetic means at least one kind of marking being used for authentication, e.g. of credit or identity cards the marking being sensed by radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/40—Manufacture
- B42D25/45—Associating two or more layers
-
- G—PHYSICS
- G07—CHECKING-DEVICES
- G07F—COIN-FREED OR LIKE APPARATUS
- G07F7/00—Mechanisms actuated by objects other than coins to free or to actuate vending, hiring, coin or paper currency dispensing or refunding apparatus
- G07F7/08—Mechanisms actuated by objects other than coins to free or to actuate vending, hiring, coin or paper currency dispensing or refunding apparatus by coded identity card or credit card or other personal identification means
- G07F7/086—Mechanisms actuated by objects other than coins to free or to actuate vending, hiring, coin or paper currency dispensing or refunding apparatus by coded identity card or credit card or other personal identification means by passive credit-cards adapted therefor, e.g. constructive particularities to avoid counterfeiting, e.g. by inclusion of a physical or chemical security-layer
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- B42D2033/08—
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- B42D2033/18—
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- B42D2033/22—
-
- B42D2033/30—
-
- B42D2033/32—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/346—Perforations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/378—Special inks
- B42D25/382—Special inks absorbing or reflecting infrared light
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S283/00—Printed matter
- Y10S283/904—Credit card
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/916—Fraud or tamper detecting
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
- Y10T428/24322—Composite web or sheet
- Y10T428/24331—Composite web or sheet including nonapertured component
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24851—Intermediate layer is discontinuous or differential
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24851—Intermediate layer is discontinuous or differential
- Y10T428/24868—Translucent outer layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
Definitions
- ABSTRACT A card suitable for use in personal and item identification; the card comprises a first film such as polyvinyl chloride with a transmission bandpass in the infra red region. and either a selectively apertured second film laminated on the first film. 0r. discrete areas of the second film laminated on preselected areas of the first film.
- the second film is opaque at a single frequency within the first film bandpass.
- the films may be formed from the same material but for the trace amounts of a carbonyl group in the structure of the second film polymer. the laminate otherwise being transparent and reflecti ely uniform in the isible light region.
- This invention relates to cards suitable for personal and item identification. and more particularly toward an improvement in reducing unauthorized detection and counterfeiting of such cards.
- Typical prior art optional systems use coded indicia on the card, which indicia are interrogated by illuminating the card with light and evaluating the reflective return.
- Makishima illustratively contemplates a fluorescent screen, non-fluorescent coded indicia carried on the screen, and an ultraviolet filter covering the coded screen to render the code invisible to the eye in ordinary light. When the screen is exposed to ultraviolet light, the screen fluoresces in the visible light region. The coded information is then set forth by contrast.
- PVC polyvinyl chloride
- PVCAC polyvinyl chloride acetate
- the card is encoded by either selectively aperturing the PVCAC film or laminating discrete portions of PVAC on selected areas of the PVC film.
- the laminate has a substantially uniform transmissivity and surface reflectance when illuminated by light in the visible region.
- the visible spectrum as seen by the average human eye. extends from violet (wavelength of 0.38 microns) to red (0.78 microns). The eye is most sensitive to yellowgrcen (0.55 microns) which lies well within the violet-red range.
- the infra red region especially in the 1.0 micron to 15 micron region is blessed with detectors such as gallium arsenide. Accordingly. the illustrative embodiment contemplates a card transparent to light in the visible region and in at least one non-visible region such as infra red.
- PVC polyvinyl chloride
- Cl n suitably permeable in the visible and infra red regions.
- PVC bandpass transmission characteristic is substantially flat and non-absorbant from about 3.5 microns to about 7.0 microns. It was also ob served that a carbonyl group attached to such a polymeric film structure would exhibit a near single fre quency absorption characteristic well within the 3.5 7.0 micron range at 5.8 microns.
- the card is formed from a film of PVC laminated onto a film of polyvinyl chloride acetate (PVCAC).
- PVAC polyvinyl chloride acetate
- the PVAC layer can be exceedingly thin.
- the indicia can be encoded onto the card by selectively aperturing the PVAC layer by punching holes before lamination. Upon lamination, the PVC is caused to fill the apertures. This renders the apertures optically indistinguishable in visible light.
- the encoding can be accomplished by the deposition of PVAC strips onto discrete preselected areas of the PVC film by rapid evaporation process.
- PVAC has substantially similar optical and physico-chemical characteristics as PVC but for its discrete near single frequency absorption characteristic. This means that light illuminating the laminate in the visible region will be either passed through the structure or partially reflected from the surfaces uniformly. As the laminate is illuminated by light in the infra red region, a spectral difference is detectable only on or about 5.8 microns.
- the best form contemplates that only the second film contain the carbonyl groups. It is recalled from Beer's law that the amount of light absorbed is proportional to the concentration of the absorbing material. Consequently. if the second film has a significantly higher concentration of carbonyl groups than the first film. then there would still be a detectable spectral difference at 5.8 microns. This factor becomes of some significance in the practice of the invention in iew of the commercial difficulty of obtaining carbonyl group free PVC. lllustrativcly. films frequently contain plasticizers. e.g.. dioctal phthalate (di-Z-ethyl hexyl phthalate) to maintain a degree of suppleness.
- plasticizers e.g.. dioctal phthalate (di-Z-ethyl hexyl phthalate) to maintain a degree of suppleness.
- This plastieizer contains as many as 2 carbonyl groups per mole.
- polyaromatic stabilizers may be added to prevent polymer degradation. These also contain carbonyl groups. Thus. it is of importance that the relative concentration be kept in mind when fashioning the invention from commercial materials.
- a PVC layer can be laminated on top of the second film forming a sandwich therefrom. Vacuum lamination. for example. avoids any trapping of gas bubbles.
- Another laminate exhibiting a notch frequency in the infra red region is a card formed from polyethylene terephthalate and polyethylene.
- the mechanical strength of the bond may vary as a function of the differences. it any. in the melting temperatures and whether the melting point is sharply defined. In the above cases. plastics having amorphous structures are used. in this actuation. a range of melt temperatures can be expected.
- the infra-red spectrum is said to be one of the most unique signatures. lndeed. as pointed out by Koji Nakanishi in. Infra-red Spectroscopy. Holden Day. Inc.. San Francisco. [962. at pages 1. 3 and I7. absorption bands that appear with a relatively high intensity in a range characteristic for a certain group and that are useful for the identification of that group are termed characteristic frequencies or characteristic absorption bands".
- characteristic frequencies or characteristic absorption bands absorption bands that appear with a relatively high intensity in a range characteristic for a certain group and that are useful for the identification of that group.
- characteristic frequencies or characteristic absorption bands are termed characteristic frequencies or characteristic absorption bands.
- the infra-red absorption intensities as with intensities in other spectral ranges can not be expressed in universal constants. In such fields as qualitative organic chemistry. the intensity is usually expressed as very strong. strong. medium. weak. etc. Thus.
- a selectively apertured second film having a sharp absorption characteristic is laminated upon a first film. whose absorption within the same light wave region is substantially less absorptive than that of the second film at a near single frequency.
- the term near single frequency is taken to mean that the second film sharp absorption characteristic is manifest on or about 5.8 microns but that there exists an illdefined region of several cycles per second above and below the nominal frequency within which the strong 5 absorption characteristic is manifest.
- a card or the like suitable for use in personal and item identification comprising:
- a card or the like suitable for use in personal and item identification comprising:
- a second film having discrete areas laminated upon preselected areas of the first film.
- said second film discrete areas having a substantially similar spectral response as that of the first film within the pre determined non-visible light wave region of the first film bandpass but for a sharp band absorption characteristic at a near single frequency.
- the first film including the portions discretely laminated with the second film further exhibiting a substantially uniform transmissivity and surface reflectance in the visible light wave region.
- a card or the like suitable for use in personal and item identification comprising:
- the second film being formed from polymeric material having a carbonyl group and an associated ester group present in the polymer structure.
- the laminate including the apertured portions thereof further exhibiting a substantially uniform transmissivity and surface reflectance in the visible light wave region.
- a card or the like suitable for use in personal and item identification comprising:
- a selectively apertured second film laminated upon the first film and formed from the same material group includes a carbonyl group and an associated cster.
- a card or the like suitable for use in personal and 5 item identification comprising:
- said laminated structure exhibiting a substantially uniform transmissivity and surface reflectance in the visible light wave region
Abstract
A card suitable for use in personal and item identification; the card comprises a first film such as polyvinyl chloride with a transmission bandpass in the infra red region, and either a selectively apertured second film laminated on the first film, or, discrete areas of the second film laminated on preselected areas of the first film. The second film is opaque at a single frequency within the first film bandpass. The films may be formed from the same material but for the trace amounts of a carbonyl group in the structure of the second film polymer, the laminate otherwise being transparent and reflectively uniform in the visible light region.
Description
United States Patent 1191 Kilmer, r. et a1.
1 1 Nov. 11, 1975 1 1 SPECTRAL DIFFERENTIAL CODED CARD [73] Assignee: International Business Machines Corporation. Amionk. NY.
[221 Filed: Mar. 20. 1974 21 Appl. No: 453.138
Related US. Application Data 163] Continuation of Ser. No. 213.201. Dec. 28. I971.
abandoned.
[52] U5. Cl 428/138; 40/22; 235/6l.11 E; 235/6112 N; 250/271; 250/569. 283/61 [51] Int. Cl. G06K 19/02: G06K 7/12 {58] Field ofSearch 117/1.1.5;l6l/1.4.5. 161/6. 36. 113. 166. 254. 256. 146; 40/22. 235/6112 N. 61.11 E; 283/6. 7. 8 R.
[56] References Cited UNITED STATES PATENTS 3.239.815 3/1966 Martens..... 340/149 3.536.894 10/1970 Tra ioli 235/616 3.725.184 4/1973 Scopp 161. 6 3.802.101 4/1974 Scantlin H 4012 2 Furahashi 3401149 A Lehrer 161/6 OTHER PUBLICATIONS Cleverly & Herrman. Infra-Red Spectra of Textiles." J. Appl. Chem. 11. Sept. 1961. pp. 348 & 350. Zbinden. Infrared Spectroscopy of High Polymers." Academic Press. 1964. pp. 13 & 90.
Primary Examiner-George F. Lesmes Asxrismnl biumzinew-Charles E. Lipsey Attorney. Agent. or Fimz-R. Bruce Brodie [57 1 ABSTRACT A card suitable for use in personal and item identification; the card comprises a first film such as polyvinyl chloride with a transmission bandpass in the infra red region. and either a selectively apertured second film laminated on the first film. 0r. discrete areas of the second film laminated on preselected areas of the first film. The second film is opaque at a single frequency within the first film bandpass. The films may be formed from the same material but for the trace amounts of a carbonyl group in the structure of the second film polymer. the laminate otherwise being transparent and reflecti ely uniform in the isible light region.
7 Claims. N0 Drawings SPECTRAL DIFFERENTIAL CODED CARD This is a continuation. of application Serial No. 213.201 filed DEc. 28, 1971, now abandoned.
BACKGROUND OF THE INVENTION This invention relates to cards suitable for personal and item identification. and more particularly toward an improvement in reducing unauthorized detection and counterfeiting of such cards.
In the prior art, as for example set forth in US. Pat. No. 3,468,046, issued to Shoji Makishima on Sept. 23, [969. credit and identity cards formed from flexibletough thermoplastics are described. Such cards usually have alphanumeric coded indicia raised portions of the card with a signature strip consisting of a titanium dioxide surface occupying other portions of the card. As Makishima correctly points out, the most serioues drawback is that such a credit or identity card can become lost or stolen so as to fall in the hands of unscrupulous persons. Relatedly. cards can also be used as keys to gain access to or activate remote communications terminals, badge readers, and the like. In the latter circumstances, protection against unauthorized reproduction is of special concern.
Many techniques have been suggested to confuse the information on the card and several to hide or mask the data. Among the approaches that have been considered are those of holograms, magnetic recording, infra red inks and phosphorescent inks. Some suffer from cost (holograms). while others suffer from ease of detection (magnetic strips). Typical prior art optional systems use coded indicia on the card, which indicia are interrogated by illuminating the card with light and evaluating the reflective return. Makishima illustratively contemplates a fluorescent screen, non-fluorescent coded indicia carried on the screen, and an ultraviolet filter covering the coded screen to render the code invisible to the eye in ordinary light. When the screen is exposed to ultraviolet light, the screen fluoresces in the visible light region. The coded information is then set forth by contrast.
The protection of a card against counterfeiting presents several aspects. Thus, it is desirable to make it difficult for an unauthorized person to reverse engineer" such a card. As an example, where coded cards emit visible light when stimulated by light in the ultraviolet region, such cards can be easily compromised due to the availability of UV. light sources in theatres, bars. and hotels. It is then apparent from the counterfeit viewpoint that the code is formed from a contrast of fluorescent and non-fluorescent areas.
SUMMARY OF THE INVENTION It is an object of this invention to devise a credit card and the like having coded indicia thereon, the structure of the card inhibiting unauthorized detection and counterfeiting thereof. Relatedly, such coded indicia should be optically readable with the card being formed from one or more materials capable of being tooled, and its optical characteristics should not be altered by the fabrication process.
The foregoing object is satisfied in an embodiment of a laminated structure of polyvinyl chloride (PVC) film fused to polyvinyl chloride acetate (PVCAC film. This provides a large spectra transmissivity difference in the near infra red region. Thatis, PVC has a bandpass transmission characteristic in the 3.5 micron to 7 micron wavelength region. PVCAC has the same transmission characteristic but for a near single frequency absorption characteristic in the 5.8 micron region. The card is encoded by either selectively aperturing the PVCAC film or laminating discrete portions of PVAC on selected areas of the PVC film. Significantly. the laminate has a substantially uniform transmissivity and surface reflectance when illuminated by light in the visible region. Also, fusing or bonding does not alter the laminates optical characteristics. Of importance is the fact that PVC and PVC AC are completely miscible and each laminate layer possesses the same mechanical characteristics as the other. This suggests to the prospective counterfeiter a homogenous and not a laminate material. Note, that commercially available film exhibits the acetate absorption characteristic. Consequently. the unauthorized person would require for example. a micro-tome to distinguish the laminate from homogenous material.
DESCRIPTION OF THE PREFERRED EMBODIMENT It is well-known that the visible spectrum, as seen by the average human eye. extends from violet (wavelength of 0.38 microns) to red (0.78 microns). The eye is most sensitive to yellowgrcen (0.55 microns) which lies well within the violet-red range. Now, the infra red region especially in the 1.0 micron to 15 micron region is blessed with detectors such as gallium arsenide. Accordingly. the illustrative embodiment contemplates a card transparent to light in the visible region and in at least one non-visible region such as infra red.
One flexible-tough thermoplastic having this spcctras requirement is polyvinyl chloride (PVC). PVC having the chemical structural form Cl n suitably permeable in the visible and infra red regions. In the latter case. PVC bandpass transmission characteristic is substantially flat and non-absorbant from about 3.5 microns to about 7.0 microns. It was also ob served that a carbonyl group attached to such a polymeric film structure would exhibit a near single fre quency absorption characteristic well within the 3.5 7.0 micron range at 5.8 microns.
in the preferred embodiment, the card is formed from a film of PVC laminated onto a film of polyvinyl chloride acetate (PVCAC). The PVAC layer can be exceedingly thin. The indicia can be encoded onto the card by selectively aperturing the PVAC layer by punching holes before lamination. Upon lamination, the PVC is caused to fill the apertures. This renders the apertures optically indistinguishable in visible light. Alternatively, the encoding can be accomplished by the deposition of PVAC strips onto discrete preselected areas of the PVC film by rapid evaporation process.
It should be recalled that PVAC has substantially similar optical and physico-chemical characteristics as PVC but for its discrete near single frequency absorption characteristic. This means that light illuminating the laminate in the visible region will be either passed through the structure or partially reflected from the surfaces uniformly. As the laminate is illuminated by light in the infra red region, a spectral difference is detectable only on or about 5.8 microns.
Since PVC and PVAC are commercially available in sheet form lamination can be effectuated by placing re spective sheets one upon the other between hot platens or calendcrs. Because the dwell time between the cal ender rolls is short in the order of a second or less. a temperature above the melting temperature of approximately 250C can be used. Note that in this form of lamination. there is only a small amount of plastic flow.
As previously mentioned. the best form contemplates that only the second film contain the carbonyl groups. It is recalled from Beer's law that the amount of light absorbed is proportional to the concentration of the absorbing material. Consequently. if the second film has a significantly higher concentration of carbonyl groups than the first film. then there would still be a detectable spectral difference at 5.8 microns. This factor becomes of some significance in the practice of the invention in iew of the commercial difficulty of obtaining carbonyl group free PVC. lllustrativcly. films frequently contain plasticizers. e.g.. dioctal phthalate (di-Z-ethyl hexyl phthalate) to maintain a degree of suppleness. This plastieizer contains as many as 2 carbonyl groups per mole. Likewise. polyaromatic stabilizers may be added to prevent polymer degradation. These also contain carbonyl groups. Thus. it is ofimportance that the relative concentration be kept in mind when fashioning the invention from commercial materials.
In circumstances where it is desired to protect the coded indicia from alteration due to wear or accidental scratching. a PVC layer can be laminated on top of the second film forming a sandwich therefrom. Vacuum lamination. for example. avoids any trapping of gas bubbles.
Another laminate exhibiting a notch frequency in the infra red region is a card formed from polyethylene terephthalate and polyethylene.
Note. that the mechanical strength of the bond may vary as a function of the differences. it any. in the melting temperatures and whether the melting point is sharply defined. In the above cases. plastics having amorphous structures are used. in this actuation. a range of melt temperatures can be expected.
It should be observed in connection with the description of the preferred embodiments that the infra-red spectrum is said to be one of the most unique signatures. lndeed. as pointed out by Koji Nakanishi in. Infra-red Spectroscopy. Holden Day. Inc.. San Francisco. [962. at pages 1. 3 and I7. absorption bands that appear with a relatively high intensity in a range characteristic for a certain group and that are useful for the identification of that group are termed characteristic frequencies or characteristic absorption bands". Un fortunately. the infra-red absorption intensities as with intensities in other spectral ranges can not be expressed in universal constants. In such fields as qualitative organic chemistry. the intensity is usually expressed as very strong. strong. medium. weak. etc. Thus. in order to qualitatively describe the optical spectral response of the preferred embodiments. it is to be understood that it is the relative spectral difference between two films in the light wave region of interest that is being characterized. lllustratively. it may be said in one of the preferred embodiments. a selectively apertured second film having a sharp absorption characteristic is laminated upon a first film. whose absorption within the same light wave region is substantially less absorptive than that of the second film at a near single frequency. The term near single frequency" is taken to mean that the second film sharp absorption characteristic is manifest on or about 5.8 microns but that there exists an illdefined region of several cycles per second above and below the nominal frequency within which the strong 5 absorption characteristic is manifest.
While this invention has been described with reference to a preferred embodiment thereof. it will be un derstood by those of skill in the art that numerous changes can be made in form and details without departing from the spirit and scope thereof.
What is claimed is: l. A card or the like suitable for use in personal and item identification comprising:
a first film having an optical bandpass transmission free from sharp band absorption characteristics in a predetermined non-visible light wave region; and
a selectively apertured second film laminated upon the first film and having a substantially similar spectral response as that of the first film within the predetermined non-visible light wave region of the first film bandpass but for a sharp band absorption characteristic at a near single frequency. the laminate including the apertured portions thereof further exhibiting a substantially uniform transmissivity and surface reflectance in the visible light wave region. 2. A card or the like suitable for use in personal and item identification comprising:
a first film having an optical bandpass transmission free from sharp band absorption characteristics in a predetermined non-visible light wave region; and
a second film having discrete areas laminated upon preselected areas of the first film. said second film discrete areas having a substantially similar spectral response as that of the first film within the pre determined non-visible light wave region of the first film bandpass but for a sharp band absorption characteristic at a near single frequency. the first film including the portions discretely laminated with the second film further exhibiting a substantially uniform transmissivity and surface reflectance in the visible light wave region.
3. A card or the like suitable for use in personal and item identification comprising:
a first film having an optical bandpass transmission free from sharp band absorption characteristics in a predetermined portion of the infra-red region; and
a selectively apertured second film laminated upon the first film and having a substantially similar spectral response as that of the first film within the predetermined portion of the infra-red region of the first film bandpass but for a sharp band absorption characteristic at a near single frequency. the second film being formed from polymeric material having a carbonyl group and an associated ester group present in the polymer structure. the laminate including the apertured portions thereof further exhibiting a substantially uniform transmissivity and surface reflectance in the visible light wave region.
4. A card or the like suitable for use in personal and item identification comprising:
a first film having an optical bandpass transmission free from sharp band absorption characteristics in a predetermined non-visible light wave region; and
Ill
a selectively apertured second film laminated upon the first film and formed from the same material group includes a carbonyl group and an associated cster.
6. A card according to claim 4. wherein; the first film comprises polyvinyl chloride. and the second film comprises polyvinyl chloride vinyl acetate copolymer.
7. A card or the like suitable for use in personal and 5 item identification comprising:
a first polyvinyl chloride film; and
a selectively aperturcd second polyvinyl chloride film laminated on the first film and having carbonyl groups attached to the second film polymeric structures in a concentration of sufficient magnitude such that its infrared spectrum shows a distinctive single frequency absorption characteristic lying within the infrared transmission band of the first film.
said laminated structure exhibiting a substantially uniform transmissivity and surface reflectance in the visible light wave region
Claims (7)
1. A CARD OR THE LIKE SUITABLE FOR USE IN PERSONAL AND ITEM IDENTIFICATION COMPRISING: A FIRST FILM HAVING AN OPTICAL BANDPASS TRANSMISSION FREE FROM SHARP BAND ABSORPTION CHARACTERISTICS IN A PREDETERMINED NON-VISIBLE LIGHT WAVE REGION; AND A SELECTIVELY APERTURED SECOND FILM LAMINATED UPON THE FIRST FILM AND HAVING A SUBSTANTIALLY SIMILAR SPECTRAL RESPONSE AS THAT OF THE FIRST FILM WITHIN THE PREDETERMINED NON-VISIBLE LIGHT WAVE REGION OF THE FIRST FILM BANDPASS BUT FOR A SHARP BAND ABSORPTION CHARACTERISTIC AT A NEAR SINGLE FREQUENCY, THE LAMINATE INCLUDING THE APERTURED PORTIONS THEREOF FURTHER EXHIBITING A SUBSTANTIALLY UNIFORM TRANSMISSIVITY AND SURFACE REFLECTANCE IN THE VISIBLE LIGHT WAVE REGION.
2. A card or the like suitable for use in personal and item identification comprising: a first film having an optical bandpass transmission free from sharp band absorption characteristics in a predetermined non-visible light wave region; and a second film having discrete areas laminated upon preselected areas of the first film, said second film discrete areas having a substantially similar spectral response as that of the first film within the predetermined non-visible light wave region of the first film bandpass but for a sharp band absorption characteristic at a near single frequency, the first film including the portions discretely laminated with the second film further exhibiting a substantially uniform transmissivity and surface reflectance in the visible light wave region.
3. A card or the like suitable for use in personal and item identification comprising: a first film having an optical bandpass transmission free from sharp band absorption characteristics in a predetermined portion of the infra-red region; and a selectively apertured second film laminated upon the first film and having a substantially similar spectral response as that of the first film within the predetermined portion of the infra-red region of the first film bandpass but for a sharp band absorption characteristic at a near single frequency, the second film being formed from polymeric material having a carbonyl group and an associated ester group present in the polymer structure, the laminate including the apertured portions thereof further exhibiting a substantially uniform transmissivity and surface reflectance in the visible light wave region.
4. A card or the like suitable for use in personal and item identification comprising: a first film having an optical bandpass transmission free from sharp band absorption characteristics in a predetermined non-visible light wave region; and a selectively apertured second film laminated upon the first film and formed from the same material but for the presence of trace amounts of a chemical group in the structure of the second film, the second film exhibiting the same spectral response as the first film within the predetermined non-visible light wave region of the first film bandpass with the exception that the chemical group is sharply spectrally absorptive at a near single frequency, the laminate including the apertured pOrtions thereof further exhibiting a substantially uniform transmissivity and surface reflectance in the visible light wave region.
5. A card according to claim 4, wherein the chemical group includes a carbonyl group and an associated ester.
6. A card according to claim 4, wherein: the first film comprises polyvinyl chloride, and the second film comprises polyvinyl chloride vinyl acetate copolymer.
7. A card or the like suitable for use in personal and item identification comprising: a first polyvinyl chloride film; and a selectively apertured second polyvinyl chloride film laminated on the first film and having carbonyl groups attached to the second film polymeric structures in a concentration of sufficient magnitude such that its infra-red spectrum shows a distinctive single frequency absorption characteristic lying within the infrared transmission band of the first film, said laminated structure exhibiting a substantially uniform transmissivity and surface reflectance in the visible light wave region.
Priority Applications (1)
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US453138A US3919447A (en) | 1971-12-28 | 1974-03-20 | Spectral differential coded card |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US21320171A | 1971-12-28 | 1971-12-28 | |
US453138A US3919447A (en) | 1971-12-28 | 1974-03-20 | Spectral differential coded card |
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US453138A Expired - Lifetime US3919447A (en) | 1971-12-28 | 1974-03-20 | Spectral differential coded card |
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US4044231A (en) * | 1975-05-27 | 1977-08-23 | Addressograph Multigraph Corporation | Secure property document and method of manufacture |
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US4420174A (en) * | 1981-12-14 | 1983-12-13 | California Interface And Software Limited Partnership | Identification card bearing latent image perceptible in the presence of background light |
US4451068A (en) * | 1981-12-14 | 1984-05-29 | California Interface And Software Limited Partnership | Engraved image identification card with opaque cover layer |
US4570252A (en) * | 1982-08-09 | 1986-02-11 | Drexler Technology Corporation | Optical data retrieval system using multi-spectral light sources |
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US4626669A (en) * | 1983-12-28 | 1986-12-02 | Fairview Partners | Intercept system for intercepting stolen, lost and fraudulent cards |
US4745267A (en) * | 1983-12-28 | 1988-05-17 | Fairview Partners | Fraudulent card intercept system |
US4583766A (en) * | 1984-05-08 | 1986-04-22 | Kenneth R. Wessel | Secure badge for infrared badge reader and process for making same |
US4626445A (en) * | 1984-11-09 | 1986-12-02 | Canadian Patents And Development Limited | Method of manufacturing an optical interference authenticating device |
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