US4798852A - Ultraviolet curable coatings for optical glass fiber - Google Patents
Ultraviolet curable coatings for optical glass fiber Download PDFInfo
- Publication number
- US4798852A US4798852A US07/007,456 US745687A US4798852A US 4798852 A US4798852 A US 4798852A US 745687 A US745687 A US 745687A US 4798852 A US4798852 A US 4798852A
- Authority
- US
- United States
- Prior art keywords
- acrylate
- monohydric
- recited
- coating composition
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/81—Unsaturated isocyanates or isothiocyanates
- C08G18/8141—Unsaturated isocyanates or isothiocyanates masked
- C08G18/815—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen
- C08G18/8158—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen
- C08G18/8175—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen with esters of acrylic or alkylacrylic acid having only one group containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/104—Coating to obtain optical fibres
- C03C25/106—Single coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/104—Coating to obtain optical fibres
- C03C25/1065—Multiple coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
- C08G18/5024—Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/671—Unsaturated compounds having only one group containing active hydrogen
- C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
Description
______________________________________ Reactants Grams (equivalents) ______________________________________ A. Polyoxypropylene glycol 59.5 (0.1241) (molecular weight = 1000) B. 2-hydroxyethyl acrylate 73.9 (0.6364) C. Isophorone diisocyanate 162.8 (1.4648) D. amine-terminated poly- 104.3 (0.7043) oxypropylated trimethylol propane, mol. wt. = 440 E Dibutyltin dilaurate 0.40 F. Phenothiazine 0.11 G. Phenoxyethyl acrylate 208.5 ______________________________________
Claims (28)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/007,456 US4798852A (en) | 1985-10-29 | 1987-01-28 | Ultraviolet curable coatings for optical glass fiber |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US79246585A | 1985-10-29 | 1985-10-29 | |
US07/007,456 US4798852A (en) | 1985-10-29 | 1987-01-28 | Ultraviolet curable coatings for optical glass fiber |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US79246585A Continuation-In-Part | 1985-10-29 | 1985-10-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
US4798852A true US4798852A (en) | 1989-01-17 |
Family
ID=26677014
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US07/007,456 Expired - Fee Related US4798852A (en) | 1985-10-29 | 1987-01-28 | Ultraviolet curable coatings for optical glass fiber |
Country Status (1)
Country | Link |
---|---|
US (1) | US4798852A (en) |
Cited By (59)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4854666A (en) * | 1987-02-04 | 1989-08-08 | Mitsui Toatsu Chemicals, Incorporated | Photosetting resin composition |
WO1990003988A1 (en) * | 1988-10-03 | 1990-04-19 | Desoto, Inc. | Ultraviolet-curable blends of vinyl ether polyurethanes and unsaturated elastomers and coatings containing the same |
WO1992006846A1 (en) * | 1990-10-19 | 1992-04-30 | Dsm Desotech, Inc. | Curable liquid resin composition |
US5219896A (en) * | 1989-09-06 | 1993-06-15 | Stamicarbon, B.V. | Primary coatings for optical glass fibers including poly(carbonate-urethane) acrylates |
US5336563A (en) * | 1989-09-06 | 1994-08-09 | Dsm Desotech, Inc. | Primary coatings for optical glass fibers including polyether acrylates |
US5416880A (en) * | 1991-10-11 | 1995-05-16 | Zeneca Limited | Optical fibre coatings and method for producing same |
US5527835A (en) * | 1992-04-24 | 1996-06-18 | Borden, Inc. | Organic solvent and water resistant hydrolytically stable ultraviolet radiation curable coatings for optical fibers |
US5614269A (en) * | 1994-12-13 | 1997-03-25 | Interface, Inc. | Method of making a water absorbing article |
US5636307A (en) * | 1988-05-23 | 1997-06-03 | The United States Of America As Represented By The Secretary Of The Navy | Fiber optic microcable produced with radiation cured composite |
US5908873A (en) * | 1995-12-20 | 1999-06-01 | Borden Chemicals, Inc. | Peelable bonded ribbon matrix material; optical fiber bonded ribbon arrays containing same; and process for preparing said optical fiber bonded ribbon arrays |
US5980996A (en) * | 1994-12-13 | 1999-11-09 | Interface, Inc. | System and method for controlling water flow through ground with a geotextile comprising water absorbing material |
US6191187B1 (en) * | 1994-10-11 | 2001-02-20 | Dsm N.V. | Optical glass fiber coating compositions |
US6316516B1 (en) | 1999-04-29 | 2001-11-13 | Corning Incorporated | Coating composition for optical fibers |
US6353041B1 (en) | 1999-10-22 | 2002-03-05 | Kerr Corporation | Dental compositions |
WO2002072498A1 (en) | 2001-03-13 | 2002-09-19 | Corning Incorporated | Optical fiber coating compositions |
US6472454B1 (en) | 1999-10-22 | 2002-10-29 | Kerr Corporation | Endodontic dental compositions |
WO2002094730A2 (en) | 2000-11-29 | 2002-11-28 | Corning Incorporated | Optical fiber coupling agent |
US6531522B1 (en) | 1999-12-30 | 2003-03-11 | Corning Incorporated | Fast curing primary optical fiber coating |
US6534618B1 (en) | 2000-11-27 | 2003-03-18 | Corning Incorporated | Methods of drying optical fiber coatings |
WO2003027037A2 (en) | 2001-09-21 | 2003-04-03 | Corning Incorporated | Optical fiber coatings with pressure sensitive adhesive characteristics |
US20030077059A1 (en) * | 2001-03-13 | 2003-04-24 | Ching-Kee Chien | Optical fiber coating compositions |
US6559197B2 (en) | 2000-05-01 | 2003-05-06 | Corning Incorporated | Optical fiber coating |
US6563996B1 (en) | 1999-12-30 | 2003-05-13 | Corning Incorporated | Optical fibers prepared with a primary coating composition including a monomer with a pendant hydroxyl functional group |
US6599956B2 (en) | 2000-12-29 | 2003-07-29 | Dsm N.V. | Non-crystal-forming oligomers for use in radiation-curable fiber optice coatings |
US6602601B2 (en) * | 2000-12-22 | 2003-08-05 | Corning Incorporated | Optical fiber coating compositions |
US6635690B2 (en) | 2001-06-19 | 2003-10-21 | 3M Innovative Properties Company | Reactive oligomers |
US6638616B2 (en) * | 1999-10-15 | 2003-10-28 | Dsm N.V. | Radiation-curable compositions comprising oligomers having an alkyd backbone |
US6643440B2 (en) * | 2001-02-09 | 2003-11-04 | 3M Innovative Properties Company | Temperature range adjusted coated optical fibers |
WO2004031091A1 (en) | 2002-10-07 | 2004-04-15 | Pirelli & C. S.P.A. | Optical fiber with cured polymeric coating |
US20050013573A1 (en) * | 2003-07-18 | 2005-01-20 | Lochkovic Gregory A. | Fiber optic articles, assemblies, and cables having optical waveguides |
US20050031283A1 (en) * | 2003-07-18 | 2005-02-10 | Fabian Michelle D. | Optical fiber coating system and coated optical fiber |
US20050215655A1 (en) * | 2004-03-29 | 2005-09-29 | Bilodeau Wayne L | Anaerobic pressure sensitive adhesive |
US20050214497A1 (en) * | 2004-03-29 | 2005-09-29 | Bilodeau Wayne L | Anaerobic activator film and labels made therefrom |
US20050230960A1 (en) * | 2004-03-29 | 2005-10-20 | Bilodeau Wayne L | Security label, secured article and method for making the label and article |
US20050254227A1 (en) * | 2004-05-13 | 2005-11-17 | Bilodeau Wayne L | Chemiluminescent light article |
US20070078247A1 (en) * | 2005-09-30 | 2007-04-05 | Winningham Michael J | Fast curing primary optical fiber coatings |
US20070117952A1 (en) * | 2003-09-16 | 2007-05-24 | Acushnet Company | Castable golf ball components using acrylate functional resins |
US20110038593A1 (en) * | 2009-08-12 | 2011-02-17 | Ching-Kee Chien | Optical Fiber Containing Multi-Layered Coating System |
WO2011156309A2 (en) | 2010-06-07 | 2011-12-15 | Corning Incorporated | Optical fiber with photoacid coating |
US8792761B2 (en) | 2009-04-23 | 2014-07-29 | Prysmian S.P.A. | Optical fiber with single coating |
WO2014168739A1 (en) | 2013-03-28 | 2014-10-16 | Corning Incorporated | Large effective area fiber with low bending losses |
WO2014172143A1 (en) | 2013-04-15 | 2014-10-23 | Corning Incorporated | Low diameter optical fiber |
WO2014179404A1 (en) | 2013-05-02 | 2014-11-06 | Corning Incorporated | Optical fiber with large mode field diameter and low microbending losses |
WO2015038728A1 (en) | 2013-09-12 | 2015-03-19 | Corning Incorporated | Fiber coatings with low young's modulus and high tear strength |
US9244221B1 (en) | 2013-12-10 | 2016-01-26 | Corning Incorporated | Low modulus primary coatings for optical fibers |
WO2018089290A1 (en) | 2016-11-08 | 2018-05-17 | Corning Incorporated | Fiber coatings with low modulus and high critical stress |
US10350861B2 (en) | 2015-07-31 | 2019-07-16 | Corning Incorporated | Laminate structures with enhanced damping properties |
US10400055B2 (en) | 2016-07-11 | 2019-09-03 | 3M Innovative Properties Company | Polymeric material and methods of making using controlled radical initiators |
WO2019212801A1 (en) | 2018-04-30 | 2019-11-07 | Corning Incorporated | Small diameter low attenuation optical fiber |
WO2019212796A1 (en) | 2018-04-30 | 2019-11-07 | Corning Incorporated | Small diameter low attenuation optical fiber |
WO2019212800A1 (en) | 2018-04-30 | 2019-11-07 | Corning Incorporated | Small outer diameter low attenuation optical fiber |
WO2020069053A1 (en) | 2018-09-28 | 2020-04-02 | Corning Research & Development Corporation | Small diameter fiber optic cables having low-friction cable jackets and optical fibers with reduced cladding and coating diameters |
US20210103092A1 (en) * | 2019-10-08 | 2021-04-08 | Corning Incorporated | Primary coating compositions with improved microbending performance |
EP3719043A4 (en) * | 2017-11-28 | 2021-08-25 | Mitsui Chemicals, Inc. | (meth)acrylate, monomer composition, dental material obtained from said composition, and production method thereof |
US11181685B2 (en) | 2020-01-07 | 2021-11-23 | Corning Incorporated | Reduced radius optical fiber with high mechanical reliability |
US11194107B2 (en) | 2019-08-20 | 2021-12-07 | Corning Incorporated | High-density FAUs and optical interconnection devices employing small diameter low attenuation optical fiber |
CN115948093A (en) * | 2022-11-18 | 2023-04-11 | 广东希贵光固化材料有限公司 | UVLED white primer for aluminous gusset plate and application thereof |
US11675122B2 (en) | 2019-01-16 | 2023-06-13 | Corning Incorporated | Optical fiber cable with high fiber count |
US11733453B2 (en) | 2020-05-12 | 2023-08-22 | Corning Incorporated | Reduced diameter single mode optical fibers with high mechanical reliability |
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-
1987
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Cited By (94)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4854666A (en) * | 1987-02-04 | 1989-08-08 | Mitsui Toatsu Chemicals, Incorporated | Photosetting resin composition |
US5636307A (en) * | 1988-05-23 | 1997-06-03 | The United States Of America As Represented By The Secretary Of The Navy | Fiber optic microcable produced with radiation cured composite |
WO1990003988A1 (en) * | 1988-10-03 | 1990-04-19 | Desoto, Inc. | Ultraviolet-curable blends of vinyl ether polyurethanes and unsaturated elastomers and coatings containing the same |
US5219896A (en) * | 1989-09-06 | 1993-06-15 | Stamicarbon, B.V. | Primary coatings for optical glass fibers including poly(carbonate-urethane) acrylates |
US5336563A (en) * | 1989-09-06 | 1994-08-09 | Dsm Desotech, Inc. | Primary coatings for optical glass fibers including polyether acrylates |
WO1992006846A1 (en) * | 1990-10-19 | 1992-04-30 | Dsm Desotech, Inc. | Curable liquid resin composition |
US5416880A (en) * | 1991-10-11 | 1995-05-16 | Zeneca Limited | Optical fibre coatings and method for producing same |
US5527835A (en) * | 1992-04-24 | 1996-06-18 | Borden, Inc. | Organic solvent and water resistant hydrolytically stable ultraviolet radiation curable coatings for optical fibers |
US5538791A (en) * | 1992-04-24 | 1996-07-23 | Borden, Inc. | Organic solvent and water resistant, thermally, oxidatively and hydrolytically stable radiation-curable coatings for optical fibers, optical fibers coated therewith and processes for making same |
US5587403A (en) * | 1992-04-24 | 1996-12-24 | Borden, Inc. | Organic solvent & water resistant hydrolytically stable ultraviolet radiation curable coatings for optical fibers |
US6191187B1 (en) * | 1994-10-11 | 2001-02-20 | Dsm N.V. | Optical glass fiber coating compositions |
US5614269A (en) * | 1994-12-13 | 1997-03-25 | Interface, Inc. | Method of making a water absorbing article |
US5980996A (en) * | 1994-12-13 | 1999-11-09 | Interface, Inc. | System and method for controlling water flow through ground with a geotextile comprising water absorbing material |
US5756159A (en) * | 1994-12-13 | 1998-05-26 | Interface, Inc. | Water absorbing compositions and methods of making and use thereof |
US5908873A (en) * | 1995-12-20 | 1999-06-01 | Borden Chemicals, Inc. | Peelable bonded ribbon matrix material; optical fiber bonded ribbon arrays containing same; and process for preparing said optical fiber bonded ribbon arrays |
US6455607B1 (en) | 1995-12-20 | 2002-09-24 | Borden Chemical, Inc. | Peelable bonded ribbon matrix material; optical fiber bonded ribbon arrays containing same; and process for preparing said optical fiber bonded ribbon arrays |
US6316516B1 (en) | 1999-04-29 | 2001-11-13 | Corning Incorporated | Coating composition for optical fibers |
US6638616B2 (en) * | 1999-10-15 | 2003-10-28 | Dsm N.V. | Radiation-curable compositions comprising oligomers having an alkyd backbone |
US7135229B2 (en) | 1999-10-15 | 2006-11-14 | Dsm Ip Assets B.V. | Radiation-curable coating composition |
US20040048946A1 (en) * | 1999-10-15 | 2004-03-11 | Anthony Tortorello | Radiation-curable coating composition |
US6353041B1 (en) | 1999-10-22 | 2002-03-05 | Kerr Corporation | Dental compositions |
US6472454B1 (en) | 1999-10-22 | 2002-10-29 | Kerr Corporation | Endodontic dental compositions |
US6531522B1 (en) | 1999-12-30 | 2003-03-11 | Corning Incorporated | Fast curing primary optical fiber coating |
US6563996B1 (en) | 1999-12-30 | 2003-05-13 | Corning Incorporated | Optical fibers prepared with a primary coating composition including a monomer with a pendant hydroxyl functional group |
US6559197B2 (en) | 2000-05-01 | 2003-05-06 | Corning Incorporated | Optical fiber coating |
US6534618B1 (en) | 2000-11-27 | 2003-03-18 | Corning Incorporated | Methods of drying optical fiber coatings |
US6553169B2 (en) | 2000-11-29 | 2003-04-22 | Corning Incorporated | Optical fiber coating compositions and coated optical fibers |
WO2002094730A2 (en) | 2000-11-29 | 2002-11-28 | Corning Incorporated | Optical fiber coupling agent |
US6602601B2 (en) * | 2000-12-22 | 2003-08-05 | Corning Incorporated | Optical fiber coating compositions |
US6599956B2 (en) | 2000-12-29 | 2003-07-29 | Dsm N.V. | Non-crystal-forming oligomers for use in radiation-curable fiber optice coatings |
US6643440B2 (en) * | 2001-02-09 | 2003-11-04 | 3M Innovative Properties Company | Temperature range adjusted coated optical fibers |
US20060115649A1 (en) * | 2001-03-13 | 2006-06-01 | Ching-Kee Chien | Optical fiber coating compositions |
US20030077059A1 (en) * | 2001-03-13 | 2003-04-24 | Ching-Kee Chien | Optical fiber coating compositions |
US7676130B2 (en) | 2001-03-13 | 2010-03-09 | Corning Incorporated | Optical fiber coating compositions |
WO2002072498A1 (en) | 2001-03-13 | 2002-09-19 | Corning Incorporated | Optical fiber coating compositions |
US7015286B2 (en) | 2001-06-19 | 2006-03-21 | 3M Innovative Properties Company | Reactive oligomers |
US20030212210A1 (en) * | 2001-06-19 | 2003-11-13 | 3M Innovative Properties Company | Reactive oligomers |
US20030216519A1 (en) * | 2001-06-19 | 2003-11-20 | 3M Innovative Properties Company | Reactive oligomers |
US6635690B2 (en) | 2001-06-19 | 2003-10-21 | 3M Innovative Properties Company | Reactive oligomers |
US7074858B2 (en) | 2001-06-19 | 2006-07-11 | Heilmann Steven M | Reactive oligomers |
WO2003027037A2 (en) | 2001-09-21 | 2003-04-03 | Corning Incorporated | Optical fiber coatings with pressure sensitive adhesive characteristics |
WO2004031091A1 (en) | 2002-10-07 | 2004-04-15 | Pirelli & C. S.P.A. | Optical fiber with cured polymeric coating |
US7764855B2 (en) | 2002-10-07 | 2010-07-27 | Prysmian Cavi E Sistemi Energia S.R.L. | Optical fiber with cured polymeric coating |
US7050688B2 (en) | 2003-07-18 | 2006-05-23 | Corning Cable Systems Llc | Fiber optic articles, assemblies, and cables having optical waveguides |
US7715675B2 (en) | 2003-07-18 | 2010-05-11 | Corning Incorporated | Optical fiber coating system and coated optical fiber |
US20050013573A1 (en) * | 2003-07-18 | 2005-01-20 | Lochkovic Gregory A. | Fiber optic articles, assemblies, and cables having optical waveguides |
US20050031283A1 (en) * | 2003-07-18 | 2005-02-10 | Fabian Michelle D. | Optical fiber coating system and coated optical fiber |
US20110165967A1 (en) * | 2003-09-16 | 2011-07-07 | Acushnet Company | Castable golf ball components using acrylate functional resins |
US7906601B2 (en) | 2003-09-16 | 2011-03-15 | Acushnet Company | Castable golf ball components using acrylate functional resins |
US8354487B2 (en) | 2003-09-16 | 2013-01-15 | Acushnet Company | Castable golf ball components using acrylate functional resins |
US20070117952A1 (en) * | 2003-09-16 | 2007-05-24 | Acushnet Company | Castable golf ball components using acrylate functional resins |
US7572873B2 (en) * | 2003-09-16 | 2009-08-11 | Acushnet Company | Castable golf ball components using acrylate functional resins |
US20050214497A1 (en) * | 2004-03-29 | 2005-09-29 | Bilodeau Wayne L | Anaerobic activator film and labels made therefrom |
US20050215655A1 (en) * | 2004-03-29 | 2005-09-29 | Bilodeau Wayne L | Anaerobic pressure sensitive adhesive |
US20050230960A1 (en) * | 2004-03-29 | 2005-10-20 | Bilodeau Wayne L | Security label, secured article and method for making the label and article |
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