US9598278B2 - Method of making a suspended membrane device - Google Patents
Method of making a suspended membrane device Download PDFInfo
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- US9598278B2 US9598278B2 US14/679,906 US201514679906A US9598278B2 US 9598278 B2 US9598278 B2 US 9598278B2 US 201514679906 A US201514679906 A US 201514679906A US 9598278 B2 US9598278 B2 US 9598278B2
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- membrane
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81C—PROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
- B81C1/00—Manufacture or treatment of devices or systems in or on a substrate
- B81C1/00015—Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems
- B81C1/00134—Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems comprising flexible or deformable structures
- B81C1/00158—Diaphragms, membranes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81B—MICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
- B81B3/00—Devices comprising flexible or deformable elements, e.g. comprising elastic tongues or membranes
- B81B3/0018—Structures acting upon the moving or flexible element for transforming energy into mechanical movement or vice versa, i.e. actuators, sensors, generators
- B81B3/0021—Transducers for transforming electrical into mechanical energy or vice versa
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81B—MICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
- B81B2203/00—Basic microelectromechanical structures
- B81B2203/01—Suspended structures, i.e. structures allowing a movement
- B81B2203/0127—Diaphragms, i.e. structures separating two media that can control the passage from one medium to another; Membranes, i.e. diaphragms with filtering function
Abstract
The present disclosure is directed to a device that includes a substrate and a sensor formed on the substrate. The sensor includes a chamber formed from a plurality of integrated cavities, a membrane above the substrate, the membrane having a plurality of openings, each opening positioned above one of the cavities, and a plurality of diamond shaped anchors positioned between the membrane and the substrate, the anchors positioned between each of the cavities. A center of each opening is also a center of one of the cavities.
Description
Technical Field
The present disclosure is directed to a method of forming a sensor having a suspended membrane.
Description of the Related Art
Mobile computing devices such as smart phones and tablets include embedded electronic sensors such as, temperature, humidity, and pressure sensors. These sensors are being included to offer consumers or program developers features that entail sensing, monitoring, or controlling local environmental conditions. Providing additional environmental sensors within smart phones, tablet computers will encourage developers to create applications that provide or utilize the information about the temperature, humidity, and pressure of an environment.
Some existing products contain miniature environmental sensors, such as electronic climate control devices or thermostats. Such sensors can activate furnaces and air conditioners for feedback control of air temperature and humidity. Electronic weather stations also rely on internal temperature sensors, barometric pressure sensors, and humidity sensors. These miniature environmental sensors are fabricated separately, on separate substrates (separate die) from one another, or the sensors are built on one substrate and associated circuitry for signal processing and control is fabricated on a separate die.
These sensors are typically formed using silicon based free standing structures, such as structures formed by forming epitaxial layers of silicon and removing portions of the epitaxial layers for form the structures. Alternatively, several wafers are stacked, such that one is a base or support substrate and another, on top of the base, is etched to form the free standing structures. A membrane is supported by the free standing structures and separated from the base by a distance. Due to process limitations it is difficult to form free standing structures and a membrane that is separated from the base by more than four microns. The processes used to form these free standing structures are not compatible with forming integrated circuits on a same die as the free standing structures. Typically, the free standing structure is formed in one die and the integrated circuits are formed in another. The two die are bonded together such that the features are not on a single die. This leads to larger packages and a larger foot print on the printed circuit board of a device that incorporates such a sensor.
The present disclosure is directed to forming a sensor having a chamber of increased dimensions that permit a distance between a top electrode and a bottom electrode to be increased. A membrane is supported by a plurality of consistently spaced and shaped anchors. The membrane includes a plurality of openings through which portions of a support layer are removed in order to form the chamber. Separate cavities are formed in the support layer as the etch is preformed and as more material is removed, eventually the cavities are integrated with each other to form the chamber. A plurality of anchors remain to support the larger chamber.
The foregoing and other features and advantages of the present disclosure will be more readily appreciated as the same become better understood from the following detailed description when taken in conjunction with the accompanying drawings.
In the following description, certain specific details are set forth in order to provide a thorough understanding of various embodiments of the disclosure. However, one skilled in the art will understand that the disclosure may be practiced without these specific details. In some instances, well-known structures associated with semiconductor manufacturing have not been described in detail to avoid obscuring the descriptions of the embodiments of the present disclosure.
Unless the context requires otherwise, throughout the specification and claims that follow, the word “comprise” and variations thereof, such as “comprises” and “comprising,” are to be construed in an open, inclusive sense, that is, as “including, but not limited to.”
Reference throughout this specification to “one embodiment” or “an embodiment” means that a particular feature, structure or characteristic described in connection with the embodiment is included in at least one embodiment. Thus, the appearances of the phrases “in one embodiment” or “in an embodiment” in various places throughout this specification are not necessarily all referring to the same embodiment. Furthermore, the particular features, structures, or characteristics may be combined in any suitable manner in one or more embodiments.
In the drawings, identical reference numbers identify similar features or elements. The size and relative positions of features in the drawings are not necessarily drawn to scale, but in many instances, do reflect actual scale and relative size between the components.
The sensors 100 may be one of a pressure sensor, a humidity sensor, a temperature sensor, an infrared sensor, or another type of sensor having a chamber. The sensors 100 are configured to include a membrane 128 formed between the bottom electrode 104 and the top electrode 108. The sensors 100 also include a chamber 144 that is configured to act as a capacitive dielectric between two capacitive plates, the top electrode 108 and the bottom electrode 104. For example, if the sensor is a pressure sensor, the membrane will move towards or away from the substrate in response to a change in pressure. An amount of movement of the membrane can be detected by a change in capacitance between the top and bottom electrode. Examples of types of sensors that could be formed using these chambers are described in the following co-owned and co-pending applications, U.S. patent application Ser. Nos. 13/853,886, 13/853,732, 13/853,801, and 13/853,805, which all have inventors in common.
The top electrode 108 is a conductive mesh 110 that includes a plurality of openings 122 thorough the conductive mesh 110 and the membrane 128. The openings 122 expose the chamber 144 and the bottom electrode 104 to ambient environmental conditions, such that the sensor 100 can detect a change in the environmental conditions.
In this embodiment, there are three sensors, each having a separate top electrode 108, where each is formed as a conductive mesh 110. Each of the top electrodes 108 are coupled to a contact pad 112 through an electrical interconnect 114. There are separate electrical interconnects 116 that couple the bottom electrode 104 to additional contact pads 118.
The sensor and fabrication method described in this disclosure can be used to form a single sensor or a plurality of sensors on a single substrate. In addition, the sensors described can be easily incorporated on a substrate that also includes integrated circuits, such as active and passive semiconductor components. For example, instead of having an application specific integrated circuit (ASIC) formed on a separate die, the transistors and other components used for detecting, analyzing, and transmitting signals and controlling the sensor can be incorporated in the substrate prior to formation of the sensor.
The conductive mesh 110 forms a plurality of intersecting rows 130 and columns 132 on top of the membrane, where the openings 122 are centrally positioned between intersections of the rows 130 and columns 132. A width 134 of the rows 130 and the columns 132 is smaller than a width 136 of the membrane 128. The difference in the widths forms a shelf or step down from the edge of the conductive mesh 110 to the membrane 128, see FIG. 3 . The width 136 of the membrane 128 extends from a right-most edge 124 d of a first opening 122 to a left-most edge 124 c of a second opening 122, that is adjacent to the first opening.
The plurality of anchors 138 are positioned beneath intersections of the rows 130 and columns 132. The anchors 138 are evenly spaced, such that a center 142 a of each anchor 138 is separated from adjacent centers 142 b, 142 c by a distance 140. Each anchor 138 is diamond shaped from a top down view. The diamond shape is formed as the plurality of cavities 146 are formed by etching through the openings 122, where boundaries of each cavity blend with boundaries of adjacent cavities. The plurality of cavities 146 are integrated together to form the chamber 144. The membrane 128 is suspended above the chamber 144.
The cavities having a square shape with rounded corners, see the dashed line representing a cavity 146. Boundaries of each cavity correspond to one face of fourth adjacent anchors and each cavity shares a top, right, bottom, and left boundary with adjacent cavities.
The arrangement of the anchors 138 and the openings 122 provide a large supported area, such that the membrane 128 and the chamber 144 span a large area. For example, the area of the chamber and the capacitive plates, the bottom and top electrodes, may be 500 microns by 500 microns. Increasing the area of the capacitive plates can increase the sensitivity of the sensor. The support layer is removed in a controlled process that forms the semi-suspended membrane 128; semi-suspended because the anchors are evenly spaced at regular intervals beneath the membrane. In addition, a height 123 of the chamber 144 may be greater than 4 microns as a result of the intervals of support provided by the anchors 138.
A second, intermediate layer, is the conductive mesh 110 of the rows 130 and columns 132 is formed on the membrane 128. In this embodiment, the conductive mesh 110 includes a barrier layer 150 on the membrane 128 and a metal layer 152 on the barrier layer 150. The barrier layer 150 may be titanium tungsten, titanium nitride, or other material with sufficient barrier properties. The metal layer 152 may be gold, aluminum, or other suitable conductive material. In some embodiments, the conductive mesh 110 may only be a single metal layer 152. The metal layer 152 may be 1000 Angstroms in one embodiment. Because of under etching when the conductive mesh is formed, the barrier layer may have a smaller width than the metal top layer.
A third, top layer, is a passivation layer 154. The passivation layer 154 covers a top of the sensor 100 and protects the layers from external factors. Silicon nitride may be utilized as the passivation layer 154.
The bottom electrode 104 is formed from a conductive layer 106 formed on a surface of the substrate 102. In some embodiments, a dielectric layer 105 is formed on the substrate 102 to isolate the bottom electrode 104 from the substrate. The dielectric layer 105 physically and electrically separates the conductive layer 106 from the substrate 102. For example, if the substrate 102 includes a plurality of transistors or other integrated circuit components 131, the dielectric layer 105 may be included to sufficiently isolate the integrated circuit components from the bottom electrode 104. The dielectric layer 105 may be a thick layer of silicon dioxide. If glass is used for the substrate, the dielectric layer 105 may be omitted.
In this view, the plurality of cavities 146 are blended together such that the chamber 144 is one open space. However, as can be seen in FIG. 4 , the cavities 146 are separated from each other by the anchors 138. The anchors provide the support to make the membrane 128 with a large surface area.
The anchors 138 and the chamber 144 have the same height 123 in a rest state. For example, the height 123 may be greater than 4 microns. During use, the membrane 128 can move towards and away from the bottom electrode 104, changing the height of the cavities 146.
The rows 130 and columns 132 of the conductive mesh 110 intersect on top of each of the anchors 138. The anchors support 138 the conductive mesh, while the membrane extends away from the anchors over the cavities 146. The width of the rows and columns is less than the width of the membrane such that the membrane is suspended above the bottom electrode 104 while the conductive mesh 110 is supported.
The differences in the widths of the conductive mesh and the membrane form steps or shelves 139, such that a top surface of the conductive mesh is positioned further away from the bottom electrode than a top surface of the membrane. The steps 139 are associated with portions of the membrane 128 that are only covered by the passivation layer 154.
The openings 164 are positioned at a center 166 of a plurality of cavities 168 formed between the membrane 160 and the substrate 162. Together the plurality of cavities 168 form a larger chamber 170. A plurality of anchors 172 are positioned beneath the membrane, separating the membrane from the substrate. The anchors are spaced at intervals in the chamber 170.
In this embodiment, the openings are generally square, however, in other embodiments, the openings may have a different shape, such as a circle. The shape of the opening affects the shape of the anchors 172. In particular, the anchors 172 are diamond shaped in this embodiment because the openings are square and because an isotropic etch was used to remove excess portions of a support layer 176. The support layer 176 starts as a thick layer of material completely separating the substrate 162 from the membrane 160. After the openings 164 are formed, an isotropic etch is performed to remove portions of the support layer 176, leaving the anchors 172.
In this view, the anchors 172 are show to be in dashed lines because the membrane 160 is on top of the anchors. A boundary 174 of the membrane 160 is spaced from an edge 208 of the chamber 144 by a distance 210. This boundary region 178 is a remaining portion of the support layer 176, covered by the membrane 160. This boundary region that remains after the etch that forms the cavities. The boundary region 178 can be seen more clearly in FIGS. 11-16 .
The membrane extends across the top of every anchor 172 and extends out to the boundary 174 of the membrane 160. Each cavity 168 is formed by etching the support layer 176 through the opening 164. An isotropic etch is performed through each opening 164 in order to form consistently shaped cavities 168. As the etchant removes the support layer 176 through each opening 164, a width 180 continues to expand to a larger width 182. As the width 180 expands to the larger width 182, adjacent cavities 168 become integrated such that there are openings between adjacent ones of the anchors 172 and the chamber 170 is formed.
In an embodiment that does include the conductive mesh 184, the openings 164 through the membrane will not be formed until after the conductive mesh is formed. This will be described in further detail below with respect to FIGS. 11-16 . The conductive mesh 184 is arranged in a plurality of rows 194 and columns 196 that intersect on top of the anchors 172. The anchors 172 are support structures that maintain the membrane 160 at a consistent distance from the substrate 162 in a rest state.
In FIG. 11 , transistors 212 are formed in the substrate 162. In this embodiment, the transistors are formed on and in a first surface of a semiconductor wafer 214. Each transistor 212 includes a gate 216 and source/drain regions 218. A first interlevel dielectric 220 is formed on the gates 216 and on the wafer 214. Vias are formed through the first interlevel dielectric 220 and filed with a conductive material to form conductive plugs 222.
A first metal layer 224 is formed on the first dielectric 220 and electrically couples the conductive plugs 222. A second interlevel dielectric 226 is formed on the first metal layer 224. Vias are formed through the second interlevel dielectric 226 and filed with a conductive material to form conductive plugs 228. A second metal layer 230 is formed on the second interlevel dielectric 226 and coupled to the conductive plug 228. A third interlevel dielectric 232 is formed on the second metal layer 230.
The third interlevel dielectric 232 may be thicker than the first and second interlevel dielectrics in order to sufficiently isolate the transistors 212 and metal layers from the chamber 170. After the active circuit elements are formed, the support layer 176 is formed. The support layer may be 4 microns or more in thickness. In one embodiment, the support layer 176 is polyimide.
Polyimide has properties that allow it to be manipulated and processed at temperatures that do not harm active elements, such as the transistors 212. The polyimide is deposited, spun, and then cured. After the cure, the polyimide may have between 2 and 8 microns in thickness, the space between the membrane and the substrate. A second polyimide may be included to make the thickness of the polyimide greater, such as between 12 and 16 microns.
The membrane 160 is formed on top of the support layer 176. In one embodiment, the membrane layer is silicon nitride. Additional materials may be used to form the membrane in the support layer by one of ordinary skill in the art.
A conductive layer 198 is formed on top of the membrane 160 before any openings are formed in the membrane 160. The membrane may be transparent, which allows the anchors below the membrane to be visible from a top down view. In this embodiment, only a single conductive layer is presented, however, the conductive mesh may be formed of a plurality of conductive layers.
A mask 204 is formed on the conductive layer 198 to define the conductive mesh 184. An etching step is performed to remove excess portions of the conductive layer 198, so that the conductive mesh 184 remains. As can be seen in FIG. 12 , each row 194 has a width 186. As can be viewed in FIG. 10 , the conductive mesh has extensions that are similar to bridges that extend between anchors, once the anchors and cavities have been formed.
In FIG. 13 , a dielectric layer 206 is formed overlying the conductive mesh 184 and the membrane 160. The dielectric layer 206 may be silicon dioxide, silicon nitride, or any other suitable material for passivating or protecting the different layers. Another mask 208 is formed overlying the dielectric layer 206 in order to form the openings 164 a, 164 b, 164 c. Subsequently, an etch is performed to remove excess portions of the dielectric layer 206 and the membrane 160, see FIG. 14 . This forms the plurality of openings 164. Each opening has the width 180, as was shown in FIG. 9 , while the membrane has the width 188 and the conductive mesh has the width 186.
In FIG. 15 , an etch is performed through the openings 164 a, 164 b, 164 c the membrane to remove excess portions of the support layer 176 such that the anchors remain. FIG. 15 shows an intermediate step in the process where the etch is not yet complete. FIG. 16 shows the sensor once the etch has been completed. None of the anchors are visible in FIG. 16 because of where the cross-section line is positioned in FIG. 10 .
In one embodiment, a O2 Plasma etch may be used to remove portions of the support layer through the openings in the membrane. During the etch, process conditions of RF 900 Watt, a pressure of 1200 mT, with O2 2000 sccm, and N2O 100 sccm are beneficial. An example of an etch machine that may be configured to perform this process is an IPC Gasonics L3510.
This process can be performed where the temperature in the chamber is kept at or below 200 degrees Celsius. Maintaining this temperature profile is beneficial in that the polyimide structural layer is removed in a controlled manner. In particular, oxygen radicals produced by a microwave generator react with the polyimide to form a gaseous by-product. This chemical reaction in controlled by the chamber pressure. The polyimide is removed by an isotropic etch until the anchors are formed.
Above 200 degrees Celsius polyimide removal can be too aggressive and can cause the remaining polyimide to be deformed. The dimensions and consistency of the anchor shape becomes more difficult as the temperature exceeds 200 degrees Celsius. At 100 degrees Celsius, the diamond shaped anchors can be formed consistently and accurately, however, the time to form the structures is significantly longer than a process at 200 degrees Celsius.
The various embodiments described above can be combined to provide further embodiments. These and other changes can be made to the embodiments in light of the above-detailed description. In general, in the following claims, the terms used should not be construed to limit the claims to the specific embodiments disclosed in the specification and the claims, but should be construed to include all possible embodiments along with the full scope of equivalents to which such claims are entitled. Accordingly, the claims are not limited by the disclosure.
Claims (20)
1. A method, comprising:
forming a support layer on a substrate;
forming a membrane layer on the support layer;
forming a plurality of openings in the membrane layer;
forming a single, contiguous chamber having a plurality of integrated cavities, each of the plurality of openings positioned above and aligned with one of the plurality of integrated cavities; and
forming a plurality of anchors in the single, contiguous chamber by removing portions of the support layer below the openings in the membrane layer.
2. The method of claim 1 , further comprising:
forming a first electrode on the substrate between the support layer and the substrate;
forming a second electrode on the membrane layer, the membrane layer being between the first electrode and the second electrode.
3. The method of claim 2 wherein the contiguous chamber and the membrane layer separate the first electrode and the second electrode.
4. The method of claim 2 , further comprising forming the second electrode as a conductive mesh having intersecting rows and columns.
5. The method of claim 4 , further comprising forming an intersection between the rows and columns above each anchor.
6. The method of claim 1 wherein each integrated cavity is centered around one of the openings and having a square shape with rounded corners, as seen from a top down view.
7. The method of claim 1 wherein the anchors are diamond shaped.
8. A method, comprising:
forming a bottom electrode on a substrate;
forming a support layer on the bottom electrode;
forming a sensor layer overlying the support layer, the sensor layer including a thin film membrane;
forming a top electrode as a conductive mesh having openings therein, the openings exposing areas of the thin film membrane; and
forming a contiguous chamber having a plurality of integrated cavities by etching the support layer through the openings for a selected time, each of the openings positioned above and aligned with one of the plurality of integrated cavities, the etching continuing until the support layer is removed sufficient to form an array of supporting anchors that suspend the thin film membrane.
9. The method of claim 8 wherein the thin film membrane is made of silicon nitride.
10. The method of claim 8 wherein forming the support layer further includes
covering the bottom electrode with a photo-patternable material;
exposing the photo-patternable material to light; and
curing the photo-patternable material.
11. The method of claim 8 wherein the support layer is made of polyimide.
12. The method of claim 8 wherein the etching entails etching the support layer in a low-temperature process, below 200 C.
13. The method of claim 8 wherein the support layer has a height within the range of 2.0-8.0 μm.
14. The method of claim 8 wherein the substrate includes an integrated circuit.
15. The method of claim 8 wherein the anchors contact a total surface area of the thin film membrane that is within the range of 5-15%.
16. The method of claim 8 wherein the etching uses an isotropic plasma etching process that produces anchors having curved sidewalls.
17. The method of claim 16 wherein the plasma etching process accesses the support layer through the openings in the exposed areas of the thin film membrane.
18. The method of claim 8 , further comprising:
forming a passivation layer covering the top electrode; and
forming openings in the passivation layer.
19. The method of claim 18 wherein the openings in the exposed areas of the thin film membrane are aligned with the openings in the passivation layer.
20. The method of claim 8 wherein the suspended thin film membrane is a flexible membrane suitable for use as a pressure sensor.
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US13/907,708 US9000542B2 (en) | 2013-05-31 | 2013-05-31 | Suspended membrane device |
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US9176089B2 (en) | 2013-03-29 | 2015-11-03 | Stmicroelectronics Pte Ltd. | Integrated multi-sensor module |
US9810653B2 (en) | 2014-07-17 | 2017-11-07 | Stmicroelectronics Pte Ltd | Integrated SMO gas sensor module |
US10254261B2 (en) | 2016-07-18 | 2019-04-09 | Stmicroelectronics Pte Ltd | Integrated air quality sensor that detects multiple gas species |
US10429330B2 (en) | 2016-07-18 | 2019-10-01 | Stmicroelectronics Pte Ltd | Gas analyzer that detects gases, humidity, and temperature |
US10557812B2 (en) | 2016-12-01 | 2020-02-11 | Stmicroelectronics Pte Ltd | Gas sensors |
US11248976B2 (en) | 2017-11-17 | 2022-02-15 | Sciosense B.V. | Capacitive pressure sensors and other devices having a suspended membrane and having rounded corners at an anchor edge |
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