USRE43004E1 - High melt strength polymers and method of making same - Google Patents
High melt strength polymers and method of making same Download PDFInfo
- Publication number
- USRE43004E1 USRE43004E1 US12/604,940 US60494009A USRE43004E US RE43004 E1 USRE43004 E1 US RE43004E1 US 60494009 A US60494009 A US 60494009A US RE43004 E USRE43004 E US RE43004E
- Authority
- US
- United States
- Prior art keywords
- silanetitanium
- dimethyl
- composition
- molecular weight
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime, expires
Links
- 0 Cc1c(C)c(C)c(C[Y]C(C)C)c1C Chemical compound Cc1c(C)c(C)c(C[Y]C(C)C)c1C 0.000 description 7
- VNWKTOKETHGBQD-UHFFFAOYSA-N C Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- IKUQYOZKWCKXFD-UHFFFAOYSA-N C.C.C.C.[KH].[KH].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K] Chemical compound C.C.C.C.[KH].[KH].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K].[K][K] IKUQYOZKWCKXFD-UHFFFAOYSA-N 0.000 description 1
- NFBVPUPIVQCGKL-UHFFFAOYSA-N CC.CCCCC1=CC=C([Si](Cl)(Cl)C2=CC=C(CCCC)C=C2)C=C1.CCCCC1=CC=C([Si](NC(C)(C)C)(C2=CC=C(CCCC)C=C2)C2C=C(N3CC4=CC=CC=C4C3)C3=C2C=CC=C3)C=C1 Chemical compound CC.CCCCC1=CC=C([Si](Cl)(Cl)C2=CC=C(CCCC)C=C2)C=C1.CCCCC1=CC=C([Si](NC(C)(C)C)(C2=CC=C(CCCC)C=C2)C2C=C(N3CC4=CC=CC=C4C3)C3=C2C=CC=C3)C=C1 NFBVPUPIVQCGKL-UHFFFAOYSA-N 0.000 description 1
- IFZBYMFQVMLWMB-UHFFFAOYSA-N CC1CC[Y]1 Chemical compound CC1CC[Y]1 IFZBYMFQVMLWMB-UHFFFAOYSA-N 0.000 description 1
- JBPMJOKITMRCNJ-UHFFFAOYSA-N CCC.CCCCC1=CC=C([Si](Cl)(NC(C)(C)C)C2=CC=C(CCCC)C=C2)C=C1 Chemical compound CCC.CCCCC1=CC=C([Si](Cl)(NC(C)(C)C)C2=CC=C(CCCC)C=C2)C=C1 JBPMJOKITMRCNJ-UHFFFAOYSA-N 0.000 description 1
- JRRGJFCYHIQIAU-UHFFFAOYSA-N CCC.CCCCC1=CC=C([Si](NC(C)(C)C)(C2=CC=C(CCCC)C=C2)C2C=C(N3CC4=CC=CC=C4C3)C3=C2C=CC=C3)C=C1 Chemical compound CCC.CCCCC1=CC=C([Si](NC(C)(C)C)(C2=CC=C(CCCC)C=C2)C2C=C(N3CC4=CC=CC=C4C3)C3=C2C=CC=C3)C=C1 JRRGJFCYHIQIAU-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/07—Long chain branching
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/02—Ziegler natta catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Abstract
Description
wherein [vinyl] is the concentration of vinyl groups in the olefin polymer produced by the low molecular weight catalyst expressed in vinyls/1,000 carbon atoms; [vinylidene], [cis] and [trans] are the concentration of vinylidene, cis and trans groups in the olefin polymer expressed in the number of the respective groups per 1,000 carbon atoms, of greater than 0.12, and wherein the HMW catalyst has a reactivity ratio, r1 of about 5 or less. In other embodiments the low molecular weight catalyst has an Rv L value that is greater than about 0.45, or greater than about 0.50. The high molecular weight catalyst of some embodiments has a reactivity ratio, r1 that is about 4 or less, or about 3 or less. Some processes of the invention comprises catalyst pairs in which the Rv L/Rv H ratio is about 0.80 to about 1.40.
wherein [vinyl] is the concentration of vinyl groups in the olefin polymer produced by the low molecular weight catalyst expressed in vinyls/1,000 carbon atoms; [vinylidene], [cis] and [trans] are the concentration of vinylidene, cis and trans groups in the olefin polymer expressed in the number of the respective groups per 1,000 carbon atoms, and wherein a ratio of Rv L/Rv H ranges from 0.5 to about 2.0. In some processes Rv L Rv H is greater than about 0.15, greater than about 0.20, greater than about 0.25, or greater than about 0.35.
where x is greater than or equal to about 12.5 and y is greater than or equal to about 3 are described.
where I2 is the melt index, x is greater than or equal to 12.5, and y is greater than or equal to 3. In some embodiments, the value for x in (I) is greater than about 14, greater than about 16, greater than about 20, greater than about 25, or greater than about 30 and the value of y, in some embodiments, is about 4.5, about 5.0, about 6.0, or about 7.0. In other embodiments, the melt strength is greater than or equal to formula (I) when x is 35 or 40 or y is about 8, about 10, about 15, or about 20.
where I2 is the melt index, x is greater than or equal to about 3, and y is greater than or equal to about 4.5 and a molecular weight distribution of greater than 3. In some embodiments, the value for x in (II) is greater than about 5, greater than about 7, greater than about 10, greater than about 12.5, or greater than about 15 and the value of y, in some embodiments, is about 5.0, about 6.0, or about 7.0. In other embodiments, the melt strength is greater than or equal to formula (II) when x is 35 or 40 or y is about 8, about 10, about 15, or about 20. In still other embodiments, the melt strength may satisfy a formula where x is greater than about any of about 14, about 16, about 20, greater than about 25, or about 30 and the value of y, in some embodiments, is about 4.5, about 5.0, about 6.0, or about 7.0.
where x is greater than or equal to about 3 and y is greater than or equal to about 4.5 and a molecular weight distribution of greater than 3.
wherein Mw H and Mw L are the respective weight average molecular weight of the HMW component and the LMW component; and WAHMH and WAHML are the respective peak width at the half maxima of the deconvoluted molecular weight distribution curve for the HMW component and the LMW component. The DOS for the new composition is about 0.01 or higher. In some embodiments, DOS is higher than about 0.05, 0.1, 0.5, or 0.8. Preferably, DOS for the bimodal components is at least about 1 or higher. For example, DOS is at least about 1.2, 1.5, 1.7, 2.0, 2.5, 3.0, 3.5, 4.0, 4.5, or 5.0. In some embodiments, DOS is between about 5.0 to abut 100, between about 100 to 500, or between about 500 to 1,000. It should be noted that DOS can be any number in the above range. In other embodiments, DOS exceeds 1,000 or even 10,000 to 25,000 or 50,000.
where g′ is the branching index, IVBr is the intrinsic viscosity of the branched thermoplastic polymer (e.g., polypropylene) and IVLin is the intrinsic viscosity of the corresponding linear thermoplastic polymer having the same weight average molecular weight and molecular weight distribution as the branched thermoplastic polymer and, in the case of copolymers and terpolymers, substantially the same relative molecular proportion or proportions of monomer units. For the purposes, the molecular weight and molecular weight distribution are considered “the same” if the respective values for the branched polymer and the corresponding linear polymer are within 10% of each other. Preferably, the molecular weights are the same and the MWD of the polymers are within 10% of each other. Intrinsic viscosity, in the formula above, in its most general sense is a measure of the capacity of a polymer molecule to enhance the viscosity of a solution. This depends on both the size and the shape of the dissolved polymer molecule. Hence, in comparing a nonlinear polymer with a linear polymer of substantially the same weight average molecular weight, it is an indication of configuration of the nonlinear polymer molecule. Indeed, the above ratio of intrinsic viscosities is a measure of the degree of branching of the nonlinear polymer. A method for determining intrinsic viscosity of polyethylene is described in Macromolecules, 2000, 33, 7489-7499. In this specification the intrinsic viscosity in each instance is determined with the polymer dissolved in decahydronaphthalene trichlorobenzene at 135° C. Another method for measuring the intrinsic viscosity of a polymer is ASTM D5225-98—Standard Test Method for Measuring Solution Viscosity of Polymers with a Differential Viscometer, which is incorporated by reference herein in its entirety.
LCBs/1000C=(7000/Mn L)((Mn L/Mn L)−2)
over a range of branch contents, y.
wherein [vinyl] is the concentration of vinyl groups in the olefin polymer produced by the low molecular weight catalyst expressed in vinyls/1,000 carbon atoms; [vinylidene], [cis] and [trans] are the concentration of vinylidene, cis and trans groups in the olefin polymer expressed in the number of the respective groups per 1,000 carbon atoms, of greater than 0.12, and wherein the HMW catalyst has a reactivity ratio, r1 of about 5 or less. Preferably, the high molecular weight catalyst and the low molecular weight catalyst have the ability to incorporate a substantially similar amount of comonomers.
where Mi refers to a monomer molecule which is arbitrarily designated as “i” where i=1, 2; and M2* refers to a growing polymer chain to which monomer i has most recently attached.
wherein: M is a metal of
wherein R′ each occurrence is independently selected from the group consisting of hydrogen, alkyl, aryl, silyl, germyl, cyano, halo and combinations thereof having up to 20 non-hydrogen atoms; X each occurrence independently is selected from the group consisting of hydride, halo, alkyl, aryl, silyl, germyl, aryloxy, alkoxy, amide, siloxy, and combinations thereof having up to 20 non-hydrogen atoms; L independently each occurrence is a neural Lewis base ligand having up to 30 non-hydrogen atoms; Y is —O—, —S—, —NR*—, —PR*—, or a neutral two electron donor ligand selected from the group consisting of OR*, SR*, NR*2, PR*2; M, n, and m are as previously defined; and Z is SIR*2, CR*2, SiR*2SiR*2, CR*2CR*2, CR*═CR*, CR*2SiR*2, GeR*2, BR*, BR*2; wherein: R* each occurrence is independently selected from the group consisting of hydrogen, alkyl, aryl, silyl, halogenated alkyl, halogenated aryl groups having up to 20 non-hydrogen atoms, and mixtures thereof, or two or more R* groups from Y, Z, or both Y and Z form a fused ring system.
wherein: M is titanium, zirconium or hafnium, bound in an η5 bonding mode to the cyclopentadienyl group; R′ each occurrence is independently selected from the group consisting of hydrogen, silyl, alkyl, aryl and combinations thereof having up to 10 carbon or silicon atoms; E is silicon or carbon; X independently each occurrence is hydride, halo, alkyl, aryl, aryloxy or alkoxy of up to 10 carbons; m is 1 or 2; and n is 1 or 2 depending on the valence of M.
wherein R1 and R2 independently are groups selected from hydrogen, hydrocarbyl, perfluoro substituted hydrocarbyl, silyl, germyl and mixtures thereof, the group containing up to 20 non-hydrogen atoms, with the proviso that at least one of R1 or R2 is not hydrogen; R3, R4, R5, and R6 independently are groups selected from hydrogen, hydrocarbyl, perfluoro substituted hydrocarbyl, silyl, germyl and mixtures thereof, the group containing up to 20 non-hydrogen atoms; M is titanium, zirconium or hafnium; Z is a divalent moiety comprising boron, or a member of Group 14 of the Periodic Table of the Elements, and also comprising nitrogen, phosphorus, sulfur or oxygen, the moiety having up to 60 non-hydrogen atoms; p is 0, 1 or 2; q is zero or one; with the proviso that: when p is 2, q is zero, M is in the +4 formal oxidation state, and X is an anionic ligand selected from the group consisting of halide, hydrocarbyl, hydrocarbyloxy, di(hydrocarbyl)amido, di(hydrocarbyl)phosphido, hydrocarbyl sulfido, and silyl groups, as well as halo-, di(hydrocarbyl)amino-, hydrocarbyloxy- and di(hydrocarbyl)phosphino-substituted derivatives thereof, the X group having up to 20 non-hydrogen atoms, when p is 1, q is zero, M is in the +3 formal oxidation state, and X is a stabilizing anionic ligand group selected from the group consisting of allyl, 2-(N,N-dimethylaminomethyl)phenyl, and 2-(N,N-dimethyl)-aminobenzyl, or M is in the +4 formal oxidation state, and X is a divalent derivative of a conjugated diene, M and X together forming a metallocyclopentene group, and when p is 0, q is 1, M is in the +2 formal oxidation state, and X′ is a neutral, conjugated or non-conjugated diene, optionally substituted with one or more hydrocarbyl groups, the X′ having up to 40 carbon atoms and forming a π-complex with M.
wherein: R1 and R2 are hydrogen or C1-6 alkyl, with the proviso that at least one of R1 or R2 is not hydrogen; R3, R4, R5, and R6 independently are hydrogen or C1-6 alkyl; M is titanium; Y is—O—, —S—, —NR*—, —PR*—; Z* is SiR*2, CR*2, SiR*2SiR*2, CR*2CR*2, CR*═CR*, CR*2SiR*2, or GeR*2; R* each occurrence is independently hydrogen, or a member selected from hydrocarbyl, hydrocarbyloxy, silyl, halogenated alkyl, halogenated aryl, and combinations thereof, the R* having up to 20 non-hydrogen atoms, and optionally, two R* groups from Z (when R* is not hydrogen), or an R* group from Z and an R* group from Y form a ring system; p is 0, 1 or 2; q is zero or one; with the proviso that: when p is 2, q is zero, M is in the +4 formal oxidation state, and X is independently each occurrence methyl or benzyl, when p is 1, q is zero, M is in the +3 formal oxidation state, and X is 2-(N,N-dimethyl)aminobenzyl; or M is in the +4 formal oxidation state and X is 1,4-butadienyl, and when p is 0, q is 1, M is in the +2 formal oxidation state, and X′ is 1,4-diphenyl-1,3-butadiene or 1,3-pentadiene. The latter diene is illustrative of unsymmetrical diene groups that result in production of metal complexes that are actually mixtures of the respective geometrical isomers.
- (t-butylamido)dimethyl(η5-2-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (t-butylamido) dimethyl (η5-2-methylindenyl)silanetitanium (II) 1,3-pentadiene; (t-butylamido) dimethyl(η5-2-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (t-butylamido) dimethyl(η5-2-methylindenyl)silanetitanium (IV)dimethyl; (t-butylamido)dimethyl(η5-2-methylindenyl)silanetitanium (IV) dibenzyl; (n-butylamido)dimethyl(η5-2-methylindenyl) silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)dimethyl(η5-2-methylindenyl) silanetitanium (II) 1,3-pentadiene; (n-butylamido)dimethyl(η5-2-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (n-butylamido)dimethyl(η5-2-methylindenyl)silanetitanium (IV) dimethyl; (n-butylamido)dimethyl(η5-2-methylindenyl)silanetitanium (IV) dibenzyl; (cyclododecylamido)dimethyl(η5-2-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)dimethyl(η5-2-methylindenyl)silanetitanium (II) 1,3-pentadiene, (cyclododecylamido)dimethyl(η5-2-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (cyclododecylamido)dimethyl(η5-2-methylindenyl)silanetitanium (IV) dimethyl; (cyclododecylamido)dimethyl(η5-2-methylindenyl)silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)dimethyl(η5-2-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)dimethyl(η5-2-methylindenyl)silanetitanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)dimethyl(η5-2-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)dimethyl(η5-2-methylindenyl)silanetitanium (IV)dimethyl; (2,4,6-trimethylanilido)dimethyl(η5-2-methylindenyl)silanetitanium (IV) dibenzyl; (1-adamantylamido)dimethyl(η5-2-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)dimethyl(η5-2-methylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)dimethyl(η5-2-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)dimethyl(η5-2-methylindenyl)silane titanium (IV)dimethyl; (1-adamantylamido)dimethyl(η5-2-methylindenyl)silanetitanium (IV) dibenzyl; (t-butylamido)dimethyl(η5-2-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (t-butylamido)dimethyl(η5-2-methylindenyl)silanetitanium (II) 1,3-pentadiene; (t-butylamido)dimethyl(η5-2-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (t-butylamido)dimethyl(η5-2-methylindenyl)silanetitanium (IV)dimethyl; (t-butylamido)dimethyl(η5-2-methyl indenyl)silanetitanium (IV) dibenzyl; (n-butylamido)diisopropoxy(η5-2-methylindenyl)silane titanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)diisopropoxy(η5-2-methylindenyl)silanetitanium (II) 1,3-pentadiene; (n-butylamido)diisopropoxy(η5-2-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (n-butylamido)diisopropoxy(η5-2-methylindenyl)silanetitanium (IV)dimethyl; (n-butylamido)diisopropoxy(η5-2-methylindenyl)silanetitanium (IV) dibenzyl; (cyclododecylamido)diisopropoxy(η5-2-methylindenyl)-silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)diisopropoxy(η5-2-methylindenyl)-silanetitanium (II) 1,3-pentadiene; (cyclododecylamido)diisopropoxy(η5-2-methylindenyl)-silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (cyclododecylamido)diisopropoxy(η5-2-methylindenyl)-silanetitanium (IV) dimethyl; (cyclododecylamido) diisopropoxy(η5-2-methylindenyl)-silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)diisopropoxy(η5-2-methyl-indenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)diisopropoxy(η5-2-methylindenyl)silanetitanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)diisopropoxy(η5-2-methylin-denyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido) diisopropoxy(η5-2-methylindenyl)silanetitanium (IV)dimethyl; (2,4,6-trimethylanilido)diisopropoxy(η5-2-methylindenyl)silanetitanium (IV) dibenzyl; (1-adamantylamido)diisopropoxy(η5-2-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)diisopropoxy(η5-2-methylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)diisopropoxy(η5-2-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)diisopropoxy(η5-2-methylindenyl)silanetitanium (IV) dimethyl; (1-adamantylamido)diisopropoxy(η5-2-methylindenyl)silanetitanium (IV) dibenzyl; (n-butylamido)dimethoxy(η5-2-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)dimethoxy(η5-2-methylindenyl)silanetitanium (II) 1,3-pentadiene; (n-butylamido)dimethoxy(η5-2-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (n-butylamido)dimethoxy(η5-2-methylindenyl)silanetitanium (IV)dimethyl; (n-butylamido)dimethoxy(η5-2-methylindenyl)silanetitanium (IV) dibenzyl; (cyclododecylamido)dimethoxy(η5-2-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)dimethoxy(η5-2-methylindenyl)silanetitanium (II) 1,3-pentadiene; (cyclododecylamido)dimethoxy(η5-2-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (cyclododecylamido)dimethoxy(η5-2-methylindenyl)silanetitanium (IV)dimethyl; (cyclododecylamido)dimethoxy(η5-2-methylindenyl)silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)dimethoxy(η5-2-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)dimethoxy(η5-2-methylindenyl)silanetitanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)dimethoxy(η5-2-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)dimethoxy(η5-2-methylindenyl)silanetitanium (IV)dimethyl; (2,4,6-trimethylanilido)dimethoxy(η5-2-methylindenyl)silanetitanium (IV) dibenzyl; (1-adamantylamido)dimethoxy(η5-2-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)dimethoxy(η5-2-methylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)dimethoxy(η5-2-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)dimethoxy(η5-2-methylindenyl)silanetitanium (IV) dimethyl; (1-adamantylamido)dimethoxy(η5-2-methylindenyl)silanetitanium (IV) dibenzyl; (n-butylamido)ethoxymethyl(η5-2-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)ethoxymethyl(η5-2-methylindenyl)silanetitanium (II) 1,3-pentadiene; (n-butylamido) ethoxymethyl(η5-2-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (n-butylamido)ethoxymethyl(η5-2-methylindenyl)silanetitanium (IV)dimethyl; (n-butylamido)ethoxymethyl(η5-2-methylindenyl)silanetitanium (IV) dibenzyl; (cyclododecylamido)ethoxymethyl(η5-2-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)ethoxymethyl(η5-2-methylindenyl)silanetitanium (II) 1,3-pentadiene; (cyclododecylamido)ethoxymethyl(η5-2-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (cyclododecylamido)ethoxymethyl(η5-2-methylindenyl)silanetitanium (IV)dimethyl; (cyclododecylamido)ethoxymethyl(η5-2-methylindenyl)silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)ethoxymethyl(η5-2-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)ethoxymethyl(η5-2-methylindenyl)silanetitanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)ethoxymethyl(η5-2-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)ethoxymethyl(η5-2-methylindenyl)silanetitanium (IV)dimethyl; (2,4,6-trimethylanilido)ethoxymethyl(η5-2-methylindenyl)silanetitanium (IV) dibenzyl; (1-adamantylamido)ethoxymethyl(η5-2-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)ethoxymethyl(η5-2-methylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)ethoxymethyl(η5-2-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)ethoxymethyl(η5-2-methylindenyl)silanetitanium (IV)dimethyl; (1-adamantylamido)ethoxymethyl(η5-2-methylindenyl)silanetitanium (IV) dibenzyl;
- 2,3-dimethylindenyl Complexes:
- (t-butylamido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (t-butylamido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (II) 1,3-pentadiene; (t-butylamido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (t-butylamido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (IV)dimethyl; (t-butylamido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (IV) dibenzyl; (n-butylamido)dimethyl(η5-2,3-dimethylindenyl)-silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)dimethyl (η5-2,3-dimethylindenyl)silanetitanium (II) 1,3-pentadiene; (n-butylamido)dimethyl(η5-2,3-dimethylindenyl)-silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (n-butylamido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (IV)dimethyl; (n-butylamido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (IV) dibenzyl; (cyclododecylamido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)dimethyl (η5-2,3-dimethylindenyl)silanetitanium (II) 1,3-pentadiene; (cyclododecylamido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (cyclododecylamido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (IV) dimethyl; (cyclododecylamido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)dimethyl(η5-2,3-dimethyl-indenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (IV)dimethyl; (2,4,6-trimethylanilido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (IV) dibenzyl; (1-adamantylamido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (IV)dimethyl; (1-adamantylamido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (IV) dibenzyl; (t-butylamido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (t-butyl amido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (II) 1,3-pentadiene; (t-butylamido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (t-butyl amido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (IV)dimethyl; (t-butylamido)dimethyl(η5-2,3-dimethylindenyl)silanetitanium (IV) dibenzyl; (n-butylamido)diisopropoxy(η5-2,3-dimethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)diisopropoxy(η5-2,3-dimethylindenyl)silanetitanium (II) 1,3-pentadiene; (n-butylamido)diisopropoxy(η5-2,3-dimethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (n-butylamido)diisopropoxy(η5-2,3-dimethylindenyl)silanetitanium (IV)dimethyl; (n-butylamido)diisopropoxy(η5-2,3-dimethylindenyl)silanetitanium (IV)dibenzyl; (cyclododecylamido)diisopropoxy(η5-2,3-dimethylindenyl)-silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)diisopropoxy(η5-2,3-dimethylindenyl)-silanetitanium (II) 1,3-pentadiene; (cyclododecylamido)diisopropoxy(η5-2,3-dimethylindenyl)-silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (cyclododecylamido)diisopropoxy(η5-2,3-dimethylindenyl)-silanetitanium (IV)dimethyl; (cyclo dodecylamido)diisopropoxy(η5-2,3-dimethylindenyl)-silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)diisopropoxy(η5-2,3-dimethyl-indenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)diisopropoxy(η5-2,3-dimethylindenyl)silanetitanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)diisopropoxy(η5-2,3-dimethylin-denyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)diisopropoxy(η5-2,3-dimethylindenyl)silanetitanium (IV)dimethyl; (2,4,6-trimethylanilido)diisopropoxy(η5-2,3-dimethylindenyl)silanetitanium (IV) dibenzyl; (1-adamantylamido)diisopropoxy(η5 -2,3-dimethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)diisopropoxy(η5-2,3-dimethylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)diisopropoxy(η5-2,3-dimethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)diisopropoxy(η5-2,3-dimethylindenyl)silanetitanium (IV)dimethyl; (1-adamantylamido)diisopropoxy(η5-2,3-dimethylindenyl)silanetitanium (IV) dibenzyl; (n-butylamido)dimethoxy(η5-2,3-dimethyl indenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (n-butyl amido)dimethoxy(η5-2,3-dimethylindenyl)silanetitanium (II) 1,3-pentadiene; (n-butylamido)dimethoxy(η5-2,3-dimethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (n-butyl amido)dimethoxy(η5-2,3-dimethylindenyl)silanetitanium (IV)dimethyl; (n-butylamido)dimethoxy(η5-2,3-dimethylindenyl)silanetitanium (IV) dibenzyl; (cyclododecylamido)dimethoxy(Θ5-2,3-dimethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)dimethoxy(η5-2,3-dimethylindenyl)silanetitanium (II) 1,3-pentadiene; (cyclo dodecylamido)dimethoxy(η5-2,3-dimethylindenyl)silanetitanium (III) 2-(N,N-dimethyl amino)benzyl; (cyclododecylamido)dimethoxy(η5-2,3-dimethylindenyl)silanetitanium (IV) dimethyl; (cyclododecylamido)dimethoxy(η5-2,3-dimethylindenyl)silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)dimethoxy(η5 -2,3-dimethyl-indenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)dimethoxy(η5-2,3-dimethyl-indenyl)silane titanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)dimethoxy(η5-2,3-dimethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)dimethoxy(η5-2,3-dimethylindenyl)silanetitanium (IV) dimethyl; (2,4,6-trimethylanilido)dimethoxy(η5-2,3-dimethylindenyl)silanetitanium (IV) dibenzyl; (1-adamantylamido)dimethoxy(η5-2,3-dimethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantyl amido)dimethoxy(η5-2,3-dimethylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)dimethoxy(η5-2,3-dimethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)dimethoxy(η5-2,3-dimethylindenyl)silanetitanium (IV) dimethyl; (1-adamantylamido)dimethoxy(η5-2,3-dimethylindenyl)silanetitanium (IV) dibenzyl; (n-butylamido)ethoxymethyl(η5-2,3-dimethylindenyl)-silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)ethoxymethyl(η5-2,3-dimethylindenyl)silanetitanium (II) 1,3-pentadiene; (n-butylamido)ethoxymethyl(η5-2,3-dimethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (n-butylamido)ethoxymethyl(η5-2,3-dimethylindenyl)silane titanium (IV)dimethyl; (n-butylamido)ethoxymethyl(η5-2,3-dimethylindenyl)silanetitanium (IV) dibenzyl; (cyclododecylamido)ethoxymethyl(η5-2,3-dimethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)ethoxymethyl(η5-2,3-dimethylindenyl)silanetitanium (II) 1,3-pentadiene; (cyclododecylamido)ethoxymethyl(η5-2,3-dimethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (cyclododecylamido)ethoxymethyl(η5-2,3-dimethylindenyl)silanetitanium (IV) dimethyl; (cyclododecyl amido)ethoxymethyl(η5-2,3-dimethylindenyl)silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)ethoxymethyl(η5-2,3-dimethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)ethoxymethyl(η5-2,3-dimethylindenyl)silanetitanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)ethoxymethyl(η5-2,3-dimethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)ethoxymethyl(η5-2,3-dimethylindenyl)silanetitanium (V)dimethyl; (2,4,6-trimethylanilido)ethoxymethyl(η5-2,3-dimethylindenyl)silanetitanium (IV) dibenzyl; (1-adamantylamido)ethoxymethyl(η5-2,3-dimethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)ethoxymethyl(η5-2,3-dimethylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)ethoxymethyl(η5-2,3-dimethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)ethoxymethyl(η5-2,3-dimethylindenyl)silanetitanium (IV) dimethyl; (1-adamantylamido)ethoxymethyl(η5-2,3-dimethylindenyl)silanetitanium (IV) dibenzyl;
- 3-methylindenyl Complexes:
- (t-butylamido)dimethyl(η5-3-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (t-butylamido)dimethyl(η5-3-methylindenyl)silanetitanium (II) 1,3-pentadiene; (t-butylamido)dimethyl(η5-3-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (t-butylamido)dimethyl(η5-3-methylindenyl)sanetitanium (IV)dimethyl; (t-butylamido)dimethyl(η5-3-methylindenyl)silanetitanium (IV) dibenzyl; (n-butylamido)dimethyl(η5-3-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)dimethyl(r)5-3-methylindenyl)silanetitanium (II) 1,3-pentadiene; (n-butylamido)dimethyl(η5-3-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (n-butylamido)dimethyl(η5-3-methylindenyl)silanetitanium (IV) dimethyl; (n-butylamido)dimethyl(η5-3-methylindenyl)silanetitanium (IV) dibenzyl; (cyclododecylamido)dimethyl(η5-3-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)dimethyl(η5-3-methylindenyl)silanetitanium (II) 1,3-pentadiene; (cyclododecylamido)dimethyl(η5-3-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (cyclododecylamido)dimethyl(η5-3-methylindenyl)silanetitanium (IV) dimethyl; (cyclododecylamido)dimethyl(η5-3-methylindenyl)silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)dimethyl(η5-3-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)dimethyl(η5-3-methylindenyl)silanetitanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)dimethyl(η5-3-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)dimethyl(η5-3-methylindenyl)silanetitanium (IV) dimethyl; (2,4,6-trimethylanilido)dimethyl(η5-3-methylindenyl)silanetitanium (IV) dibenzyl; (1-adamantylamido)dimethyl(η5-3-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)dimethyl(η5-3-methylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)dimethyl(η5-3-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)dimethyl(η5-3-methylindenyl)silanetitanium (IV) dimethyl; (1-adamantylamido)dimethyl(η5-3-methylindenyl)silanetitanium (IV) dibenzyl; (t-butylamido)dimethyl(η5-3-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (t-butylamido)dimethyl(η5-3-methylindenyl)silanetitanium (II) 1,3-pentadiene; (t-butylamido)dimethyl(η5-3-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (t-butylamido)dimethyl(η5-3-methylindenyl)silanetitanium (IV) dimethyl; (t-butylamido)dimethyl(η5-3-methylindenyl)silanetitanium (IV) dibenzyl; (n-butylamido)diisopropoxy(η5-3-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)diisopropoxy(η5-3-methylindenyl)silanetitanium (II). 1,3-pentadiene; (n-butylamido)diisopropoxy(η5-3-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (n-butylamido)diisopropoxy(η5-3-methylindenyl)silanetitanium (IV) dimethyl; (n-butylamido)diisopropoxy(η5-3-methylindenyl)silanetitanium (IV) dibenzyl; (cyclododecylamido)diisopropoxy(η5-3-methylindenyl)-silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)diisopropoxy(η5-3-methylindenyl)-silanetitanium (II) 1,3-pentadiene; (cyclododecylamido)diisopropoxy(η5-3-methylindenyl)-silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (cyclododecylamido)diisopropoxy(η5-3-methylindenyl)-silanetitanium (IV) dimethyl; (cyclododecylamido)diisopropoxy(η5-3-methylindenyl)-silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)diisopropoxy(η5-3-methyl-indenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)diisopropoxy(η5-3-methylindenyl)silanetitanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)diisopropoxy(η5-3-methylin-denyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)diisopropoxy(η5-3-methylindenyl)silanetitanium (IV) dimethyl; (2,4,6-trimethylanilido)diisopropoxy(η5-3-methylindenyl)silanetitanium (IV) dibenzyl; (1-adamantylamido)diisopropoxy(η5-3-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)diisopropoxy(η5-3-methylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)diisopropoxy(η5-3-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)diisopropoxy(η5-3-methylindenyl)silanetitanium (IV) dimethyl; (1-adamantylamido)diisopropoxy(η5-3-methylindenyl)silanetitanium (IV) dibenzyl; (n-butylamido)dimethoxy(η5-3-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)dimethoxy(η5-3-methylindenyl)silane titanium (II) 1,3-pentadiene; (n-butylamido)dimethoxy(η5-3-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (n-butylamido)dimethoxy(η5-3-methylindenyl)silane titanium (IV) dimethyl; (n-butylamido)dimethoxy(η5-3-methylindenyl)silanetitanium (IV) dibenzyl; (cyclododecylamido)dimethoxy(η5-3-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)dimethoxy (η5-3-methylindenyl)silanetitanium (II) 1,3-pentadiene; (cyclododecylamido)dimethoxy(η5-3-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (cyclododecylamido)dimethoxy(η5-3-methylindenyl)silane titanium (IV) dimethyl; (cyclododecylamido)dimethoxy (η5-3-methylindenyl)silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)dimethoxy(η5-3-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)dimethoxy(η5-3-methylindenyl)silane titanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)dimethoxy(η5-3-methylindenyl)silane titanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)dimethoxy(η5-3-methylindenyl)silanetitanium (IV) dimethyl; (2,4,6-trimethylanilido)dimethoxy(η5-3-methylindenyl)silanetitanium (IV) dibenzyl; (1-adamantylamido)dimethoxy(η5-3-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)dimethoxy(η5-3-methylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)dimethoxy(η5-3-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)dimethoxy(η5-3-methylindenyl)silanetitanium (IV) dimethyl; (1-adamantylamido)dimethoxy(η5-3-methylindenyl)silanetitanium (IV) dibenzyl; (n-butylamido)ethoxymethyl(η5-3-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)ethoxymethyl(η5-3-methylindenyl)silanetitanium (II) 1,3-pentadiene; (n-butylamido)ethoxymethyl(η5-3-methylindenyl)silanetitanium (III) 2-(N,N-dimethyl amino)benzyl; (n-butylamido)ethoxymethyl(η5-3-methylindenyl)silanetitanium (IV) dimethyl; (n-butylamido)ethoxymethyl(η5-3-methylindenyl)silanetitanium (IV) dibenzyl; (cyclododecylamido)ethoxymethyl(η5-3-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)ethoxymethyl(η5-3-methylindenyl)silanetitanium (II) 1,3-pentadiene; (cyclododecylamido)ethoxymethyl(η5-3-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (cyclododecylamido)ethoxymethyl(η5-3-methylindenyl)silane titanium (IV) dimethyl; (cyclododecylamido)ethoxymethyl(η5-3-methylindenyl)silane titanium (IV) dibenzyl; (2,4,6-trimethylanilido)ethoxymethyl(η5-3-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)ethoxymethyl(η5-3-methylindenyl)silanetitanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)ethoxymethyl(η5-3-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)ethoxymethyl(η5-3-methylindenyl)silanetitanium (IV) dimethyl; (2,4,6-trimethylanilido)ethoxymethyl(η5-3-methylindenyl)silanetitanium (IV) dibenzyl; (1-adamantylamido)ethoxymethyl(η5-3-methylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)ethoxymethyl(η5-3-methylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)ethoxymethyl(η5-3-methylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)ethoxymethyl(η5-3-methylindenyl)silane titanium (IV) dimethyl; (1-adamantylamido)ethoxymethyl (η5-3-methylindenyl)silanetitanium (IV) dibenzyl;
- 2-methyl-3-ethylindenyl Complexes:
- (t-butylamido)dimethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (t-butylamido)dimethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,3-pentadiene; (t-butylamido)dimethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (t-butylamido)dimethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dimethyl; (t-butylamido)dimethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dibenzyl; (n-butylamido)dimethyl(η5-2-methyl-3-ethylindenyl)-silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)dimethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,3-pentadiene; (n-butylamido)dimethyl(η5-2-methyl-3-ethylindenyl)-silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (n-butylamido)dimethyl(η5-2-methyl-3-ethylindenyl)silane titanium (IV) dimethyl; (n-butylamido)dimethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dibenzyl; (cyclododecylamido)dimethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)dimethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,3-pentadiene; (cyclododecylamido)dimethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (III) 2-(N,N-dimethyl amino)benzyl; (cyclododecyl amido)dimethyl(-2-methyl-3-ethylindenyl)silanetitanium (IV) dimethyl; (cyclododecyl amido)dimethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)dimethyl(η5-2-methyl-3-ethyl-indenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)dimethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)dimethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)dimethyl (η5-2-methyl-3-ethylindenyl) silanetitanium (IV) dimethyl; (2,4,6-trimethylanilido)dimethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dibenzyl; (1-adamantylamido)dimethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)dimethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)dimethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)dimethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dimethyl; (1-adamantylamido)dimethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dibenzyl; (t-butylamido)dimethyl(η5-2-methyl-3-ethylindenyl)-silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (t-butylamido)dimethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,3-pentadiene; (t-butylamido)dimethyl (η5-2-methyl-3-ethylindenyl)-silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (t-butylamido)dimethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dimethyl; (t-butylamido)dimethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dibenzyl; (n-butylamido)diisopropoxy(η5-2-methyl-3-ethyl-indenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)diisopropoxy(η5-2-methyl-3-ethylindenyl)silane titanium (II) 1,3-pentadiene; (n-butylamido)diisopropoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (n-butylamido)diisopropoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dimethyl; (n-butylamido)diisopropoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dibenzyl; (cyclododecylamido)diisopropoxy(-2-methyl-3-ethyl-indenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)diisopropoxy(η5-2-methyl-3-ethylindenyl)-silanetitanium (II) 1,3-pentadiene; (cyclododecylamido)diisopropoxy(η5-2-methyl-3-ethylindenyl)-silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (cyclododecylamido)diisopropoxy(η5-2-methyl-3-ethylindenyl)-silane titanium (IV) dimethyl; (cyclododecylamido)diisopropoxy(η5-2-methyl-3-ethylindenyl)-silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)diisopropoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)diisopropoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)diisopropoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)diisopropoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dimethyl; (2,4,6-trimethylanilido)diisopropoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dibenzyl; (1-adamantylamido)diisopropoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)diisopropoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)diisopropoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)diisopropoxy(η5-2-methyl-3-ethylindenyl)silane titanium (IV) dimethyl; (1-adamantylamido)diisopropoxy(η5-2-methyl-3-ethylindenyl)silane titanium (IV) dibenzyl; (n-butylamido)dimethoxy(η5-2-methyl-3-ethylindenyl)silane titanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)dimethoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,3-pentadiene; (n-butylamido)dimethoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (n-butylamido)dimethoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dimethyl; (n-butylamido)dimethoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dibenzyl; (cyclododecylamido)dimethoxy(η5-2-methyl-3-ethyl-indenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)dimethoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,3-pentadiene; (cyclododecyl amido)dimethoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (cyclododecylamido)dimethoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dimethyl; (cyclododecylamido)dimethoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)dimethoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)dimethoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)dimethoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)dimethoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dimethyl; (2,4,6-trimethylanilido)dimethoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dibenzyl; (1-adamantylamido)dimethoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)dimethoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)dimethoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)dimethoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dimethyl; (1-adamantylamido)dimethoxy(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dibenzyl; (n-butylamido)ethoxymethyl(η5-2-methyl-3-ethyl-indenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)ethoxy methyl(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,3-pentadiene; (n-butylamido)ethoxy methyl(η5-2-methyl-3-ethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (n-butylamido)ethoxymethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dimethyl; (n-butylamido)ethoxymethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dibenzyl; (cyclododecylamido)ethoxymethyl(η5-2-methyl-3-ethyl-indenyl)silane-titanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)ethoxymethyl(η5-2-methyl-3-ethylindenyl)silane-titanium (II) 1,3-pentadiene; (cyclododecylamido)ethoxymethyl(η5-2-methyl-3-ethylindenyl)silane-titanium (III) 2-(N,N-dimethylamino)benzyl; (cyclododecylamido)ethoxymethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dimethyl; (cyclododecyl amido)ethoxymethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)ethoxymethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)ethoxymethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)ethoxymethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)ethoxymethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dimethyl; (2,4,6-trimethylanilido)ethoxymethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dibenzyl; (1-adamantylamido)ethoxymethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)ethoxymethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)ethoxymethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)ethoxymethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dimethyl; (1-adamantylamido)ethoxymethyl(η5-2-methyl-3-ethylindenyl)silanetitanium (IV) dibenzyl;
- 2,3,4,6-tetramethylindenyl Complexes:
- (t-butylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (t-butylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,3-pentadiene; (t-butylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (t-butylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silane titanium (IV) dimethyl; t-butylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dibenzyl; (n-butylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silane titanium (II) 1,3-pentadiene; (n-butylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silane titanium (III) 2-(N,N-dimethylamino)benzyl; (n-butylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dimethyl; (n-butylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dibenzyl; (cyclododecylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silane titanium (II) 1,3-pentadiene; (cyclododecylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silane titanium (III) 2-(N,N-dimethylamino)benzyl; (cyclododecylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silane titanium (IV) dimethyl; (cyclododecylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silane titanium (IV) dimethyl; (2,4,6-trimethylanilido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silane titanium (IV) dibenzyl; (1-adamantylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silane titanium (II) 1,3-pentadiene; (1-adamantylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silane titanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dimethyl; (1-adamantylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dibenzyl; (t-butylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)-silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (t-butylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,3-pentadiene; (t-butylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)-silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (t-butylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dimethyl; (t-butylamido)dimethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dibenzyl; (n-butylamido)diisopropoxy(η5-2,3,4,6-tetramethylindenyl)silane-titanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)diisopropoxy(η5-2,3,4,6-tetramethylindenyl)silane-titanium (II) 1,3-pentadiene; (n-butylamido)diisopropoxy(η5-2,3,4,6-tetramethylindenyl)-silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (n-butylamido)diisopropoxy(η5-2,3,4,6-tetramethylindenyl)silane-titanium (IV) dimethyl; (n-butylamido)diisopropoxy(η5-2,3,4,6-tetramethylindenyl)silane-titanium (IV) dibenzyl; (cyclododecylamido)diisopropoxy(η5-2,3,4,6-tetramethylindenyl)-silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)diisopropoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,3-pentadiene; (cyclododecylamido)diisopropoxy(-2,3,4,6-tetramethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; cyclododecylamido)diisopropoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dimethyl; (cyclododecylamido)diisopropoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)diisopropoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)diisopropoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)diisopropoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)diisopropoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dimethyl; (2,4,6-trimethylanilido)diisopropoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dibenzyl; (1-adamantylamido)diisopropoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)diisopropoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)diisopropoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)diisopropoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dimethyl; (1-adamantylamido)diisopropoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dibenzyl; (n-butylamido)dimethoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)dimethoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,3-pentadiene; (n-butylamido)dimethoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (n-butylamido)dimethoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dimethyl; (n-butylamido)dimethoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dibenzyl; (cyclododecylamido)dimethoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)dimethoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,3-pentadiene; (cyclododecylamido)dimethoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (cyclododecylamido)dimethoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dimethyl; (cyclododecylamido)dimethoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)dimethoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3 butadiene; (2,4,6-trimethylanilido)dimethoxy(η5-2,3,4,6-tetramethylindenyl)silane titanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)dimethoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)dimethoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dimethyl; (2,4,6-trimethylanilido)dimethoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dibenzyl; (1-adamantylamido)dimethoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)dimethoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)dimethoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)dimethoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dimethyl; (1-adamantylamido)dimethoxy(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dibenzyl; (n-butylamido)ethoxymethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)ethoxymethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,3-pentadiene; (n-butylamido)ethoxymethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (n-butylamido)ethoxymethyl(η5-2,3,4,6-tetramethylindenyl)silane titanium (IV) dimethyl; (n-butylamido)ethoxymethyl(η5-2,3,4,6-tetramethylindenyl)silane titanium (IV) dibenzyl; (cyclododecylamido)ethoxymethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)ethoxymethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,3-pentadiene; (cyclododecylamido)ethoxymethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (cyclododecylamido)ethoxymethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dimethyl; (cyclododecylamido)ethoxymethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)ethoxymethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)ethoxymethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)ethoxymethyl(η5-2,3,4,6-tetramethylindenyl)silane titanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)ethoxymethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dimethyl; (2,4,6-trimethylanilido)ethoxymethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dibenzyl; (1-adamantylamido)ethoxymethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)ethoxymethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)ethoxymethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)ethoxymethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dimethyl; and (1-adamantylamido)ethoxymethyl(η5-2,3,4,6-tetramethylindenyl)silanetitanium (IV) dibenzyl.
- 2,3,4,6,7-pentamethylindenyl Complexes:
- (t-butylamido)dimethyl(η5-2,3,4,6,7-pentamethyl-indenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (t-butylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,3-pentadiene; (t-butylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (t-butylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dimethyl; (t-butylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dibenzyl; (n-butylamido)dimethyl(η5-2,3,4,6,7-pentamethyl-indenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,3-pentadiene; (n-butylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)-silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (n-butylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dimethyl; (n-butylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dibenzyl; (cyclododecylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,3-pentadiene; (cyclododecylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (cyclododecylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dimethyl; (cyclododecylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)dimethyl(η5-2,3,4,6,7-pentamethyl-indenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)dimethyl(η5-2,3,4,6,7-pentamethyl-indenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dimethyl; (2,4,6-trimethylanilido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dibenzyl; (1-adamantylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dimethyl; (1-adamantylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dibenzyl; (t-butylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)-silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (t-butylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,3-pentadiene; (t-butylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)-silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (t-butylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dimethyl; (t-butylamido)dimethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dibenzyl; (n-butylamido)diisopropoxy(η5-2,3,4,6,7-pentamethyl-indenyl)silane-titanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)diisopropoxy(η5 -2,3,4,6,7-pentamethylindenyl)silane-titanium (II) 1,3-pentadiene; (n-butylamido)diisopropoxy(η5-2,3,4,6,7-pentamethylindenyl)-silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (n-butylamido)diisopropoxy(η5-2,3,4,6,7-pentamethylindenyl)silane-titanium (IV) dimethyl; (n-butylamido)diisopropoxy(η5-2,3,4,6,7-pentamethylindenyl)silane-titanium (IV) dibenzyl; (cyclododecylamido)diisopropoxy(η5-2,3,4,6,7-pentamethyl-indenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)diisopropoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,3-pentadiene; (cyclododecylamido)diisopropoxy(-2,3,4,6,7-pentamethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (cyclododecylamido)diisopropoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dimethyl; (cyclododecylamido)diisopropoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)diisopropoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)diisopropoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)diisopropoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)diisopropoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dimethyl; (2,4,6-trimethylanilido)diisopropoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dibenzyl; (1-adamantylamido)diisopropoxy(η5-2,3,4,6,7-pentamethyl-indenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)diisopropoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)diisopropoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)diisopropoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dimethyl; (1-adamantylamido)diisopropoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dibenzyl; (n-butylamido)dimethoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)dimethoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,3-pentadiene; (n-butylamido)dimethoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (n-butylamido)dimethoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dimethyl; (n-butylamido)dimethoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dibenzyl; (cyclododecylamido)dimethoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)dimethoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,3-pentadiene; (cyclododecylamido)dimethoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (cyclododecylamido)dimethoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dimethyl; (cyclododecylamido)dimethoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)dimethoxy(η5-2,3,4,6,7-pentamethylindenyl)silane titanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)dimethoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)dimethoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)dimethoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dimethyl; (2,4,6-trimethylanilido)dimethoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dibenzyl; (1-adamantylamido)dimethoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)dimethoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)dimethoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)dimethoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dimethyl; (1-adamantylamido)dimethoxy(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dibenzyl; (n-butylamido)ethoxymethyl(η5-2,3,4,6,7-pentamethyl-indenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (n-butylamido)ethoxymethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,3-pentadiene; (n-butylamido)ethoxymethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (n-butylamido)ethoxymethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dimethyl; (n-butylamido)ethoxymethyl(η5 -2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dibenzyl; (cyclododecylamido)ethoxymethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (cyclododecylamido)ethoxymethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,3-pentadiene; (cyclododecylamido)ethoxymethyl(η5-2,3,4,6,7-pentamethylindenyl)silane titanium (III) 2-(N,N-dimethylamino)benzyl; (cyclododecylamido)ethoxymethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dimethyl; (cyclododecylamido)ethoxymethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dibenzyl; (2,4,6-trimethylanilido)ethoxymethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (2,4,6-trimethylanilido)ethoxymethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,3-pentadiene; (2,4,6-trimethylanilido)ethoxymethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (2,4,6-trimethylanilido)ethoxymethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dimethyl; (2,4,6-trimethylanilido)ethoxymethyl(η5-2,3,4,6,7-pentamethylindenyl)silane titanium (IV) dibenzyl; (1-adamantylamido)ethoxymethyl(η5-2,3,4,6,7-pentamethyl-indenyl)silanetitanium (II) 1,4-diphenyl-1,3-butadiene; (1-adamantylamido)ethoxymethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (II) 1,3-pentadiene; (1-adamantylamido)ethoxymethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (III) 2-(N,N-dimethylamino)benzyl; (1-adamantylamido)ethoxymethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dimethyl; and (1-adamantylamido)ethoxymethyl(η5-2,3,4,6,7-pentamethylindenyl)silanetitanium (IV) dibenzyl.
(L*−H)d 30 (A)d− Formula VII
wherein L* is a neutral Lewis base; (L*−H)+ is a Bronsted acid; Ad− is an anion having a charge of d−, and d is an integer from 1 to 3. More preferably Ad− corresponds to the formula: [M′Q4]−, wherein M′ is boron or aluminum in the +3 formal oxidation state; and Q independently each occurrence is selected from hydride, dialkylamido, halide, hydrocarbyl, hydrocarbyloxide, halosubstituted-hydrocarbyl, halosubstituted hydrocarbyloxy, and halo-substituted silylhydrocarbyl radicals (including perhalogenated hydrocarbyl-perhalogenated hydrocarbyloxy- and perhalogenated silylhydrocarbyl radicals), the Q having up to 20 carbons with the proviso that in not more than one occurrence is Q halide. Examples of suitable hydrocarbyloxide Q groups are disclosed in U.S. Pat. No. 5,296,433.
(L*−H)+(M′Q4)−; Formula VIII
wherein L* is as previously defined; M′ is boron or aluminum in a formal oxidation state of 3; and Q is a hydrocarbyl-, hydrocarbyloxy-, fluorinated hydrocarbyl-, fluorinated hydrocarbyloxy-, or fluorinated silylhydrocarbyl-group of up to 20 non-hydrogen atoms, with the proviso that in not more than one occasion is Q hydrocarbyl. Most preferably, Q in each occurrence is a fluorinated aryl group, especially a pentafluorophenyl group. Preferred (L*−H)+ cations are N,N-dimethylanilinium, N,N-di(octadecyl)anilinium, di(o-ctadecyl)methylammonium, methylbis(hydrogenated tallowyl)ammonium, and tributylammonium.
(Oxe+)d(Ad−)e Formula IX
wherein: Oxe+ is a cationic oxidizing agent having a charge of e+; e is an integer from 1 to 3; and Ad− and d are as previously defined.
R3Si(X′)q +A− Formula X
wherein [vinyl] is the concentration of vinyl groups in the isolated polymer in vinyls/1,000 carbon atoms; [vinylidene], [cis], and [trans] are the concentration of vinylidene, cis and trans groups in the isolated polymer in amount/1,000 carbon atoms, respectively. The determination of unsaturated chain ends can be accomplished by methods which are known in the art, including preferably NMR spectroscopy, particularly 13C NMR spectroscopy, and most preferably 1H NMR spectroscopy. An example of the use of 1H NMR spectroscopy to quantify unsaturated chain ends in ethylene/alpha olefin copolymers is given in Hasegawa, et al. (J. Poly. Sci., Part A, Vol 38 (2000), pages 4641-4648), the disclosure of which is incorporated herein by reference.
Mpolyethylene=Ax(Mpolystyrene)B
where M is the molecular weight, A has a value of 0.4316 and B is equal to 1.0. The molecular weight calculations were performed with the Viscotek TriSEC software.
The variable, CumNDj,k, is calculated using the EXCEL™ function “NORMDIST (x, mean, standard_dev, cumulative)” with the parameters set as follows:
x=μj+(k−10)*σj/3
mean=μj
standard dev=σj
cumulative=TRUE
TABLE I |
Variable Definitions |
Variable | |
Name | Definition |
λj,k | Reciprocal of the number average molecular weight |
of most probable (Flory) distribution for component j, | |
normal distribution slice k | |
σj | Sigma (square root of variance) for normal (Gaussian) |
spreading function for component j. | |
wj | Weight fraction of component j |
K | Normalization term (1.0/Loge 10) |
Mi | Molecular weight at elution volume slice i |
hi | Height of log10 (molecular weight) plot at slice i |
n | Number of slices in Log molecular weight plot |
i | Log molecular weight slice index (1 to n) |
j | Component index (1 to 3) |
1. k | Normal distribution slice index |
Δlog10M | Average difference between log10Mi and log10Mi−1 in height |
vs. log10M plot | |
TABLE II |
Constraint summary |
Description | Constraint |
Maximum of fraction 1 | w1 < 0.95 (User adjustable) |
Lower limit of spreading function | σ1, σ2, σ3 > 0.001 (must be positive) |
Upper limit of spreading function | σ1, σ2, σ3 < 0.2 (User adjustable) |
Normalized fractions | w1 + w2 + w3 = 1.0 |
TABLE III |
Solver settings |
Label | Value or selection | ||
Max Time (seconds) | 1000 | ||
Iterations | 100 | ||
Precision | 0.000001 | ||
Tolerance (%) | 5 | ||
Convergence | 0.001 | ||
Estimates | Tangent | ||
Derivatives | Forward | ||
Search | Newton | ||
ALL OTHER SELECTIONS | Not selected | ||
The values of μ1, μ2, w1, and w2 are then calculated. These should be adjusted carefully to allow for a small error term, w3, and to meet the constraints in Table II before entering into Solver for the minimization step. Starting values for σj are all set to 0.05.
-
- plunger speed=0.423 mm/s
- wheel acceleration=2.4 mm/s/s
- capillary diameter=2.1 mm
- capillary length=42 mm
- barrel diameter=9.52 mm
TABLE IV |
Catalyst Properties |
Mole % | ||||
Catalyst | Rv | 1-octene | Mw | |
A | (N-(1,1-dimethylethyl)-1,1-di-(4- | 0.20 | 2.62 | 196,000 |
nbutylphenyl)-1-((1,2,3,3a,7a-η)-3-(1,3- | ||||
dihydro-2H-isoindol-2-yl)-1H-inden-1- | ||||
yl)-silanaminato-(2-)- | ||||
N-)dimethyltitanium | ||||
B | rac-[1,2-ethanediylbis(1-indenyl)]zir- | 0.44 | 0.64 | 19,200 |
conium (1,4-diphenyl-1,3-butadiene) | ||||
C | (C5Me4SiMe2NtBu)Ti(η4-1,3-pentadiene) | 0.17 | 2.01 | 82,000 |
D | dimethylsilyl(2-methyl-s-indacenyl)(t- | 0.23 | 2.28 | 119,400 |
butylamido) titanium 1,3-pentadiene | ||||
E | [(3-Phenylindenyl)SiMe2NtBut]TiMe2 | 0.39 | 2.01 | 85,700 |
F | dimethylamidoborane-bis-η5-(2-methyl- | 0.34 | 3.33 | 44,000 |
4-naphthylinden-1-yl)zirconium η4-1,4- | ||||
diphenyl-1,3-butadiene | ||||
G | (N-(1,1-dimethylethyl)-1,1-dimethyl-1- | 0.44 | 2.97 | 105,000 |
((1,2,3,3a,9a,-h)-5,6,7,8-tetrahydro-3- | ||||
phenyl-5,5,8,8-tetramethy1-1H-benz- | ||||
(f)inden-1-yl)silanaminato(2-)N)- | ||||
dimethyltitanium | ||||
H | bis(n-butylcyclopentadienyl)zirconium | 0.16 | 0.3 | 10,000 |
dimethyl | ||||
I | meso-dimethylsilylbis(1- | 0.07 | 1.11 | 21,600 |
indenyl)]hafnium dimethyl | ||||
TABLE V |
Polymerization conditions and properties of resulting polymer |
ethylene | solvent. | octene | H2 | ethylene | ||
temper- | flow, | flow, | flow, | flow, | conver- | |
Example | ature, C. | lb./hr | lb/hr | lb/hr | sccm | sion, % |
1 | 140.3 | 4.50 | 22.6 | 0.00 | 50.0 | 90.23 |
2 | 139.0 | 4.50 | 26.5 | 0.00 | 5.0 | 90.08 |
3 | 140.2 | 4.50 | 29.2 | 0.00 | 0.0 | 90.20 |
4 | 138.5 | 4.50 | 31.0 | 0.00 | 4.1 | 94.88 |
5 | 140.2 | 4.50 | 31.0 | 0.00 | 4.7 | 94.88 |
6 | 139.8 | 4.50 | 31.0 | 0.00 | 6.9 | 95.15 |
7 | 140.9 | 4.50 | 31.0 | 0.00 | 99.9 | 97.67 |
8 | 140.7 | 4.50 | 31.0 | 0.00 | 75.0 | 98.57 |
9 | 140.8 | 4.50 | 31.0 | 0.00 | 64.9 | 98.53 |
10 | 141.0 | 4.50 | 26.50 | 0.00 | 0.00 | 90.23 |
11 | 140.7 | 4.50 | 26.50 | 0.00 | 0.00 | 90.19 |
12 | 130.3 | 4.50 | 30.20 | 0.70 | 0.00 | 89.97 |
13 | 130.9 | 4.50 | 30.20 | 0.70 | 0.00 | 90.28 |
ppm metal | efficiency, | polymer | ||||
Cat A/ | g/g | production | density, | |||
Example | Cat B | metal | rate, lb/hr | g/mL | I2 | I10/I2 |
1 | 0.65/0.35 | 14,900,000 | 4 | 0.9638 | — | — |
2 | 0.65/0.35 | 20,300,000 | 4 | 0.9609 | — | — |
3 | 0.65/0.35 | 20,500,000 | 4 | 0.9616 | — | — |
4 | 0.65/0.35 | 9,500,000 | 4 | 0.9561 | — | — |
5 | 0.65/0.35 | 9,500,000 | 4 | 0.9594 | — | — |
6 | 0.65/0.35 | 9,500,000 | 4 | 0.9582 | — | — |
7 | 13.52/2.48 | 500,000 | 4 | 0.9579 | — | — |
8 | 13.52/2.48 | 600,000 | 4 | 0.9539 | — | — |
9 | 13.52/2.48 | 600,000 | 4 | 0.9537 | — | — |
10 | 0.31/0.90 | 30,900,000 | 4 | 0.9643 | 9.17 | 8.66 |
11 | 0.15/0.45 | 34,000,000 | 4 | 0.9643 | 10.86 | 8.43 |
12 | 0.72/1.64 | 4,500,000 | 4 | 0.9432 | 1.31 | 16.34 |
13 | 0.72/1.64 | 4,500,000 | 4 | 0.9431 | 0.97 | 16.24 |
ppm | ||||||
Wt % | Wt % | H2 of | ||||
ethyl- | poly- | reactor | ||||
Example | ene | mer | feed | Mw | Mn | MWD |
1 | 100 | — | — | 94,500 | 12,200 | 7.75 |
2 | 100 | — | — | 170,400 | 24200 | 7.04 |
3 | 100 | — | — | 189,900 | 18,700 | 10.16 |
4 | 100 | — | — | 186,400 | 21,600 | 8.63 |
5 | 100 | — | — | 149,800 | 20,500 | 7.31 |
6 | 100 | — | — | 159,500 | 13,900 | 11.47 |
7 | 100 | — | — | 71,700 | 8750 | 8.19 |
8 | 100 | — | — | 87,000 | 15,400 | 5.65 |
9 | 100 | — | — | 99,600 | 16,000 | 6.23 |
10 | 100 | — | — | 56,700 | 18,900 | 3.00 |
11 | 100 | — | — | 54,300 | 36,100 | 2.89 |
12 | 97.4 | — | — | 112,200 | 35,100 | 5.61 |
13 | 97.2 | — | — | 115,100 | 35,600 | 5.40 |
TABLE VI |
Deconvoluted Polymer Properties |
Mw of High | Mn of High | MWD of | Mw of Low | Mn of Low | MWD of | |||
MW | MW | High MW | MW | MW | Low MW | |||
Example | Split | Fraction | Fraction | Fraction | Fraction | Fraction | Fraction | Mw H/ |
1 | 0.28 | 291708 | 136383 | 2.14 | 32,517 | 13790 | 2.36 | 8.98 |
2 | 0.20 | 606850 | 297850 | 2.04 | 39,335 | 17816 | 2.21 | 15.43 |
3 | 0.24 | 743170 | 365057 | 2.04 | 38817 | 17897 | 2.17 | 19.15 |
4 | 0.30 | 578758 | 283139 | 2.04 | 39415 | 17713 | 2.23 | 14.68 |
5 | 0.23 | 575660 | 285589 | 2.02 | 40421 | 17785 | 2.27 | 14.24 |
6 | 0.28 | 540461 | 266306 | 2.03 | 39871 | 17603 | 2.27 | 13.56 |
7 | 0.72 | 110248 | 45076 | 2.45 | 15566 | 6301 | 2.47 | 7.08 |
8 | 0.86 | 99920 | 41537 | 2.41 | 11688 | 4734 | 2.47 | 8.55 |
9 | 0.74 | 137167 | 56167 | 2.44 | 17418 | 7049 | 2.47 | 7.88 |
10 | 0.03 | 663,868 | 268,196 | 2.48 | 40,908 | 18,409 | 2.22 | 16.22 |
11 | 0.03 | 555,572 | 273,900 | 2.03 | 40,669 | 18,298 | 2.22 | 13.66 |
12 | 0.12 | 691,422 | 345,719 | 2.00 | 38,821 | 18,292 | 2.12 | 17.81 |
13 | 0.13 | 659,512 | 327,888 | 2.01 | 38,981 | 18,279 | 2.13 | 16.91 |
TABLE VII |
Polymer Characterization Data |
LDPE | LDPE | ||||||
Resin | Example 1 | Example 2 | Example 3 | Example 4 | 682I | 170A | |
Density | grams/cc | 0.9643 | 0.9643 | 0.9432 | 0.9431 | 0.9211 | 0.9225 | |
I5 | 27.99 | 29.60 | 5.74 | 4.27 | 2.38 | 2.96 | ||
I10 | g/10 min | 79.47 | 91.54 | 21.40 | 15.75 | 8.25 | 9.86 | |
I2 | g/10 min | 9.17 | 10.86 | 1.31 | 0.97 | 0.6923 | 0.5643 | |
I10/I2 | — | 8.66 | 8.43 | 16.34 | 16.24 | 11.9 | 17.5 | |
GPC Data | ||||||||
Mw | — | 56,700 | 54,300 | 112,200 | 115,100 | 84,000 | 91,700 | |
Mp | — | 35600 | 36100 | 35100 | 35600 | 61,300 | 56,500 | |
Mn | — | 18,900 | 36,100 | 35,100 | 35,600 | 25,300 | 17,000 | |
Mw/Mn | — | 3.00 | 2.89 | 5.61 | 5.40 | 3.32 | 5.39 | |
| cN | 7 | 7 | 33 | 36 | 18 | 16 | |
TABLE VIII |
Process Conditions and Polymer Properties for Examples 14-19 |
Melt Strength |
Solv | Ethyl | H2 | Temp | Catalyst B | Catalyst A | Conv | Force | Velocity | ||
Example | kg/lh | kg/hr | sml/min | ° C. | gr/hr | gr/hr | % | I2 | (cN) | mm/s |
14 | 32 | 4.34 | 0 | 143 | 27 | 135 | 91.5 | 0.97 | 28 | 41.6 |
15 | 32 | 3.8 | 19 | 140 | 50 | 45 | 90 | 1.27 | 19 | 60.8 |
16 | 34 | 3.8 | 38 | 140 | 50 | 50 | 92 | 1.05 | 13 | 89.4 |
17 | 34 | 3.8 | 38 | 140 | 50 | 50 | 92 | 0.80 | 13 | 77.4 |
18 | 34 | 3.8 | 54 | 141 | 55 | 67 | 91.5 | 0.99 | 9 | 134.3 |
19 | 34 | 3.8 | 54 | 141 | 55 | 69 | 92 | 0.82 | 9 | 73.2 |
Claims (31)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/604,940 USRE43004E1 (en) | 2001-03-16 | 2009-10-23 | High melt strength polymers and method of making same |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US27671901P | 2001-03-16 | 2001-03-16 | |
US10/100,687 US6875816B2 (en) | 2001-03-16 | 2002-03-15 | High melt strength polymers and method of making same |
US10/920,485 US7300983B2 (en) | 2001-03-16 | 2004-08-17 | High melt strength polymers and method of making same |
US12/604,940 USRE43004E1 (en) | 2001-03-16 | 2009-10-23 | High melt strength polymers and method of making same |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/920,485 Reissue US7300983B2 (en) | 2001-03-16 | 2004-08-17 | High melt strength polymers and method of making same |
Publications (1)
Publication Number | Publication Date |
---|---|
USRE43004E1 true USRE43004E1 (en) | 2011-12-06 |
Family
ID=23057813
Family Applications (8)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/100,557 Expired - Lifetime US6924342B2 (en) | 2001-03-16 | 2002-03-15 | Method of making interpolymers and products made therefrom |
US10/100,687 Ceased US6875816B2 (en) | 2001-03-16 | 2002-03-15 | High melt strength polymers and method of making same |
US10/918,906 Expired - Fee Related US7999039B2 (en) | 2001-03-16 | 2004-08-16 | High melt strength polymers and method of making same |
US10/920,485 Expired - Lifetime US7300983B2 (en) | 2001-03-16 | 2004-08-17 | High melt strength polymers and method of making same |
US11/085,793 Expired - Lifetime US7148305B2 (en) | 2001-03-16 | 2005-03-21 | Method of making interpolymers and products made therefrom |
US11/085,390 Expired - Lifetime US7271221B2 (en) | 2001-03-16 | 2005-03-21 | Method of making interpolymers and products made therefrom |
US12/604,940 Expired - Lifetime USRE43004E1 (en) | 2001-03-16 | 2009-10-23 | High melt strength polymers and method of making same |
US12/604,905 Expired - Lifetime USRE42276E1 (en) | 2001-03-16 | 2009-10-23 | High melt strength polymers and method of making same |
Family Applications Before (6)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/100,557 Expired - Lifetime US6924342B2 (en) | 2001-03-16 | 2002-03-15 | Method of making interpolymers and products made therefrom |
US10/100,687 Ceased US6875816B2 (en) | 2001-03-16 | 2002-03-15 | High melt strength polymers and method of making same |
US10/918,906 Expired - Fee Related US7999039B2 (en) | 2001-03-16 | 2004-08-16 | High melt strength polymers and method of making same |
US10/920,485 Expired - Lifetime US7300983B2 (en) | 2001-03-16 | 2004-08-17 | High melt strength polymers and method of making same |
US11/085,793 Expired - Lifetime US7148305B2 (en) | 2001-03-16 | 2005-03-21 | Method of making interpolymers and products made therefrom |
US11/085,390 Expired - Lifetime US7271221B2 (en) | 2001-03-16 | 2005-03-21 | Method of making interpolymers and products made therefrom |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/604,905 Expired - Lifetime USRE42276E1 (en) | 2001-03-16 | 2009-10-23 | High melt strength polymers and method of making same |
Country Status (16)
Country | Link |
---|---|
US (8) | US6924342B2 (en) |
EP (2) | EP1412398B1 (en) |
JP (5) | JP4249984B2 (en) |
KR (4) | KR100900605B1 (en) |
CN (4) | CN1309744C (en) |
AR (2) | AR033003A1 (en) |
AU (3) | AU2002258526B2 (en) |
BR (2) | BR0208485A (en) |
CA (3) | CA2441028C (en) |
CZ (2) | CZ20032817A3 (en) |
ES (2) | ES2742501T3 (en) |
MX (2) | MXPA03008322A (en) |
MY (2) | MY137183A (en) |
NO (2) | NO20034079L (en) |
PL (2) | PL364603A1 (en) |
WO (2) | WO2002074817A2 (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10259892B2 (en) | 2014-06-24 | 2019-04-16 | Basell Polyolefine Gmbh | Polyethylene composition for injection moulding |
US10442920B2 (en) | 2017-04-19 | 2019-10-15 | Nova Chemicals (International) S.A. | Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations |
US10442921B2 (en) | 2017-04-19 | 2019-10-15 | Nova Chemicals (International) S.A. | Means for increasing the molecular weight and decreasing the density employing mixed homogeneous catalyst formulations |
US10683376B2 (en) | 2017-11-07 | 2020-06-16 | Nova Chemicals (International) S.A. | Manufacturing ethylene interpolymer products at higher production rate |
US10995166B2 (en) | 2017-11-07 | 2021-05-04 | Nova Chemicals (International) S.A. | Ethylene interpolymer products and films |
US11046843B2 (en) | 2019-07-29 | 2021-06-29 | Nova Chemicals (International) S.A. | Ethylene copolymers and films with excellent sealing properties |
Families Citing this family (125)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6576583B1 (en) | 2000-02-11 | 2003-06-10 | Phillips Petroleum Company | Organometal catalyst composition |
MY137183A (en) * | 2001-03-16 | 2009-01-30 | Dow Global Technologies Inc | Method of making interpolymers and products made therefrom |
US6946531B2 (en) | 2001-05-14 | 2005-09-20 | Dow Global Technologies Inc. | Low molecular weight ethylene interpolymers and polymerization process |
WO2003098208A1 (en) * | 2002-05-15 | 2003-11-27 | Dow Global Technologies Inc | Molecular topological frationation of macromolecules |
ES2257710T5 (en) | 2002-10-02 | 2011-11-22 | Dow Global Technologies Llc | ETHYLENE POLYMERS WITH LOW MOLECULAR WEIGHT AND GEL TYPE. |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
US8618219B2 (en) * | 2002-10-15 | 2013-12-31 | Exxonmobil Chemical Patents Inc. | Propylene copolymers for adhesive applications |
US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
US8653169B2 (en) | 2002-10-15 | 2014-02-18 | Exxonmobil Chemical Patents Inc. | Propylene copolymers for adhesive applications |
CN101724110B (en) | 2002-10-15 | 2013-03-27 | 埃克森美孚化学专利公司 | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
EP1590168A4 (en) | 2003-01-16 | 2008-08-06 | Ian Orde Michael Jacobs | Methods, compositions and blends for forming articles having improved environmental stress crack resistance |
US6967228B2 (en) * | 2003-05-01 | 2005-11-22 | Firestone Polymers, Llc | Stable free radical polymers |
US20040220345A1 (en) * | 2003-05-01 | 2004-11-04 | Firestone Polymers, Llc | Stable free radical polymers |
EP1905807B1 (en) | 2003-08-19 | 2010-01-20 | Dow Global Technologies Inc. | Interpolymers suitable for use in hot melt adhesives and processes to prepare same |
EP1664165B1 (en) | 2003-09-05 | 2013-11-13 | Dow Global Technologies LLC | Improved resin compositions for extrusion coating |
WO2005048184A1 (en) * | 2003-11-17 | 2005-05-26 | Nec Corporation | Active learning method and system |
SG151301A1 (en) * | 2004-03-17 | 2009-04-30 | Dow Global Technologies Inc | Catalyst composition comprising shuttling agent for ethylene multi- block copolymer formation |
US8816006B2 (en) | 2004-03-17 | 2014-08-26 | Dow Global Technologies Llc | Compositions of ethylene/α-olefin multi-block interpolymer suitable for films |
US7582716B2 (en) * | 2004-03-17 | 2009-09-01 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for blown films with high hot tack |
ATE461231T1 (en) * | 2004-03-17 | 2010-04-15 | Dow Global Technologies Inc | CATALYST COMPOSITION WITH SHUTTERING AGENT FOR PRODUCING ETHYLENE MULTIBLOCK COPOLYMER |
BRPI0508173B1 (en) * | 2004-03-17 | 2016-03-15 | Dow Global Technologies Inc | multiblock copolymers, polymer, copolymer, a functional derivative, homogeneous polymer blend, process for preparing a propylene-containing multiblock copolymer and process for preparing a 4-methyl-1-pentene multiblock copolymer |
US7355089B2 (en) * | 2004-03-17 | 2008-04-08 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates |
US7803728B2 (en) | 2004-03-17 | 2010-09-28 | Dow Global Technologies Inc. | Fibers made from copolymers of ethylene/α-olefins |
US7504347B2 (en) * | 2004-03-17 | 2009-03-17 | Dow Global Technologies Inc. | Fibers made from copolymers of propylene/α-olefins |
KR101223331B1 (en) * | 2004-03-19 | 2013-01-16 | 다우 글로벌 테크놀로지스 엘엘씨 | Film Layers Made from Polymer Formulations |
WO2006007094A2 (en) * | 2004-06-16 | 2006-01-19 | Dow Global Technologies Inc. | Technique for selecting polymerization modifiers |
JP4765277B2 (en) * | 2004-07-30 | 2011-09-07 | 東ソー株式会社 | Laminated body |
WO2006044149A1 (en) | 2004-10-13 | 2006-04-27 | Exxonmobil Chemical Patents Inc. | Elastomeric reactor blend compositions |
WO2006065651A2 (en) | 2004-12-17 | 2006-06-22 | Dow Global Technologies Inc. | Rheology modified polyethylene compositions |
WO2006101927A2 (en) * | 2005-03-17 | 2006-09-28 | Dow Global Technologies Inc. | Fibers made from copolymers of propylene/alpha-olefins |
MX2007011319A (en) * | 2005-03-17 | 2007-11-08 | Dow Global Technologies Inc | Compositions of ethylene/alpha-olefin multi-block interpolymer suitable for films. |
WO2006101596A1 (en) * | 2005-03-17 | 2006-09-28 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation |
JP4975730B2 (en) * | 2005-03-17 | 2012-07-11 | ダウ グローバル テクノロジーズ エルエルシー | Fibers made from ethylene / α-olefin copolymers |
EP2894176B1 (en) * | 2005-03-17 | 2022-06-01 | Dow Global Technologies LLC | Catalyst composition comprising shuttling agent for regio-irregular multi-block copolymer formation |
US9410009B2 (en) | 2005-03-17 | 2016-08-09 | Dow Global Technologies Llc | Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation |
AU2006227350B2 (en) * | 2005-03-17 | 2011-11-03 | Dow Global Technologies Llc | Compositions of ethylene/alpha-olefin multi-block interpolymer for blown films with high hot tack |
DE102005017200A1 (en) * | 2005-04-13 | 2006-10-19 | Degussa Ag | Use of a high-viscosity, largely amorphous polyolefin for producing a film |
US7279527B2 (en) * | 2005-04-22 | 2007-10-09 | Bridgestone Corporation | Method of converting anionic living end to protected free radical living end and applications thereof |
US7538173B2 (en) * | 2005-11-21 | 2009-05-26 | Equistar Chemicals Lp | Polyolefin compositions |
US7611652B2 (en) * | 2005-11-22 | 2009-11-03 | Shaw Industries Group, Inc. | Monoxially-oriented and annealed films with high cross machine toughness and related process |
CA2529920C (en) * | 2005-12-13 | 2013-08-20 | Nova Chemicals Corporation | On the fly catalyst transitions |
WO2007078697A1 (en) * | 2005-12-29 | 2007-07-12 | Dow Global Technologies Inc. | Low molecular weight ethylene interpolymers, methods of making, and uses thereof |
US20070203299A1 (en) * | 2006-02-27 | 2007-08-30 | Novolen Technology Holdings C.V. | High melt strength polypropylene |
US8354484B2 (en) | 2006-05-17 | 2013-01-15 | Dow Global Technologies, Llc | High temperature solution polymerization process |
JP4506740B2 (en) * | 2006-09-14 | 2010-07-21 | トヨタ自動車株式会社 | Catalyst structure for fuel cell, membrane electrode assembly, fuel cell, and method for producing catalyst structure for fuel cell |
US7737218B2 (en) * | 2006-12-29 | 2010-06-15 | Bridgestone Corporation | Method for generating free radical capable polymers using tin or silicon halide compounds |
US7560509B2 (en) * | 2006-12-29 | 2009-07-14 | Bridgestone Corporation | Method of directing grafting by controlling the location of high vinyl segments in a polymer |
US7396887B1 (en) * | 2006-12-29 | 2008-07-08 | Bridgestone Corporation | Insitu removal of chelator from anionic polymerization reactions |
US8030410B2 (en) * | 2006-12-29 | 2011-10-04 | Bridgestone Corporation | Method for generating free radical capable polymers using carbonyl-containing compounds |
US20080157641A1 (en) * | 2006-12-31 | 2008-07-03 | Rachael Wren Grout | Multi-use Free Standing Seating and Storage Unit |
EP2028218A1 (en) * | 2007-08-24 | 2009-02-25 | Total Petrochemicals Research Feluy | Reinforced and conductive resin compositions comprising polyolefins and poly(hydroxy carboxylic acid) |
EP2030994A1 (en) * | 2007-09-03 | 2009-03-04 | INEOS Manufacturing Belgium NV | Slurry phase polymerisation process |
EP2799235A1 (en) * | 2007-10-22 | 2014-11-05 | Dow Global Technologies LLC | Multilayer films |
ES2435568T3 (en) * | 2007-11-19 | 2013-12-20 | Dow Global Technologies Llc | Propylene-alpha-olefin copolymers with long chain branching |
US20090163666A1 (en) * | 2007-12-21 | 2009-06-25 | David John Lohse | Polymer compositions exhibiting enhanced flow-induced crystallization |
JP5697997B2 (en) * | 2008-02-29 | 2015-04-08 | ダウ グローバル テクノロジーズ エルエルシー | Fibers and fabrics made from ethylene / α-olefin interpolymers |
TWI445751B (en) | 2008-07-16 | 2014-07-21 | Univation Tech Llc | Polyethylene compositions |
CN102292356B (en) * | 2008-11-21 | 2013-09-04 | 陶氏环球技术有限责任公司 | Medium voltage cable sheath comprising an olefin-based polymer |
US20110003940A1 (en) | 2009-07-01 | 2011-01-06 | Dow Global Technologies Inc. | Ethylene-based polymer compositions for use as a blend component in shrinkage film applications |
US8629214B2 (en) | 2009-07-01 | 2014-01-14 | Dow Global Technologies Llc. | Ethylene-based polymer compositions for use as a blend component in shrinkage film applications |
US20110054117A1 (en) * | 2009-08-27 | 2011-03-03 | Hall Gregory K | Polyolefin Adhesive Compositions and Method of Making Thereof |
US8987385B2 (en) * | 2009-09-14 | 2015-03-24 | Dow Global Technologies Llc | Interconnected copolymers of ethylene in combination with one other polyalkene |
US8679639B2 (en) * | 2009-11-24 | 2014-03-25 | Dow Global Technologies Llc | Extrusion coating composition |
EP2348057A1 (en) * | 2010-01-21 | 2011-07-27 | INEOS Manufacturing Belgium NV | Novel polymers |
MX350592B (en) | 2010-05-17 | 2017-09-11 | Dow Global Tech Llc * | Process for selectively polymerizing ethylene and catalyst therefor. |
EP2580279B1 (en) | 2010-06-14 | 2019-01-09 | Dow Global Technologies LLC | Ethylene-based polymer compositions for use as a blend component in shrinkage film applications |
KR20180066258A (en) | 2010-08-25 | 2018-06-18 | 다우 글로벌 테크놀로지스 엘엘씨 | Process for polymerizing a polymerizable olefin and catalyst therefor |
WO2012061706A1 (en) | 2010-11-04 | 2012-05-10 | Dow Global Technologies Llc | Double shuttling of polyolefin polymeryl chains |
KR101863985B1 (en) * | 2011-03-28 | 2018-06-01 | 다우 글로벌 테크놀로지스 엘엘씨 | Process to produce enhanced melt strength ethylene/alpha-olefin copolymers and articles thereof |
EP3290450B1 (en) * | 2011-07-05 | 2019-12-25 | Dow Global Technologies LLC | Composition comprising at least one ethylene-based polymer, prepared from a free-radical polymerization |
JP2013053308A (en) * | 2011-08-11 | 2013-03-21 | Sumitomo Chemical Co Ltd | Olefin polymer producing method, ethylene polymer and mold product |
WO2013101376A1 (en) | 2011-12-29 | 2013-07-04 | Dow Global Technologies Llc | Hyperbranched olefin oil-based dielectric fluid |
US9522855B2 (en) | 2011-12-29 | 2016-12-20 | Dow Global Technologies Llc | Process for producing low molecular weight ethylene- and alpha-olefin-based materials |
KR102006040B1 (en) | 2011-12-31 | 2019-07-31 | 가부시키가이샤 브리지스톤 | Functionalized polymer |
US9115237B2 (en) | 2012-07-18 | 2015-08-25 | Chevron Oronite Company Llc | Viscosity improver grafted with unsaturated acylating agent and an aryloxyalylkene monoamine |
US9045568B2 (en) * | 2012-08-03 | 2015-06-02 | Exxonmobil Chemical Patents Inc. | Vinyl terminated polyethylene with long chain branching |
EP2880096B1 (en) * | 2012-08-03 | 2018-01-03 | ExxonMobil Chemical Patents Inc. | Process for preparing polyalphaolefins using modified salan catalyst compounds and polyalphaolefins prepared therewith |
US9382349B2 (en) * | 2012-08-03 | 2016-07-05 | Exxonmobil Chemical Patents Inc. | Polyalphaolefins prepared using modified Salan catalyst compounds |
BR112015010241B1 (en) | 2012-11-07 | 2021-07-20 | Chevron Phillips Chemical Company Lp | LOW DENSITY POLYOLEFIN RESINS AND FILMS MADE FROM THEM |
AU2014239318A1 (en) | 2013-03-14 | 2015-10-15 | Berry Plastics Corporation | Container |
JP6326202B2 (en) * | 2013-05-16 | 2018-05-16 | 三井化学株式会社 | Solid catalyst component for olefin polymerization and process for producing olefin polymer using the same |
CN105189637B (en) * | 2013-05-22 | 2018-02-06 | 陶氏环球技术有限责任公司 | Composition containing tool high molten intensity low density ethylene based polyalcohol and the film formed by it |
JP2014234403A (en) * | 2013-05-31 | 2014-12-15 | 東ソー株式会社 | Polyethylene resin composition and blow-molded body comprising the same |
JP2014234404A (en) * | 2013-05-31 | 2014-12-15 | 東ソー株式会社 | Polyolefin-based coated electric wire |
ES2589053T3 (en) * | 2013-06-10 | 2016-11-08 | Borealis Ag | Procedure for the preparation of a propylene polymer |
WO2014209256A1 (en) | 2013-06-24 | 2014-12-31 | Dow Global Technologies Llc | Reinforced polypropylene composition |
CA2917475A1 (en) | 2013-07-12 | 2015-01-15 | Berry Plastics Corporation | Polymeric material for container |
TW201521993A (en) | 2013-08-30 | 2015-06-16 | Berry Plastics Corp | Polymeric material for container |
US9181370B2 (en) | 2013-11-06 | 2015-11-10 | Chevron Phillips Chemical Company Lp | Low density polyolefin resins with low molecular weight and high molecular weight components, and films made therefrom |
US9163098B2 (en) | 2014-01-10 | 2015-10-20 | Chevron Phillips Chemical Company Lp | Processes for preparing metallocene-based catalyst systems |
US9273170B2 (en) | 2014-03-12 | 2016-03-01 | Chevron Phillips Chemical Company Lp | Polymers with improved toughness and ESCR for large-part blow molding applications |
US9169337B2 (en) | 2014-03-12 | 2015-10-27 | Chevron Phillips Chemical Company Lp | Polymers with improved ESCR for blow molding applications |
WO2015142547A1 (en) | 2014-03-21 | 2015-09-24 | Exxonmobil Chemical Patents Inc. | Process to produce ethylene propylene copolymers |
US9079993B1 (en) * | 2014-05-22 | 2015-07-14 | Chevron Phillips Chemical Company Lp | High clarity low haze compositions |
US10072110B2 (en) | 2014-06-10 | 2018-09-11 | Lg Chem, Ltd. | Propylene-based elastomer |
JP5743010B1 (en) * | 2014-06-20 | 2015-07-01 | 富士ゼロックス株式会社 | Image forming apparatus, coating apparatus, coating agent, and conveying apparatus |
US9284389B2 (en) | 2014-07-29 | 2016-03-15 | Chevron Phillips Chemical Company Lp | Bimodal resins having good film processability |
CA2868640C (en) | 2014-10-21 | 2021-10-26 | Nova Chemicals Corporation | Solution polymerization process |
WO2016063205A2 (en) | 2014-10-21 | 2016-04-28 | Nova Chemicals (International) S.A. | Dilution index |
WO2016141179A1 (en) | 2015-03-04 | 2016-09-09 | Berry Plastics Corporation | Polymeric material for container |
JP6547484B2 (en) * | 2015-07-22 | 2019-07-24 | 日本ポリエチレン株式会社 | Method for producing ethylene-based polymer having unsaturated bond |
US9650459B2 (en) | 2015-09-09 | 2017-05-16 | Chevron Phillips Chemical Company Lp | Methods for controlling die swell in dual catalyst olefin polymerization systems |
US9493589B1 (en) | 2015-09-09 | 2016-11-15 | Chevron Phillips Chemical Company Lp | Polymers with improved ESCR for blow molding applications |
CA2914166C (en) * | 2015-12-08 | 2022-07-26 | Nova Chemicals Corporation | High density rotomolding resin |
EP3398976A4 (en) | 2015-12-31 | 2020-02-26 | Hanwha Chemical Corporation | Hybrid supported metallocene catalyst, method for preparing olefin polymer by using same, and olefin polymer having improved melt strength |
WO2017127637A1 (en) | 2016-01-22 | 2017-07-27 | Chevron Oronite Company Llc | Synergistic lubricating oil composition containing a mixture of olefin copolymer dispersant-type viscosity improver and amine compound |
WO2017165009A1 (en) | 2016-03-23 | 2017-09-28 | Exxonmobil Chemical Patents, Inc. | Comb-block high density polyethylenes and methods of making them |
WO2017165743A1 (en) * | 2016-03-25 | 2017-09-28 | Arkema France | Enhanced melt strength acrylic formulation |
KR20190021323A (en) * | 2016-06-17 | 2019-03-05 | 보레알리스 아게 | Raw or amorphous polyethylene with low unsaturation levels |
CN109641990B (en) | 2016-07-13 | 2022-08-19 | 埃克森美孚化学专利公司 | Dual metallocene catalyst copolymer compositions |
CN109641989B (en) | 2016-07-13 | 2022-05-03 | 埃克森美孚化学专利公司 | Bimetallic metallocene catalyst copolymer composition |
EP3484984B1 (en) | 2016-07-14 | 2022-08-03 | ExxonMobil Chemical Patents Inc. | Lubricating oil compositions comprising dual metallocene-catalyzed bimodal copolymer compositions useful as viscosity modifiers |
JP6957596B2 (en) * | 2016-07-29 | 2021-11-02 | ダウ グローバル テクノロジーズ エルエルシー | Mixed catalyst system for multimodal elastomer formation |
KR101846412B1 (en) * | 2016-12-06 | 2018-05-18 | 한화케미칼 주식회사 | Transition metal compound used to prepare catalyst for polymerizing olefin, catalyst for polymerizing olefin comprising the same and polyolefin polymerized by using the same |
US10329412B2 (en) | 2017-02-16 | 2019-06-25 | Nova Chemicals (International) S.A. | Caps and closures |
US11193008B2 (en) * | 2017-04-10 | 2021-12-07 | Exxonmobil Chemical Patents Inc. | Methods for making polyolefin polymer compositions |
EP3638730B1 (en) | 2017-06-14 | 2024-05-01 | ExxonMobil Chemical Patents Inc. | Ethylene copolymer blends for cross-linking applications |
US10590213B2 (en) | 2018-03-13 | 2020-03-17 | Chevron Phillips Chemical Company Lp | Bimodal polyethylene resins and pipes produced therefrom |
JP7216184B2 (en) * | 2018-07-23 | 2023-01-31 | エクソンモービル・ケミカル・パテンツ・インク | Preparation of bimodal rubber, thermoplastic vulcanizates and articles made therefrom |
US10882987B2 (en) | 2019-01-09 | 2021-01-05 | Nova Chemicals (International) S.A. | Ethylene interpolymer products having intermediate branching |
CN110156606A (en) * | 2019-05-31 | 2019-08-23 | 镇江巨杰新材料技术研发中心(有限合伙) | The synthetic method and application of a kind of N, N- bis- (octadecyl) aniline |
KR102203007B1 (en) * | 2019-06-05 | 2021-01-14 | 대림산업 주식회사 | Method for manufacturing multimodal polyolefins using multistage continuous polymerization process |
EP4004070A1 (en) * | 2019-07-31 | 2022-06-01 | Dow Global Technologies LLC | Polymerization catalysts for production of polyethylene with high molecular weight |
WO2023130032A1 (en) * | 2021-12-30 | 2023-07-06 | Dow Global Technologies Llc | Multimodal ethylene-based copolymer compositions and processes of producing |
CN115029810B (en) * | 2022-06-17 | 2023-08-01 | 上海化工研究院有限公司 | High-performance polyethylene heavy denier monofilament for wind wave resistant fishery rope net and preparation method thereof |
Citations (48)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3984610A (en) | 1971-04-16 | 1976-10-05 | Du Pont Of Canada Limited | Ethylene polymers with long chain branching |
US4500648A (en) | 1983-04-25 | 1985-02-19 | Exxon Research & Engineering Co. | Long chain branching in polyolefins from ziegler-natta catalysts |
US4530914A (en) | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
US4532052A (en) * | 1978-09-28 | 1985-07-30 | Halliburton Company | Polymeric well treating method |
US4752597A (en) | 1985-12-12 | 1988-06-21 | Exxon Chemical Patents Inc. | New polymerization catalyst |
US4851489A (en) | 1983-04-25 | 1989-07-25 | Exxon Research & Engineering Company | Long chain branching in polyolefins from Ziegler-Natta catalysts |
US4935474A (en) | 1983-06-06 | 1990-06-19 | Exxon Research & Engineering Company | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
US4937299A (en) | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
US4939217A (en) | 1987-04-03 | 1990-07-03 | Phillips Petroleum Company | Process for producing polyolefins and polyolefin catalysts |
US5047485A (en) | 1989-02-21 | 1991-09-10 | Himont Incorporated | Process for making a propylene polymer with free-end long chain branching and use thereof |
US5055438A (en) | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
US5057475A (en) | 1989-09-13 | 1991-10-15 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization |
US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
US5096867A (en) | 1990-06-04 | 1992-03-17 | Exxon Chemical Patents Inc. | Monocyclopentadienyl transition metal olefin polymerization catalysts |
US5272236A (en) | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
US5470811A (en) | 1993-08-06 | 1995-11-28 | Exxon Chemical Patents Inc. | Polymerization catalysts, their production and use |
US5530072A (en) | 1995-04-19 | 1996-06-25 | Mobil Oil Corporation | Introduction of long chain branching into linear polyethylenes |
EP0773257A2 (en) | 1995-11-07 | 1997-05-14 | Union Carbide Chemicals & Plastics Technology Corporation | Film extruded from an in situ blend of ethylene copolymers |
US5631069A (en) * | 1994-05-09 | 1997-05-20 | The Dow Chemical Company | Medium modulus molded material comprising substantially linear polyethlene and fabrication method |
US5665800A (en) | 1991-10-15 | 1997-09-09 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
WO1997048735A1 (en) | 1996-06-17 | 1997-12-24 | Exxon Chemical Patents Inc. | Mixed transition metal catalyst systems for olefin polymerization |
US5703187A (en) | 1989-08-31 | 1997-12-30 | The Dow Chemical Company | Pseudo-random copolymers formed by use of constrained geometry addition polymerization catalysts |
US5703180A (en) | 1992-11-19 | 1997-12-30 | Mitsui Petrochemical Industries, Ltd. | Catalyst for olefin polymerization, process for olefin polymerization using the same, ethylene/α-olefin copolymer, graft modified ethylene/α-olefin copolymer, and ethylene copolymer composition |
US5783638A (en) | 1991-10-15 | 1998-07-21 | The Dow Chemical Company | Elastic substantially linear ethylene polymers |
US5792534A (en) * | 1994-10-21 | 1998-08-11 | The Dow Chemical Company | Polyolefin film exhibiting heat resistivity, low hexane extractives and controlled modulus |
US5795941A (en) * | 1995-10-03 | 1998-08-18 | The Dow Chemical Company | Crosslinkable bimodal polyolefin compositions |
US5849823A (en) * | 1996-09-04 | 1998-12-15 | The Dow Chemical Company | Homogeneously branched ethylene α-olefin interpolymer compositions for use in gasket applications |
US5852152A (en) | 1991-10-15 | 1998-12-22 | The Dow Chemical Company | Packaging and wrapping film |
US5902867A (en) | 1994-05-06 | 1999-05-11 | Dsm Nv | Process for the preparation of an elastomeric polymer from ethylene, alpha-olefine and optionally diene |
US5965756A (en) | 1996-12-19 | 1999-10-12 | The Dow Chemical Company | Fused ring substituted indenyl metal complexes and polymerization process |
US6001941A (en) | 1992-11-19 | 1999-12-14 | Mitsui Chemicals, Inc. | Ethylene α-olefin copolymer obtained by copolymerizing ethylene with an α-olefin |
US6015868A (en) | 1996-10-03 | 2000-01-18 | The Dow Chemical Company | Substituted indenyl containing metal complexes and olefin polymerization process |
US6034021A (en) | 1996-07-22 | 2000-03-07 | The Dow Chemical Company | Metal complexes containing bridged, non-aromatic, anionic, dienyl groups and addition polymerization catalysts therefrom |
US6107147A (en) | 1998-12-18 | 2000-08-22 | Texas Instruments Incorporated | Stacked poly/amorphous silicon gate giving low sheet resistance silicide film at submicron linewidths |
WO2000050466A1 (en) | 1999-02-22 | 2000-08-31 | Borealis Technology Oy | Olefin polymerisation process |
US6114486A (en) | 1996-03-05 | 2000-09-05 | The Dow Chemical Company | Rheology-modified polyolefins |
US6114457A (en) | 1997-02-07 | 2000-09-05 | Exxon Chemical Patents Inc. | High melt strength polyethylene compositions |
US6143854A (en) | 1993-08-06 | 2000-11-07 | Exxon Chemical Patents, Inc. | Polymerization catalysts, their production and use |
US6147180A (en) | 1997-02-07 | 2000-11-14 | Exxon Chemical Patents Inc. | Thermoplastic elastomer compositions from branched olefin copolymers |
EP1059332A1 (en) | 1999-06-10 | 2000-12-13 | Fina Research S.A. | Polypropylene with high melt strength and drawability |
US6185349B1 (en) | 1998-12-18 | 2001-02-06 | Borealis Polymers Oy | Multimodal polymer composition |
WO2001014434A1 (en) | 1999-08-19 | 2001-03-01 | Dupont Dow Elastomers L.L.C. | Process for preparing in a single reactor polymer blends having a broad molecular weight distribution |
US6197910B1 (en) | 1997-12-10 | 2001-03-06 | Exxon Chemical Patents, Inc. | Propylene polymers incorporating macromers |
US6207606B1 (en) | 1998-05-15 | 2001-03-27 | Univation Technologies, Llc | Mixed catalysts and their use in a polymerization process |
US6265493B1 (en) * | 1999-07-21 | 2001-07-24 | The Penn State Research Foundation | Polyolefin graft copolymers derived from linear copolymers of alpha-olefins and divinylbenzene having narrow molecular weight and composition distributions and process for preparing same |
US6277931B1 (en) | 1998-09-22 | 2001-08-21 | Nova Chemical (International) S.A. | Dual reactor ethylene polymerization process |
US6346575B1 (en) | 1998-09-25 | 2002-02-12 | Fina Research, S.A | Production of multimodal polythylene |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US600941A (en) * | 1898-03-22 | Magnetic-clutch and power-station system | ||
US4438238A (en) * | 1981-01-30 | 1984-03-20 | Sumitomo Chemical Company, Limited | Low density copolymer composition of two ethylene-α-olefin copolymers |
US4789714A (en) * | 1983-06-15 | 1988-12-06 | Exxon Research & Engineering Co. | Molecular weight distribution modification in tubular reactor |
US4814135A (en) | 1987-12-22 | 1989-03-21 | Union Carbide Corporation | Process for extrusion |
US5382631A (en) * | 1988-09-30 | 1995-01-17 | Exxon Chemical Patents Inc. | Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distributions |
US5382630A (en) * | 1988-09-30 | 1995-01-17 | Exxon Chemical Patents Inc. | Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distribution |
US5098867A (en) * | 1990-11-13 | 1992-03-24 | Samsung Electronics Co., Ltd. | Heat treatment for compound semiconductor wafer |
JPH0565373A (en) * | 1991-09-06 | 1993-03-19 | Nippon Petrochem Co Ltd | Polyethylene composition |
JP3186218B2 (en) * | 1992-05-20 | 2001-07-11 | 出光興産株式会社 | Terminal vinyl ethylene-propylene copolymer and method for producing the same |
JPH06289518A (en) * | 1993-04-05 | 1994-10-18 | Fuji Photo Film Co Ltd | Silver halide color photographic sensitive material |
DK0705269T3 (en) * | 1993-06-24 | 1997-07-28 | Dow Chemical Co | Titanium (II) or zirconium (II) complexes and addition polymerization catalysts thereof. |
ATE194993T1 (en) * | 1994-04-07 | 2000-08-15 | Bp Chem Int Ltd | POLYMERIZATION PROCESS |
EP0779837B1 (en) * | 1994-09-08 | 2001-08-01 | Mobil Oil Corporation | Catalytic control of the mwd of a broad/bimodal resin in a single reactor |
US5882750A (en) | 1995-07-03 | 1999-03-16 | Mobil Oil Corporation | Single reactor bimodal HMW-HDPE film resin with improved bubble stability |
US5679816A (en) * | 1996-01-03 | 1997-10-21 | The Dow Chemical Company | Preparation of biscyclopentadienyl diene complexes |
KR100486991B1 (en) * | 1996-06-17 | 2005-06-17 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | Mixed transition metal catalyst systems for olefin polymerization |
JPH1112289A (en) * | 1997-06-19 | 1999-01-19 | Sumitomo Chem Co Ltd | Production of crosslinking-type transition metal complex |
WO1999009096A1 (en) * | 1997-08-15 | 1999-02-25 | The Dow Chemical Company | Films produced from substantially linear homogeneous olefin polymer compositions |
JPH11106417A (en) * | 1997-10-06 | 1999-04-20 | Asahi Chem Ind Co Ltd | Ultra-high-molecular-weight ethylene polymer excellent in wear property and composition thereof |
JPH11130807A (en) * | 1997-10-29 | 1999-05-18 | Idemitsu Petrochem Co Ltd | Transition metallic compound, catalyst for polymerizing propylene, production of propylene polymer using the same catalyst and propylene polymer |
US6015898A (en) * | 1998-05-01 | 2000-01-18 | The United States Of America, As Represented By The Secretary Of The Army | Processes and compositions for nitration of N-substituted isowurtzitane compounds with concentrated nitric acid at elevated temperatures to form HNIW and recovery of gamma HNIW with high yields and purities |
AR022608A1 (en) * | 1999-02-17 | 2002-09-04 | Dow Chemical Co | AROMATIC INTERPOLIMERIC PRODUCT OF ALFA-OLEFINA / VINYL OR VINYLIDENE AND PROCESS FOR THEIR DEVELOPMENT THROUGH MULTIPLE CATALYSTING SYSTEMS |
US6114488A (en) * | 1999-03-02 | 2000-09-05 | Air Products And Chemicals, Inc. | Polyurethaneurea elastomers for dynamic applications |
JP2001064314A (en) * | 1999-08-26 | 2001-03-13 | Idemitsu Petrochem Co Ltd | Olefin polymerization catalyst and production of olefin polymer |
US6372868B1 (en) * | 1999-12-07 | 2002-04-16 | Univation Technologies, Llc | Start up methods for multiple catalyst systems |
DE60006146T2 (en) * | 1999-11-04 | 2004-09-30 | Exxonmobil Chemical Patents Inc., Baytown | PROPYLENE COPOLYMER FOAMS AND THEIR USE |
AU1773901A (en) * | 1999-12-10 | 2001-06-18 | Dow Chemical Company, The | Substituted group 4 metal complexes, catalysts and olefin polymerization process |
KR100745227B1 (en) * | 2000-05-26 | 2007-08-01 | 다우 글로벌 테크놀로지스 인크. | Polyethylene Rich/Polypropylene Blends and Their Uses |
US6545094B2 (en) * | 2001-03-09 | 2003-04-08 | The Dow Chemical Company | Blends of ethylenic polymers with improved modulus and melt strength and articles fabricated from these blends |
MY137183A (en) * | 2001-03-16 | 2009-01-30 | Dow Global Technologies Inc | Method of making interpolymers and products made therefrom |
-
2002
- 2002-03-14 MY MYPI20020940A patent/MY137183A/en unknown
- 2002-03-14 MY MYPI20020945A patent/MY131000A/en unknown
- 2002-03-15 JP JP2002573823A patent/JP4249984B2/en not_active Expired - Lifetime
- 2002-03-15 KR KR1020087007775A patent/KR100900605B1/en active IP Right Grant
- 2002-03-15 CN CNB028066960A patent/CN1309744C/en not_active Expired - Lifetime
- 2002-03-15 KR KR1020037012069A patent/KR100880097B1/en active IP Right Grant
- 2002-03-15 AU AU2002258526A patent/AU2002258526B2/en not_active Ceased
- 2002-03-15 AR ARP020100936A patent/AR033003A1/en not_active Application Discontinuation
- 2002-03-15 CN CNB028067029A patent/CN1255439C/en not_active Expired - Fee Related
- 2002-03-15 CA CA2441028A patent/CA2441028C/en not_active Expired - Lifetime
- 2002-03-15 US US10/100,557 patent/US6924342B2/en not_active Expired - Lifetime
- 2002-03-15 CN CNB2006100730457A patent/CN100519588C/en not_active Expired - Fee Related
- 2002-03-15 JP JP2002573822A patent/JP2004536895A/en active Pending
- 2002-03-15 EP EP02728477.7A patent/EP1412398B1/en not_active Expired - Lifetime
- 2002-03-15 US US10/100,687 patent/US6875816B2/en not_active Ceased
- 2002-03-15 EP EP02726644.4A patent/EP1377613B1/en not_active Expired - Lifetime
- 2002-03-15 BR BR0208485-6A patent/BR0208485A/en not_active Application Discontinuation
- 2002-03-15 CA CA2441262A patent/CA2441262C/en not_active Expired - Lifetime
- 2002-03-15 CA CA2797698A patent/CA2797698C/en not_active Expired - Lifetime
- 2002-03-15 CZ CZ20032817A patent/CZ20032817A3/en unknown
- 2002-03-15 ES ES02726644T patent/ES2742501T3/en not_active Expired - Lifetime
- 2002-03-15 CN CN2007100070841A patent/CN101143908B/en not_active Expired - Lifetime
- 2002-03-15 WO PCT/US2002/008121 patent/WO2002074817A2/en active IP Right Grant
- 2002-03-15 MX MXPA03008322A patent/MXPA03008322A/en active IP Right Grant
- 2002-03-15 BR BR0208486-4A patent/BR0208486A/en not_active Application Discontinuation
- 2002-03-15 PL PL02364603A patent/PL364603A1/en not_active Application Discontinuation
- 2002-03-15 PL PL02368551A patent/PL368551A1/en not_active Application Discontinuation
- 2002-03-15 AR ARP020100935A patent/AR033002A1/en not_active Application Discontinuation
- 2002-03-15 KR KR1020087007772A patent/KR100898436B1/en active IP Right Grant
- 2002-03-15 KR KR1020037012067A patent/KR100917540B1/en active IP Right Grant
- 2002-03-15 ES ES02728477T patent/ES2734429T3/en not_active Expired - Lifetime
- 2002-03-15 WO PCT/US2002/007919 patent/WO2002074816A2/en not_active Application Discontinuation
- 2002-03-15 MX MXPA03008321A patent/MXPA03008321A/en active IP Right Grant
- 2002-03-15 CZ CZ20032816A patent/CZ20032816A3/en unknown
-
2003
- 2003-09-15 NO NO20034079A patent/NO20034079L/en not_active Application Discontinuation
- 2003-09-15 NO NO20034078A patent/NO20034078L/en not_active Application Discontinuation
-
2004
- 2004-08-16 US US10/918,906 patent/US7999039B2/en not_active Expired - Fee Related
- 2004-08-17 US US10/920,485 patent/US7300983B2/en not_active Expired - Lifetime
-
2005
- 2005-03-21 US US11/085,793 patent/US7148305B2/en not_active Expired - Lifetime
- 2005-03-21 US US11/085,390 patent/US7271221B2/en not_active Expired - Lifetime
-
2007
- 2007-02-02 AU AU2007200466A patent/AU2007200466B2/en not_active Ceased
- 2007-07-19 AU AU2007203338A patent/AU2007203338B2/en not_active Ceased
-
2008
- 2008-03-06 JP JP2008056619A patent/JP2008179825A/en not_active Withdrawn
- 2008-04-21 JP JP2008110304A patent/JP2008231433A/en active Pending
-
2009
- 2009-10-23 US US12/604,940 patent/USRE43004E1/en not_active Expired - Lifetime
- 2009-10-23 US US12/604,905 patent/USRE42276E1/en not_active Expired - Lifetime
-
2011
- 2011-08-26 JP JP2011184218A patent/JP5323150B2/en not_active Expired - Fee Related
Patent Citations (51)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3984610A (en) | 1971-04-16 | 1976-10-05 | Du Pont Of Canada Limited | Ethylene polymers with long chain branching |
US4532052A (en) * | 1978-09-28 | 1985-07-30 | Halliburton Company | Polymeric well treating method |
US4500648A (en) | 1983-04-25 | 1985-02-19 | Exxon Research & Engineering Co. | Long chain branching in polyolefins from ziegler-natta catalysts |
US4851489A (en) | 1983-04-25 | 1989-07-25 | Exxon Research & Engineering Company | Long chain branching in polyolefins from Ziegler-Natta catalysts |
US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
US4530914A (en) | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
US4935474A (en) | 1983-06-06 | 1990-06-19 | Exxon Research & Engineering Company | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
US4937299A (en) | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
US4752597A (en) | 1985-12-12 | 1988-06-21 | Exxon Chemical Patents Inc. | New polymerization catalyst |
US4939217A (en) | 1987-04-03 | 1990-07-03 | Phillips Petroleum Company | Process for producing polyolefins and polyolefin catalysts |
US5047485A (en) | 1989-02-21 | 1991-09-10 | Himont Incorporated | Process for making a propylene polymer with free-end long chain branching and use thereof |
US5703187A (en) | 1989-08-31 | 1997-12-30 | The Dow Chemical Company | Pseudo-random copolymers formed by use of constrained geometry addition polymerization catalysts |
US5055438A (en) | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
US5057475A (en) | 1989-09-13 | 1991-10-15 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization |
US5132380A (en) | 1989-09-14 | 1992-07-21 | The Dow Chemical Company | Metal complex compounds |
US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
US5096867A (en) | 1990-06-04 | 1992-03-17 | Exxon Chemical Patents Inc. | Monocyclopentadienyl transition metal olefin polymerization catalysts |
US5272236A (en) | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
US5852152A (en) | 1991-10-15 | 1998-12-22 | The Dow Chemical Company | Packaging and wrapping film |
US5783638A (en) | 1991-10-15 | 1998-07-21 | The Dow Chemical Company | Elastic substantially linear ethylene polymers |
US5685128A (en) | 1991-10-15 | 1997-11-11 | The Dow Chemical Company | Method of packaging food products |
US5665800A (en) | 1991-10-15 | 1997-09-09 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
US5703180A (en) | 1992-11-19 | 1997-12-30 | Mitsui Petrochemical Industries, Ltd. | Catalyst for olefin polymerization, process for olefin polymerization using the same, ethylene/α-olefin copolymer, graft modified ethylene/α-olefin copolymer, and ethylene copolymer composition |
US6001941A (en) | 1992-11-19 | 1999-12-14 | Mitsui Chemicals, Inc. | Ethylene α-olefin copolymer obtained by copolymerizing ethylene with an α-olefin |
US5470811A (en) | 1993-08-06 | 1995-11-28 | Exxon Chemical Patents Inc. | Polymerization catalysts, their production and use |
US6143854A (en) | 1993-08-06 | 2000-11-07 | Exxon Chemical Patents, Inc. | Polymerization catalysts, their production and use |
US5902867A (en) | 1994-05-06 | 1999-05-11 | Dsm Nv | Process for the preparation of an elastomeric polymer from ethylene, alpha-olefine and optionally diene |
US5631069A (en) * | 1994-05-09 | 1997-05-20 | The Dow Chemical Company | Medium modulus molded material comprising substantially linear polyethlene and fabrication method |
US5792534A (en) * | 1994-10-21 | 1998-08-11 | The Dow Chemical Company | Polyolefin film exhibiting heat resistivity, low hexane extractives and controlled modulus |
US5530072A (en) | 1995-04-19 | 1996-06-25 | Mobil Oil Corporation | Introduction of long chain branching into linear polyethylenes |
US5795941A (en) * | 1995-10-03 | 1998-08-18 | The Dow Chemical Company | Crosslinkable bimodal polyolefin compositions |
EP0773257A2 (en) | 1995-11-07 | 1997-05-14 | Union Carbide Chemicals & Plastics Technology Corporation | Film extruded from an in situ blend of ethylene copolymers |
US6114486A (en) | 1996-03-05 | 2000-09-05 | The Dow Chemical Company | Rheology-modified polyolefins |
WO1997048735A1 (en) | 1996-06-17 | 1997-12-24 | Exxon Chemical Patents Inc. | Mixed transition metal catalyst systems for olefin polymerization |
US6034021A (en) | 1996-07-22 | 2000-03-07 | The Dow Chemical Company | Metal complexes containing bridged, non-aromatic, anionic, dienyl groups and addition polymerization catalysts therefrom |
US5849823A (en) * | 1996-09-04 | 1998-12-15 | The Dow Chemical Company | Homogeneously branched ethylene α-olefin interpolymer compositions for use in gasket applications |
US6015868A (en) | 1996-10-03 | 2000-01-18 | The Dow Chemical Company | Substituted indenyl containing metal complexes and olefin polymerization process |
US5965756A (en) | 1996-12-19 | 1999-10-12 | The Dow Chemical Company | Fused ring substituted indenyl metal complexes and polymerization process |
US6114457A (en) | 1997-02-07 | 2000-09-05 | Exxon Chemical Patents Inc. | High melt strength polyethylene compositions |
US6147180A (en) | 1997-02-07 | 2000-11-14 | Exxon Chemical Patents Inc. | Thermoplastic elastomer compositions from branched olefin copolymers |
US6197910B1 (en) | 1997-12-10 | 2001-03-06 | Exxon Chemical Patents, Inc. | Propylene polymers incorporating macromers |
US6207606B1 (en) | 1998-05-15 | 2001-03-27 | Univation Technologies, Llc | Mixed catalysts and their use in a polymerization process |
US6277931B1 (en) | 1998-09-22 | 2001-08-21 | Nova Chemical (International) S.A. | Dual reactor ethylene polymerization process |
US6346575B1 (en) | 1998-09-25 | 2002-02-12 | Fina Research, S.A | Production of multimodal polythylene |
US6107147A (en) | 1998-12-18 | 2000-08-22 | Texas Instruments Incorporated | Stacked poly/amorphous silicon gate giving low sheet resistance silicide film at submicron linewidths |
US6185349B1 (en) | 1998-12-18 | 2001-02-06 | Borealis Polymers Oy | Multimodal polymer composition |
WO2000050466A1 (en) | 1999-02-22 | 2000-08-31 | Borealis Technology Oy | Olefin polymerisation process |
EP1059332A1 (en) | 1999-06-10 | 2000-12-13 | Fina Research S.A. | Polypropylene with high melt strength and drawability |
US6265493B1 (en) * | 1999-07-21 | 2001-07-24 | The Penn State Research Foundation | Polyolefin graft copolymers derived from linear copolymers of alpha-olefins and divinylbenzene having narrow molecular weight and composition distributions and process for preparing same |
WO2001014434A1 (en) | 1999-08-19 | 2001-03-01 | Dupont Dow Elastomers L.L.C. | Process for preparing in a single reactor polymer blends having a broad molecular weight distribution |
US6369176B1 (en) | 1999-08-19 | 2002-04-09 | Dupont Dow Elastomers Llc | Process for preparing in a single reactor polymer blends having a broad molecular weight distribution |
Non-Patent Citations (1)
Title |
---|
International Search Report, Jan. 24, 2003. |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10259892B2 (en) | 2014-06-24 | 2019-04-16 | Basell Polyolefine Gmbh | Polyethylene composition for injection moulding |
US10442920B2 (en) | 2017-04-19 | 2019-10-15 | Nova Chemicals (International) S.A. | Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations |
US10442921B2 (en) | 2017-04-19 | 2019-10-15 | Nova Chemicals (International) S.A. | Means for increasing the molecular weight and decreasing the density employing mixed homogeneous catalyst formulations |
US10738183B2 (en) | 2017-04-19 | 2020-08-11 | Nova Chemicals (International) S.A. | Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations |
US11015044B2 (en) | 2017-04-19 | 2021-05-25 | Nova Chemicals (International) S.A. | Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing mixed homogeneous catalyst formulations |
US11111368B2 (en) | 2017-04-19 | 2021-09-07 | Nova Chemicals (International) S.A. | Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations |
US10683376B2 (en) | 2017-11-07 | 2020-06-16 | Nova Chemicals (International) S.A. | Manufacturing ethylene interpolymer products at higher production rate |
US10995166B2 (en) | 2017-11-07 | 2021-05-04 | Nova Chemicals (International) S.A. | Ethylene interpolymer products and films |
US11708437B2 (en) | 2017-11-07 | 2023-07-25 | Nova Chemicals (International) S.A. | Ethylene interpolymer products and films |
US11773197B2 (en) | 2017-11-07 | 2023-10-03 | Nova Chemicals (International) S.A. | Manufacturing ethylene interpolymer products at higher production rate |
US11046843B2 (en) | 2019-07-29 | 2021-06-29 | Nova Chemicals (International) S.A. | Ethylene copolymers and films with excellent sealing properties |
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
USRE43004E1 (en) | High melt strength polymers and method of making same | |
AU2002258526A1 (en) | High melt strength polymers and method of making same | |
US20030050411A1 (en) | Use of polar monomers in olefin polymerization and polymers thereof | |
AU2002257063B2 (en) | Method of making interpolymers and products made therefrom | |
AU2002257063A1 (en) | Method of making interpolymers and products made therefrom |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FPAY | Fee payment |
Year of fee payment: 8 |
|
AS | Assignment |
Owner name: THE DOW CHEMICAL COMPANY, MICHIGAN Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:DEGROOT, ALEXANDER W.;STEVENS, JAMES C.;DESJARDINS, SYLVIE Y.;AND OTHERS;SIGNING DATES FROM 20020503 TO 20020530;REEL/FRAME:043892/0374 Owner name: DOW GLOBAL TECHNOLOGIES LLC, MICHIGAN Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:THE DOW CHEMICAL COMPANY;REEL/FRAME:044344/0355 Effective date: 20030904 |
|
MAFP | Maintenance fee payment |
Free format text: PAYMENT OF MAINTENANCE FEE, 12TH YEAR, LARGE ENTITY (ORIGINAL EVENT CODE: M1553); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY Year of fee payment: 12 |