WO1986000093A1 - Method for producing diamond-like carbon layers - Google Patents
Method for producing diamond-like carbon layers Download PDFInfo
- Publication number
- WO1986000093A1 WO1986000093A1 PCT/EP1985/000275 EP8500275W WO8600093A1 WO 1986000093 A1 WO1986000093 A1 WO 1986000093A1 EP 8500275 W EP8500275 W EP 8500275W WO 8600093 A1 WO8600093 A1 WO 8600093A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- substrate
- plasma discharge
- hydrocarbon
- hydrogen
- gases
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/26—Deposition of carbon only
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/11—Anti-reflection coatings
- G02B1/111—Anti-reflection coatings using layers comprising organic materials
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/14—Protective coatings, e.g. hard coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/28—Other inorganic materials
- C03C2217/282—Carbides, silicides
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
- C03C2218/152—Deposition methods from the vapour phase by cvd
- C03C2218/153—Deposition methods from the vapour phase by cvd by plasma-enhanced cvd
Definitions
- the invention relates to a process for the production of diamond-like carbon layers, in which hydrocarbons and hydrogen optionally in
- Presence of an inert gas can be ionized by a plasma discharge.
- Diamond-like carbon layers are used in particular for the coating of IR optics, for example lenses, mirrors or the like. Such objects are coated under vacuum conditions, a gas mixture of hydrocarbons, for example acetylene, and a noble gas, for example argon, being exposed to a plasma discharge.
- the layers produced in this way are not transparent in the visible wavelength range and are of a yellow, brownish blue or black color. For this reason, these layers cannot be used as a scratch layer for optics in the visible spectral range, but only for the IR wavelength range. From GB-A-2 128 637 a method for cutting a diamond-like carbon film is known, in which carbon and other ions are generated in separate fixed sources, directed onto a surface of the substrate to be coated and accelerated .
- the function of the second type of ion is to remove the undesired carbon forms from the film formed by so-called chemical sputtering. Hydrogen is also used for this purpose.
- the substrate is heated to a temperature of 100 to 200 ° C. In this way, yellow to brown colored layers are obtained, which are also suitable for IR optics.
- the substrate to 'obtain a must all-round coating can be rotated relative to the sources. Coating larger quantities at the same time is technically possible but very complex.
- Another disadvantage is that a relatively low growth rate of typically 0.1 to 1 ⁇ m per hour can be achieved.
- the object of the present invention is to create a method for producing undyed diamond-like carbon layers which are also transparent in the visible region and which are moreover low in internal stress. Furthermore, the procedure should also enable a simultaneous, homogeneous coating of large quantities.
- a hydrocarbon gas or a mixture of hydrocarbon gases and pure hydrogen is fed to the substrate to be coated and is at room temperature, and in that an oxygen-free plasma discharge by high-frequency excitation around the substrate is generated, which is carried by the supplied gases themselves, the gases being excited, dissociated, ionized and accelerated onto the substrate in the plasma discharge.
- the partial pressure of the coal Hydrogen gas is preferably between 10 " and 1 mbar and the ratio of the partial pressures hydrocarbon: hydrogen is between 0.05 and 20, preferably 0.5 and 10.
- the ratio of the partial pressures is Hydrocarbon: noble gas between 0.1 and 10, preferably 1 and 5.
- the coating is introduced under vacuum conditions, preferably at a residual gas pressure of less than 2 x 10 mbar.
- the coating according to the invention is carried out without the need to heat the substrate beforehand or during the coating.
- the temperature of the substrate is preferably 10 to 20 ° C. Cooling down to - 100 ° C is possible.
- the plasma discharge takes place at low voltages, e.g. B. between 50 to 600 volts, preferably 150 to 250 volts.
- the coating process is carried out intermittently.
- the hydrocarbon supply is interrupted during the temporary interruptions, so that the substrate is only bombarded with noble gas and / or hydrogen.
- the partial pressure of the noble gas and / or hydrogen can be increased.
- z. B each 1 second to 20 minutes, preferably 2 seconds to 2 minutes, coated and 1 second to 10 minutes, preferably 1 second to 1 minute, the hydrocarbon supply is interrupted.
- Any saturated or unsaturated hydrocarbons with possibly no more than 10 carbon atoms can be used as hydrocarbons, e.g. B. acetylene, ethylene, methyl alcohol and the like. According to the invention, pure hydrogen and pure noble gases are used.
- All working gases can be mixed in the specified composition and then admitted, or they are fed individually into the discharge space, where they mix.
- the coating apparatus e.g. B. a diode system, triode or thermally supported triode system but also magnetic field supported systems is evacuated according to the invention to a pressure of less than 2 x 10 " mbar, if possible. The working gases are then let in in the desired mixing ratio.
- the process is carried out dynamically, i. H. the gas supply is regulated in such a way that the above-mentioned working pressure is reached while the vacuum pump is running. After the working pressure has been adjusted, the plasma discharge is ignited and burns homogeneously around the substrate to be coated if the process is carried out appropriately. High frequency excitation is usually used to maintain the plasma discharge.
- the working gases are excited, dissociated and ionized in the plasma room. Due to the negative bias on the substrate, which is known to be pre-cleaned Ions are drawn from the plasma space onto this. They hit there with a sufficiently high energy, as a result of which the crystal lattice of the layer at least partially receives a diamond structure.
- transparent and uncolored layers can also be produced in the visible wavelength range.
- larger layer thicknesses can be produced since the layers deposited by the method according to the invention have lower internal stresses.
- the diamond-like carbon layers also show a high hardness of more than 3,500 HV, high resistivity of up to 10 -5-O-cm, a low coefficient of friction, especially in vacuum, which also makes them ideal for space applications.
- the method according to the invention enables a large growth rate of up to 10 ⁇ per second. Since the substrates can be coated on all sides without rotation in a vacuum, it is possible to coat large quantities simultaneously during one operation. .
- the glass sheet was then placed in a commercial coating facility that was at a residual gas pressure
- Example 1 A cylindrical glass body with a diameter of 3.5 mm and a length of 25 mm was cleaned as described in Example 1. After the coating system had been evacuated to the values given in Example 1, the following gases were admitted:
- the discharge voltage was 150 volts.
- the coating was carried out for 40 minutes. A layer thickness of 3 ⁇ was achieved. The shift was. adheres well and very hard.
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE8585902985T DE3581501D1 (de) | 1984-06-12 | 1985-06-07 | Verfahren zur herstellung von diamantartigen kohlenstoffschichten. |
AT85902985T ATE60371T1 (de) | 1984-06-12 | 1985-06-07 | Verfahren zur herstellung von diamantartigen kohlenstoffschichten. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP3421739.8 | 1984-06-12 | ||
DE19843421739 DE3421739A1 (de) | 1984-06-12 | 1984-06-12 | Verfahren zur herstellung von diamantartigen kohlenstoffschichten |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1986000093A1 true WO1986000093A1 (en) | 1986-01-03 |
Family
ID=6238146
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1985/000275 WO1986000093A1 (en) | 1984-06-12 | 1985-06-07 | Method for producing diamond-like carbon layers |
Country Status (7)
Country | Link |
---|---|
US (1) | US4728529A (de) |
EP (1) | EP0182889B1 (de) |
JP (1) | JPS61502403A (de) |
CA (1) | CA1269061C (de) |
DE (2) | DE3421739A1 (de) |
DK (1) | DK260785A (de) |
WO (1) | WO1986000093A1 (de) |
Cited By (8)
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---|---|---|---|---|
EP0259791A1 (de) * | 1986-09-06 | 1988-03-16 | Forschungszentrum Jülich Gmbh | Verfahren zur Herstellung von Werkstücken mit einer Oberflächenschicht aus Kohlenstoff |
EP0259792A1 (de) * | 1986-09-06 | 1988-03-16 | Forschungszentrum Jülich Gmbh | Verfahren zur Herstellung von wärmebelasteten Bauelementen mit einer schützenden Schicht |
FR2606165A1 (fr) * | 1986-06-18 | 1988-05-06 | Raytheon Co | Procede pour faire adherer une couche de carbone dur sur une base, notamment pour elements optiques |
EP0279898A1 (de) * | 1987-02-27 | 1988-08-31 | Ernst Winter & Sohn (GmbH & Co.) | Verfahren zum Auftragen einer Verschleissschutzschicht und danach hergestelltes Ezeugnis |
EP0605814A1 (de) * | 1993-01-07 | 1994-07-13 | International Business Machines Corporation | Diamantähnliche Kohlenstoffilme hergestellt aus einem Kohlenwasserstoff-Helium-Plasma |
US5546770A (en) * | 1993-04-06 | 1996-08-20 | Citizen Watch Co., Ltd. | Knitting parts of knitting machine |
WO2002036513A2 (en) * | 2000-10-30 | 2002-05-10 | Guardian Industries Corp. | Low-e coating system including protective dlc |
WO2002038515A3 (en) * | 2000-10-30 | 2002-07-04 | Guardian Industries | Solar management coating system including protective dlc |
Families Citing this family (47)
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---|---|---|---|---|
DE3442208C3 (de) * | 1984-11-19 | 1998-06-10 | Leybold Ag | Verfahren und Vorrichtung zum Herstellen harter Kohlenstoffschichten |
DE3538261A1 (de) * | 1985-10-28 | 1987-04-30 | Battelle Institut E V | Gegeneinander abdichtende ventilelemente fuer mischarmaturen |
DD243514B1 (de) * | 1985-12-17 | 1989-04-26 | Karl Marx Stadt Tech Hochschul | Hartstoffschichten fuer mechanisch und korrosiv beanspruchte teile |
JPS62202899A (ja) * | 1986-03-03 | 1987-09-07 | Nippon Gakki Seizo Kk | 装飾品の製法 |
JPH0676666B2 (ja) * | 1987-02-10 | 1994-09-28 | 株式会社半導体エネルギ−研究所 | 炭素膜作製方法 |
US4926791A (en) | 1987-04-27 | 1990-05-22 | Semiconductor Energy Laboratory Co., Ltd. | Microwave plasma apparatus employing helmholtz coils and ioffe bars |
JPS6461396A (en) * | 1987-09-01 | 1989-03-08 | Idemitsu Petrochemical Co | Synthesis of diamond and installation therefor |
NL8800911A (nl) * | 1987-09-30 | 1989-04-17 | Pelt & Hooykaas | Optisch element voor het behandelen van licht, werkwijze voor het vervaardigen van een dergelijk optisch element en een dergelijke optische elementen omvattende laseropstelling. |
US5055318A (en) * | 1988-10-11 | 1991-10-08 | Beamalloy Corporation | Dual ion beam ballistic alloying process |
US4992298A (en) * | 1988-10-11 | 1991-02-12 | Beamalloy Corporation | Dual ion beam ballistic alloying process |
US4958590A (en) * | 1989-09-06 | 1990-09-25 | General Atomics | Microwave traveling-wave diamond production device and method |
US5023109A (en) * | 1989-09-06 | 1991-06-11 | General Atomics | Deposition of synthetic diamonds |
US4976324A (en) * | 1989-09-22 | 1990-12-11 | Baker Hughes Incorporated | Drill bit having diamond film cutting surface |
US5095052A (en) * | 1990-06-28 | 1992-03-10 | The United States Of America As Represented By The Secretary Of The Air Force | Low impulse coatings |
US5337844A (en) * | 1992-07-16 | 1994-08-16 | Baker Hughes, Incorporated | Drill bit having diamond film cutting elements |
US5474816A (en) * | 1993-04-16 | 1995-12-12 | The Regents Of The University Of California | Fabrication of amorphous diamond films |
DE19544498C2 (de) * | 1994-12-10 | 1997-10-30 | Antec Angewandte Neue Technolo | Verfahren zur plasmaunterstützten Abscheidung von dünnen Schichten |
US5677003A (en) * | 1995-10-30 | 1997-10-14 | Sam Shin Precision, Co., Ltd. | Method for coating diamond-like carbon on head drums of a video cassette recorder |
US5986857A (en) * | 1997-02-13 | 1999-11-16 | Sanyo Electric Co., Ltd. | Thin film magnetic head including adhesion enhancing interlayers, and upper and lower gap insulative layers having different hydrogen contents and internal stress states |
US6964731B1 (en) * | 1998-12-21 | 2005-11-15 | Cardinal Cg Company | Soil-resistant coating for glass surfaces |
US6974629B1 (en) | 1999-08-06 | 2005-12-13 | Cardinal Cg Company | Low-emissivity, soil-resistant coating for glass surfaces |
US6660365B1 (en) * | 1998-12-21 | 2003-12-09 | Cardinal Cg Company | Soil-resistant coating for glass surfaces |
US6572935B1 (en) * | 1999-03-13 | 2003-06-03 | The Regents Of The University Of California | Optically transparent, scratch-resistant, diamond-like carbon coatings |
US6261693B1 (en) * | 1999-05-03 | 2001-07-17 | Guardian Industries Corporation | Highly tetrahedral amorphous carbon coating on glass |
US6303225B1 (en) | 2000-05-24 | 2001-10-16 | Guardian Industries Corporation | Hydrophilic coating including DLC on substrate |
US20010044027A1 (en) * | 1999-12-30 | 2001-11-22 | Anderson Jerrel Charles | Diamond-like carbon coating on glass for added hardness and abrasion resistance |
US20040028906A1 (en) * | 2000-01-04 | 2004-02-12 | Anderson Jerrel Charles | Diamond-like carbon coating on glass and plastic for added hardness and abrasion resistance |
US6713179B2 (en) * | 2000-05-24 | 2004-03-30 | Guardian Industries Corp. | Hydrophilic DLC on substrate with UV exposure |
US6524755B2 (en) | 2000-09-07 | 2003-02-25 | Gray Scale Technologies, Inc. | Phase-shift masks and methods of fabrication |
US20020051286A1 (en) * | 2000-10-27 | 2002-05-02 | Honeywell, Inc. | Wavlength specific coating for mirrored optics and method for reducing reflection of white light |
US6783253B2 (en) * | 2002-03-21 | 2004-08-31 | Guardian Industries Corp. | First surface mirror with DLC coating |
JP2004220968A (ja) * | 2003-01-16 | 2004-08-05 | Pioneer Electronic Corp | ディスプレイパネルおよびその製造方法 |
US20040154528A1 (en) * | 2003-02-11 | 2004-08-12 | Page Robert E. | Method for making synthetic gems comprising elements recovered from humans or animals and the product thereof |
US7306778B2 (en) * | 2003-06-19 | 2007-12-11 | Nanotech Llc | Diamond films and methods of making diamond films |
EP1713736B1 (de) * | 2003-12-22 | 2016-04-27 | Cardinal CG Company | Gradierte photokatalytische beschichtungen und verfahren zur herstellung |
DE602005003228T2 (de) | 2004-07-12 | 2008-08-28 | Cardinal Cg Co., Eden Prairie | Wartungsarme beschichtungen |
US8092660B2 (en) * | 2004-12-03 | 2012-01-10 | Cardinal Cg Company | Methods and equipment for depositing hydrophilic coatings, and deposition technologies for thin films |
US7923114B2 (en) * | 2004-12-03 | 2011-04-12 | Cardinal Cg Company | Hydrophilic coatings, methods for depositing hydrophilic coatings, and improved deposition technology for thin films |
US7989094B2 (en) * | 2006-04-19 | 2011-08-02 | Cardinal Cg Company | Opposed functional coatings having comparable single surface reflectances |
US20080011599A1 (en) | 2006-07-12 | 2008-01-17 | Brabender Dennis M | Sputtering apparatus including novel target mounting and/or control |
US7820309B2 (en) * | 2007-09-14 | 2010-10-26 | Cardinal Cg Company | Low-maintenance coatings, and methods for producing low-maintenance coatings |
DE102010052971A1 (de) | 2010-11-30 | 2012-05-31 | Amg Coating Technologies Gmbh | Werkstück mit Si-DLC Beschichtung und Verfahren zur Herstellung von Beschichtungen |
EP2628817B1 (de) | 2012-02-15 | 2016-11-02 | IHI Hauzer Techno Coating B.V. | Beschichteter Artikel aus Martensitstahl und Verfahren zur Herstellung eines beschichteten Artikels aus Stahl |
EP2628822B1 (de) | 2012-02-15 | 2015-05-20 | IHI Hauzer Techno Coating B.V. | Stromisolierende Lagerkomponenten und Lager |
DE102012007796A1 (de) | 2012-04-20 | 2013-10-24 | Amg Coating Technologies Gmbh | Beschichtung enthaltend Si-DLC, DLC und Me-DLC und Verfahren zur Herstellung von Beschichtungen |
DE102012007763A1 (de) | 2012-04-20 | 2013-10-24 | Ulrich Schmidt | Modularer Rahmen für Steckdosen und Schalter |
EP3541762B1 (de) | 2016-11-17 | 2022-03-02 | Cardinal CG Company | Statisch-dissipative beschichtungstechnologie |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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US3167449A (en) * | 1961-04-26 | 1965-01-26 | Gen Electric | Method of forming carbon coating |
DE3047888A1 (de) * | 1980-12-19 | 1982-07-15 | Philips Patentverwaltung Gmbh, 2000 Hamburg | "schneidwerkzeug, verfahren zu seiner herstellung und seine verwendung" |
US4410504A (en) * | 1982-04-30 | 1983-10-18 | United Technologies Corporation | Method of producing high density carbon |
US4434188A (en) * | 1981-12-17 | 1984-02-28 | National Institute For Researches In Inorganic Materials | Method for synthesizing diamond |
Family Cites Families (3)
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US3167444A (en) * | 1962-11-19 | 1965-01-26 | Nashua Corp | Heat responsive marking sheets |
JPS5856249B2 (ja) * | 1978-09-07 | 1983-12-14 | 松下電子工業株式会社 | プラズマ反応による薄膜の製造方法 |
US4486286A (en) * | 1982-09-28 | 1984-12-04 | Nerken Research Corp. | Method of depositing a carbon film on a substrate and products obtained thereby |
-
1984
- 1984-06-12 DE DE19843421739 patent/DE3421739A1/de active Granted
-
1985
- 1985-06-07 US US06/813,280 patent/US4728529A/en not_active Expired - Fee Related
- 1985-06-07 JP JP60502667A patent/JPS61502403A/ja active Pending
- 1985-06-07 EP EP85902985A patent/EP0182889B1/de not_active Expired - Lifetime
- 1985-06-07 WO PCT/EP1985/000275 patent/WO1986000093A1/de not_active Application Discontinuation
- 1985-06-07 DE DE8585902985T patent/DE3581501D1/de not_active Expired - Lifetime
- 1985-06-11 DK DK260785A patent/DK260785A/da not_active Application Discontinuation
- 1985-06-12 CA CA483754A patent/CA1269061C/en not_active Expired - Lifetime
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US3167449A (en) * | 1961-04-26 | 1965-01-26 | Gen Electric | Method of forming carbon coating |
DE3047888A1 (de) * | 1980-12-19 | 1982-07-15 | Philips Patentverwaltung Gmbh, 2000 Hamburg | "schneidwerkzeug, verfahren zu seiner herstellung und seine verwendung" |
US4434188A (en) * | 1981-12-17 | 1984-02-28 | National Institute For Researches In Inorganic Materials | Method for synthesizing diamond |
US4410504A (en) * | 1982-04-30 | 1983-10-18 | United Technologies Corporation | Method of producing high density carbon |
Non-Patent Citations (3)
Title |
---|
4ieme Colloque International sur les Plasmas et la Pulverisation Cathodique, C.I.P. 82, Nuc 13-17 September 1982 J.M. MACKOWSKI: "Comparaison Physiochimique des couches de Carbone a large Bande Interdite (I-C) Elaborees par Differentes Techniques Plasma", pages 99 to 106, see page 99, column 4 * |
Journal of Applied Physics, Vol. 54, No 8, August 1983, New York (US) A. BUBENZER: "Rf -Plasma Deposited Amorphous Hydrogenated Hard Carbon thin Films: Preparation, Properties, and Applications", pages 4590 to 4595, see page 4591, left column B * |
PATENTS ABSTRACTS OF JAPAN, Vol. 4, No 67, 20 May 1980, page 103E11 & JP, A, 5536980 (Matsushita) 14 March 1980 * |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2606165A1 (fr) * | 1986-06-18 | 1988-05-06 | Raytheon Co | Procede pour faire adherer une couche de carbone dur sur une base, notamment pour elements optiques |
EP0259791A1 (de) * | 1986-09-06 | 1988-03-16 | Forschungszentrum Jülich Gmbh | Verfahren zur Herstellung von Werkstücken mit einer Oberflächenschicht aus Kohlenstoff |
EP0259792A1 (de) * | 1986-09-06 | 1988-03-16 | Forschungszentrum Jülich Gmbh | Verfahren zur Herstellung von wärmebelasteten Bauelementen mit einer schützenden Schicht |
EP0279898A1 (de) * | 1987-02-27 | 1988-08-31 | Ernst Winter & Sohn (GmbH & Co.) | Verfahren zum Auftragen einer Verschleissschutzschicht und danach hergestelltes Ezeugnis |
EP0605814A1 (de) * | 1993-01-07 | 1994-07-13 | International Business Machines Corporation | Diamantähnliche Kohlenstoffilme hergestellt aus einem Kohlenwasserstoff-Helium-Plasma |
US5546770A (en) * | 1993-04-06 | 1996-08-20 | Citizen Watch Co., Ltd. | Knitting parts of knitting machine |
WO2002036513A2 (en) * | 2000-10-30 | 2002-05-10 | Guardian Industries Corp. | Low-e coating system including protective dlc |
WO2002036513A3 (en) * | 2000-10-30 | 2002-07-04 | Guardian Industries | Low-e coating system including protective dlc |
WO2002038515A3 (en) * | 2000-10-30 | 2002-07-04 | Guardian Industries | Solar management coating system including protective dlc |
Also Published As
Publication number | Publication date |
---|---|
CA1269061A (en) | 1990-05-15 |
DK260785A (da) | 1985-12-13 |
JPS61502403A (ja) | 1986-10-23 |
DK260785D0 (da) | 1985-06-11 |
DE3421739C2 (de) | 1987-01-02 |
EP0182889B1 (de) | 1991-01-23 |
EP0182889A1 (de) | 1986-06-04 |
DE3421739A1 (de) | 1985-12-12 |
US4728529A (en) | 1988-03-01 |
DE3581501D1 (de) | 1991-02-28 |
CA1269061C (en) | 1990-05-15 |
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