WO1988001272A3 - Borated amine salts of monothiophosphoric acids - Google Patents

Borated amine salts of monothiophosphoric acids Download PDF

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Publication number
WO1988001272A3
WO1988001272A3 PCT/US1987/001941 US8701941W WO8801272A3 WO 1988001272 A3 WO1988001272 A3 WO 1988001272A3 US 8701941 W US8701941 W US 8701941W WO 8801272 A3 WO8801272 A3 WO 8801272A3
Authority
WO
WIPO (PCT)
Prior art keywords
amine salts
lubricating
borated
image
borated amine
Prior art date
Application number
PCT/US1987/001941
Other languages
French (fr)
Other versions
WO1988001272A2 (en
Inventor
Louis Burjes
Biase Stephen A Di
Original Assignee
Lubrizol Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lubrizol Corp filed Critical Lubrizol Corp
Priority to AT87905693T priority Critical patent/ATE80887T1/en
Priority to DE8787905693T priority patent/DE3781895T2/en
Publication of WO1988001272A2 publication Critical patent/WO1988001272A2/en
Publication of WO1988001272A3 publication Critical patent/WO1988001272A3/en
Priority to SG161/93A priority patent/SG16193G/en
Priority to HK370/93A priority patent/HK37093A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
    • C07F9/165—Esters of thiophosphoric acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C07F5/02—Boron compounds
    • C07F5/022—Boron compounds without C-boron linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C07F5/02—Boron compounds
    • C07F5/04—Esters of boric acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C10M137/04—Phosphate esters
    • C10M137/10—Thio derivatives
    • C10M137/105—Thio derivatives not containing metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12—Reaction products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/047—Thioderivatives not containing metallic elements
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061—Esters derived from boron
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061—Esters derived from boron
    • C10M2227/062—Cyclic esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B75/00—Other engines
    • F02B75/02—Engines characterised by their cycles, e.g. six-stroke
    • F02B2075/022—Engines characterised by their cycles, e.g. six-stroke having less than six strokes per cycle
    • F02B2075/025—Engines characterised by their cycles, e.g. six-stroke having less than six strokes per cycle two
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Abstract

This invention is directed to borated amine salts of dihydrocarbyl monothiophosphoric acids, and to lubricating and functional fluid compositions containing said borated amine salts. The lubricating and functional fluid compositions have improved extreme pressure properties and high temperature stability. The borated amine salts of the invention may be characterized by the formula <IMAGE> (I) <IMAGE> (II) <IMAGE> (III) or mixtures thereof wherein R1 and R2 are each independently hydrocarbyl groups containing from 1 to about 30 carbon atoms. In one preferred embodiment, the amine salts are derived from hydroxyhydrocarbyl amines. The lubricating and functional fluid compositions may contain, in addition to the borated amine salts, at least one nitrogen-containing composition prepared by the reaction of a hydrocarbon-substituted succinic acid-producing compound with at least about one-half equivalent, per equivalent of acid-producing compound, of an amine containing at least one hydrogen attached to a nitrogen atom. The lubricating compositions of the present invention are particularly useful as lubricating oils, functional fluids and greases.
PCT/US1987/001941 1986-08-14 1987-08-07 Borated amine salts of monothiophosphoric acids WO1988001272A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
AT87905693T ATE80887T1 (en) 1986-08-14 1987-08-07 BORONIC AMINE SALTS OF MONOTHIOPHOSPHORIC ACIDS.
DE8787905693T DE3781895T2 (en) 1986-08-14 1987-08-07 BORINE AMINE SALTS FROM MONOTHIOPHOSPHORIC ACIDS.
SG161/93A SG16193G (en) 1986-08-14 1993-02-12 Borated amine salts of monothiophosphoric acids
HK370/93A HK37093A (en) 1986-08-14 1993-04-15 Borated amine salts of monothiophosphoric acids

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/896,539 US4755311A (en) 1986-08-14 1986-08-14 Phosphorus-, sulfur- and boron-containing compositions, and lubricant and functional fluid compositions containing same
US896,539 1992-06-09

Publications (2)

Publication Number Publication Date
WO1988001272A2 WO1988001272A2 (en) 1988-02-25
WO1988001272A3 true WO1988001272A3 (en) 1988-03-10

Family

ID=25406390

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1987/001941 WO1988001272A2 (en) 1986-08-14 1987-08-07 Borated amine salts of monothiophosphoric acids

Country Status (13)

Country Link
US (1) US4755311A (en)
EP (1) EP0318511B1 (en)
JP (1) JP2720969B2 (en)
AT (1) ATE80887T1 (en)
AU (1) AU608248B2 (en)
CA (1) CA1339847C (en)
DE (1) DE3781895T2 (en)
ES (1) ES2007686A6 (en)
HK (1) HK37093A (en)
MX (1) MX163473B (en)
SG (1) SG16193G (en)
WO (1) WO1988001272A2 (en)
ZA (1) ZA875961B (en)

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MX163473B (en) 1992-05-19
CA1339847C (en) 1998-04-28
JP2720969B2 (en) 1998-03-04
AU608248B2 (en) 1991-03-28
ATE80887T1 (en) 1992-10-15
HK37093A (en) 1993-04-23
EP0318511A1 (en) 1989-06-07
JPH01503781A (en) 1989-12-21
EP0318511B1 (en) 1992-09-23
US4755311A (en) 1988-07-05
WO1988001272A2 (en) 1988-02-25
SG16193G (en) 1993-04-16
DE3781895D1 (en) 1992-10-29
AU7874887A (en) 1988-03-08
ES2007686A6 (en) 1989-07-01
DE3781895T2 (en) 1993-02-11
ZA875961B (en) 1988-10-26

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