WO1994008463A1 - Vegetables and fruit preservation bag - Google Patents

Vegetables and fruit preservation bag Download PDF

Info

Publication number
WO1994008463A1
WO1994008463A1 PCT/JP1993/001512 JP9301512W WO9408463A1 WO 1994008463 A1 WO1994008463 A1 WO 1994008463A1 JP 9301512 W JP9301512 W JP 9301512W WO 9408463 A1 WO9408463 A1 WO 9408463A1
Authority
WO
WIPO (PCT)
Prior art keywords
bag
vegetables
surface area
fruits
area ratio
Prior art date
Application number
PCT/JP1993/001512
Other languages
French (fr)
Japanese (ja)
Inventor
Takahide Saito
Original Assignee
Sumitomo Bakelite Company Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP28164792A external-priority patent/JP3154440B2/en
Priority claimed from JP28164892A external-priority patent/JP3154441B2/en
Priority claimed from JP28164392A external-priority patent/JP3117556B2/en
Priority claimed from JP28164692A external-priority patent/JP3117559B2/en
Priority claimed from JP28164492A external-priority patent/JP3117557B2/en
Priority claimed from JP28164992A external-priority patent/JP3154442B2/en
Priority claimed from JP28165092A external-priority patent/JP3154443B2/en
Priority claimed from JP28164592A external-priority patent/JP3117558B2/en
Priority claimed from JP29531092A external-priority patent/JP3154445B2/en
Priority claimed from JP29531292A external-priority patent/JP3154447B2/en
Priority claimed from JP29531192A external-priority patent/JP3154446B2/en
Application filed by Sumitomo Bakelite Company Limited filed Critical Sumitomo Bakelite Company Limited
Priority to AU52857/93A priority Critical patent/AU5285793A/en
Publication of WO1994008463A1 publication Critical patent/WO1994008463A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D33/00Details of, or accessories for, sacks or bags
    • B65D33/01Ventilation or drainage of bags

Definitions

  • the fruits and vegetables can be resealed to maintain freshness by continuing respiration under an appropriate oxygen atmosphere even after the fruits and vegetables are repackaged in a perforated plastic film bag. It relates to a bag for storing fruits and vegetables with a mechanism.
  • bags for storing fruits and vegetables which are generally provided as bags for storing fruits and vegetables, especially for films containing mineral substances, or for permeating oxygen and releasing moisture.
  • a bag made of perforated film is marketed as a bag for storing fruits and vegetables.
  • most of the films using these minerals (1) had poor transparency, and none of them could satisfy the reproducibility of the effect on the preservation of fruits and vegetables.
  • bags made of the above-mentioned film for general household use are marketed as bags for storing fruits and vegetables.
  • the opening of the bag must be covered with a rubber band. It is a method that can be stopped or folded and stopped with a clip, etc., or tied and tied, and the sealing property is unstable, so it is not satisfactory because it lacks uniformity and stability of storage What won.
  • Japanese Patent Application Laid-Open No. 54-79393 discloses that small pores having a diameter of 0.5 to 3.6 mm have a total pore area of 1.0 to 10 mm 2 with a surface area of 600 cm z.
  • a method of packaging ripening fruits in which a polyethylene film bag having a percentage of ripening is sealed is described.However, each pore is quite large, and taking the minimum value of the total pore area, While opening area ratio 1. is 6 7 X 1 0 one 4% looking at the example, pore size 1. 5 mm 2 pieces hole or pore diameter 1. 0 mm hole four surface area 6 0 0 0 since those provided in a polyethylene bag cm 2, open area ratio in this case is 5.
  • fruits and vegetables need to supply a small amount of oxygen and maintain an oxygen amount within a range that does not cause anaerobic respiration. Has been found to be able to maintain its freshness over a long period of time.
  • JP-A-53-51096 discloses that a laminated film of a heat-sealable film and a film having a melting point higher than that of the heat-sealable film has a hole of 0.1 to 2 mm in diameter of lcm. 2 per 2 5 ⁇ : L 0 0 pieces arranged breathability
  • a packaging material is described, but the actual packaged product is an oxygen scavenger containing hydrosulfite as a main material and disclosed in Japanese Patent Application Laid-Open No. 54-07793. It is one order of magnitude higher than the pore area ratio. Purpose of the invention
  • the object of the present invention was made as a result of various studies to solve the problem of the conventional bag for storing fruits and vegetables, wherein the film of the body constituting the bag was formed of a perforated film, and By providing a bag with a mouth opening and closing mechanism that can be resealed at the opening, the minimum amount of oxygen necessary for the survival of fruits and vegetables is provided, and by keeping the fruits and vegetables in a so-called hibernation state, An object of the present invention is to provide a bag capable of stably storing fruits and vegetables over a long period of time by suppressing browning and growth, which are obstacles to high oxygen content. Disclosure of the invention
  • one or both surfaces constituting the body of the bag may have pores having an average pore diameter of 10 to 150 m, preferably 40 to L0 m, and particularly preferably 50 to 80 ⁇ . It consists of a plastic film or a composite film consisting of a plurality of plastic films and metal foil, paper, cloth, etc., and the ratio of the open area of the perforated film surface to the total inner surface area of the bag is 1 X 10 _7 to 2 X 10 _4 %, which is a bag for storing fruits and vegetables, characterized in that a resealable mouth opening / closing mechanism is provided at the top opening of the bag.
  • FIG. 1 is a side view of a flat bag that is at least ordinary among the bags of the present invention: Preferred embodiments of the invention
  • the inside surface area of the bag for storing fruits and vegetables of the present invention is preferably 50 to 350 cm 2 per 10 g of the fruits and vegetables to be filled.
  • the shape of the bag can be a flat bag, a gusset bag or a self-supporting bag.
  • the body of the bag has a shape drawn toward the inside of the bag and has a shape provided with a rib mechanism.
  • the zipper is provided with an uneven zipper for fitting and locking into the opening of the bag.
  • the plastic film constituting the bag for preserving fruits and vegetables of the present invention is not particularly limited, and may be any film, for example, polyolefin such as polyethylene and polypropylene, polyvinyl chloride, polyamide, polyester and the like. Or a functional multilayer film combining these plastics.
  • a material such as a two-layer film of nylon Z polyethylene is excellent in terms of washing and reuse. ing.
  • a composite film made of a combination of plastic and other materials such as metal foil, paper, and cloth.
  • the film forming the body of the bag of the present invention has a fine structure. It is essential to make a hole, and the ratio of the area of the hole to the total inner surface area of the bag must be selected from the range of 1 X 10 "to 2 X 10_4 %. fruits or vegetables when the area ratio is saved vegetables and fruits if 1 X 1 0- 7% or less is there a risk cormorants want to anaerobic respiration, also 2 X 1 ⁇ too permeate oxygen is equal to or one more than 4% want In addition, respiratory action becomes active and long-term storage becomes difficult.
  • the perforated film constituting the bag of the present invention may be one in which only one side of the body of the bag is opened or one in which both sides are opened.
  • the hole shape may be a polygon such as a circle, a triangle, or a rectangle, and the average diameter is 10 to 150; m. It is preferably from 40 to 80 xm, more preferably from 40 to 80 xm. If the pore size is 10 or less, processability is poor, and if it is 150 or more, the moisture evaporating from the fruits and vegetables goes out of the bag, which is not preferable.
  • the number of holes in the hole is calculated based on the ratio of the opening area and the average hole diameter.
  • the holes may be blocked due to adhesion of contents or external conditions such as the attachment of a price list.
  • multiple holes are preferable, and more than 5 holes are required per bag.
  • the aperture area ratio must be set to a large value of 0.1 to 3.0%. It is impossible to control gas and other gas, and oxygen gas is virtually free-passed, so in the case of the present invention, the sum of the water vapor transmission rate of the film itself and the water vapor transmission rate from the opening is used.
  • water vapor transmission rate as the value is, 8 0 0 g JIT 2 d one 1 atm "1 below (2 5 ° C, measured at a relative humidity of 7 5%), preferably 8 0 gm one 2 d one 1 atm one 1 below , particularly preferably der 1 0 gm one 2 d one 1 atm one 1 below Adjust so that
  • the shape of the bag of the present invention is a flat bag, a gusset bag or a free-standing bag.
  • the shape of the self-standing bag may be a Dipak-shaped bag or a square-bottomed bag. There is no problem if the part is squeezed upward, that is, a so-called bottle shape, or a part of the body part that is squeezed. It can be a self-standing bag that has a squeezed shape and a shape with a rib mechanism.
  • the opening of the bag of the present invention needs to be provided with a mouth opening / closing mechanism capable of resealing, and a zipper-shaped one having an uneven shape for fitting and locking these mechanisms.
  • a mouth opening / closing mechanism capable of resealing
  • a zipper-shaped one having an uneven shape for fitting and locking these mechanisms.
  • a zipper having a heat-sealed upper portion for improving the sealing property and having a virgin property can be used.
  • the leafy vegetables are spinach, broccoli, moloheiya, cabbage, Chinese cabbage, beans containing pods (eg, green soybeans), green peas, peppers, green onions, asparagus, etc.
  • the fruits are apples, pears, grapes, power bosses, sudachi, etc.
  • the root vegetables are onions, carrots, turnips, radish And so on. Bananas are exceptionally breathable among fruits, and need to be considered separately from ordinary fruits.
  • temperature control during distribution and storage is an important point in maintaining the freshness of vegetables, etc., and the respiration of fruits and vegetables naturally depends on these temperatures. Although their respiratory volume also increases, the present invention assumes that these temperatures are between 0 and 15 ° C, usually between 5 and 15 ° C.
  • the bag for storing fruits and vegetables is a bag using a perforated film and having an opening / closing mechanism capable of being resealed. It has several levels of storage stability compared to storage in a bag made of non-porous plastic film, and has several times the storage stability of non-wrapped plastic film. In other words, while preventing the odor generated by anaerobic respiration of fruits and vegetables, and also preventing the digestion of sugar by anaerobic respiration, preventing browning, growth and ripening due to excessive oxygen, and maintaining the freshness of fruits and vegetables It can be stored for a long time.
  • the optimal range of the open area ratio and bag surface area did not seem to change much depending on the type of fruits and vegetables, but there was considerable variation in each optimal range, contrary to expectations.
  • the respective optimum ranges are as follows. Spinach open area ratio 7 X 1 0 3 ⁇ 2 X 1 0 one 40/0 bag surface area 2 0 0 ⁇ 9 OO c mV l OO g broccoli open area ratio 1 X 1 0 _s ⁇ 2 X 1 0 _4% , bag surface area 1 0 0 ⁇ 7 0 0 cm 2 /1 0 0 g I catcher open area to Morro ratio 1 X 1 0 ⁇ 2 X 1 0 one 4%
  • Bag surface area 6 0 0 ⁇ 2 0 0 0 cm 2/1 0 0 g sliced cabbage open area ratio 1 X 1 0 _s ⁇ 2 X 1 ⁇ _4%
  • Bag surface area 100 to 600 cm z / 100 g Apple Open area ratio 1 X 10 to 5 X 10 15 %
  • a bag with the same size and thickness as in Example 1 but with a jigper.It is non-porous and packed with 150 g of spinach as in Example 1, stored in a refrigerator for 7 days, and then opened. saw. There was an odor, and soft rot was seen at the tip of the leaf, and he was hesitant to eat it.
  • Example 2 In the bag with a zipper used in Example 1, 16 holes (average hole diameter: 40 ⁇ m) were opened (8 on each side), and a bag having an opening area ratio of 1.7 X 10 _S % was used. tri Te apples 3 pieces of (Fuji) (8 2 5 g) insertion (apples 1 0 0 g bag surface area 14 5 C m z Atari), after storage for 3 weeks in the refrigerator to seal closed the zipper I put it out and saw the taste. Apple ⁇ is in a state before storage There was also a clear pattern of the cut surface, and the apple scent was also ample.
  • Example 2 An apple was used in the same manner as in Example 2 except that a bag having the same size as that used in Example 2 and four holes with a diameter of 5 mm were drilled (open area ratio 6. ⁇ 4X10 to 2 %). 3 pieces were put, and the opening part was bent, and it was stopped with cellophane tape, put in a refrigerator, stored for 3 weeks, and taken out. The appearance was withered and the color of the skin was darkened, the taste was slightly blurred, the cut surface was blurred, and the pattern was not clear.
  • a self-standing bag with a zipper made of polyethylene film of the same thickness as that of the bag used in Example 3 and a self-standing bag with lint (50 g) were put in, the zipper was closed and sealed, taken out of the refrigerator and stored for 3 weeks, and then taken out. .
  • the cut onion has started to softly decay on the leaf tip, and when the bag is opened, it is released by anaerobic respiration. Along with the fermented odor, the odor peculiar to leeks was too strong to use.
  • Example 4 250 g of sprouts were packed in a nonporous flat bag of the same material, size and thickness as in Example 4, stored in a refrigerator for 3 days, and then opened. There was no browning or greening, but it had an odor and was hesitant for food.
  • Zino as shown here. "—A flat bag with an inner size of 15 cm x 20 cm and a thickness of 25 ⁇ m and a thickness of 25 ⁇ m.
  • the body 1 of the bag 1 has eight holes 2 with an average pore size of 60 ⁇ m (4 per side). Open each, and make the opening area ratio 3.8 x 10 " 5 %, put about 200 g of green soybean in this bag (the inner surface area of bag per 100 g of green soybean is 300 cm 2 ), Close zipper 4 in opening 3 and in refrigerator (about 5 ° C)
  • Example 5 Similar to Example 5, 200 g of green soybeans were packed in a non-porous flat bag having the same material, size, and thickness as in Example 5, stored in a refrigerator for 3 days, and then opened. No browning or greening was observed, but there was some odor and the taste was not good due to the decrease in sugar content.
  • Protocollie was packed in a non-porous flat bag having the same material, size and thickness as in Example 6, stored in a refrigerator for 3 days, and then opened. No yellowing was observed, but the odor was strong, mold had developed, and decay had started.
  • Example 7 100 g of Morohya was packed in a nonporous flat bag having the same material, size and thickness as in Example 7, stored in a refrigerator for 3 days, and then opened. No browning and wilting were observed, but the leaves had begun to darken and were hesitant to eat.
  • Fig. 1 the body of a two-layer film bag made of nylon (thickness: 15 ⁇ ) and polyethylene (thickness: 35 m) with inner dimensions of 32 cm x 35 cm and a zippered flat bag as shown in Figure 1 Drill 14 holes (7 on each side) with an average pore diameter of 8 Om in part 1 and make the open area ratio 3.1 X 10 _S %. Put 1 kg of sliced cabbage in this bag (slice 100 g of cabbage was heated in a bag with a surface area of 224 cm 2 ), the zipper 4 in the opening 3 was closed, stored in a refrigerator (about 5 ° ⁇ ) for 7 days, then removed and observed for odor and appearance. The fruits were almost the same as before storage, and were fully edible. Comparative Example 9
  • Example 8 1 kg of sliced cabbage was packed in a nonporous flat bag of the same material, size and thickness as in Example 8, stored in a refrigerator for 3 days, and then opened. The fermentation smell was strong, and decay had begun.
  • a flat bag with a zipper as shown in Fig. 1 and a double-layer film bag of nylon (thickness: 15 ⁇ ) and polyethylene (thickness: 35 m) with inner dimensions of 32 cm x 35 cm and a thickness of 50 m 16 holes 2 (8 holes on each side) with an average pore diameter of 8 Om are opened in the body 1 of the bag, and the opening area ratio is 3.6 X 10 _s %.
  • Example 1 In a non-porous flat bag of the same material, size and thickness as in Example 10, pack 1 kg of sliced onion as in Example 10 and store it in a refrigerator (about 5 ° C) for 3 days. I tried. The slicing surface became transparent and rot began: Example 1 1
  • Fig. 1 It is a flat bag with a zipper as shown in Fig. 1 and is made of a nylon (15 m thick) / polyethylene (35 ⁇ m thick) two-layer film with an inner dimension of 25 cm x 35 cm and a thickness of 50 m. 40 holes 2 with an average diameter of 80 m in the body 1 of the bag
  • Example 11 As in Example 11, 1 kg of shredded cucumber was packed in a nonporous flat bag of the same material, size and thickness as in Example 1 and stored in a refrigerator (about 5 ° C) for 3 days. Then I opened it. It had discolored, had a strong odor, and had started to rot.
  • Example 12 Using the same stretched polypropylene of 30 m thickness as in Example 12 Product ratio is 7. 0 X 1 0 over 4 ° /.
  • Product ratio is 7. 0 X 1 0 over 4 ° /.
  • 250 g of asparagus was packed in a flat bag having 94 holes with an average pore diameter of 100 m, and stored in a refrigerator (about 5 ° C) for 3 days. Then I opened it. There was no odor, but it had discolored and the tip had started to rot.
  • Fig. 1 It is a flat bag with a zipper as shown in Fig. 1 and has an inner dimension of 32 cm x 35 cm and a thickness of 50 im of nylon (thickness 15 / irn) / polyethylene (thickness 35 ⁇ m). 3 6 holes 2 with an average pore size of 80 / «m in the body 1 of the layer film bag
  • Example 13 1 kg of shredded carrot is packed in a non-porous flat bag of the same material, size and thickness as in Example 13 and stored in a refrigerator (about 5 ° C) for 3 days. I sealed it. The lactic acid fermented smell was strong, and rot had begun.

Abstract

A vegetables and fruit preservation bag wherein one or both surfaces constituting a body portion of the bag consist of a porous plastic film or a porous composite film of plastic film and metal foil, paper, cloth, etc. having a plurality of pores having a mean pore diameter of 10 to 150 νm, an open pore area ratio of the porous film surface to the total inner surface area of the bag is from 1x10-7 to 2x10-4 % and a resealable mouth open/close mechanism is provided to the open portion at the upper part of the bag. The bag can stably preserve vegetables and fruit for a long time.

Description

明 細 書  Specification
青果物保存用袋  Fruits and vegetables storage bag
技術分野  Technical field
本発明は、 青果物が有孔合成樹脂フィルムの袋によリ包装された後も 青果物が適正な酸素雰囲気下で呼吸作用を継続させることによって、 鮮 度保持をさせるための再密封の可能な開閉機構を備えた青果物保存用袋 に関するものである。  According to the present invention, the fruits and vegetables can be resealed to maintain freshness by continuing respiration under an appropriate oxygen atmosphere even after the fruits and vegetables are repackaged in a perforated plastic film bag. It relates to a bag for storing fruits and vegetables with a mechanism.
•背景技術 • Background technology
青果物は収穫された後も呼吸作用を持続する。 このため収穫後の貯蔵 流通の間および食するまで、 青果物の品質劣化を防止する保存方法が望 まれていた。  Fruits and vegetables continue to breathe after being harvested. Therefore, there is a need for a preservation method that prevents deterioration of the quality of fruits and vegetables during storage and distribution after harvest and until eating.
従来、 一般に提供されている青果物保存用袋は、 種々の形態のものが あり、 特に青果物保存用袋として、 鉱物質のものを練り込んだフィルム, または酸素の透過、 水分の発散を目的とした孔を開けたフィルムからな る袋が青果物保存用袋として上市されている。 しかしながらこれらの鉱 物質 ¾1陳リ込んだフィルム一を用いたものは、 透明性が悪いものが多く、 また青果物保存性についてもその効果の再現性が満足できるものはなか つた。  Conventionally, there are various types of bags for storing fruits and vegetables, which are generally provided as bags for storing fruits and vegetables, especially for films containing mineral substances, or for permeating oxygen and releasing moisture. A bag made of perforated film is marketed as a bag for storing fruits and vegetables. However, most of the films using these minerals (1) had poor transparency, and none of them could satisfy the reproducibility of the effect on the preservation of fruits and vegetables.
更に、 一般家庭用として前述のようなフィルムからなる袋が青果物保 存用袋と して上市されており、 青果物をこれらの袋に入れて冷蔵庫等で 保存をする場合、 袋の開口部を輪ゴムでとめたり、 折り畳んでクリ ッブ 等で止めたリ、 あるいは縛って結ぶ方法がとられており、 密封性が不安 定であリこのため保存の均一性、 安定性に欠け、 満足できるものではな かった。 Furthermore, bags made of the above-mentioned film for general household use are marketed as bags for storing fruits and vegetables. When storing fruits and vegetables in these bags and storing them in a refrigerator or the like, the opening of the bag must be covered with a rubber band. It is a method that can be stopped or folded and stopped with a clip, etc., or tied and tied, and the sealing property is unstable, so it is not satisfactory because it lacks uniformity and stability of storage What won.
また、 一般の青果物に関して、 酸素を供給し、 普通の状態での呼吸を させ、 鮮度を保つ方法と して有孔フィルムを用いる方法が提案されてい る (特開昭 6 2 - 1 4 8 24 7号公報、 特開昭 6 3— 1 1 9 64 7号公 報等) が、 これらのフィルムは開孔面積比率が 2 X 1 0一2〜 2 X 1 0 % と極めて大きく、 これらのフィルムで包装しても袋内の酸素は殆ど大気 状態と変わらず、 オープン状態と同じである。 In addition, a method using a perforated film has been proposed as a method for maintaining the freshness of oxygen by supplying oxygen, breathing in a normal state for general fruits and vegetables (Japanese Patent Application Laid-Open No. 62-14824). No. 7 and Japanese Patent Application Laid-Open No. 63-119647), these films have an extremely large aperture area ratio of 2 × 10 12 to 2 × 10%. Even if the package is packed with oxygen, the oxygen in the bag is almost the same as the atmospheric state, which is the same as the open state.
一方、 特開昭 54— 4 0 7 9 3号公報には、 直径 0. 5〜3. 6 mm の小孔を表面積 6 0 0 0 c mzに対し総孔面積 1. 0〜1 0 mm2の割合 で有するポリエチレンフィルムの袋を密封した追熟性果実の包装方法が 記載されているが、 1つ 1つの小孔はかなり大きなものであり、 総孔面 積の最小値を採ると、 その開孔面積比率が 1. 6 7 X 1 0一 4%であるが, 実施例をみると、 孔径 1 . 5 mmの孔 2個または孔径 1. 0 mmの孔 4 個を表面積 6 0 0 0 c m2のポリエチレン袋に設けたものであるから、 この場合の開孔面積比率は 5. 8 9 X 1 0一4または 5. 2 3 X 1 0 ~4 % であり、 本発明の最小値のほぼ 2. 8倍と大きいものであり、 これでは 酸素^!^量が多すぎ、 青果" ^の痛みが早くなることが判っている。 On the other hand, Japanese Patent Application Laid-Open No. 54-79393 discloses that small pores having a diameter of 0.5 to 3.6 mm have a total pore area of 1.0 to 10 mm 2 with a surface area of 600 cm z. A method of packaging ripening fruits in which a polyethylene film bag having a percentage of ripening is sealed is described.However, each pore is quite large, and taking the minimum value of the total pore area, While opening area ratio 1. is 6 7 X 1 0 one 4% looking at the example, pore size 1. 5 mm 2 pieces hole or pore diameter 1. 0 mm hole four surface area 6 0 0 0 since those provided in a polyethylene bag cm 2, open area ratio in this case is 5. 8 9 X 1 0 one 4 or 5. 2 3 X 1 0 ~ 4 %, the minimum value of the present invention It is almost 2.8 times larger, which means that there is too much oxygen ^! ^, And the pain of fruits and vegetables "^" becomes faster.
本発明者の研究によれば、 青果物は、 酸素の供給量を少なく し嫌気呼 吸とならない範囲内の酸素量を保たせることが必要であリ、 これを守つ てやれば、 その呼吸量が低下し、 長期間にわたってその鮮度を保持する ことができることが判ってきたのである。  According to the research of the present inventors, fruits and vegetables need to supply a small amount of oxygen and maintain an oxygen amount within a range that does not cause anaerobic respiration. Has been found to be able to maintain its freshness over a long period of time.
また、 特開昭 5 3 - 5 1 0 9 6号公報には、 熱シール可能なフィルム と熱シール可能なフイルムより融点の高いフィルムとの積層フィルムに 孔径 0. 1〜 2 mmの孔を l c m2あたり 2 5〜: L 0 0個設けた通気性 包装材が記載されているが、 実際に包装されている品物はハイドロサル フアイ トを主材とする脱酸素剤であリ、 かつ前記特開昭 5 4 - 4 0 7 9 3号公報の開孔面積比率よりさらに 1桁高いものである。 発明の目的 JP-A-53-51096 discloses that a laminated film of a heat-sealable film and a film having a melting point higher than that of the heat-sealable film has a hole of 0.1 to 2 mm in diameter of lcm. 2 per 2 5~: L 0 0 pieces arranged breathability A packaging material is described, but the actual packaged product is an oxygen scavenger containing hydrosulfite as a main material and disclosed in Japanese Patent Application Laid-Open No. 54-07793. It is one order of magnitude higher than the pore area ratio. Purpose of the invention
本発明の目的とするところは、 従来の青果物保存用袋の問題を解決す るため種々検討した結果なされたものであり、 袋を構成する胴部のフィ ルムを有孔フィルムで構成し、 かつ開口部に再密封が可能である口部開 閉機構を付してなる袋を提供することによって青果物の生存に必要な最 低量の酸素を供給し、 青果物をいわば冬眠状態に保つことにより、 高酸 素量の障害である褐変と成長を抑えて、 青果物を長期間にわたって安定 保存することが可能である袋を提供することにある。 発明の開示  The object of the present invention was made as a result of various studies to solve the problem of the conventional bag for storing fruits and vegetables, wherein the film of the body constituting the bag was formed of a perforated film, and By providing a bag with a mouth opening and closing mechanism that can be resealed at the opening, the minimum amount of oxygen necessary for the survival of fruits and vegetables is provided, and by keeping the fruits and vegetables in a so-called hibernation state, An object of the present invention is to provide a bag capable of stably storing fruits and vegetables over a long period of time by suppressing browning and growth, which are obstacles to high oxygen content. Disclosure of the invention
本発明は、 袋の胴部を構成する片面または両面が、 平均孔径が 1 0〜 1 5 0 m、 好ましくは 4 0〜; L 0 0 m、 とくに好ましくは 5 0〜 8 0 ^の孔を複数個有するプラスチックフィルムまたはプラスチジク と金属箔、 紙、 布等からなる複合フィルムよりなり、 袋の全内表面積に 対する有孔フィルム面の開孔面積比率が 1 X 1 0 _7〜 2 X 1 0 _4 %であ り、 袋上部開口部に再密封可能な口部開閉機構を付したことを特徴とす る青果物保存用袋である。 図面の簡単な説明 In the present invention, one or both surfaces constituting the body of the bag may have pores having an average pore diameter of 10 to 150 m, preferably 40 to L0 m, and particularly preferably 50 to 80 ^. It consists of a plastic film or a composite film consisting of a plurality of plastic films and metal foil, paper, cloth, etc., and the ratio of the open area of the perforated film surface to the total inner surface area of the bag is 1 X 10 _7 to 2 X 10 _4 %, Which is a bag for storing fruits and vegetables, characterized in that a resealable mouth opening / closing mechanism is provided at the top opening of the bag. BRIEF DESCRIPTION OF THE FIGURES
図 1は、 本発明の袋のうち、 もつとも平凡な平袋の側面図である: 発明の好ましい態様 FIG. 1 is a side view of a flat bag that is at least ordinary among the bags of the present invention: Preferred embodiments of the invention
本発明の青果物保存用袋の袋内表面積は、 充填される青果物 1 0 〇 g 当り 5 0〜 3 5 0 0 c m 2であることが好ましい。 The inside surface area of the bag for storing fruits and vegetables of the present invention is preferably 50 to 350 cm 2 per 10 g of the fruits and vegetables to be filled.
前記、 袋の形状は平袋、 ガゼッ ト袋あるいは自立用袋であることがで きる。 とくに自立用袋の場合には、 袋の胴部に袋の内側に向けての絞り 形状を有し、 かつリブ機構を付した形状とすることが好ましい。 また、 本発明においては、 袋の開口部に嵌合係止するための凹凸形状のジッパ 一を付した形状とすることが好ましい。  The shape of the bag can be a flat bag, a gusset bag or a self-supporting bag. In particular, in the case of a self-supporting bag, it is preferable that the body of the bag has a shape drawn toward the inside of the bag and has a shape provided with a rib mechanism. Further, in the present invention, it is preferable that the zipper is provided with an uneven zipper for fitting and locking into the opening of the bag.
本発明の青果物保存用袋を構成するプラスチックフィルムは特に限定 されるものではなく、 どのようなものであってもよく、 例えばポリェチ レン、 ポリプロピレンなどのポリオレフイン、 ポリ塩化ビニル、 ポリア ミ ド、 ポリエステルなどの単層のものでも良く、 これらのプラスチック スを組み合おせた機能性多層フィルムであっても良く、 例えばナイロン Zポリエチレンの 2層フィルムのような材質が洗浄、 再利用する面で優 れている。 さ らにはプラスチックと他のもの、 たとえば金属箔、 紙、 布 等のものと組み合わせた複合フィルムからなるものでも何等差し支えが ない。— ―  The plastic film constituting the bag for preserving fruits and vegetables of the present invention is not particularly limited, and may be any film, for example, polyolefin such as polyethylene and polypropylene, polyvinyl chloride, polyamide, polyester and the like. Or a functional multilayer film combining these plastics. For example, a material such as a two-layer film of nylon Z polyethylene is excellent in terms of washing and reuse. ing. In addition, there is no problem with a composite film made of a combination of plastic and other materials such as metal foil, paper, and cloth. — —
また、 青果物は収穫された後も呼吸作用を続けており、 これらを保存 するには適正な酸素を補給してやらなければならず、 このために本発明 の袋の胴部を形成するフィルムは微細な孔を開けてなることが必須であ り、 この孔の袋全内表面積に対する開孔面積比率は 1 X 1 0 "〜 2 X 1 0 _4 %の範囲から選ばれることが必要であり、 開孔面積比率が 1 X 1 0—7 %以下であれば青果物を保存した時に青果物が嫌気呼吸してしま う恐れがあり、 また 2 X 1 ◦一 4 %以上であれば酸素が透過しすぎてしま い、 呼吸作用が活発化して長期の保存が困難となってしまう。 In addition, fruits and vegetables continue to breathe even after they have been harvested, and they must be replenished with appropriate oxygen in order to preserve them. For this reason, the film forming the body of the bag of the present invention has a fine structure. It is essential to make a hole, and the ratio of the area of the hole to the total inner surface area of the bag must be selected from the range of 1 X 10 "to 2 X 10_4 %. fruits or vegetables when the area ratio is saved vegetables and fruits if 1 X 1 0- 7% or less is there a risk cormorants want to anaerobic respiration, also 2 X 1 ◦ too permeate oxygen is equal to or one more than 4% want In addition, respiratory action becomes active and long-term storage becomes difficult.
更に、 本発明の袋を構成する有孔フィルムは、 袋の胴部の片面のみに 開孔したものであってもまた両面に開孔したものであっても差し支えな く、 さらには胴部を構成する表裏のフィルムの材質が異なるものであつ ても何等差し支えがなく、 孔の形状も円形、 三角形、 四角形などの多角 形であってもよく、 その平均径は 1 0〜 1 5 0 ; m、 好ましくは 4 0〜 Ι Ο Ο ΠΚ と く に好ましくは 5 0〜 8 0 x mのものが望ましい。 孔径 が 1 0 以下であれば加工性が悪く、 1 5 0 以上であれば青果物 からの蒸散水分が袋外に出てしまい好ましくなく、 また青果物入リ包装 袋に用いる有孔高分子フィルムの袋当たリの孔の個数は開孔面積比率と 平均孔径ょリ算出されるが、 できる限り複数個とすること ^望ましい。 内容物の付着や外的条件たとえば値段表の添付等で孔がふさがれてしま う場合があるので、 鮮度を保証するには複数個の孔が好ましく、 さらに 袋あたり 5個以上の孔をもち、 孔 1個あたりの影響度を 2 0 %以下にす ることが望ましい。 孔の数は複数個であることが外的要因によって孔が ふさがれてしまうといつた危険性の回避の面から必要である。  Further, the perforated film constituting the bag of the present invention may be one in which only one side of the body of the bag is opened or one in which both sides are opened. There is no problem even if the material of the front and back films is different, and the hole shape may be a polygon such as a circle, a triangle, or a rectangle, and the average diameter is 10 to 150; m. It is preferably from 40 to 80 xm, more preferably from 40 to 80 xm. If the pore size is 10 or less, processability is poor, and if it is 150 or more, the moisture evaporating from the fruits and vegetables goes out of the bag, which is not preferable. The number of holes in the hole is calculated based on the ratio of the opening area and the average hole diameter. The holes may be blocked due to adhesion of contents or external conditions such as the attachment of a price list.To guarantee freshness, multiple holes are preferable, and more than 5 holes are required per bag. However, it is desirable to reduce the degree of influence per hole to 20% or less. It is necessary for the number of holes to be more than one in order to avoid the danger in the event that holes are closed due to external factors.
孔 t「よってのみ水蒸気 IT透過させようとすると、 開孔面積比率を 0. 1〜 3. 0 %という大きい値にしなければならない。 しかしながら、 こ のような開孔面積比率にしたのでは、 酸素ガスなどのガスコントロール は不可能であり、 酸素ガスは実質上フリーパスになってしまう。 そこで、 本発明の場合は、 フィルムそれ自体の水蒸気透過率と開口部からの水蒸 気透過率の合計値としての水蒸気透過率が、 8 0 0 g JIT2 d一1 a t m"1 以下 ( 2 5 °C、 相対湿度 7 5 %において測定) 、 好ましくは 8 0 g m一2 d一1 a t m一1以下、 とくに好ましくは 1 0 g m一2 d一1 a t m一1以下であ るよう調整する。 In order to allow the water vapor IT to permeate only through the pores t, the aperture area ratio must be set to a large value of 0.1 to 3.0%. It is impossible to control gas and other gas, and oxygen gas is virtually free-passed, so in the case of the present invention, the sum of the water vapor transmission rate of the film itself and the water vapor transmission rate from the opening is used. water vapor transmission rate as the value is, 8 0 0 g JIT 2 d one 1 atm "1 below (2 5 ° C, measured at a relative humidity of 7 5%), preferably 8 0 gm one 2 d one 1 atm one 1 below , particularly preferably der 1 0 gm one 2 d one 1 atm one 1 below Adjust so that
本発明の袋の形状については、 平袋、 ガゼッ ト袋または自立形状の袋 であり、 自立袋の形状としてはドィパック形状のものでも、 角底のもの であっても何等差し支えなく、 更には胴部が上方に向かって絞られた、 いわゆる瓶形状をした形状のものや、 胴部の一部を絞つた形状のもので あっても何等差し支えなく、 袋の胴部に袋の内側に向けての絞リ形状を 有し、 かつリブ機構を付した形状の自立用袋で差し支えない。  The shape of the bag of the present invention is a flat bag, a gusset bag or a free-standing bag. The shape of the self-standing bag may be a Dipak-shaped bag or a square-bottomed bag. There is no problem if the part is squeezed upward, that is, a so-called bottle shape, or a part of the body part that is squeezed. It can be a self-standing bag that has a squeezed shape and a shape with a rib mechanism.
また本発明の袋の開口部は再密閉が可能の口部開閉機構を付してなる ことが必要であり、 これらの機構が嵌合係止するための凹凸形状を有す るジッパー形状のものが、 その取り扱い上望ましく、 当然ながら密封性 に優れたものであることが必要である。 更に密封性をあげバージン性を 有するためにジッパーの上部をヒ一トシ一ルをしたものも使用すること ができる。  Further, the opening of the bag of the present invention needs to be provided with a mouth opening / closing mechanism capable of resealing, and a zipper-shaped one having an uneven shape for fitting and locking these mechanisms. However, it is desirable in terms of handling and, of course, must be excellent in sealing performance. Further, a zipper having a heat-sealed upper portion for improving the sealing property and having a virgin property can be used.
更に、 本発明者の研究によれば、 保存の対象とする青果物は、 その種 類により予想以上に呼吸量が異なついてることがわかった。 したがって、 それに応じて開孔比率を変えて用いることが望ましいが、 一般家庭で使 用す^"のに数種類のものを 備することは困難であリ、 青果物を 2〜3 種ほどに、 例えば葉物野菜用 (袋全内表面積に対する孔の開孔面積比率 は 1 X 1 0一 ε〜2 X 1 0 "4 % ) 、 果実または根菜用 (いずれもカツ 卜さ れていないものを対象とする。 ただし、 バナナは例外である。 ) (袋全 内表面積に対する孔の開孔面積比率は 5 X 1 0 _7〜 5 X 1 0 _s % ) とい うように 2種に別けて用いることが望ましく、 これらについては、 袋に 印刷等によって明示するといった方法も探りうる。 Further, according to the study of the present inventors, it has been found that the fruits and vegetables to be preserved have different respiratory volumes than expected depending on the type. Therefore, it is desirable to use different aperture ratios accordingly, but it is difficult to equip several types for general household use, for example, to produce 2-3 kinds of fruits and vegetables, for example. For leafy vegetables (the open area ratio of pores to the total surface area of the bag is 1 × 10-1ε to 2 × 10 ” 4 %), for fruits or root vegetables (both are not cut) However, bananas are an exception.) It is desirable to use two separate types such as (the ratio of the open area of the holes to the total inner surface area of the bag is 5 X 10 _7 to 5 X 10 _s %). However, for these, it is also possible to search for a method of specifying them by printing on the bag.
葉物野菜とは、 ほうれん草、 ブロッコリ一、 モロヘイヤ、 キヤべヅ、 白菜、 さや入り豆類 (たとえば枝豆) 、 グリンピース、 ピーマン、 ネギ アスパラガス等であり、 果実とは、 リンゴ、 ナシ、 ブドウ、 力ボス、 ス ダチ等であり、 根菜とはタマネギ、 にんじん、 蕪、 大根等である。 なお. バナナは果実のなかで例外的に呼吸が活発であり、 普通の果実とは別枠 で考える必要がある。 The leafy vegetables are spinach, broccoli, moloheiya, cabbage, Chinese cabbage, beans containing pods (eg, green soybeans), green peas, peppers, green onions, asparagus, etc. The fruits are apples, pears, grapes, power bosses, sudachi, etc. The root vegetables are onions, carrots, turnips, radish And so on. Bananas are exceptionally breathable among fruits, and need to be considered separately from ordinary fruits.
なお、 野菜等の鮮度保持には、 当然ながら、 その流通過程及び保存時 における温度管理が重要なポイントであり、 青果物の呼吸量も当然これ らの温度に依存し、 これらの温度が高くなるにつれてその呼吸量も増加 するが、 本発明はこれらの温度を 0〜 1 5 °C、 通常は 5〜 1 5 °Cと想定 したものである。  Naturally, temperature control during distribution and storage is an important point in maintaining the freshness of vegetables, etc., and the respiration of fruits and vegetables naturally depends on these temperatures. Although their respiratory volume also increases, the present invention assumes that these temperatures are between 0 and 15 ° C, usually between 5 and 15 ° C.
本発明による青果物保存用袋は、 有孔のフィルムを用いて、 しかも再 密閉が可能の開閉機構を持つ袋であリ、 この袋に青果物を入れて密閉し, 冷蔵庫にて保存すれば、 従来の無孔のプラスチックフィルムからなる袋 に入れて保存した場合に比較して数段上の保存性があリ、 また無包装の ものに比べると数倍の保存性を有するものである。 即ち青果物の嫌気呼 吸のため発生する臭気を防ぎ、 しかも嫌気呼吸による糖分の消化を防止 し、 、 過剰の酸素によ-る褐変および成長、 熟成を防ぎ、 青果物の鮮 度を保つた状態で永く保存することができる。  The bag for storing fruits and vegetables according to the present invention is a bag using a perforated film and having an opening / closing mechanism capable of being resealed. It has several levels of storage stability compared to storage in a bag made of non-porous plastic film, and has several times the storage stability of non-wrapped plastic film. In other words, while preventing the odor generated by anaerobic respiration of fruits and vegetables, and also preventing the digestion of sugar by anaerobic respiration, preventing browning, growth and ripening due to excessive oxygen, and maintaining the freshness of fruits and vegetables It can be stored for a long time.
青果物の種類によって開孔面積比率や袋内表面積の最適範囲はさほど 変わリはないと思われたが、 予想に反してそれぞれの最適範囲にはかな りのばらつきが認められた。 それぞれの最適範囲は次ぎの通りである。 ほうれん草 開孔面積比率 7 X 1 0 3〜 2 X 1 0一40 /0 袋内表面積 2 0 0〜 9 O O c mV l O O g ブロッコリー 開孔面積比率 1 X 1 0 _s〜 2 X 1 0 _4 %、 袋内表面積 1 0 0〜 7 0 0 c m2/ 1 0 0 g モロへィャ 開孔面積比率 1 X 1 0 〜 2 X 1 0一 4 % The optimal range of the open area ratio and bag surface area did not seem to change much depending on the type of fruits and vegetables, but there was considerable variation in each optimal range, contrary to expectations. The respective optimum ranges are as follows. Spinach open area ratio 7 X 1 0 3 ~ 2 X 1 0 one 40/0 bag surface area 2 0 0~ 9 OO c mV l OO g broccoli open area ratio 1 X 1 0 _s ~ 2 X 1 0 _4% , bag surface area 1 0 0~ 7 0 0 cm 2 /1 0 0 g I catcher open area to Morro ratio 1 X 1 0 ~ 2 X 1 0 one 4%
袋内表面積 6 0 0〜 2 0 0 0 c m2/ 1 0 0 g スライスキャベツ 開孔面積比率 1 X 1 0 _s〜 2 X 1 〇 _4 % Bag surface area 6 0 0~ 2 0 0 0 cm 2/1 0 0 g sliced cabbage open area ratio 1 X 1 0 _s ~ 2 X 1 〇 _4%
袋内表面積 1 0 0〜 6 0 0 c m2/ 1 0 0 g スライスネギ 開孔面積比率 1 X 1 0一5〜 2 X 1 0一 4 % Bag surface area 1 0 0~ 6 0 0 cm 2 /1 0 0 g slice leek open area ratio 1 X 1 0 one 5 ~ 2 X 1 0 one 4%
袋内表面積 2 0 0〜 3 5 0 0 c in2/ 1 0 0 g アスパラガス 開孔面積比率 3 X 1 0一 s〜 2 X 1 0一 4 % Bag surface area 2 0 0~ 3 5 0 0 c in 2/1 0 0 g Asparagus open area ratio 3 X 1 0 one s ~ 2 X 1 0 one 4%
袋内表面積 5 0〜6 0 O c mV l O O g サャ入りの豆類 開孔面積比率 1 X 1 0 _s〜 2 X 1 0 _4 % Bag surface area 50 to 60 O c mV l OO g Beans with syrup Open area ratio 1 X 10 _s to 2 X 10 _4 %
袋内表面積 2 0 0〜 6 00 c mz/ 1 0 0 g スライスタマネギ 開孔面積比率 1 X 1 0一 s〜 2 X 1 〇一4 % Bag surface area 2 0 0~ 6 00 cm z / 1 0 0 g sliced onion open area ratio 1 X 1 0 one s ~ 2 X 1 〇 one 4%
袋内表面積 1 0 0〜6 0 0 c m2/ 1 0 0 g スラ^ rスにんじん 開孔 積比率 3 X 1 0 _s〜 2 X 1 0一40 /0 The bag surface area 1 0 0~6 0 0 cm 2/ 1 0 0 g slide ^ r scan carrot opening product ratio 3 X 1 0 _s ~ 2 X 1 0 one 40/0
袋内表面積 1 0 0〜 6 00 c m2/ 1 0 0 g スライスきゅう リ 開孔面積比率 3 X 1 0一 c〜 2 X 1 0一 4 % Bag surface area 1 0 0~ 6 00 cm 2/ 1 0 0 g slice old Li open area ratio 3 X 1 0 one c ~ 2 X 1 0 one 4%
袋内表面積 1 0 0〜 6 0 0 c mz/ 1 00 g リンゴ 開孔面積比率 1 X 1 0 〜 5 X 1 0一5 % Bag surface area 100 to 600 cm z / 100 g Apple Open area ratio 1 X 10 to 5 X 10 15 %
袋内表面積 1 0 0〜 60 0 c mz/ 1 00 g バナナ 開孔面積比率 7 X 1 〇一5〜 2 X 1 0一4 % Bag surface area 1 0 0~ 60 0 cm z / 1 00 g Banana open area ratio 7 X 1 〇 one 5 ~ 2 X 1 0 one 4%
袋内表面積 1 0 0〜 6 0 0 c m2/ 1 0 0 g 実施例 The bag surface area 1 0 0~ 6 0 0 cm 2 /1 0 0 g Example
以下、 本発明の青果物保存用袋を用いた例について説明する。  Hereinafter, an example using the bag for storing fruits and vegetables of the present invention will be described.
実施例 1 Example 1
図 1に示すようなジッパー付き袋で、 内寸が 2 0 c m X 3 0 c mで厚 さ 2 5 μ mの延伸ポリプロピレンの袋の胴部 1に平均孔径 8 0 mの孔 2を 2 8個 (片面に 1 4個ずつ) 開け、 開孔面積比率 1. 2 X 1 0—4% と し、 この袋にほうれん草を約 1 5 0 g入れて (ほうれん草 1 0 0 gあ たリの袋内表面積 8 0 0 c mz) 開口部 3のジッパー 4を閉じて冷蔵庫 (約 1 0 °C) で 7 日間保存し、 その後取り出して臭気及び外観を観察し た結杲は保存前の状態と殆ど変わらず、 十分に食用に堪えるものであつ た。 比較例 1 A bag with a zipper as shown in Fig. 1 and an inner diameter of 20 cm x 30 cm and a thickness of 25 μm. (one of four on one side) opened, and opening area ratio 1. 2 X 1 0- 4%, spinach in the bag about 1 5 0 g put (spinach 1 0 0 g Ah was Li in the bag (Surface area: 800 cm z ) Close the zipper 4 in the opening 3 and store it in a refrigerator (about 10 ° C) for 7 days, then take it out and observe its odor and appearance.The result is almost the same as before storage. And it was edible enough. Comparative Example 1
実施例 1 と同様のジクパー付きで大きさ、 厚さの袋であり、 無孔のも のに実施例 1 と同様にほうれん草を 1 5 0 g詰めて冷蔵庫に 7 日間保存 し、 その後開封してみた。 臭気があり、 しかも葉先に軟腐が見られ、 食 用と してはためらうような状態であった。  A bag with the same size and thickness as in Example 1 but with a jigper.It is non-porous and packed with 150 g of spinach as in Example 1, stored in a refrigerator for 7 days, and then opened. saw. There was an odor, and soft rot was seen at the tip of the leaf, and he was hesitant to eat it.
比較例 2 Comparative Example 2
ほ ir lん草を新聞紙に^"んだまま冷蔵庫にいれて 7 日間保存しと リだ して見たら、 萎れが激しく、 とても食用に堪えるものではなかった。 実施例 2  When the herb was placed in a newspaper and stored in a refrigerator for 7 days, it was found to be very wilted and not very edible. Example 2
実施例 1で用いたジッパー付きの袋に平均孔径 4 0 μ mの孔を 1 6個 (片面に 8個ずつ) 開け、 開孔面積比率が 1. 7 X 1 0_S%となる袋を 用いてリンゴ (富士) を 3個 ( 8 2 5 g ) 入れ (りんご 1 0 0 gあたリ の袋内表面積 14 5 C mz) 、 ジッパーを閉じ密閉して冷蔵庫で 3週間 保存した後に取リ出して食味を見た。 リンゴの晾は保存前の状態とかわ らず、 切断面の密の状態もはっきり した模様が見られ、 リンゴの香りも 十分にあるものであった。 In the bag with a zipper used in Example 1, 16 holes (average hole diameter: 40 μm) were opened (8 on each side), and a bag having an opening area ratio of 1.7 X 10 _S % was used. tri Te apples 3 pieces of (Fuji) (8 2 5 g) insertion (apples 1 0 0 g bag surface area 14 5 C m z Atari), after storage for 3 weeks in the refrigerator to seal closed the zipper I put it out and saw the taste. Apple 晾 is in a state before storage There was also a clear pattern of the cut surface, and the apple scent was also ample.
比較例 3 Comparative Example 3
実施例 2で用いたものと同じサイズの袋に直径 5 mmの孔を 4個あけ たもの (開孔面積比率 6. δ 4 X 1 0 ~2 % ) を用い、 実施例 2と同様に リンゴを 3個入れ、 開口部を折り曲げた状態でセロハンテープでとめ、 冷蔵庫に入れ 3週間保存した後に取り出した。 外観は表皮が萎凋し、 又 色も黒ずんできており、 味は少しぼけてきており、 切断面もぼけており . 模様もはっきリ しない状態であった。 An apple was used in the same manner as in Example 2 except that a bag having the same size as that used in Example 2 and four holes with a diameter of 5 mm were drilled (open area ratio 6.δ4X10 to 2 %). 3 pieces were put, and the opening part was bent, and it was stopped with cellophane tape, put in a refrigerator, stored for 3 weeks, and taken out. The appearance was withered and the color of the skin was darkened, the taste was slightly blurred, the cut surface was blurred, and the pattern was not clear.
実施例 3 Example 3
袋表面内寸法が 1 5 c m X 2 0 c m、 底面積 6 0 c m2 (表面積 6 6 0 c m2) のナイロン (厚み 1 5 μ πι) /ポリエチレン (厚み 3 5 μ πι) の 2層フィルムからなり、 この袋の両表面に平均直径 5 0 μ πιの孔を 1 0個 (片面に 5個) あけ、 開孔面積比率が 3. 0 X 1 0— 5 %となるジッ パー付き自立袋にカッ トネギ 5 0 gを充填し (カッ トネギ 1 0 0 gあた りの袋内表面積 6 0 0 c mz) 、 ジッパーを閉じ密封し、 更に該ジツバ —の をヒートシールし一、 バージン性と密封を完全にした。 このもの を冷蔵庫で 3週間保存した後に取り出した。 カツ トネギは保存前の状態 とかわらず、 袋を開けたときには腐つた臭いもなかつた。 From a two-layer film of nylon (thickness: 15 μπι) / polyethylene (thickness: 35 μππ) with a bag surface dimension of 15 cm × 20 cm and a base area of 60 cm 2 (surface area: 660 cm 2 ) becomes, 1 0 the mean diameter 5 0 mu Paiiota holes on both surfaces of the bag (5 on one side) opened, the jitter par with freestanding bag opening area ratio is 0 X 1 0- 5% 3. filling the cut Tonegi 5 0 g (cut Tonegi 1 0 0 g per Ri in the bag surface area 6 0 0 cm z), sealed closed zipper, further said Jitsuba - heat sealing of by one, virgin property and sealing Was complete. This was stored in the refrigerator for 3 weeks and then removed. The cut leeks did not smell rotten when the bag was opened, regardless of the condition before storage.
比較例 4 Comparative Example 4
実施例 3で用いた袋と同じ大きさの厚み のポリエチレンフィ ルムからなるジッパ一付き自立袋力ッ トネギ 5 0 gをいれジッパ一を閉 じ密閉し、 冷蔵庫に入れ 3週間保存した後に取り出した。 カッ トネギは 葉先部分が軟腐を始めており、 又袋を開けたときには嫌気呼吸による発 酵臭と共に、 ネギ独特の臭気が強く使用に耐えないものであった。 A self-standing bag with a zipper made of polyethylene film of the same thickness as that of the bag used in Example 3 and a self-standing bag with lint (50 g) were put in, the zipper was closed and sealed, taken out of the refrigerator and stored for 3 weeks, and then taken out. . The cut onion has started to softly decay on the leaf tip, and when the bag is opened, it is released by anaerobic respiration. Along with the fermented odor, the odor peculiar to leeks was too strong to use.
実施例 4 Example 4
図 1に示すようなジッパー付き平袋で、 内寸が 20 c m X 24 c mで 厚さ 3 5 μ mの延伸ポリプロピレンの袋の胴咅! 5·1に平均孔径 80 mの 孔 2を 2 0個 (片面に 1 0個ずつ) 開け、 開孔面積比率 1. 0 X 1 0_4 %と し、 この袋に水洗い、 水きリ処理したもやしを約 2 5 0 g入れて (もやし 1 0 0 gあたりの袋内表面積 3 84 c m2) 、 開口部 3のジッ バ一4 を閉じ、 冷蔵庫 (約 1 0。C) で 5 日間保存し、 その後敢リ出して 臭気及び外観を観察した結果は保存前の状態と殆ど変わらず、 十分に食 用に堪えるものであった。 A flat bag with a zipper as shown in Fig. 1 and having an inner dimension of 20 cm x 24 cm and a thickness of 35 μm in a stretched polypropylene bag. number (single-sided single zero by the) open, the open area ratio 1. 0 X 1 0_ 4%, washed in the bag, a water-out re-treated sprouts placed about 2 5 0 g (bean sprouts 1 0 0 The bag surface area per g of 3 84 cm 2 ), the zipper 1 of the opening 3 was closed, and it was stored in a refrigerator (about 10 C) for 5 days. The condition was almost the same as before storage, and it was edible enough.
比較例 5 Comparative Example 5
実施例 4 と同じ材質、 大きさ、 厚さの無孔の平袋に実施例 4と同様に もやしを 2 5 0 g詰めて冷蔵庫に 3 日間保存し、 その後開封してみた。 褐変および緑化は見られなかったが、 臭気があり、 食用としてはためら うような状態であつた。  As in Example 4, 250 g of sprouts were packed in a nonporous flat bag of the same material, size and thickness as in Example 4, stored in a refrigerator for 3 days, and then opened. There was no browning or greening, but it had an odor and was hesitant for food.
実施例 5 ' Example 5 '
図: Πこ示すようなジッノ、。 "—付き平袋で、 内寸が 1 5 c m X 2 0 c mで 厚さ 2 5 μ mの延伸ポリプロピレンの袋の胴部 1に平均孔径 6 0 μ mの 孔 2を 8個 (片面に 4個ずつ) 開け、 開孔面積比率 3. 8 X 1 0 "5 %と し、 この袋に枝豆を約 2 00 g入れて (枝豆 1 00 gあたりの袋内表面 積 3 0 0 c m2) 、 開口部 3のジッパー 4を閉じ、 冷蔵庫 (約 5 °C) でFigure: Zino, as shown here. "—A flat bag with an inner size of 15 cm x 20 cm and a thickness of 25 μm and a thickness of 25 μm. The body 1 of the bag 1 has eight holes 2 with an average pore size of 60 μm (4 per side). Open each, and make the opening area ratio 3.8 x 10 " 5 %, put about 200 g of green soybean in this bag (the inner surface area of bag per 100 g of green soybean is 300 cm 2 ), Close zipper 4 in opening 3 and in refrigerator (about 5 ° C)
7 日間保存し、 その後取り出して臭気及び外観を観察した結果は保存前 の状態と殆ど変わらず、 食味は採りたてのものと変わらなかった c 比較例 6 It was stored for 7 days, then taken out and observed for odor and appearance.The result was almost the same as before storage, and the taste was the same as freshly picked c Comparative Example 6
実施例 5と同じ材質、 大きさ、 厚さの無孔の平袋に実施例 5と同様に 枝豆を 2 0 0 g詰めて冷蔵庫に 3 日間保存し、 その後開封してみた。 褐 変および緑化は見られなかったが、 多少臭気があり、 食味は糖度の減少 によリおいしくなかつた。 Similar to Example 5, 200 g of green soybeans were packed in a non-porous flat bag having the same material, size, and thickness as in Example 5, stored in a refrigerator for 3 days, and then opened. No browning or greening was observed, but there was some odor and the taste was not good due to the decrease in sugar content.
実施例 6 Example 6
図 1に示すようなジッパー付き平袋で、 内寸が 2 0 c m X 2 0 c mで 厚さ 2 5 A mの延伸ポリプ口ピレンの袋の胴部 1に平均孔径 6 0 / mの 孔 2 を 8個 (片面に 4個ずつ) 開け、 開孔面積比率 2. 8 X 1 0 "5 %と し、 この袋にブロッコ リ一を約 2 0 0 g入れて (ブロッコリ一 1 0 0 g あたりの袋内表面積 4 0 0 c m2) 、 開口部 3のジッパー 4を閉じ、 冷 蔵庫 (約 5 °C) で 7 日間保存し、 その後取り出して臭気及び外観を観察 した結果は保存前の状態と殆ど変わらず、 十分に食用に堪えるものであ つた。 A flat bag with a zipper as shown in Fig. 1 and having an inner diameter of 20 cm x 20 cm and a thickness of 25 Am Open 8 pieces (4 pieces per side), set the open area ratio to 2.8 x 10 " 5 %, put about 200 g of broccoli in this bag (per 100 g of broccoli) The inner surface of the bag is 400 cm 2 ), the zipper 4 at the opening 3 is closed, and stored in a refrigerator (about 5 ° C) for 7 days, then taken out and observed for odor and appearance. It was almost the same as edible.
比較例 7 Comparative Example 7
実施例 6と同じ材質、 大きさ、 厚さの無孔の平袋に実施例 6と同様に プロツーコリーを 2 0 0 g詰一めて冷蔵庫に 3 日間保存し、 その後開封して みた。 黄化は見られなかったが、 臭気が強く、 カビが発生し、 腐敗が始 まっていた。  In the same manner as in Example 6, 200 g of Protocollie was packed in a non-porous flat bag having the same material, size and thickness as in Example 6, stored in a refrigerator for 3 days, and then opened. No yellowing was observed, but the odor was strong, mold had developed, and decay had started.
実施例 7 Example 7
図 1に示すようなジッパー付き平袋で、 内寸が 2 0 c m X 3 5 c mで 厚さ 3 0 mの延伸ポリプロピレンの袋の胴部 1に平均孔径 6 0 mの 孔 2を 1 8個 (片面に 9個ずつ) 開け、 開孔面積比率 3. 6 X 1 0 "5 % と し、 この袋にモロヘイヤーを 1 0 0 g入れて (モロヘイヤ一 1 0 0 £' あたりの袋内表面積 1 4 0 0 c m 2 ) 、 開口部 3のジッパー 4を閉じ、 冷蔵庫 (約 5 °C) で 7 日間保存し、 その後取り出して臭気及び^観を観 察した結果は保存前の状態と殆ど変わらず、 十分に食招に堪えるもので めった A flat bag with a zipper as shown in Fig. 1 and an inner diameter of 20 cm x 35 cm and a length of 30 m, a stretched polypropylene bag with 18 holes 2 with an average pore diameter of 60 m in the body 1 (9 pieces on one side) Open, set the open area ratio to 3.6 X 10 " 5 %, and put 100 g of Morohaiya into this bag. 1 400 cm 2 ), close the zipper 4 in the opening 3 and store it in a refrigerator (about 5 ° C) for 7 days, then take it out and observe the odor and view Almost the same as the state of
比較例 8 Comparative Example 8
実施例 7と同じ材質、 大きさ、 厚さの無孔の平袋に実施例 7と同様に モロへィャ一を 1 0 0 g詰めて冷蔵庫に 3 日間保存し、 その後開封して みた。 褐変およびしおれは見られなかったが、 葉先が黒ずんできはじめ ており、 食用としてはためらうような状態であった。  In the same manner as in Example 7, 100 g of Morohya was packed in a nonporous flat bag having the same material, size and thickness as in Example 7, stored in a refrigerator for 3 days, and then opened. No browning and wilting were observed, but the leaves had begun to darken and were hesitant to eat.
実施例 8 Example 8
図 1 に示すようなジッパー付き平袋で、 内寸が 3 2 c m X 3 5 c mで 厚さ のナイロン (厚み 1 5 μ πι) Ζポリエチレン (厚み 3 5 m) の 2層フィルムの袋の胴部 1に平均孔径 8 O mの孔 2を 1 4倔 (片面に 7個ずつ) 開け、 開孔面積比率 3. 1 X 1 0_S %とし、 この袋 にスライスキャベツを 1 k g入れて (スライスキャベツ 1 0 0 gあたリ の袋内表面積 224 c m2) 、 開口部 3のジッパー 4を閉じ、 冷蔵庫 ( 約 5°σ) で 7 日間保存し、一その後取り出して臭気及び外観を観察した結 果は保存前の状態と殆ど変わらず、 十分に食用に堪えるものであった。 比較例 9 As shown in Fig. 1, the body of a two-layer film bag made of nylon (thickness: 15 μπι) and polyethylene (thickness: 35 m) with inner dimensions of 32 cm x 35 cm and a zippered flat bag as shown in Figure 1 Drill 14 holes (7 on each side) with an average pore diameter of 8 Om in part 1 and make the open area ratio 3.1 X 10 _S %. Put 1 kg of sliced cabbage in this bag (slice 100 g of cabbage was heated in a bag with a surface area of 224 cm 2 ), the zipper 4 in the opening 3 was closed, stored in a refrigerator (about 5 ° σ) for 7 days, then removed and observed for odor and appearance. The fruits were almost the same as before storage, and were fully edible. Comparative Example 9
実施例 8と同じ材質、 大きさ、 厚さの無孔の平袋に実施例 8と同様に スライスキャベツを l k g詰めて冷蔵庫に 3 日間保存し、 その後開封し てみた。 発酵臭が強く、 腐敗が始まっていた。  As in Example 8, 1 kg of sliced cabbage was packed in a nonporous flat bag of the same material, size and thickness as in Example 8, stored in a refrigerator for 3 days, and then opened. The fermentation smell was strong, and decay had begun.
実施例 9 Example 9
図 1 に示すようなジッパー付き平袋で、 内寸が 2 0 c m X 2 0 c mで 厚さ 3 0 mの延伸ナイロン 延伸ポリスチレンの 2層フィルムの袋の 胴部 1に平均孔径 6 O it mの孔 2を 3 2個 (片面に 1 6個ずつ) 開け、 開孔面積比率 1. 1 X 1 0_4%とし、 この袋にバナナを 6 0 0 g入れてA flat bag with a zipper as shown in Fig. 1, measuring 20 cm x 20 cm Stretched nylon with a thickness of 30 m Stretched 2 layers of average diameter 6 Oitm 2 (16 holes per side) in the trunk 1 of a bag of two-layer film of stretched polystyrene, and open area ratio 1. 1 X 10 _4 %, put 600 g of banana in this bag
(バナナ 1 0 0 gあたりの袋内表面積 1 3 3 c m2) 、 開口部 3のジッ パー 4 を閉じ、 2 0 °Cで 5 日間保存し、 その後取り出して臭気及び外観 を観察した結果は保存前の状態と殆ど変わらず、 非常においしいもので あつに c (Banana 1 0 0 bag surface area per g 1 3 3 cm 2), to close the jitter par 4 openings 3, 2 0 ° save C for five days, save result of observation of the odor and appearance then removed almost unchanged from the previous state, to the thickness of very delicious c
比較例 1 〇 Comparative Example 1
バナナを袋に詰めず 6 0 0 gを 2 0°Cで 2 日間保存したが、 臭気はあ まリ変わらなかったがシュガーポッ 卜が発生しており、 外観上商品価値 がいちじるしく低下したものであった。  Although 600 g was stored at 20 ° C for 2 days without packing the bananas, the odor did not change much but sugarpots were generated, and the product value in appearance was significantly reduced. there were.
実施例 1 0 Example 10
図 1に示すようなジッパー付き平袋で、 内寸が 3 2 c m X 3 5 c mで 厚さ 5 0 mのナイロン (厚み 1 5 ΠΙ) Zポリエチレン (厚み 3 5 m) の 2層フィルムの袋の胴部 1に平均孔径 8 O mの孔 2を 1 6個 (片面に 8個ずつ) 開け、 開孔面積比率 3. 6 X 1 0_s %とし、 この袋 にス^ Γスタマネギを 1 k—g入れて (スライスタマネギ 1 0 0 gあたり の袋内表面積 2 24 c m2) 、 開口部 3のジッパー 4を閉じ、 冷蔵庫 ( 約 5°C) で 7日間保存し、 その後取り出して臭気及び外観を観察した結 果は保存前の状態と殆ど変わらず、 十分に食用に堪えるものであった。 比較例 1 1 A flat bag with a zipper as shown in Fig. 1 and a double-layer film bag of nylon (thickness: 15ΠΙ) and polyethylene (thickness: 35 m) with inner dimensions of 32 cm x 35 cm and a thickness of 50 m 16 holes 2 (8 holes on each side) with an average pore diameter of 8 Om are opened in the body 1 of the bag, and the opening area ratio is 3.6 X 10 _s %. —Put g (100 g of sliced onion per bag in surface area of 2 24 cm 2 ), close zipper 4 in opening 3, store in refrigerator (about 5 ° C) for 7 days, then remove to remove odor and appearance The result of observation was almost the same as the condition before storage, and was sufficiently edible. Comparative Example 1 1
実施例 1 0と同じ材質、 大きさ、 厚さの無孔の平袋に実施例 1 0と同 様にスライスタマネギを l k g詰めて冷蔵庫 (約 5°C) に 3 日間保存し. その後開封してみた。 スライス面が透明状になり、 腐敗が始まっていた: 実施例 1 1 In a non-porous flat bag of the same material, size and thickness as in Example 10, pack 1 kg of sliced onion as in Example 10 and store it in a refrigerator (about 5 ° C) for 3 days. I tried. The slicing surface became transparent and rot began: Example 1 1
図 1に示すようなジッパー付き平袋で、 内寸が 2 5 c m X 3 5 c mで 厚さ 5 0 mのナイロン (厚み 1 5 m) /ポリエチレン (厚み 3 5 μ m) の 2層フィルムの袋の胴部 1に平均孔径 8 0 mの孔 2を 4 0個 It is a flat bag with a zipper as shown in Fig. 1 and is made of a nylon (15 m thick) / polyethylene (35 μm thick) two-layer film with an inner dimension of 25 cm x 35 cm and a thickness of 50 m. 40 holes 2 with an average diameter of 80 m in the body 1 of the bag
(片面に 2 0個ずつ) 開け、 開孔面積比率 1. 1 X 1 0_4%とし、 この 袋に千切りきゅう リを 1 k g入れて (千切りきゅう り 1 0 0 gあたりの 袋内表面積 1 7 5 c m2) 、 開口部 3のジッパー 4を閉じ、 冷蔵庫 (約 5 °C) で 7 日間保存し、 その後取り出して臭気及び外観を観察した結果 は保存前の状態と殆ど変わらず、 十分に食用に堪えるものであった。 比較例 1 2 (20 pieces on each side) Open, set the open area ratio to 1.1 X 10 _4 %, put 1 kg of shredded cucumber in this bag (surface area in bag per 100 g of shredded cucumber 1 7) 5 cm 2 ), close the zipper 4 in the opening 3, store in a refrigerator (about 5 ° C) for 7 days, remove it and observe the odor and appearance. Was tolerable. Comparative Example 1 2
実施例 1 1 と同じ材質、 大きさ、 厚さの無孔の平袋に実施例 1 1 と同 様に千切りきゆう りを 1 k g詰めて冷蔵庫 (約 5°C) に 3日間保存し、 その後開封してみた。 変色し、 臭気が強く、 腐敗が始まっていた。  Example 11 As in Example 11, 1 kg of shredded cucumber was packed in a nonporous flat bag of the same material, size and thickness as in Example 1 and stored in a refrigerator (about 5 ° C) for 3 days. Then I opened it. It had discolored, had a strong odor, and had started to rot.
実施例 1 2 Example 1 2
図 1に示すようなジッパー付き平袋で、 内寸が 1 5 c m X 3 5 c mで 厚さ 3 0 mの延伸ポリプロピレンの袋の胴部 1に平均孔径 6 0 mの 孔 2を" 4 0個 (片面に 2 01®ずつ) 開け、 開孔面積比率 1. 1 X 1 0一4 %とし、 この袋にアスパラガスを 2 5 0 g入れて (アスパラガス 1 0 0 gあたりの袋内表面積 4 2 0 c m2) 、 開口部 3のジッパー 4を閉じて 冷蔵庫 (約 5°C) で 7 日間保存し、 その後取リ出して臭気及び外観を観 察した結果は保存前の状態と殆ど変わらず、 十分に食用に堪えるもので めつ 7こ 0 A flat bag with a zipper as shown in Fig. 1 and having an inner dimension of 15 cm x 35 cm and a thickness of 30 m, a polypropylene bag with a thickness of 30 m has a hole 2 with an average pore diameter of 60 m in the body 1. each (one side by 2 01®) opened, the open area ratio 1. 1 X 1 0 one 4%, bag surface area of 2 5 0 g put (per asparagus 1 0 0 g asparagus in the bag 4 20 cm 2 ) Close the zipper 4 in the opening 3 and store it in a refrigerator (about 5 ° C) for 7 days, then remove it and observe the odor and appearance.The result is almost the same as before storage. not, blinking 7 this 0 in what enough to meet the edible
比較例 1 3 Comparative Example 1 3
実施例 1 2 と同様な 3 0 m厚の延伸ポリプロピレンを用い、 開孔面 積比率が 7. 0 X 1 0ー4° /。となるよう平均孔径が 1 0 0 mの孔を 94 個開けた平袋に実施例 1 2と同様にアスパラガスを 2 5 0 g詰めて冷蔵 庫 (約 5 °C) に 3 日間保存し、 その後開封してみた。 臭気はなかったが 変色し、 穂先の腐敗が始まっていた。 Using the same stretched polypropylene of 30 m thickness as in Example 12 Product ratio is 7. 0 X 1 0 over 4 ° /. As in Example 12, 250 g of asparagus was packed in a flat bag having 94 holes with an average pore diameter of 100 m, and stored in a refrigerator (about 5 ° C) for 3 days. Then I opened it. There was no odor, but it had discolored and the tip had started to rot.
実施例 1 3 Example 13
図 1に示すようなジッパ一付き平袋で、 内寸が 3 2 c m X 3 5 c mで 厚さ 5 0 i mのナイロン (厚み 1 5 /i rn) /ポリエチレン (厚み 3 5 μ m) の 2層フィルムの袋の胴部 1 に平均孔径 80 /« mの孔 2を 3 6個 It is a flat bag with a zipper as shown in Fig. 1 and has an inner dimension of 32 cm x 35 cm and a thickness of 50 im of nylon (thickness 15 / irn) / polyethylene (thickness 35 μm). 3 6 holes 2 with an average pore size of 80 / «m in the body 1 of the layer film bag
(片面に 1 8個ずつ) 開け、 開孔面積比率 8. 1 X 1 0— s °/0とし、 この 袋に千切りにんじんを 1 k g入れて (千切りにんじん 1 〇 0 gあたりの 袋内表面積 14 0 c mz) 、 開口部 3のジッパー 4を閉じ、 冷蔵庫 (約 1 〇 °C) でつ 日間保存し、 その後取り出して臭気及び外観を観察した結 果は保存前の状態と殆ど変おらず、 十分に食用に堪えるものであった。 比較例 14 Opened (18 per side) Open hole area ratio 8.1 x 10— s ° / 0, and put 1 kg of shredded carrot in this bag (surface area of bag per 1〇0 g of shredded carrot 14 0 cm z ), close the zipper 4 in the opening 3, store it in a refrigerator (about 1 〇 ° C) for one day, remove it and observe the odor and appearance.The result is almost the same as before storage. They were edible enough. Comparative Example 14
実施例 1 3と同じ材質、 大きさ、 厚さの無孔の平袋に実施例 1 3と同 様に千切りにんじんを 1 k g詰めて冷蔵庫 (約 5 °C) に 3 日間保存し、 その後 §封してみた。 乳酸 酵臭が強く、 腐敗が始まっていた。  As in Example 13, 1 kg of shredded carrot is packed in a non-porous flat bag of the same material, size and thickness as in Example 13 and stored in a refrigerator (about 5 ° C) for 3 days. I sealed it. The lactic acid fermented smell was strong, and rot had begun.

Claims

請 求 の 範 囲 The scope of the claims
1. 袋の胴部を構成する片面または両面が、 平均孔径が 1 0〜 1 5 0 の孔を複数個有するプラスチジクフィルムまたはプラスチックと金属 箔、 紙、 布等からなる複合フィルムよりなり、 袋の全内表面積に対す る有孔フィルム面の開孔面積比率が 1 X 1 0一7〜 2 X 1 0一 4%であり 袋上部開口部に再密封可能な口部開閉機構を付したことを特徴とする 青果物保存用袋。 1. One or both sides of the body of the bag are made of a plastic film or a composite film made of plastic and metal foil, paper, cloth, etc., having a plurality of holes with an average pore diameter of 10 to 150. the opening area ratio of the perforated film surface against the total internal surface area given the resealable mouth closing mechanism has bag upper opening in 1 X 1 0 one 7 ~ 2 X 1 0 one 4% A bag for storing fruits and vegetables.
2. 袋内表面積が 5 0〜 3 5 0 0 c m2/ 1 0 0 gである請求の範囲第 1項記載の青果物保存用袋。 2. bag surface area 5 0~ 3 5 0 0 cm 2 /1 0 0 g a fruit or vegetable storage bag Claims paragraph 1, wherein.
3. 水蒸気透過率が 8 0 0 g m一2 d— 1 a t m_1以下である請求の範囲第 1項または第 2項記載の青果物保存用袋。 3. a water vapor transmission rate of 8 0 0 gm one 2 d-1 atm _1 claim 1, wherein at a less or fruits or vegetables storage bag of the second Claims.
4. 袋が平袋、 ガゼッ ト袋または自立形状の袋である請求の範囲第 1、 2項または第 3項記載の青果物保存用袋。  4. The bag for storing fruits and vegetables according to claim 1, 2 or 3, wherein the bag is a flat bag, a gusset bag or a free-standing bag.
5. 袋が袋の胴部に袋の内側に向けての絞り形状を有し、 かつリブ機構 を付した形状の自立用袋である請求の範囲第 1、 2、 3または第 4項 記 ITの青果物保存用袋。 ―  5. Claims 1, 2, 3 or 4 wherein the bag is a self-standing bag having a shape drawn toward the inside of the bag on the body of the bag and having a rib mechanism. For storing fruits and vegetables. ―
6. 袋上部開口部の再密封可能な口部開閉機構が嵌合係止するための凹 凸形状を有するジッパーからなる請求の範囲第 1、 2、 3、 4項また は第 5項記載の青果物保存用袋。  6. A zipper having a concave-convex shape for engaging and locking a resealable mouth opening / closing mechanism for the upper opening of the bag according to claim 1, 2, 3, 4, or 5. Fruit and vegetable storage bag.
7. ジッパーの上部がヒ一トシ一ルされている請求の範囲第 6項記載の 青果物保存用袋。  7. The bag for storing fruits and vegetables according to claim 6, wherein the upper part of the zipper is heat-sealed.
8. 青果物が葉物野菜またはカッ ト野菜であり、 開孔面積比率が 1 X 1 〇一6〜 2 X 1 0_4%である請求の範囲第 1、 2、 3、 4、 5、 6項ま たは第 7項記載の青果物保存用袋。 8. Claims 1, 2, 3, 4, 5, and 6 in which the fruits and vegetables are leafy vegetables or cut vegetables, and the ratio of open area is 1 X 1-6 to 2 X 10_4 % Ma Or the bag for storing fruits and vegetables according to Item 7.
9. 葉物野菜がほうれん草であリ、 開孔面積比率 7 X 1 0一5〜 2 X 1 0 "4%, 袋内表面積 2 0 0〜 9 0 0 c m2 / 1 0 0 gである請求の範囲 第 8項記載の青果物保存用袋。 、 9. leafy vegetables in spinach ants, open area ratio 7 X 1 0 one 5 ~ 2 X 1 0 "4 %, wherein a bag surface area 2 0 0~ 9 0 0 cm 2 /1 0 0 g The bag for storing fruits and vegetables according to Item 8.
10. 葉物野菜がプロッコリ一であり、 開孔面積比率 1 X 1 0 〜 2 X 1 0 ~4 % , 袋内表面積 1 0 0〜 7 0 0 c m2 / 1 0 0 gである請求の 範囲第 8項記載の青果物保存用袋。 10. leafy vegetables is Purokkori one, open area ratio 1 X 1 0 ~ 2 X 1 0 ~ 4%, claims a bag surface area 1 0 0~ 7 0 0 cm 2 /1 0 0 g A bag for storing fruits and vegetables according to Item 8.
11. 葉物野菜がモロヘイヤであり、 開孔面積比率 1 X 1 0 〜 2 X 1'0_4%、 袋内表面積 6 0 0〜 20 0 0 c m2/ 1 0 0 gである請求 の範囲第 8項記載の青果物保存用袋。 11. leafy vegetables are Jew, open area ratio 1 X 1 0 ~ 2 X 1'0_ 4%, claims a bag surface area 6 0 0~ 20 0 0 cm 2 /1 0 0 g No. 8. The bag for storing fruits and vegetables according to item 8.
12. 葉物野菜がスライスキャベツであり、 開孔面積比率 1 X 1 0_s〜 2 X 1 0— 4%、 袋内表面積 1 00〜6 0 0 ^ ^2 1 00 £である請求 の範囲第 8項記載の青果物保存用袋。 12. leafy vegetables are sliced cabbage, open area ratio 1 X 1 0 _s ~ 2 X 1 0- 4%, claims bag surface area 1 00~6 0 0 ^ ^ 2 1 00 £ a is the 8. The bag for storing fruits and vegetables according to item 8.
13. 葉物野菜がスライスネギであり、 開孔面積比率 1 X 1 0 〜 2 X 13. The leafy vegetables are sliced green onions, and the open area ratio is 1 X 10 to 2 X
1 0_4%、 袋内表面積 2 0 0〜 3 5 0 0 c m2Z 1 0 0 gである請求 の範囲第 8項記載の青果物保存用袋。 9. The bag for storing fruits and vegetables according to claim 8, wherein the bag has a surface area of 100 to 4 % and a surface area of the bag of 200 to 350 cm 2 Z 100 g.
14. 葉 野菜がアスパラガスであり、 開孔面積比率 3 X 1 0 〜 2 X 14. Leaves Vegetables are asparagus, open area ratio 3 X 10 to 2 X
1 0— 4%、 袋内表面積 5 0〜 6 0 0 c m2Z l 0 0 gである請求の範 囲第 8項記載の青果物保存用袋。 9. The bag for storing fruits and vegetables according to claim 8, wherein the bag has a surface area of 10 to 4 % and a bag inner surface area of 50 to 600 cm 2 Z 100 g.
15. 葉物野菜がサャ入りの豆類であり、 開孔面積比率 1 X 1 0"5~ 2 X 1 0_4%、 袋内表面積 2 0 0〜6 0 0 c m2/ 1 0 0 gである請求の 範囲第 8項記載の青果物保存用袋。 15. leafy vegetables are legumes containing Saya, open area ratio 1 X 1 0 "5 ~ 2 X 1 0 _4%, is bag surface area 2 0 0~6 0 0 cm 2/ 1 0 0 g 9. The bag for storing fruits and vegetables according to claim 8.
16. カッ ト野菜がスライスタマネギであり、 開孔面積比率 1 X 1 0一5〜 2 X 1 0一 4 %、 袋内表面積 1 0 0〜 6 0 0 c mzZ l 0 0 gである請 求の範囲第 8項記載の青果物保存用袋。 16. a cut vegetables slices onion, a open area ratio 1 X 1 0 one 5 ~ 2 X 1 0 one 4%, the bag surface area 1 0 0~ 6 0 0 cm z Z l 0 0 g請 9. The bag for storing fruits and vegetables according to item 8 of the claim.
17. カッ ト野菜が千切りにんじんであり、 開孔面積比率 3 X 1 0一5〜 2 X 1 0_4%、 袋内表面積 1 0 0〜6 0 0 c m2/ 1 0 0 gである請求 の範囲第 8項記載の青果物保存用袋。 17. Cut vegetables are shredded carrots, open area ratio 3 X 1 0 one 5 ~ 2 X 1 0 _4% , according a bag surface area 1 0 0~6 0 0 cm 2/ 1 0 0 g 9. The bag for storing fruits and vegetables according to item 8 above.
18. カッ ト野菜がスライスきゆう りであり、 開孔面積比率 3 X 1 0 〜  18. Cut vegetables are sliced, and open area ratio 3 X 10 〜
2 X 1 0一 4%、 袋内表面積 1 0 0〜 6 0 0 c mzZ 1 00 gである請 求の範囲第 8項記載の青果物保存用袋。 2 X 1 0 one 4%, the bag surface area 1 0 0~ 6 0 0 cm z Z 1 00 g fruit and vegetable storage bag billed ranging paragraph 8 wherein the.
19. 青果物が果実であり、 開孔面積比率が 5 X 1 0_7〜5 X 1 0_5 %で ある請求の範囲第 1、 2、 3, 4、 5、 6項または第 7項記載の青果 物保存用袋。 19. The fruits and vegetables according to claim 1, 2, 3, 4, 5, 6, or 7 wherein the fruits and vegetables are fruits and the open area ratio is 5 X 10 _7 to 5 X 10 _ 5 %. Bag for storing things.
20. 果実がリンゴであリ、 開孔面積比率 1 X 1 0一6〜 5 X 1 0_s%、 袋内表面積 1 0 0〜 6 00 c m2Z l 0 0 gである請求の範囲第 1 9 項記載の青果物保存用袋。 20. The fruit is an apple, the open area ratio is 1 × 10 16 to 5 × 10 _s %, and the inside surface area of the bag is 100 to 600 cm 2 Z 100 g. 9. The bag for storing fruits and vegetables according to item 9.
21. 青果物がバナナであり、 開孔面積比率 7 X 1 0_s〜 2 X 1 0—4%、 袋内表面積 1 0 0〜6 00 c m2Z 1 0 0 gである請求の範囲第 1、 2、 3、 4、 5、 6項または第 7項記載の青果物保存用袋。 21. fruit or vegetable is banana, open area ratio 7 X 1 0 _s ~ 2 X 1 0- 4%, the bag surface area 1 0 0~6 00 cm 2 Z 1 0 0 first claims is g, A bag for storing fruits and vegetables according to paragraph 2, 3, 4, 5, 6 or 7.
PCT/JP1993/001512 1992-10-20 1993-10-20 Vegetables and fruit preservation bag WO1994008463A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU52857/93A AU5285793A (en) 1992-10-20 1993-10-20 Vegetables and fruit preservation bag

Applications Claiming Priority (24)

Application Number Priority Date Filing Date Title
JP4/281648 1992-10-20
JP28164692A JP3117559B2 (en) 1992-10-20 1992-10-20 Package containing Moroheiya
JP4/281649 1992-10-20
JP4/281647 1992-10-20
JP4/281650 1992-10-20
JP28164492A JP3117557B2 (en) 1992-10-20 1992-10-20 Packaging with spinach
JP28164992A JP3154442B2 (en) 1992-10-20 1992-10-20 Package with sliced green onion
JP4/281643 1992-10-20
JP28164792A JP3154440B2 (en) 1992-10-20 1992-10-20 Package containing sliced cabbage
JP28164392A JP3117556B2 (en) 1992-10-20 1992-10-20 Edamame package
JP4/281645 1992-10-20
JP4/281646 1992-10-20
JP4/281644 1992-10-20
JP28164892A JP3154441B2 (en) 1992-10-20 1992-10-20 Banana package
JP28165092A JP3154443B2 (en) 1992-10-20 1992-10-20 Package with sliced onion
JP28164592A JP3117558B2 (en) 1992-10-20 1992-10-20 Broccoli package
JP28307992 1992-10-21
JP4/283079 1992-10-21
JP4/295311 1992-11-04
JP29531092A JP3154445B2 (en) 1992-11-04 1992-11-04 Shredded cucumber package
JP4/295310 1992-11-04
JP29531292A JP3154447B2 (en) 1992-11-04 1992-11-04 Shredded carrot package
JP4/295312 1992-11-04
JP29531192A JP3154446B2 (en) 1992-11-04 1992-11-04 Package containing asparagus

Publications (1)

Publication Number Publication Date
WO1994008463A1 true WO1994008463A1 (en) 1994-04-28

Family

ID=27583534

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP1993/001512 WO1994008463A1 (en) 1992-10-20 1993-10-20 Vegetables and fruit preservation bag

Country Status (1)

Country Link
WO (1) WO1994008463A1 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000007895A1 (en) * 1998-08-07 2000-02-17 General Mills, Inc. Container for storing fine particles
US6126975A (en) * 1998-08-07 2000-10-03 General Mills, Inc. Container for storing fine particles
US6378272B1 (en) 1998-08-07 2002-04-30 General Mills, Inc. Method of making a container for storing fine particles
WO2003066476A1 (en) * 2002-02-09 2003-08-14 Sherman Kau A sterilized bag with multilayer filtering films
WO2019082147A1 (en) * 2017-10-27 2019-05-02 Instituto De Capacitación E Investigación Del Plástico Y Del Caucho - Icipc Surface for exchanging gaseous substances

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61259982A (en) * 1985-11-12 1986-11-18 東洋紡績株式会社 Method of preserving vegetable and fruit
JPH0372843A (en) * 1989-08-11 1991-03-28 Kureha Tec Kk Complex packaging material
JPH0453445A (en) * 1990-06-21 1992-02-21 Sumitomo Chem Co Ltd Packaging bag for retaining freshness of vegetables and fruits
JPH05168400A (en) * 1991-12-26 1993-07-02 Sumitomo Bakelite Co Ltd Packaging material containing vegetable or fruit

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61259982A (en) * 1985-11-12 1986-11-18 東洋紡績株式会社 Method of preserving vegetable and fruit
JPH0372843A (en) * 1989-08-11 1991-03-28 Kureha Tec Kk Complex packaging material
JPH0453445A (en) * 1990-06-21 1992-02-21 Sumitomo Chem Co Ltd Packaging bag for retaining freshness of vegetables and fruits
JPH05168400A (en) * 1991-12-26 1993-07-02 Sumitomo Bakelite Co Ltd Packaging material containing vegetable or fruit

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000007895A1 (en) * 1998-08-07 2000-02-17 General Mills, Inc. Container for storing fine particles
US6126975A (en) * 1998-08-07 2000-10-03 General Mills, Inc. Container for storing fine particles
US6378272B1 (en) 1998-08-07 2002-04-30 General Mills, Inc. Method of making a container for storing fine particles
WO2003066476A1 (en) * 2002-02-09 2003-08-14 Sherman Kau A sterilized bag with multilayer filtering films
WO2019082147A1 (en) * 2017-10-27 2019-05-02 Instituto De Capacitación E Investigación Del Plástico Y Del Caucho - Icipc Surface for exchanging gaseous substances

Similar Documents

Publication Publication Date Title
US5565230A (en) Cherry preservation packaging method
US4883674A (en) Controlled atmosphere cut fruit package and method
JPH06199385A (en) Preservative bag for fruit and vegetable
US4943440A (en) Controlled atmosphere cut vegetable produce package and method
KR0182261B1 (en) Packaging method
US3450543A (en) Method of packaging perishable plant foods to prolong storage life
US6190710B1 (en) Plastic packaging material
BARMORE Packing technology for fresh and minimally processed fruits and vegetables
JP6372510B2 (en) Fruit and vegetable mold growth suppression packaging bag, package containing fruits and vegetables, and method for maintaining freshness of fruits and vegetables
US20180049447A1 (en) Freshness preservation method
US20110083810A1 (en) Container Sealing Machine for Food Packaging
US20050266129A1 (en) Packaging material and method for perishable food product
JP6146061B2 (en) Vegetable and fruit packaging bag and fruit and vegetable packaging
JP2634526B2 (en) Package containing fruits and vegetables
WO1994008463A1 (en) Vegetables and fruit preservation bag
JP6826681B1 (en) How to keep the freshness of cut vegetables
JPH02175140A (en) Film for preserving freshness of vegetable and fruit
JP3346002B2 (en) How to keep fruits and vegetables fresh
JPH05153907A (en) Mushroom-containing package
JP2012144278A (en) Packing bag for fruit and vegetable, and fruit and vegetable packing body
AU650877B2 (en) Materials for preserving freshness of edible materials and method of preserving freshness of same
JP3117556B2 (en) Edamame package
JP2002068320A (en) Vegetable and fruit freshness keeping package and method for cooking vegetable and fruit
NL2029437B1 (en) Package for preserving respiring produce and method
HOBSON et al. The application of plastic film technology to the preservation of fresh horticultural produce

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AU NZ US

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE

121 Ep: the epo has been informed by wipo that ep was designated in this application
122 Ep: pct application non-entry in european phase