WO1994026960A1 - Light colored conductive sealant material and method of producing same - Google Patents
Light colored conductive sealant material and method of producing same Download PDFInfo
- Publication number
- WO1994026960A1 WO1994026960A1 PCT/US1994/004911 US9404911W WO9426960A1 WO 1994026960 A1 WO1994026960 A1 WO 1994026960A1 US 9404911 W US9404911 W US 9404911W WO 9426960 A1 WO9426960 A1 WO 9426960A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- fiber
- thermally conductive
- colored
- light
- ptfe
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/08—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of halogenated hydrocarbons
- D01F6/12—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of halogenated hydrocarbons from polymers of fluorinated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
Definitions
- the present invention relates to thermally conductive fibers used in a variety of applications and especially as packings and seals.
- a packing is a sealing material used to minimize leakage between two components of a fluid container, and especially in containers where the components undergo motion relative to each other, such as in a pump.
- a good packing material should have a number of properties, including: fitting correctly in the packing space, being able to withstand inherent temperature and pressure conditions, being negligibly affected by the fluid being sealed, and being sufficiently flexible to accommodate varying degrees of longitudinal and/or radial displacement.
- Common packings comprise fibers which are first woven, twisted, braided or otherwise joined together, and then formed into appropriate shapes (e.g. coils, spirals, or rings) for insertion around a shaft or other component.
- the packing material should permit the escape of small amounts of liquid to help reduce friction and heat build-up between the components.
- the packing should also have a relatively high thermal conductivity to assist in dissipating frictional heat generated by the movement of the component parts.
- PTFE polytetrafluoroethylene
- a fine powder dispersion of PTFE is combined with a liquid lubricant and graphite and mixed with sufficient shearing force to form a thermally conductive expanded PTFE material which is resistant to shedding graphite.
- a thermally conductive expanded PTFE material which is resistant to shedding graphite.
- a typical example of such light-colored material comprises a fiber of expanded PTFE dipped in an aqueous dispersion of tetrafluoroethylene (TFE) and silicone oil.
- TFE tetrafluoroethylene
- silicone oil a standard grade white packing material 1s available from U. L. Gore & Associates, Inc. under the trademark GORE-TEX (prelubricated) fiber. Although this material 1s quite acceptable for light-colored applications and provides very good lubricity, its thermal conductivity is considerably lower than the material taught in United States Patent 4,256,806.
- the present invention provides an improved composition and method to produce a material suitable for use in packing and sealing which is both thermally conductive and Ught-colored. While contributing necessary lubricity and thermal protection for component parts, the fiber of the present Invention avoids risk of dark particulate contamination in light colored manufactured products such as paper, food, pharmaceuticals, and chemicals. Additionally, in certain embodiments the material of the present invention has proven to be electrically non-conductive, which makes it uniquely applicable to for use in electrical insulation and as a non-corrosive packing material, such as in- marine environments to reduce or eliminate galvanic corrosion.
- the present Invention employs a combination of polytetrafluoroethylene (PTFE) and a light-colored thermally conductive filler material such as boron nitride or tin powder.
- PTFE polytetrafluoroethylene
- a light-colored thermally conductive filler material such as boron nitride or tin powder.
- a further embodiment of the present invention employs the above described fiber or a fiber of expanded PTFE, preferably a towed fiber, which is impregnated and/or coated with a dispersion of tetrafluoroethylene, a light-colored thermally conductive filler, and a lubricant. Mechanical working of the coated fiber shears the dispersion and provides a light-colored thermally conductive fiber.
- the present invention can be applied in any suitable manner, including as a twisted, braided or woven fiber, and shaped for virtually any form of application, including as sheets, tubes, rings, spirals, or coils.
- the present invention provides an improved light-colored fiber which is thermally conductive and suitable for use in a variety of applications, and particularly for use as a packing material to assist in sealing around component parts to reduce or eliminate fluid leakage.
- the fiber is formed by mixing together a fine powder dispersion of polytetrafluoroethylene (PTFE), a mixing medium such as a mineral spirits, and a light-colored thermally conductive filler such as boron nitride.
- PTFE polytetrafluoroethylene
- a mixing medium such as a mineral spirits
- a light-colored thermally conductive filler such as boron nitride.
- the light-colored conductive filler and water are mixed to form a slurry.
- a dispersion of fine powder PTFE is then added to the slurry and vigorously agitated, preferably in the presence of the mixing medium, until the mixture coagulates. Mixing is complete once the coagulated solids precipitate to the bottom of the container in the form of a coagulum, leaving a substantially clear effluent.
- the coagulum is then thoroughly dried, such as through use of a convention oven or similar means, to remove the water.
- the dried coagulum formed in this process can then be formed or worked in any suitable manner, including heated and expanded in a process such as that disclosed in United States Patent 3,953,566, issued April 27, 1976, to Gore.
- the coagulum is ram extruded into a paste or tape.
- the tape can then be heated to approximately 250-350°F and stretched approximately 2 to 150 times its original dimensions to form a tape of expanded PTFE (ePTFE).
- ePTFE expanded PTFE
- the tape can then be further treated in a variety of manners, including being slit and formed into fibers, driven through cutting elements to form a tow, etc.
- This process can be performed with a broad range of beginning proportions, such as of 2-75% by dry weight boron nitride filler, 15-85% by dry weight PTFE, and 10-30% by weight mineral spirits.
- a tape is produced with a boron nitride content of 2-75% and a PTFE content of 25-98%.
- the fiber of this composition is preferred for high pressure applications and in processes which are sensitive to oil contamination.
- PTFE fine powder dispersions are obtained by polymerization of tetrafluoroethylene (TFE) in liquid water containing suitable dispersing agent.
- TFE tetrafluoroethylene
- the preferred dispersion for use in the present invention comprises 30% by weight PTFE solids. Suitable material is available from ICI Americas, Inc. of Wilmington, DE, under the trademark FLU0N(AD-l).
- the mixing medium may comprise any substance which can provide sufficient lubricity in mixing or extruding processes to allow the PTFE dispersion to be sheared.
- suitable lubricants include water, silicone oil, kerosene, naptha, propylene, petroleum extractants, and other similar lubricants.
- the boron nitride is preferably a fine powder. This material is available from Advanced Ceramics of Cleveland, Ohio, under the trade designation HCP grade. Although boron nitride is the preferred filler for use in the present invention, a number of other light-colored thermally conductive materials may also be used. Examples include aluminum oxide, tin, zinc oxide, calcium oxide, or glass fiber.
- the term "coating" as used herein 1s intended to encompass any application of the mixture of the present invention onto or into a substrate, whether merely applied over the surface of the substrate or impregnated below the substrate's surface.
- this coating process comprises dipping, spraying or otherwise covering the fiber of the present invention with the lubricant.
- the lubricant should have kinematic viscosity of about 50,000 centistokes or less, and preferably a kinematic viscosity of 1000 centistokes or less.
- the suitable lubricants are silicone oil, mineral oil, paraffin wax, or petroleum based oil.
- the lubricant comprises polydimethyl siloxane, such as that sold by Dow Corning Corp. of Midland, MI, under the designation DOW CORNING 200.
- a preferred coating for use with the present invention is a liquid or paste comprising PTFE dispersion, light-colored thermally conductive filler, and the lubricant.
- This coating can be formed by combining 25-75% by weight light-colored thermally conductive filler (e.g. boron nitride powder), 20-70% by weight lubricant (e.g. polydimethyl silica), and 25-80% by weight dispersion of PTFE (e.g. 60% solids dispersion available from E.I. duPont de Nemours and Co., of Wilmington, DE, under the trademark TEFLON). The components are blended thoroughly to form a relatively uniform mixture.
- light-colored thermally conductive filler e.g. boron nitride powder
- lubricant e.g. polydimethyl silica
- dispersion of PTFE e.g. 60% solids dispersion available from E.I. duPont de Nemours and Co., of Wilmington,
- the coating can be applied to a variety of substrates to produce a thermally conductive fiber.
- substrates which can be employed are PTFE, expanded PTFE, PTFE composites (e.g. plated, filled, or Impregnated PTFE), fiberglass, polyimides fibers, acrylics, etc.
- the coating 1s combined with the light-colored thermally conductive tape previously described. This may be accomplished through any suitable means, including by dip coating the fibers or tape in the coating, intermixing the coating between fibers, merging the tape and the coating, or coextaiding coating and substrate.
- Another embodiment of the present invention employs a substrate of towed expanded PTFE fiber (either filled in accordance with the present invention or unfilled) which is dipped or otherwise coated with a composition of fluoropoly er (e.g. PTFE or tetrafluoroethylene (TFE)) mixed with the light-colored thermally conductive filler.
- a composition of fluoropoly er e.g. PTFE or tetrafluoroethylene (TFE)
- TFE tetrafluoroethylene
- PTFE and TFE are sometimes used interchangeably, especially when referring to original supplies of PTFE which contain very short chain homopolymers of TFE, except as is specifically addressed herein, the term PTFE is intended to encompass any polymer of TFE regardless of length.
- Mechanical working of the substrate may take any appropriate form, such as sliding it across one or more fixed surfaces, rotating it around one or more spool surfaces, driving it between nip rollers, or driving it through "counter-current” rollers actuated in the opposite direction from the direction of material movement.
- mechanical working of the composite fiber can be avoided or limited by shearing the coating prior to application to the substrate and applying the coating before its water base evaporates.
- the combined proportions of components in the substrate and the coating in the final product should generally comprise: 25-75% by weight light-colored thermally conductive filler (within a broad range of 10- 95%); 10-40% by weight lubricant (within a broad range of 10-60%); and 45-85% by weight expanded PTFE and/or TFE (within a broad range of 5-90%).
- the composition comprises 30-60% boron nitride, 20-30% lubricant, and 50-70% PTFE and/or TFE.
- the material can be formed as fibers, sheets, tubes, beading, tapes, etc.
- the composition can be formed into packing material through any known manner, such as braids, wovens, composites, twisted ropes, etc.
- the material is calendered or otherwise formed to achieve its operative shape.
- These fibers are particularly useful as pump packings, valve stem packings, and similar products when braided Into a square or round cross section.
- the combination of the material properties and the dimensions will form dynamic and static liquid seal inside a pump stuffing box and valve body.
- This material can be readily braided into square sizes ranging from 0.125 inches (0.32 cm) to 3 Inches (7.6 cm).
- the material can also be used as a filler fiber within a braid or a jacket fiber over core material.
- Other possible applications for this material include as sealing devices (e.g. as gaskets sealing an opening), heat sinks, electrical insulation, etc.
- the fibers of the present invention have numerous advantages over existing packing materials.
- the fibers of the present invention are both thermally conductive and electrically non-conductive.
- the fibers of the present invention can be freely placed in direct contact with metals subject to oxidation (e.g. iron or steel), even in the presence of a corrosive media like seawater, without risk of establishing a corrosive galvanic cell.
- the fiber of the present Invention is particularly useful as a packing or sealing media in difficult corrosive environments, such as in submerged marine applications.
- a slurry of 4.38 Kg of boron nitride and 55.01 of de ionized H2O was prepared in a 1151 baffled stainless steel container.
- the boron nitride was grade HCP obtained from Advanced Ceramics, Inc. While the slurry was agitating, 4.32 Kg. of PTFE in the form of a 15.7% dispersion was rapidly poured into the vessel.
- the PTFE dispersion was an aqueous dispersion obtained from ICI Americas Inc. The mixture coagulated and after 2 minutes the mixer was stopped. The solids settled to the bottom of the vessel and the effluent was clear.
- the coagulum was dried at 165°C in a convection oven for 24 hours.
- the material dried in small cracked cakes and was chilled to below 0°C.
- the chilled cake was hand ground using a tight circular motion with minimal downward force through a ⁇ .635 cm stainless steel screen, then 0.267 Kg of mineral spirits per Kg of powder was added.
- the mixture was chilled, again passed through a 0.635 cm screen, tumbled for 10 minutes, then allowed to sit at 18°C for 24 hours.
- a pellet was formed in a cylinder by pulling vacuum and pressing at 850 psi. The pellet was heated to 49°C and then extruded into tape form.
- the tape was then calendered through heated rolls to 0.043 cm.
- the lubricant was dried and the tape was stretched by running it across heated rolls at 275°C maximum temperature, at a stretch rate of 5.9-1 ratio and 48.7 meters/min. output speed.
- Example 2 The composition from Example 1 was employed.
- the tape was stretched across a heated plate at 385°C, at a stretch rate of 3.4:1 ratio and 34 meters/min output speed.
- the tape was then stretched across heated plate at 365°C at a ratio of 1.2:1 and 41 meters/min. output speed.
- the tape was sintered across a heated plate at 405 ⁇ C at 42 meters/min.
- the tape was then slit into a fiber 1.5 inches (3.8 cm) wide and the fiber was converted into a 0.375 inch (0.95 cm) square braid.
- the braid incorporated 196 fibers.
- Braid was made as per Examples 1 and 2.
- the braid was dipped into a 1000 centistoke silicone oil to form a lubrication coating thereon.
- Tape was made as per Examples 1 and 2. The tape was calendered through heated rolls to 0.0008 Inches (0.002 cm) thick. The tape was then slit into a fiber 1.5 inches (3.8 cm) wide and the fiber was converted into a 0.375 inch (0.95 cm) square braid. The braid incorporated 108 fibers.
- Tape was made as per Examples 1 and 2. The tape was calendered through heated rolls to 0.0012 inches (0.003 cm) thick. The tape was then slit into a fiber 1.5 inches (3.8 cm) wide. The fiber was then converted into a .0375 inch (0.95 cm) square braid. The braid incorporated 108 fibers.
- Tape was made as per Examples 1 and 2. Multiple pieces of tape were merged with a thermally conductive liquid comprised of 13.2% by weight of a 60% aqueous PTFE dispersion, 29.4% by weight of HCP grade boron nitride, 28% by weight water, 27.5% by weight of a 1000 centistoke silicone oil, 1.8% by weight on a non-ionic surfactant, and 0.1% by weight of a 5% ammonium hydroxide.
- the composite was dried in an oven at 190°C for 18 hours. The composite was slit into a fiber approximately 0.6 Inches (1.5 cm) wide. The fiber was converted into a 0.375 inch (0.95 cm) square braid. The braid incorporated 42 fibers.
- Thermal conductivity is the material property that determines the amount of heat that will flow through an object when a temperature difference exits across the object. Thermal conductivity is a steady state property; it can only be directly measured under conditions in which the temperature distribution is not changing and all heat flows are steady. In the instant case, thermal conductivity was determined in a manner similar to that described in ASTM (American Society for Testing and Materials) Standard Test Method E 1225 (Standard Test Method for Thermal Conductivity of Solids by Means of the Guarded-Comparative -Longitudinal Heat Flow Technique).
- thermal conductivity was measured at a nominal temperature of 200°C using the guarded comparative longitudinal heat flow technique.
- the samples were submitted as braided lengths of material.
- the samples were cut into 2-inch lengths; these were laid side-by-side to produce test samples 2 inches square. No thermocouples were placed In the test samples. Surface temperatures of the test samples were obtained by extrapolation from thermocouples in the reference samples.
- PYREX material type-7740 was used as the thermal conductivity reference material .
- thermal conductivity (°C or ⁇ F) ⁇ X - the thickness (m or ft) A - the cross sectional area ( ⁇ r or ft*).
- thermal insulators Materials that have low values of thermal conductivity allow only a small amount of heat flow and are called thermal insulators. Materials with large values of thermal conductivity allow more heat to flow across the slab with the same temperature difference. Thermal conductivity is a material property and does not depend upon the geometry of the sample. In general, thermal conductivity is a function of the mean sample temperature.
- thermocouples were placed at known separations. The thermocouples were placed into holes or grooves in the reference material and also in the sample whenever the sample was thick enough to accommodate them.
- the stack was clamped with a reproducible load to insure intimate contact between the components.
- a guard tube was placed around the stack and the intervening space was filled with insulating grains of vermiculite or zeolite.
- the temperature gradient in the guard was matched to that in the stack to reduce radial heat flow further.
- the comparative method is a steady state method of measuring thermal conductivity. When equilibrium was reached, the heat flux (analogous to current flow) down the stack was determined from the references.
- the heat into the sample is given by the following formula: and the heat out of the sample is given by:
- the sample thermal conductivity is then found from ⁇ sample - Q/(d ⁇ /dx) sam pi e .
- --Theoretical Coefficient of Expansion was derived by determining the coefficient of thermal expansion of each of the components from product literature or through established sources. The overall coefficient of thermal expansion was determined by multiplying each of the individual component's coefficient of thermal expansions by its weight percentage in the mixture and taking the sum of this amount for the combined components in the mixture.
- An expanded PTFE fiber from W. L. Gore & Associates, Inc., of Elkton, MD, was formed into a tow material by passing it through a series of rotating cutting elements.
- the towed expanded PTFE fiber was then dipped into an aqueous tetrafluoroethylene (TFE) homopoly er dispersion including a doping of about 10% by weight tin powder.
- TFE aqueous tetrafluoroethylene
- the TFE dispersion comprised a 60% solution of TFE solids suspended in deionized water.
- the dispersion was acquired from ICI Americas, Inc., of Wilmington, DE, under the trademark FLU0N AD-1.
- the tin powder was acquired from AEE of Bergenfield, NJ, under the trade designation Powdered Tin (1-2 mm particle size).
- the TFE dispersion was sheared in place on the fiber, encapsulating the tin particles in and on the towed fiber, by pulling the coated fiber across two 1/8 inch diameter stationary bars at a rate of 55 ft/min (16.8 m/min). The fiber was then heated to 180°C for about 45 seconds to drive off the water. The final product fiber contained approximately 3-4% by weight tin. Thermal conductivity was measured at 0.45 W/m-K.
- Tin is thermally conductive and has a silvery tinge to it. It is a good lubricant with excellent corrosion resistant qualities.
- a towed expanded PTFE fiber similar to that employed in Example 8 was dipped into an aqueous TFE homopolymer dispersion including a doping of 20% by weight boron nitride powder acquired from Aldrich Chemical Co., Inc., of Milwaukee, WI.
- the dipped fiber was then mechanically worked by agitating in the following manner of stirring the aqueous bath by hand with a 3/8 inch diameter stirring rod and then running the material through a series of two 1/8 inch diameter stationary bars at a rate of 30 ft/min (9.1 m/min) to cause the TFE to shear.
- the shearing of the TFE dispersion encapsulated the boron nitride particles in and on the towed fiber.
- the fiber was heated to 180°C for about 1 to 2 minutes to drive off the water.
- the dipped fiber contained approximately 7% by weight boron nitride.
- This fiber was formed into a braid.
- the braided material tested to have a thermal conductivity of 0.60 W/m-K, considerably better than a conventional packing fiber.
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6525518A JPH08510018A (en) | 1993-05-07 | 1994-05-04 | Light-colored thermally conductive sealant material and method for producing the same |
EP94915998A EP0697039A1 (en) | 1993-05-07 | 1994-05-04 | Light colored conductive sealant material and method of producing same |
AU67816/94A AU6781694A (en) | 1993-05-07 | 1994-05-04 | Light colored conductive sealant material and method of producing same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US5916393A | 1993-05-07 | 1993-05-07 | |
US08/059,163 | 1993-05-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1994026960A1 true WO1994026960A1 (en) | 1994-11-24 |
Family
ID=22021240
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1994/004911 WO1994026960A1 (en) | 1993-05-07 | 1994-05-04 | Light colored conductive sealant material and method of producing same |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0697039A1 (en) |
JP (1) | JPH08510018A (en) |
AU (1) | AU6781694A (en) |
CA (1) | CA2160026A1 (en) |
WO (1) | WO1994026960A1 (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0730017A2 (en) * | 1995-03-02 | 1996-09-04 | W.L. GORE & ASSOCIATES, INC. | Improved resilient sealing gasket |
EP0794227A2 (en) * | 1996-03-05 | 1997-09-10 | Advanced Ceramics Corporation | Enhanced boron nitride composition and polymer based high thermal conductivity molding compound |
WO1997033949A1 (en) * | 1996-03-13 | 1997-09-18 | W.L. Gore & Associates Gmbh | Gasket with corrosion inhibitor |
WO2004040175A1 (en) * | 2002-10-28 | 2004-05-13 | Carl Freudenberg Kg | Sealing material for stuffing-box packing |
EP2109639A1 (en) * | 2007-02-06 | 2009-10-21 | Enpro - Garlock Sealing Technologies | Boron nitride filled ptfe |
CN106084285A (en) * | 2016-06-17 | 2016-11-09 | 中国石油化工股份有限公司 | A kind of nanometer BN fills the method that PTFE prepares Wear-resistant, high-temperature resistant composite |
CN110437807A (en) * | 2019-08-15 | 2019-11-12 | 常州富烯科技股份有限公司 | Interface Heat Conduction Material and preparation method thereof |
CN112708229A (en) * | 2020-12-24 | 2021-04-27 | 浙江国泰萧星密封材料股份有限公司 | Preparation method of high-temperature-resistant mud-shaped filler |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3945624A1 (en) * | 2020-07-30 | 2022-02-02 | 3M Innovative Properties Company | Composite material comprising polytetrafluoroethylene and hexagonal boron nitride particles |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2971908A (en) * | 1957-08-15 | 1961-02-14 | Shamban & Co W S | Process for reinforcing polytetra-fluoroethylene resin |
FR1554950A (en) * | 1967-01-24 | 1969-01-24 | ||
US4096227A (en) * | 1973-07-03 | 1978-06-20 | W. L. Gore & Associates, Inc. | Process for producing filled porous PTFE products |
GB2054627A (en) * | 1979-07-05 | 1981-02-18 | Gore & Ass | Graphite coatings |
SU214078A1 (en) * | 1966-01-03 | 1990-08-15 | Vni Kt I Asbestovykh Tekhn Izd | Method of producing packings |
WO1990010673A1 (en) * | 1989-03-16 | 1990-09-20 | W.L. Gore & Associates, Inc. | Polytetrafluoroethylene film |
-
1994
- 1994-05-04 JP JP6525518A patent/JPH08510018A/en active Pending
- 1994-05-04 WO PCT/US1994/004911 patent/WO1994026960A1/en not_active Application Discontinuation
- 1994-05-04 CA CA002160026A patent/CA2160026A1/en not_active Abandoned
- 1994-05-04 AU AU67816/94A patent/AU6781694A/en not_active Abandoned
- 1994-05-04 EP EP94915998A patent/EP0697039A1/en not_active Withdrawn
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2971908A (en) * | 1957-08-15 | 1961-02-14 | Shamban & Co W S | Process for reinforcing polytetra-fluoroethylene resin |
SU214078A1 (en) * | 1966-01-03 | 1990-08-15 | Vni Kt I Asbestovykh Tekhn Izd | Method of producing packings |
FR1554950A (en) * | 1967-01-24 | 1969-01-24 | ||
US4096227A (en) * | 1973-07-03 | 1978-06-20 | W. L. Gore & Associates, Inc. | Process for producing filled porous PTFE products |
GB2054627A (en) * | 1979-07-05 | 1981-02-18 | Gore & Ass | Graphite coatings |
US4256806A (en) * | 1979-07-05 | 1981-03-17 | W. L. Gore & Associates, Inc. | Smudge free graphite coated polymeric substrate and a method for preparing the same |
WO1990010673A1 (en) * | 1989-03-16 | 1990-09-20 | W.L. Gore & Associates, Inc. | Polytetrafluoroethylene film |
Non-Patent Citations (1)
Title |
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DATABASE WPI Section Ch Week 9117, Derwent World Patents Index; Class A, AN 91-123269 * |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0730017A2 (en) * | 1995-03-02 | 1996-09-04 | W.L. GORE & ASSOCIATES, INC. | Improved resilient sealing gasket |
EP0730017A3 (en) * | 1995-03-02 | 1996-09-18 | Gore & Ass | |
EP0794227A2 (en) * | 1996-03-05 | 1997-09-10 | Advanced Ceramics Corporation | Enhanced boron nitride composition and polymer based high thermal conductivity molding compound |
EP0794227A3 (en) * | 1996-03-05 | 1999-12-29 | Advanced Ceramics Corporation | Enhanced boron nitride composition and polymer based high thermal conductivity molding compound |
WO1997033949A1 (en) * | 1996-03-13 | 1997-09-18 | W.L. Gore & Associates Gmbh | Gasket with corrosion inhibitor |
US6194074B1 (en) | 1996-03-13 | 2001-02-27 | Amadeus Wiesemann | Gasket with corrosion inhibitor |
WO2004040175A1 (en) * | 2002-10-28 | 2004-05-13 | Carl Freudenberg Kg | Sealing material for stuffing-box packing |
DE10250264B4 (en) * | 2002-10-28 | 2005-07-28 | Carl Freudenberg Kg | Sealing material for stuffing box packings |
EP2109639A1 (en) * | 2007-02-06 | 2009-10-21 | Enpro - Garlock Sealing Technologies | Boron nitride filled ptfe |
EP2109639A4 (en) * | 2007-02-06 | 2010-08-25 | Garlock Sealing Technologies | Boron nitride filled ptfe |
CN106084285A (en) * | 2016-06-17 | 2016-11-09 | 中国石油化工股份有限公司 | A kind of nanometer BN fills the method that PTFE prepares Wear-resistant, high-temperature resistant composite |
CN110437807A (en) * | 2019-08-15 | 2019-11-12 | 常州富烯科技股份有限公司 | Interface Heat Conduction Material and preparation method thereof |
CN112708229A (en) * | 2020-12-24 | 2021-04-27 | 浙江国泰萧星密封材料股份有限公司 | Preparation method of high-temperature-resistant mud-shaped filler |
Also Published As
Publication number | Publication date |
---|---|
JPH08510018A (en) | 1996-10-22 |
AU6781694A (en) | 1994-12-12 |
CA2160026A1 (en) | 1994-11-24 |
EP0697039A1 (en) | 1996-02-21 |
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