WO1996033202A3 - Transition metal catalyst based on bidentate ligands containing pyridine or quinoline moiety - Google Patents

Transition metal catalyst based on bidentate ligands containing pyridine or quinoline moiety Download PDF

Info

Publication number
WO1996033202A3
WO1996033202A3 PCT/US1996/003656 US9603656W WO9633202A3 WO 1996033202 A3 WO1996033202 A3 WO 1996033202A3 US 9603656 W US9603656 W US 9603656W WO 9633202 A3 WO9633202 A3 WO 9633202A3
Authority
WO
WIPO (PCT)
Prior art keywords
transition metal
metal catalyst
independently selected
catalyst based
bidentate ligands
Prior art date
Application number
PCT/US1996/003656
Other languages
French (fr)
Other versions
WO1996033202A2 (en
Inventor
Sandor Nagy
Ramesh Krishnamurti
John A Tyrell
Leonard V Cribbs
Mary Cocoman
Original Assignee
Occidental Chem Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Occidental Chem Co filed Critical Occidental Chem Co
Priority to BR9608224-0A priority Critical patent/BR9608224A/en
Priority to MX9707982A priority patent/MX9707982A/en
Priority to DE69615554T priority patent/DE69615554T2/en
Priority to AU53144/96A priority patent/AU5314496A/en
Priority to EP96909748A priority patent/EP0832089B1/en
Priority to CA002218638A priority patent/CA2218638C/en
Priority to JP8531730A priority patent/JPH11503785A/en
Publication of WO1996033202A2 publication Critical patent/WO1996033202A2/en
Publication of WO1996033202A3 publication Critical patent/WO1996033202A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic System without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/28—Titanium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/49—Hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/56—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/57—Niobium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/66—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/828—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/226—Sulfur, e.g. thiocarbamates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Abstract

Disclosed is a novel bidentate pyridine transition metal catalyst having general formula (1), where Y is O, S, NR, (2), or (3), each R is independently selected from hydrogen or C1 to C6 alkyl, each R' is independently selected from C1 to C6 alkyl, C1 to C6 alkoxy, C6 to C16 aryl, halogen, or CF3, M is titanium, zirconium, or hafnium, each X is independently selected from halogen, C1 to C6 alkyl, C1 to C6 alkoxy, or (4), L is X, cyclopentadienyl, C1 to C6 alkyl substituted cyclopentadienyl, indenyl, fluorenyl, or (5), 'm' is 0 to 4, and 'n' is 1 to 4. Also disclosed is a method of making a poly-α-olefin comprising polymerizing an α-olefin monomer using that catalyst or a catalyst that has general formula (6), where Y, M, L, X, and R' were previously defined and each 'p' is independently selected from 0 to 3.
PCT/US1996/003656 1995-04-17 1996-03-18 Transition metal catalyst based on bidentate ligands containing pyridine or quinoline moiety WO1996033202A2 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
BR9608224-0A BR9608224A (en) 1995-04-17 1996-03-18 Polymerization of alpha-olefins with transition metal catalysts based on bidentated binders containing half pyridine or quinoline
MX9707982A MX9707982A (en) 1995-04-17 1996-03-18 Transition metal catalyst based on bidentate ligands containing pyridine or quinoline moiety.
DE69615554T DE69615554T2 (en) 1995-04-17 1996-03-18 PYRIDINE-CONTAINING TWO-TEED LIGANDS-BASED TRANSITION METAL CATALYST
AU53144/96A AU5314496A (en) 1995-04-17 1996-03-18 Transition metal catalyst based on bidentate ligands containing pyridine or quinoline moiety
EP96909748A EP0832089B1 (en) 1995-04-17 1996-03-18 Transition metal catalyst based on bidentate ligands containing pyridine moiety
CA002218638A CA2218638C (en) 1995-04-17 1996-03-18 Polymerization of alpha-olefins with transition metal catalysts based on bidentate ligands containing pyridine or quinoline moiety
JP8531730A JPH11503785A (en) 1995-04-17 1996-03-18 Polymerization of α-olefins using transition metal catalysts based on bidentate ligands containing pyridine or quinoline

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/423,232 1995-04-17
US08/423,232 US5637660A (en) 1995-04-17 1995-04-17 Polymerization of α-olefins with transition metal catalysts based on bidentate ligands containing pyridine or quinoline moiety

Publications (2)

Publication Number Publication Date
WO1996033202A2 WO1996033202A2 (en) 1996-10-24
WO1996033202A3 true WO1996033202A3 (en) 1996-11-28

Family

ID=23678124

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1996/003656 WO1996033202A2 (en) 1995-04-17 1996-03-18 Transition metal catalyst based on bidentate ligands containing pyridine or quinoline moiety

Country Status (12)

Country Link
US (3) US5637660A (en)
EP (2) EP0832089B1 (en)
JP (1) JPH11503785A (en)
KR (1) KR19990007920A (en)
CN (1) CN1068331C (en)
AU (1) AU5314496A (en)
BR (1) BR9608224A (en)
DE (2) DE69635719T2 (en)
ES (2) ES2164878T3 (en)
MX (1) MX9707982A (en)
RU (1) RU2169735C2 (en)
WO (1) WO1996033202A2 (en)

Families Citing this family (179)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5637660A (en) * 1995-04-17 1997-06-10 Lyondell Petrochemical Company Polymerization of α-olefins with transition metal catalysts based on bidentate ligands containing pyridine or quinoline moiety
EP0852230B1 (en) * 1995-08-31 2001-12-05 Sumitomo Chemical Company Limited Transition metal complexes, catalyst for olefin polymerization, and process for producing olefin polymers
US5852146A (en) * 1996-06-27 1998-12-22 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
WO1998016311A1 (en) * 1996-10-15 1998-04-23 Northwestern University Phenolate constrained geometry metallocene olefin polymerization catalyst, method of making, and method of using
US6214761B1 (en) * 1996-12-17 2001-04-10 E. I. Du Pont De Nemours And Company Iron catalyst for the polymerization of olefins
US6417305B2 (en) * 1996-12-17 2002-07-09 E. I. Du Pont De Nemours And Company Oligomerization of ethylene
US6432862B1 (en) * 1996-12-17 2002-08-13 E. I. Du Pont De Nemours And Company Cobalt catalysts for the polymerization of olefins
US6451938B1 (en) 1997-02-25 2002-09-17 Exxon Mobil Chemical Patents Inc. Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands
TWI246520B (en) * 1997-04-25 2006-01-01 Mitsui Chemicals Inc Processes for olefin polymerization
US6268447B1 (en) * 1998-12-18 2001-07-31 Univation Technologies, L.L.C. Olefin polymerization catalyst
US6103657A (en) * 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
US6096676A (en) * 1997-07-02 2000-08-01 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
US6136748A (en) * 1997-07-02 2000-10-24 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for the polymerization of olefins
CN1067690C (en) * 1998-03-04 2001-06-27 中国科学院化学研究所 Catalyst system for syndiotactic polymerization, its preparing method and use thereof
GB9809207D0 (en) * 1998-04-29 1998-07-01 Bp Chem Int Ltd Novel catalysts for olefin polymerisation
JP2002519497A (en) 1998-07-01 2002-07-02 エクソンモービル・ケミカル・パテンツ・インク Elastic blend comprising a crystalline propylene polymer and a crystallizable propylene polymer
US6303719B1 (en) 1998-12-18 2001-10-16 Univation Technologies Olefin polymerization catalyst system
US6333389B2 (en) * 1998-12-18 2001-12-25 Univation Technologies, Llc Olefin polymerization catalysts, their production and use
US6180552B1 (en) 1999-04-07 2001-01-30 Equistar Chemicals, L.P. Transition metal complexes containing neutral, multidentate azacyclic ligands
US6204216B1 (en) 1999-04-15 2001-03-20 Equistar Chemicals, L.P. Olefin polymerization catalysts containing amine derivatives
US6201076B1 (en) 1999-04-29 2001-03-13 Equistar Chemicals, L.P. Olefin polymerization process with fatty amine additives for improved activity and reduced fouling
US6020493A (en) * 1999-05-06 2000-02-01 Equistar Chemicals, Lp Single-site catalyst preparation
US6271325B1 (en) 1999-05-17 2001-08-07 Univation Technologies, Llc Method of polymerization
US6291386B1 (en) 1999-05-25 2001-09-18 Equistar Chemicals, Lp Process for the in-situ preparation of single-site transition metal catalysts and polymerization process
US6211311B1 (en) * 1999-05-25 2001-04-03 Equistar Chemicals, L.P. Supported olefin polymerization catalysts
US6239062B1 (en) 1999-09-02 2001-05-29 Equistar Chemicals, L.P. Olefin polymerization catalysts containing indolyl-amido ligands
US6194527B1 (en) 1999-09-22 2001-02-27 Equistar Chemicals, L.P. Process for making polyolefins
US6265504B1 (en) 1999-09-22 2001-07-24 Equistar Chemicals, Lp Preparation of ultra-high-molecular-weight polyethylene
US6232260B1 (en) 1999-10-14 2001-05-15 Equistar Chemicals, L.P. Single-site catalysts for olefin polymerization
US6228959B1 (en) 1999-10-15 2001-05-08 Equistar Chemicals, L.P. Single-site catalysts containing homoaromatic ligands
US6274684B1 (en) * 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US6417304B1 (en) 1999-11-18 2002-07-09 Univation Technologies, Llc Method of polymerization and polymer produced therefrom
US6271323B1 (en) 1999-10-28 2001-08-07 Univation Technologies, Llc Mixed catalyst compounds, catalyst systems and their use in a polymerization process
US6380328B1 (en) 1999-12-10 2002-04-30 Univation Technologies, Llc Catalyst systems and their use in a polymerization process
US6265505B1 (en) 1999-11-18 2001-07-24 Univation Technologies, Llc Catalyst system and its use in a polymerization process
US6300438B1 (en) 1999-10-22 2001-10-09 Univation Technolgies, Llc Hafnium transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6300439B1 (en) 1999-11-08 2001-10-09 Univation Technologies, Llc Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6624107B2 (en) 1999-10-22 2003-09-23 Univation Technologies, Llc Transition metal catalyst compounds having deuterium substituted ligand and catalyst systems thereof
BR0015192B1 (en) * 1999-11-01 2010-11-03 supported bi-or tri-dented catalyst composition, heterogeneous and active for olefin polymerization.
US6294626B1 (en) 1999-11-15 2001-09-25 Equistar Chemicals, Lp Olefin polymerization catalysts containing modified boraaryl ligands
US6281155B1 (en) 1999-11-19 2001-08-28 Equistar Chemicals, L.P. Supported olefin polymerization catalysts
US6281306B1 (en) * 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
US6239239B1 (en) * 2000-02-17 2001-05-29 Equistar Chemicals, L.P. Quinolinoxy and pyridinoxy single-site catalysts containing benzyl ligands
US6255415B1 (en) * 2000-02-29 2001-07-03 Equistar Chemicals, L.P. Ethylene polymerization process
US6476165B1 (en) 2000-03-08 2002-11-05 Equistar Chemicals, Lp Olefin polymerization process using fatty amine additives and boron-modified supported catalyst
US6498221B1 (en) * 2000-03-30 2002-12-24 Equistar Chemicals, Lp Single-site catalysts containing chelating N-oxide ligands
US6812304B2 (en) 2000-06-14 2004-11-02 Equistar Chemicals, Lp Process for producing improved premixed supported boraaryl catalysts
JP2004504420A (en) * 2000-07-17 2004-02-12 ユニベーション・テクノロジーズ・エルエルシー Catalyst systems and their use in polymerization processes
US6433088B1 (en) 2000-08-04 2002-08-13 Equistar Chemicals, Lp Clear and printable polypropylene films
US6486270B1 (en) 2000-08-25 2002-11-26 Equistar Chemicals, Lp High molecular weight, medium density polyethylene
US6355733B1 (en) 2000-10-13 2002-03-12 Equistar Chemicals, Lp Polyethylene blends and films
US6414099B1 (en) 2000-10-18 2002-07-02 Equistar Chemicals, Lp Single-site catalysts based on caged diimide ligands
AU2002225662A1 (en) * 2000-11-07 2002-05-21 Symyx Technologies, Inc. Substituted pyridyl amine ligands, complexes and catalysts therefrom; processes for producing polyolefins therewith
US6660678B1 (en) * 2000-11-21 2003-12-09 Equistar Chemicals, Lp Single-site catalysts for olefin polymerization
DE60137590D1 (en) * 2000-12-06 2009-03-19 Omlidon Technologies Llc Melt-processable, wear-resistant polyethylene
EP1700870B9 (en) 2000-12-06 2009-09-02 Eidgenössische Technische Hochschule Zürich Melt-processible, wear resistant polyethylene
WO2002053603A2 (en) 2000-12-28 2002-07-11 Univation Technologies, Llc Polymerization catalyst system, polymerization process and polymer therefrom
US6673882B2 (en) * 2001-02-12 2004-01-06 Equistar Chemicals, Lp Supported single-site catalysts useful for olefin polymerization
US6664349B2 (en) 2001-03-29 2003-12-16 Equistar Chemicals, Lp Ethylene polymerization process
US6579957B2 (en) 2001-04-11 2003-06-17 Equistar Chemicals, Lp Single-site catalysts based on anionic thiopyran dioxide ligands
JP5156167B2 (en) 2001-04-12 2013-03-06 エクソンモービル・ケミカル・パテンツ・インク Propylene-ethylene polymer and production method
US6391988B1 (en) 2001-04-18 2002-05-21 Equistar Chemicals L.P. Tris(pyrazoyl) based anions
US6583240B2 (en) 2001-05-23 2003-06-24 Equistar Chemicals, Lp Ethylene polymerization process
US6759361B2 (en) 2001-06-04 2004-07-06 Equistar Chemicals, Lp Aluminoboronate activators for single-site olefin polymerization catalysts
US6489414B1 (en) 2001-06-06 2002-12-03 Equistar Chemicals, Lp Chelating pyrimidines as ligands for single-site olefin polymerization catalysts
US6544918B1 (en) 2001-07-17 2003-04-08 Equistar Chemicals, Lp Olefin polymerization catalysts containing chelating dianionic ligands
US6583242B2 (en) 2001-08-02 2003-06-24 Equistar Chemicals, Lp Supported olefin polymerization catalysts
WO2003025028A1 (en) * 2001-09-14 2003-03-27 Basell Polyolefine Gmbh Method for the polymerization of olefins
WO2003024983A1 (en) * 2001-09-14 2003-03-27 Sumitomo Chemical Company, Limited Transition metal complex, catalyst for olefin polymerization, and process for producing olefin polymer with the same
DE10145453A1 (en) * 2001-09-14 2003-06-05 Basell Polyolefine Gmbh Monocyclopentadienyl complexes with a condensed heterocycle
CN1160381C (en) * 2001-09-27 2004-08-04 中国石油化工股份有限公司 Olefine polymerization catalyst containing double schiff base ligand and preparing method and use
US6927256B2 (en) * 2001-11-06 2005-08-09 Dow Global Technologies Inc. Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent
US6906160B2 (en) * 2001-11-06 2005-06-14 Dow Global Technologies Inc. Isotactic propylene copolymer fibers, their preparation and use
US6960635B2 (en) * 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
EP1308450A3 (en) * 2001-11-06 2003-10-01 Symyx Technologies, Inc. Titanium substituted pyridyl amine complexes, catalysts and processes for polymerizing ethylene and styrene
JP2005508415A (en) 2001-11-06 2005-03-31 ダウ グローバル テクノロジーズ インコーポレイティド Isotactic propylene copolymers, their production and use
US7001863B2 (en) 2001-12-18 2006-02-21 Univation Technologies, Llc Monoamide based catalyst compositions for the polymerization of olefins
US6831187B2 (en) 2001-12-18 2004-12-14 Univation Technologies, Llc Multimetallic catalyst compositions for the polymerization of olefins
US6864205B2 (en) 2001-12-18 2005-03-08 Univation Technologies, Llc Heterocyclic-amide catalyst compositions for the polymerization of olefins
US7199255B2 (en) 2001-12-18 2007-04-03 Univation Technologies, Llc Imino-amide catalysts for olefin polymerization
US6919467B2 (en) 2001-12-18 2005-07-19 Univation Technologies, Llc Imino-amide catalyst compositions for the polymerization of olefins
US6586545B1 (en) 2001-12-20 2003-07-01 Equistar Chemicals, Lp Complexes based on four-membered cyclic anionic six-electron-donor ligands
US6596826B1 (en) 2001-12-20 2003-07-22 Equistar Chemicals, Lp Olefin polymerization catalysts containing 1,3-diboretanyl ligands
US6635728B2 (en) * 2002-01-10 2003-10-21 Equistar Chemicals, Lp Preparation of ultra-high-molecular-weight polyethylene
US6613841B2 (en) 2002-01-28 2003-09-02 Equistar Chemicals, Lp Preparation of machine direction oriented polyethylene films
US6780807B2 (en) 2002-02-04 2004-08-24 Equistar Chemicals L.P. Acyclic anionic six-electron-donor ancillary ligands
US6825296B2 (en) * 2002-03-29 2004-11-30 The University Of Hong Kong Catalyst component for olefin polymerization
US6693157B2 (en) * 2002-04-08 2004-02-17 Equistar Chemicals, Lp Olefin polymerization catalysts containing triquinane ligands
US6908972B2 (en) 2002-04-16 2005-06-21 Equistar Chemicals, Lp Method for making polyolefins
US7094723B2 (en) * 2002-04-18 2006-08-22 Equistar Chemicals Lp Catalysts containing at least one heterocyclic ligand for improving the catalysts' performance of olefin polymerization
US6642326B1 (en) 2002-05-03 2003-11-04 Equistar Chemicals, Lp Use of silanes to enhance activity in single-site polymerizations
US6649698B1 (en) 2002-05-17 2003-11-18 Equistar Chemicals, Lp Polyethylene blends
US6762255B2 (en) 2002-06-06 2004-07-13 Equistar Chemicals L.P. Prealkylated olefin polymerization catalysts and olefin polymerization employing such catalysts
US6630547B1 (en) 2002-06-11 2003-10-07 Equistar Chemicals, Lp Use of silanes to control molecular weight in olefin polymerizations
US7105672B2 (en) * 2002-08-19 2006-09-12 The University Of Hong Kong Cyclometallated catalysts
US6765074B2 (en) 2002-09-27 2004-07-20 Equistar Chemicals, Lp Olefin polymerization process
KR101113341B1 (en) 2002-10-15 2012-09-27 엑손모빌 케미칼 패턴츠 인코포레이티드 Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US6884749B2 (en) 2002-10-17 2005-04-26 Equistar Chemicals L.P. Supported catalysts which reduce sheeting in olefin polymerization, process for the preparation and the use thereof
US6630548B1 (en) 2002-11-01 2003-10-07 Equistar Chemicals, Lp Static reduction
US7579407B2 (en) * 2002-11-05 2009-08-25 Dow Global Technologies Inc. Thermoplastic elastomer compositions
US7459500B2 (en) * 2002-11-05 2008-12-02 Dow Global Technologies Inc. Thermoplastic elastomer compositions
US6716936B1 (en) 2002-12-16 2004-04-06 Equistar Chemicals L.P. Cascaded boiling pool slurry reactors for producing bimodal low to medium density polyethylene polymers
US6713576B1 (en) 2003-02-25 2004-03-30 Equistar Chemicals, Lp Olefin polymerization catalysts based on convex, polcyclic ligands
EP1611169B1 (en) 2003-03-21 2010-06-02 Dow Global Technologies Inc. Morphology controlled olefin polymerization process
WO2004089963A1 (en) * 2003-04-04 2004-10-21 San Diego State University Foundation Compositions and methods for facilitating reaction at room temperature
US6710005B1 (en) 2003-04-10 2004-03-23 Equistar Chemicals, Lp Aluminoxane modification
US6984599B2 (en) * 2003-04-23 2006-01-10 Equistar Chemicals, Lp Olefin polymerization catalysts based on hydroxyl-depleted calixarene ligands
US6774078B1 (en) 2003-04-23 2004-08-10 Equistar Chemicals, Lp Olefin polymerization catalysts based on annulated cyclopentadienyl ligands
US6953764B2 (en) 2003-05-02 2005-10-11 Dow Global Technologies Inc. High activity olefin polymerization catalyst and process
US6995216B2 (en) * 2003-06-16 2006-02-07 Equistar Chemicals, Lp Process for manufacturing single-site polyolefins
US6767975B1 (en) * 2003-07-14 2004-07-27 Equistar Chemicals, Lp Olefin polymerization with pyridine moiety-containing singe-site catalysts
US6930156B2 (en) * 2003-10-22 2005-08-16 Equistar Chemicals, Lp Polymer bound single-site catalysts
US20050148742A1 (en) * 2004-01-02 2005-07-07 Hagerty Robert O. Method for controlling sheeting in gas phase reactors
US7985811B2 (en) * 2004-01-02 2011-07-26 Univation Technologies, Llc Method for controlling sheeting in gas phase reactors
US20070073012A1 (en) * 2005-09-28 2007-03-29 Pannell Richard B Method for seed bed treatment before a polymerization reaction
US7011892B2 (en) * 2004-01-29 2006-03-14 Equistar Chemicals, Lp Preparation of polyethylene films
US20050200046A1 (en) * 2004-03-10 2005-09-15 Breese D. R. Machine-direction oriented multilayer films
US7037987B2 (en) * 2004-03-26 2006-05-02 Rohn And Haas Company Olefin polymerization catalyst and polymerization process
WO2005099432A2 (en) * 2004-04-05 2005-10-27 Leucadia, Inc. Degradable netting
US7598328B2 (en) * 2004-04-07 2009-10-06 Dow Global Technologies, Inc. Supported catalysts for manufacture of polymers
US7175918B2 (en) * 2004-04-27 2007-02-13 Equistar Chemicals, Lp Polyolefin compositions
WO2006009980A2 (en) * 2004-06-21 2006-01-26 Exxonmobil Chemical Patents Inc. Olefin polymerisation process
US8440125B2 (en) 2004-06-28 2013-05-14 Equistar Chemicals, Lp Polyethylene films having high resistance to deformation or elongation
CA2473378A1 (en) * 2004-07-08 2006-01-08 Nova Chemicals Corporation Novel borate activator
US7125939B2 (en) * 2004-08-30 2006-10-24 Equistar Chemicals, Lp Olefin polymerization with polymer bound single-site catalysts
US7402546B2 (en) * 2004-09-23 2008-07-22 Equistar Chemicals, Lp Magnesium chloride support
WO2006049699A1 (en) 2004-10-29 2006-05-11 Exxonmobil Chemical Patents Inc Catalyst compound containing divalent tridentate ligand
US7705157B2 (en) * 2004-12-16 2010-04-27 Symyx Solutions, Inc. Phenol-heterocyclic ligands, metal complexes, and their uses as catalysts
US20060177641A1 (en) * 2005-02-09 2006-08-10 Breese D R Multilayer polyethylene thin films
US8034461B2 (en) * 2005-02-09 2011-10-11 Equistar Chemicals, Lp Preparation of multilayer polyethylene thin films
EP1856010B1 (en) * 2005-03-09 2010-07-28 ExxonMobil Chemical Patents Inc. Methods for oligomerizing olefins
US7414006B2 (en) * 2005-03-09 2008-08-19 Exxonmobil Chemical Patents Inc. Methods for oligomerizing olefins
US8461223B2 (en) * 2005-04-07 2013-06-11 Aspen Aerogels, Inc. Microporous polycyclopentadiene-based aerogels
US9469739B2 (en) 2005-04-07 2016-10-18 Aspen Aerogels, Inc. Microporous polyolefin-based aerogels
WO2007005400A2 (en) 2005-07-01 2007-01-11 Albemarle Corporation Aluminoxanate salt compositions having improved stability in aromatic and aliphatic solvents
US7232604B2 (en) * 2005-07-28 2007-06-19 Equistar Chemicals, Lp Flame retardant crosslinkable compositions and articles
US7273914B2 (en) * 2005-08-03 2007-09-25 Equistar Chemicals, Lp Olefin polymerization methods
US7091291B1 (en) 2005-11-23 2006-08-15 Equistar Chemicals, Lp Olefin polymerization process
US7608327B2 (en) * 2005-12-20 2009-10-27 Equistar Chemicals, Lp High tear strength film
EP1803747A1 (en) 2005-12-30 2007-07-04 Borealis Technology Oy Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films
US7982085B2 (en) * 2006-02-03 2011-07-19 Exxonmobil Chemical Patents Inc. In-line process for generating comonomer
US8003839B2 (en) * 2006-02-03 2011-08-23 Exxonmobil Chemical Patents Inc. Process for generating linear apha olefin comonomers
US8076524B2 (en) * 2006-02-03 2011-12-13 Exxonmobil Chemical Patents Inc. Process for generating alpha olefin comonomers
US8404915B2 (en) * 2006-08-30 2013-03-26 Exxonmobil Chemical Patents Inc. Phosphine ligand-metal compositions, complexes, and catalysts for ethylene trimerizations
US8067609B2 (en) * 2007-01-08 2011-11-29 Exxonmobil Chemical Patents Inc. Methods for oligomerizing olefins with chromium pyridine thioether catalysts
US20080182951A1 (en) * 2007-01-08 2008-07-31 Ackerman Lily J Chromium Pyridine Bis(Oxazoline) And Related Catalysts For Ethylene Dimerization
US8138348B2 (en) * 2007-01-08 2012-03-20 Exxonmobil Chemical Patents Inc. Methods for oligomerizing olefins with chromium pyridine mono-oxazoline catalysts
US8629280B2 (en) * 2007-01-08 2014-01-14 Exxonmobil Chemical Patents Inc. Methods for oligomerizing olefins with chromium pyridine ether catalysts
US20080163978A1 (en) * 2007-01-09 2008-07-10 Botros Maged G Process for producing multi-layer structures having improved metal adhesion
US7794848B2 (en) * 2007-01-25 2010-09-14 Equistar Chemicals, Lp MDO multilayer polyethylene film
BRPI0703586B1 (en) 2007-10-19 2018-02-06 Braskem S.A SUPPORTED METALOCENE CATALYST, AND HIGH AND ULTRA HIGH MOLECULAR ALPHA ETHYLENE COPOLYMERS
US20090286944A1 (en) * 2008-05-15 2009-11-19 Symyx Technologies, Inc. Select phenol-heterocycle ligands, metal complexes formed therefrom, and their uses as catalysts
KR101142117B1 (en) * 2008-09-25 2012-05-09 에스케이이노베이션 주식회사 Transition metal catalytic systems and methods for preparing ethylene homopolymers or copolymers of ethylene and ?-olefins using the same
KR101142122B1 (en) * 2008-09-30 2012-05-09 에스케이이노베이션 주식회사 New transition metal catalytic systems and methods for preparing ethylene homopolymers or copolymers of ethylene and ?-olefins using the same
WO2010056822A2 (en) * 2008-11-13 2010-05-20 Conwed Plastics Llc Oxo-biodegradable netting
WO2010106105A2 (en) * 2009-03-20 2010-09-23 Basf Se Biodegradable material consisting of a polymer containing a porous organometallic framework
US8227653B2 (en) 2009-03-27 2012-07-24 Exxonmobil Chemical Patents Inc. Olefin oligomerization reaction processes exhibiting reduced fouling
US8153544B2 (en) 2009-07-22 2012-04-10 Equistar Chemicals, Lp Method for preparing non-metallocene catalysts
US8158733B2 (en) 2009-07-22 2012-04-17 Equistar Chemicals, Lp Catalysts based on 2-(2-aryloxy)quinoline or 2-(2-aryloxy)dihydroquinoline ligands
US7858718B1 (en) 2009-07-22 2010-12-28 Equistar Chemicals, Lp Catalysts based on 2-aryl-8-anilinoquinoline ligands
CA2688217C (en) * 2009-12-11 2016-07-12 Nova Chemicals Corporation Multi reactor process
EP2526129B1 (en) * 2010-01-21 2017-09-27 Saudi Basic Industries Corporation (Sabic) Ethylene polymerisation process
WO2011102990A2 (en) * 2010-02-19 2011-08-25 Dow Global Technologies Llc Process for polymerizing an olefin monomer and catalyst therefor
CN101857651B (en) * 2010-06-12 2012-06-20 上海化工研究院 Preparation method of ultra-high molecular weight polyethylene catalyst with single activity site
US20120016092A1 (en) 2010-07-14 2012-01-19 Sandor Nagy Catalysts based on quinoline precursors
US20130202860A1 (en) 2010-08-18 2013-08-08 Huanyu Wei Chlorine-free ink and coating compositions & a method for printing on untreated polyolefin films with improved adhesion
KR101972725B1 (en) 2010-11-22 2019-04-25 더블유.알. 그레이스 앤드 캄파니-콘. Activator compositions, their preparation, and their use in catalysis
KR102064629B1 (en) 2012-04-27 2020-01-08 더블유.알. 그레이스 앤드 캄파니-콘. Activator compositions, their preparation, and their use in catalysts
RU2690857C2 (en) * 2014-09-17 2019-06-06 ВЕРСАЛИС С.п.А. Pyridine complex of zirconium, a catalyst system containing said pyridine complex of zirconium, and a method for (co)polymerisation of conjugated dienes
CA2864573C (en) 2014-09-22 2021-07-06 Nova Chemicals Corporation Shrink film from single site catalyzed polyethylene
CN107001504B (en) 2014-11-25 2020-07-17 尤尼威蒂恩技术有限责任公司 Method for controlling melt index of polyolefin
CA2874895C (en) 2014-12-16 2022-02-15 Nova Chemicals Corporation High modulus single-site lldpe
KR101931234B1 (en) 2016-02-12 2018-12-21 주식회사 엘지화학 Novel ligand compound and transition metal compound
WO2017138783A1 (en) * 2016-02-12 2017-08-17 주식회사 엘지화학 Novel ligand compound and transition metal compound
CN112646065B (en) * 2019-10-11 2022-11-18 中国石油化工股份有限公司 Novel single metallocene transition metal compound, catalyst composition containing same and application
CN111747995B (en) * 2020-07-30 2023-02-21 上海化工研究院有限公司 Nitrogen-containing aryloxy cyclopentadienyl titanium compound and preparation method and application thereof
EP4330294A1 (en) 2021-04-30 2024-03-06 ExxonMobil Chemical Patents Inc. Processes for transitioning between different polymerization catalysts in a polymerization reactor
CN116410224B (en) * 2023-06-05 2023-11-10 研峰科技(北京)有限公司 Synthesis process of cyclopentadiene titanium trichloride

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3900452A (en) * 1963-06-07 1975-08-19 Montedison Spa Olefinic copolymers and process for the preparation thereof
WO1991010634A1 (en) * 1990-01-16 1991-07-25 Texas A&M University System Nitrogen-containing aromatic heterocyclic ligand-metal complexes and their use for the activation of hydrogen peroxide and dioxygen in the reaction of organic compounds

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5637660A (en) * 1995-04-17 1997-06-10 Lyondell Petrochemical Company Polymerization of α-olefins with transition metal catalysts based on bidentate ligands containing pyridine or quinoline moiety
US5852146A (en) * 1996-06-27 1998-12-22 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3900452A (en) * 1963-06-07 1975-08-19 Montedison Spa Olefinic copolymers and process for the preparation thereof
WO1991010634A1 (en) * 1990-01-16 1991-07-25 Texas A&M University System Nitrogen-containing aromatic heterocyclic ligand-metal complexes and their use for the activation of hydrogen peroxide and dioxygen in the reaction of organic compounds

Also Published As

Publication number Publication date
EP0832089A2 (en) 1998-04-01
DE69635719T2 (en) 2006-09-28
BR9608224A (en) 1999-11-30
CN1188481A (en) 1998-07-22
MX9707982A (en) 1998-02-28
JPH11503785A (en) 1999-03-30
RU2169735C2 (en) 2001-06-27
EP1059310A3 (en) 2004-08-04
US5637660A (en) 1997-06-10
KR19990007920A (en) 1999-01-25
CN1068331C (en) 2001-07-11
ES2255914T3 (en) 2006-07-16
EP0832089B1 (en) 2001-09-26
US6790918B2 (en) 2004-09-14
DE69615554T2 (en) 2002-05-08
US6759493B1 (en) 2004-07-06
ES2164878T3 (en) 2002-03-01
EP1059310B1 (en) 2006-01-11
AU5314496A (en) 1996-11-07
DE69635719D1 (en) 2006-04-06
WO1996033202A2 (en) 1996-10-24
DE69615554D1 (en) 2001-10-31
US20040097670A1 (en) 2004-05-20
EP1059310A2 (en) 2000-12-13

Similar Documents

Publication Publication Date Title
WO1996033202A3 (en) Transition metal catalyst based on bidentate ligands containing pyridine or quinoline moiety
MX9708182A (en) Azaborolinyl metal complexes as olefin polymerization catalysts.
EP0748822B1 (en) Catalyst component useful for the polymerization of olefins
EP0528041A4 (en) Novel transition metal compound and process for polymerizing olefin by using the same
KR970042568A (en) Process for preparing cycloolefin copolymer
WO1996023004A3 (en) Borabenzene based olefin polymerization catalysts
CA2055218A1 (en) Metallocenes containing ligands of 2-substituted indenyl derivatives, process for their preparation, and their use as catalysts
MY132919A (en) Metallocenes and catalysts for the polymerization of olefins containing them
CA2084017A1 (en) Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts
AU1713492A (en) Process for the preparation of syndiotactic polyolefins having a broad molecular weight distribution
CA2099214A1 (en) Metallocenes containing aryl-substituted indenyl derivatives as ligands, process for their preparation, and their use as catalysts
CA2204803A1 (en) Process to prepare bridged phosphole-cyclopentadienyl compounds
EP0872492A3 (en) Transition metal compound as catalyst component for polymerization, aromatic vinyl compound-olefin copolymer having stereoregularity and method for its preparation by means of the transition metal compound as catalyst component
US6084043A (en) Catalyst component for polymerization of alpha-olefins and process for producing alpha-olefin polymers using the same
CA2222917A1 (en) Metallocenes, their preparation and use in the polymerization of alpha-olefins
CA2103379A1 (en) Catalyst for olefin polymerization, process for olefin polymerization using the same, ethylene/.alpha.-olefin copolymer, graft modified ethylene/.alpha.-olefin copolymer, and ethylene copolymer composition
CA2071706A1 (en) Catalyst for Olefin Polymerization, Process for the Polymerization of Olefin, and Transition Metal Compound Employable for the Catalyst
GB9715317D0 (en) Polymerisation catalysts
CA2158710A1 (en) Olefin Polymerization Catalyst and Process for Olefin Polymerization
CA2192156A1 (en) Catalyst and process for producing conjugated diene polymer
AU3199693A (en) Catalyst and process for the polymerization and copolymerization of olefins
KR880009056A (en) Styrene-based copolymer and method for producing
ATE199093T1 (en) METHOD FOR PRODUCING OLEFIN POLYMERS USING METALLOCE CATALYST
CA2218638A1 (en) Polymerization of alpha-olefins with transition metal catalysts based on bidentate ligands containing pyridine or quinoline moiety
DK0791607T3 (en) Substituted metallocene catalyst for (co) polymerization of olefins

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 96194004.2

Country of ref document: CN

AK Designated states

Kind code of ref document: A2

Designated state(s): AL AM AU AZ BB BG BR BY CA CN CZ EE GE HU IS JP KG KP KR KZ LK LR LT LV MD MG MK MN MX NZ PL RO RU SG SI SK TJ TM TR TT UA UZ VN

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): KE LS MW SD SZ UG AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN ML MR NE SN TD TG

AK Designated states

Kind code of ref document: A3

Designated state(s): AL AM AU AZ BB BG BR BY CA CN CZ EE GE HU IS JP KG KP KR KZ LK LR LT LV MD MG MK MN MX NZ PL RO RU SG SI SK TJ TM TR TT UA UZ VN

AL Designated countries for regional patents

Kind code of ref document: A3

Designated state(s): KE LS MW SD SZ UG AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN ML MR NE SN TD TG

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
ENP Entry into the national phase

Ref document number: 2218638

Country of ref document: CA

Ref document number: 2218638

Country of ref document: CA

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 1996909748

Country of ref document: EP

ENP Entry into the national phase

Ref document number: 1996 531730

Country of ref document: JP

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 1019970707443

Country of ref document: KR

WWP Wipo information: published in national office

Ref document number: 1996909748

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 1019970707443

Country of ref document: KR

WWG Wipo information: grant in national office

Ref document number: 1996909748

Country of ref document: EP

WWR Wipo information: refused in national office

Ref document number: 1019970707443

Country of ref document: KR