WO1996039717A1 - Reduced leakage antifuse structure and fabrication method - Google Patents

Reduced leakage antifuse structure and fabrication method Download PDF

Info

Publication number
WO1996039717A1
WO1996039717A1 PCT/US1996/009235 US9609235W WO9639717A1 WO 1996039717 A1 WO1996039717 A1 WO 1996039717A1 US 9609235 W US9609235 W US 9609235W WO 9639717 A1 WO9639717 A1 WO 9639717A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
silicon
antifuse
conductive electrode
disposed
Prior art date
Application number
PCT/US1996/009235
Other languages
French (fr)
Inventor
John L. Mccollum
Frank W. Hawley
Original Assignee
Actel Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Actel Corporation filed Critical Actel Corporation
Priority to EP96918237A priority Critical patent/EP0774163B1/en
Priority to JP9501608A priority patent/JP3051454B2/en
Priority to DE69617169T priority patent/DE69617169T2/en
Priority to KR1019970700794A priority patent/KR100230158B1/en
Publication of WO1996039717A1 publication Critical patent/WO1996039717A1/en

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/77Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
    • H01L21/78Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
    • H01L21/82Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/52Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
    • H01L23/522Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
    • H01L23/525Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body with adaptable interconnections
    • H01L23/5252Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body with adaptable interconnections comprising anti-fuses, i.e. connections having their state changed from non-conductive to conductive
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/0001Technical content checked by a classifier
    • H01L2924/0002Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/30Technical effects
    • H01L2924/301Electrical effects
    • H01L2924/3011Impedance

Definitions

  • the present invention relates to antifuses. More particularly, the present invention relates to an improved metal-to-metal amorphous silicon antifuse structure and fabrication method.
  • a common problem with amoiphous silicon antifuses is the high level of leakage exhibited by unprogrammed antifuses. This leakage is typically a few nanoamperes at an applied voltage of 5 volts. In isolation, such leakage exhibited by a single antifuse might be considered to be insignificant. The problem becomes apparent, however, when practical antifuse based products are considered. Large FPGA integrated circuits may employ more than one million antifuses having an aggregate leakage of a few milliamperes. This leakage rapidly worsens with temperatures, especially high temperatures of 70 to 125°C which may be encountered in FPGA arrays under normal operating conditions.
  • silicon nitride-amorphous silicon-silicon nitride antifuse material does not significantly reduce this leakage. There is thus a need for an antifuse structure which avoids this problem.
  • An antifuse according to the present invention comprises an antifuse material disposed between a lower conductive electtode and an upper conductive electrode.
  • the antifuse material comprises a layer of amorphous silicon disposed between two layers of silicon nitride.
  • a thin layer of silicon dioxide i.e., from about 1 to about 300 angstroms, preferably about 30 angstroms is disposed between the layer of amorphous silicon and one of the silicon nitride layers.
  • the thin layer of silicon dioxide is disposed between the layer of amoiphous silicon and d e lower silicon nitride layer.
  • the thin layer of silicon dioxide is disposed between the layer of amoiphous silicon and the upper silicon nitride layer.
  • the antifuse of the first embodiment of the invention exhibits a higher BVG in a direction where the positive Vpp potential is applied to the lower electrode.
  • the antifuse of the second embodiment of the invention exhibits a higher BVG in a direction where the positive Vpp potential is applied to the upper electrode.
  • the amount of the difference in BVG in both cases is about 0.5 to 3 volts, typically about 2 volts.
  • the antifuse of the present invention exhibits leakage in its unprogrammed state of about a few to tens of picoamperes at 5 volts. This is lower than the leakage of prior ait antifuses by a factor of about 100.
  • FIG. 1 is a cross sectional view of an antifuse according to a first embodiment of the present invention.
  • FIG. 2 is a cross sectional view of an antifuse according to a second embodiment of the present invention.
  • FIGS. 3a-3e are cross sectional views of an antifuse having an antifuse material structure like that of FIG. 1 after completion of selected steps in the fabrication process.
  • FIGS. 4a-4d are cross sectional views of an antifuse having an antifuse material structure like that of FIG. 2 after completion of selected steps in the fabrication process.
  • FIGS. 1 and 2 two embodiments of antifuses according to the present invention are shown in cross-sectional view. Those of ordinary skill in the art will understand that FIGS.
  • 1 and 2 merely show the relative positions of the various layers which comprises the antifuses depicted therein, and that various antifuse geometries may be employed in practicing the present invention, such as ones in which the lower electrode and antifuse material are disposed below the interlayer dielectric containing the aperture, ones in which the layers comprising the antifuse material are disposed in the antifuse aperture in the interlayer dielectric, ones, in which the layers comprising the antifuse material are located above a plug in the antifuse aperture, and ones employing combinations of these concepts.
  • an antifuse 10 according to the first embodiment of the present invention is shown in cross-sectional view.
  • Antifuse 10 is fabricated over a substrate 12.
  • substrate 12 may comprise an insulating layer disposed over a semiconductor substrate containing active devices or over a conducting substrate, or substrate 12 may itself be a substrate formed from an insulating material.
  • a lower conductive electrode 14 for antifuse 10 is disposed over the upper surface of substrate 12 and may be formed from materials such as titanium nitride/aluminum.
  • lower conductive electrode 14 is defined from a portion of a metal interconnect layer in an integrated circuit and persons of ordinary skill in the art will readily appreciate that lower conductive electrode 14 may be formed from any of the known materials used for such purposes.
  • Such layers have thicknesses typically in the range of from about 5,000 angstroms to about 12,000 angstroms, typically about 9.000 angstroms.
  • a first silicon nitride layer 16 is disposed on the upper surface of lower conductive electrode 14.
  • First silicon nitride layer 16 may typically have a thickness in the range of from about 1 angstrom to about 300 angstroms, preferably about 65 angstroms.
  • a thin layer of silicon dioxide 18 i.e., from about 1 to about 300 angstroms, preferably about 30 angstroms) is disposed on the upper surface of first silicon nitride layer 16.
  • Amorphous silicon layer 20 may be undoped or may be doped to a concentration of less than lei 8 using phosphorus, arsenic, nitrogen, or oxygen as a dopant species.
  • a second silicon nitride layer 22 is disposed on the upper surface of amorphous silicon layer 20. Second silicon nitride layer 22 may typically have a thickness in the range of from about 1 angstrom to about 300 angstroms, preferably about 65 angstroms. Together, layers 16, 18, 20, and 22 comprise a composite antifuse material 24.
  • the final element of antifuse 10 of FIG. 1 is an upper conductive elecUOde 26 disposed over the upper surface of second silicon nitride layer 22.
  • upper conductive electrode 26 may comprise a portion of a metal interconnect layer and may be formed from materials known for use for this memepose.
  • both lower conductive electrode 14 and upper conductive electrode 26 may include a barrier layer (not shown in FIG. l).
  • barrier layer not shown in FIG. l.
  • FIG. 2 A second embodiment of an antifuse according to the present invention is depicted in cross- sectional view in FIG. 2.
  • Antifuse 30 of FIG. 2 is similar to antifuse 10 of FIG. 1 except for the location of the thin oxide layer 1 .
  • elements of antifuse 30 which are present in antifuse 10 will be designated by the same reference numerals as their counterparts in FIG. 1.
  • Persons of ordinary skill in the art will appreciate that the various layers in antifuse 30 of FIG. 2 may comprise the same materials as the corresponding layers in the antifuse 10 of FIG. 1. and may have the same or similar thicknesses.
  • antifuse 30 is also fabricated over substrate 12.
  • a lower conductive electrode 14 for antifuse 30 is formed on the upper surface of substrate 12.
  • lower conductive electrode 14 is defined is usually defined from a portion of a metal interconnect layer in an integrated circuit.
  • a first silicon nitride layer 16 is disposed on the upper surface of lower conductive electrode 14. So far, the antifuse 30 of FIG. 2 is identical to the antifuse 10 of FIG. 1.
  • a layer of amoiphous silicon 20 is disposed on the upper surface of first silicon nitride layer 16 in the antifuse 30 of FIG. 2.
  • Amorphous silicon layer 20 may be undoped or may be doped to a concentration of less than lei 8 using phosphorus, arsenic, nitrogen, or oxygen as a dopant species.
  • a thin layer of silicon dioxide 18 (i.e., from about 1 to about 300 angstroms, preferably about 30 angstroms) is disposed on the upper surface of amoiphous silicon layer 20.
  • a second silicon nitride layer 22 is disposed on the upper surface of the thin layer of silicon dioxide 18.
  • the final element of antifuse 30 of FIG. 2 is an upper conductive electrode 26 disposed over the upper surface of second silicon nitride layer 22.
  • upper conductive electrode 26 may comprise a portion of a metal interconnect layer and may be formed from materials known for use for this memepose.
  • both lower conductive electrode 14 and upper conductive electrode 26 in antifuse 30 of FIG. 2 may include a barrier layer (not shown in FIG. 2).
  • Layers 16, 18, 20, and 22 together form the antifuse material 24 of antifuses 10 and 30 of FIGS. 1 and 2, respectively.
  • the combined thicknesses of its constituent layers will determine the voltage at which antifuses 10 and 30 will program, i.e., change from a high-impedance to a low-impedance state.
  • first silicon nitride layer 16 having a thickness of about 65 angstroms
  • a thin layer of silicon dioxide 18 having a thickness of about 30 angstroms
  • a layer of amoiphous silicon 20 having a thickness of about 450 angstroms
  • a second silicon nitride layer 22 having a thickness of about 65 angstroms will exhibit a programming voltage of about 12 volts if the positive potential is applied to the lower conductive electrode 14 and about 10.5 volts if the positive potential is applied to the upper conductive electrode 26 .
  • the antifuse of FIG. 2 is fabricated using the above-recited layer thicknesses, it will exhibit a programming voltage of about 12 volts if the positive potential is applied to the upper conductive electrode 26 and about 10.5 volts if the positive potential is applied to the lower conductive electrode 14.
  • antifuses 10 and 30 configured according to the present invention, the reduction in leakage is affected in both directions, whereas the BVG is only affected in one direction. Thus it is possible to adjust which direction of current flow has a lower breakdown voltage.
  • This non-symmetrical programming voltage feature of the present invention is the ability to avoid unintentional programming of antifuses in an array by spurious programming paths which place reverse polarity programming voltages across them.
  • the composite antifuse material 24 described above may be disposed in an antifuse aperture formed in an interlayer dielectric layer, or may be formed entirely or partly above or below such an aperture if conductive plug technology or similar technology is used. Any particular antifuse geometry using the antifuses according to the present invention thus falls within the scope of the present invention.
  • the steps for forming an interlayer dielectric, forming an aperture therein, and plug formation will precede die steps used to form the multilayer composite antifuse material 24.
  • the steps used to form the multilayer composite antifuse material 24 will be performed prior to the steps for forming an interlayer dielectric, forming an aperture therein and forming the upper antifuse electrode.
  • the thin layer of oxide In any process for fabricating the antifuses of the present invention, the thin layer of oxide
  • the oxide layer 1 is formed by plasma oxidation in O 2 .
  • This process can be performed in equipment commonly used to remove photoresist. As will be appreciated by those of ordinary skill in the art, this process may also be performed in situ during the nitride and silicon depositions in the same piece of equipment, thereby simplifying the antifuse fabrication process.
  • FIGS. 3a-3e cross sectional views of two alternative versions of an antifuse according to the first embodiment of the invention are presented showing the structure resulting after performance of selected steps in the fabrication process.
  • the particular antifuse geometry depicted in FIGS. 3a-3e is that of a plug antifuse, but persons of ordinary skill in the art will understand that the concepts of the present invention are not limited to the particular antifuse geometry depicted in the figures. In fact, such skilled persons will understand that the present invention may be employed in virtually any form of antifuse, such as ones in which the composite antifuse material is formed within a via formed in an interlayer dielectric material, or wholly or partially above or below such a via.
  • a lower conductive electrode 14 has been formed on the upper surface of substrate 12, which will usually, but not necessarily, comprise an insulating layer disposed above other layers in a microcircuit.
  • Lower conductive electrode 14 is most often a portion of a metal interconnect layer in an integrated circuit and will thus be formed from materials employed in such layers using standard processing techniques, but those of ordinary skill in the art will recognize that many other conductive materials could be used instead.
  • Interlayer dielectric layer 32 is formed over the upper surface of lower conductive electrode 14.
  • Interlayer dielectric layer 32 is typically formed from a material such as CVD silicon dioxide typically ranging in thickness from about 5,000 angstroms to 15,(X)() angstroms, usually about 9,000 angstroms.
  • a conventional masking and etching sequence is next employed to form an antifuse aperture 34 communicating with the upper surface of lower electrode 14 through interlayer dielectric layer 32.
  • a conductive plug 36 comprising a material such as tungsten, is formed in antifuse aperture 34 using techniques such as blanket deposition followed by an etching step to planarize the top of the conductive plug 36 and the upper surface of the interlayer dielectric layer 32.
  • Tungsten plug technology is well known in the art.
  • FIG. 3a shows the structure resulting after performance of the aforementioned steps.
  • composite antifuse material layer 24 is formed.
  • a first layer of silicon nitride 16 is formed to a thickness of between about 1 angstrom and about 300 angstroms, typically about 65 angstroms, using CVD techniques.
  • a thin layer of silicon dioxide 1 having a thickness of between about 1 to 300 angstroms, preferably about 30 angstroms, is formed over the upper surface of silicon nitride layer 16, preferably using CVD techniques.
  • a layer of amoiphous silicon 20 is then formed over the silicon dioxide layer 18 to a thickness of between about 100 angstroms and about 1,500 angstroms, typically about 450 angstroms, using CVD techniques.
  • the amoiphous silicon layer 20 may be undoped or may be doped to a level of preferably less than about lei 8 using phosphorous, arsenic, nitrogen, or oxygen.
  • a second silicon nitride layer 22 having a thickness of between about 1 angstrom and about 300 angstroms, typically about 65 angstroms, is next formed over the surface of the amoiphous silicon layer 20 using CVD techniques.
  • banier layer 28 not only serves to act to prevent interdiffusion of the metal electrode material into the antifuse material, but also functions as an etch stop for the etching of the antifuse stack to be performed in the next process step.
  • FIG. 3b shows the structure resulting after performance of the stack etching step but prior to removal of masking layer 38.
  • the masking layer 38 is then removed and an oxide spacer 40 is formed around the edge of the stacked structure.
  • the spacer 40 may be formed by a blanket deposition of silicon dioxide (i.e., about 3.000 angstroms) followed by a plasma etching step.
  • spacer 40 improves the step coverage of the layers overlying the stack in the completed antifuse and also prevents diffusion of atoms from the upper electrode into the composite antifuse material 24.
  • FIG. 3c shows the structure resulting after completion of the spacer etching step.
  • the upper conductive electrode 26 is formed over the stacked structure, the oxide spacers 40, and the interlayer dielectric 32.
  • upper conductive electrode 26 may be formed from a portion of an interconnect metal layer in an integrated circuit and fabrication of this layer is well known to such skilled persons. Additional conventional back-end steps (not shown) are then used to passivate and otherwise complete the integrated circuit structure.
  • the banier layer 28 may be formed after performance of the stack etch step and removal of photoresist layer 38, and would thus serve to encapsulate the stacked antifuse structure 24.
  • the upper conductive electrode 26 would then be formed over the banier layer 28 and the two would be defined using conventional masking and etching steps.
  • FIG. 3e a cross-sectional view of the antifuse shown after completion of the steps to form the blanket barrier layer 28 and the overlying upper conductive electrode 26.
  • the banier layer 28 in the embodiment shown in FIG. 3e has step coverage adequate to eliminate the spacers 40 and also performs the function of preventing diffusion of metal atoms into the composite antifuse material 24.
  • the design choice of whedier the spacers or blanket banier layer are to be used will largely depend on the capabilities of the wafer fabrication facility in which the integrated circuits will be manufactured.
  • FIGS. 3a and 4a-4d cross sectional views of two variations of an antifuse according to the second embodiment of the invention (FIG. 2) are presented showing the structure resulting after performance of selected steps in the fabrication process.
  • the antifuse geometry depicted in FIGS. 3a and 4a-4d is a plug antifuse, but persons of ordinary skill in the art will understand that the present invention is not limited to this particular antifuse geometry.
  • the details of the fabrication steps relating to materials, formation and etching processes, thicknesses, etc. are the same as those recited for the fabrication of the antifuse shown in FIG. 1 and will not be needlessly repeated.
  • the fabrication of a plug-type antifuse having a composite antifuse material structure like that shown in FIG. 2 starts out utilizing the same steps which would be used to fabricate a plug-type antifuse having a composite antifuse material structure shown in FIG. 1.
  • the lower conductive electrode 14 has been formed on the upper surface of substrate 12.
  • the interlayer dielectric layer 32 is formed over the upper surface of lower conductive electrode 14, and a conventional masking and etching sequence is next employed to form an antifuse aperture 34 communicating with the upper surface of lower electrode 14 through interlayer dielectric layer 32.
  • a conductive plug 36 comprising a material such as tungsten, is formed in aperture 34 using techniques such as blanket deposition followed by an etching step to planarize the top of the plug 36 and the upper surface of the interlayer dielectric layer 32.
  • Tungsten plug technology is well known in the art.
  • FIG. 3a shows the structure resulting after performance of the aforementioned steps.
  • a first layer of silicon nitride 16 is formed.
  • a layer of amoiphous silicon 20 is then formed over the first silicon nitride layer 16.
  • a thin layer of silicon dioxide 18 is formed over the upper surface of amorphous silicon layer 20.
  • a second silicon nitride layer 22 is next formed over the surface of the thin silicon dioxide layer 18.
  • barrier layer 28 formed from a material such as titanium nitride, is formed over the surface of second silicon nitride layer 22.
  • FIG. 4a shows the structure resulting after performance of the stack etching step but prior to removal of masking layer 38.
  • FIG. 4b shows the structure resulting after completion of the spacer etching step.
  • the upper conductive electrode 26 is formed over the stacked structure, the oxide spacers 40, and the interlayer dielectric layer 32.
  • additional conventional back-end steps (not shown) are then used to passivate and otherwise complete the integrated circuit structure.
  • the spacers may be eliminated in favor of a blanket banier layer deposition step after removal of the photomask 38.
  • FIG. 4d is a cross-sectional view of an antifuse according to a variation of the present invention wherein a blanket banier layer 28, formed from a material such as titanium nitride, is formed after removal of masking layer 38. An upper conductive electrode 26 is then formed over the upper surface of banier layer 28.
  • FIG. 4d shows the structure resulting after completion of these steps and prior to conventional back-end processing steps used to complete the integrated circuit.

Abstract

An antifuse (10) comprises an antifuse material (24) disposed between a lower conductive electrode (14) and an upper conductive electrode (26). The antifuse material (24) comprises a layer of amorphous silicon (20) disposed between two layers of silicon nitride (16, 20). A thin layer of silicon dioxide (18) is disposed between the layer of amorphous silicon (20) and one of the silicon nitride layers (16, 22).

Description

S P E C I F I C A T I O N
REDUCED LEAKAGE ANTIFUSE STRUCTURE AND FABRICATION METHOD
BACKGROUND OF THE INVENTION
1. Field Of The Invention
The present invention relates to antifuses. More particularly, the present invention relates to an improved metal-to-metal amorphous silicon antifuse structure and fabrication method.
2. The Prior Art A common problem with amoiphous silicon antifuses is the high level of leakage exhibited by unprogrammed antifuses. This leakage is typically a few nanoamperes at an applied voltage of 5 volts. In isolation, such leakage exhibited by a single antifuse might be considered to be insignificant. The problem becomes apparent, however, when practical antifuse based products are considered. Large FPGA integrated circuits may employ more than one million antifuses having an aggregate leakage of a few milliamperes. This leakage rapidly worsens with temperatures, especially high temperatures of 70 to 125°C which may be encountered in FPGA arrays under normal operating conditions.
The addition of one or more layers of silicon nitride to the antifuse layer (typically silicon nitride-amorphous silicon-silicon nitride antifuse material) does not significantly reduce this leakage. There is thus a need for an antifuse structure which avoids this problem.
In addition, a problem in antifuse arrays has been the unintended programming of antifuses during the process of programming intended antifuses. An antifuse structure which would aid in preventing the unintended programming of antifuses while substantially reducing the leakage of unprogrammed antifuses would also be desirable.
It is therefore an object of the present invention to provide an antifuse having reduced leakage in its unprogrammed state.
It is a further object of the present invention to provide an antifuse which may be disposed in an array of antifuses and which is less susceptible to unintentional programming than prior art antifuses. BRIEF DESCRIPTION OF THE INVENTION An antifuse according to the present invention comprises an antifuse material disposed between a lower conductive electtode and an upper conductive electrode. The antifuse material comprises a layer of amorphous silicon disposed between two layers of silicon nitride. A thin layer of silicon dioxide (i.e., from about 1 to about 300 angstroms, preferably about 30 angstroms) is disposed between the layer of amorphous silicon and one of the silicon nitride layers.
In a first embodiment of the present invention, the thin layer of silicon dioxide is disposed between the layer of amoiphous silicon and d e lower silicon nitride layer. In a second embodiment of the present invention, the thin layer of silicon dioxide is disposed between the layer of amoiphous silicon and the upper silicon nitride layer. The antifuse of the first embodiment of the invention exhibits a higher BVG in a direction where the positive Vpp potential is applied to the lower electrode. The antifuse of the second embodiment of the invention exhibits a higher BVG in a direction where the positive Vpp potential is applied to the upper electrode. The amount of the difference in BVG in both cases is about 0.5 to 3 volts, typically about 2 volts.
It has been determined by the inventors that the antifuse of the present invention exhibits leakage in its unprogrammed state of about a few to tens of picoamperes at 5 volts. This is lower than the leakage of prior ait antifuses by a factor of about 100.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a cross sectional view of an antifuse according to a first embodiment of the present invention.
FIG. 2 is a cross sectional view of an antifuse according to a second embodiment of the present invention.
FIGS. 3a-3e are cross sectional views of an antifuse having an antifuse material structure like that of FIG. 1 after completion of selected steps in the fabrication process.
FIGS. 4a-4d are cross sectional views of an antifuse having an antifuse material structure like that of FIG. 2 after completion of selected steps in the fabrication process.
DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT Those of ordinary skill in the art will realize that the following description of the present invention is illustrative only and not in any way limiting. Other embodiments of the invention will readily suggest themselves to such skilled persons. Referring first to FIGS. 1 and 2, two embodiments of antifuses according to the present invention are shown in cross-sectional view. Those of ordinary skill in the art will understand that FIGS. 1 and 2 merely show the relative positions of the various layers which comprises the antifuses depicted therein, and that various antifuse geometries may be employed in practicing the present invention, such as ones in which the lower electrode and antifuse material are disposed below the interlayer dielectric containing the aperture, ones in which the layers comprising the antifuse material are disposed in the antifuse aperture in the interlayer dielectric, ones, in which the layers comprising the antifuse material are located above a plug in the antifuse aperture, and ones employing combinations of these concepts.
Referring first to FIG. 1, an antifuse 10 according to the first embodiment of the present invention is shown in cross-sectional view. Antifuse 10 is fabricated over a substrate 12. Those of ordinary skill in the art will recognize that substrate 12 may comprise an insulating layer disposed over a semiconductor substrate containing active devices or over a conducting substrate, or substrate 12 may itself be a substrate formed from an insulating material.
A lower conductive electrode 14 for antifuse 10 is disposed over the upper surface of substrate 12 and may be formed from materials such as titanium nitride/aluminum. Usually, although not necessarily, lower conductive electrode 14 is defined from a portion of a metal interconnect layer in an integrated circuit and persons of ordinary skill in the art will readily appreciate that lower conductive electrode 14 may be formed from any of the known materials used for such purposes. Such layers have thicknesses typically in the range of from about 5,000 angstroms to about 12,000 angstroms, typically about 9.000 angstroms.
A first silicon nitride layer 16 is disposed on the upper surface of lower conductive electrode 14. First silicon nitride layer 16 may typically have a thickness in the range of from about 1 angstrom to about 300 angstroms, preferably about 65 angstroms. A thin layer of silicon dioxide 18 (i.e., from about 1 to about 300 angstroms, preferably about 30 angstroms) is disposed on the upper surface of first silicon nitride layer 16. A layer of amoiphous silicon 20, having a thickness of between about 100 angstroms to about 1,500 angstroms, typically about 450 angstroms, is disposed on the upper surface of silicon dioxide layer 18. Amorphous silicon layer 20 may be undoped or may be doped to a concentration of less than lei 8 using phosphorus, arsenic, nitrogen, or oxygen as a dopant species. A second silicon nitride layer 22 is disposed on the upper surface of amorphous silicon layer 20. Second silicon nitride layer 22 may typically have a thickness in the range of from about 1 angstrom to about 300 angstroms, preferably about 65 angstroms. Together, layers 16, 18, 20, and 22 comprise a composite antifuse material 24. The final element of antifuse 10 of FIG. 1 is an upper conductive elecUOde 26 disposed over the upper surface of second silicon nitride layer 22. As with the lower conductive electrode 14, upper conductive electrode 26 may comprise a portion of a metal interconnect layer and may be formed from materials known for use for this puipose. As will be appreciated by those of ordinary skill in the art, both lower conductive electrode 14 and upper conductive electrode 26 may include a barrier layer (not shown in FIG. l).Those of ordinary skill in the art will appreciate that other layers, such as passivation, will be employed in the fabrication of actual devices containing the antifuse of the present invention. Such layers, their puipose and formation processes are well known in the an and will not be described herein in order to avoid overcomplicating the disclosure and thus obscuring the disclosure of the present invention.
A second embodiment of an antifuse according to the present invention is depicted in cross- sectional view in FIG. 2. Antifuse 30 of FIG. 2 is similar to antifuse 10 of FIG. 1 except for the location of the thin oxide layer 1 . For ease of understanding of the disclosure, elements of antifuse 30 which are present in antifuse 10 will be designated by the same reference numerals as their counterparts in FIG. 1. Persons of ordinary skill in the art will appreciate that the various layers in antifuse 30 of FIG. 2 may comprise the same materials as the corresponding layers in the antifuse 10 of FIG. 1. and may have the same or similar thicknesses.
Thus, from an examination of FIG. 2, it may be seen that antifuse 30 is also fabricated over substrate 12. A lower conductive electrode 14 for antifuse 30 is formed on the upper surface of substrate 12. As in the embodiment of FIG. 1, lower conductive electrode 14 is defined is usually defined from a portion of a metal interconnect layer in an integrated circuit.
A first silicon nitride layer 16 is disposed on the upper surface of lower conductive electrode 14. So far, the antifuse 30 of FIG. 2 is identical to the antifuse 10 of FIG. 1.
It is at this point in the structure that the antifuses of FIGS. 1 and 2 differ. Unlike the antifuse 10 of FIG. 1. a layer of amoiphous silicon 20 is disposed on the upper surface of first silicon nitride layer 16 in the antifuse 30 of FIG. 2. Amorphous silicon layer 20 may be undoped or may be doped to a concentration of less than lei 8 using phosphorus, arsenic, nitrogen, or oxygen as a dopant species.
A thin layer of silicon dioxide 18 (i.e., from about 1 to about 300 angstroms, preferably about 30 angstroms) is disposed on the upper surface of amoiphous silicon layer 20. A second silicon nitride layer 22 is disposed on the upper surface of the thin layer of silicon dioxide 18.
The final element of antifuse 30 of FIG. 2 is an upper conductive electrode 26 disposed over the upper surface of second silicon nitride layer 22. As with the lower conductive electtode 14, upper conductive electrode 26 may comprise a portion of a metal interconnect layer and may be formed from materials known for use for this puipose. As in the antifuse of FIG. 1, both lower conductive electrode 14 and upper conductive electrode 26 in antifuse 30 of FIG. 2 may include a barrier layer (not shown in FIG. 2).
As in the antifuse 10 of FIG. 1, those of ordinary skill in the art will appreciate that other layers, such as passivation, will be employed in the fabrication of actual devices containing the antifuse 30 of the present invention depicted in FIG. 2. Such layers, their puipose and formation processes are well known in the art and will not be described herein in order to avoid overcomplicating the disclosure and thus obscuring the disclosure of the present invention.
Layers 16, 18, 20, and 22 together form the antifuse material 24 of antifuses 10 and 30 of FIGS. 1 and 2, respectively. The combined thicknesses of its constituent layers will determine the voltage at which antifuses 10 and 30 will program, i.e., change from a high-impedance to a low-impedance state. As an example, an antifuse 10 of FIG. 1 according to the present invention including a first silicon nitride layer 16 having a thickness of about 65 angstroms, a thin layer of silicon dioxide 18 having a thickness of about 30 angstroms, a layer of amoiphous silicon 20, having a thickness of about 450 angstroms, and a second silicon nitride layer 22 having a thickness of about 65 angstroms will exhibit a programming voltage of about 12 volts if the positive potential is applied to the lower conductive electrode 14 and about 10.5 volts if the positive potential is applied to the upper conductive electrode 26 . If the antifuse of FIG. 2 is fabricated using the above-recited layer thicknesses, it will exhibit a programming voltage of about 12 volts if the positive potential is applied to the upper conductive electrode 26 and about 10.5 volts if the positive potential is applied to the lower conductive electrode 14.
The addition of the thin layer of silicon dioxide 1 between one of the silicon nitride layers 16 and 22 and amorphous silicon layer 20 in both antifuses 10 of FIG. 1 and 30 of FIG. 2 dramatically reduces the leakage of antifuses 10 and 30 by a factor of about 100. This remarkable reduction in leakage is believed to be due to the fact that nitride is a hole conductor and oxide is an electron conductor. This causes the nitride to support a much larger voltage at a reduced leakage as the conduction is limited to electrons.
In antifuses 10 and 30 configured according to the present invention, the reduction in leakage is affected in both directions, whereas the BVG is only affected in one direction. Thus it is possible to adjust which direction of current flow has a lower breakdown voltage. Herein lies the practical reason for the difference between antifuse 10 of FIG. 1 and antifuse 30 of FIG. 2. By choosing to place the oxide 18 between the first silicon nitride layer 16 and the amorphous silicon layer 20 or between the amorphous silicon layer 20 and the second silicon nitride layer 22, programming yield can be improved by reducing the chances of programming antifuses that should not be programmed but are nevertheless stressed at large voltages during programming.
The advantage provided by this non-symmetrical programming voltage feature of the present invention is the ability to avoid unintentional programming of antifuses in an array by spurious programming paths which place reverse polarity programming voltages across them.
As previously noted, the composite antifuse material 24 described above may be disposed in an antifuse aperture formed in an interlayer dielectric layer, or may be formed entirely or partly above or below such an aperture if conductive plug technology or similar technology is used. Any particular antifuse geometry using the antifuses according to the present invention thus falls within the scope of the present invention.
Numerous processes can be used to formulate the antifuses of the present invention. The exact order of the processing steps will depend upon the particular antifuse geometry desired. For example, if plug-type antifuses are fabricated according to the teachings of the present invention, the steps for forming an interlayer dielectric, forming an aperture therein, and plug formation will precede die steps used to form the multilayer composite antifuse material 24. In other planar antifuse structures, the steps used to form the multilayer composite antifuse material 24 will be performed prior to the steps for forming an interlayer dielectric, forming an aperture therein and forming the upper antifuse electrode.
In any process for fabricating the antifuses of the present invention, the thin layer of oxide
18 in the multilayer composite antifuse material 24 can be formed using various methods including plasma oxidations, plasma depositions, other CVD methods, and thermal oxidation in an oxygen environment. According to a presently preferred embodiment of the invention, the oxide layer 1 is formed by plasma oxidation in O2. This process can be performed in equipment commonly used to remove photoresist. As will be appreciated by those of ordinary skill in the art, this process may also be performed in situ during the nitride and silicon depositions in the same piece of equipment, thereby simplifying the antifuse fabrication process.
Referring now to FIGS. 3a-3e, cross sectional views of two alternative versions of an antifuse according to the first embodiment of the invention are presented showing the structure resulting after performance of selected steps in the fabrication process. The particular antifuse geometry depicted in FIGS. 3a-3e is that of a plug antifuse, but persons of ordinary skill in the art will understand that the concepts of the present invention are not limited to the particular antifuse geometry depicted in the figures. In fact, such skilled persons will understand that the present invention may be employed in virtually any form of antifuse, such as ones in which the composite antifuse material is formed within a via formed in an interlayer dielectric material, or wholly or partially above or below such a via.
Referring initially to FIG. 3a, a lower conductive electrode 14 has been formed on the upper surface of substrate 12, which will usually, but not necessarily, comprise an insulating layer disposed above other layers in a microcircuit. Lower conductive electrode 14 is most often a portion of a metal interconnect layer in an integrated circuit and will thus be formed from materials employed in such layers using standard processing techniques, but those of ordinary skill in the art will recognize that many other conductive materials could be used instead.
An interlayer dielectric layer 32 is formed over the upper surface of lower conductive electrode 14. Interlayer dielectric layer 32 is typically formed from a material such as CVD silicon dioxide typically ranging in thickness from about 5,000 angstroms to 15,(X)() angstroms, usually about 9,000 angstroms. A conventional masking and etching sequence is next employed to form an antifuse aperture 34 communicating with the upper surface of lower electrode 14 through interlayer dielectric layer 32.
A conductive plug 36, comprising a material such as tungsten, is formed in antifuse aperture 34 using techniques such as blanket deposition followed by an etching step to planarize the top of the conductive plug 36 and the upper surface of the interlayer dielectric layer 32. Tungsten plug technology is well known in the art. FIG. 3a shows the structure resulting after performance of the aforementioned steps.
Referring now to FIG. 3b, composite antifuse material layer 24 is formed. According to a presently preferred embodiment of the invention, a first layer of silicon nitride 16 is formed to a thickness of between about 1 angstrom and about 300 angstroms, typically about 65 angstroms, using CVD techniques. Next, a thin layer of silicon dioxide 1 , having a thickness of between about 1 to 300 angstroms, preferably about 30 angstroms, is formed over the upper surface of silicon nitride layer 16, preferably using CVD techniques. A layer of amoiphous silicon 20 is then formed over the silicon dioxide layer 18 to a thickness of between about 100 angstroms and about 1,500 angstroms, typically about 450 angstroms, using CVD techniques. The amoiphous silicon layer 20 may be undoped or may be doped to a level of preferably less than about lei 8 using phosphorous, arsenic, nitrogen, or oxygen. A second silicon nitride layer 22 having a thickness of between about 1 angstrom and about 300 angstroms, typically about 65 angstroms, is next formed over the surface of the amoiphous silicon layer 20 using CVD techniques. A barrier layer 28 of titanium nitride.having a thickness of between about 500 angstroms and about 3,000 angstroms, typically about 2,000 angstroms, is next formed over the surface of the second silicon nitride layer 22. As will be understood by those of ordinary skill in the art, banier layer 28 not only serves to act to prevent interdiffusion of the metal electrode material into the antifuse material, but also functions as an etch stop for the etching of the antifuse stack to be performed in the next process step.
After completion of the stacked antifuse material structure 24, and the banier layer 28, a masking layer 38 is placed over the upper surface of barrier layer 28 and the stack is defined using a stack etching step. Several etching methods, such as RIE or plasma, may be employed to perform this step. FIG. 3b shows the structure resulting after performance of the stack etching step but prior to removal of masking layer 38.
Referring now to FIG. 3c, the masking layer 38 is then removed and an oxide spacer 40 is formed around the edge of the stacked structure. As is well known in the art, the spacer 40 may be formed by a blanket deposition of silicon dioxide (i.e., about 3.000 angstroms) followed by a plasma etching step. As will be appreciated by those of ordinary skill in the art, spacer 40 improves the step coverage of the layers overlying the stack in the completed antifuse and also prevents diffusion of atoms from the upper electrode into the composite antifuse material 24. FIG. 3c shows the structure resulting after completion of the spacer etching step.
Next, with reference to FIG. 3d, the upper conductive electrode 26 is formed over the stacked structure, the oxide spacers 40, and the interlayer dielectric 32. As will be appreciated by those of ordinary skill in the art, upper conductive electrode 26 may be formed from a portion of an interconnect metal layer in an integrated circuit and fabrication of this layer is well known to such skilled persons. Additional conventional back-end steps (not shown) are then used to passivate and otherwise complete the integrated circuit structure.
As an alternative to the use of oxide spacers 40, those of ordinary skill in the art will recognize that the banier layer 28 may be formed after performance of the stack etch step and removal of photoresist layer 38, and would thus serve to encapsulate the stacked antifuse structure 24. The upper conductive electrode 26 would then be formed over the banier layer 28 and the two would be defined using conventional masking and etching steps. Such a variation on the antifuse structure of the present invention is depicted in FIG. 3e, a cross-sectional view of the antifuse shown after completion of the steps to form the blanket barrier layer 28 and the overlying upper conductive electrode 26.
The banier layer 28 in the embodiment shown in FIG. 3e has step coverage adequate to eliminate the spacers 40 and also performs the function of preventing diffusion of metal atoms into the composite antifuse material 24. The design choice of whedier the spacers or blanket banier layer are to be used will largely depend on the capabilities of the wafer fabrication facility in which the integrated circuits will be manufactured.
Referring now to FIGS. 3a and 4a-4d, cross sectional views of two variations of an antifuse according to the second embodiment of the invention (FIG. 2) are presented showing the structure resulting after performance of selected steps in the fabrication process. As with the antifuse shown progressively fabricated in FIGS. 3a-3d, the antifuse geometry depicted in FIGS. 3a and 4a-4d is a plug antifuse, but persons of ordinary skill in the art will understand that the present invention is not limited to this particular antifuse geometry. Further, the details of the fabrication steps relating to materials, formation and etching processes, thicknesses, etc., are the same as those recited for the fabrication of the antifuse shown in FIG. 1 and will not be needlessly repeated.
Refening again to FIG. 3a, the fabrication of a plug-type antifuse having a composite antifuse material structure like that shown in FIG. 2 starts out utilizing the same steps which would be used to fabricate a plug-type antifuse having a composite antifuse material structure shown in FIG. 1. The lower conductive electrode 14 has been formed on the upper surface of substrate 12.
The interlayer dielectric layer 32 is formed over the upper surface of lower conductive electrode 14, and a conventional masking and etching sequence is next employed to form an antifuse aperture 34 communicating with the upper surface of lower electrode 14 through interlayer dielectric layer 32.
A conductive plug 36, comprising a material such as tungsten, is formed in aperture 34 using techniques such as blanket deposition followed by an etching step to planarize the top of the plug 36 and the upper surface of the interlayer dielectric layer 32. Tungsten plug technology is well known in the art. FIG. 3a shows the structure resulting after performance of the aforementioned steps.
Refening now to FIG. 4a, the difference between the fabrication of an antifuse having the composite antifuse structure shown in FIG. 1 and an antifuse having the composite antifuse structure shown in FIG. 2 may be easily seen. A first layer of silicon nitride 16 is formed. A layer of amoiphous silicon 20 is then formed over the first silicon nitride layer 16. Next, a thin layer of silicon dioxide 18 is formed over the upper surface of amorphous silicon layer 20. A second silicon nitride layer 22 is next formed over the surface of the thin silicon dioxide layer 18.
Finally, a barrier layer 28, formed from a material such as titanium nitride, is formed over the surface of second silicon nitride layer 22.
After completion of the stacked antifuse material structure 24, a masking layer 38 is placed over the upper surface of banier layer 28 and the stack is defined using an etching step. FIG. 4a shows the structure resulting after performance of the stack etching step but prior to removal of masking layer 38.
Referring now to FIG. 4b, the masking layer 38 is then removed and an oxide spacer 40 is formed around the edge of the stacked structure to improve step coverage for overlying layers and to prevent diffusion of metal atoms from the metal electrodes into the antifuse material. FIG. 4b shows the structure resulting after completion of the spacer etching step.
Next, with reference to FIG. 4c, the upper conductive electrode 26 is formed over the stacked structure, the oxide spacers 40, and the interlayer dielectric layer 32. As in the instance of the previously disclosed embodiment, additional conventional back-end steps (not shown) are then used to passivate and otherwise complete the integrated circuit structure. In addition, those skilled in the art will understand that, as was the case in the embodiment of FIG. 1, the spacers may be eliminated in favor of a blanket banier layer deposition step after removal of the photomask 38.
FIG. 4d is a cross-sectional view of an antifuse according to a variation of the present invention wherein a blanket banier layer 28, formed from a material such as titanium nitride, is formed after removal of masking layer 38. An upper conductive electrode 26 is then formed over the upper surface of banier layer 28. FIG. 4d shows the structure resulting after completion of these steps and prior to conventional back-end processing steps used to complete the integrated circuit.
While embodiments and applications of this invention have been shown and described, it would be apparent to those skilled in the art that many more modifications than mentioned above are possible without departing from the inventive concepts herein. The invention, therefore, is not to be restricted except in the spirit of the appended claims.

Claims

What is Claimed is:
1. An antifuse comprising: a lower conductive electrode; an upper conductive electrode; an antifuse material disposed between said lower conductive electrode and said upper conductive electrode, said antifuse material comprising a layer of amoiphous silicon disposed between a first layer of silicon nitride and a second layer of silicon nitride, said antifuse material further comprising a thin layer of silicon dioxide disposed between said layer of amorphous silicon and one of said first and second silicon nitride layers.
2. The antifuse of claim 1 wherein said thin layer of silicon dioxide is disposed between said layer of amoiphous silicon and said first silicon nitride layer.
3. The antifuse of claim 1 wherein said thin layer of silicon dioxide is disposed between said layer of amorphous silicon and said second silicon nitride layer.
4. An antifuse comprising: a lower conductive electrode having an upper surface and disposed over an insulating layer; an interlayer dielectric layer disposed over said upper surface of said lower conductive electrode, said interlayer dielectric layer having an upper surface and having an aperture communicating with said lower conductive electrode foπned therein; a conductive plug disposed in said aperture, said conductive plug having an upper surface substantially planar with said upper surface of said interlayer dielectric layer; an antifuse layer having an upper surface and disposed over said upper surface of said conductive plug and at least a portion of said upper surface of said interlayer dielectric layer, said antifuse layer comprising a first layer formed from silicon nitride, a second layer formed from silicon dioxide having a ti ickness between about 1 angstrom and 300 angstroms, a third layer formed from amoiphous silicon, and a fourth layer formed from silicon nitride; and an upper electrode disposed over said upper surface of said antifuse layer.
5. The antifuse of claim 4 wherein outer edges of said first layer said second layer and said third layer form a substantial vertical wall and further including an oxide spacer in contact with said vertical wall.
6. An antifuse comprising: a lower conductive electrode having an upper surface and disposed over an insulating layer; an interlayer dielectric layer disposed over said upper surface of said lower conductive electrode, said interlayer dielectric layer having an upper surface and having an aperture communicating with said lower conductive electrode formed therein; a conductive plug disposed in said aperture, said conductive plug having an upper surface substantially planar with said upper surface of said interlayer dielectric layer; an antifuse layer having an upper surface and disposed over said upper surface of said conductive plug and at least a portion of said upper surface of said interlayer dielectric layer, said antifuse layer comprising a first layer formed from silicon nitiide, a second layer formed from amorphous silicon, a third layer formed from silicon dioxide having a thickness between about 1 angstrom and 3(X) angstroms and a fourth layer formed from silicon nitride: and an upper electrode disposed over said upper surface of said antifuse layer.
7. The antifuse of claim 6 wherein outer edges of said first layer said second layer and said third layer foπn a substantial vertical wall and further including an oxide spacer in contact with said vertical wall.
8. A method for fabricating an antifuse comprising the steps of: forming a lower conductive electrode; forming a first layer of silicon nitride on an upper surface of said lower conductive electrode; forming a layer of amoiphous silicon on an upper surface of said first layer of silicon nitride; forming a thin layer of silicon dioxide on an upper surface of said layer of amoiphous silicon: forming a second layer of silicon nitiide on an upper surface of said thin layer of silicon dioxide; and forming an upper conductive electrode on an upper surface of said second layer of silicon nitride.
9. The method of claim 8 further including the steps of stack etching outer edges of said first layer of silicon nitiide, said layer of amorphous silicon, said thin layer of silicon dioxide, and said second layer of silicon nitiide to form a substantial vertical wall and forming an oxide spacer in contact with said vertical wall prior to the step of forming said upper conductive electrode.
10. A method for fabricating an antifuse comprising die steps of: tormina a lower conductive electrode; forming a first layer of silicon nitride on an upper surface of said lower conductive electrode; forming a thin layer of silicon dioxide on an upper surface of said first layer of silicon nitride; forming a layer of amorphous silicon on an upper surface of said thin layer of silicon dioxide; forming a second layer of silicon nitride on an upper surface of said layer of amorphous silicon; and forming an upper conductive electrode on an upper surface of said second layer of silicon nitride.
11. The method of claim 10 further including the steps of stack etching outer edges of said first layer of silicon nitiide, said thin layer of silicon dioxide, said layer of amoiphous silicon, and said second layer of silicon nitiide to form a substantial vertical wall and forming an oxide spacer in contact with said vertical wall prior to the step of forming said upper conductive electrode.
12. A composite antifuse material for use in an antifuse including a first conductive electrode and a second conductive electrode, the composite antifuse material disposed between the first conductive electrode and the second conductive electrode comprising: a layer of amoiphous silicon disposed between a first layer of silicon nitiide and a second layer of silicon nitiide, said antifuse material further comprising a thin layer of silicon dioxide disposed between said layer of amorphous silicon and one of said first and second silicon nitride layers.
13. The antifuse of claim 12 wherein said thin layer of silicon dioxide is disposed between said layer of amorphous silicon and said first silicon nitiide layer.
14. The antifuse of claim 12 wherein said thin layer of silicon dioxide is disposed between said layer of amoiphous silicon and said second silicon nitiide layer.
PCT/US1996/009235 1995-06-06 1996-06-05 Reduced leakage antifuse structure and fabrication method WO1996039717A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP96918237A EP0774163B1 (en) 1995-06-06 1996-06-05 Reduced leakage antifuse structure and fabrication method
JP9501608A JP3051454B2 (en) 1995-06-06 1996-06-05 Low-leakage non-fuse, method of assembling the same and non-fuse material
DE69617169T DE69617169T2 (en) 1995-06-06 1996-06-05 ANTI-SECURING STRUCTURE WITH REDUCED LEAKAGE CURRENT AND MANUFACTURING METHOD
KR1019970700794A KR100230158B1 (en) 1995-06-06 1996-06-05 Reduced leakage antifuse structure and fabrication method

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/472,050 US5986322A (en) 1995-06-06 1995-06-06 Reduced leakage antifuse structure
US08/472,050 1995-06-06

Publications (1)

Publication Number Publication Date
WO1996039717A1 true WO1996039717A1 (en) 1996-12-12

Family

ID=23874005

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1996/009235 WO1996039717A1 (en) 1995-06-06 1996-06-05 Reduced leakage antifuse structure and fabrication method

Country Status (7)

Country Link
US (2) US5986322A (en)
EP (1) EP0774163B1 (en)
JP (1) JP3051454B2 (en)
KR (1) KR100230158B1 (en)
CA (1) CA2196307A1 (en)
DE (1) DE69617169T2 (en)
WO (1) WO1996039717A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5789764A (en) * 1995-04-14 1998-08-04 Actel Corporation Antifuse with improved antifuse material
CN1321456C (en) * 2002-07-19 2007-06-13 联华电子股份有限公司 Method of forming molten through hole structure

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5581111A (en) * 1993-07-07 1996-12-03 Actel Corporation Dielectric-polysilicon-dielectric antifuse for field programmable logic applications
US5856234A (en) * 1993-09-14 1999-01-05 Actel Corporation Method of fabricating an antifuse
US5485031A (en) 1993-11-22 1996-01-16 Actel Corporation Antifuse structure suitable for VLSI application
EP0774164A1 (en) * 1995-06-02 1997-05-21 Actel Corporation Raised tungsten plug antifuse and fabrication process
US5986322A (en) * 1995-06-06 1999-11-16 Mccollum; John L. Reduced leakage antifuse structure
JPH1056066A (en) * 1996-08-08 1998-02-24 Matsushita Electron Corp Anti-fuse device and manufacture thereof
US6016001A (en) * 1997-06-18 2000-01-18 Vlsi Technology, Inc. Metal to amorphous silicon to metal anti-fuse structure
US5989718A (en) * 1997-09-24 1999-11-23 Micron Technology Dielectric diffusion barrier
US5904507A (en) * 1998-02-23 1999-05-18 National Semiconductor Corporation Programmable anti-fuses using laser writing
US6107165A (en) 1998-08-13 2000-08-22 Quicklogic Corporation Metal-to-metal antifuse having improved barrier layer
US5955751A (en) * 1998-08-13 1999-09-21 Quicklogic Corporation Programmable device having antifuses without programmable material edges and/or corners underneath metal
US6249010B1 (en) * 1998-08-17 2001-06-19 National Semiconductor Corporation Dielectric-based anti-fuse cell with polysilicon contact plug and method for its manufacture
US6483736B2 (en) 1998-11-16 2002-11-19 Matrix Semiconductor, Inc. Vertically stacked field programmable nonvolatile memory and method of fabrication
US6515343B1 (en) 1998-11-19 2003-02-04 Quicklogic Corporation Metal-to-metal antifuse with non-conductive diffusion barrier
US6436839B1 (en) * 1999-06-01 2002-08-20 Taiwan Semiconductor Manufacturing Company Increasing programming silicide process window by forming native oxide film on amourphous Si after metal etching
US6362102B1 (en) 1999-12-27 2002-03-26 Chartered Semiconductor Manufacturing Ltd Method of forming top metal contact to antifuse
US8575719B2 (en) 2000-04-28 2013-11-05 Sandisk 3D Llc Silicon nitride antifuse for use in diode-antifuse memory arrays
US20050090073A1 (en) * 2000-12-20 2005-04-28 Actel Corporation, A California Corporation MOS transistor having improved total radiation-induced leakage current
US20050090047A1 (en) * 2000-12-20 2005-04-28 Actel Corporation, A California Corporation. Method of making a MOS transistor having improved total radiation-induced leakage current
US6773967B1 (en) * 2002-01-04 2004-08-10 Taiwan Semiconductor Manufacturing Company Method to prevent antifuse Si damage using sidewall spacers
US8415650B2 (en) 2009-07-02 2013-04-09 Actel Corporation Front to back resistive random access memory cells
US10270451B2 (en) 2015-12-17 2019-04-23 Microsemi SoC Corporation Low leakage ReRAM FPGA configuration cell
US10147485B2 (en) 2016-09-29 2018-12-04 Microsemi Soc Corp. Circuits and methods for preventing over-programming of ReRAM-based memory cells
US9990993B2 (en) 2016-09-29 2018-06-05 Microsemi SoC Corporation Three-transistor resistive random access memory cells
US9704573B1 (en) 2016-09-30 2017-07-11 Microsemi SoC Corporation Three-transistor resistive random access memory cells
CN110036484B (en) 2016-12-09 2021-04-30 美高森美SoC公司 Resistive random access memory cell
KR20180085120A (en) 2017-01-17 2018-07-26 삼성전자주식회사 Semiconductor memory device
CN111033624B (en) 2017-08-11 2023-10-03 美高森美SoC公司 Circuit and method for programming a resistive random access memory device
KR102018318B1 (en) * 2018-09-11 2019-09-04 주식회사 유진테크 Method for forming a thin film
US11541204B2 (en) 2018-09-26 2023-01-03 W. L. Gore & Associates, Inc. Cyclic expansion tissue treatment programs and associated systems
US10763210B2 (en) * 2019-01-03 2020-09-01 International Business Machines Corporation Circular ring shaped antifuse device

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0416903A2 (en) * 1989-09-07 1991-03-13 Quicklogic Corporation Method of fabricating a programmable interconnect structure
US5308795A (en) * 1992-11-04 1994-05-03 Actel Corporation Above via metal-to-metal antifuse
US5404029A (en) * 1990-04-12 1995-04-04 Actel Corporation Electrically programmable antifuse element
US5411917A (en) * 1990-04-12 1995-05-02 Actel Corporation Electrically programmable antifuse incorporating dielectric and amorphous silicon interlayer

Family Cites Families (99)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4099069A (en) * 1976-10-08 1978-07-04 Westinghouse Electric Corp. Circuit producing a common clear signal for erasing selected arrays in a mnos memory system
US4177473A (en) * 1977-05-18 1979-12-04 Energy Conversion Devices, Inc. Amorphous semiconductor member and method of making the same
US4276557A (en) * 1978-12-29 1981-06-30 Bell Telephone Laboratories, Incorporated Integrated semiconductor circuit structure and method for making it
JPS5998971A (en) * 1982-11-30 1984-06-07 株式会社ナカ技術研究所 Bearing structure of ceiling inspection port
US4847732A (en) * 1983-09-15 1989-07-11 Mosaic Systems, Inc. Wafer and method of making same
US4796075A (en) * 1983-12-21 1989-01-03 Advanced Micro Devices, Inc. Fusible link structure for integrated circuits
GB8400959D0 (en) * 1984-01-13 1984-02-15 British Petroleum Co Plc Semiconductor device
US4651409A (en) * 1984-02-09 1987-03-24 Ncr Corporation Method of fabricating a high density, low power, merged vertical fuse/bipolar transistor
US4870302A (en) * 1984-03-12 1989-09-26 Xilinx, Inc. Configurable electrical circuit having configurable logic elements and configurable interconnects
JPS6249651A (en) * 1985-06-25 1987-03-04 テキサス インスツルメンツインコ−ポレイテツド Antifuse, making thereof, electrically programmable memory cell and programming thereof
EP0231271A1 (en) * 1985-07-29 1987-08-12 AT&T Corp. Three-level interconnection scheme for integrated circuits
US4748490A (en) * 1985-08-01 1988-05-31 Texas Instruments Incorporated Deep polysilicon emitter antifuse memory cell
AU6596286A (en) * 1985-10-29 1987-05-19 4C Electronics, Inc. Progammable integrated crosspoint switch
US4899205A (en) * 1986-05-09 1990-02-06 Actel Corporation Electrically-programmable low-impedance anti-fuse element
US5266829A (en) * 1986-05-09 1993-11-30 Actel Corporation Electrically-programmable low-impedance anti-fuse element
US5134457A (en) * 1986-05-09 1992-07-28 Actel Corporation Programmable low-impedance anti-fuse element
US4943538A (en) * 1986-05-09 1990-07-24 Actel Corporation Programmable low impedance anti-fuse element
US4822753A (en) * 1988-05-09 1989-04-18 Motorola, Inc. Method for making a w/tin contact
US4933576A (en) * 1988-05-13 1990-06-12 Fujitsu Limited Gate array device having macro cells for forming master and slave cells of master-slave flip-flop circuit
GB2222024B (en) * 1988-08-18 1992-02-19 Stc Plc Improvements in integrated circuits
DE3927033C2 (en) * 1988-08-23 2000-12-21 Seiko Epson Corp Semiconductor component with antifuse electrode arrangement and method for its production
US4914055A (en) * 1989-08-24 1990-04-03 Advanced Micro Devices, Inc. Semiconductor antifuse structure and method
US5552627A (en) * 1990-04-12 1996-09-03 Actel Corporation Electrically programmable antifuse incorporating dielectric and amorphous silicon interlayers
US5780323A (en) * 1990-04-12 1998-07-14 Actel Corporation Fabrication method for metal-to-metal antifuses incorporating a tungsten via plug
US5272101A (en) * 1990-04-12 1993-12-21 Actel Corporation Electrically programmable antifuse and fabrication processes
US5541441A (en) * 1994-10-06 1996-07-30 Actel Corporation Metal to metal antifuse
US5381035A (en) * 1992-09-23 1995-01-10 Chen; Wenn-Jei Metal-to-metal antifuse including etch stop layer
US5866937A (en) * 1990-04-12 1999-02-02 Actel Corporation Double half via antifuse
US5070384A (en) * 1990-04-12 1991-12-03 Actel Corporation Electrically programmable antifuse element incorporating a dielectric and amorphous silicon interlayer
KR910019241A (en) * 1990-04-30 1991-11-30 리챠드 데이빗 라우만 Integrated circuit with antifuse
US5194759A (en) * 1990-05-18 1993-03-16 Actel Corporation Methods for preventing disturbance of antifuses during programming
US5095362A (en) * 1990-10-23 1992-03-10 Instant Circuit Corporation Method for reducing resistance for programmed antifuse
JPH06505368A (en) * 1991-01-17 1994-06-16 クロスポイント・ソルーションズ・インコーポレイテッド Improved antifuse circuit structure and method for its fabrication for use in field programmable gate arrays
US5163180A (en) * 1991-01-18 1992-11-10 Actel Corporation Low voltage programming antifuse and transistor breakdown method for making same
US5166556A (en) * 1991-01-22 1992-11-24 Myson Technology, Inc. Programmable antifuse structure, process, logic cell and architecture for programmable integrated circuits
US5219782A (en) * 1992-03-30 1993-06-15 Texas Instruments Incorporated Sublithographic antifuse method for manufacturing
EP0500034B1 (en) * 1991-02-19 2001-06-06 Texas Instruments Incorporated Sidewall anti-fuse structure and method for making
US5100827A (en) * 1991-02-27 1992-03-31 At&T Bell Laboratories Buried antifuse
US5322812A (en) * 1991-03-20 1994-06-21 Crosspoint Solutions, Inc. Improved method of fabricating antifuses in an integrated circuit device and resulting structure
US5196724A (en) * 1991-04-26 1993-03-23 Quicklogic Corporation Programmable interconnect structures and programmable integrated circuits
US5233217A (en) * 1991-05-03 1993-08-03 Crosspoint Solutions Plug contact with antifuse
US5290734A (en) * 1991-06-04 1994-03-01 Vlsi Technology, Inc. Method for making anti-fuse structures
US5120679A (en) * 1991-06-04 1992-06-09 Vlsi Technology, Inc. Anti-fuse structures and methods for making same
US5242851A (en) * 1991-07-16 1993-09-07 Samsung Semiconductor, Inc. Programmable interconnect device and method of manufacturing same
US5258643A (en) * 1991-07-25 1993-11-02 Massachusetts Institute Of Technology Electrically programmable link structures and methods of making same
US5302546A (en) * 1991-07-31 1994-04-12 Quicklogic Corporation Programming of antifuses
US5327024A (en) * 1992-07-02 1994-07-05 Quicklogic Corporation Field programmable antifuse device and programming method therefor
WO1993004499A1 (en) * 1991-08-19 1993-03-04 Crosspoint Solutions, Inc. An improved antifuse and method of manufacture thereof
US5241496A (en) * 1991-08-19 1993-08-31 Micron Technology, Inc. Array of read-only memory cells, eacch of which has a one-time, voltage-programmable antifuse element constructed within a trench shared by a pair of cells
WO1993005514A1 (en) * 1991-09-04 1993-03-18 Vlsi Technology, Inc. Anti-fuse structures and methods for making same
US5126290A (en) * 1991-09-11 1992-06-30 Micron Technology, Inc. Method of making memory devices utilizing one-sided ozone teos spacers
US5272666A (en) * 1991-10-18 1993-12-21 Lattice Semiconductor Corporation Programmable semiconductor antifuse structure and method of fabricating
EP0539197A1 (en) * 1991-10-23 1993-04-28 Fujitsu Limited Semiconductor device with anti-fuse and production method
JPH05243385A (en) * 1992-02-27 1993-09-21 Fujitsu Ltd Semiconductor device and its manufacture
US5250464A (en) * 1992-03-11 1993-10-05 Texas Instruments Incorporated Method of making a low capacitance, low resistance sidewall antifuse structure
US5298784A (en) * 1992-03-27 1994-03-29 International Business Machines Corporation Electrically programmable antifuse using metal penetration of a junction
US5329153A (en) * 1992-04-10 1994-07-12 Crosspoint Solutions, Inc. Antifuse with nonstoichiometric tin layer and method of manufacture thereof
US5475253A (en) * 1992-08-21 1995-12-12 Xilinx, Inc. Antifuse structure with increased breakdown at edges
US5293133A (en) * 1992-08-27 1994-03-08 Quicklogic Corporation Method of determining an electrical characteristic of an antifuse and apparatus therefor
US5284788A (en) * 1992-09-25 1994-02-08 Texas Instruments Incorporated Method and device for controlling current in a circuit
US5248632A (en) * 1992-09-29 1993-09-28 Texas Instruments Incorporated Method of forming an antifuse
US5395797A (en) * 1992-12-01 1995-03-07 Texas Instruments Incorporated Antifuse structure and method of fabrication
US5373169A (en) * 1992-12-17 1994-12-13 Actel Corporation Low-temperature process metal-to-metal antifuse employing silicon link
TW232091B (en) * 1992-12-17 1994-10-11 American Telephone & Telegraph
JPH06204341A (en) * 1992-12-28 1994-07-22 Fujitsu Ltd Manufacture of semiconductor device
US5387311A (en) * 1993-02-16 1995-02-07 Vlsi Technology, Inc. Method for manufacturing anti-fuse structures
US5270251A (en) * 1993-02-25 1993-12-14 Massachusetts Institute Of Technology Incoherent radiation regulated voltage programmable link
US5332929A (en) * 1993-04-08 1994-07-26 Xilinx, Inc. Power management for programmable logic devices
US5300456A (en) * 1993-06-17 1994-04-05 Texas Instruments Incorporated Metal-to-metal antifuse structure
US5390141A (en) * 1993-07-07 1995-02-14 Massachusetts Institute Of Technology Voltage programmable links programmed with low current transistors
KR960015326B1 (en) * 1993-07-26 1996-11-07 재단법인 한국전자통신연구소 Fuse element and method of manufacturing the same
US5391518A (en) * 1993-09-24 1995-02-21 Vlsi Technology, Inc. Method of making a field programmable read only memory (ROM) cell using an amorphous silicon fuse with buried contact polysilicon and metal electrodes
US5523612A (en) * 1993-11-19 1996-06-04 Crosspoint Solutions, Inc. Method of manufacturing an antifuse with doped barrier metal layer and resulting antifuse
US5485031A (en) * 1993-11-22 1996-01-16 Actel Corporation Antifuse structure suitable for VLSI application
US5391513A (en) * 1993-12-22 1995-02-21 Vlsi Technology, Inc. Wet/dry anti-fuse via etch
US5403778A (en) * 1994-01-06 1995-04-04 Texas Instruments Incorporated Limited metal reaction for contact cleaning and improved metal-to-metal antifuse contact cleaning method
US5412593A (en) * 1994-01-12 1995-05-02 Texas Instruments Incorporated Fuse and antifuse reprogrammable link for integrated circuits
US5834824A (en) * 1994-02-08 1998-11-10 Prolinx Labs Corporation Use of conductive particles in a nonconductive body as an integrated circuit antifuse
US5440167A (en) * 1994-02-23 1995-08-08 Crosspoint Solutions, Inc. Antifuse with double via contact and method of manufacture therefor
US5572062A (en) * 1994-03-31 1996-11-05 Crosspoint Solutions, Inc. Antifuse with silicon spacers
US5521440A (en) * 1994-05-25 1996-05-28 Crosspoint Solutions, Inc. Low-capacitance, plugged antifuse and method of manufacture therefor
US5756367A (en) * 1994-11-07 1998-05-26 Advanced Micro Devices, Inc. Method of making a spacer based antifuse structure for low capacitance and high reliability
US5789764A (en) * 1995-04-14 1998-08-04 Actel Corporation Antifuse with improved antifuse material
US5610084A (en) * 1995-04-21 1997-03-11 U.S. Phillips Corporation Method of manufacturing an antifuse utilizing nitrogen implantation
EP0774164A1 (en) * 1995-06-02 1997-05-21 Actel Corporation Raised tungsten plug antifuse and fabrication process
US5986322A (en) * 1995-06-06 1999-11-16 Mccollum; John L. Reduced leakage antifuse structure
US5844297A (en) * 1995-09-26 1998-12-01 Symbios, Inc. Antifuse device for use on a field programmable interconnect chip
US5708291A (en) * 1995-09-29 1998-01-13 Intel Corporation Silicide agglomeration fuse device
US5759876A (en) * 1995-11-01 1998-06-02 United Technologies Corporation Method of making an antifuse structure using a metal cap layer
US5658819A (en) * 1995-11-01 1997-08-19 United Technologies Corporation Antifuse structure and process for manufacturing the same
US5783467A (en) * 1995-12-29 1998-07-21 Vlsi Technology, Inc. Method of making antifuse structures using implantation of both neutral and dopant species
US5602053A (en) * 1996-04-08 1997-02-11 Chartered Semidconductor Manufacturing Pte, Ltd. Method of making a dual damascene antifuse structure
JPH1056066A (en) * 1996-08-08 1998-02-24 Matsushita Electron Corp Anti-fuse device and manufacture thereof
US5831325A (en) * 1996-08-16 1998-11-03 Zhang; Guobiao Antifuse structures with improved manufacturability
JPH1084043A (en) * 1996-09-09 1998-03-31 Matsushita Electron Corp Semiconductor device
US6023431A (en) * 1996-10-03 2000-02-08 Micron Technology, Inc. Low current redundancy anti-fuse method and apparatus
US5852323A (en) * 1997-01-16 1998-12-22 Xilinx, Inc. Electrically programmable antifuse using metal penetration of a P-N junction
JPH10284604A (en) * 1997-04-08 1998-10-23 Matsushita Electron Corp Anti-fuse element and manufacture therefor
US5811870A (en) * 1997-05-02 1998-09-22 International Business Machines Corporation Antifuse structure

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0416903A2 (en) * 1989-09-07 1991-03-13 Quicklogic Corporation Method of fabricating a programmable interconnect structure
US5404029A (en) * 1990-04-12 1995-04-04 Actel Corporation Electrically programmable antifuse element
US5411917A (en) * 1990-04-12 1995-05-02 Actel Corporation Electrically programmable antifuse incorporating dielectric and amorphous silicon interlayer
US5308795A (en) * 1992-11-04 1994-05-03 Actel Corporation Above via metal-to-metal antifuse

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5789764A (en) * 1995-04-14 1998-08-04 Actel Corporation Antifuse with improved antifuse material
CN1321456C (en) * 2002-07-19 2007-06-13 联华电子股份有限公司 Method of forming molten through hole structure

Also Published As

Publication number Publication date
CA2196307A1 (en) 1996-12-12
JP3051454B2 (en) 2000-06-12
KR100230158B1 (en) 1999-11-15
DE69617169T2 (en) 2002-04-18
US5763299A (en) 1998-06-09
US5986322A (en) 1999-11-16
KR970705175A (en) 1997-09-06
JPH10503062A (en) 1998-03-17
EP0774163B1 (en) 2001-11-21
EP0774163A1 (en) 1997-05-21
DE69617169D1 (en) 2002-01-03

Similar Documents

Publication Publication Date Title
US5986322A (en) Reduced leakage antifuse structure
US5804500A (en) Fabrication process for raised tungsten plug antifuse
US5373169A (en) Low-temperature process metal-to-metal antifuse employing silicon link
US5466629A (en) Process for fabricating ferroelectric integrated circuit
US5248632A (en) Method of forming an antifuse
US5670818A (en) Electrically programmable antifuse
US6646323B2 (en) Zero mask high density metal/insulator/metal capacitor
US5663091A (en) Method for fabricating an electrically programmable antifuse
US20050014334A1 (en) Method for making high density nonvolatile memory
US20060125049A1 (en) Resistive structure integrated in a semiconductor substrate
JPH08504302A (en) Anti-fuse structure with increased edge breakdown voltage
US5789764A (en) Antifuse with improved antifuse material
KR19980087544A (en) Semiconductor device having metal-insulator-metal capacitor and method of manufacturing the same
US6249010B1 (en) Dielectric-based anti-fuse cell with polysilicon contact plug and method for its manufacture
KR100306202B1 (en) Semiconductor device and manufacturing method thereof
US6465282B1 (en) Method of forming a self-aligned antifuse link
WO2002061802A2 (en) Metal-to-metal antifuse structure and fabrication method
US6700474B1 (en) High value polysilicon resistor
US20020072154A1 (en) Antifuse with improved radiation SEDR
US6713369B1 (en) Antifuse incorporating tantalum nitride barrier layer
JPH03157966A (en) Manufacture of semiconductor device
WO1993002473A1 (en) Voltage programmable links for integrated circuits

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): CA JP KR

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE

WWE Wipo information: entry into national phase

Ref document number: 2196307

Country of ref document: CA

WWE Wipo information: entry into national phase

Ref document number: 1996918237

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 1019970700794

Country of ref document: KR

121 Ep: the epo has been informed by wipo that ep was designated in this application
WWP Wipo information: published in national office

Ref document number: 1996918237

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 1019970700794

Country of ref document: KR

WWG Wipo information: grant in national office

Ref document number: 1019970700794

Country of ref document: KR

WWG Wipo information: grant in national office

Ref document number: 1996918237

Country of ref document: EP