WO1996040480A1 - Extrusion coating process for making protective and decorative films - Google Patents
Extrusion coating process for making protective and decorative films Download PDFInfo
- Publication number
- WO1996040480A1 WO1996040480A1 PCT/US1996/009893 US9609893W WO9640480A1 WO 1996040480 A1 WO1996040480 A1 WO 1996040480A1 US 9609893 W US9609893 W US 9609893W WO 9640480 A1 WO9640480 A1 WO 9640480A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- coat
- process according
- layer
- film
- sheet
- Prior art date
Links
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/22—Making multilayered or multicoloured articles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/28—Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers
- B05D1/286—Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers using a temporary backing to which the coating has been applied
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
- B29C48/08—Flat, e.g. panels flexible, e.g. films
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B32B37/153—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
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- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2327/16—Homopolymers or copolymers of vinylidene fluoride
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/00—Stock material or miscellaneous articles
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- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24893—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material
- Y10T428/24901—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material including coloring matter
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
- Y10T428/31913—Monoolefin polymer
Definitions
- extruded films have been used for making exterior automotive clear coat/color coat films.
- International application PCT US93 07097 to Duhme describes an approach in which paint films are made by coextruding a base coat and a clear coat as separate extruded layers onto a carrier sheet.
- the carrier is used as a supporting sheet for the clear coat and color coat in a subsequent injection molding process.
- the extruded clear coat and color coat are supported in the mold by the carrier and shaped in the mold.
- the clear coat is a coextruded sheet having different proportions of polyvinylidene fluoride (PVDF) and acrylic resins in each layer of the coextrusion.
- PVDF polyvinylidene fluoride
- FIG. 18 is schematic diagram illustrating an in-line decorative transfer and embossing step in the process for making extruded plastic siding panels with embossed decorative wood grain surfaces.
- FIG. 1 schematically illustrates roll coating of a solvent cast PVDF/acrylic color coat material 22 onto the clear extruded topcoat on the PET carrier.
- the extruded clear coated film 28 travels to the roll coating station 30 where a polyvinylidene fluoride/acrylic pigmented color coat is roll coated onto the extrusion topcoated carrier.
- One preferred ratio of polyvinylidene fluoride copolymer to acrylic polymer is 75/25 by weight based on the total PVDF copolymer/acrylic polymer solids contained in the color coat.
- Kynar 7201 Elf Atochem
- Elvacite 2008 I.C.I.
- the line speed was held at 15 ft/min.
- the first oven zone was set at 240°F and the second oven zone was set at 250°F.
- the applicator roll ratio was held at 115% of line speed, and the metering roll was held at 20% of line speed. Under these conditions 25 gm m 2 of dried color coat was deposited onto the one mil PVDF/acrylic topcoat.
- the film was subsequently coated with a solvent based black Avloy ® color coat (using a Bird bar) and was then dried.
- the solvent based black color coat had the following formulation: INGREDIENTS PARTS
- the supply roll of the carrier film is shown with the carrier sheet passing around a series of rolls prior to applying a release coat to the surface of the carrier by a conventional gravure cylinder.
- the release coat is preferably a thermosetting resinous material which, when exposed to heat for drying it, also crosslinks and permanently bonds as a surface film adhered to the carrier sheet.
- the solids contained in the matte release coat preferably include, as a principal component, one or more crosslinking agents to provide good adhesion of the dried crosslinked coating to the polyester carrier film.
- the matte release coat formulation includes a primary crosslinking resin such as a vinyl resin that bonds to the polyester film.
- the substrate can be an extruded rigid pigmented PVC compound with a thin coextruded acrylic tie layer extrusion as a coextrusion from the extrader die 176.
- the substrate polymer compound is preformed as an extrudable material in pellet or dry flowable powder form from the hopper into the extrader to the feed block and die.
- the coextrasion die is adjacent to the calendar stack of three temperamre controlled rolls 178, 180 and 182.
- the tie coat is preformed as an extrudable material in pellet form fed from the hopper into a second extrader to the same feed block or die as die substrate polymer.
- the coextrusion is typically fed horizontally into a set opening between the top and middle rolls of the three roll calendar stack.
- the top roll 178 is used for metering and the middle roll 180 is set at line speed to support the substrate while it starts to solidify.
- the bottom roll 182 is used to smooth the top surface of the tie coat and to finish cooling the substrate for proper handling.
- mixed metal oxide pigments in the wood grain print inks and color coats is desirable because of the excellent durability of mixed metal oxides and the availability of an infrared-reflective mixed metal black pigment which minimizes heat build-up in the wood grain decorated vinyl siding panel.
- the mixed metal oxide pigments can result in excessive gravure cylinder wear when the grain ink patterns are coated with chrome finished gravure cylinders.
- the etched cylinders were coated with a metal nitride such as a titanium nitride ceramic coating.
- the cylinders are coated with a conventional vacuum metallization process.
Abstract
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/793,836 US6336988B1 (en) | 1995-06-07 | 1996-06-07 | Extrusion coating process for making protective and decorative films |
DE69629700T DE69629700T2 (en) | 1995-06-07 | 1996-06-07 | EXTRUSION COATING METHOD FOR PRODUCING PROTECTIVE AND DECORATIVE FILMS |
CA002223690A CA2223690C (en) | 1995-06-07 | 1996-06-07 | Extrusion coating process for making protective and decorative films |
AU63826/96A AU6382696A (en) | 1995-06-07 | 1996-06-07 | Extrusion coating process for making protective and decorative films |
EP96923266A EP0842029B1 (en) | 1995-06-07 | 1996-06-07 | Extrusion coating process for making protective and decorative films |
AT96923266T ATE248052T1 (en) | 1995-06-07 | 1996-06-07 | EXTRUSION COATING PROCESS FOR PRODUCING PROTECTIVE AND DECORATIVE FILMS |
JP09502073A JP2000513282A (en) | 1995-06-07 | 1996-06-07 | Extrusion coating method for producing protective and decorative films |
US11/850,631 US20080113148A1 (en) | 1996-06-07 | 2007-09-05 | Extruded polymeric high transparency films |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US47966595A | 1995-06-07 | 1995-06-07 | |
US08/479,665 | 1995-06-07 |
Related Parent Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US47966595A Continuation-In-Part | 1995-06-07 | 1995-06-07 | |
US47966595A Continuation | 1995-06-07 | 1995-06-07 |
Related Child Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US08/793,836 A-371-Of-International US6336988B1 (en) | 1995-06-07 | 1996-06-07 | Extrusion coating process for making protective and decorative films |
US09/256,967 Continuation-In-Part US6254712B1 (en) | 1995-06-07 | 1999-02-24 | Extrusion coating process for making high transparency protective and decorative films |
US10/041,432 Division US6733870B2 (en) | 1995-06-07 | 2002-01-08 | Extrusion coating process for making protective and decorative films |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1996040480A1 true WO1996040480A1 (en) | 1996-12-19 |
Family
ID=23904912
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1996/009893 WO1996040480A1 (en) | 1995-06-07 | 1996-06-07 | Extrusion coating process for making protective and decorative films |
Country Status (12)
Country | Link |
---|---|
US (2) | US6336988B1 (en) |
EP (2) | EP0842029B1 (en) |
JP (1) | JP2000513282A (en) |
KR (1) | KR100266942B1 (en) |
CN (1) | CN1084662C (en) |
AR (1) | AR000433A1 (en) |
AT (1) | ATE248052T1 (en) |
AU (1) | AU6382696A (en) |
CA (1) | CA2223690C (en) |
DE (1) | DE69629700T2 (en) |
WO (1) | WO1996040480A1 (en) |
ZA (1) | ZA964731B (en) |
Cited By (21)
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EP0933183A1 (en) * | 1997-07-22 | 1999-08-04 | Nissha Printing Co., Ltd. | Sheet for molded-in foil decoration and method of producing molded resin having molded-in foil decoration by using the sheet |
US5985079A (en) * | 1996-03-28 | 1999-11-16 | Rexam Industries Corp. | Flexible composite surfacing film and method for producing same |
WO2000037237A1 (en) * | 1998-12-22 | 2000-06-29 | Röhm GmbH & Co. KG | Methods for producing films having a layer containing a mixture of fluoropolymers and polyacrylates |
US6284183B1 (en) | 1998-06-08 | 2001-09-04 | Avery Dennison Corporation | Thick sheet laminating process for making exterior automotive body panels |
US6399193B1 (en) | 1998-12-18 | 2002-06-04 | The University Of Massachusetts Lowell | Surfacing laminate with bonded with pigmented pressure sensitive adhesive |
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US6843874B1 (en) * | 1997-12-01 | 2005-01-18 | H.B. Fuller Licensing & Financing Inc. | Method for producing a substantially continuous, nonporous thermoplastic coating and articles constructed therefrom |
KR100475627B1 (en) * | 2001-12-22 | 2005-03-15 | 세화정밀주식회사 | Apparatus and method for decoration resin sheet |
US6866938B2 (en) | 1997-07-22 | 2005-03-15 | Nissha Printing Co., Ltd. | Foil-detecting sheet and method of producing a foil-decorated resin article using the same |
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KR100733542B1 (en) | 2005-10-31 | 2007-06-28 | 재단법인 포항산업과학연구원 | The on-line Splice Method of Film onto Plastic Sheet |
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US8119235B1 (en) | 2000-04-14 | 2012-02-21 | E. I. Du Pont De Nemours And Company | Multilayer, co-extruded, ionomeric decorative surfacing |
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US8551279B2 (en) | 2008-03-25 | 2013-10-08 | 3M Innovative Properties Company | Multilayer articles and methods of making and using the same |
US8932424B2 (en) | 2008-03-25 | 2015-01-13 | 3M Innovative Properties Company | Paint film composites and methods of making and using the same |
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Also Published As
Publication number | Publication date |
---|---|
DE69629700T2 (en) | 2004-06-17 |
US6336988B1 (en) | 2002-01-08 |
KR100266942B1 (en) | 2000-09-15 |
ZA964731B (en) | 1997-01-07 |
KR19990022743A (en) | 1999-03-25 |
EP0842029A4 (en) | 2000-02-09 |
CN1190922A (en) | 1998-08-19 |
EP0842029A1 (en) | 1998-05-20 |
JP2000513282A (en) | 2000-10-10 |
US6733870B2 (en) | 2004-05-11 |
AR000433A1 (en) | 1997-06-18 |
CA2223690A1 (en) | 1996-12-19 |
EP1340615A2 (en) | 2003-09-03 |
AU6382696A (en) | 1996-12-30 |
EP1340615A3 (en) | 2009-07-15 |
ATE248052T1 (en) | 2003-09-15 |
DE69629700D1 (en) | 2003-10-02 |
EP0842029B1 (en) | 2003-08-27 |
CA2223690C (en) | 2003-09-23 |
US20020157772A1 (en) | 2002-10-31 |
CN1084662C (en) | 2002-05-15 |
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