WO1997000263A1 - Method for manufacturing cobalt catalysts - Google Patents
Method for manufacturing cobalt catalysts Download PDFInfo
- Publication number
- WO1997000263A1 WO1997000263A1 PCT/US1996/001086 US9601086W WO9700263A1 WO 1997000263 A1 WO1997000263 A1 WO 1997000263A1 US 9601086 W US9601086 W US 9601086W WO 9700263 A1 WO9700263 A1 WO 9700263A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- formula
- unsubstituted
- cobalt
- substituted
- reacting
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/06—Cobalt compounds
- C07F15/065—Cobalt compounds without a metal-carbon linkage
Definitions
- T y vriierein M ligand is selected from substituted and unsubstituted C1-C30 carboxylic acids having the formula: RC(O)O-.
- catalysts are particularly useful in bleach-containing consumer compositions, especially automatic dishwashing detergents and laundry detergents comprising bleach.
- Cobalt catalysts are well known, as are a variety of methods for manufacturing them. Most synthesis methods, however, are directed simply to methods effective for obtaining experimental quantities for academic studies. These are described, for example, in M. L. Tobe, "Base Hydrolysis of Transition-Metal Complexes", Adv. Inorg. Bioinorg. Mech.. (1983), 2, pages 1-94; J. Chem. Ed. (1989), 66 (12), 1043-45; “The Synthesis and Characterization of Inorganic Compounds", W.L. Jolly (Prentice-Hall; 1970), pp. 461-3; Inorg. Chem.. .18, 1497- 1502 (1979); Inorg. Chem..
- cobalt catalysts for use in consumer products, however, it is necessary that the cobalt catalysts be prepared in large quantities by the most cost effective manner with the highest possible purity. It has been discovered by the present invention that cobalt catalysts containing carboxylate ligands can be prepared on an industrially useful scale by the present process. BACKGROUND ART
- the present invention relates to methods for manufacturing cobalt complexes having the formula:
- T is one or more counteranions present in a number y to obtain a charge-balanced salt
- T are selected from the group consisting of chloride, iodide, 13", formate, nitrate, nitrite, sulfate, sulfite, citrate, acetate, carbonate, bromide, PFg-, BF4-, B(Ph)4", phosphate, phosphite, silicate, tosylate, methanesulfonate, and combinations thereof
- y is 1 or 2; with concentrated ammonium hydroxide and ammonium chloride; followed by
- step (b) reacting the product of step (a) with an oxidizing agent selected from the group consisting of oxygen, hydrogen peroxide, and mixtures thereof; followed by
- step (c) reacting the product of step (b) with a carboxylic acid anhydride of the formula:
- each R is independently selected from substituted or unsubstituted C1-C30 moieties (preferably both R are the same);
- the present invention relates to a method for manufacturing cobalt complexes having the formula:
- This method comprises the first step of reacting a cobalt (II) salt having the formula:
- T is one or more counteranions present in a number y to obtain a charge-balanced salt
- T are selected from the group consisting of chloride, iodide, 13", formate, nitrate, nitrite, sulfate, sulfite, citrate, acetate, carbonate, bromide, PFg", BF4", B(Ph)4", phosphate, phosphite, silicate, tosylate, methanesulfonate, and combinations thereof
- y is 1 or 2; with concentrated ammonium hydroxide and ammonium chloride (preferably at least 20%, more preferably at least 25%, and typically between 28-32% solutions of concentrated ammonium hydroxide).
- This step is typically conducted at room temperature; preferred temperatures are below about 90 °C, more preferably below 80 °C. Preferred is to use from about 5.0 to about 10.0 equivalents, more preferably from about 5.0 to about 5.5 equivalents, of ammonium hydroxide in a concentrated aqueous solution so as to minimize the volume of water present during the reaction.
- This first step is followed by a step whereby the product of the first step is reacted with an oxidizing agent selected from the group consisting of an oxidizing source such as oxygen and, especially, hydrogen peroxide (preferably at concentrations of at least about 30% and more preferably at least about 50% by weight).
- an oxidizing agent selected from the group consisting of an oxidizing source such as oxygen and, especially, hydrogen peroxide (preferably at concentrations of at least about 30% and more preferably at least about 50% by weight).
- This step is also typically conducted at room temperature; preferred temperatures are below about 90 °C, more preferably below 80 °C.
- This reaction step is then followed by reacting the product of the previous step with a carboxylic acid anhydride ofthe formula: RC(O)O(O)CR wherein each R is independently selected from substituted or unsubstituted C1-C30 moieties. It is preferred that both R moieties are the same, but mixed anhydrides may be used as desired for the desired cobalt complex being synthesized.
- Reaction conditions for this step are typically room temperature (preferred temperatures are below about 90 °C, more preferably below 80 °C) for from about 10 to about 60 minutes. Additionally, about 1.0 to about 2.0 equivalents of the ammonium carboxylate salt can be added prior to the addition of the carboxylic acid anhydride to facilitate synthesis ofthe desired cobalt complex.
- This reaction step is then optionally followed by exchanging the T counterion ofthe prepared cobalt complex with another T counterion. This may be carried out, for example, by treating the complex with an acid (e.g., HCl or HCIO4), or a sa (e.g., NaPF 6 ).
- an acid e.g., HCl or HCIO4
- a sa e.g., NaPF 6
- the mixture is optionally filtered and the cobalt complex is collected.
- Preferred collection methods include, for example, evaporation to remove the solvent or lyophiiization or precipitation (e.g., by addition of a co-solvent).
- the cobalt complex collected may be used as is, or further purified or modified for inco ⁇ oration into the desired product or use to be made of the complex. This includes optionally washing the solid product with a suitable solvent, e.g., ethanol, to remove non-cobalt salts.
- the present invention method preferably is carried out in one reaction vessel without isolation or separation of the intermediate reaction products. However, if desired, one or more of the reaction steps may be conducted in separate reaction vessels, and may be followed or preceeded by optional separation and/or collection steps ofthe intermediate reaction materials.
- T are selected from the group consisting of chloride, iodide, I3", formate, nitrate, nitrite, sulfate, sulfite, citrate, acetate, carbonate, bromide, PFg", BF4", B(Ph)4", phosphate, phosphite, silicate, tosylate, methanesulfonate, and combinations thereof.
- T can be protonated if more than one anionic group exists in T, e.g., HPO4 2 -, HCO3", H2PO4-, etc.
- T may be selected from the group consisting of non-traditional inorganic anions such as anionic surfactants (e.g., linear alkylbenzene sulfonates (LAS), alkyl sulfates (AS), alkylethoxysulfonates (AES), etc.) and/or anionic polymers (e.g., polyacrylates, polymethacrylates, etc.).
- anionic surfactants e.g., linear alkylbenzene sulfonates (LAS), alkyl sulfates (AS), alkylethoxysulfonates (AES), etc.
- anionic polymers e.g., polyacrylates, polymethacrylates, etc.
- R is preferably selected from the group consisting of hydrogen and
- C--C30 (preferably Cj-Cig) unsubstituted and substituted alkyl, C6-C30 (preferably Cg-Cjg) unsubstituted and substituted aryl, and C3-C30 (preferably C5-C18) unsubstituted and substituted heteroaryl, wherein substituents are selected from the group consisting of -NR* 3 , -NR' 4 + , -C(O)OR, -OR', -C(O)NR' , wherein R' is selected from the group consisting of hydrogen and Cj-Cg moieties.
- Such substituted R therefore include the moieties -(CH2) n OH and -(CH2) n NR'4 + , wherein n is an integer from 1 to about 16, preferably from about 2 to about 10, and most preferably from about 2 to about 5.
- M are carboxyUc acids having the formula above wherein R is selected from the group consisting of hydrogen, methyl, ethyl, propyl, straight or branched C4-C12 alkyl, and benzyl. Most preferred R is methyl.
- the M moieties include mono-carboxylates, which are preferred, but more than one carboxylate may be present in the moiety as long as the binding to the cobalt is by only one carboxylate per moiety (in which case the other carboxylate in the M moiety may be protonated or in its salt form).
- Preferred carboxylic acid M moieties include formic, benzoic, octanoic, nonanoic, decanoic, dodecanoic, malonic, maleic, succinic, adipic, phthalic, 2-ethylhexanoic, naphthenoic, oleic, palmitic, triflate, tartrate, stearic, butyric, citric, acrylic, aspartic, fumaric, lauric, linoleic, lactic, malic, and especially acetic acid. Therefore, most preferred methods use the anhydrides comprising these carboxyUc acids, and preferred anhydrides are the same acids. Most preferred anhydride is acetic anhydride.
- the preferred cobalt complexes prepared by the present invention are cobalt(m) pentaamineacetate dichloride, i.e. [Co(NH3)5OAc]Cl2 (herein "PAC"); cobalt(m) pentaamineacetate diacetate, i.e. [Co(NH3)5OAc](OAc)2; [Co(NH 3 ) 5 OAc](PF 6 )2; [Co(NH 3 ) 5 OAcj(SO4); and [Co(NH 3 )5OAc](BF 4 )2.
- PAC cobalt(m) pentaamineacetate dichloride
- PAC cobalt(m) pentaamineacetate dichloride
- PAC cobalt(m) pentaamineacetate diacetate
- the starting cobalt(II) complexes useful herein, the [Co(H2O)g] T y complexes, are commercially available and can be prepared by a variety of methods.
- the foUowing nonlimiting examples further Ulustrate the method according to the present invention.
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002224462A CA2224462C (en) | 1995-06-16 | 1996-01-25 | Method for manufacturing cobalt catalysts |
EP96903702A EP0832088B1 (en) | 1995-06-16 | 1996-01-25 | Method for manufacturing cobalt catalysts |
AT96903702T ATE192453T1 (en) | 1995-06-16 | 1996-01-25 | METHOD FOR PRODUCING COBALT CATALYSTS |
DE69608102T DE69608102T2 (en) | 1995-06-16 | 1996-01-25 | METHOD FOR PRODUCING COBALT CATALYSTS |
AU47700/96A AU4770096A (en) | 1995-06-16 | 1996-01-25 | Method for manufacturing cobalt catalysts |
JP9503028A JPH11509529A (en) | 1995-06-16 | 1996-01-25 | Manufacturing method of cobalt catalyst |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US49118595A | 1995-06-16 | 1995-06-16 | |
US08/491,185 | 1995-06-16 | ||
US08/508,198 | 1995-07-27 | ||
US08/508,198 US5597936A (en) | 1995-06-16 | 1995-07-27 | Method for manufacturing cobalt catalysts |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1997000263A1 true WO1997000263A1 (en) | 1997-01-03 |
Family
ID=27050331
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1996/001086 WO1997000263A1 (en) | 1995-06-16 | 1996-01-25 | Method for manufacturing cobalt catalysts |
Country Status (8)
Country | Link |
---|---|
US (1) | US5597936A (en) |
EP (1) | EP0832088B1 (en) |
JP (1) | JPH11509529A (en) |
AT (1) | ATE192453T1 (en) |
AU (1) | AU4770096A (en) |
CA (1) | CA2224462C (en) |
DE (1) | DE69608102T2 (en) |
WO (1) | WO1997000263A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010010106A1 (en) | 2008-07-23 | 2010-01-28 | Pharmaleads | Aminophosphinic derivatives that can be used in the treatment of pain |
Families Citing this family (398)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5968881A (en) * | 1995-02-02 | 1999-10-19 | The Procter & Gamble Company | Phosphate built automatic dishwashing compositions comprising catalysts |
US5877134A (en) * | 1996-09-11 | 1999-03-02 | The Procter & Gamble Company | Low foaming automatic dishwashing compositions |
AR015977A1 (en) | 1997-10-23 | 2001-05-30 | Genencor Int | PROTEASA VARIANTS MULTIPLY SUBSTITUTED WITH ALTERED NET LOAD FOR USE IN DETERGENTS |
DE19925511A1 (en) * | 1999-06-04 | 2000-12-07 | Henkel Kgaa | Production of a bleach-catalytically active combination of active ingredients |
BR0012517B1 (en) | 1999-07-16 | 2010-12-28 | laundry detergent compositions comprising zwitterionic polyamines and branched intermediate chain surfactants. | |
DE60034365D1 (en) | 1999-11-09 | 2007-05-24 | Procter & Gamble | DETERGENT FORMULATIONS WITH HYDROPHOBIC MODIFIED POLYAMINES |
US6696401B1 (en) * | 1999-11-09 | 2004-02-24 | The Procter & Gamble Company | Laundry detergent compositions comprising zwitterionic polyamines |
US6812198B2 (en) * | 1999-11-09 | 2004-11-02 | The Procter & Gamble Company | Laundry detergent compositions comprising hydrophobically modified polyamines |
JP5111718B2 (en) | 2000-10-27 | 2013-01-09 | ザ プロクター アンド ギャンブル カンパニー | Stabilized liquid composition |
US6911485B1 (en) * | 2002-04-19 | 2005-06-28 | The University Of Georgia Research Foundation, Inc. | Anionic and Lewis base photopolymerization process and its use for making optical articles |
US7169744B2 (en) | 2002-06-06 | 2007-01-30 | Procter & Gamble Company | Organic catalyst with enhanced solubility |
US7557076B2 (en) * | 2002-06-06 | 2009-07-07 | The Procter & Gamble Company | Organic catalyst with enhanced enzyme compatibility |
BR0303954A (en) * | 2002-10-10 | 2004-09-08 | Int Flavors & Fragrances Inc | Composition, fragrance, method for dividing an olfactory effective amount of fragrance into a non-rinse and non-rinse product |
US7585824B2 (en) | 2002-10-10 | 2009-09-08 | International Flavors & Fragrances Inc. | Encapsulated fragrance chemicals |
DE60327248D1 (en) * | 2002-12-18 | 2009-05-28 | Procter & Gamble | ORGANIC ACTIVATOR |
US20050113246A1 (en) * | 2003-11-06 | 2005-05-26 | The Procter & Gamble Company | Process of producing an organic catalyst |
US7985569B2 (en) | 2003-11-19 | 2011-07-26 | Danisco Us Inc. | Cellulomonas 69B4 serine protease variants |
EP1694847B1 (en) | 2003-11-19 | 2012-06-13 | Danisco US Inc. | Serine proteases, nucleic acids encoding serine enzymes and vectors and host cells incorporating same |
US7105064B2 (en) * | 2003-11-20 | 2006-09-12 | International Flavors & Fragrances Inc. | Particulate fragrance deposition on surfaces and malodour elimination from surfaces |
US20050112152A1 (en) * | 2003-11-20 | 2005-05-26 | Popplewell Lewis M. | Encapsulated materials |
US20050113282A1 (en) * | 2003-11-20 | 2005-05-26 | Parekh Prabodh P. | Melamine-formaldehyde microcapsule slurries for fabric article freshening |
MXPA06005652A (en) | 2003-12-03 | 2006-08-17 | Genencor Int | Perhydrolase. |
US8476052B2 (en) * | 2003-12-03 | 2013-07-02 | Danisco Us Inc. | Enzyme for the production of long chain peracid |
US7754460B2 (en) * | 2003-12-03 | 2010-07-13 | Danisco Us Inc. | Enzyme for the production of long chain peracid |
US20050159327A1 (en) * | 2004-01-16 | 2005-07-21 | The Procter & Gamble Company | Organic catalyst system |
US20050181969A1 (en) * | 2004-02-13 | 2005-08-18 | Mort Paul R.Iii | Active containing delivery particle |
US20070196502A1 (en) * | 2004-02-13 | 2007-08-23 | The Procter & Gamble Company | Flowable particulates |
US20050227907A1 (en) * | 2004-04-13 | 2005-10-13 | Kaiping Lee | Stable fragrance microcapsule suspension and process for using same |
US20050226900A1 (en) * | 2004-04-13 | 2005-10-13 | Winton Brooks Clint D | Skin and hair treatment composition and process for using same resulting in controllably-releasable fragrance and/or malodour counteractant evolution |
US7425527B2 (en) * | 2004-06-04 | 2008-09-16 | The Procter & Gamble Company | Organic activator |
US20050276831A1 (en) * | 2004-06-10 | 2005-12-15 | Dihora Jiten O | Benefit agent containing delivery particle |
US20050288200A1 (en) * | 2004-06-24 | 2005-12-29 | Willey Alan D | Photo Bleach Compositions |
US7419943B2 (en) | 2004-08-20 | 2008-09-02 | International Flavors & Fragrances Inc. | Methanoazuenofurans and methanoazulenone compounds and uses of these compounds as fragrance materials |
US7594594B2 (en) * | 2004-11-17 | 2009-09-29 | International Flavors & Fragrances Inc. | Multi-compartment storage and delivery containers and delivery system for microencapsulated fragrances |
US7686892B2 (en) | 2004-11-19 | 2010-03-30 | The Procter & Gamble Company | Whiteness perception compositions |
EP1661977A1 (en) * | 2004-11-29 | 2006-05-31 | The Procter & Gamble Company | Detergent compositions |
US7871972B2 (en) * | 2005-01-12 | 2011-01-18 | Amcol International Corporation | Compositions containing benefit agents pre-emulsified using colloidal cationic particles |
US7977288B2 (en) * | 2005-01-12 | 2011-07-12 | Amcol International Corporation | Compositions containing cationically surface-modified microparticulate carrier for benefit agents |
US7888306B2 (en) | 2007-05-14 | 2011-02-15 | Amcol International Corporation | Compositions containing benefit agent composites pre-emulsified using colloidal cationic particles |
WO2006076454A1 (en) * | 2005-01-12 | 2006-07-20 | Amcol International Corporation | Detersive compositions containing hydrophobic benefit agents pre-emulsified using colloidal cationic particles |
US20070207174A1 (en) * | 2005-05-06 | 2007-09-06 | Pluyter Johan G L | Encapsulated fragrance materials and methods for making same |
AR051659A1 (en) * | 2005-06-17 | 2007-01-31 | Procter & Gamble | A COMPOSITION THAT INCLUDES AN ORGANIC CATALYST WITH IMPROVED ENZYMATIC COMPATIBILITY |
PL1754781T3 (en) | 2005-08-19 | 2013-09-30 | Procter & Gamble | A solid laundry detergent composition comprising anionic detersive surfactant and a calcium-augmented technology |
US20070044824A1 (en) | 2005-09-01 | 2007-03-01 | Scott William Capeci | Processing system and method of processing |
EP1948775B1 (en) * | 2005-09-27 | 2017-01-11 | The Procter & Gamble Company | Microcapsule and method of producing same |
AU2006299783B2 (en) | 2005-10-12 | 2012-06-14 | Danisco Us Inc. | Use and production of storage-stable neutral metalloprotease |
ES2377571T3 (en) * | 2005-10-24 | 2012-03-29 | The Procter & Gamble Company | Compositions and systems for the care of tissues comprising organosilicone microemulsions and methods employing them |
US7678752B2 (en) * | 2005-10-24 | 2010-03-16 | The Procter & Gamble Company | Fabric care composition comprising organosilicone microemulsion and anionic/nitrogen-containing surfactant system |
US20070123440A1 (en) * | 2005-11-28 | 2007-05-31 | Loughnane Brian J | Stable odorant systems |
US20090311395A1 (en) * | 2005-12-09 | 2009-12-17 | Cervin Marguerite A | ACYL Transferase Useful for Decontamination |
US20070138674A1 (en) | 2005-12-15 | 2007-06-21 | Theodore James Anastasiou | Encapsulated active material with reduced formaldehyde potential |
US20070138673A1 (en) | 2005-12-15 | 2007-06-21 | Kaiping Lee | Process for Preparing a High Stability Microcapsule Product and Method for Using Same |
US20070191247A1 (en) * | 2006-01-23 | 2007-08-16 | The Procter & Gamble Company | Detergent compositions |
JP2009523903A (en) * | 2006-01-23 | 2009-06-25 | ミリケン・アンド・カンパニー | Laundry care composition having a thiazolium dye |
EP2248882A1 (en) * | 2006-01-23 | 2010-11-10 | The Procter and Gamble Company | Enzyme and fabric hueing agent containing compositions |
US20070191249A1 (en) * | 2006-01-23 | 2007-08-16 | The Procter & Gamble Company | Enzyme and photobleach containing compositions |
EP1976967A2 (en) * | 2006-01-23 | 2008-10-08 | The Procter and Gamble Company | Detergent compositions |
EP1989283A2 (en) * | 2006-02-28 | 2008-11-12 | The Procter and Gamble Company | Compositions comprising benefit agent containing delivery particles |
CN101421383B (en) * | 2006-03-02 | 2011-12-14 | 金克克国际有限公司 | surface active bleach and dynamic pH |
US20070249513A1 (en) * | 2006-04-20 | 2007-10-25 | Mort Paul R | Solid particulate laundry detergent composition comprising aesthetic particle |
US20080027575A1 (en) * | 2006-04-21 | 2008-01-31 | Jones Stevan D | Modeling systems for health and beauty consumer goods |
US7629158B2 (en) | 2006-06-16 | 2009-12-08 | The Procter & Gamble Company | Cleaning and/or treatment compositions |
US20080025960A1 (en) * | 2006-07-06 | 2008-01-31 | Manoj Kumar | Detergents with stabilized enzyme systems |
EP2046269B1 (en) | 2006-08-01 | 2010-12-15 | The Procter & Gamble Company | Benefit agent containing delivery particle |
EP2557148A1 (en) | 2006-11-22 | 2013-02-13 | Appleton Papers Inc. | Benefit agent containing delivery particle |
US7833960B2 (en) | 2006-12-15 | 2010-11-16 | International Flavors & Fragrances Inc. | Encapsulated active material containing nanoscaled material |
US20080177089A1 (en) * | 2007-01-19 | 2008-07-24 | Eugene Steven Sadlowski | Novel whitening agents for cellulosic substrates |
MX2009008576A (en) * | 2007-02-09 | 2009-08-18 | Procter & Gamble | Perfume systems. |
BRPI0807098A2 (en) * | 2007-02-15 | 2014-04-29 | Procter & Gamble | BENEFIT AGENT RELEASE COMPOSITIONS |
US20080305977A1 (en) * | 2007-06-05 | 2008-12-11 | The Procter & Gamble Company | Perfume systems |
MY157950A (en) | 2007-06-11 | 2016-08-30 | Procter & Gamble | Benefit agent containing delivery particle |
US8558051B2 (en) * | 2007-07-18 | 2013-10-15 | The Procter & Gamble Company | Disposable absorbent article having odor control system |
US8021436B2 (en) | 2007-09-27 | 2011-09-20 | The Procter & Gamble Company | Cleaning and/or treatment compositions comprising a xyloglucan conjugate |
US20090094006A1 (en) | 2007-10-03 | 2009-04-09 | William David Laidig | Modeling systems for consumer goods |
EP2205732A2 (en) | 2007-11-01 | 2010-07-14 | Danisco US Inc. | Production of thermolysin and variants thereof and use in liquid detergents |
US8198503B2 (en) * | 2007-11-19 | 2012-06-12 | The Procter & Gamble Company | Disposable absorbent articles comprising odor controlling materials |
EP2071017A1 (en) | 2007-12-04 | 2009-06-17 | The Procter and Gamble Company | Detergent composition |
WO2009087524A1 (en) * | 2008-01-04 | 2009-07-16 | The Procter & Gamble Company | Enzyme and fabric hueing agent containing compositions |
CN101910391B (en) * | 2008-01-04 | 2013-04-17 | 宝洁公司 | Laundry detergent composition comprising a glycosyl hydrolase and a benefit agent-containing delivery particle |
EP2085070A1 (en) * | 2008-01-11 | 2009-08-05 | Procter & Gamble International Operations SA. | Cleaning and/or treatment compositions |
EP2083065A1 (en) * | 2008-01-22 | 2009-07-29 | The Procter and Gamble Company | Colour-Care Composition |
EP2265702A1 (en) | 2008-02-08 | 2010-12-29 | Amcol International Corporation | Compositions containing cationically surface-modified microparticulate carrier for benefit agents |
US8048412B2 (en) * | 2008-02-11 | 2011-11-01 | Danisco Us Inc. | Enzyme with microbial lysis activity from Trichoderma reesei |
MX346974B (en) | 2008-02-14 | 2017-04-07 | Danisco Us Inc | Small enzyme-containing granules. |
US20090209447A1 (en) | 2008-02-15 | 2009-08-20 | Michelle Meek | Cleaning compositions |
EP2247275B1 (en) * | 2008-02-15 | 2017-11-29 | The Procter and Gamble Company | Delivery particle |
BRPI0909220A2 (en) * | 2008-03-26 | 2015-08-25 | Procter & Gamble | Release particle |
CA2721086A1 (en) | 2008-04-11 | 2009-10-15 | Amcol International Corporation | Multilayer fragrance encapsulation |
US8188022B2 (en) | 2008-04-11 | 2012-05-29 | Amcol International Corporation | Multilayer fragrance encapsulation comprising kappa carrageenan |
US7923426B2 (en) * | 2008-06-04 | 2011-04-12 | The Procter & Gamble Company | Detergent composition |
BRPI0913623A8 (en) | 2008-06-06 | 2017-10-03 | Danisco Us Inc | COMPOSITIONS AND METHODS COMPRISING MICROBIAL PROTEASE VARIANTS |
EP2272941B1 (en) | 2008-06-20 | 2013-08-14 | The Procter & Gamble Company | Laundry composition |
EP2135933B1 (en) | 2008-06-20 | 2013-04-03 | The Procter and Gamble Company | Laundry composition |
EP2313058B1 (en) | 2008-07-30 | 2022-09-28 | The Procter & Gamble Company | Delivery particle |
CA2731106A1 (en) | 2008-08-15 | 2010-02-18 | Jennifer Beth Ponder | Benefit compositions comprising polyglycerol esters |
EP2163606A1 (en) * | 2008-08-27 | 2010-03-17 | The Procter and Gamble Company | A detergent composition comprising gluco-oligosaccharide oxidase |
EP2166077A1 (en) | 2008-09-12 | 2010-03-24 | The Procter and Gamble Company | Particles comprising a hueing dye |
EP2163608A1 (en) * | 2008-09-12 | 2010-03-17 | The Procter & Gamble Company | Laundry particle made by extrusion comprising a hueing dye and fatty acid soap |
EP2166078B1 (en) * | 2008-09-12 | 2018-11-21 | The Procter & Gamble Company | Laundry particle made by extrusion comprising a hueing dye |
US7915215B2 (en) * | 2008-10-17 | 2011-03-29 | Appleton Papers Inc. | Fragrance-delivery composition comprising boron and persulfate ion-crosslinked polyvinyl alcohol microcapsules and method of use thereof |
MX2011004847A (en) * | 2008-11-07 | 2011-05-30 | Procter & Gamble | Benefit agent containing delivery particle. |
US8183024B2 (en) | 2008-11-11 | 2012-05-22 | Danisco Us Inc. | Compositions and methods comprising a subtilisin variant |
MX339402B (en) | 2008-11-11 | 2016-05-25 | Danisco Us Inc | Compositions and methods comprising serine protease variants. |
JP5508431B2 (en) | 2008-11-11 | 2014-05-28 | ダニスコ・ユーエス・インク | Compositions and methods comprising subtilisin variants |
JP2012508031A (en) | 2008-11-11 | 2012-04-05 | ダニスコ・ユーエス・インク | Protease containing one or more combination mutations |
BRPI0922770A2 (en) * | 2008-12-01 | 2019-09-24 | Procter & Gamble | perfume systems |
US8754028B2 (en) * | 2008-12-16 | 2014-06-17 | The Procter & Gamble Company | Perfume systems |
US20100190673A1 (en) * | 2009-01-29 | 2010-07-29 | Johan Smets | Encapsulates |
US20100190674A1 (en) * | 2009-01-29 | 2010-07-29 | Johan Smets | Encapsulates |
EP2414497A1 (en) | 2009-04-02 | 2012-02-08 | The Procter & Gamble Company | Composition comprising delivery particles |
MX2011012192A (en) * | 2009-05-15 | 2011-12-08 | Procter & Gamble | Perfume systems. |
US20100305019A1 (en) * | 2009-06-01 | 2010-12-02 | Lapinig Daniel Victoria | Hand Fabric Laundering System |
MX2011013918A (en) | 2009-06-30 | 2012-02-23 | Procter & Gamble | Fabric care compositions, process of making, and method of use. |
US20100325812A1 (en) | 2009-06-30 | 2010-12-30 | Rajan Keshav Panandiker | Rinse Added Aminosilicone Containing Compositions and Methods of Using Same |
BR112012000531A2 (en) | 2009-07-09 | 2019-09-24 | Procter & Gamble | catalytic laundry detergent composition comprising relatively low levels of water-soluble electrolyte |
WO2011005623A1 (en) | 2009-07-09 | 2011-01-13 | The Procter & Gamble Company | Laundry detergent composition comprising low level of bleach |
EP2451915A1 (en) | 2009-07-09 | 2012-05-16 | The Procter & Gamble Company | A catalytic laundry detergent composition comprising relatively low levels of water-soluble electrolyte |
EP2451925A1 (en) * | 2009-07-09 | 2012-05-16 | The Procter & Gamble Company | Method of laundering fabric using a compacted laundry detergent composition |
WO2011005804A1 (en) | 2009-07-09 | 2011-01-13 | The Procter & Gamble Company | Method of laundering fabric using a liquid laundry detergent composition |
US20110005001A1 (en) | 2009-07-09 | 2011-01-13 | Eric San Jose Robles | Detergent Composition |
WO2011016958A2 (en) | 2009-07-27 | 2011-02-10 | The Procter & Gamble Company | Detergent composition |
EP2292725B2 (en) | 2009-08-13 | 2022-08-24 | The Procter & Gamble Company | Method of laundering fabrics at low temperature |
CN102120167B (en) | 2009-09-18 | 2014-10-29 | 国际香料和香精公司 | encapsulated active material |
WO2011056934A1 (en) * | 2009-11-06 | 2011-05-12 | The Procter & Gamble Company | High efficiency capsules comprising benefit agent |
US8728790B2 (en) | 2009-12-09 | 2014-05-20 | Danisco Us Inc. | Compositions and methods comprising protease variants |
EP3434764A3 (en) | 2009-12-09 | 2019-04-03 | The Procter & Gamble Company | Fabric and home care products |
EP2512406B1 (en) | 2009-12-18 | 2018-01-24 | The Procter and Gamble Company | Perfumes and perfume encapsulates |
EP2513280A1 (en) | 2009-12-18 | 2012-10-24 | The Procter & Gamble Company | Composition comprising encapsulates, and process for making them |
EP2516612A1 (en) | 2009-12-21 | 2012-10-31 | Danisco US Inc. | Detergent compositions containing bacillus subtilis lipase and methods of use thereof |
CN102712880A (en) | 2009-12-21 | 2012-10-03 | 丹尼斯科美国公司 | Detergent compositions containing geobacillus stearothermophilus lipase and methods of use thereof |
MX2012007168A (en) | 2009-12-21 | 2012-07-23 | Danisco Us Inc | Detergent compositions containing thermobifida fusca lipase and methods of use thereof. |
US8933131B2 (en) | 2010-01-12 | 2015-01-13 | The Procter & Gamble Company | Intermediates and surfactants useful in household cleaning and personal care compositions, and methods of making the same |
BR112012018250A2 (en) | 2010-01-21 | 2019-09-24 | Procter & Gamble | process for preparing a particle |
WO2011109322A1 (en) | 2010-03-04 | 2011-09-09 | The Procter & Gamble Company | Detergent composition |
US20110243875A1 (en) | 2010-04-01 | 2011-10-06 | Rajan Keshav Panandiker | Care polymers |
EP2556139B1 (en) | 2010-04-06 | 2017-08-02 | The Procter and Gamble Company | Encapsulates |
ES2576987T3 (en) | 2010-04-06 | 2016-07-12 | The Procter & Gamble Company | Encapsulated |
EP2558573B1 (en) | 2010-04-15 | 2017-02-22 | Danisco US Inc. | Compositions and methods comprising variant proteases |
BR112012026915A2 (en) | 2010-04-19 | 2016-07-12 | Procter & Gamble Comapny | detergent composition |
US9993793B2 (en) | 2010-04-28 | 2018-06-12 | The Procter & Gamble Company | Delivery particles |
US9186642B2 (en) | 2010-04-28 | 2015-11-17 | The Procter & Gamble Company | Delivery particle |
US20110269657A1 (en) | 2010-04-28 | 2011-11-03 | Jiten Odhavji Dihora | Delivery particles |
DK2566960T3 (en) | 2010-05-06 | 2017-05-22 | Procter & Gamble | CONSUMER PRODUCTS WITH PROTEASE VARIETIES |
US8536108B2 (en) | 2010-05-12 | 2013-09-17 | The Procter & Gamble Company | Care polymers |
BR112012029133A2 (en) | 2010-05-18 | 2016-09-13 | Milliken & Co | optical brighteners and compositions comprising the same |
US8262743B2 (en) | 2010-05-18 | 2012-09-11 | Milliken & Company | Optical brighteners and compositions comprising the same |
BR112012030525A2 (en) | 2010-05-26 | 2016-08-09 | Procter & Gamble | encapsulated |
US8476216B2 (en) | 2010-05-28 | 2013-07-02 | Milliken & Company | Colored speckles having delayed release properties |
AR081423A1 (en) | 2010-05-28 | 2012-08-29 | Danisco Us Inc | DETERGENT COMPOSITIONS WITH STREPTOMYCES GRISEUS LIPASE CONTENT AND METHODS TO USE THEM |
PL2585569T3 (en) | 2010-06-22 | 2017-03-31 | The Procter And Gamble Company | Perfume systems |
CA2799484C (en) | 2010-06-22 | 2016-02-02 | The Procter & Gamble Company | Perfume systems |
MX339494B (en) | 2010-06-30 | 2016-05-26 | Procter & Gamble | Rinse added aminosilicone containing compositions and methods of using same. |
RU2543892C2 (en) | 2010-07-02 | 2015-03-10 | Дзе Проктер Энд Гэмбл Компани | Production of films from nonwoven webs |
WO2012003367A2 (en) | 2010-07-02 | 2012-01-05 | The Procter & Gamble Company | Method for delivering an active agent |
WO2012003300A2 (en) | 2010-07-02 | 2012-01-05 | The Procter & Gamble Company | Filaments comprising a non-perfume active agent nonwoven webs and methods for making same |
CN103003476B (en) | 2010-07-02 | 2016-02-10 | 宝洁公司 | Web material and the method for the manufacture of web material |
JP5859526B2 (en) | 2010-07-02 | 2016-02-10 | ザ プロクター アンド ギャンブルカンパニー | Filaments containing an activator nonwoven web and methods for making the same |
US8765651B2 (en) | 2010-07-15 | 2014-07-01 | The Procter & Gamble Company | Method of cleansing hair |
WO2012009660A2 (en) | 2010-07-15 | 2012-01-19 | The Procter & Gamble Company | Detergent compositions comprising microbially produced fatty alcohols and derivatives thereof |
CN103003407B (en) | 2010-07-20 | 2017-09-05 | 宝洁公司 | Particle with multiple coatings |
AR083328A1 (en) | 2010-07-20 | 2013-02-21 | Procter & Gamble | SUPPLY PARTICLE |
EP2619271B1 (en) | 2010-09-20 | 2018-05-16 | The Procter and Gamble Company | Non-fluoropolymer surface protection composition |
JP2013538282A (en) | 2010-09-20 | 2013-10-10 | ザ プロクター アンド ギャンブル カンパニー | Non-fluoropolymer surface protection composition |
EP2619299B1 (en) | 2010-09-20 | 2018-02-28 | Wacker Chemie AG | Fabric care formulations and methods |
WO2011026154A2 (en) | 2010-10-29 | 2011-03-03 | The Procter & Gamble Company | Cleaning and/or treatment compositions |
WO2012057781A1 (en) | 2010-10-29 | 2012-05-03 | The Procter & Gamble Company | Cleaning and/or treatment compositions comprising a fungal serine protease |
US8715368B2 (en) | 2010-11-12 | 2014-05-06 | The Procter & Gamble Company | Thiophene azo dyes and laundry care compositions containing the same |
EP2468239B1 (en) | 2010-12-21 | 2013-09-18 | Procter & Gamble International Operations SA | Encapsulates |
CN103380204B (en) | 2011-02-17 | 2016-02-03 | 宝洁公司 | Comprise the composition of the mixture of C10-C13 alkyl benzene sulfonate |
WO2012112828A1 (en) | 2011-02-17 | 2012-08-23 | The Procter & Gamble Company | Bio-based linear alkylphenyl sulfonates |
WO2012116021A1 (en) | 2011-02-25 | 2012-08-30 | Milliken & Company | Capsules and compositions comprising the same |
ES2919933T3 (en) | 2011-03-18 | 2022-07-29 | Int Flavors & Fragrances Inc | Microcapsules produced from combined sol-gel precursors and production method thereof |
JP6283607B2 (en) | 2011-04-07 | 2018-02-21 | ザ プロクター アンド ギャンブル カンパニー | Personal cleansing composition with increased deposition of polyacrylate microcapsules |
CN103458858B (en) | 2011-04-07 | 2016-04-27 | 宝洁公司 | There is the shampoo Compositions of the deposition of the polyacrylate microcapsule of enhancing |
US8980292B2 (en) | 2011-04-07 | 2015-03-17 | The Procter & Gamble Company | Conditioner compositions with increased deposition of polyacrylate microcapsules |
WO2012142087A1 (en) | 2011-04-12 | 2012-10-18 | The Procter & Gamble Company | Metal bleach catalysts |
EP2702072A1 (en) | 2011-04-29 | 2014-03-05 | Danisco US Inc. | Detergent compositions containing bacillus agaradhaerens mannanase and methods of use thereof |
US20140073548A1 (en) | 2011-04-29 | 2014-03-13 | Danisco Us Inc. | Detergent compositions containing bacillus sp. mannanase and methods of use thereof |
EP2712363A1 (en) | 2011-04-29 | 2014-04-02 | Danisco US Inc. | Detergent compositions containing geobacillus tepidamans mannanase and methods of use thereof |
MX357386B (en) | 2011-05-05 | 2018-07-06 | Procter & Gamble | Compositions and methods comprising serine protease variants. |
AR086281A1 (en) | 2011-05-05 | 2013-12-04 | Danisco Us Inc | COMPOSITIONS AND METHODS THAT INCLUDE VARIANTS OF SERINA PROTEASAS |
US20140371435A9 (en) | 2011-06-03 | 2014-12-18 | Eduardo Torres | Laundry Care Compositions Containing Thiophene Azo Dyes |
EP2537918A1 (en) | 2011-06-20 | 2012-12-26 | The Procter & Gamble Company | Consumer products with lipase comprising coated particles |
US10829721B2 (en) | 2011-06-20 | 2020-11-10 | Novozymes A/S | Particulate composition |
EP2723841B1 (en) | 2011-06-23 | 2017-01-04 | The Procter and Gamble Company | Perfume systems |
MX2013015187A (en) | 2011-06-27 | 2014-02-17 | Procter & Gamble | Stable polymer containing two phase systems. |
WO2013002786A1 (en) | 2011-06-29 | 2013-01-03 | Solae | Baked food compositions comprising soy whey proteins that have been isolated from processing streams |
MX347260B (en) | 2011-08-10 | 2017-04-20 | Procter & Gamble | Encapsulates. |
CN103781903A (en) | 2011-08-31 | 2014-05-07 | 丹尼斯科美国公司 | Compositions and methods comprising a lipolytic enzyme variant |
EP2756065B1 (en) | 2011-09-13 | 2018-10-24 | The Procter and Gamble Company | Encapsulates |
CN103797102A (en) | 2011-09-20 | 2014-05-14 | 宝洁公司 | Detergent compositions comprising sustainable surfactant systems comprising isoprenoid-derived surfactants |
CA2849478A1 (en) | 2011-09-20 | 2013-03-28 | The Procter & Gamble Company | Detergent compositions comprising primary surfactant systems comprising highly branched surfactants especially isoprenoid - based surfactants |
WO2013043855A2 (en) | 2011-09-20 | 2013-03-28 | The Procter & Gamble Company | High suds detergent compositions comprising isoprenoid-based surfactants |
CN103827280A (en) | 2011-09-20 | 2014-05-28 | 宝洁公司 | Detergent compositions comprising specific blend ratios of isoprenoid-based surfactants |
WO2013043852A2 (en) | 2011-09-20 | 2013-03-28 | The Procter & Gamble Company | Easy-rinse detergent compositions comprising isoprenoid-based surfactants |
EP2581438A1 (en) | 2011-10-12 | 2013-04-17 | The Procter and Gamble Company | Detergent composition |
US20130118531A1 (en) | 2011-11-11 | 2013-05-16 | The Procter & Gamble Company | Emulsions containing polymeric cationic emulsifiers, substance and process |
CN104023705B (en) | 2011-11-11 | 2017-02-15 | 巴斯夫欧洲公司 | Self-emulsifiable |
WO2013096653A1 (en) | 2011-12-22 | 2013-06-27 | Danisco Us Inc. | Compositions and methods comprising a lipolytic enzyme variant |
MX353496B (en) | 2012-01-04 | 2018-01-16 | Procter & Gamble | Active containing fibrous structures with multiple regions. |
CN104039945B (en) | 2012-01-04 | 2017-03-15 | 宝洁公司 | There is the fibre structure containing active substance in multiple regions of different densities |
CN104040061B (en) | 2012-01-04 | 2019-11-08 | 宝洁公司 | Fibre structure and its manufacturing method comprising particle |
BR112014017513A8 (en) | 2012-01-18 | 2017-07-04 | Procter & Gamble | perfume systems |
MX353896B (en) | 2012-02-03 | 2018-02-01 | Procter & Gamble | Compositions and methods for surface treatment with lipases. |
ES2794644T3 (en) | 2012-02-03 | 2020-11-18 | Novozymes As | Lipase variants and polynucleotides that encode them |
CA2867361C (en) | 2012-03-19 | 2017-07-25 | Milliken & Company | Carboxylate dyes |
EP2831214B1 (en) | 2012-03-26 | 2016-03-23 | The Procter and Gamble Company | Cleaning compositions comprising ph-switchable amine surfactants |
WO2013149858A1 (en) | 2012-04-02 | 2013-10-10 | Novozymes A/S | Lipase variants and polynucleotides encoding same |
JP2015525248A (en) | 2012-05-16 | 2015-09-03 | ノボザイムス アクティーゼルスカブ | Composition comprising lipase and method of use thereof |
EP2674475A1 (en) | 2012-06-11 | 2013-12-18 | The Procter & Gamble Company | Detergent composition |
CN104471048B (en) | 2012-07-12 | 2018-11-16 | 诺维信公司 | Polypeptide with lipase active and the polynucleotides for encoding it |
EP2877562B1 (en) | 2012-07-26 | 2018-04-25 | The Procter and Gamble Company | Low ph liquid cleaning compositions with enzymes |
US9796952B2 (en) | 2012-09-25 | 2017-10-24 | The Procter & Gamble Company | Laundry care compositions with thiazolium dye |
EP2712915A1 (en) | 2012-10-01 | 2014-04-02 | The Procter and Gamble Company | Methods of treating a surface and compositions for use therein |
CN105026541A (en) | 2012-10-04 | 2015-11-04 | 艺康美国股份有限公司 | Pre-soak technology for laundry and other hard surface cleaning |
KR20150067336A (en) | 2012-10-12 | 2015-06-17 | 다니스코 유에스 인크. | Compositions and methods comprising a lipolytic enzyme variant |
CA2888341A1 (en) | 2012-10-24 | 2014-05-01 | The Procter & Gamble Company | Anti foam compositions comprising aryl bearing polyorganosilicons |
US9133421B2 (en) | 2012-10-24 | 2015-09-15 | The Procter & Gamble Company | Compositions comprising anti-foams |
EP2914720B1 (en) | 2012-11-05 | 2022-08-31 | Danisco US Inc. | Compositions and methods comprising thermolysin protease variants |
US9303232B2 (en) | 2012-12-06 | 2016-04-05 | The Procter & Gamble Company | Perfume systems |
US20140161741A1 (en) | 2012-12-06 | 2014-06-12 | The Procter & Gamble Company | Perfume systems |
WO2014093747A2 (en) | 2012-12-14 | 2014-06-19 | The Procter & Gamble Company | Antiperspirant and deodorant compositions |
EP2935573A1 (en) | 2012-12-19 | 2015-10-28 | Danisco US Inc. | Novel mannanase, compositions and methods of use thereof |
JP6251296B2 (en) | 2013-03-05 | 2017-12-20 | ザ プロクター アンド ギャンブル カンパニー | Mixed sugar composition |
MX360759B (en) | 2013-03-21 | 2018-11-15 | Novozymes As | Polypeptides with lipase activity and polynucleotides encoding same. |
AU2014241193B2 (en) | 2013-03-28 | 2016-10-20 | The Procter And Gamble Company | Cleaning compositions containing a polyetheramine |
US9340757B2 (en) | 2013-04-18 | 2016-05-17 | The Procter & Gamble Company | Fragrance materials |
CN105209612A (en) | 2013-05-14 | 2015-12-30 | 诺维信公司 | Detergent compositions |
EP2806018A1 (en) | 2013-05-20 | 2014-11-26 | The Procter & Gamble Company | Encapsulates |
US20140338134A1 (en) | 2013-05-20 | 2014-11-20 | The Procter & Gamble Company | Encapsulates |
EP3699256A1 (en) | 2013-05-28 | 2020-08-26 | The Procter & Gamble Company | Surface treatment compositions comprising photochromic dyes |
WO2014194032A1 (en) | 2013-05-29 | 2014-12-04 | Danisco Us Inc. | Novel metalloproteases |
CN105492603B (en) | 2013-05-29 | 2022-06-03 | 丹尼斯科美国公司 | Novel metalloproteases |
JP6367930B2 (en) | 2013-05-29 | 2018-08-01 | ダニスコ・ユーエス・インク | Novel metalloprotease |
EP3260538B1 (en) | 2013-05-29 | 2021-04-14 | Danisco US Inc. | Novel metalloproteases |
EP3019603A1 (en) | 2013-07-09 | 2016-05-18 | Novozymes A/S | Polypeptides with lipase activity and polynucleotides encoding same |
US20160160197A1 (en) | 2013-07-19 | 2016-06-09 | Danisco Us Inc. | Compositions and Methods Comprising a Lipolytic Enzyme Variant |
CN103408118A (en) * | 2013-08-05 | 2013-11-27 | 东华大学 | Method of treating printing and dyeing wastewater through flocculation oxidation |
BR112016003137B1 (en) | 2013-08-15 | 2020-10-27 | International Flavors & Fragrances Inc | polyurea capsule composition, method for preparing a polyurea capsule composition and, consumer product |
BR112016005286A2 (en) | 2013-09-12 | 2017-09-12 | Danisco Us Inc | compositions and methods comprising lg12 clade protease variants |
JP6185182B2 (en) | 2013-09-18 | 2017-08-23 | ザ プロクター アンド ギャンブル カンパニー | Laundry care composition containing a thiophene azocarboxylate dye |
CN105555935A (en) | 2013-09-18 | 2016-05-04 | 宝洁公司 | Laundry care composition comprising carboxylate dye |
US9834682B2 (en) | 2013-09-18 | 2017-12-05 | Milliken & Company | Laundry care composition comprising carboxylate dye |
CN105555936A (en) | 2013-09-18 | 2016-05-04 | 宝洁公司 | Laundry care composition comprising carboxylate dye |
US9610228B2 (en) | 2013-10-11 | 2017-04-04 | International Flavors & Fragrances Inc. | Terpolymer-coated polymer encapsulated active material |
EP2862597B1 (en) | 2013-10-18 | 2018-01-03 | International Flavors & Fragrances Inc. | Stable, flowable silica capsule formulation |
CN109536316A (en) | 2013-11-11 | 2019-03-29 | 国际香料和香精公司 | More capsule compositions |
MX2016007157A (en) | 2013-12-09 | 2016-07-21 | Procter & Gamble | Fibrous structures including an active agent and having a graphic printed thereon. |
CN106029881B (en) | 2013-12-13 | 2023-01-10 | 丹尼斯科美国公司 | Serine proteases of the bacillus gibsonii-clade |
ES2723948T3 (en) | 2013-12-13 | 2019-09-04 | Danisco Us Inc | Serine proteases from Bacillus species |
EP3097175B1 (en) | 2014-01-22 | 2018-10-17 | The Procter and Gamble Company | Fabric treatment composition |
WO2015109972A1 (en) | 2014-01-22 | 2015-07-30 | Novozymes A/S | Polypeptides with lipase activity and polynucleotides encoding same |
EP3097174A1 (en) | 2014-01-22 | 2016-11-30 | The Procter & Gamble Company | Method of treating textile fabrics |
EP3097172A1 (en) | 2014-01-22 | 2016-11-30 | The Procter & Gamble Company | Method of treating textile fabrics |
WO2015112339A1 (en) | 2014-01-22 | 2015-07-30 | The Procter & Gamble Company | Fabric treatment composition |
WO2015138576A1 (en) | 2014-03-12 | 2015-09-17 | The Procter & Gamble Company | Detergent composition |
US10155935B2 (en) | 2014-03-12 | 2018-12-18 | Novozymes A/S | Polypeptides with lipase activity and polynucleotides encoding same |
JP6585698B2 (en) | 2014-03-21 | 2019-10-02 | ダニスコ・ユーエス・インク | Serine protease of Bacillus species |
EP3122847B1 (en) | 2014-03-26 | 2019-05-15 | The Procter and Gamble Company | Perfume systems |
EP3122850A1 (en) | 2014-03-27 | 2017-02-01 | The Procter & Gamble Company | Cleaning compositions containing a polyetheramine |
JP6275864B2 (en) | 2014-03-27 | 2018-02-07 | ザ プロクター アンド ギャンブル カンパニー | Cleaning composition containing polyetheramine |
EP3131921B1 (en) | 2014-04-15 | 2020-06-10 | Novozymes A/S | Polypeptides with lipase activity and polynucleotides encoding same |
EP3139902A2 (en) | 2014-05-06 | 2017-03-15 | The Procter & Gamble Company | Fragrance compositions |
EP3140384B1 (en) | 2014-05-06 | 2024-02-14 | Milliken & Company | Laundry care compositions |
CN106459937A (en) | 2014-05-27 | 2017-02-22 | 诺维信公司 | Methods for producing lipases |
EP3760713A3 (en) | 2014-05-27 | 2021-03-31 | Novozymes A/S | Lipase variants and polynucleotides encoding same |
EP3152288A1 (en) | 2014-06-06 | 2017-04-12 | The Procter & Gamble Company | Detergent composition comprising polyalkyleneimine polymers |
EP3197424A1 (en) | 2014-09-26 | 2017-08-02 | The Procter & Gamble Company | Freshening compositions and devices comprising same |
DK3207129T3 (en) | 2014-10-17 | 2020-02-24 | Danisco Us Inc | SERIN PROTEAS OF THE BACILLUS ART |
CN107148472A (en) | 2014-10-27 | 2017-09-08 | 丹尼斯科美国公司 | The serine protease of Bacillus spec |
EP3212783A1 (en) | 2014-10-27 | 2017-09-06 | Danisco US Inc. | Serine proteases |
US20170335306A1 (en) | 2014-10-27 | 2017-11-23 | Danisco Us Inc. | Serine proteases |
EP3212782B1 (en) | 2014-10-27 | 2019-04-17 | Danisco US Inc. | Serine proteases |
WO2016069552A1 (en) | 2014-10-27 | 2016-05-06 | Danisco Us Inc. | Serine proteases |
WO2016081437A1 (en) | 2014-11-17 | 2016-05-26 | The Procter & Gamble Company | Benefit agent delivery compositions |
MX2017007103A (en) | 2014-12-05 | 2017-08-24 | Novozymes As | Lipase variants and polynucleotides encoding same. |
US20160230124A1 (en) | 2015-02-10 | 2016-08-11 | The Procter & Gamble Company | Liquid laundry cleaning composition |
US9499770B2 (en) | 2015-03-10 | 2016-11-22 | The Procter & Gamble Company | Freshening compositions resisting scent habituation |
EP3611259A1 (en) | 2015-03-12 | 2020-02-19 | Danisco US Inc. | Compositions and methods comprising lg12-clade protease variants |
WO2016172699A1 (en) | 2015-04-24 | 2016-10-27 | International Flavors & Fragrances Inc. | Delivery systems and methods of preparing the same |
DK3088503T3 (en) | 2015-04-29 | 2018-08-20 | Procter & Gamble | PROCEDURE FOR TREATING A TEXTILE SUBSTANCE |
CN107548415A (en) | 2015-04-29 | 2018-01-05 | 宝洁公司 | The method of laundering of textile fabrics |
DK3088506T3 (en) | 2015-04-29 | 2018-08-13 | Procter & Gamble | detergent |
CN107624127A (en) | 2015-04-29 | 2018-01-23 | 宝洁公司 | The method for handling fabric |
DK3088502T3 (en) | 2015-04-29 | 2018-08-13 | Procter & Gamble | PROCEDURE FOR TREATING A TEXTILE SUBSTANCE |
JP6866302B2 (en) | 2015-05-04 | 2021-04-28 | ミリケン・アンド・カンパニーMilliken & Company | Leukotriphenylmethane dye as a bluish agent in laundry care compositions |
WO2016184944A1 (en) | 2015-05-19 | 2016-11-24 | Novozymes A/S | Odor reduction |
US10226544B2 (en) | 2015-06-05 | 2019-03-12 | International Flavors & Fragrances Inc. | Malodor counteracting compositions |
WO2016202739A1 (en) | 2015-06-16 | 2016-12-22 | Novozymes A/S | Polypeptides with lipase activity and polynucleotides encoding same |
WO2016205008A1 (en) | 2015-06-19 | 2016-12-22 | The Procter & Gamble Company | Computer-implemeted method of making perfumed goods |
CA2987160C (en) | 2015-07-01 | 2022-12-13 | Novozymes A/S | Methods of reducing odor |
CN107969136B (en) | 2015-07-06 | 2021-12-21 | 诺维信公司 | Lipase variants and polynucleotides encoding same |
US10155868B2 (en) | 2015-10-13 | 2018-12-18 | Milliken & Company | Whitening agents for cellulosic substrates |
US9976035B2 (en) | 2015-10-13 | 2018-05-22 | Milliken & Company | Whitening agents for cellulosic substrates |
US9745544B2 (en) | 2015-10-13 | 2017-08-29 | The Procter & Gamble Company | Whitening agents for cellulosic substrates |
US10597614B2 (en) | 2015-10-13 | 2020-03-24 | The Procter & Gamble Company | Whitening agents for cellulosic substrates |
US9902923B2 (en) | 2015-10-13 | 2018-02-27 | The Procter & Gamble Company | Polyglycerol dye whitening agents for cellulosic substrates |
US9777250B2 (en) | 2015-10-13 | 2017-10-03 | Milliken & Company | Whitening agents for cellulosic substrates |
CN109072208A (en) | 2015-11-05 | 2018-12-21 | 丹尼斯科美国公司 | Series bacillus species mannase |
CN108603183B (en) | 2015-11-05 | 2023-11-03 | 丹尼斯科美国公司 | Paenibacillus species and bacillus species mannanases |
EP3173467A1 (en) | 2015-11-26 | 2017-05-31 | The Procter & Gamble Company | Cleaning compositions comprising enzymes |
WO2017093318A1 (en) | 2015-12-01 | 2017-06-08 | Novozymes A/S | Methods for producing lipases |
US10308900B2 (en) | 2015-12-22 | 2019-06-04 | Milliken & Company | Occult particles for use in granular laundry care compositions |
US20170204223A1 (en) | 2016-01-15 | 2017-07-20 | International Flavors & Fragrances Inc. | Polyalkoxy-polyimine adducts for use in delayed release of fragrance ingredients |
WO2017143174A1 (en) | 2016-02-18 | 2017-08-24 | International Flavors & Fragrances Inc. | Polyurea capsule compositions |
EP3432856A1 (en) | 2016-03-24 | 2019-01-30 | The Procter and Gamble Company | Hair care compositions comprising malodor reduction compositions |
WO2017192692A1 (en) | 2016-05-03 | 2017-11-09 | Danisco Us Inc | Protease variants and uses thereof |
US20190136218A1 (en) | 2016-05-05 | 2019-05-09 | Danisco Us Inc | Protease variants and uses thereof |
JP2019523645A (en) | 2016-05-31 | 2019-08-29 | ダニスコ・ユーエス・インク | Protease variants and uses thereof |
CA3027745A1 (en) | 2016-06-17 | 2017-12-21 | Danisco Us Inc. | Protease variants and uses thereof |
EP4357453A2 (en) | 2016-07-18 | 2024-04-24 | Novozymes A/S | Lipase variants, polynucleotides encoding same and the use thereof |
EP4209264A1 (en) | 2016-09-16 | 2023-07-12 | International Flavors & Fragrances Inc. | Microcapsule compositions stabilized with viscosity control agents |
US20180085291A1 (en) | 2016-09-28 | 2018-03-29 | International Flavors & Fragrances Inc. | Microcapsule compositions containing amino silicone |
WO2018085390A1 (en) | 2016-11-01 | 2018-05-11 | Milliken & Company | Leuco colorants as bluing agents in laundry care compositions |
JP6790257B2 (en) | 2016-11-01 | 2020-11-25 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | Leuco colorants as bluish agents in laundry care compositions, their packaging, kits and methods |
CA3038855A1 (en) | 2016-11-01 | 2018-05-11 | The Procter & Gamble Company | Leuco colorants as bluing agents in laundry care compositions |
US20180119056A1 (en) | 2016-11-03 | 2018-05-03 | Milliken & Company | Leuco Triphenylmethane Colorants As Bluing Agents in Laundry Care Compositions |
US20190264138A1 (en) | 2016-11-07 | 2019-08-29 | Danisco Us Inc. | Laundry detergent composition |
US10577571B2 (en) | 2016-11-08 | 2020-03-03 | Ecolab Usa Inc. | Non-aqueous cleaner for vegetable oil soils |
CN110312794B (en) | 2016-12-21 | 2024-04-12 | 丹尼斯科美国公司 | Bacillus gibsonii clade serine protease |
CA3046690A1 (en) | 2017-01-27 | 2018-08-02 | The Procter & Gamble Company | Active agent-containing articles that exhibit consumer acceptable article in-use properties |
US11697905B2 (en) | 2017-01-27 | 2023-07-11 | The Procter & Gamble Company | Active agent-containing articles that exhibit consumer acceptable article in-use properties |
US11697904B2 (en) | 2017-01-27 | 2023-07-11 | The Procter & Gamble Company | Active agent-containing articles that exhibit consumer acceptable article in-use properties |
US11697906B2 (en) | 2017-01-27 | 2023-07-11 | The Procter & Gamble Company | Active agent-containing articles and product-shipping assemblies for containing the same |
WO2018202846A1 (en) | 2017-05-05 | 2018-11-08 | Novozymes A/S | Compositions comprising lipase and sulfite |
US20180362892A1 (en) | 2017-06-20 | 2018-12-20 | The Procter & Gamble Company | Systems comprising a bleaching agent and encapsulates |
US11332725B2 (en) | 2017-09-27 | 2022-05-17 | Novozymes A/S | Lipase variants and microcapsule compositions comprising such lipase variants |
US11607373B2 (en) | 2017-10-10 | 2023-03-21 | The Procter & Gamble Company | Sulfate free clear personal cleansing composition comprising low inorganic salt |
MX2020003103A (en) | 2017-10-12 | 2020-07-28 | Procter & Gamble | Leuco colorants as bluing agents in laundry care composition. |
TWI715878B (en) | 2017-10-12 | 2021-01-11 | 美商美力肯及公司 | Leuco colorants and compositions |
WO2019075148A1 (en) | 2017-10-12 | 2019-04-18 | The Procter & Gamble Company | Leuco colorants as bluing agents in laundry care compositions |
BR112020006988A2 (en) | 2017-10-12 | 2020-10-06 | The Procter & Gamble Company | white dyes in combination with a second bleaching agent as bleaching agents in laundry care compositions |
EP3704193A1 (en) | 2017-11-01 | 2020-09-09 | Milliken & Company | Leuco compounds, colorant compounds, and compositions containing the same |
US11725197B2 (en) | 2017-12-04 | 2023-08-15 | Novozymes A/S | Lipase variants and polynucleotides encoding same |
BR112020011278A2 (en) | 2017-12-08 | 2020-11-17 | Novozymes A/S | alpha-amylase variant, composition, polynucleotide, nucleic acid construct, expression vector, host cell, methods for producing an alpha-amylase variant and for increasing the stability of a parent alpha-amylase, use of the variant, and, process for producing a syrup from material containing starch |
US10792384B2 (en) | 2017-12-15 | 2020-10-06 | The Procter & Gamble Company | Rolled fibrous structures comprising encapsulated malodor reduction compositions |
US20210071156A1 (en) | 2018-02-08 | 2021-03-11 | Novozymes A/S | Lipase Variants and Compositions Thereof |
EP3749761A1 (en) | 2018-02-08 | 2020-12-16 | Novozymes A/S | Lipases, lipase variants and compositions thereof |
US20210214703A1 (en) | 2018-06-19 | 2021-07-15 | Danisco Us Inc | Subtilisin variants |
WO2019245705A1 (en) | 2018-06-19 | 2019-12-26 | Danisco Us Inc | Subtilisin variants |
EP3844255A1 (en) | 2018-08-30 | 2021-07-07 | Danisco US Inc. | Enzyme-containing granules |
EP3833731A1 (en) | 2018-08-30 | 2021-06-16 | Danisco US Inc. | Compositions comprising a lipolytic enzyme variant and methods of use thereof |
CN113166682A (en) | 2018-09-27 | 2021-07-23 | 丹尼斯科美国公司 | Composition for cleaning medical instruments |
US11518963B2 (en) | 2018-10-18 | 2022-12-06 | Milliken & Company | Polyethyleneimine compounds containing N-halamine and derivatives thereof |
US20200123475A1 (en) | 2018-10-18 | 2020-04-23 | Milliken & Company | Polyethyleneimine compounds containing n-halamine and derivatives thereof |
US20200123319A1 (en) | 2018-10-18 | 2020-04-23 | Milliken & Company | Polyethyleneimine compounds containing n-halamine and derivatives thereof |
US11466122B2 (en) | 2018-10-18 | 2022-10-11 | Milliken & Company | Polyethyleneimine compounds containing N-halamine and derivatives thereof |
US20200123472A1 (en) | 2018-10-18 | 2020-04-23 | Milliken & Company | Polyethyleneimine compounds containing n-halamine and derivatives thereof |
US11299591B2 (en) | 2018-10-18 | 2022-04-12 | Milliken & Company | Polyethyleneimine compounds containing N-halamine and derivatives thereof |
US11732218B2 (en) | 2018-10-18 | 2023-08-22 | Milliken & Company | Polyethyleneimine compounds containing N-halamine and derivatives thereof |
WO2020123889A1 (en) | 2018-12-14 | 2020-06-18 | The Procter & Gamble Company | Foaming fibrous structures comprising particles and methods for making same |
EP3897522A4 (en) | 2018-12-18 | 2023-03-22 | International Flavors & Fragrances Inc. | Microcapsule compositions |
CN114174504A (en) | 2019-05-24 | 2022-03-11 | 丹尼斯科美国公司 | Subtilisin variants and methods of use |
EP3980517A1 (en) | 2019-06-06 | 2022-04-13 | Danisco US Inc. | Methods and compositions for cleaning |
EP3994255A1 (en) | 2019-07-02 | 2022-05-11 | Novozymes A/S | Lipase variants and compositions thereof |
US11485934B2 (en) | 2019-08-02 | 2022-11-01 | The Procter & Gamble Company | Foaming compositions for producing a stable foam and methods for making same |
US11873465B2 (en) | 2019-08-14 | 2024-01-16 | Ecolab Usa Inc. | Methods of cleaning and soil release of highly oil absorbing substrates employing optimized extended chain nonionic surfactants |
WO2021037878A1 (en) | 2019-08-27 | 2021-03-04 | Novozymes A/S | Composition comprising a lipase |
US20210148044A1 (en) | 2019-11-15 | 2021-05-20 | The Procter & Gamble Company | Graphic-Containing Soluble Articles and Methods for Making Same |
US20230049452A1 (en) | 2020-01-13 | 2023-02-16 | Danisco Us Inc | Compositions comprising a lipolytic enzyme variant and methods of use thereof |
US11679065B2 (en) | 2020-02-27 | 2023-06-20 | The Procter & Gamble Company | Compositions with sulfur having enhanced efficacy and aesthetics |
US11718814B2 (en) | 2020-03-02 | 2023-08-08 | Milliken & Company | Composition comprising hueing agent |
US20210277335A1 (en) | 2020-03-02 | 2021-09-09 | Milliken & Company | Composition Comprising Hueing Agent |
US20210269747A1 (en) | 2020-03-02 | 2021-09-02 | Milliken & Company | Composition Comprising Hueing Agent |
CA3173147A1 (en) | 2020-06-05 | 2021-12-09 | Phillip Kyle Vinson | Detergent compositions containing a branched surfactant |
US20220002636A1 (en) | 2020-07-06 | 2022-01-06 | Ecolab Usa Inc. | Peg-modified castor oil based compositions for microemulsifying and removing multiple oily soils |
AU2021306707A1 (en) | 2020-07-06 | 2023-02-09 | Ecolab Usa Inc. | Foaming mixed alcohol/water compositions comprising a structured alkoxylated siloxane |
US20220000757A1 (en) | 2020-07-06 | 2022-01-06 | Ecolab Usa Inc. | Foaming mixed alcohol/water compositions comprising a combination of alkyl siloxane and a hydrotrope/solubilizer |
EP4204553A1 (en) | 2020-08-27 | 2023-07-05 | Danisco US Inc. | Enzymes and enzyme compositions for cleaning |
US20220079862A1 (en) | 2020-09-14 | 2022-03-17 | Milliken & Company | Hair care composition containing polymeric colorant |
US11351106B2 (en) | 2020-09-14 | 2022-06-07 | Milliken & Company | Oxidative hair cream composition containing thiophene azo colorant |
US11344492B2 (en) | 2020-09-14 | 2022-05-31 | Milliken & Company | Oxidative hair cream composition containing polymeric colorant |
EP4237498A1 (en) | 2020-10-27 | 2023-09-06 | Milliken & Company | Compositions comprising leuco compounds and colorants |
BR112023008326A2 (en) | 2020-10-29 | 2023-12-12 | Novozymes As | LIPASE VARIANTS AND COMPOSITIONS COMPRISING SUCH LIPASE VARIANTS |
CN116670261A (en) | 2020-11-13 | 2023-08-29 | 诺维信公司 | Detergent compositions comprising lipase |
MX2023005963A (en) | 2020-12-04 | 2023-06-07 | Procter & Gamble | Hair care compositions comprising malodor reduction materials. |
US20240117275A1 (en) | 2021-01-29 | 2024-04-11 | Danisco Us Inc. | Compositions for cleaning and methods related thereto |
WO2022197295A1 (en) | 2021-03-17 | 2022-09-22 | Milliken & Company | Polymeric colorants with reduced staining |
US11771635B2 (en) | 2021-05-14 | 2023-10-03 | The Procter & Gamble Company | Shampoo composition |
US20220403558A1 (en) | 2021-05-28 | 2022-12-22 | The Procter & Gamble Company | Natural polymer-based fibrous elements comprising a surfactant and methods for making same |
CN117616120A (en) | 2021-06-30 | 2024-02-27 | 丹尼斯科美国公司 | Variant lipases and uses thereof |
EP4124383A1 (en) | 2021-07-27 | 2023-02-01 | International Flavors & Fragrances Inc. | Biodegradable microcapsules |
CN117916354A (en) | 2021-09-03 | 2024-04-19 | 丹尼斯科美国公司 | Laundry compositions for cleaning |
WO2023039270A2 (en) | 2021-09-13 | 2023-03-16 | Danisco Us Inc. | Bioactive-containing granules |
EP4154974A1 (en) | 2021-09-23 | 2023-03-29 | International Flavors & Fragrances Inc. | Biodegradable microcapsules |
EP4194537A1 (en) | 2021-12-08 | 2023-06-14 | The Procter & Gamble Company | Laundry treatment cartridge |
EP4194536A1 (en) | 2021-12-08 | 2023-06-14 | The Procter & Gamble Company | Laundry treatment cartridge |
WO2023114939A2 (en) | 2021-12-16 | 2023-06-22 | Danisco Us Inc. | Subtilisin variants and methods of use |
WO2023114936A2 (en) | 2021-12-16 | 2023-06-22 | Danisco Us Inc. | Subtilisin variants and methods of use |
WO2023116569A1 (en) | 2021-12-21 | 2023-06-29 | Novozymes A/S | Composition comprising a lipase and a booster |
EP4212239A1 (en) | 2022-01-14 | 2023-07-19 | International Flavors & Fragrances Inc. | Biodegradable prepolymer microcapsules |
WO2023168234A1 (en) | 2022-03-01 | 2023-09-07 | Danisco Us Inc. | Enzymes and enzyme compositions for cleaning |
WO2023250301A1 (en) | 2022-06-21 | 2023-12-28 | Danisco Us Inc. | Methods and compositions for cleaning comprising a polypeptide having thermolysin activity |
WO2023247664A2 (en) | 2022-06-24 | 2023-12-28 | Novozymes A/S | Lipase variants and compositions comprising such lipase variants |
WO2024020445A1 (en) | 2022-07-20 | 2024-01-25 | Ecolab Usa Inc. | Novel nonionic extended surfactants, compositions and methods of use thereof |
EP4321604A1 (en) | 2022-08-08 | 2024-02-14 | The Procter & Gamble Company | A fabric and home care composition comprising surfactant and a polyester |
WO2024050343A1 (en) | 2022-09-02 | 2024-03-07 | Danisco Us Inc. | Subtilisin variants and methods related thereto |
WO2024050339A1 (en) | 2022-09-02 | 2024-03-07 | Danisco Us Inc. | Mannanase variants and methods of use |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2034061A (en) * | 1978-09-27 | 1980-05-29 | Fuji Photo Film Co Ltd | Silver halide colour photographic lightsensitive material |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2054109A1 (en) * | 1970-11-04 | 1972-05-10 | Krupp Gmbh | Device for guiding rolled pieces into adjacent tracks |
US4425278A (en) * | 1977-09-07 | 1984-01-10 | Ciba-Geigy Corporation | Complex compounds, process for their preparation, and their use |
CH629231A5 (en) * | 1977-11-04 | 1982-04-15 | Ciba Geigy Ag | METHOD FOR PRODUCING METAL SALT-AMINE COMPLEXES. |
US4325884A (en) * | 1980-06-27 | 1982-04-20 | The Firestone Tire & Rubber Company | Method for the preparation of bis(ρ-aminobenzoato) cobalt |
US4364871A (en) * | 1980-09-08 | 1982-12-21 | The Dow Chemical Company | Process for making aminopolycarboxylic acid chelates of iron |
GR76237B (en) * | 1981-08-08 | 1984-08-04 | Procter & Gamble | |
US4915854A (en) * | 1986-11-14 | 1990-04-10 | The Procter & Gamble Company | Ion-pair complex conditioning agent and compositions containing same |
GB8629837D0 (en) * | 1986-12-13 | 1987-01-21 | Interox Chemicals Ltd | Bleach activation |
GB8908416D0 (en) * | 1989-04-13 | 1989-06-01 | Unilever Plc | Bleach activation |
GB8915781D0 (en) * | 1989-07-10 | 1989-08-31 | Unilever Plc | Bleach activation |
ES2100925T3 (en) * | 1990-05-21 | 1997-07-01 | Unilever Nv | WHITENING ACTIVATION. |
US5173207A (en) * | 1991-05-31 | 1992-12-22 | Colgate-Palmolive Company | Powered automatic dishwashing composition containing enzymes |
GB9118242D0 (en) * | 1991-08-23 | 1991-10-09 | Unilever Plc | Machine dishwashing composition |
CA2085642A1 (en) * | 1991-12-20 | 1993-06-21 | Ronald Hage | Bleach activation |
-
1995
- 1995-07-27 US US08/508,198 patent/US5597936A/en not_active Expired - Fee Related
-
1996
- 1996-01-25 DE DE69608102T patent/DE69608102T2/en not_active Expired - Fee Related
- 1996-01-25 JP JP9503028A patent/JPH11509529A/en not_active Withdrawn
- 1996-01-25 CA CA002224462A patent/CA2224462C/en not_active Expired - Fee Related
- 1996-01-25 AT AT96903702T patent/ATE192453T1/en not_active IP Right Cessation
- 1996-01-25 AU AU47700/96A patent/AU4770096A/en not_active Abandoned
- 1996-01-25 EP EP96903702A patent/EP0832088B1/en not_active Expired - Lifetime
- 1996-01-25 WO PCT/US1996/001086 patent/WO1997000263A1/en active IP Right Grant
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2034061A (en) * | 1978-09-27 | 1980-05-29 | Fuji Photo Film Co Ltd | Silver halide colour photographic lightsensitive material |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010010106A1 (en) | 2008-07-23 | 2010-01-28 | Pharmaleads | Aminophosphinic derivatives that can be used in the treatment of pain |
Also Published As
Publication number | Publication date |
---|---|
AU4770096A (en) | 1997-01-15 |
EP0832088B1 (en) | 2000-05-03 |
DE69608102T2 (en) | 2001-01-11 |
JPH11509529A (en) | 1999-08-24 |
US5597936A (en) | 1997-01-28 |
EP0832088A1 (en) | 1998-04-01 |
CA2224462A1 (en) | 1997-01-03 |
DE69608102D1 (en) | 2000-06-08 |
ATE192453T1 (en) | 2000-05-15 |
CA2224462C (en) | 2001-05-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0832088B1 (en) | Method for manufacturing cobalt catalysts | |
EP0848714B1 (en) | Method for manufacturing cobalt catalysts | |
US5581005A (en) | Method for manufacturing cobalt catalysts | |
Pelizzi et al. | Synthesis and properties of new calixarene-based ditopic receptors for the simultaneous complexation of cations and carboxylate anions | |
JP5648815B2 (en) | Method for producing 3,7-diaza-bicyclo [3.3.1] nonane-metal complex | |
JP3997232B2 (en) | Process for producing 1,2-diaminocyclohexane-platinum (II) -complex | |
JP5746634B2 (en) | Method for producing 3,7-diaza-bicyclo [3.3.1] nonane metal complex | |
Krumm et al. | Palladium-1-methylcytosine chemistry: N3 and N3, N4 metal binding to 1-methylcytosine and an unexpected trans. fwdarw. cis isomerization of two diamminepalladium (II) entities | |
JP2013521235A (en) | Preparation of stray catalyst | |
DE69727460T2 (en) | A CONNECTION THAT CAN BE USED IN A CATALYTIC COMPOSITION | |
Dodo et al. | Synthesis of ruthenium complexes with planar-chiral cyclopentadienyl-pyridine or-phosphine bidentate ligands | |
Mai et al. | Preparations and structures of (η6-arene) ruthenium (II) complexes bearing 1, 1′-bis (diphenylphosphinomethyl) ferrocene or 1, 1′-bis (diphenylphosphino) ferrocene | |
Vicente et al. | Gold (I) and Palladium (II) Complexes Containing the Functionalized Ylides Triarylphosphonium Cyanomethylide or 2‐Cyanoethylide (R3P= CHR′, R′= CN, CH2CN) | |
Suzuki | Crystal and Molecular Structures of Bis [8-(diphenylphosphino) quinoline] palladium (II) Complexes: Pd (Ph2Pqn) 2XY (XY= Cl2, Br2 or ClBF4) | |
EP0938490A1 (en) | New dipalladaphosphacyclobutanes and a process for preparing the same | |
CN113234104B (en) | Pincer-shaped molybdenum complex, preparation method thereof, catalytic composition, application and alcohol preparation method | |
Mosteiro et al. | Nucleophilic addition of 1, 3-dicarbonyl compounds as a route to functionalized cyclopalladated complexes with chelated 1, 1-bis (diphenylphosphino) ethene | |
Vicente et al. | Synthesis of the first acetonylgold (III) complexes by C–H activation of acetone with 2-phenylazophenylgold (III) complexes | |
Xu et al. | Coordination chemistry of organometallic polydentate ligand Reactive chemistry of the tridentate ligand trans‐Fe (Ph2PQu‐P) 2‐(CO) 3 [PhzPQu= 2‐diphenyl‐phosphino‐4‐methylquinoline] and molecular structure of [Fe (CO) 3 (μ‐Ph2PQu) 2HgI]+[HgI3] | |
Powell et al. | Synthesis and structural characterization of [PtCl2 {meso-Ph (HO) PCH2CH2P (OH) Ph}] and structurally related derivatives | |
Kemmitt et al. | Carbon–chlorine bond activation in 2-chloromethylallyl complexes of platinum (II) | |
Raveendranathan | A Metalloligand Approach to Heterometallic Coordination Polymers | |
Bortoluzzi et al. | Sciences at Ca’Foscari | |
Hassan et al. | Nucleophilic (Michael) additions to (Ph 2 P) 2 C [double bond, length half m-dash] CH 2 when chelated to dimethylplatinum (II), di (o-tolyl) platinum (II), or iodo (trimethyl) platinum (IV). Crystal structure of [PtMe 3 I {(PPh 2) CH (PPh 2) CH 2 NHCH 2 Ph}] | |
Carvalho et al. | Preparation and properties of mer-[ReCl (N 2)(CNR){P (OMe) 3} 3](R= Me, Et, Bu t, C 6 H 4 Me-4, or C 6 H 4 Cl-4) and [ReCl (N 2)(CNMe)(PPh 3){P (OEt) 3} 2]. X-Ray crystal structure of mer-[ReCl (N 2)(CNMe){P (OMe) 3} 3] and reductive cleavage of the lsocyanide ligands to primary amines upon protonation |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AL AM AT AU AZ BB BG BR BY CA CH CN CZ DE DK EE ES FI GB GE HU IS JP KE KG KP KR KZ LK LR LS LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK TJ TM TR TT UA UG UZ VN AZ BY KG KZ RU TJ TM |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): KE LS MW SD SZ UG AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN ML MR NE SN |
|
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 1996903702 Country of ref document: EP |
|
ENP | Entry into the national phase |
Ref document number: 2224462 Country of ref document: CA Ref country code: CA Ref document number: 2224462 Kind code of ref document: A Format of ref document f/p: F |
|
ENP | Entry into the national phase |
Ref country code: JP Ref document number: 1997 503028 Kind code of ref document: A Format of ref document f/p: F |
|
WWP | Wipo information: published in national office |
Ref document number: 1996903702 Country of ref document: EP |
|
REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |
|
WWG | Wipo information: grant in national office |
Ref document number: 1996903702 Country of ref document: EP |