WO1997018594A1

WO1997018594A1 - Method of providing an internal electrical connection in a sealed battery cell

Info

Publication number: WO1997018594A1
Application number: PCT/SE1996/001453
Authority: WO
Inventors: Nils-Erik BÄRRING; Per-Åke OHLSSON
Original assignee: Ni-Me Hydrid Ab
Priority date: 1995-11-14
Filing date: 1996-11-12
Publication date: 1997-05-22
Also published as: EP0871982A1; AU7659596A; SE9504022L; SE9504022D0

Abstract

In a battery cell electrical connection between electrodes (1, 3) and electrically conducting end members (6, 7) of the cell container (5 - 7) is accomplished in that a battery coil (4A) consisting of wound electrodes and separators (2), wherein the electrodes have axially protruding, electrically conducting net edges (1', 3'), is placed in the cell container with the net edges in contact with the end members and in that welding joints are externally accomplished between the net edges and the end members.

Description

METHOD OF PROVIDING AN INTERNAL ELECTRICAL CONNECTION IN A SEALED BATTERY CELL

Technical Field

The present invention relates to a method of provi¬ ding an electrical connection in a sealed battery cell be- tween an electrode and an electrically conducting end mem¬ ber of the cell container. The invention also relates to a battery cell manufactured in this way. Technical Background At the manufacture of battery cells it is of great importance to accomplish the electrical connection between the internal electrodes of the cell and the externally accessible contact portions of the cell container, i e nor¬ mally the bottom and the end cover, in the cheapest pos¬ sible way and with asserted functional security. A typical example of a prior technique for this pur¬ pose is shown in FR-A-2 356 284. Here, one of the electro¬ des in a battery coil directly contacts the cylindrical side wall of the metallic cell container, whereas the other electrode has protruding end edges, which downwardly rest against an electrically isolating bottom plate in the cell container and which upwardly directly or under assistance of contact plates contact the cover of the cell container. The uppwardly extending end edges can hereby be soldered to the cover or the contact plate . The manufacture is comparatively expensive due to the relatively great number of working steps and related mem¬ bers, and the volume utilization in the cell container is far from optimal. Further, no guarantee for adequate con¬ tact can be given. Other examples of previously known techniques are EP- A-029 925 and EP-A-413 867, where internal contact members are welded to electrically conducting end portions of a battery coil before the insertion thereof in a conventional cell container. The contact members are in turn in contact with externally conducting portions of the cell container. Also this technique suffers from the deficiencies mentioned above.

The Invention

For removing the drawbacks mentioned above with pre¬ viously known techniques and for accomplishing an adequate and satisfactory electrical connection in the simpliest and cheapest way with best possible volume utilization the method according to the invention is characterized in that an electrically conducting net edge is left at the application of electrode material on an electrode net for the production of a plate shaped electrode, that the electrode - together with another electrode and separators - is wound into a battery coil with the net edge protruding from one end, that the battery coil is placed in the cell container with the net edge in contact with the end member, and that a welding joint between the end member and the net edge is externally accomplished.

Preferably line shaped welding joints are accomp¬ lished by laser welding, but any other conventional welding technique may also be utilized. Two such parallel welding joints can be accomplished.

If the cell container consists of a cylindrical tube of a plastic material and two electrically conducting end covers, the welding joints can preferably be concurrently accomplished in the two ends .

Electrolyte shall preferably be poured into the battery cell only after an accomplished welding operation, which is possible if the upper end cover has a center hole for a safety valve, which is mounted later. The invention also relates to a battery cell manufac¬ tured in the above mentioned way. This battery cell can have the characteristics defined in claims 5 - 8. The Drawings The invention shall be further described below refe¬ rence being made to the accompanying drawings, in which Fig 1 in a side view shows the different components of a battery coil before winding, Figs 2 and 3 in a side view and a top view, respectively, show a wound battery coil, Fig 4 is a side view of a battery coil after formation, Figs 5 - 7 in a longitudinal section, a top view and a bottom view, respectively, show a battery cell after a wel¬ ding operation and Figs 8 and 9 are enlargements of the upper and lower portions, respectively, of Fig 5. Detailed Description of a Preferred Embodiment

The starting material for an electrode coil for a battery cell according to the invention comprises, - as is shown in Fig 1 - a negative, plate shaped electrode 1, a separator 2, a positive, plate shaped electrode 3 and again a separator 2. In a nickel/metal hydride battery the posi¬ tive electrode contains nickel material and the negative electrode a metal hydride.

The electrode material for the respective electrodes is rolled or pressed onto a metal thread net. As especially appears from Fig 1, an edge of the electrically conducting net material 1' and 3', respectively, protrudes from the negative electrode at its lower end and the positive elec¬ trode at its upper end. It will appear that these net edges form lugs or connections for the electrodes. At the manu- facture of battery cells of type AA the total widths or heights in Fig 1 of the electrodes proper can be about 45 mm whereas the respective net edge can have a width of 1.5 mm. The electrode nets with the net edges can be manufactu¬ red of electrically conducting thread with a diameter of about 0.2 mm. For obtaining a good mechanical stability the net edges 1' and 3' can be folded against themselves.

After winding, a battery coil 4 with an appearance according to Figs 2 and 3 will be formed, where the lower lug formed by the net edge 1' forms part of the negative electrode and the upper lug formed by the net edge 3 ' forms part of the positive electrode. At the winding a central, axial hole through the battery coil 4 is formed, as most clearly appears in Fig 3. The diameter of the coil can be about 12.5 mm and the diameter of the hole 3 mm.

In a following process step the ends of the battery coil are pressed to the oblique shape shown in Fig 4. The battery coil thus modified has the reference numeral 4A. This modified battery coil 4A is arranged in a battery cell container, which is most clearly shown in Fig 5 and which consists of a mainly cylindrical tube 5 with two discs 6 and 7 closing the two ends. This battery con¬ tainer 5 - 7 is described in more detail in the internatio¬ nal patent application PCT/SE95/01064 from the same appli- cant; reference is made to this application, but the fol¬ lowing short description can be made in this context:

The cylindrical tube 5 is manufactured of a thermo¬ plastic material, whereas the circular discs or covers 6 and 7 are manufactured of an electrically conducting plate material and are so melted or pressed into the tube 5 that a pressure tight sealing is accomplished. In a completed battery cell the upper cover 7 can be provided with a safety valve, which is described in the patent application mentioned above and in Figs 5 and 8 appears as a central hole. The outer diameter of the tube 5 can be 14 mm and its length 50.5 mm.

At the insertion of the battery coil 4A in the bat^¬ tery cell container the latter may already be provided with the bottom cover 6 and be upwardly open. After the inser- tion of the battery coil 4A the top cover 7 is placed or pressed in position and is attached by melting, so that a battery cell container 5 - 7, which is closed with the ex¬ ception of the safety valve, is accomplished. This comple¬ ted container can have a length of about 49 mm. Due to the oblique formation of the ends of the battery coil 4 descri¬ bed above in connection with Fig 4 the battery coil will fill the cell container 5 - 7 well, so that a best possible capacity utilization is obtained.

After the insertion of the battery coil 4A in the upwardly open cell container and the sealing thereof by means of the upper cover 7 the net edges or net lugs 1' and 3' will contact their respective covers 6 and 7.

In order to accomplish the necessary, safe electrical contact between the net lugs 1' and 3' and the respective covers 6 and 7 a preferably line shape welding is made externally at the covers 6 and 7, so that the net lugs 1' and 3' are melted to the respective covers 6 and 7. In Figs 5 - 9 two such line shaped welding joints 8 are shown. The welding operations are preferably concurrently performed at the two ends of the battery cell.

The welding is preferably performed with laser tech¬ nique, but other well known welding techniques are also possible. At the welding operation the cover material is in principle melted in lines, whereas the underlying net mate- rial is heated, so that the materials of the cover and the net are melted together in an electrically conducting and mechanically strong joint.

After the welding a suitable electrolyte is filled through the hole of the safety valve, whereupon the safety valve, which is not shown and described here, is mounted.

Claims

1. A method of providing an electrical connection in a battery cell between an electrode (1, 3) and an electri¬ cally conducting end member (6, 7) of a cell container (5 - 7) , c h a r a c t e r i z e d in that an electrically conducting net edge (1' , 3') is left at the application of electrode material on an elec¬ trode net for the production of a plate shaped electrode (1, 3) , that the electrode - together with another electrode and separators (2) - is wound into a battery coil (4A) with the net edge protruding from one end, that the battery coil is placed in the cell container (5 - 7) with the net edge in contact with the end member (6, 7) , and that a welding joint between the end member and the net edge is externally accomplished.

2. A method according to claim 1, c h a r a c t e r¬ i z e d in that line shaped welding joints (8) are accomp- lished by laser welding.

3. A method according to claim 1 or 2, the cell con¬ tainer (5 - 7) consisting of a cylindrical tube (5) of a plastic material and two electrically conducting end covers

(6, 7) , c h a r a c t e r i z e d in that the welding joints (8) are concurrently accomplished in the two ends.

4. A method according to any of the preceding claims, the end cover (7) , having a center hole for a safety valve, c h a r a c t e r i z e d in that electrolyte is poured through the hole after welding but before the mounting of the safety valve.

5. A battery cell, including a cell container (5 - 7) with an electrically conducting end member (6, 7) and a battery coil (4A) therein comprising electrodes (1, 3) and separators (2) wound together, c h a r a c t e r i z e d in that an electrically conducting net edge (1' , 3') axi- ally protruding from an electrode (1, 3) in the battery coil (4A) is welded together with the end member (6, 7) .

6. A battery cell according to claim 5, c h a r a c¬ t e r i z e d in that the welding joint (8) accomplished between the net edge (1', 3') and the end member (6, 7) is line shaped.

7. A battery cell according to claim 6, c h a r a c¬ t e r i z e d in that two welding joints (8) are accomp¬ lished between the net edge (1' , 3') and the end member (6, 7) .

8. A battery cell according to any of the claims 5 - 7, its cell container (5 - 7) consisting of a cylindrical tube (5) of a plastic material and two electrically conduc¬ ting end covers {6, 7) , c h a r a c t e r i z e d in that welding joints (8) are accomplished in both ends of the battery cell.