WO1998006670A1 - Oxyde composite de lithium/nickel/cobalt, procede pour sa preparation, et materiau actif de cathode pour batterie rechargeable - Google Patents
Oxyde composite de lithium/nickel/cobalt, procede pour sa preparation, et materiau actif de cathode pour batterie rechargeable Download PDFInfo
- Publication number
- WO1998006670A1 WO1998006670A1 PCT/JP1997/002803 JP9702803W WO9806670A1 WO 1998006670 A1 WO1998006670 A1 WO 1998006670A1 JP 9702803 W JP9702803 W JP 9702803W WO 9806670 A1 WO9806670 A1 WO 9806670A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- chi
- general formula
- composite oxide
- represented
- aqueous medium
- Prior art date
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 75
- 238000004519 manufacturing process Methods 0.000 title claims description 26
- 239000006182 cathode active material Substances 0.000 title abstract description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title description 45
- 229910052744 lithium Inorganic materials 0.000 title description 9
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title description 7
- 229910052759 nickel Inorganic materials 0.000 title description 4
- 229910017052 cobalt Inorganic materials 0.000 title description 2
- 239000010941 cobalt Substances 0.000 title description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title description 2
- 229910052796 boron Inorganic materials 0.000 claims abstract description 24
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 23
- 229910052742 iron Inorganic materials 0.000 claims abstract description 20
- 239000011164 primary particle Substances 0.000 claims description 40
- 239000002002 slurry Substances 0.000 claims description 37
- 239000002245 particle Substances 0.000 claims description 27
- -1 basic metal salt Chemical class 0.000 claims description 26
- 229910052728 basic metal Inorganic materials 0.000 claims description 24
- 238000010304 firing Methods 0.000 claims description 23
- 150000002642 lithium compounds Chemical class 0.000 claims description 19
- 239000007774 positive electrode material Substances 0.000 claims description 17
- 150000001450 anions Chemical class 0.000 claims description 15
- 239000012736 aqueous medium Substances 0.000 claims description 15
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 14
- 239000011163 secondary particle Substances 0.000 claims description 14
- 238000000465 moulding Methods 0.000 claims description 13
- 230000001590 oxidative effect Effects 0.000 claims description 13
- 150000001639 boron compounds Chemical class 0.000 claims description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims description 8
- 238000004108 freeze drying Methods 0.000 claims description 7
- 238000001354 calcination Methods 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- 238000002441 X-ray diffraction Methods 0.000 claims description 5
- 238000009826 distribution Methods 0.000 claims description 5
- 238000005507 spraying Methods 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 239000004480 active ingredient Substances 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims 1
- 230000001568 sexual effect Effects 0.000 claims 1
- 229910003005 LiNiO2 Inorganic materials 0.000 abstract 1
- WMFOQBRAJBCJND-UHFFFAOYSA-M lithium hydroxide Inorganic materials [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 49
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 48
- 239000007864 aqueous solution Substances 0.000 description 43
- 238000006243 chemical reaction Methods 0.000 description 43
- 238000000034 method Methods 0.000 description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 30
- 239000000203 mixture Substances 0.000 description 28
- 238000012360 testing method Methods 0.000 description 25
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 22
- 239000001301 oxygen Substances 0.000 description 22
- 229910052760 oxygen Inorganic materials 0.000 description 22
- 239000000047 product Substances 0.000 description 20
- 239000000243 solution Substances 0.000 description 17
- 238000001694 spray drying Methods 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 16
- 238000000634 powder X-ray diffraction Methods 0.000 description 16
- 239000011572 manganese Substances 0.000 description 15
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 14
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 13
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 12
- 239000004327 boric acid Substances 0.000 description 12
- 239000007795 chemical reaction product Substances 0.000 description 11
- 238000010586 diagram Methods 0.000 description 11
- 239000004570 mortar (masonry) Substances 0.000 description 11
- 230000000704 physical effect Effects 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 9
- 229910002651 NO3 Inorganic materials 0.000 description 9
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 9
- 239000013078 crystal Substances 0.000 description 9
- 229910001416 lithium ion Inorganic materials 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- 239000006104 solid solution Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- PFYQFCKUASLJLL-UHFFFAOYSA-N [Co].[Ni].[Li] Chemical compound [Co].[Ni].[Li] PFYQFCKUASLJLL-UHFFFAOYSA-N 0.000 description 8
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 239000006227 byproduct Substances 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 description 3
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 description 3
- 230000001186 cumulative effect Effects 0.000 description 3
- 238000003795 desorption Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 150000004679 hydroxides Chemical class 0.000 description 3
- 239000011259 mixed solution Substances 0.000 description 3
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- 229910013716 LiNi Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 101100194322 Caenorhabditis elegans rei-1 gene Proteins 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000005169 Debye-Scherrer Methods 0.000 description 1
- 229910000976 Electrical steel Inorganic materials 0.000 description 1
- 108010014173 Factor X Proteins 0.000 description 1
- 229910013290 LiNiO 2 Inorganic materials 0.000 description 1
- VLDIHELOHZKRMB-UHFFFAOYSA-N O[N+]([O-])=O.O[N+]([O-])=O.O[N+]([O-])=O Chemical compound O[N+]([O-])=O.O[N+]([O-])=O.O[N+]([O-])=O VLDIHELOHZKRMB-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- KPSZQYZCNSCYGG-UHFFFAOYSA-N [B].[B] Chemical compound [B].[B] KPSZQYZCNSCYGG-UHFFFAOYSA-N 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- DBDNZCBRIPTLJF-UHFFFAOYSA-N boron(1-) monohydride Chemical compound [BH-] DBDNZCBRIPTLJF-UHFFFAOYSA-N 0.000 description 1
- OJIJEKBXJYRIBZ-UHFFFAOYSA-N cadmium nickel Chemical compound [Ni].[Cd] OJIJEKBXJYRIBZ-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 239000006258 conductive agent Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- PSHMSSXLYVAENJ-UHFFFAOYSA-N dilithium;[oxido(oxoboranyloxy)boranyl]oxy-oxoboranyloxyborinate Chemical compound [Li+].[Li+].O=BOB([O-])OB([O-])OB=O PSHMSSXLYVAENJ-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002641 lithium Chemical class 0.000 description 1
- RSNHXDVSISOZOB-UHFFFAOYSA-N lithium nickel Chemical compound [Li].[Ni] RSNHXDVSISOZOB-UHFFFAOYSA-N 0.000 description 1
- URIIGZKXFBNRAU-UHFFFAOYSA-N lithium;oxonickel Chemical compound [Li].[Ni]=O URIIGZKXFBNRAU-UHFFFAOYSA-N 0.000 description 1
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/40—Nickelates
- C01G53/42—Nickelates containing alkali metals, e.g. LiNiO2
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/40—Nickelates
- C01G53/42—Nickelates containing alkali metals, e.g. LiNiO2
- C01G53/44—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese
- C01G53/50—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese of the type [MnO2]n-, e.g. Li(NixMn1-x)O2, Li(MyNixMn1-x-y)O2
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/60—Compounds characterised by their crystallite size
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/74—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by peak-intensities or a ratio thereof only
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/30—Particle morphology extending in three dimensions
- C01P2004/32—Spheres
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/51—Particles with a specific particle size distribution
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE69740063T DE69740063D1 (de) | 1996-08-12 | 1997-08-11 | Lithium/nickel/kobalt verbundoxid, verfahren zur herstellung und kathode-aktives material für wiederaufladbare batterie |
JP50959598A JP4131521B2 (ja) | 1996-08-12 | 1997-08-11 | リチウムニッケルコバルト複合酸化物、その製法及び二次電池用正極活物質 |
EP97934763A EP0918041B1 (en) | 1996-08-12 | 1997-08-11 | Lithium/nickel/cobalt composite oxide, process for preparing the same, and cathode active material for rechargeable battery |
US09/242,308 US6395250B2 (en) | 1996-08-12 | 1997-08-11 | Lithium/nickel/cobalt composite oxide, process for preparing the same, and cathode active material for rechargeable battery |
CA002263320A CA2263320C (en) | 1996-08-12 | 1997-08-11 | A lithium nickel cobalt complex oxide, a process for preparing the same and a positive electrode active material for a secondary battery |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP23139696 | 1996-08-12 | ||
JP8/231396 | 1996-08-12 | ||
JP35512096 | 1996-12-20 | ||
JP8/355120 | 1996-12-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1998006670A1 true WO1998006670A1 (fr) | 1998-02-19 |
Family
ID=26529841
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1997/002803 WO1998006670A1 (fr) | 1996-08-12 | 1997-08-11 | Oxyde composite de lithium/nickel/cobalt, procede pour sa preparation, et materiau actif de cathode pour batterie rechargeable |
Country Status (9)
Country | Link |
---|---|
US (1) | US6395250B2 (ja) |
EP (2) | EP0918041B1 (ja) |
JP (1) | JP4131521B2 (ja) |
KR (1) | KR100490708B1 (ja) |
CN (1) | CN1155525C (ja) |
CA (1) | CA2263320C (ja) |
DE (1) | DE69740063D1 (ja) |
TW (1) | TW363940B (ja) |
WO (1) | WO1998006670A1 (ja) |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0872450A1 (en) * | 1997-04-15 | 1998-10-21 | SANYO ELECTRIC Co., Ltd. | Positive electrode material for use in non-aqueous electrolyte battery, process for preparing the same, and non-aqueous electrolyte battery |
EP0944125A1 (en) * | 1998-03-19 | 1999-09-22 | Sanyo Electric Co., Ltd. | Positive electrode material for lithium secondary battery |
US5989744A (en) * | 1996-07-31 | 1999-11-23 | Sony Corporation | Non-aqueous electrolyte secondary cell |
EP0973217A2 (en) * | 1998-07-13 | 2000-01-19 | Ngk Insulators, Ltd. | Lithium transition metal compound for lithium secondary battery |
JP2001192208A (ja) * | 1999-06-03 | 2001-07-17 | Titan Kogyo Kk | リチウムチタン複合酸化物及びその製造方法、並びにその用途 |
JP2002170562A (ja) * | 2000-11-30 | 2002-06-14 | Nikko Materials Co Ltd | リチウム二次電池用正極材料及び及びその製造方法 |
JP2002211931A (ja) * | 2001-01-10 | 2002-07-31 | Toyota Central Res & Dev Lab Inc | リチウム二次電池正極活物質用リチウムニッケル複合酸化物 |
EP0782206B1 (en) * | 1995-12-29 | 2003-04-16 | Japan Storage Battery Company Limited | Positive electrode active material for lithium secondary battery, method of producing thereof, and lithium secondary battery |
JP2004006277A (ja) * | 2002-03-28 | 2004-01-08 | Mitsubishi Chemicals Corp | リチウム二次電池用正極材料およびそれを用いた二次電池ならびにリチウム二次電池用正極材料の製造方法 |
JPWO2003044881A1 (ja) * | 2001-11-22 | 2005-03-24 | 株式会社ユアサコーポレーション | リチウム二次電池用正極活物質及びリチウム二次電池 |
US6998069B1 (en) * | 1999-12-03 | 2006-02-14 | Ferro Gmbh | Electrode material for positive electrodes of rechargeable lithium batteries |
JP2008195608A (ja) * | 2000-11-06 | 2008-08-28 | Tanaka Chemical Corp | 高密度コバルトマンガン共沈水酸化ニッケル及びその製造法 |
JP2008195610A (ja) * | 1997-05-19 | 2008-08-28 | Showa Denko Kk | リチウム含有複合金属酸化物、その製造方法及び用途 |
JP2009245949A (ja) * | 2002-03-28 | 2009-10-22 | Mitsubishi Chemicals Corp | リチウム二次電池用正極材料およびそれを用いた二次電池ならびにリチウム二次電池用正極材料の製造方法 |
US7824807B2 (en) | 2004-12-10 | 2010-11-02 | Shin-Kobe Electric Machinery Co., Ltd. | Positive electrode material for lithium secondary battery and lithium secondary battery |
US7923147B2 (en) | 2003-05-13 | 2011-04-12 | Mitsubishi Chemical Corporation | Layered lithium-nickel-based compound oxide powder and its prodution process |
US7998619B2 (en) | 2002-03-28 | 2011-08-16 | Mitsubishi Chemical Corporation | Positive-electrode material for lithium secondary battery, secondary battery employing the same, and process for producing positive-electrode material for lithium secondary battery |
WO2014133064A1 (ja) * | 2013-02-28 | 2014-09-04 | 日産自動車株式会社 | 正極活物質、正極材料、正極および非水電解質二次電池 |
JP2017500685A (ja) * | 2013-10-24 | 2017-01-05 | ダウ グローバル テクノロジーズ エルエルシー | 改善されたリチウム金属酸化物カソード材料及びそれらを作製するための方法 |
US9843033B2 (en) | 2013-02-28 | 2017-12-12 | Nissan Motor Co., Ltd. | Positive electrode active substance, positive electrode material, positive electrode, and non-aqueous electrolyte secondary battery |
WO2020145116A1 (ja) | 2019-01-10 | 2020-07-16 | 住友金属鉱山株式会社 | リチウムイオン二次電池用正極活物質の製造方法、及び、成形体 |
Families Citing this family (99)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002289261A (ja) * | 2001-01-16 | 2002-10-04 | Matsushita Electric Ind Co Ltd | 非水電解質二次電池 |
DE69907261T3 (de) | 1998-11-13 | 2016-07-21 | Umicore | Schichtgitterstruktur besitzende lithiumhaltige metalloxide, die frei von lokalen kubisch-spinell-artigen phasen sind, und herstellung derselben |
CN1181580C (zh) * | 1999-05-25 | 2004-12-22 | 三星Sdi株式会社 | 可充电锂电池的正极活性材料组合物及其使用该组合物制备正极的方法 |
US6660432B2 (en) | 2000-09-14 | 2003-12-09 | Ilion Technology Corporation | Lithiated oxide materials and methods of manufacture |
EP1295851A4 (en) * | 2000-11-16 | 2008-08-20 | Hitachi Maxell | LITHIUM CONTENT COMPOSITE OXIDE AND NONAQUEOUS SECONDARY CELL USING THE SAME, AND METHOD FOR MANUFACTURING THE SAME |
EP1372202B8 (en) * | 2001-03-14 | 2013-12-18 | GS Yuasa International Ltd. | Positive electrode active material and nonaqueous electrolyte secondary cell comprising the same |
US6964828B2 (en) * | 2001-04-27 | 2005-11-15 | 3M Innovative Properties Company | Cathode compositions for lithium-ion batteries |
CA2388936C (en) * | 2001-06-07 | 2006-07-18 | Kawatetsu Mining Co., Ltd. | Cathode material for use in lithium secondary battery and manufacturing method thereof |
GB0117235D0 (en) * | 2001-07-14 | 2001-09-05 | Univ St Andrews | Improvements in or relating to electrochemical cells |
CN100459242C (zh) | 2001-08-07 | 2009-02-04 | 3M创新有限公司 | 锂离子电池用的改进的正极组合物 |
US7410511B2 (en) | 2002-08-08 | 2008-08-12 | Matsushita Electric Industrial Co., Ltd. | Production method of positive electrode active material for non-aqueous electrolyte secondary battery and positive electrode active material |
US20060263690A1 (en) * | 2002-09-26 | 2006-11-23 | Seimi Chemical Co., Ltd. | Positive electrode active material for lithium secondary battery and process for producing the same |
US20040121234A1 (en) * | 2002-12-23 | 2004-06-24 | 3M Innovative Properties Company | Cathode composition for rechargeable lithium battery |
JP5236878B2 (ja) * | 2003-05-28 | 2013-07-17 | ナショナル リサーチ カウンシル オブ カナダ | リチウムセルおよびバッテリー用の酸化リチウム電極 |
US7211237B2 (en) * | 2003-11-26 | 2007-05-01 | 3M Innovative Properties Company | Solid state synthesis of lithium ion battery cathode material |
JP2005339887A (ja) * | 2004-05-25 | 2005-12-08 | Sanyo Electric Co Ltd | 非水電解質二次電池 |
US7608332B2 (en) * | 2004-06-14 | 2009-10-27 | Industrial Technology Research Institute | Cathode material particle comprising of plurality of cores of coated grains |
DE102004044557B3 (de) | 2004-09-15 | 2006-06-14 | Bayer Inc., Sarnia | Mischmetallhydroxide, deren Herstellung und Verwendung |
CN101048898B (zh) * | 2004-10-29 | 2012-02-01 | 麦德托尼克公司 | 锂离子电池及医疗装置 |
TWI262618B (en) * | 2004-11-03 | 2006-09-21 | Tatung Co | A co-precipitation method for Li1+xNi1-yCoyO2-based cathode materials |
WO2006068143A1 (ja) * | 2004-12-24 | 2006-06-29 | Matsushita Electric Industrial Co., Ltd. | 非水電解質二次電池 |
US8187748B2 (en) * | 2004-12-24 | 2012-05-29 | Panasonic Corporation | Non-aqueous electrolyte secondary battery |
US20070072082A1 (en) * | 2005-09-27 | 2007-03-29 | Scott Erik R | Battery having a highly compressed positive electrode |
WO2007094645A1 (en) * | 2006-02-17 | 2007-08-23 | Lg Chem, Ltd. | Lithium-metal composite oxides and electrochemical device using the same |
JP5405126B2 (ja) * | 2006-02-17 | 2014-02-05 | エルジー・ケム・リミテッド | リチウム−金属複合酸化物の製造方法 |
JP5128779B2 (ja) * | 2006-03-06 | 2013-01-23 | パナソニック株式会社 | リチウムイオン二次電池 |
KR100822012B1 (ko) | 2006-03-30 | 2008-04-14 | 한양대학교 산학협력단 | 리튬 전지용 양극 활물질, 그 제조 방법 및 그를 포함하는리튬 이차 전지 |
CN100502106C (zh) | 2006-05-12 | 2009-06-17 | 盐光科技(嘉兴)有限公司 | 二次电池正极材料及制备方法 |
JP4211865B2 (ja) * | 2006-12-06 | 2009-01-21 | 戸田工業株式会社 | 非水電解質二次電池用Li−Ni複合酸化物粒子粉末及びその製造方法、並びに非水電解質二次電池 |
US20080280205A1 (en) * | 2007-05-07 | 2008-11-13 | 3M Innovative Properties Company | Lithium mixed metal oxide cathode compositions and lithium-ion electrochemical cells incorporating same |
BRPI0813288A2 (pt) | 2007-06-22 | 2014-12-30 | Boston Power Inc | Dispositivo de interrupção de corrente, bateria, bateria de íons de lítio, métodos para manufaturar um dispositivo de interrupção de corrente, uma bateria, e uma bateria de íons de lítio. |
WO2009128289A1 (ja) * | 2008-04-17 | 2009-10-22 | 日鉱金属株式会社 | リチウムイオン電池用正極活物質、二次電池用正極及びリチウムイオン電池 |
US8153301B2 (en) * | 2008-07-21 | 2012-04-10 | 3M Innovative Properties Company | Cathode compositions for lithium-ion electrochemical cells |
EP2368851B1 (en) * | 2008-12-04 | 2018-05-16 | Toda Kogyo Corp. | Powder of lithium complex compound particles, method for producing the same, and nonaqueous electrolyte secondary cell |
KR101250710B1 (ko) * | 2008-12-05 | 2013-04-03 | 제이엑스 닛코 닛세키 킨조쿠 가부시키가이샤 | 리튬 이온 전지용 정극 활물질, 동 정극 활물질을 사용한 2 차 전지용 정극 및 2 차 전지 정극을 사용한 리튬 이온 2 차 전지 |
JP5389620B2 (ja) * | 2009-11-27 | 2014-01-15 | 株式会社日立製作所 | リチウムイオン二次電池用正極材料およびそれを用いたリチウムイオン二次電池 |
JP5661646B2 (ja) | 2009-12-18 | 2015-01-28 | Jx日鉱日石金属株式会社 | リチウムイオン電池用正極及びその製造方法、並びに、リチウムイオン電池 |
KR101347126B1 (ko) | 2010-02-08 | 2014-01-02 | 가부시키가이샤 도요다 지도숏키 | 복합 산화물의 제조 방법, 리튬 이온 2차 전지용 정극 활물질, 리튬 이온 2차 전지 및 차량 |
CN102714312A (zh) | 2010-12-03 | 2012-10-03 | Jx日矿日石金属株式会社 | 锂离子电池用正极活性物质、锂离子电池用正极及锂离子电池 |
JP5812682B2 (ja) * | 2011-05-19 | 2015-11-17 | Jx日鉱日石金属株式会社 | リチウムイオン電池用正極活物質及びその製造方法 |
CN105810893B (zh) | 2011-06-03 | 2018-10-26 | 株式会社半导体能源研究所 | 电极的制造方法 |
US9218916B2 (en) | 2011-06-24 | 2015-12-22 | Semiconductor Energy Laboratory Co., Ltd. | Graphene, power storage device, and electric device |
US9249524B2 (en) | 2011-08-31 | 2016-02-02 | Semiconductor Energy Laboratory Co., Ltd. | Manufacturing method of composite oxide and manufacturing method of power storage device |
WO2013047630A1 (en) | 2011-09-30 | 2013-04-04 | Semiconductor Energy Laboratory Co., Ltd. | Graphene and power storage device, and manufacturing method thereof |
CN103035922B (zh) | 2011-10-07 | 2019-02-19 | 株式会社半导体能源研究所 | 蓄电装置 |
US9487880B2 (en) | 2011-11-25 | 2016-11-08 | Semiconductor Energy Laboratory Co., Ltd. | Flexible substrate processing apparatus |
US10263244B2 (en) * | 2011-11-25 | 2019-04-16 | Mitsui Mining & Smelting Co., Ltd. | Lithium metal composite oxide having layered structure |
JP6016597B2 (ja) | 2011-12-16 | 2016-10-26 | 株式会社半導体エネルギー研究所 | リチウムイオン二次電池用正極の製造方法 |
KR101644258B1 (ko) * | 2012-02-23 | 2016-07-29 | 스미토모 긴조쿠 고잔 가부시키가이샤 | 니켈 복합 수산화물과 그의 제조 방법, 비수계 전해질 이차 전지용 정극 활물질과 그의 제조 방법, 및 비수계 전해질 이차 전지 |
JP5719859B2 (ja) | 2012-02-29 | 2015-05-20 | 株式会社半導体エネルギー研究所 | 蓄電装置 |
EP2833446B1 (en) | 2012-03-31 | 2017-08-23 | IUCF-HYU (Industry-University Cooperation Foundation Hanyang University) | Method for preparing cathode active material precursor for lithium secondary battery and cathode active material precursor for lithium secondary battery prepared thereby |
US9225003B2 (en) | 2012-06-15 | 2015-12-29 | Semiconductor Energy Laboratory Co., Ltd. | Method for manufacturing storage battery electrode, storage battery electrode, storage battery, and electronic device |
US9911518B2 (en) | 2012-09-28 | 2018-03-06 | Jx Nippon Mining & Metals Corporation | Cathode active material for lithium-ion battery, cathode for lithium-ion battery and lithium-ion battery |
JP6112118B2 (ja) * | 2012-10-17 | 2017-04-12 | 戸田工業株式会社 | Li−Ni複合酸化物粒子粉末並びに非水電解質二次電池 |
CA2888419A1 (en) * | 2012-10-17 | 2014-04-24 | Toda Kogyo Corp. | Li-ni composite oxide particles and process for producing the same, and non-aqueous electrolyte secondary battery |
JP6159228B2 (ja) | 2012-11-07 | 2017-07-05 | 株式会社半導体エネルギー研究所 | 非水系二次電池用正極の製造方法 |
US9673454B2 (en) | 2013-02-18 | 2017-06-06 | Semiconductor Energy Laboratory Co., Ltd. | Sodium-ion secondary battery |
US9490472B2 (en) | 2013-03-28 | 2016-11-08 | Semiconductor Energy Laboratory Co., Ltd. | Method for manufacturing electrode for storage battery |
DE112014002346B4 (de) | 2013-05-10 | 2021-07-29 | Semiconductor Energy Laboratory Co., Ltd. | Speicherbatterie mit Lithiummanganoxid-Verbundstoff und deren Verwendung |
KR20170055569A (ko) | 2013-07-09 | 2017-05-19 | 다우 글로벌 테크놀로지스 엘엘씨 | 리튬 금속 산화물 및 리튬 금속 포스페이트를 포함하는 혼합된 양성 활성 물질 |
US9293236B2 (en) | 2013-07-15 | 2016-03-22 | Semidonconductor Energy Laboratory Co., Ltd. | Lithium—manganese composite oxide, secondary battery, and electric device |
KR20160065837A (ko) | 2013-10-04 | 2016-06-09 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 리튬 망가니즈 복합 산화물, 이차 전지, 및 전자 기기, 및 층의 형성 방법 |
US9865867B2 (en) | 2013-10-04 | 2018-01-09 | Semiconductor Energy Laboratory Co., Ltd. | Lithium manganese composite oxide, secondary battery, and electrical device |
KR102353681B1 (ko) | 2013-11-29 | 2022-01-19 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 리튬 망가니즈 복합 산화물 및 이차 전지 |
CN106463699B (zh) | 2014-05-09 | 2019-08-27 | 株式会社半导体能源研究所 | 锂离子二次电池及电子装置 |
ES2927109T3 (es) | 2014-05-27 | 2022-11-02 | Jiangsu Hengtron Nanotech Co Ltd | Materiales de cátodo de óxido de litio y metal mejorados y método para fabricarlos |
JP6745587B2 (ja) | 2014-05-29 | 2020-08-26 | 株式会社半導体エネルギー研究所 | 電極の製造方法 |
KR101568263B1 (ko) | 2014-08-07 | 2015-11-11 | 주식회사 에코프로 | 리튬 이차 전지용 양극활물질 및 이를 포함하는 리튬 이차 전지 |
KR101577179B1 (ko) | 2014-09-11 | 2015-12-16 | 주식회사 에코프로 | 리튬 이차 전지용 양극활물질 및 이를 포함하는 리튬 이차 전지 |
KR101555594B1 (ko) | 2014-10-02 | 2015-10-06 | 주식회사 에코프로 | 리튬 이차 전지용 양극활물질 및 이를 포함하는 리튬 이차 전지 |
JP6813487B2 (ja) | 2014-12-18 | 2021-01-13 | ダウ グローバル テクノロジーズ エルエルシー | 改善された熱安定性を有するリチウムイオンバッテリ |
US10256470B2 (en) | 2014-12-26 | 2019-04-09 | Semiconductor Energy Laboratory Co., Ltd. | Electrode, power storage device, electronic device, and manufacturing method of electrode |
KR20160090580A (ko) * | 2015-01-22 | 2016-08-01 | 삼성에스디아이 주식회사 | 양극 활물질, 그 제조방법 및 이를 포함하는 리튬이차전지 |
EP3261158A4 (en) | 2015-02-17 | 2018-08-08 | Toda Kogyo Corp. | Positive electrode active material for nonaqueous electrolyte secondary batteries, and nonaqueous electrolyte secondary battery |
JP6580886B2 (ja) * | 2015-06-30 | 2019-09-25 | 株式会社エンビジョンAescジャパン | リチウムイオン二次電池 |
JP6250853B2 (ja) | 2016-03-31 | 2017-12-20 | 本田技研工業株式会社 | 非水系電解質二次電池用正極活物質 |
EP3225592B1 (en) | 2016-03-31 | 2019-07-10 | Honda Motor Co., Ltd. | Positive electrode active material for nonaqueous electrolyte secondary battery |
US11005099B2 (en) * | 2016-03-31 | 2021-05-11 | Panasonic Intellectual Property Management Co., Ltd. | Nonaqueous electrolyte secondary battery |
DE112017002507T5 (de) | 2016-07-05 | 2019-03-07 | Semiconductor Energy Laboratory Co., Ltd. | Positivelektrodenaktivmaterial, Verfahren zum Herstellen des Positivelektrodenaktivmaterials undSekundärbatterie |
WO2018026650A1 (en) * | 2016-08-02 | 2018-02-08 | Apple Inc. | Coated nickel-based cathode materials and methods of preparation |
JP6862727B2 (ja) * | 2016-09-13 | 2021-04-21 | 住友金属鉱山株式会社 | 非水系電解質二次電池用正極活物質とその製造方法、および該正極活物質を用いた非水系電解質二次電池 |
KR20230101939A (ko) | 2016-10-12 | 2023-07-06 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 양극 활물질 입자 및 양극 활물질 입자의 제작 방법 |
JP6836369B2 (ja) | 2016-10-31 | 2021-03-03 | 住友化学株式会社 | リチウム二次電池用正極活物質前駆体、リチウム二次電池用正極活物質の製造方法 |
CN106784801A (zh) * | 2016-12-30 | 2017-05-31 | 惠州龙为科技有限公司 | 一种动力型、高容量改性nca正极材料的制备方法 |
US11489151B2 (en) | 2017-05-12 | 2022-11-01 | Semiconductor Energy Laboratory Co., Ltd. | Positive electrode active material particle |
CN110574193B (zh) | 2017-05-19 | 2023-08-29 | 株式会社半导体能源研究所 | 正极活性物质、正极活性物质的制造方法以及二次电池 |
KR101826612B1 (ko) | 2017-06-07 | 2018-02-07 | 주식회사 엘 앤 에프 | 양극 활물질, 및 이를 포함하는 리튬 이차 전지 |
KR102588500B1 (ko) | 2017-06-26 | 2023-10-11 | 가부시키가이샤 한도오따이 에네루기 켄큐쇼 | 양극 활물질의 제작 방법 및 이차 전지 |
PL3486978T3 (pl) | 2017-11-15 | 2021-06-28 | Ecopro Bm Co., Ltd. | Materiał czynny katody i sposób jego wytwarzania |
KR102130484B1 (ko) | 2017-11-15 | 2020-07-06 | 주식회사 에코프로비엠 | 이차전지용 양극 활물질 및 이의 제조 방법 |
US10787368B2 (en) | 2018-06-06 | 2020-09-29 | Basf Corporation | Process for producing lithiated transition metal oxides |
KR20200071989A (ko) | 2018-12-12 | 2020-06-22 | 한국교통대학교산학협력단 | 코어-쉘-쉘' 삼중층 구조를 가지는 리튬 이차전지용 양극 활물질, 이의 제조방법 및 이를 이용한 리튬 이차전지 |
US11362333B2 (en) | 2019-01-23 | 2022-06-14 | Ut-Battelle, Llc | Cobalt-free layered oxide cathodes |
KR102172381B1 (ko) * | 2019-02-14 | 2020-10-30 | 울산과학기술원 | 양극활물질, 이의 제조방법 및 이를 포함하는 양극을 포함한 리튬이차전지 |
WO2021112606A1 (ko) * | 2019-12-05 | 2021-06-10 | 주식회사 엘지에너지솔루션 | 리튬 이차전지용 양극 활물질, 상기 양극 활물질의 제조 방법 |
US11764355B2 (en) | 2020-01-22 | 2023-09-19 | Uchicago Argonne, Llc | Cathode active materials for secondary batteries |
KR20220159404A (ko) | 2020-03-27 | 2022-12-02 | 더 보드 오브 리젠츠 오브 더 유니버시티 오브 텍사스 시스템 | 리튬 배터리용 저코발트 및 무코발트, 고에너지 캐소드 소재 |
WO2022066584A1 (en) * | 2020-09-22 | 2022-03-31 | Tesla, Inc. | Sintered cathode active material elements and methods thereof |
CN114426313A (zh) * | 2022-01-07 | 2022-05-03 | 云南大学 | 一种高能量密度三元正极材料及其制备方法和应用 |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05151998A (ja) | 1991-11-30 | 1993-06-18 | Sony Corp | 非水電解液二次電池 |
JPH06342657A (ja) * | 1990-07-23 | 1994-12-13 | Her Majesty The Queen In Right Of The Province Of British Columbia As Represented By The Minister | リチウム化二酸化ニッケルカソード活性物質とその製造方法および電気化学的電池 |
JPH0837007A (ja) * | 1994-05-16 | 1996-02-06 | Tosoh Corp | リチウム含有遷移金属複合酸化物及びその製造方法並びにその用途 |
JPH0855624A (ja) * | 1994-03-07 | 1996-02-27 | Tdk Corp | 層状構造酸化物および二次電池 |
JPH08130013A (ja) * | 1993-04-01 | 1996-05-21 | Fuji Chem Ind Co Ltd | LiM3+O2 またはLiMn2 O4 の製造方法及び 2次電池正極材用LiNi3+O2 |
JPH08213052A (ja) * | 1994-08-04 | 1996-08-20 | Seiko Instr Inc | 非水電解質二次電池 |
JPH08217452A (ja) * | 1995-02-14 | 1996-08-27 | Tosoh Corp | マンガン複合酸化物及びその製造方法並びにその用途 |
JPH08298115A (ja) * | 1995-04-26 | 1996-11-12 | Japan Storage Battery Co Ltd | リチウム電池用正極活物質およびその製造法 |
JPH08319120A (ja) * | 1995-05-19 | 1996-12-03 | Nippon Chem Ind Co Ltd | リチウム複合酸化物、その製造方法およびリチウム二次電池 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06275275A (ja) * | 1993-03-17 | 1994-09-30 | Sanyo Electric Co Ltd | 非水系電池 |
DE69620154T2 (de) * | 1995-11-24 | 2002-10-02 | Fuji Chem Ind Co Ltd | Lithium-nickel-verbundoxid, verfahren zu seiner herstellung und positives aktives material für sekundäre batterie |
-
1997
- 1997-08-05 TW TW086111199A patent/TW363940B/zh not_active IP Right Cessation
- 1997-08-11 DE DE69740063T patent/DE69740063D1/de not_active Expired - Lifetime
- 1997-08-11 CA CA002263320A patent/CA2263320C/en not_active Expired - Lifetime
- 1997-08-11 US US09/242,308 patent/US6395250B2/en not_active Expired - Lifetime
- 1997-08-11 KR KR10-1999-7001211A patent/KR100490708B1/ko not_active IP Right Cessation
- 1997-08-11 JP JP50959598A patent/JP4131521B2/ja not_active Expired - Lifetime
- 1997-08-11 EP EP97934763A patent/EP0918041B1/en not_active Expired - Lifetime
- 1997-08-11 EP EP08016213A patent/EP2058281B1/en not_active Expired - Lifetime
- 1997-08-11 WO PCT/JP1997/002803 patent/WO1998006670A1/ja active IP Right Grant
- 1997-08-11 CN CNB971984697A patent/CN1155525C/zh not_active Expired - Lifetime
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06342657A (ja) * | 1990-07-23 | 1994-12-13 | Her Majesty The Queen In Right Of The Province Of British Columbia As Represented By The Minister | リチウム化二酸化ニッケルカソード活性物質とその製造方法および電気化学的電池 |
JPH05151998A (ja) | 1991-11-30 | 1993-06-18 | Sony Corp | 非水電解液二次電池 |
JPH08130013A (ja) * | 1993-04-01 | 1996-05-21 | Fuji Chem Ind Co Ltd | LiM3+O2 またはLiMn2 O4 の製造方法及び 2次電池正極材用LiNi3+O2 |
JPH0855624A (ja) * | 1994-03-07 | 1996-02-27 | Tdk Corp | 層状構造酸化物および二次電池 |
JPH0837007A (ja) * | 1994-05-16 | 1996-02-06 | Tosoh Corp | リチウム含有遷移金属複合酸化物及びその製造方法並びにその用途 |
JPH08213052A (ja) * | 1994-08-04 | 1996-08-20 | Seiko Instr Inc | 非水電解質二次電池 |
JPH08217452A (ja) * | 1995-02-14 | 1996-08-27 | Tosoh Corp | マンガン複合酸化物及びその製造方法並びにその用途 |
JPH08298115A (ja) * | 1995-04-26 | 1996-11-12 | Japan Storage Battery Co Ltd | リチウム電池用正極活物質およびその製造法 |
JPH08319120A (ja) * | 1995-05-19 | 1996-12-03 | Nippon Chem Ind Co Ltd | リチウム複合酸化物、その製造方法およびリチウム二次電池 |
Cited By (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0782206B1 (en) * | 1995-12-29 | 2003-04-16 | Japan Storage Battery Company Limited | Positive electrode active material for lithium secondary battery, method of producing thereof, and lithium secondary battery |
US5989744A (en) * | 1996-07-31 | 1999-11-23 | Sony Corporation | Non-aqueous electrolyte secondary cell |
US6040090A (en) * | 1997-04-15 | 2000-03-21 | Sanyo Electric Co., Ltd. | Positive electrode material for use in non-aqueous electrolyte battery, process for preparing the same, and non-aqueous electrolyte battery |
EP0872450A1 (en) * | 1997-04-15 | 1998-10-21 | SANYO ELECTRIC Co., Ltd. | Positive electrode material for use in non-aqueous electrolyte battery, process for preparing the same, and non-aqueous electrolyte battery |
JP2008195610A (ja) * | 1997-05-19 | 2008-08-28 | Showa Denko Kk | リチウム含有複合金属酸化物、その製造方法及び用途 |
US6333128B1 (en) | 1998-03-19 | 2001-12-25 | Sanyo Electric Co., Ltd. | Lithium secondary battery |
EP0944125A1 (en) * | 1998-03-19 | 1999-09-22 | Sanyo Electric Co., Ltd. | Positive electrode material for lithium secondary battery |
US6368750B1 (en) | 1998-07-13 | 2002-04-09 | Ngk Insulators, Ltd. | Lithium secondary battery |
EP0973217A3 (en) * | 1998-07-13 | 2000-06-28 | Ngk Insulators, Ltd. | Lithium transition metal compound for lithium secondary battery |
EP0973217A2 (en) * | 1998-07-13 | 2000-01-19 | Ngk Insulators, Ltd. | Lithium transition metal compound for lithium secondary battery |
JP2001192208A (ja) * | 1999-06-03 | 2001-07-17 | Titan Kogyo Kk | リチウムチタン複合酸化物及びその製造方法、並びにその用途 |
US6998069B1 (en) * | 1999-12-03 | 2006-02-14 | Ferro Gmbh | Electrode material for positive electrodes of rechargeable lithium batteries |
JP2008195608A (ja) * | 2000-11-06 | 2008-08-28 | Tanaka Chemical Corp | 高密度コバルトマンガン共沈水酸化ニッケル及びその製造法 |
JP4592931B2 (ja) * | 2000-11-30 | 2010-12-08 | Jx日鉱日石金属株式会社 | リチウム二次電池用正極材料及び及びその製造方法 |
JP2002170562A (ja) * | 2000-11-30 | 2002-06-14 | Nikko Materials Co Ltd | リチウム二次電池用正極材料及び及びその製造方法 |
JP2002211931A (ja) * | 2001-01-10 | 2002-07-31 | Toyota Central Res & Dev Lab Inc | リチウム二次電池正極活物質用リチウムニッケル複合酸化物 |
JP4697504B2 (ja) * | 2001-01-10 | 2011-06-08 | 株式会社豊田中央研究所 | リチウム二次電池正極活物質用リチウムニッケル複合酸化物及びその製造方法 |
JP4956883B2 (ja) * | 2001-11-22 | 2012-06-20 | 株式会社Gsユアサ | リチウム二次電池用正極活物質及びリチウム二次電池 |
JPWO2003044881A1 (ja) * | 2001-11-22 | 2005-03-24 | 株式会社ユアサコーポレーション | リチウム二次電池用正極活物質及びリチウム二次電池 |
JP4655453B2 (ja) * | 2002-03-28 | 2011-03-23 | 三菱化学株式会社 | リチウム二次電池用正極材料およびそれを用いた二次電池ならびにリチウム二次電池用正極材料の製造方法 |
JP2009245949A (ja) * | 2002-03-28 | 2009-10-22 | Mitsubishi Chemicals Corp | リチウム二次電池用正極材料およびそれを用いた二次電池ならびにリチウム二次電池用正極材料の製造方法 |
US7998619B2 (en) | 2002-03-28 | 2011-08-16 | Mitsubishi Chemical Corporation | Positive-electrode material for lithium secondary battery, secondary battery employing the same, and process for producing positive-electrode material for lithium secondary battery |
JP2004006277A (ja) * | 2002-03-28 | 2004-01-08 | Mitsubishi Chemicals Corp | リチウム二次電池用正極材料およびそれを用いた二次電池ならびにリチウム二次電池用正極材料の製造方法 |
US8383270B2 (en) | 2002-03-28 | 2013-02-26 | Mitsubishi Chemical Corporation | Positive-electrode material for lithium secondary battery, secondary battery employing the same, and process for producing positive-electrode material for lithium secondary battery |
US7923147B2 (en) | 2003-05-13 | 2011-04-12 | Mitsubishi Chemical Corporation | Layered lithium-nickel-based compound oxide powder and its prodution process |
US7824807B2 (en) | 2004-12-10 | 2010-11-02 | Shin-Kobe Electric Machinery Co., Ltd. | Positive electrode material for lithium secondary battery and lithium secondary battery |
WO2014133064A1 (ja) * | 2013-02-28 | 2014-09-04 | 日産自動車株式会社 | 正極活物質、正極材料、正極および非水電解質二次電池 |
US9537148B2 (en) | 2013-02-28 | 2017-01-03 | Nissan Motor Co., Ltd. | Positive electrode active substance, positive electrode material, positive electrode, and non-aqueous electrolyte secondary battery |
JPWO2014133064A1 (ja) * | 2013-02-28 | 2017-02-02 | 日産自動車株式会社 | 正極活物質、正極材料、正極および非水電解質二次電池 |
US9843033B2 (en) | 2013-02-28 | 2017-12-12 | Nissan Motor Co., Ltd. | Positive electrode active substance, positive electrode material, positive electrode, and non-aqueous electrolyte secondary battery |
JP2017500685A (ja) * | 2013-10-24 | 2017-01-05 | ダウ グローバル テクノロジーズ エルエルシー | 改善されたリチウム金属酸化物カソード材料及びそれらを作製するための方法 |
WO2020145116A1 (ja) | 2019-01-10 | 2020-07-16 | 住友金属鉱山株式会社 | リチウムイオン二次電池用正極活物質の製造方法、及び、成形体 |
Also Published As
Publication number | Publication date |
---|---|
EP0918041B1 (en) | 2010-11-24 |
US6395250B2 (en) | 2002-05-28 |
CN1232438A (zh) | 1999-10-20 |
CA2263320C (en) | 2006-08-08 |
EP0918041A1 (en) | 1999-05-26 |
JP4131521B2 (ja) | 2008-08-13 |
CA2263320A1 (en) | 1998-02-19 |
US20010010807A1 (en) | 2001-08-02 |
TW363940B (en) | 1999-07-11 |
KR20000029966A (ko) | 2000-05-25 |
DE69740063D1 (de) | 2011-01-05 |
KR100490708B1 (ko) | 2005-05-24 |
EP0918041A4 (en) | 2006-05-17 |
EP2058281B1 (en) | 2012-09-19 |
EP2058281A2 (en) | 2009-05-13 |
EP2058281A3 (en) | 2009-12-23 |
CN1155525C (zh) | 2004-06-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO1998006670A1 (fr) | Oxyde composite de lithium/nickel/cobalt, procede pour sa preparation, et materiau actif de cathode pour batterie rechargeable | |
JP3130813B2 (ja) | リチウムニッケル複合酸化物、その製造方法および二次電池用正極活物質 | |
Oh et al. | Effect of calcination temperature on morphology, crystallinity and electrochemical properties of nano-crystalline metal oxides (Co3O4, CuO, and NiO) prepared via ultrasonic spray pyrolysis | |
WO1997019023A1 (fr) | Oxyde composite lithium-nickel, son procede de preparation, et materiau actif positif destine a une batterie secondaire | |
CN102763247B (zh) | 锂离子电池用正极活性物质、锂离子电池用正极以及锂离子电池 | |
WO2023184960A1 (zh) | 磷酸锰铁锂的制备方法,正极材料及锂离子电池 | |
KR20100041721A (ko) | 리튬-금속 복합산화물의 제조방법 | |
CN104078669B (zh) | 一种多元正极材料的制备方法 | |
WO2015025795A1 (ja) | 異方性構造を有するアルカリ金属チタン酸化物及びチタン酸化物並びにこれらの酸化物を含む電極活物質及び蓄電デバイス | |
JPH08130013A (ja) | LiM3+O2 またはLiMn2 O4 の製造方法及び 2次電池正極材用LiNi3+O2 | |
JP3922040B2 (ja) | リチウムマンガン複合酸化物とその製造方法並びにその用途 | |
JP4760805B2 (ja) | リチウムニッケルコバルト複合酸化物その製法及び二次電池用正極活物質 | |
JP5701863B2 (ja) | 新規チタン酸リチウム及びその製造方法、並びに該チタン酸リチウムを含む電極活物質、該電極活物質を用いてなる蓄電デバイス | |
JP4066472B2 (ja) | 板状水酸化ニッケル粒子、その製造方法及びこれを原料とするリチウム・ニッケル複合酸化物粒子の製造方法 | |
JP6128303B2 (ja) | リチウムマンガン系複合酸化物およびその製造方法 | |
JP2022174094A (ja) | 非水系電解質二次電池用正極活物質の製造方法、及び、成形体 | |
WO2019124943A1 (ko) | 리튬 이차전지용 양극 활물질 및 그 제조방법, 리튬 이차전지 | |
JP3609229B2 (ja) | 非水系二次電池用正極活物質の製造方法及びそれを使用したリチウム二次電池 | |
JP2001122628A (ja) | リチウムマンガン複合酸化物粒子状組成物とその製造方法及び二次電池 | |
JP5099328B2 (ja) | リチウムニッケルコバルト複合酸化物その製法及び二次電池用正極活物質 | |
KR100668051B1 (ko) | 공침법을 이용한 망간산화물, 이를 이용한 리튬이차전지스피넬형 양극 활물질 및 그 제조방법 | |
JPH11121006A (ja) | リチウム二次電池用正極活物質 | |
KR100668050B1 (ko) | 망간복합산화물, 이를 이용한 리튬이차전지 스피넬형양극활물질 및 그 제조방법 | |
JP4055269B2 (ja) | マンガン酸化物及びその製造方法、並びにマンガン酸化物を用いたリチウムマンガン複合酸化物及びその製造方法 | |
JPWO2018066633A1 (ja) | チタン及び/又はゲルマニウム置換リチウムマンガン系複合酸化物及びその製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 97198469.7 Country of ref document: CN |
|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): CA CN JP KR US |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE |
|
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
ENP | Entry into the national phase |
Ref document number: 2263320 Country of ref document: CA Ref document number: 2263320 Country of ref document: CA Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 09242308 Country of ref document: US Ref document number: 1019997001211 Country of ref document: KR |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1997934763 Country of ref document: EP |
|
WWP | Wipo information: published in national office |
Ref document number: 1997934763 Country of ref document: EP |
|
WWP | Wipo information: published in national office |
Ref document number: 1019997001211 Country of ref document: KR |
|
WWG | Wipo information: grant in national office |
Ref document number: 1019997001211 Country of ref document: KR |