WO1998059385A1 - Lithium recovery and purification - Google Patents
Lithium recovery and purification Download PDFInfo
- Publication number
- WO1998059385A1 WO1998059385A1 PCT/NZ1998/000087 NZ9800087W WO9859385A1 WO 1998059385 A1 WO1998059385 A1 WO 1998059385A1 NZ 9800087 W NZ9800087 W NZ 9800087W WO 9859385 A1 WO9859385 A1 WO 9859385A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- lithium
- membrane
- solution
- nanofiltration
- purification
- Prior art date
Links
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 62
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 62
- 238000000746 purification Methods 0.000 title claims abstract description 26
- 238000011084 recovery Methods 0.000 title claims abstract description 19
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims abstract description 144
- 239000012528 membrane Substances 0.000 claims abstract description 68
- 238000000034 method Methods 0.000 claims abstract description 60
- 239000000243 solution Substances 0.000 claims abstract description 51
- 238000001728 nano-filtration Methods 0.000 claims abstract description 40
- 239000002699 waste material Substances 0.000 claims abstract description 30
- 229910003002 lithium salt Inorganic materials 0.000 claims abstract description 27
- 159000000002 lithium salts Chemical class 0.000 claims abstract description 27
- 230000008569 process Effects 0.000 claims abstract description 21
- 239000012466 permeate Substances 0.000 claims abstract description 20
- 238000005341 cation exchange Methods 0.000 claims abstract description 9
- 239000012266 salt solution Substances 0.000 claims abstract description 9
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910001416 lithium ion Inorganic materials 0.000 claims abstract description 7
- 239000002002 slurry Substances 0.000 claims abstract description 6
- 239000002198 insoluble material Substances 0.000 claims abstract description 3
- 238000001914 filtration Methods 0.000 claims description 19
- 239000007789 gas Substances 0.000 claims description 13
- 229910052808 lithium carbonate Inorganic materials 0.000 claims description 10
- 239000008367 deionised water Substances 0.000 claims description 9
- 238000005406 washing Methods 0.000 claims description 9
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical group [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- 229920000557 Nafion® Polymers 0.000 claims description 7
- 239000012527 feed solution Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 239000011550 stock solution Substances 0.000 claims description 3
- 239000001117 sulphuric acid Substances 0.000 claims description 3
- 235000011149 sulphuric acid Nutrition 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 238000010248 power generation Methods 0.000 claims description 2
- 239000010409 thin film Substances 0.000 claims description 2
- 239000006227 byproduct Substances 0.000 claims 1
- 229920006254 polymer film Polymers 0.000 claims 1
- 230000000063 preceeding effect Effects 0.000 claims 1
- 238000005086 pumping Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 7
- 239000005864 Sulphur Substances 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 239000012465 retentate Substances 0.000 description 7
- 238000000605 extraction Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 238000012546 transfer Methods 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 5
- 230000005012 migration Effects 0.000 description 5
- 238000013508 migration Methods 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910021653 sulphate ion Inorganic materials 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- -1 alkali metal salts Chemical class 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 238000000909 electrodialysis Methods 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 239000002894 chemical waste Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 125000003636 chemical group Chemical group 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000009285 membrane fouling Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000004094 preconcentration Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/027—Nanofiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
- B01D61/44—Ion-selective electrodialysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/58—Multistep processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
- C01D15/02—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/14—Alkali metal compounds
- C25B1/16—Hydroxides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/54—Reclaiming serviceable parts of waste accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/52—Reclaiming serviceable parts of waste cells or batteries, e.g. recycling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
- B01D61/422—Electrodialysis
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP50423599A JP2001508925A (en) | 1997-06-23 | 1998-06-18 | Lithium recovery and purification |
AU82471/98A AU8247198A (en) | 1997-06-23 | 1998-06-18 | Lithium recovery and purification |
EP98932642A EP1016152A1 (en) | 1997-06-23 | 1998-06-18 | Lithium recovery and purification |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NZ32815097 | 1997-06-23 | ||
NZ328150 | 1997-06-23 | ||
NZ32830197 | 1997-07-10 | ||
NZ328301 | 1997-07-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1998059385A1 true WO1998059385A1 (en) | 1998-12-30 |
Family
ID=26651808
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/NZ1998/000087 WO1998059385A1 (en) | 1997-06-23 | 1998-06-18 | Lithium recovery and purification |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP1016152A1 (en) |
JP (1) | JP2001508925A (en) |
AU (1) | AU8247198A (en) |
WO (1) | WO1998059385A1 (en) |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2001092152A1 (en) * | 2000-05-31 | 2001-12-06 | Carboxyque Francaise | Method for recuperating a metal in carbonate or hydrogenocarbonate form |
EP2365867A1 (en) * | 2008-11-17 | 2011-09-21 | Chemetall Foote Corporation | Recovery of lithium from aqueous solutions |
NL2004860C2 (en) * | 2010-06-09 | 2011-12-12 | Stichting Wetsus Ct Excellence Sustainable Water Technology | Apparatus and method for obtaining a specific ion from a fluid. |
EP2841623A4 (en) * | 2012-04-23 | 2016-04-13 | Nemaska Lithium Inc | Processes for preparing lithium hydroxide |
US9994931B2 (en) | 2012-07-31 | 2018-06-12 | Posco | Method for extracting lithium from solution containing lithium |
CN108251648A (en) * | 2017-12-22 | 2018-07-06 | 中国科学院宁波材料技术与工程研究所 | Nanofiltering membrane efficiently separates recovery method to metallic element in waste and old lithium ion battery |
CN108314065A (en) * | 2018-02-09 | 2018-07-24 | 陕西省膜分离技术研究院有限公司 | Divide the full membrane separating method that salt produces lithium liquor by salt lake bittern multistage nanofiltration |
CN108314064A (en) * | 2018-02-09 | 2018-07-24 | 陕西省膜分离技术研究院有限公司 | The full membrane separating method of production lithium liquor is concentrated by salt lake bittern Multistage Membranes |
US10036094B2 (en) | 2013-10-23 | 2018-07-31 | Nemaska Lithium Inc. | Processes and systems for preparing lithium hydroxide |
US10544512B2 (en) | 2014-02-24 | 2020-01-28 | Nemaska Lithium Inc. | Methods for treating lithium-containing materials |
US10597305B2 (en) | 2015-08-27 | 2020-03-24 | Nemaska Lithium Inc. | Methods for treating lithium-containing materials |
US10800663B2 (en) | 2012-05-30 | 2020-10-13 | Nemaska Lithium Inc. | Processes for preparing lithium carbonate |
US11078583B2 (en) | 2013-03-15 | 2021-08-03 | Nemaska Lithium Inc. | Processes for preparing lithium hydroxide |
US11083978B2 (en) | 2016-08-26 | 2021-08-10 | Nemaska Lithium Inc. | Processes for treating aqueous compositions comprising lithium sulfate and sulfuric acid |
CN113422123A (en) * | 2021-06-28 | 2021-09-21 | 郑州大学 | Waste battery lithium resource recovery device based on solid electrolyte |
US11142466B2 (en) | 2017-11-22 | 2021-10-12 | Nemaska Lithium Inc. | Processes for preparing hydroxides and oxides of various metals and derivatives thereof |
CN113856490A (en) * | 2021-10-11 | 2021-12-31 | 中南大学 | Preparation method of lithium ion sieve membrane and two-stage electrodialysis device |
WO2022173852A1 (en) * | 2021-02-09 | 2022-08-18 | Energy Exploration Technologies, Inc. | Systems and methods for direct lithium hydroxide production |
US11697861B2 (en) | 2013-10-23 | 2023-07-11 | Nemaska Lithium Inc. | Processes for preparing lithium carbonate |
KR20230162984A (en) | 2021-03-31 | 2023-11-29 | 에코스타-나우테크 코포레이션 리미티드 | Method for producing high purity lithium hydroxide monohydrate |
US11905180B2 (en) | 2020-04-21 | 2024-02-20 | Toray Industries, Inc. | Method for recovering rare metal salt |
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JP4896109B2 (en) * | 2008-10-24 | 2012-03-14 | 日本化学工業株式会社 | Method for producing high purity lithium carbonate |
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JP2011154811A (en) * | 2010-01-26 | 2011-08-11 | Dowa Eco-System Co Ltd | Method for leaching lithium and method for recovering lithium |
EP2749535B1 (en) * | 2010-02-17 | 2019-07-31 | All American Lithium LLC | Processes for preparing highly pure lithium carbonate and other highly pure lithium containing compounds |
JP5422495B2 (en) | 2010-02-23 | 2014-02-19 | 株式会社日立製作所 | Metal recovery method and dialysis machine |
AR084006A1 (en) * | 2010-12-01 | 2013-04-17 | Toray Industries | PROCEDURE FOR THE SEPARATION AND RECOVERY OF A PURIFIED ALCALINE METAL SALT |
AR086461A1 (en) * | 2011-01-07 | 2013-12-18 | Toray Industries | ALCALINE METAL SEPARATION AND RECOVERY PROCEDURE AND ALCALINO METAL SEPARATION AND RECOVERY APPARATUS |
JP2012200666A (en) * | 2011-03-25 | 2012-10-22 | Dowa Eco-System Co Ltd | Li SOLUTION RECOVERY APPARATUS AND Li SOLUTION RECOVERY METHOD |
JP5872788B2 (en) * | 2011-04-26 | 2016-03-01 | Dowaエコシステム株式会社 | Lithium carbonate manufacturing method and lithium carbonate manufacturing apparatus |
JPWO2013005694A1 (en) * | 2011-07-04 | 2015-02-23 | 東レ株式会社 | Alkali metal separation and recovery method and alkali metal separation and recovery apparatus |
JPWO2013146391A1 (en) * | 2012-03-30 | 2015-12-10 | 東レ株式会社 | Alkali metal separation and recovery method and alkali metal separation and recovery apparatus |
US10450633B2 (en) * | 2017-07-21 | 2019-10-22 | Larry Lien | Recovery of lithium from an acid solution |
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CN113026035B (en) * | 2021-03-02 | 2022-03-29 | 常熟理工学院 | Method for recovering lithium in lithium iron phosphate cathode material by utilizing waste incineration fly ash |
JP7060899B1 (en) * | 2021-09-30 | 2022-04-27 | 株式会社アサカ理研 | Lithium recovery system from waste lithium-ion batteries |
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CN115178134B (en) * | 2022-06-02 | 2023-09-12 | 广东邦普循环科技有限公司 | Stirring mechanism for extracting lithium from waste liquid of lithium iron phosphate battery |
KR20240020097A (en) * | 2022-08-05 | 2024-02-14 | 한양대학교 산학협력단 | Method for Extracting Lithium with Electrolysis and Lithium Extraction Apparatus Therefor |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4036713A (en) * | 1976-03-04 | 1977-07-19 | Foote Mineral Company | Process for the production of high purity lithium hydroxide |
US4636295A (en) * | 1985-11-19 | 1987-01-13 | Cominco Ltd. | Method for the recovery of lithium from solutions by electrodialysis |
US4882017A (en) * | 1988-06-20 | 1989-11-21 | Aluminum Company Of America | Method and apparatus for making light metal-alkali metal master alloy using alkali metal-containing scrap |
US5254257A (en) * | 1993-01-19 | 1993-10-19 | Culligan International Company | Reclaiming of spent brine |
EP0618633A1 (en) * | 1993-04-01 | 1994-10-05 | Hitachi, Ltd. | Lithium cell treating method and lithium cell treating apparatus |
US5587083A (en) * | 1995-04-17 | 1996-12-24 | Chemetics International Company Ltd. | Nanofiltration of concentrated aqueous salt solutions |
-
1998
- 1998-06-18 AU AU82471/98A patent/AU8247198A/en not_active Abandoned
- 1998-06-18 WO PCT/NZ1998/000087 patent/WO1998059385A1/en active Search and Examination
- 1998-06-18 JP JP50423599A patent/JP2001508925A/en not_active Ceased
- 1998-06-18 EP EP98932642A patent/EP1016152A1/en not_active Withdrawn
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4036713A (en) * | 1976-03-04 | 1977-07-19 | Foote Mineral Company | Process for the production of high purity lithium hydroxide |
US4636295A (en) * | 1985-11-19 | 1987-01-13 | Cominco Ltd. | Method for the recovery of lithium from solutions by electrodialysis |
US4882017A (en) * | 1988-06-20 | 1989-11-21 | Aluminum Company Of America | Method and apparatus for making light metal-alkali metal master alloy using alkali metal-containing scrap |
US5254257A (en) * | 1993-01-19 | 1993-10-19 | Culligan International Company | Reclaiming of spent brine |
EP0618633A1 (en) * | 1993-04-01 | 1994-10-05 | Hitachi, Ltd. | Lithium cell treating method and lithium cell treating apparatus |
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EP1016152A1 (en) | 2000-07-05 |
AU8247198A (en) | 1999-01-04 |
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