WO1999054938A1 - Cmos image sensor employing a silicide exclusion mask - Google Patents

Cmos image sensor employing a silicide exclusion mask Download PDF

Info

Publication number
WO1999054938A1
WO1999054938A1 PCT/US1999/007535 US9907535W WO9954938A1 WO 1999054938 A1 WO1999054938 A1 WO 1999054938A1 US 9907535 W US9907535 W US 9907535W WO 9954938 A1 WO9954938 A1 WO 9954938A1
Authority
WO
WIPO (PCT)
Prior art keywords
photodiode
photon
capacitor
sensor
photon sensor
Prior art date
Application number
PCT/US1999/007535
Other languages
French (fr)
Inventor
Richard B. Merrill
Original Assignee
Foveonics, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foveonics, Inc. filed Critical Foveonics, Inc.
Publication of WO1999054938A1 publication Critical patent/WO1999054938A1/en

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/14683Processes or apparatus peculiar to the manufacture or treatment of these devices or parts thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/14601Structural or functional details thereof
    • H01L27/14609Pixel-elements with integrated switching, control, storage or amplification elements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/14643Photodiode arrays; MOS imagers

Definitions

  • the invention pertains to the field of image sensor arrays and more particularly to CMOS image sensor array active pixel apparatus and manufacturing methods that use suicide exclusion masks for improved performance by reducing dark current leakage in critical pixel element sensor and storage areas, and for improving conductivity in unmasked areas by using suicides.
  • the effective sheet resistance is reduced by forming a low-resistivity shunting layer of suicide on their surfaces by depositing an appropriate metal using evaporation, sputtering, or chemical vapor deposition (CVD) techniques and then applying heat so that the metal reacts with the silicon (and polysilicon) and produces the desired suicide.
  • CVD chemical vapor deposition
  • Silicides are normally applied in unmasked process steps for reducing the contact resistance and the effective sheet resistance of the source, drain, and gate.
  • the cross-sectional view of Figures 1(a)- 1(d) show the formation of silicides in an ⁇ -type MOS structure.
  • transistor 100 built on a p-type substrate, has a source area 101, drain area 102, silicon dioxide (SiO.,) layer 103, and polysilicon gate 110.
  • a deposited SiO 2 film 120 is included for forming an oxide spacer around gate 110.
  • Fig. 1(b) shows the MOS structure after selective etching of SiO 2 layer 120 for forming an oxide spacer 130 around polysilicon gate 1 10.
  • a suitable unmasked metallic film 150' is deposited over MOS structure 100 by evaporation, sputtering, or CVD techniques in preparation for forming a silicide film (typically CoSi 2 , HfSi 2 , MoSi,, TaSi 2 , TiSi 2 , WSi 2 , or ZrSi 2 ).
  • Fig. 1(d) shows silicide film 150 which is formed by heating (sintering). Wherever metallic film 150' is in contact with silicon substrate 101 or polysilicon 1 10, silicide is formed and the unreacted metallic film is removed by etching.
  • the unmasked formation of silicides which is commonly employed in CMOS processing, creates, without discrimination, silicides on all silicon (and polysilicon) circuit components wherever they come in contact with the silicide forming metallic layer.
  • silicides are not considered suitable for use in the manufacturing process because unmasked silicide formation would form photon shields over the photo-sensitive pixel cells (photodiodes). Also, silicides are commonly used beneficially under circuit contacts for reducing contact 3
  • silicide deposits also cause increased electrical leakage at any junction to which they are applied. Consequently, pixel cells are adversely effected by the increased leakage at the junctions associated with photon detection by increasing leakage (dark) current in the pixel cell.
  • silicides in image pixel arrays can have beneficial effects (increased conductivity of polysilicon and diffusions) as well as detrimental effects (increased photodiode dark current and opaqueness), it is highly desirable that the beneficial effects of silicides be realized without the detrimental effects.
  • the present invention provides a novel strategy for selectively masking silicides in the manufacture of active pixels and active pixel arrays so that the benefits of silicides can be selectively realized while avoiding the detrimental effects.
  • a method for selectively masking silicides in a CMOS pixel and/or CMOS pixel array, for optimizing optical characteristics by efficiently coupling photons into the silicon and optimizing electrical characteristics by allowing for compact structures with highly conductive lateral contacts for capacitor structures, and for providing highly conductive 4 contacts between readout transistors and metal readout lines, is based on identifying the circuit elements associated with photon sensing that require efficient photon coupling into the photon sensor and associated circuitry elements that require low leakage characteristics for minimizing leakage (dark) current; and selectively masking the circuit elements identified in the previous step for preventing the formation of silicides while forming silicides in the unmasked areas.
  • CMOS active pixel image sensor apparatus having selectively formed silicide deposits for improved optical and electrical performance.
  • the apparatus having a pixel with a photon sensor and associated electrical elements that include photon sensor associated electrical elements requiring low leakage electrical characteristics for maintaining low photon sensor dark current, and photon sensor readout elements.
  • the photon sensor readout elements use silicides for improving polysilicon and diffusion sheet conductivity, for improving silicon to metal connector conductivity, and for improving capacitor plate and contact conductivity.
  • Figure 1(a) is a cross-sectional view of an n-type MOS transistor with polysilicon gate and deposited silicon oxide layer.
  • Figure 1(b) is a cross-sectional view of an n-type MOS transistor with polysilicon gate and oxide spacer after etching.
  • Figure 1(c) is a cross-sectional view of an n-type MOS transistor with polysilicon gate and a deposited silicide forming metal film.
  • Figure 1(d) is a cross-sectional view of an n-type MOS transistor with polysilicon gate after forming silicide deposits.
  • Figure 2 shows a block diagram of a generic CMOS active pixel array showing silicide masking of the photon sensor circuits.
  • Figure 3(a) is a circuit diagram of a three-transistor pixel circuit.
  • Figure 3(b) shows a layout view of the three-transistor pixel circuit of Fig. 3(a) and silicide exclusion areas.
  • Figure 4(a) is a circuit diagram of a four-transistor pixel circuit with capacitor memory.
  • Figure 4(b) shows a layout view of the four-transistor pixel circuit of Fig. 4(a) and silicide exclusion areas.
  • Figure 5 is a block diagram of a CMOS active pixel image sensor array.
  • Figure 6(a) is a cross-sectional view of an n-type MOS transistor array.
  • Figure 6(b) is a cross-sectional view of the n-type MOS transistor array of Figure 6(a) with a globally deposited silicon dioxide layer.
  • Figure 6(c) is a cross-sectional view of the n-type MOS transistor array of Figure 6(b) with a silicide exclusion mask patterned in the photoresist. 6
  • Figure 6(d) is a cross-sectional view of the n-type MOS transistor array of Figure 6(c) after etching of the exposed silicon dioxide layer.
  • Figure 6(e) is a cross-sectional view of the n-type MOS transistor array of Figure 6(d) after globally depositing a layer of suiciding metal.
  • Figure 6(f) is a cross-sectional view of the n-type MOS transistor array of Figure 6(e) after forming silicide by applying heat.
  • Figure 6(h) is a cross-sectional view of the n-type MOS transistor array of Figure
  • Figure 6(i) is a cross-sectional view of the n-type MOS transistor array of Figure 6(h) after contact cuts are etched through the first silicon dioxide layer in preparation for applying the normal MOS first metal layer.
  • Figure 7 shows an example of a silicide exclusion mask for a 3x3 array of four- transistor pixels.
  • silicides have not been used in CMOS active sensor arrays because of two major reasons.
  • silicide opaqueness inhibits the coupling of photons into the silicon of the photon sensor (detector).
  • silicides can cause increased electrical leakage at junctions to which they are applied.
  • silicides for overall improved performance of active pixel imaging apparatus.
  • CMOS pixel subsequently referred to simply as "pixel"
  • pixel array should be analyzed to identify areas that contain photon sensing elements that require exposure to image generated photons, areas that contain silicon-to-metal connections that are associated with the photon sensing elements that if treated to improve connection or sheet conductivity through the use of silicides would result in an unacceptable level of photon sensor electrical leakage (dark current); and areas with connections that would benefit from the application of silicides.
  • a silicide exclusion mask can be designed that would prevent the deposition of silicides on areas identified in steps (a) and (b) while allowing the deposition of silicides on the areas identified in (c).
  • Figure 2 is a block diagram that symbolically represents the silicide mask 200 showing a masked area 201 where the formation of silicides is to be prevented and an unmasked area 202 where silicides are to be formed.
  • Figure 3(a) is a schematic diagram of three-transistor active NMOS pixel sensor 300 in which the circuit elements that are to be protected by silicide exclusion masking are identified.
  • Pixel 300 is shown divided into the photon sensor circuit 310 and the output circuit 320.
  • Photon sensor circuit section includes photodiode 301 for detecting photons generated by the image subject and NMOS reset transistor 302 for resetting photodiode 301 by means of the gate labeled RESET.
  • RESET When RESET is activated, the cathode of n + /p photodiode 301 is connected to the drain supply voltage, V cc , so that the capacitance of the reverse-biased diode is charged to V cc .
  • the charge accumulating node (cathode) of photodiode 301 is also connected to the gate of NMOS transistor 303 which is operated in a source-follower mode with row-select switch NMOS transistor 304 connected as the source load.
  • the source of transistor 304 is connected to column output transfer line 90 and transfers a signal representative of the charge on the charge accumulating node of photodiode 301 when the SELECT gate of row select transistor 304 is activated.
  • the pixel Upon resetting the pixel by activating the RESET gate 306 of transistor 302, the pixel is ready for a new exposure.
  • Silicide exclusion mask area in which no silicide is to be formed, corresponds to section 310 that encompasses photodiode 301 and reset transistor 302, while silicides may be formed, as required, in the pixel output section 320.
  • Figure 3(b) is a top layout view of the active pixel 300 showing the areas in which the circuit elements of Figure 3(a) are formed on the p-type substrate of pixel 300.
  • the two areas are labeled 310 and 320 designating the respective area where no silicide is to be formed and the area in which silicide may be formed.
  • Transistors 302- 304 are built on n + active area 340 with their respective polysilicon gates shown as cross- hatched areas traversing n + active area 340 at right angles.
  • the outlines of photodiode 301 which has a n + region for the cathode and the p-substrate as its anode, is shown.
  • Upper layer metal line 305 connects the charge accumulating node (cathode) of photodiode 301 at connection pad 312, the n + source of transistor 302 at pad 313, and the 9 gate of transistor 303 at pad 311. Accordingly, photodiode 301 and reset transistor 302 are to be masked from any silicide formation. Because the gate of transistor 302 is insulated by a SiO 2 layer, silicide can be applied to connector pad 306 for improved conductance with a metallic reset control line.
  • area 320 includes, in addition to connector pad 306, the outlines of transistor 303, select transistor 304, V cc connection pad 306 in the n + region forming the drains of transistors 302 and 303, output connection pad 307 for connecting to column output line 90, and connection pad 311 for connecting to the gate of transistor 303.
  • candidate circuit elements for depositing silicides include the polysilicon gates of transistors 302-304, and connection pads 307 and 309.
  • Figure 4(a) is an example of a NMOS pixel storage sensor 400 that uses a photodiode 401, four transistors 402-405, and a capacitor 406 as a photodiode current accumulating memory.
  • Capacitor 406 is typically implemented as an NMOS storage capacitor transistor.
  • Pixel sensor 400 is initialized by activating the RESET gate 424 of transistor 402 and the XFR gate 423 of transistor 403 so that supply voltage V cc (407) is connected to the cathode of photodiode 401 and to capacitor 406 for charging to an initial value of V cc .
  • reset transistor 402 is turned off by lowering the RESET gate voltage and photodiode 401 is ready to receive image subject generated photons.
  • transfer transistor 403 is turned off by lowering the XFR gate voltage thus isolating capacitor 406 from photodiode 401.
  • the value of charge on capacitor 406 is read-out through the source-follower circuit comprising transistors 404 and 405 by activating the SELECT gate 428 of transistor 405.
  • the pixel is reset after readout, it is ready to receive another image.
  • Silicide exclusion mask 410 encompasses photodiode 401 and transistors 402- 403, which are to be protected from silicide formation because of the opaqueness and increased electrical (dark current) leakage that would result.
  • the circuit elements in the 10 unmasked area 420 can be deposited with silicide for the beneficial results that would obtain.
  • Figure 4(b) is a layout view of storage pixel 400 as formed on a p-type silicon substrate. Circuit components of Figure 4(b) are labeled with the same indices that are used for corresponding elements in Figure 4(a).
  • NMOS storage pixel sensor 400 is fabricated on a -type substrate.
  • Photodiode 401 has a n + layer for the cathode and the p- type substrate as its anode.
  • Capacitor 406 has a polysilicon layer upper-plate 435 and a SiO 2 dielectric layer separating n + implant lower plate 409. A p + implant region, 436, makes contact with the -type substrate.
  • the lower plate of capacitor 406 is connected to the substrate by connecting regions 436 and 409.
  • N- channel MOS transistors 401-405 are formed in n + active region 429.
  • Metal line 422 connects the n + polysilicon region of the upper-plate of capacitor 406 to the n + drain region of ⁇ MOS transistor 403.
  • the n + cathode region of photodiode 401 is connected by metal line 421 to the n + contact 434 that forms the source of ⁇ MOS transistors 402 and 403.
  • V cc connection 407 is in the n + region that forms the drains of ⁇ MOS transistors 402 and 404.
  • the n + region between the gates of transistors 404 and 405 forms the source of transistor 404 and the drain of transistor 405.
  • Output connection pad 408 is formed in the n + source region of transistor 405.
  • the p-type substrate may have p-well regions defined in it as described in the referenced related patent application.
  • Circuit elements that are to be protected from silicide formation are in masked areas 410 and include photodiode 401, and transistors 402-403.
  • Candidate circuit elements for silicide formation include the capacitor 406 plate formed by polysilicon gate 427, the polysilicon gates of transistors 404-405, and connection pads 407-408.
  • An upper layer metallic line 421 connects the cathode of photodiode 401 and the source of transistor 402.
  • Metallic line 422 provides a connection between the upper plate of 1 1 capacitor 406 and the source of transistor 403.
  • Connection pad 407 is used to make a metal connection to V cc and connection pads 408 and 428 respectively are used to make a metal connection from transistor 405 source to output column line 90 and from transistor 405 gate to the row select line 91.
  • a CMOS active pixel image sensor array 500 such as might be used in an electronic camera to form the camera subject image at the focal plane, is shown in Figure 5.
  • the structure is an m x n array of CMOS active pixels 400 (such as shown in Figure 4(a) and 4(b)).
  • One or more columns can be used for parallel output of photon sensor data on column output lines 90(l)-90(n).
  • Each pixel 400 in a given column has its output terminal 408 connected to a common column line 90(l)-90(n).
  • a particular row is selected by activating the corresponding row line from row lines 91(1)- 91(m) which causes transistor 405 to switch on.
  • a common transfer (XFER) line 93 is used for controlling the gate of transistor switch 403 in each pixel 400 for parallel connecting capacitor 406 to, and disconnecting capacitor 406 from, photodiode 401.
  • activating the RESET line causes the photodiode and capacitor to be charged to the prescribed initial voltage.
  • RESET line the image can be formed on the pixel array for a prescribed interval during which each pixel 400 integrates the photodiode current in capacitor 406.
  • XFER line 93 deactivates the gate of transistor switch 403 which disconnects capacitor 406 from photodiode 401.
  • the image is now stored on capacitor 406 of each pixel 400 and is ready for readout row- by-row, on column lines 90(l)-90(n), by sequentially activating row control lines 91(1)- 91(m).
  • each n-type 12 transistor 100 is formed on a -type substrate with diffused n + source area 101, diffused n + drain area 102, and polysilicon gate 110 isolated by oxide spacer 130 (as previously described with respect to Figure 1).
  • Transistors are isolated by silicon dioxide (SiO 2 ) barrier 131.
  • the areas to be protected from the formation of silicides are selectively masked by first depositing a SiO 2 global layer 132 of approximately 100 nm as shown in Figure 6(b).
  • Figure 6(c) shows the use of a silicide exclusion mask for patterning of a photoresist layer deposited over the elements that are to be masked from silicide formation.
  • Figure 6(d) shows the result of selectively etching away SiO 2 deposit 132 in the areas not masked by photoresist mask 140 for exposing the silicon and polysilicon elements in the regions to be suicided (e.g. the non-masked output circuit regions of 320 and 420 of Figures 3(a)-(b) and 4(a)-(b).
  • a suitable silicide forming metal 150' (typically titanium (Ti) or cobalt (Co)) is deposited over the entire surface as shown in Figure 6(e) and then the surface is heated to form silicide 150 wherever the silicide forming metal is in contact with the silicon and polysilicon surfaces as shown in Figure 6(f)-
  • the unreacted metal film 150' is etched away to leave the desired silicide deposits 150 as shown in Figure 6(g).
  • the methods for depositing SiO 2 and silicide forming metals and for etching to remove the same are well known in the art (op. cit. Jaeger, R. C).
  • the next fabrication step (Figure 6(h)) is the usual CMOS deposition of SiO 2 for first dielectric layer 133.
  • Figure 6(i) shows contact cuts 160 that are made in dielectric layers 132 and 133 for making metal-to-silicon and metal-to-silicide connections. (Stopping the cuts shortly after detecting the presence of silicide controls the depth of contact cuts.)
  • Figure 7 is an example of a silicide exclusion mask for a 3x3 active pixel array with pixels of the type shown in Figures 4(a) and 4(b). Exclusion areas that are to be protected from the formation of silicides are shown shaded and labeled 410.
  • connection 13 pads for connecting silicon or polysilicon to metal lines are shown as small shaded squares that are identified by indices that correspond to those used in Figure 4(b) as follows: 431 is the non-silicided connection pad on photodiode 401; 432 is the connection on upper plate 424 of capacitor 406; 433-434 are the non-silicided connections at the drain of transistor 403 and the source of transistors 402-403, respectively; 423-424 are the suicided gate connectors of transistors 403 and 402, respectively; 407, 408, and 428 are suicided connection pads respectively at the drains (V cc ) of transistors 402 and 404 , and the source (OUTPUT) and gate of transistor 405.
  • Silicide exclusion areas 410 under which the non-silicided connection pads 431, 433 and 434 are located, would prevent the formation of silicide under the masked silicide exclusion areas by preventing the silicide forming metal layer from contacting the silicon and polysilicon areas under the mask.
  • the silicide masking ensures photon sensitivity of the photodiode by preventing the formation of a silicide photon shield over the photodiode and also reduces dark current leakage associated with suicided diode junction areas.
  • silicide exclusion masking protects against increased electrical leakage of the photon detection associated transistors 402 and 403.
  • Gate connection pads 423-424 of transistors 403 and 404 are relatively immune to silicide caused electrical leakage because of the insulating SiO 2 layer beneath the polysilicon gates.
  • connection pads 433 and 434 violates the widely accepted fabrication design rules that call for the use of silicide on all connection pads.
  • improved photon sensitivity is realized by eliminating silicides in the photon detection circuitry silicon-to-metal connection pads because the low-level photon generated currents involved do not cause excessive voltage drops due to the non-silicided connections. Also, because the mask layout shown in Figure 7 has sufficient contact cuts in the 14

Abstract

An active CMOS pixel or pixel array and method for manufacturing uses silicides to improve sheet conductivity of polysilicon and diffusions and for improved conductivity of silicon to metal connections without downgrading the photon sensing performance of the pixels. Masks are used in manufacturing of the pixels by selectively masking photon sensors from the optical opaqueness of silicides and photon sensor related circuit elements from silicide induced photon sensor dark current leakage while allowing formation of silicides for providing highly conductive contacts between. Silicides are used for improving the sheet conductivity of polysilicon and diffusions in the readout transistors and for improved conductivity of silicon to metal line connection pads.

Description

S P E C I F I C A T I O N
CMOS IMAGE SENSOR EMPLOYING A SILICIDE EXCLUSION MASK
BACKGROUND OF THE INVENTION
1. Field of the Invention
The invention pertains to the field of image sensor arrays and more particularly to CMOS image sensor array active pixel apparatus and manufacturing methods that use suicide exclusion masks for improved performance by reducing dark current leakage in critical pixel element sensor and storage areas, and for improving conductivity in unmasked areas by using suicides.
2. The Prior Art
The use of suicides in CMOS multilayer-contact technology for the reduction of the sheet resistance of thin polysilicon and shallow diffusions is well known in the art (Jaeger, R. C, "Introduction to Microelectronic Fabrication", Vol. V, Section 7.5, of Neudick, G. R. et al., editors, "Modular Series on Solid State Devices", Addison- Wesley, Reading, MA, 1993). Interconnect delays caused by high sheet resistance and distributed capacitance of polysilicon and diffusions can limit the speed of very-large- scale-integrated (VLSI) circuits. The effective sheet resistance is reduced by forming a low-resistivity shunting layer of suicide on their surfaces by depositing an appropriate metal using evaporation, sputtering, or chemical vapor deposition (CVD) techniques and then applying heat so that the metal reacts with the silicon (and polysilicon) and produces the desired suicide. (Suicides have also been used in bipolar processes since 1960.)
Although suicides have been used to optimize the electrical performance of standard CMOS processes, the use of suicides in CMOS active pixel sensor and storage arrays has been generally avoided because the suicide is nearly optically opaque and inhibits photon penetration into the silicon pixel sensor. Most imager publications do not mention suicides because they are not used and some explicitly mention that silicides are not used in the process. For example see Blanksby, A. J., et al., "Noise Performance of a Color CMOS Photogate Image Sensor", Proc. IEEE - IEDM 1997, p. 8.6.1, Sec. A. Monochrome Image Sensor, in which it is stated that "A 352x288 photogate sensor was fabricated in a Lucent Technologies non-silicided 0.8-m CMOS process.
Silicides are normally applied in unmasked process steps for reducing the contact resistance and the effective sheet resistance of the source, drain, and gate. For example, the cross-sectional view of Figures 1(a)- 1(d) show the formation of silicides in an π-type MOS structure. In Figure 1(a), transistor 100. built on a p-type substrate, has a source area 101, drain area 102, silicon dioxide (SiO.,) layer 103, and polysilicon gate 110. In addition, a deposited SiO2 film 120 is included for forming an oxide spacer around gate 110. Fig. 1(b) shows the MOS structure after selective etching of SiO2 layer 120 for forming an oxide spacer 130 around polysilicon gate 1 10. In the next step, shown in Fig. 1(c), a suitable unmasked metallic film 150' is deposited over MOS structure 100 by evaporation, sputtering, or CVD techniques in preparation for forming a silicide film (typically CoSi2, HfSi2, MoSi,, TaSi2, TiSi2, WSi2, or ZrSi2). Fig. 1(d) shows silicide film 150 which is formed by heating (sintering). Wherever metallic film 150' is in contact with silicon substrate 101 or polysilicon 1 10, silicide is formed and the unreacted metallic film is removed by etching. Thus, the unmasked formation of silicides, which is commonly employed in CMOS processing, creates, without discrimination, silicides on all silicon (and polysilicon) circuit components wherever they come in contact with the silicide forming metallic layer.
In the case of circuits that include image sensor and storage circuits, silicides are not considered suitable for use in the manufacturing process because unmasked silicide formation would form photon shields over the photo-sensitive pixel cells (photodiodes). Also, silicides are commonly used beneficially under circuit contacts for reducing contact 3
resistance and for providing a good stop for the contact etch step. However, silicide deposits also cause increased electrical leakage at any junction to which they are applied. Consequently, pixel cells are adversely effected by the increased leakage at the junctions associated with photon detection by increasing leakage (dark) current in the pixel cell.
Because the use of silicides in image pixel arrays can have beneficial effects (increased conductivity of polysilicon and diffusions) as well as detrimental effects (increased photodiode dark current and opaqueness), it is highly desirable that the beneficial effects of silicides be realized without the detrimental effects.
The present invention provides a novel strategy for selectively masking silicides in the manufacture of active pixels and active pixel arrays so that the benefits of silicides can be selectively realized while avoiding the detrimental effects.
It should be noted that this novel concept of selectively masking the formation of silicides does not conform to commonly accepted design and manufacturing rule that prohibits contact cuts for connection pads in silicide exclusion areas. Circuit and layout designers typically limit their designs to stay within the rules. Adherence to the rule ensures that the contact cut etch process, which depends on the detection of a chemical etch product that indicates when the contact cuts reach the silicide layer, has completed the contact cut. Based on the insight provided by the present invention, this design rule is violated without sacrificing reliability of the fabrication process while gaining the benefits mentioned above.
BRIEF DESCRIPTION OF THE INVENTION
A method for selectively masking silicides in a CMOS pixel and/or CMOS pixel array, for optimizing optical characteristics by efficiently coupling photons into the silicon and optimizing electrical characteristics by allowing for compact structures with highly conductive lateral contacts for capacitor structures, and for providing highly conductive 4 contacts between readout transistors and metal readout lines, is based on identifying the circuit elements associated with photon sensing that require efficient photon coupling into the photon sensor and associated circuitry elements that require low leakage characteristics for minimizing leakage (dark) current; and selectively masking the circuit elements identified in the previous step for preventing the formation of silicides while forming silicides in the unmasked areas.
Another embodiment is for a CMOS active pixel image sensor apparatus having selectively formed silicide deposits for improved optical and electrical performance. The apparatus having a pixel with a photon sensor and associated electrical elements that include photon sensor associated electrical elements requiring low leakage electrical characteristics for maintaining low photon sensor dark current, and photon sensor readout elements. The photon sensor readout elements use silicides for improving polysilicon and diffusion sheet conductivity, for improving silicon to metal connector conductivity, and for improving capacitor plate and contact conductivity.
BRIEF DESCRIPTION OF THE DRAWINGS
The present invention may be more fully understood from the detailed description given below and from the accompanying drawings of the preferred embodiments of the invention, which, however, should not be taken to limit the invention to the specific embodiment but are for explanation and understanding only.
Figure 1(a) is a cross-sectional view of an n-type MOS transistor with polysilicon gate and deposited silicon oxide layer.
Figure 1(b) is a cross-sectional view of an n-type MOS transistor with polysilicon gate and oxide spacer after etching.
Figure 1(c) is a cross-sectional view of an n-type MOS transistor with polysilicon gate and a deposited silicide forming metal film. Figure 1(d) is a cross-sectional view of an n-type MOS transistor with polysilicon gate after forming silicide deposits.
Figure 2 shows a block diagram of a generic CMOS active pixel array showing silicide masking of the photon sensor circuits.
Figure 3(a) is a circuit diagram of a three-transistor pixel circuit.
Figure 3(b) shows a layout view of the three-transistor pixel circuit of Fig. 3(a) and silicide exclusion areas.
Figure 4(a) is a circuit diagram of a four-transistor pixel circuit with capacitor memory.
Figure 4(b) shows a layout view of the four-transistor pixel circuit of Fig. 4(a) and silicide exclusion areas.
Figure 5 is a block diagram of a CMOS active pixel image sensor array.
Figure 6(a) is a cross-sectional view of an n-type MOS transistor array.
Figure 6(b) is a cross-sectional view of the n-type MOS transistor array of Figure 6(a) with a globally deposited silicon dioxide layer.
Figure 6(c) is a cross-sectional view of the n-type MOS transistor array of Figure 6(b) with a silicide exclusion mask patterned in the photoresist. 6
Figure 6(d) is a cross-sectional view of the n-type MOS transistor array of Figure 6(c) after etching of the exposed silicon dioxide layer.
Figure 6(e) is a cross-sectional view of the n-type MOS transistor array of Figure 6(d) after globally depositing a layer of suiciding metal.
Figure 6(f) is a cross-sectional view of the n-type MOS transistor array of Figure 6(e) after forming silicide by applying heat.
after removal of the unreacted suiciding metal.
Figure 6(h) is a cross-sectional view of the n-type MOS transistor array of Figure
6(g) after globally depositing a first silicon dioxide layer.
Figure 6(i) is a cross-sectional view of the n-type MOS transistor array of Figure 6(h) after contact cuts are etched through the first silicon dioxide layer in preparation for applying the normal MOS first metal layer.
Figure 7 shows an example of a silicide exclusion mask for a 3x3 array of four- transistor pixels.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
Although there are beneficial effects of silicides in CMOS circuits, i.e. increased sheet conductivity of silicon (and polysilicon) and improved conductivity of metal to silicon connections, silicides have not been used in CMOS active sensor arrays because of two major reasons. First, silicide opaqueness inhibits the coupling of photons into the silicon of the photon sensor (detector). In addition, silicides can cause increased electrical leakage at junctions to which they are applied.
However, because of the benefits that can be obtained through the use of silicides in those areas of a CMOS active pixel sensor or sensor array that do not require exposure to photons or can tolerate the increased electrical leakage associated with the use of silicides, it may be desirable to use silicides for overall improved performance of active pixel imaging apparatus.
As a general rule, to take advantage of the potentially beneficial effects of silicide deposition, a CMOS pixel (subsequently referred to simply as "pixel") or pixel array should be analyzed to identify areas that contain photon sensing elements that require exposure to image generated photons, areas that contain silicon-to-metal connections that are associated with the photon sensing elements that if treated to improve connection or sheet conductivity through the use of silicides would result in an unacceptable level of photon sensor electrical leakage (dark current); and areas with connections that would benefit from the application of silicides.
Having identified these areas, a silicide exclusion mask can be designed that would prevent the deposition of silicides on areas identified in steps (a) and (b) while allowing the deposition of silicides on the areas identified in (c). Figure 2 is a block diagram that symbolically represents the silicide mask 200 showing a masked area 201 where the formation of silicides is to be prevented and an unmasked area 202 where silicides are to be formed. By use of such a mask, the beneficial uses of silicides in active pixel sensor apparatus can be realized without the detrimental effects. 8
As a specific example, Figure 3(a) is a schematic diagram of three-transistor active NMOS pixel sensor 300 in which the circuit elements that are to be protected by silicide exclusion masking are identified. Pixel 300 is shown divided into the photon sensor circuit 310 and the output circuit 320. Photon sensor circuit section includes photodiode 301 for detecting photons generated by the image subject and NMOS reset transistor 302 for resetting photodiode 301 by means of the gate labeled RESET. When RESET is activated, the cathode of n+/p photodiode 301 is connected to the drain supply voltage, Vcc, so that the capacitance of the reverse-biased diode is charged to Vcc. The charge accumulating node (cathode) of photodiode 301 is also connected to the gate of NMOS transistor 303 which is operated in a source-follower mode with row-select switch NMOS transistor 304 connected as the source load. The source of transistor 304 is connected to column output transfer line 90 and transfers a signal representative of the charge on the charge accumulating node of photodiode 301 when the SELECT gate of row select transistor 304 is activated. Upon resetting the pixel by activating the RESET gate 306 of transistor 302, the pixel is ready for a new exposure. Silicide exclusion mask area, in which no silicide is to be formed, corresponds to section 310 that encompasses photodiode 301 and reset transistor 302, while silicides may be formed, as required, in the pixel output section 320.
Figure 3(b) is a top layout view of the active pixel 300 showing the areas in which the circuit elements of Figure 3(a) are formed on the p-type substrate of pixel 300. As in Figure 3(a), the two areas are labeled 310 and 320 designating the respective area where no silicide is to be formed and the area in which silicide may be formed. Transistors 302- 304 are built on n+ active area 340 with their respective polysilicon gates shown as cross- hatched areas traversing n+ active area 340 at right angles. Within area 310, the outlines of photodiode 301, which has a n+ region for the cathode and the p-substrate as its anode, is shown. Upper layer metal line 305 connects the charge accumulating node (cathode) of photodiode 301 at connection pad 312, the n+ source of transistor 302 at pad 313, and the 9 gate of transistor 303 at pad 311. Accordingly, photodiode 301 and reset transistor 302 are to be masked from any silicide formation. Because the gate of transistor 302 is insulated by a SiO2 layer, silicide can be applied to connector pad 306 for improved conductance with a metallic reset control line. Thus, area 320 includes, in addition to connector pad 306, the outlines of transistor 303, select transistor 304, Vcc connection pad 306 in the n+ region forming the drains of transistors 302 and 303, output connection pad 307 for connecting to column output line 90, and connection pad 311 for connecting to the gate of transistor 303. In area 320, candidate circuit elements for depositing silicides include the polysilicon gates of transistors 302-304, and connection pads 307 and 309.
Figure 4(a) is an example of a NMOS pixel storage sensor 400 that uses a photodiode 401, four transistors 402-405, and a capacitor 406 as a photodiode current accumulating memory. (Capacitor 406 is typically implemented as an NMOS storage capacitor transistor.) Pixel sensor 400 is initialized by activating the RESET gate 424 of transistor 402 and the XFR gate 423 of transistor 403 so that supply voltage Vcc (407) is connected to the cathode of photodiode 401 and to capacitor 406 for charging to an initial value of Vcc. After initial charging is completed, reset transistor 402 is turned off by lowering the RESET gate voltage and photodiode 401 is ready to receive image subject generated photons. After sufficient number of photons have been received and the associated photodiode current is integrated in capacitor 406, transfer transistor 403 is turned off by lowering the XFR gate voltage thus isolating capacitor 406 from photodiode 401. When required, the value of charge on capacitor 406 is read-out through the source-follower circuit comprising transistors 404 and 405 by activating the SELECT gate 428 of transistor 405. When the pixel is reset after readout, it is ready to receive another image. Silicide exclusion mask 410 encompasses photodiode 401 and transistors 402- 403, which are to be protected from silicide formation because of the opaqueness and increased electrical (dark current) leakage that would result. The circuit elements in the 10 unmasked area 420 can be deposited with silicide for the beneficial results that would obtain.
Figure 4(b) is a layout view of storage pixel 400 as formed on a p-type silicon substrate. Circuit components of Figure 4(b) are labeled with the same indices that are used for corresponding elements in Figure 4(a). NMOS storage pixel sensor 400 is fabricated on a -type substrate. Photodiode 401 has a n+ layer for the cathode and the p- type substrate as its anode. Capacitor 406 has a polysilicon layer upper-plate 435 and a SiO2 dielectric layer separating n+ implant lower plate 409. A p+ implant region, 436, makes contact with the -type substrate. The lower plate of capacitor 406 is connected to the substrate by connecting regions 436 and 409. Because silicide is not excluded from area 420, regions 436 and 409 are connected by a region of overlapping silicide. N- channel MOS transistors 401-405 are formed in n+ active region 429. Metal line 422 connects the n+ polysilicon region of the upper-plate of capacitor 406 to the n+ drain region of ΝMOS transistor 403. The n+ cathode region of photodiode 401 is connected by metal line 421 to the n+ contact 434 that forms the source of ΝMOS transistors 402 and 403. Vcc connection 407 is in the n+ region that forms the drains of ΝMOS transistors 402 and 404. The n+ region between the gates of transistors 404 and 405 forms the source of transistor 404 and the drain of transistor 405. Output connection pad 408 is formed in the n+ source region of transistor 405. The p-type substrate may have p-well regions defined in it as described in the referenced related patent application.
Circuit elements that are to be protected from silicide formation are in masked areas 410 and include photodiode 401, and transistors 402-403. Candidate circuit elements for silicide formation include the capacitor 406 plate formed by polysilicon gate 427, the polysilicon gates of transistors 404-405, and connection pads 407-408. An upper layer metallic line 421 connects the cathode of photodiode 401 and the source of transistor 402. Metallic line 422 provides a connection between the upper plate of 1 1 capacitor 406 and the source of transistor 403. Connection pad 407 is used to make a metal connection to Vcc and connection pads 408 and 428 respectively are used to make a metal connection from transistor 405 source to output column line 90 and from transistor 405 gate to the row select line 91.
A CMOS active pixel image sensor array 500, such as might be used in an electronic camera to form the camera subject image at the focal plane, is shown in Figure 5. In this example, the structure is an m x n array of CMOS active pixels 400 (such as shown in Figure 4(a) and 4(b)). One or more columns can be used for parallel output of photon sensor data on column output lines 90(l)-90(n). Each pixel 400 in a given column has its output terminal 408 connected to a common column line 90(l)-90(n). A particular row is selected by activating the corresponding row line from row lines 91(1)- 91(m) which causes transistor 405 to switch on. A common transfer (XFER) line 93 is used for controlling the gate of transistor switch 403 in each pixel 400 for parallel connecting capacitor 406 to, and disconnecting capacitor 406 from, photodiode 401. With each capacitor 406 connected in parallel with its associated photodiode 401, activating the RESET line causes the photodiode and capacitor to be charged to the prescribed initial voltage. Upon deactivating RESET line, the image can be formed on the pixel array for a prescribed interval during which each pixel 400 integrates the photodiode current in capacitor 406. When the prescribed interval expires, XFER line 93 deactivates the gate of transistor switch 403 which disconnects capacitor 406 from photodiode 401. The image is now stored on capacitor 406 of each pixel 400 and is ready for readout row- by-row, on column lines 90(l)-90(n), by sequentially activating row control lines 91(1)- 91(m).
The formation of silicides on selected portions of the output circuit areas 320 and 420 of Figures 3(a)-(b) and 5(a)-(b), respectively, is preferably by the method shown in Figures 6(a)-(i) or by some equivalent method. Referring to Figure 6(a), each n-type 12 transistor 100 is formed on a -type substrate with diffused n+ source area 101, diffused n+ drain area 102, and polysilicon gate 110 isolated by oxide spacer 130 (as previously described with respect to Figure 1). Transistors are isolated by silicon dioxide (SiO2) barrier 131. The areas to be protected from the formation of silicides are selectively masked by first depositing a SiO2 global layer 132 of approximately 100 nm as shown in Figure 6(b). Figure 6(c) shows the use of a silicide exclusion mask for patterning of a photoresist layer deposited over the elements that are to be masked from silicide formation. Figure 6(d) shows the result of selectively etching away SiO2 deposit 132 in the areas not masked by photoresist mask 140 for exposing the silicon and polysilicon elements in the regions to be suicided (e.g. the non-masked output circuit regions of 320 and 420 of Figures 3(a)-(b) and 4(a)-(b). A suitable silicide forming metal 150' (typically titanium (Ti) or cobalt (Co)) is deposited over the entire surface as shown in Figure 6(e) and then the surface is heated to form silicide 150 wherever the silicide forming metal is in contact with the silicon and polysilicon surfaces as shown in Figure 6(f)- The unreacted metal film 150' is etched away to leave the desired silicide deposits 150 as shown in Figure 6(g). The methods for depositing SiO2and silicide forming metals and for etching to remove the same are well known in the art (op. cit. Jaeger, R. C). Normally, the next fabrication step (Figure 6(h)) is the usual CMOS deposition of SiO2 for first dielectric layer 133. (The added thickness of SiO2 layer 132 is insignificant, although shown exaggerated for clarity). Figure 6(i) shows contact cuts 160 that are made in dielectric layers 132 and 133 for making metal-to-silicon and metal-to-silicide connections. (Stopping the cuts shortly after detecting the presence of silicide controls the depth of contact cuts.)
Figure 7 is an example of a silicide exclusion mask for a 3x3 active pixel array with pixels of the type shown in Figures 4(a) and 4(b). Exclusion areas that are to be protected from the formation of silicides are shown shaded and labeled 410. For ease in relating masked areas 410 with the elements of the pixel shown in Figure 4(b), connection 13 pads for connecting silicon or polysilicon to metal lines are shown as small shaded squares that are identified by indices that correspond to those used in Figure 4(b) as follows: 431 is the non-silicided connection pad on photodiode 401; 432 is the connection on upper plate 424 of capacitor 406; 433-434 are the non-silicided connections at the drain of transistor 403 and the source of transistors 402-403, respectively; 423-424 are the suicided gate connectors of transistors 403 and 402, respectively; 407, 408, and 428 are suicided connection pads respectively at the drains (Vcc) of transistors 402 and 404 , and the source (OUTPUT) and gate of transistor 405.
Silicide exclusion areas 410, under which the non-silicided connection pads 431, 433 and 434 are located, would prevent the formation of silicide under the masked silicide exclusion areas by preventing the silicide forming metal layer from contacting the silicon and polysilicon areas under the mask. In case of connection pad 431 , the silicide masking ensures photon sensitivity of the photodiode by preventing the formation of a silicide photon shield over the photodiode and also reduces dark current leakage associated with suicided diode junction areas. In the case of connection pads 433 and 434, silicide exclusion masking protects against increased electrical leakage of the photon detection associated transistors 402 and 403. Gate connection pads 423-424 of transistors 403 and 404 are relatively immune to silicide caused electrical leakage because of the insulating SiO2 layer beneath the polysilicon gates.
It should be noted that the exclusion of silicide from connection pads 433 and 434 violates the widely accepted fabrication design rules that call for the use of silicide on all connection pads. By recognizing the benefits that accrue from violating current practice, improved photon sensitivity is realized by eliminating silicides in the photon detection circuitry silicon-to-metal connection pads because the low-level photon generated currents involved do not cause excessive voltage drops due to the non-silicided connections. Also, because the mask layout shown in Figure 7 has sufficient contact cuts in the 14
suicided areas to give a reliable etch stop indication, fabrication of an optimally designed CMOS active pixel array is realized.
The above description was limited to NMOS type structures for clarity of explanation of the invention. However, the use of PMOS type structures for obtaining functionally equivalent circuits is well known so that the principles described above may be readily applied. The description was limited to active pixels, but it will be understood that similar advantages may be obtained by applying the invention to passive pixel circuits that comprise charge accumulation nodes and readout circuits. As will be understood by those skilled in the art, many other changes in the methods and apparatus described above may be made by the skilled practitioner without departing from the spirit and scope of the invention, which should be limited only as set forth in the claims that follow.

Claims

15ClaimsWhat is claimed is:
1 . A pixel sensor apparatus comprising a plurality of silicon circuit elements, the silicon circuit elements belonging to either a first or a second set of elements, said second set of elements including a photosensor and a charge accumulation node, wherein silicide is selectively formed on silicon surface of the first set of elements and selectively excluded from forming on the second set of elements.
2. The apparatus of claim 1 wherein the photon sensor is a photodiode.
3. A CMOS active pixel image sensor apparatus having selectively formed silicide deposits for improved optical and electrical performance, the apparatus comprising a pixel with a photon sensor and associated circuit elements, the associated circuit elements requiring low leakage electrical characteristics for maintaining low photon sensor dark current, the apparatus further comprising a photon sensor output circuit for accessing the photon sensor, wherein only the photon sensor output circuit elements employ silicides on silicon surfaces thereof for improved electrical conductivity.
4. The apparatus of claim 3 wherein the photon sensor output circuit includes a capacitor for storing photon sensor generated electrical charge.
5. The apparatus of claim 3 wherein the photon sensor is a photodiode.
6. A CMOS active pixel image sensor array comprising an array of CMOS active pixels, each CMOS active pixel comprising selectively formed silicide deposits for improved optical and electrical performance, each pixel having a photon sensor and associated circuit elements, the associated circuit elements requiring low leakage electrical characteristics for maintaining low photon sensor dark current, each CMOS active pixel 16 further comprising a photon sensor readout circuit for reading out photon sensor data, wherein only selected photon sensor readout circuit elements employ silicides on silicon surfaces thereof for improved electrical conductivity.
7. A CMOS active pixel image sensor apparatus optimized for optical and electrical performance through the selective formation of silicides for improved electrical sheet and connection conductivity while maintaining optimal photon coupling to, and low dark current leakage from, the active pixel image sensor apparatus photon sensor, the apparatus comprising:
(a) a photon sensor circuit that includes a photodiode for a photon sensor, and a reset circuit for initializing the photon sensor circuit by charging the photodiode cathode-to-anode capacitance to a known voltage level; and
(b) a readout circuit coupled to the photodiode cathode for reading out the photodiode charge level after the photodiode has been exposed to photons generated by an image subject, the readout circuit further comprising a silicide layer formed on silicon surfaces thereof for increased conductivity of selected circuit elements.
8. The apparatus of claim 7 wherein the selected circuit elements include polysilicon gates.
9. The apparatus of claim 7 wherein the selected circuit elements include diffusions.
10. The apparatus of claim 7 wherein the selected circuit elements include silicon to metal connections.
1 1. The apparatus of claim 7 wherein the readout circuit further includes a switch for selectively connecting the readout circuit output to an array column output line. 17
12. A CMOS active pixel image sensor apparatus optimized for optical and electrical performance through the selective formation of silicides for improved electrical sheet and connection conductivity while maintaining optimal photon coupling to, and low dark current leakage from, the sensor apparatus photon sensor, the apparatus comprising:
(a) a photon sensor circuit that includes a photodiode for sensing image subject generated photons and producing a photodiode current that is representative of the number of photons sensed, an externally controlled first switch for selectively connecting a capacitor in parallel with the photodiode for integrating the photodiode current to produce a charge representative of the integrated current, and an externally controlled reset circuit, externally controlled by a second switch for initializing the photon sensor circuit by charging the photodiode cathode-to-anode capacitance and by charging a capacitor to a known voltage level when the capacitor is connected in parallel with the photodiode by the first switch; and
(b) a readout circuit having a capacitor selectively connected in parallel with the photodiode by the externally controlled first switch for initializing the capacitor charge and for integrating the photodiode current for producing a charge representative of the integrated photodiode current, and an externally controlled third switch for selectively connecting the capacitor charge to an output connection after the photodiode has been exposed to photons for a prescribed interval of time, the output connection connected to a column output line by the third switch that is controlled by a common row select line, the readout circuit further comprising a silicide layer formed on silicon surfaces thereof for increased conductivity of selected circuit elements.
13. The apparatus of claim 12 wherein the selected circuit elements include polysilicon gates.
14. The apparatus of claim 12 wherein the selected circuit elements include diffusions. 18
15. The apparatus of claim 12 wherein the selected circuit elements include silicon to metal connections.
16. The apparatus of claim 12 wherein the capacitor is a MOS transistor connected to form a capacitor between the transistor gate and the commonly connected source and drain of the transistor.
17. The apparatus of claim 12 wherein the first switch for connecting the capacitor in parallel with the photodiode when the capacitor is used to integrate photodiode current is also used for disconnecting the capacitor from the photodiode when the photodiode current is no longer to be integrated.
18. The array of claim 12 wherein the first, second, and third externally controlled switches are gate-controlled MOS transistors with suicided gates and connection pads for improved conductivity.
19. An array of CMOS active pixel image sensors organized to cover an area of a camera image-plane, each active pixel image sensor assigned to a specific location in the image-plane, the specific location specified by a row and column coordinate, and each active pixel image sensor connected by a selectable common row select line and a common selectable column output line for outputting a selected active pixel image sensor, each active pixel image sensor apparatus optimized for optical and electrical performance through the selective formation of silicides for improved electrical sheet and connection conductivity while maintaining optimal photon coupling to, and low dark current leakage from, the sensor apparatus photon sensor, each active pixel image sensor comprising:
(a) a photon sensor circuit that includes a photodiode for sensing image subject generated photons and producing a photodiode current that is representative of the number of photons sensed, an externally controlled first switch for selectively connecting a capacitor in parallel with the photodiode for integrating the photodiode 19 current to produce a charge representative of the integrated current, and an externally controlled reset circuit, externally controlled by a second switch for initializing the photon sensor circuit by charging the photodiode cathode-to-anode capacitance and by charging a capacitor to a known voltage level when the capacitor is connected in parallel with the photodiode by the first switch; and
(b) a readout circuit having a capacitor selectively connected in parallel with the photodiode by the externally controlled first switch for initializing the capacitor charge and for integrating the photodiode current and for producing a charge representative of the integrated photodiode current, and an externally controlled third switch for selectively connecting the capacitor charge to an output connection after the photodiode has been exposed to photons for a prescribed interval of time, the output connection connected to a column output line by the third switch that is controlled by a common row select line, the readout circuit further comprising a silicide layer formed on silicon surfaces thereof for increased conductivity of selected circuit elements.
20. The apparatus of claim 19 wherein the selected circuit elements include polysilicon gates.
21. The apparatus of claim 19 wherein the selected circuit elements include diffusions.
22. The apparatus of claim 19 wherein the selected circuit elements include silicon to metal connections.
23. The apparatus of claim 19 wherein the capacitor is a MOS transistor connected to form a capacitor between the transistor gate and the commonly connected source and drain of the transistor. 20
24. The apparatus of claim 19 wherein the first switch for connecting the capacitor in parallel with the photodiode when the capacitor is used to integrate photodiode current is also used for disconnecting the capacitor from the photodiode when the photodiode current is no longer to be accumulated.
25. The apparatus of claim 20 wherein the first, second, and third externally controlled switches are gate-controlled MOS transistors with suicided connection pads on the gates for improved conductivity.
26. A method for selectively masking the formation of silicide deposits in a CMOS active pixel circuit, having a photon sensor and associated electrical elements, for optimizing optical characteristics by efficiently coupling photons into the silicon while maintaining a low electrical leakage environment with reduced photon sensor dark current, and for optimizing electrical characteristics by improved sheet conductance of polysilicon and diffusions, and by improved metal-to-silicon contact conductance, the method comprising:
(a) identifying the photon sensor elements of each photon sensor that require efficient photon coupling;
(b) identifying the associated pixel elements that require low leakage characteristics for maintaining low photon sensor dark current;
(c) selectively masking the identified photon sensor elements and the associated pixel elements for preventing silicide formation on the identified pixel elements in the selectively masked areas; and
(d) forming silicides on silicon and polysilicon surfaces that are not selectively masked.
27. The method of claim 26 wherein the photon sensor is a photodiode. 21
28. A method for selectively masking the formation of silicide deposits in each CMOS active pixel circuit of a pixel array, each active pixel circuit having a photon sensor and associated electrical elements, for optimizing optical characteristics by efficiently coupling photons into the silicon while maintaining a low electrical leakage environment with reduced photon sensor dark current, and for optimizing electrical characteristics by improved sheet conductance of polysilicon and diffusions, and by improved metal-to- silicon contact conductance, the method comprising:
(a) identifying the photon sensor elements associated with each photon sensor that requires efficient photon coupling;
(b) identifying the associated electrical elements of each pixel that requires low leakage characteristics for maintaining low photon sensor dark current;
(c) selectively masking the identified photon sensor elements and associated electrical elements for preventing silicide formation on the identified photon sensors and associated electrical elements;
(d) forming silicides on silicon and polysilicon surfaces not selectively masked.
PCT/US1999/007535 1998-04-21 1999-04-06 Cmos image sensor employing a silicide exclusion mask WO1999054938A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/064,234 1998-04-21
US09/064,234 US6160282A (en) 1998-04-21 1998-04-21 CMOS image sensor employing silicide exclusion mask to reduce leakage and improve performance

Publications (1)

Publication Number Publication Date
WO1999054938A1 true WO1999054938A1 (en) 1999-10-28

Family

ID=22054493

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1999/007535 WO1999054938A1 (en) 1998-04-21 1999-04-06 Cmos image sensor employing a silicide exclusion mask

Country Status (3)

Country Link
US (1) US6160282A (en)
TW (1) TW440914B (en)
WO (1) WO1999054938A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6979435B1 (en) 2001-04-03 2005-12-27 Northwestern University p-Type transparent conducting oxides and methods for preparation
EP1075028A3 (en) * 1999-08-05 2008-06-04 Canon Kabushiki Kaisha Photoelectric conversion device and process for its fabrication

Families Citing this family (57)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6838320B2 (en) * 2000-08-02 2005-01-04 Renesas Technology Corp. Method for manufacturing a semiconductor integrated circuit device
KR100279295B1 (en) * 1998-06-02 2001-02-01 윤종용 Active pixel sensor
FR2781929B1 (en) * 1998-07-28 2002-08-30 St Microelectronics Sa IMAGE SENSOR WITH PHOTODIODE ARRAY
US6587142B1 (en) * 1998-09-09 2003-07-01 Pictos Technologies, Inc. Low-noise active-pixel sensor for imaging arrays with high speed row reset
JP4148615B2 (en) * 1998-11-27 2008-09-10 三洋電機株式会社 Manufacturing method of semiconductor device
US6809767B1 (en) * 1999-03-16 2004-10-26 Kozlowski Lester J Low-noise CMOS active pixel sensor for imaging arrays with high speed global or row reset
US6614562B1 (en) * 1999-06-30 2003-09-02 Intel Corporation Reducing dark current noise in an imaging system
US6433326B1 (en) * 1999-07-14 2002-08-13 Sarnoff Corporation CMOS/CCD line transfer imager with low dark current
US6333205B1 (en) * 1999-08-16 2001-12-25 Micron Technology, Inc. CMOS imager with selectively silicided gates
US20030235936A1 (en) * 1999-12-16 2003-12-25 Snyder John P. Schottky barrier CMOS device and method
US6303479B1 (en) * 1999-12-16 2001-10-16 Spinnaker Semiconductor, Inc. Method of manufacturing a short-channel FET with Schottky-barrier source and drain contacts
JP2003524345A (en) * 2000-02-23 2003-08-12 フォトビット コーポレーション Frame shutter pixel with separate storage node
US7129979B1 (en) * 2000-04-28 2006-10-31 Eastman Kodak Company Image sensor pixel for global electronic shuttering
US6365926B1 (en) * 2000-09-20 2002-04-02 Eastman Kodak Company CMOS active pixel with scavenging diode
FR2820882B1 (en) 2001-02-12 2003-06-13 St Microelectronics Sa THREE TRANSISTOR PHOTODETECTOR
FR2820883B1 (en) 2001-02-12 2003-06-13 St Microelectronics Sa HIGH CAPACITY PHOTODIODE
FR2824665B1 (en) * 2001-05-09 2004-07-23 St Microelectronics Sa CMOS TYPE PHOTODETECTOR
US6518080B2 (en) 2001-06-19 2003-02-11 Sensors Unlimited, Inc. Method of fabricating low dark current photodiode arrays
JP2004538650A (en) * 2001-08-10 2004-12-24 スピネカ セミコンダクター, インコーポレイテッド Transistor having high dielectric constant gate insulating layer, source and drain forming Schottky contact with substrate
US20060079059A1 (en) * 2001-08-10 2006-04-13 Snyder John P Transistor having high dielectric constant gate insulating layer and source and drain forming schottky contact with substrate
KR100399938B1 (en) * 2001-11-19 2003-09-29 주식회사 하이닉스반도체 Image sensor for measuring the dark signal
US6700163B2 (en) * 2001-12-07 2004-03-02 International Business Machines Corporation Selective silicide blocking
US6965102B1 (en) * 2002-04-05 2005-11-15 Foveon, Inc. Large dynamic range, low-leakage vertical color pixel sensor
KR101053323B1 (en) * 2002-05-14 2011-08-01 소니 주식회사 Semiconductor device, manufacturing method thereof, and electronic device
US6974737B2 (en) * 2002-05-16 2005-12-13 Spinnaker Semiconductor, Inc. Schottky barrier CMOS fabrication method
US6844585B1 (en) 2002-06-17 2005-01-18 National Semiconductor Corporation Circuit and method of forming the circuit having subsurface conductors
US6646318B1 (en) 2002-08-15 2003-11-11 National Semiconductor Corporation Bandgap tuned vertical color imager cell
JP3795846B2 (en) 2002-08-29 2006-07-12 富士通株式会社 Semiconductor device
US6806521B2 (en) * 2003-01-08 2004-10-19 Taiwan Semiconductor Manufacturing Co., Ltd. Integrated high performance MOS tunneling LED in ULSI technology
EP1465258A1 (en) * 2003-02-21 2004-10-06 STMicroelectronics Limited CMOS image sensors
EP1475957B1 (en) * 2003-05-08 2010-11-03 STMicroelectronics (Research & Development) Limited Method and apparatus for removing column fixed pattern noise in solid state image sensors
US7502058B2 (en) * 2003-06-09 2009-03-10 Micron Technology, Inc. Imager with tuned color filter
US7105373B1 (en) 2003-08-14 2006-09-12 National Semiconductor Corporation Vertical photodiode with heavily-doped regions of alternating conductivity types
KR100561971B1 (en) * 2003-09-24 2006-03-22 동부아남반도체 주식회사 Method for manufacturing CMOS image sensor
US7022968B1 (en) 2003-10-21 2006-04-04 National Semiconductor Corporation Optical sensor that measures the light output by the combustion chamber of an internal combustion engine
US6958194B1 (en) 2003-10-21 2005-10-25 Foveon, Inc. Imager with improved sensitivity
US6852562B1 (en) 2003-12-05 2005-02-08 Eastman Kodak Company Low-cost method of forming a color imager
US6972457B1 (en) 2004-04-09 2005-12-06 Eastman Kodak Company Imaging cell that has a long integration period and method of operating the imaging cell
US6972995B1 (en) 2004-04-09 2005-12-06 Eastman Kodak Company Imaging cell with a non-volatile memory that provides a long integration period and method of operating the imaging cell
KR100674908B1 (en) * 2004-06-01 2007-01-26 삼성전자주식회사 CMOS image device improved fill factor
US7247898B2 (en) * 2004-06-15 2007-07-24 Dialog Imaging Systems Gmbh Self adjusting transfer gate APS
JP4054321B2 (en) * 2004-06-23 2008-02-27 松下電器産業株式会社 Semiconductor device
TWI229456B (en) * 2004-07-23 2005-03-11 Pixart Imaging Inc Active pixel sensor with isolated photo sensing region and peripheral circuit region
CN100369259C (en) * 2004-08-04 2008-02-13 原相科技股份有限公司 Light-sensing area and peripheral circuit area insulated active image-finding element
US7109079B2 (en) * 2005-01-26 2006-09-19 Freescale Semiconductor, Inc. Metal gate transistor CMOS process and method for making
US20060183323A1 (en) * 2005-02-14 2006-08-17 Omnivision Technologies, Inc. Salicide process using CMP for image sensor
US8179296B2 (en) * 2005-09-30 2012-05-15 The Massachusetts Institute Of Technology Digital readout method and apparatus
US20100226495A1 (en) 2007-10-29 2010-09-09 Michael Kelly Digital readout method and apparatus
US20080237811A1 (en) * 2007-03-30 2008-10-02 Rohit Pal Method for preserving processing history on a wafer
JP5023768B2 (en) * 2007-03-30 2012-09-12 ソニー株式会社 Solid-state imaging device and manufacturing method thereof
US7432578B1 (en) * 2007-04-24 2008-10-07 Taiwan Semiconductor Manufacturing Co., Ltd. CMOS image sensor with enhanced photosensitivity
KR100900867B1 (en) * 2007-07-19 2009-06-04 주식회사 동부하이텍 Semiconductor device and method for fabricating the same
CN102725961B (en) * 2010-01-15 2017-10-13 株式会社半导体能源研究所 Semiconductor devices and electronic equipment
US8492214B2 (en) 2011-03-18 2013-07-23 International Business Machines Corporation Damascene metal gate and shield structure, methods of manufacture and design structures
US20140301133A1 (en) * 2013-04-03 2014-10-09 Maxlinear, Inc. Method and system for a high-density, low-cost, cmos compatible memory
US8999799B2 (en) 2013-08-29 2015-04-07 International Business Machines Corporation Maskless dual silicide contact formation
KR102245973B1 (en) 2014-02-17 2021-04-29 삼성전자주식회사 Correlated double sampling circuit and image sensor including the same

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5614744A (en) * 1995-08-04 1997-03-25 National Semiconductor Corporation CMOS-based, low leakage active pixel array with anti-blooming isolation
WO1998057369A1 (en) * 1997-06-12 1998-12-17 Intel Corporation A well to substrate photodiode for use in a cmos sensor on a salicide process

Family Cites Families (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3934161A (en) * 1974-04-29 1976-01-20 Texas Instruments Incorporated Electronic shutter for a charge-coupled imager
US3988619A (en) * 1974-12-27 1976-10-26 International Business Machines Corporation Random access solid-state image sensor with non-destructive read-out
JPS5850030B2 (en) * 1979-03-08 1983-11-08 日本放送協会 Photoelectric conversion device and solid-state imaging plate using it
US4499529A (en) * 1981-05-21 1985-02-12 Figueroa Luisito A Light reflector
JPS6020687A (en) * 1983-07-15 1985-02-01 Nippon Kogaku Kk <Nikon> Electronic still camera
JPS6058780A (en) * 1983-09-09 1985-04-04 Olympus Optical Co Ltd Solid-state image pickup device provided with photometric function
US4742238A (en) * 1985-10-02 1988-05-03 Canon Kabushiki Kaisha Non-linear photoelectric converting apparatus with means for changing drainage performance
US4654714A (en) * 1985-10-30 1987-03-31 Rca Corporation Pixel addressing system
JPS63100879A (en) * 1986-10-17 1988-05-02 Hitachi Ltd Solid-state image pickup device
US4839735A (en) * 1986-12-22 1989-06-13 Hamamatsu Photonics K.K. Solid state image sensor having variable charge accumulation time period
JPH07114474B2 (en) * 1987-01-05 1995-12-06 株式会社東芝 Electronic still camera
US4901129A (en) * 1987-04-10 1990-02-13 Texas Instruments Incorporated Bulk charge modulated transistor threshold image sensor elements and method of making
IL83213A (en) * 1987-07-16 1991-08-16 Technion Res & Dev Foundation Intelligent scan image sensor
US5014107A (en) * 1987-07-29 1991-05-07 Fairchild Semiconductor Corporation Process for fabricating complementary contactless vertical bipolar transistors
US5055418A (en) * 1987-07-29 1991-10-08 National Semiconductor Corporation Process for fabricating complementary contactless vertical bipolar transistors
JPH0666452B2 (en) * 1987-09-04 1994-08-24 株式会社東芝 Method of manufacturing solid-state imaging device
JPH0399589A (en) * 1989-09-13 1991-04-24 Toshiba Corp Solid-state camera
US5021853A (en) * 1990-04-27 1991-06-04 Digital Equipment Corporation N-channel clamp for ESD protection in self-aligned silicided CMOS process
US5276521A (en) * 1990-07-30 1994-01-04 Olympus Optical Co., Ltd. Solid state imaging device having a constant pixel integrating period and blooming resistance
JP3142327B2 (en) * 1991-02-05 2001-03-07 株式会社東芝 Solid-state imaging device and manufacturing method thereof
JP2993144B2 (en) * 1991-02-22 1999-12-20 株式会社デンソー Image sensor
US5335015A (en) * 1992-10-30 1994-08-02 Texas Instruments Incorporated Method for improved dynamic range of BCMD image sensors
US5317174A (en) * 1993-02-19 1994-05-31 Texas Instruments Incorporated Bulk charge modulated device photocell
US5341008A (en) * 1993-09-21 1994-08-23 Texas Instruments Incorporated Bulk charge modulated device photocell with lateral charge drain
US5428390A (en) * 1994-01-21 1995-06-27 Texas Instruments Incorporated Apparatus and method for focal plane zoom and pan
US5475335A (en) * 1994-04-01 1995-12-12 National Semiconductor Corporation High voltage cascaded charge pump
US5589423A (en) * 1994-10-03 1996-12-31 Motorola Inc. Process for fabricating a non-silicided region in an integrated circuit
US5631704A (en) * 1994-10-14 1997-05-20 Lucent Technologies, Inc. Active pixel sensor and imaging system having differential mode
US5541402A (en) * 1994-10-17 1996-07-30 At&T Corp. Imaging active pixel device having a non-destructive read-out gate
US5576763A (en) * 1994-11-22 1996-11-19 Lucent Technologies Inc. Single-polysilicon CMOS active pixel
US5625210A (en) * 1995-04-13 1997-04-29 Eastman Kodak Company Active pixel sensor integrated with a pinned photodiode
US5739562A (en) * 1995-08-01 1998-04-14 Lucent Technologies Inc. Combined photogate and photodiode active pixel image sensor
EP0777379B1 (en) * 1995-11-21 2002-02-20 STMicroelectronics S.r.l. Adaptive optical sensor
US5547881A (en) * 1996-03-06 1996-08-20 Taiwan Semiconductor Manufacturing Company Ltd Method of forming a resistor for ESD protection in a self aligned silicide process
US5705441A (en) * 1996-03-19 1998-01-06 Taiwan Semiconductor Manufacturing Company, Ltd. Ion implant silicon nitride mask for a silicide free contact region in a self aligned silicide process
US5614948A (en) * 1996-04-26 1997-03-25 Intel Corporation Camera having an adaptive gain control
US5986297A (en) * 1996-05-22 1999-11-16 Eastman Kodak Company Color active pixel sensor with electronic shuttering, anti-blooming and low cross-talk

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5614744A (en) * 1995-08-04 1997-03-25 National Semiconductor Corporation CMOS-based, low leakage active pixel array with anti-blooming isolation
WO1998057369A1 (en) * 1997-06-12 1998-12-17 Intel Corporation A well to substrate photodiode for use in a cmos sensor on a salicide process

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
YANG D X D ET AL: "Test structures for characterization and comparative analysis of CMOS image sensors", ADVANCED FOCAL PLANE ARRAYS AND ELECTRONIC CAMERAS, BERLIN, GERMANY, 9-10 OCT. 1996, vol. 2950, ISSN 0277-786X, Proceedings of the SPIE - The International Society for Optical Engineering, 1996, SPIE-Int. Soc. Opt. Eng, USA, pages 8 - 17, XP002107564 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1075028A3 (en) * 1999-08-05 2008-06-04 Canon Kabushiki Kaisha Photoelectric conversion device and process for its fabrication
US7476560B2 (en) 1999-08-05 2009-01-13 Canon Kabushiki Kaisha Photoelectric conversion device, and process for its fabrication
EP2270861A3 (en) * 1999-08-05 2011-02-09 Canon Kabushiki Kaisha Photoelectric conversion device, and process for its fabrication
EP2325887A3 (en) * 1999-08-05 2011-08-03 Canon Kabushiki Kaisha Photoelectric conversion device, and process for its fabrication
US6979435B1 (en) 2001-04-03 2005-12-27 Northwestern University p-Type transparent conducting oxides and methods for preparation

Also Published As

Publication number Publication date
US6160282A (en) 2000-12-12
TW440914B (en) 2001-06-16

Similar Documents

Publication Publication Date Title
US6160282A (en) CMOS image sensor employing silicide exclusion mask to reduce leakage and improve performance
US7405101B2 (en) CMOS imager with selectively silicided gate
EP1075028B1 (en) Photoelectric conversion device and process for its fabrication
EP1649685B1 (en) Cmos imaging for automatic exposure control and correlated double sampling
US7115923B2 (en) Imaging with gate controlled charge storage
US7772027B2 (en) Barrier regions for image sensors
US6548352B1 (en) Multi-layered gate for a CMOS imager
EP1004140A1 (en) A well to substrate photodiode for use in a cmos sensor on a salicide process
JP2006523034A (en) Improved imager light shield
KR100614650B1 (en) Image sensor and method for forming the same
KR20000017459A (en) Solid-state image sensor and method of fabricating the same
US20080220614A1 (en) Method for manufacturing image sensor device
KR100757653B1 (en) Method for fabricating light detecting device

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): KR

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
122 Ep: pct application non-entry in european phase