WO2000018202A1 - Tableau de connexions multicouche d'accumulation - Google Patents
Tableau de connexions multicouche d'accumulation Download PDFInfo
- Publication number
- WO2000018202A1 WO2000018202A1 PCT/JP1999/004895 JP9904895W WO0018202A1 WO 2000018202 A1 WO2000018202 A1 WO 2000018202A1 JP 9904895 W JP9904895 W JP 9904895W WO 0018202 A1 WO0018202 A1 WO 0018202A1
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- Prior art keywords
- layer
- hole
- conductor
- wiring board
- wiring
- Prior art date
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- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920001652 poly(etherketoneketone) Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- -1 polytetrafluoroethylene Polymers 0.000 description 1
- XTFKWYDMKGAZKK-UHFFFAOYSA-N potassium;gold(1+);dicyanide Chemical compound [K+].[Au+].N#[C-].N#[C-] XTFKWYDMKGAZKK-UHFFFAOYSA-N 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 239000003351 stiffener Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- YFNKIDBQEZZDLK-UHFFFAOYSA-N triglyme Chemical compound COCCOCCOCCOC YFNKIDBQEZZDLK-UHFFFAOYSA-N 0.000 description 1
Classifications
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/0213—Electrical arrangements not otherwise provided for
- H05K1/0216—Reduction of cross-talk, noise or electromagnetic interference
- H05K1/0218—Reduction of cross-talk, noise or electromagnetic interference by printed shielding conductors, ground planes or power plane
- H05K1/0224—Patterned shielding planes, ground planes or power planes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
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- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/34—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies not provided for in groups H01L21/0405, H01L21/0445, H01L21/06, H01L21/16 and H01L21/18 with or without impurities, e.g. doping materials
- H01L21/46—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/428
- H01L21/461—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/428 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/4763—Deposition of non-insulating, e.g. conductive -, resistive -, layers on insulating layers; After-treatment of these layers
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- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
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- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/22—Secondary treatment of printed circuits
- H05K3/24—Reinforcing the conductive pattern
- H05K3/244—Finish plating of conductors, especially of copper conductors, e.g. for pads or lands
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- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/40—Forming printed elements for providing electric connections to or between printed circuits
- H05K3/403—Edge contacts; Windows or holes in the substrate having plural connections on the walls thereof
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- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
- H05K3/4602—Manufacturing multilayer circuits characterized by a special circuit board as base or central core whereon additional circuit layers are built or additional circuit boards are laminated
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- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/10—Bump connectors; Manufacturing methods related thereto
- H01L2224/15—Structure, shape, material or disposition of the bump connectors after the connecting process
- H01L2224/16—Structure, shape, material or disposition of the bump connectors after the connecting process of an individual bump connector
- H01L2224/161—Disposition
- H01L2224/16151—Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
- H01L2224/16221—Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
- H01L2224/16225—Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation
- H01L2224/16227—Disposition the bump connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation the bump connector connecting to a bond pad of the item
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- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/26—Layer connectors, e.g. plate connectors, solder or adhesive layers; Manufacturing methods related thereto
- H01L2224/31—Structure, shape, material or disposition of the layer connectors after the connecting process
- H01L2224/32—Structure, shape, material or disposition of the layer connectors after the connecting process of an individual layer connector
- H01L2224/321—Disposition
- H01L2224/32151—Disposition the layer connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
- H01L2224/32221—Disposition the layer connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
- H01L2224/32225—Disposition the layer connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation
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- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/73—Means for bonding being of different types provided for in two or more of groups H01L2224/10, H01L2224/18, H01L2224/26, H01L2224/34, H01L2224/42, H01L2224/50, H01L2224/63, H01L2224/71
- H01L2224/732—Location after the connecting process
- H01L2224/73201—Location after the connecting process on the same surface
- H01L2224/73203—Bump and layer connectors
- H01L2224/73204—Bump and layer connectors the bump connector being embedded into the layer connector
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/15—Details of package parts other than the semiconductor or other solid state devices to be connected
- H01L2924/151—Die mounting substrate
- H01L2924/153—Connection portion
- H01L2924/1531—Connection portion the connection portion being formed only on the surface of the substrate opposite to the die mounting surface
- H01L2924/15311—Connection portion the connection portion being formed only on the surface of the substrate opposite to the die mounting surface being a ball array, e.g. BGA
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- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/0213—Electrical arrangements not otherwise provided for
- H05K1/0237—High frequency adaptations
- H05K1/025—Impedance arrangements, e.g. impedance matching, reduction of parasitic impedance
- H05K1/0253—Impedance adaptations of transmission lines by special lay-out of power planes, e.g. providing openings
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- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/03—Conductive materials
- H05K2201/0332—Structure of the conductor
- H05K2201/0335—Layered conductors or foils
- H05K2201/0347—Overplating, e.g. for reinforcing conductors or bumps; Plating over filled vias
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- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/06—Thermal details
- H05K2201/062—Means for thermal insulation, e.g. for protection of parts
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- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/09—Shape and layout
- H05K2201/09209—Shape and layout details of conductors
- H05K2201/0929—Conductive planes
- H05K2201/093—Layout of power planes, ground planes or power supply conductors, e.g. having special clearance holes therein
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- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/09—Shape and layout
- H05K2201/09209—Shape and layout details of conductors
- H05K2201/095—Conductive through-holes or vias
- H05K2201/09509—Blind vias, i.e. vias having one side closed
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- H05K2201/09—Shape and layout
- H05K2201/09209—Shape and layout details of conductors
- H05K2201/095—Conductive through-holes or vias
- H05K2201/09536—Buried plated through-holes, i.e. plated through-holes formed in a core before lamination
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- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/09—Shape and layout
- H05K2201/09209—Shape and layout details of conductors
- H05K2201/095—Conductive through-holes or vias
- H05K2201/0959—Plated through-holes or plated blind vias filled with insulating material
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- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/09—Shape and layout
- H05K2201/09209—Shape and layout details of conductors
- H05K2201/095—Conductive through-holes or vias
- H05K2201/096—Vertically aligned vias, holes or stacked vias
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- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/09—Shape and layout
- H05K2201/09209—Shape and layout details of conductors
- H05K2201/095—Conductive through-holes or vias
- H05K2201/09645—Patterning on via walls; Plural lands around one hole
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- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/09—Shape and layout
- H05K2201/09209—Shape and layout details of conductors
- H05K2201/09654—Shape and layout details of conductors covering at least two types of conductors provided for in H05K2201/09218 - H05K2201/095
- H05K2201/09681—Mesh conductors, e.g. as a ground plane
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- H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
- H05K2203/11—Treatments characterised by their effect, e.g. heating, cooling, roughening
- H05K2203/1178—Means for venting or for letting gases escape
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- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/02—Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding
- H05K3/06—Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding the conductive material being removed chemically or electrolytically, e.g. by photo-etch process
- H05K3/061—Etching masks
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- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/38—Improvement of the adhesion between the insulating substrate and the metal
- H05K3/382—Improvement of the adhesion between the insulating substrate and the metal by special treatment of the metal
Definitions
- the present invention relates to a multilayer build-up wiring board in which a build-up wiring layer in which an interlayer resin insulating layer and a conductor layer are alternately laminated is formed on both sides of a core substrate, and particularly to a power supply conductor layer (power supply layer). ) Or a multilayer build-up wiring board including a plane layer formed as a grounding conductor layer (ground layer).
- the use of one conductor circuit as a ground layer or power layer can reduce noise. It is performed for the purpose of reduction.
- the plane layer 559 constituting the conductor layer for grounding (ground layer) or the conductor layer for power supply (power supply layer) is meshed with a mesh. It is often used to form a mesh pattern having holes 559 a.
- the mesh holes 559a are provided because the plane layer 559 is formed of copper having low connectivity with resin, and therefore, the interlayer resin insulation layer disposed above the plane layer (see FIG.
- the resin core substrate (not shown) provided in the lower layer can be connected by directly contacting the interlayer resin excellence layer and the core substrate at the mesh holes 559a. Improve. Further, it is for facilitating the emission of the gas composed of the moisture and the like absorbed in the interlayer resin insulating layer through the mesh hole 559a.
- the present inventor has discovered that there is a correlation between the insulating property of the interlayer resin insulating layer and the relative positional relationship of the through holes formed in the upper and lower plane layers. Then, a multilayer build-up wiring board was formed while adjusting the position of the through-hole, and the insulation properties of the interlayer resin insulation layer were measured. As a result, as shown in FIG. 9 (B), the through-hole of the upper plane layer 559 was formed. It was concluded that shifting the mesh holes 555 a of the lower plane layer 559 B and the mesh holes 555 a of the lower plane layer 559 B markedly reduced the glossiness of the interlayer resin insulation layer.
- the present invention has been made to solve the above-described problems, and an object of the present invention is to provide a multi-layer build-up wiring board having a plane layer and having little color fringing deterioration of an interlayer resin yarn edge layer. is there.
- the present invention has been made to solve the above-described problem, and an object of the present invention is to provide a multilayer build-up wire plate that can form a chip mounting area flat with little insulation deterioration of an interlayer resin edge layer. It is in.
- a multi-layer build-up wire board that constitutes a package board for mounting an IC chip, etc., builds up an interlayer resin insulation layer and a conductor layer alternately on a core board having a through-hole formed on the core board. It is formed by arranging bumps for connection to the IC chip and arranging bumps on the lower surface for connecting to the mother port.
- the connection between the upper and lower conductor layers is made by forming via holes, and the upper via hole and the lower via hole in the core substrate are connected to each other through holes. Connection is established through the rule.
- via holes are formed by providing non-through holes in the interlayer resin insulation layer, the number of via holes that can be formed in a multilayer build-up wiring board of a certain size is physically limited. This is one of the factors that hinder high-density wiring in multilayer build-up wiring boards.
- the present invention has been made to solve the above-described problems, and an object of the present invention is to provide a multilayer build-up wiring board capable of increasing the density of wiring.
- Japanese Patent Publication No. 4-55555-55 discloses an epoxy acrylate on a glass epoxy substrate on which a circuit is formed and an interlayer resin yarn.
- a method is proposed in which a conductive layer and via holes are formed by forming via holes using photolithography, roughening the surface, providing a plating resist, and plating. Have been.
- a roughened layer made of a Cu—Ni-P alloy for covering the conductor circuit and the like is formed by electroless plating, and an interlayer resin insulation is formed thereon. Layer was formed.
- the present invention has been made in order to solve such problems of the related art, and an object of the present invention is to prevent concentration of stress due to a temperature change in a formed corner of a conductor circuit.
- a wiring board and a multilayer build-up wiring board configured to prevent cracks from occurring in a resin yarn edge layer. It is in. Disclosure of the invention
- the multilayer build-up five-wire board according to claim 1 is a multilayer build-up wiring board in which interlayer resin layers and conductor layers are alternately laminated.
- a technical feature is that mesh holes are formed in the plurality of plane layers so as to at least partially overlap.
- a plane layer (which functions as a power supply conductor layer or a ground conductor layer) is formed as a conductor layer formed on at least one surface of the core substrate, and at least one of the conductor layers formed between the interlayer resin insulating layers is formed.
- One is to form a plane layer,
- a technical feature is that mesh holes are formed in the plane layer of the core substrate and the plane layer between the interlayer resin thread color edge layers so as to at least partially overlap.
- the diameter of the mesh holes is 75 to 300 m and the distance between the mesh holes is 100 to 150; um according to Claim 1 or 2. Characteristic.
- the insulating property of the interlayer resin insulating layer does not significantly decrease.
- the diameter of the mesh hole is 75 to 300 m. If the diameter is less than 75 m, it will be difficult to overlap the upper and lower mesh holes, while if it exceeds 300 ⁇ m, the power supply conductor layer (power supply layer) or the grounding conductor This is because it does not function as a layer (ground layer). Also, each mesh hole It is desirable that the distance between them is 100 to 150 m. This is because if the distance is less than 100 m, the area of the plane layer becomes small and the function cannot be performed.On the other hand, if the distance exceeds 150 im, the degree of insulation deterioration of the interlayer resin insulation layer becomes significant. This is because it becomes bigger.
- an electroless plating adhesive as the interlayer resin insulating layer.
- This adhesive for electroless plating is obtained by dispersing heat-resistant resin particles soluble in a cured acid or oxidizing agent in an unhardened heat-resistant resin hardly soluble in an acid or oxidizing agent. Things are best.
- the heat-resistant resin particles are dissolved and removed, and a roughened surface made of an octopus pot-like anchor can be formed on the surface.
- the cured heat-resistant resin particles are: 1) a heat-resistant resin powder having an average particle diameter of 10 zm or less, and 2) a heat-resistant resin having an average particle diameter of 2 m or less.
- Agglomerated particles obtained by aggregating the powder 3 a mixture of a heat-resistant resin powder having an average particle diameter of 2 to 10 m and a heat-resistant resin powder having an average particle diameter of 2 am or less, 4 an average particle diameter of 2 to: 10 m pseudo particle obtained by adhering at least one of a heat resistant resin powder and an inorganic powder having an average particle diameter of 2 m or less to the surface of a heat resistant resin powder having an average particle diameter of 0.1 to 0.1 m.
- Examples of the heat-resistant resin hardly soluble in an acid or an oxidizing agent include a “resin composite composed of a thermosetting resin and a thermoplastic resin” or a “resin composite composed of a photosensitive resin and a thermoplastic resin”. Is desirable. This is because the former has high heat resistance, and the latter can form an opening for a via hole by photolithography.
- Epoxy resin, phenolic resin, polyimide resin Fats and the like can be used.
- a thermosetting group such as methacrylic acid or acrylic acid is subjected to an acrylation reaction.
- acrylate of epoxy resin is most suitable.
- a nopolak type epoxy resin such as a phenol novolak type or a cresol nopolak type, or an alicyclic epoxy resin modified with dicyclopentene can be used.
- thermoplastic resins examples include polyethersulfone (PES), polysulfone (PSF), polyphenylene sulfone (PPS), polyphenylene sulfide (PPES), polyphenyl ether (PPE), and polyetherimide (PI). Can be used.
- PES polyethersulfone
- PPS polysulfone
- PES polyphenylene sulfone
- PPES polyphenylene sulfide
- PPE polyphenyl ether
- PI polyetherimide
- the mixing ratio of the curable resin (photosensitive resin) and the thermoplastic resin is preferably set to 95 to 5 to 50 Z50. This is because a high toughness value can be secured without impairing the heat resistance.
- the mixing weight ratio of the heat resistant appearance particles is 5 to 50% by weight, preferably 10 to 40% by weight based on the solid content of the heat resistant resin matrix.
- the heat-resistant resin particles are preferably amino resin (melamine resin, urea resin, guanamine resin), epoxy resin and the like.
- the adhesive may be composed of two layers having different compositions.
- solder resist layer can be added to the surface of the multilayer build-up wiring board.
- resins can be used as the solder resist layer to be added to the surface of the multilayer build-up wiring board.
- bisphenol A type epoxy resin acrylate of bisphenol A type epoxy resin, novolak type epoxy resin, A resin obtained by hardening the acrylate of a polac-type epoxy resin with an amine-based curing agent or an imidazole curing agent can be used.
- solder resist layer is composed of a resin having an oka value skeleton, peeling may occur. For this reason, by providing the reinforcing layer, the solder resist layer can be prevented from peeling off.
- the acrylate of the novolak type epoxy resin an epoxy resin obtained by reacting glycidyl ether of phenol nopolak ⁇ cresol novolac with acrylic acid ⁇ methacrylic acid or the like can be used.
- the imidazole curing agent is desirably liquid at 25 ° C. This is because the liquid can be uniformly mixed.
- liquid imidazole stiffeners examples include 1-benzyl-2-methylimidazole (product name: 1B2MZ), 1-cyanoethyl-2-ethyl-4-methylimidazolile (product name: 2E4MZ-CN), and 4-methyl-2 -Ethyl imidazole (product name: 2E4MZ) can be used.
- the addition amount of the imidazole curing agent is desirably 1 to 10% by weight based on the total solid content of the solder resist composition. The reason for this is that if the added amount is within this range, the uniform mixing is slow.
- a dalicol ether solvent for the composition before curing of the solder resist, it is desirable to use a dalicol ether solvent as a solvent.
- solder resist layer using such a composition does not generate free acid and does not oxidize the surface of the copper pad. It is also less harmful to the human body.
- glycol ether-based solvent one having the following structural formula, particularly preferably at least one selected from diethylene glycol dimethyl ether (DMDG) and triethylene glycol dimethyl ether (DMTG) is used. This is because these solvents can completely dissolve Benzophenone-Michler's ketone as a reaction initiator by heating at about 30 to 50 ° C.
- DMDG diethylene glycol dimethyl ether
- DMTG triethylene glycol dimethyl ether
- the dalicol ether solvent is 10 to 7 parts by weight based on the total weight of the solder resist composition.
- solder resist composition In addition to the solder resist composition described above, various antifoaming agents and repelling agents, heat resistance, thermosetting resin for improving base resistance and flexibility, and photosensitive for improving resolution
- a functional monomer may be added.
- the repelling agent one composed of a polymer of acrylic acid ester is preferable.
- the initiator Irgacure I907 from Ciba-Geigy I, and DETX-S from Nippon Kayaku as the photosensitizer are preferable.
- a dye or a pigment may be added to the solder resist composition. wiring This is because the pattern can be hidden and hidden. It is desirable to use phthalocyanine green as this dye.
- thermosetting resin As an additional component, a bisphenol-type epoxy resin can be used.
- This bisphenol-type epoxy resin includes bisphenol A-type epoxy resin and bisphenol F-type epoxy resin. When the basic resistance is important, the former is required. The latter is better.
- An acrylic monomer can be used as the photosensitive monomer as an additional component. This is because polyacrylic monomers can improve the resolution.
- ⁇ PE-6A manufactured by Nippon Kayaku and R-604 manufactured by Kyoeisha Chemical can be used as the acrylic monomer.
- solder resist compositions are preferably 0.5 to 10 Pa-s at 25 ° C., more preferably 1 to 10 Pa-s. This is because it has a viscosity that can be easily applied over the mouth.
- a fourth aspect of the present invention provides a multilayer structure in which an interlayer resin insulating layer and a conductor layer are alternately laminated, a chip mounting area for mounting a chip is provided on the uppermost layer, and the conductor layers are connected by via holes.
- the build-up wiring board In the build-up wiring board,
- a mesh hole is provided in the plane layer formed as the conductor layer, and at least a part of the mesh hole in a region opposed to the chip mounting region via the interlayer resin insulating layer, and a through hole or
- the technical feature is that the land of the via hole and the pad connecting the via hole are arranged.
- a mesh hole is formed in a region opposing the uppermost chip mounting region in the plane layer via the interlayer resin paper edge layer, and at least a part of the mesh holes is formed. Since the through-holes or via-hole lands and the pads to be connected to the via-holes are provided at an interval from the periphery of the mesh holes, the interlayer resin provided above the plain layer by the mesh holes provided around the lands Since the insulating layer and the interlayer fiber layer (or resin core substrate) provided below are directly in contact with each other, the adhesiveness can be improved. In addition, it is absorbed by the interlayer resin insulation layer through the mesh holes provided on the outer periphery of these lands.
- Claim 5 relates to a multilayer build-up wiring board in which an interlayer shelf layer and a conductor layer are alternately laminated, a chip mounting area for mounting a chip on the uppermost layer, and the conductor layers are connected by via holes.
- a mesh hole is provided in the plane layer formed as the conductor layer, and at least a part of the mesh hole in a region facing the chip mounting region via the interlayer resin insulating layer, and a land of a via hole is formed in the hole.
- a mesh hole is formed in a region facing the uppermost chip mounting region of the plane layer via the interlayer resin edge layer, and at least a part of the mesh holes is formed in the hole.
- the via hole is disposed at the interlayer resin insulating layer and the lower layer which are disposed at the upper layer of the plane layer by the mesh hole provided at the outer periphery of the land of the via hole. Since the interlayer resin insulating layer (or resin core substrate) is brought into direct contact, the adhesiveness can be improved.
- a gas consisting of moisture or the like absorbed in the interlayer resin insulating layer can be radiated through a mesh hole provided on the outer periphery of the land of the via hole, so that it is possible to improve the excellence of the interlayer resin yarn contact layer. Become. Further, since a via hole is formed in the mesh hole in the chip mounting area, no irregularities are formed, and the chip mounting area can be flattened.
- Claim 6 A multilayer build-up wiring board comprising a chip mounting area for mounting a chip on an uppermost layer, wherein an insulating layer and a conductor layer are alternately laminated between layers, and wherein the plane formed as the conductor layer is provided.
- a mesh hole is provided in the layer, and at least a part of the mesh hole in a region opposed to the chip mounting region via the interlayer resin insulating layer, and a bell-shaped conductor layer is provided in the hole. Is a technical feature.
- a mesh hole is formed in a region facing the uppermost chip mounting region in the plane layer via the interlayer resin insulating layer, and the mesh hole is formed.
- the solid conductor layer is arranged on the upper layer of the plane layer by the mesh holes provided on the outer periphery of the solid conductor layer.
- Claim 7 relates to a multilayer build-up wiring board having a chip mounting area for mounting a chip on an uppermost layer, wherein an interlayer resin insulating layer and a conductor layer are alternately laminated on a substrate having a through hole.
- a mesh hole is provided in the plane layer formed as the conductor layer, and at least a part of the mesh hole in a region opposed to the chip mounting region via the interlayer resin layer, and the inside of the hole is formed. It is a technical feature that the land of the through-hole is arranged in this area.
- a mesh hole is formed in a region facing the uppermost chip mounting region in the plane layer via the interlayer resin insulating layer, and a through hole is formed in at least a part of the mesh holes.
- a gas consisting of moisture or the like absorbed in the interlayer resin insulating layer can be diffused through the mesh holes provided on the outer periphery of the land, so that the insulating property of the interlayer resin insulating layer can be improved. Further, since lands are formed in the mesh holes of the chip mounting area, no irregularities are formed, and the chip mounting area can be made flat.
- the plane layer may be opposed to the chip mounting area via at least one or more interlayer resin insulating layers.
- a multilayer wiring layer in which the interlayer layers are alternately laminated with the conductive layers and the conductive layers are connected alternately by via holes is defined as a core.
- the one via hole is formed by a plurality of wiring paths.
- a ninth aspect of the present invention provides a multi-layer structure in which a multi-layer wiring layer is formed on a core substrate, wherein the multi-layer wiring layer is formed by alternately laminating a yarn edge layer and a conductor layer, and connecting the conductor layers by via holes.
- the build-up wiring board In the build-up wiring board,
- a technical feature is that the one via hole is formed by two wiring paths.
- the multilayer build-up wiring board according to claim 9 since one via hole is composed of two wiring paths, a wiring path twice as large as the via hole can be passed through the interlayer resin yarn layer, and the wiring of the multilayer build-up wiring board is provided. Density can be increased.
- an interlayer resin yarn edge layer and a conductor layer are alternately laminated with each other, and a multilayer wiring layer in which each conductor layer is connected by a via hole is formed on a core substrate.
- a multilayer build-up wiring board electrically connected to a conductor layer on the back surface side of the core substrate by through holes formed in the core substrate, a plurality of wiring paths are arranged in one through hole of the core substrate.
- a technical feature is that a via hole composed of a plurality of wiring paths connected to each of the wiring paths is provided immediately above the through hole in which the plurality of wiring paths are provided.
- the multilayer build-up wiring board of claim 10 since a plurality of wiring paths are provided in one through hole, wiring paths several times as large as the through holes can be passed through the core substrate. Since the via hole provided immediately above the via hole is composed of a plurality of wiring paths, wiring paths several times as large as the via holes can be passed through the insulating layer in the interlayer. Therefore, it is possible to increase the density of wiring of the multilayer build-up wiring board. Furthermore, since the via hole is formed immediately above the through hole, the wiring length is shortened, and it is possible to cope with high-speed wiring of a multilayer build-up wiring board.
- Claim 11 is a multilayer wiring layer in which interlayer layers and conductive layers are alternately laminated and each conductive layer is connected by a via hole, wherein the multilayer wiring layers are formed on both sides of the core substrate, and the conductors on both sides of the core substrate are provided.
- a multilayer build-up wiring board in which layers are electrically connected to each other by through holes formed in a core substrate,
- a technical feature is that a via hole composed of a plurality of wiring paths connected to each of the wiring paths is provided immediately above the through hole in which the plurality of wiring paths are provided.
- the multilayer build-up wiring board of claim 11 since a plurality of wiring paths are provided in one through hole, wiring paths several times larger than the through holes can be passed through the core substrate. Since the via hole disposed immediately above the via hole is composed of a plurality of wiring paths, wiring paths several times as large as the via holes can be passed through the interlayer resin insulating layer. Therefore, it is possible to increase the density of wiring of the multilayer build-up wiring board. Further, since the via hole is formed immediately above the through hole, the wiring length is shortened, and it is possible to cope with a high-speed multi-layer build-up wiring board.
- wiring paths several times as large as the through holes can be passed through the core substrate. For this reason, wiring can be integrated at the same pace between the multilayer wiring layer formed on the front side of the core substrate and the multilayer wiring layer formed on the back side, so that the layer between the upper multilayer wiring layer and the lower multilayer wiring layer can be integrated. By making the numbers equal, the number of layers can be minimized.
- a multilayer build-up wiring board in which conductive layers are electrically connected to each other by through holes formed in a core substrate in which conductive layers are electrically connected to each other by through holes formed in a core substrate,
- the through hole of the core substrate is filled with a filler and the filler A conductor layer covering the exposed surface from the through hole is formed,
- the through hole and the conductor layer are divided into a plurality
- a via hole including a wiring path connected to each of the divided conductor layers is provided immediately above the through hole covered with the divided conductor layer.
- a filler is filled in a through hole provided in the core substrate, and further, a conductor layer is formed to cover an exposed surface of the filler from the through hole.
- the via-hole is connected to the via hole to connect the build-up wiring layer and the through-hole.
- a dead space is eliminated by making the area immediately above the through hole function as an inner layer pad, and since there is no need to wire an inner layer pad for connecting the through hole to the via hole, the land shape of the through hole is eliminated. Can be a perfect circle.
- the density of through holes provided in the multilayer core substrate is improved, and the number of through holes can be increased.
- the signal line of the backside 13-layer is connected to the buildup of the front side. You can connect to layers.
- the filler filled in the through hole is preferably made of metal particles and a curable or thermoplastic resin.
- the filler to be filled in the through-holes with the self-made wire plate is preferably made of a metal particle, a force consisting of an i-curable resin and a binder, or a metal particle and a thermoplastic resin.
- a solvent may be added.
- the metal particles are exposed by polishing the surface thereof, and the plating film of the conductor layer formed thereon through the exposed metal particles Since it is integrated with the conductor layer, peeling is less likely to occur at the interface with the conductor layer even under severe high-temperature and high-humidity conditions such as PCT (pressure cooker test).
- PCT pressure cooker test
- metal particles copper, gold, silver, aluminum, nickel, titanium, chromium, tin Z lead, palladium, platinum and the like can be used.
- the metal particles preferably have a particle size of 0.1 to 50 zm. The reason is that if it is less than 0, the copper surface is oxidized and the wettability S to the resin is deteriorated, whereas if it exceeds 50 m, the printability is deteriorated.
- the amount of the metal particles is preferably 30 to 9% by weight based on the total amount. The reason for this is that if the amount is less than 30 wt%, the adhesion of the lid attachment is poor, while if it exceeds 9 Owt%, the printability is poor.
- resins used include epoxy resins such as bisphenol A type and bisphenol F type, phenolic resins, polyimide resins, fluorine resins such as polytetrafluoroethylene (PTFE), bismaleimide triazine (BT) resins, and the like.
- FEP, PFA, PPS, PEN, PES, nylon, aramide, PEEK :, PEKK :, PET, etc. can be used.
- imidazole-based, phenol-based, and amine-based curing agents can be used as the curing agent.
- Solvents include NMP (normal methylpyrrolidone), DMDG (diethylene glycol dimethyl ether), glycerin, water, 1- or 2- or 3-cyclohexanol, cyclohexanone, methylsecsolve, methylsecsolvesolve, methanol , Ethanol, butanol, propanol, etc. can be used.
- NMP normal methylpyrrolidone
- DMDG diethylene glycol dimethyl ether
- glycerin water
- 1- or 2- or 3-cyclohexanol cyclohexanone
- methylsecsolve methylsecsolvesolve
- methanol Ethanol, butanol, propanol, etc.
- the filler is non-conductive. This is because the non-conductive material has a smaller curing shrinkage and is less likely to peel off from the conductive layer or via hole.
- the inventors of the present invention have intensively studied for realizing the above object, and as a result, have conceived an invention having the following content as a gist configuration.
- the wiring board according to claim 13 is a wiring board having a conductor circuit including a conductor layer having a two-layer structure in which a second metal film thinner than the first metal film is stacked on the first metal film.
- the side surface of the second metal film constituting the conductor layer extends outside the side surface of the first metal film.
- the multilayer build-up wiring board according to claim 14 is a multilayer build-up wiring board having a structure in which a resin fiber layer and one or more conductive circuits are formed on a resin substrate, respectively.
- FIGS. 1 (A), 1 (B), 1 (C), and 1 (D) are manufacturing process diagrams of a multilayer build-up wiring board according to the first embodiment of the present invention.
- FIG. 2 (E), FIG. 2 (F), FIG. 2 (G), and FIG. 2 (H) are manufacturing process diagrams of the multilayer build-up wiring board according to the first embodiment of the present invention.
- FIG. 3 (1), FIG. 3 (J), FIG. 3 (K), and FIG. 3 (L) show a multilayer build-up according to the first embodiment of the present invention. It is a manufacturing process figure of a ⁇ wire plate.
- FIG. 4 ( ⁇ ), FIG. 4 ( ⁇ ), and FIG. 4 (0) are manufacturing process diagrams of the multilayer build-up wiring board according to the first embodiment of the present invention.
- FIG. 5 ( ⁇ ) and FIG. 5 (Q) are manufacturing process diagrams of the multilayer build-up wire plate according to the first embodiment of the present invention.
- FIG. 6 is a multilayer build buffer according to the first embodiment of the present invention.
- FIG. 3 is a cross-sectional view of the ⁇ wire plate.
- FIG. 7 ( ⁇ ) is a sectional view taken along the line A- ⁇ of FIG. 6, and FIG. 7 (B) is a sectional view taken along the line BB of FIG.
- FIG. 8 (A) is a cross-sectional view of a multilayer build-up wiring board according to an experimental example of the present invention
- FIGS. 8 (B) and 8 (B) are explanatory views showing the arrangement of mesh holes. Ah You.
- FIG. 9 (A) is a cross-sectional view of a multilayer build-up wire plate according to a first comparative example
- FIG. 9 (B) is an explanatory diagram showing an arrangement of mesh holes in the first comparative example.
- (C) is a plan view of a conventional plane layer.
- FIG. 10 is a graph of an extraordinarily test of an interlayer resin insulating layer of the multilayer build-up wiring board according to the experimental example and the first comparative example.
- FIG. 11 (A), FIG. 11 (B), FIG. 11 (C), and FIG. 11 (D) show a manufacturing process of a multilayer build-up wiring board according to the second embodiment of the present invention.
- FIG. 11 (B), FIG. 11 (C), and FIG. 11 (D) show a manufacturing process of a multilayer build-up wiring board according to the second embodiment of the present invention.
- FIG. 12 (E), FIG. 12 (F), FIG. 12 (G), and FIG. 12 (H) show the manufacturing process of the multilayer build-up wiring board according to the second embodiment of the present invention.
- FIG. 13 (1), FIG. 13 (J), FIG. 13 (K), and FIG. 13 (L) show the manufacture of a multilayer build-up wiring board according to the second embodiment of the present invention. It is a process drawing.
- FIG. 14 ( ⁇ ), FIG. 14 ( ⁇ ), FIG. 14 ( ⁇ ), and FIG. 14 ( ⁇ ) show the manufacture of the multilayer build-up wiring board according to the second embodiment of the present invention. It is a process drawing.
- FIG. 15 (Q), FIG. 15 (R), and FIG. 15 (S) are manufacturing process diagrams of the multilayer build-up self-wired board according to the second embodiment of the present invention.
- FIG. 16 is a sectional view of a multilayer build-up wiring board according to a second embodiment of the present invention.
- FIG. 17 is a multilayer build-up according to a second embodiment of the present invention.
- FIG. 3 is a cross-sectional view of the E-wire plate.
- FIG. 18 (A) is a cross-sectional view taken along line D-D of FIG. 17, and FIG. 18 (B) is an enlarged view of the mesh hole of FIG. 18 (A).
- Figure (C) is an enlarged view of a mesh hole according to a modification.
- FIG. 19 is a cross-sectional view of a multilayer build-up wiring board according to a first modification of the second embodiment.
- FIG. 20 (A) is a cross-sectional view taken along line FF of FIG. 19, and FIG. 20 (B) is an enlarged view of the mesh hole shown in FIG. 20 (A).
- FIG. 0 (C) is an enlarged view of a mesh hole according to a modification.
- FIG. 21 (A) is a multilayer build-up according to a second modification of the second embodiment.
- IH line FIG. 21 (B) is a plan view of a plane layer of the plate, and
- FIG. 21 (B) is an enlarged view of a modified example of the mesh hole shown in FIG. 21 (A).
- FIG. 22 (A) is a plan view of a plane layer of a multilayer build-up wiring board according to a third modification of the second embodiment
- FIG. 22 (B) is a cross-sectional view of the multilayer printed wiring board
- FIG. 22 (C) is a cross-sectional view of a multilayer printed wiring board according to a modification.
- FIG. 23 is a plan view of a plane layer of a multilayer build-up wiring board according to the related art.
- FIGS. 24 (A;), 24 (B), 24 (C), 24 (D), and 24 (E) show the third embodiment of the present invention.
- FIG. 7 is a manufacturing process diagram of such a multilayer build-up wiring board.
- FIG. 25 (F), FIG. 25 (G), FIG. 25 (H), FIG. 25 (1), and FIG. 25 (J) relate to the third embodiment of the present invention.
- FIG. 7 is a manufacturing process diagram of the multilayer build-up wiring board.
- Fig. 26 (K), Fig. 26 (L), Fig. 26 (M), Fig. 26 (N;), Fig. 26 ( ⁇ ) show the third embodiment of the present invention.
- FIG. 4 is a manufacturing process diagram of the multilayer build-up wiring board according to the embodiment.
- FIG. 27 (P), FIG. 27 (Q), FIG. 27 (R), and FIG. 27 (S) show the manufacture of a multilayer build-up self-contained wire according to the third embodiment of the present invention. It is a process drawing.
- FIG. 28 (T), FIG. 28 (U), and FIG. 28 (V) are manufacturing process diagrams of the multilayer build-up wiring board according to the third embodiment of the present invention.
- FIGS. 29 (W), 29 (X), and 29 (Y) are manufacturing process diagrams of the multilayer build-up wiring board according to the third embodiment of the present invention.
- FIG. 30 (ZA), FIG. 30 (ZB), and FIG. 30 (ZC) are manufacturing process diagrams of the multilayer build-up wiring board according to the third embodiment of the present invention.
- FIG. 31 is a sectional view of a multilayer build-up wiring board according to a third embodiment of the present invention.
- FIG. 32 is a cross-sectional view showing a state where an IC chip is mounted on a multilayer build-up wiring board according to a third embodiment of the present invention.
- FIG. 33 (A) is a cross-sectional view taken along the line AA of FIG. 31.
- FIG. 33 (B) is an explanatory view of a via hole of the multilayer build-up self-wired board of the third embodiment.
- FIG. 33 (C) is a cross-sectional view taken along the line CC of FIG. 31, and
- FIG. 33 (D) is a multilayer build-up buffer according to the third embodiment. It is explanatory drawing of the through-hole of E line board.
- FIGS. 34 (A) and 34 (B) are cross-sectional views of a multilayer build-off wire according to a first modification of the third embodiment.
- FIG. 35 (A) is a cross-sectional view of a multilayer build-up 1 ⁇ wire plate according to a first modification of the third embodiment
- FIG. 35 (B) is a cross-sectional view of a through hole and a land according to the first modification. It is a top view.
- FIG. 36 is a cross-sectional view schematically showing one example of the wiring board according to the fourth embodiment of the present invention.
- FIG. 37 (A), FIG. 37 (B), FIG. 37 (C), FIG. 37 (D), and FIG. 37 (E) show the wiring board according to the fourth embodiment.
- FIG. 38 (A), FIG. 38 (B), FIG. 38 (C), and FIG. 38 (D) show the manufacturing process of the multilayer build-up self-wire sheet according to the fourth embodiment. It is sectional drawing which shows a part.
- Fig. 39 (A), Fig. 39 (B), Fig. 39 (C), and Fig. 39 (D) show the multi-layer buildoff according to the fourth embodiment.
- FIG. 40 (A), FIG. 40 (B), FIG. 40 (C), and FIG. 40 (D) show a multilayered build-up of the fourth embodiment. It is sectional drawing which shows a part of manufacturing process of E wire plate.
- FIG. 41 (A), FIG. 41 (B), FIG. 41 (C), and FIG. 41 (D) show one example of the manufacturing process of the multilayer build-up wire plate according to the fourth embodiment. It is sectional drawing which shows a part.
- FIGS. 42 (A), 42 (B), and 42 (C) are cross-sectional views showing a part of the manufacturing process of the multilayer build-up device according to the fourth embodiment. is there.
- FIGS. 43 (A) and 43 (B) are cross-sectional views of the multilayer build-up wiring board obtained in the fourth embodiment.
- the configuration of the multilayer build-up wiring board 10 according to the first embodiment of the present invention will be described with reference to FIG.
- a plane layer 35 that forms a ground layer is formed on the front surface and the back surface of the core substrate 30.
- Build-up wiring layers 80 ⁇ and 80 ⁇ are formed on the front-side plane layer 35 and the back-side plane layer 35.
- the built-up layer 8 OA is composed of a via hole 60, a conductor circuit 58, an interlayer resin insulation layer 50 on which a plane layer 59 serving as a power supply layer is formed, and a noise hole 160 and a conductor circuit 158. It is composed of an interlayer resin layer 150 formed.
- the build-up wiring layer 80 B is formed of the interlayer resin insulation layer 50 on which the via hole 60 and the conductor circuit 58 are formed, and the via hole 160 and the conductor circuit 158 on which the via hole 60 and the conductor circuit 58 are formed. It is composed of an interlayer resin insulation layer 150.
- solder bump 76 U for connecting to a land of an integrated circuit chip (not shown) is provided.
- the solder bump 76 U is connected to the through hole 36 via the via hole 160 and the via hole 60.
- solder bumps 76D are provided on the lower surface to connect to the lands of the Doyuichi board (not shown).
- the solder bump 76 D is connected to the through hole 36 via the via hole 160 and the via hole 60.
- FIG. 7 (A) shows the A-A cross section of FIG. 6, that is, the plane of the plane layer 59 formed on the surface of the interlayer resin insulating layer 50
- FIG. 7 (B) The plane of the plane layer 35 formed on the surface of the core substrate 30 is shown in FIG. 7 (B).
- the plane layer 59 on the surface of the interlayer resin insulation layer 50 is formed with mesh holes 509 having a diameter of 200 m at a pitch P (500 ⁇ m). ing.
- a mesh hole 35 a having a diameter of 200 im is formed on the surface side plane layer 35 of the core substrate 30 at a pitch P (500 m) interval. Is formed.
- a mesh hole 35a is similarly formed on the back surface of the core substrate 30.
- the mesh holes 35a, 35a of the plane layers 35, 35 on both sides of the core board 30, are arranged so that the mesh holes 59 a of the plane layer 59 of the inter-resin insulating layer 50 completely overlap. For this reason, the flexibility of the interlayer resin ⁇ layer 50 does not decrease.
- PES polyether sulfone
- epoxy resin particles manufactured by Sanyo Chemical Co., polymer pole
- NMP 30 parts by weight of NMP was further added, and the mixture was stirred and mixed by a bead mill.
- Bisphenol F-type epoxy monomer i (manufactured by Yuka Shell, molecular weight 310, YL983U) 100 parts by weight, Si_ ⁇ 2 spherical particles having an average particle diameter of 1.6 m to silane force coupling agent on the surface is co one coating (Admatechs Ltd., CRS 1101_CE, where the maximum particle size is 170 parts by weight of the inner layer copper pattern thickness described below (15 ⁇ m or less), and 1.5 parts by weight of a leveling agent (manufactured by San Nopco, Perenol S4) By mixing, the viscosity of the mixture was adjusted to 45,000-49,000 cps at 23 ° C and 1 ° C to obtain.
- Imidazole curing agent (2E4MZ-CN, Shikoku Chemicals) 6.5 parts by weight.
- the viscosity was measured using a B-type viscometer (Tokyo Keiki, DVL-B type) with rotor No. 4 at 60 rpm and Royuichi No. 3 at 6 rpm.
- a manufacturing process of the multilayer build-up wiring board according to the first embodiment will be described with reference to FIGS.
- a multilayer build-up wiring board is formed by a semi-additive method.
- a copper-clad laminate in which 18 m of copper foil 32 is laminated on both sides of a substrate 30 made of lmm thick glass epoxy resin or BT (bismaleimide triazine) resin 3 OA was the starting material.
- the copper-clad laminate 3OA is drilled, subjected to an electroless plating process, and etched in a pattern to form a through hole 36 and a plane layer 35, and the core shown in FIG. 1 (B) is formed.
- the substrate 30 is formed.
- mesh holes 35a are formed in the plane layer 35.
- the resin filler 40 was cured by performing a heat treatment at 100 ° C for 1 hour, 120 ° C for 3 hours, 150 ° C for 1 hour, and 180 ° C for 7 hours.
- the surface layer of the resin filler 40 filled in the through-holes 36 and the like and the roughened layer 38 on the upper surface of the plane layer 35 are removed to smooth both surfaces of the substrate 30, and then the resin filler 40 and the plain A side surface of the layer 35 was firmly adhered through the roughened layer 38, and a wiring board in which the inner wall surface of the through hole 36 and the resin filler 40 were firmly adhered through the roughened layer 38 was obtained. That is, by this step, the surface of the resin filler 40 and the surface of the plain layer 35 are flush with each other.
- the substrate 30 on which the plane layer 35 was formed was alkali-degreased and soft-etched, and then treated with a catalyst solution composed of palladium chloride and an organic acid to provide a Pd catalyst and activate the catalyst.
- a catalyst solution composed of palladium chloride and an organic acid to provide a Pd catalyst and activate the catalyst.
- the raw material composition for preparing an electroless plating adhesive of A was stirred and mixed, and the viscosity was adjusted to 7 Pa ⁇ s to obtain an electroless plating adhesive solution (for upper layer).
- an interlayer resin having a viscosity of 1.5 Pa
- P TJ rim (for lower layer) 44 Apply it with a roll coat overnight, leave it in a horizontal state for 20 minutes, and dry (pre-bake) at 60t: for 30 minutes
- the photosensitive adhesive solution (for upper layer) 46 having a viscosity of 7 Pa ⁇ s obtained in the above (7) within 24 hours after preparation, leave it in a horizontal state for 20 minutes, and then Drying (prebaking) was performed for 30 minutes in the, and 50 adhesive layers with a thickness of 35 m were formed (see Fig. 2 (G)).
- a photomask film (not shown) on which a black circle of 85 ( ⁇ ) is printed is brought into close contact with both surfaces of the substrate 30 on which the adhesive layer has been formed in the above (8). exposed with 500mJZcm 2. This was spray developed with a DMTG solution, further exposing the substrate 30 to a super-high pressure mercury lamp at 3000mJZcm 2, 1 hour at 100 V, 1 hour at 120, then 3 hours at 0.99 ° C By performing a heat treatment (bottoming), a 35 m thick interlayer resin insulation layer (opening for forming a via hole) 48 with an 85 mm ⁇ opening (via hole forming opening) 48 with excellent dimensional accuracy equivalent to a photomask film (See FIG. 2 (5).) A tin plating layer (not shown) was partially exposed in the opening 48 to be a via hole.
- the substrate 30 having the openings 48 formed therein is immersed in chromic acid for 19 minutes to dissolve and remove the epoxy resin particles present on the surface of the interlayer resin yarn edge layer 50, thereby forming the interlayer resin insulation layer 50.
- the surface was roughened (see Fig. 3 (I)), and then immersed in a neutralizing solution (manufactured by Shipley) and then washed with water.
- the electroless plating film 52 under the plating resist is dissolved and removed by etching with a mixed solution of sulfuric acid and hydrogen peroxide.
- a conductor circuit 58, a plane layer 59, and a via hole 60 having a thickness of 18 m comprising an electroless copper plating film 52 and an electrolytic copper plating film 56 were formed (Fig. 4).
- mesh holes 59 a are formed in the plane layer 59 as described above with reference to FIG. 7A, and the mesh holes 59 a are formed on both sides of the core substrate 30. It is formed so as to overlap with the mesh hole 35 a of the formed plane layer 35.
- an upper interlayer resin insulation layer 150, via holes 160, and conductor circuits 158 are further formed to complete a multilayer build-up wiring board (fourth step). (See figure (O)). Note that, in the step of forming the upper conductive circuit, Sn substitution was not performed.
- solder bumps are formed on the above-mentioned multilayer build-up wiring board.
- the solder resist composition described in the above D. is applied in a thickness of 45 m.
- a 5 mm thick photomask film (not shown) on which a circular pattern (mask pattern) is drawn is brought into close contact. placed Te, and exposed to ultraviolet rays of LOOOmJZcm 2, to DMTG development treatment.
- solder-resist layer (thickness: 20 m) 70 having an opening (opening diameter 200 m) 71 is formed (see FIG. 5 (P)).
- nickel chloride 2.31X10 one 1 mo 1/1, p H 4. Electroless five two consisting of sodium hypophosphite 2.8 XlO ⁇ mo 1 / Kuen sodium 1.85X10- 'mo 1 / The substrate 30 was immersed in a solution for attaching to a gel, for 20 minutes, to form a nickel plating layer 72 having a thickness of 5 m in the opening 71.
- the substrate potassium gold cyanide 4.1 X 10 one 2 mo 1/1, chloride Anmoniumu 1.87X10 one 'mo 1Z1, sodium Kuen acid 1.16X10-' mo 1Z1, hypophosphorous acid sodium ⁇ beam 1.7 XLO ⁇ mo
- a solder pad 75 is formed on the conductor circuit 160 (not shown) (see FIG. 5 (Q)).
- solder paste is printed on the opening 71 of the solder resist layer 70 and a riff is formed at 200 ° C to form solder bumps (solder bodies) 76U and 76D, thereby forming a multilayer build-up.
- the self-drawing plate 10 was formed (see FIG. 6).
- FIG. 8 (A) shows a cross section of a multilayer build-up wire plate according to an experimental example of the present invention.
- the multilayer build-up wiring board of this experimental example is formed similarly to the multilayer build-up wiring board 10 of the first embodiment described above. However, in the first embodiment, through holes were formed in the core substrate, but in this experimental example, no through holes were formed.
- the plane layers 135 were formed on the upper and lower surfaces of the core substrate 130, and the upper and lower interlayer resin insulating layers 170 and the outermost interlayer resin insulating layer were formed. Plane layers 179 and 189 are formed on 180, respectively.
- FIG. 8 (B) shows the mesh holes 179 a of the plane layer 179 formed on the interlayer resin insulation layer 170 and the plane layer 1 formed on the outermost interlayer resin insulation layer 180. This shows the correspondence relationship between 89 and the mesh hole 1 89a.
- mesh holes 135 a of the plane layer 135 of the core substrate 130 and meshes of the plane layer 179 The hole 179a is formed so as to overlap the mesh hole 189a of the plane layer 189.
- the mesh holes have a diameter of 250 and are arranged at a pitch of 550.
- FIG. 9 (A) shows a cross section of a multilayer build-up wiring board according to the first comparative example
- FIG. 9 (B) shows a plane layer 17 9 of the multilayer build-up wiring board of the first comparative example.
- the corresponding relationship between the mesh hole 1 79 a of the plane layer 1 89 a and the mesh hole 1 89 a of the plane layer 1 89 is shown.
- the multilayer build-up wiring board of the first comparative example is manufactured in exactly the same manner as the above-described experimental example, but differs from the experimental example shown in FIG. 8 (A) in that the plane layer 13 of the core substrate 130 is formed.
- the 5 mesh holes 1 35 a, the mesh holes 1 79 a of the plane layer 1 79, and the mesh holes 1 89 a of the plane layer 1 89 are arranged so as not to alternately overlap.
- an STEC test was performed as an insulation test.
- the state of 1 atm was maintained for 33 36 hours, and the insulation resistance between the interlayer resin insulation layers was measured.
- the numbers on the vertical axis in the graph indicate multipliers, and the horizontal axis shows the pitch m) between mesh holes and the mesh hole diameter (/ xm).
- Diameter of the mesh hole at 2 5 0 m in Experimental Example it can be maintained when setting the pitch to 5 5 0 m (shown in FIG. (A)) 1 X 1 0 9 ⁇ close insulation resistance I have.
- the insulation resistance is decreased to degrees about 1 X 1 0 8 Omega as shown in FIG. (C).
- the diameter of the mesh hole at 2 5 0 m in Experimental Example when setting the pitch to 5 0 0 m (shown in FIG. (B)) 1 X 1 0 9 to maintain the more insulation resistance ⁇ Has been made.
- ⁇ resistance is lowered to 1 X 1 0 about 8 Omega as shown in FIG.
- Fig. 8 (C) shows the mesh hole 18a of the plane layer 189 formed on the outermost interlayer resin insulation layer 180 and the plane layer formed on the interlayer resin insulation layer 170. The positional relationship between the mesh hole 1 79 and the mesh hole 1 79 a is shown.
- a position error of about 35 m occurs between the upper and lower mesh holes 189a and 179a. Even if a position error of about 35 m occurs, by setting the diameter of the mesh hole to 70 m or more, at least a part of the mesh hole overlaps, so that the insulation resistance of the interlayer resin insulation layer can be increased. .
- the insulation of the interlayer resin insulating layer may be reduced. Disappears.
- FIG. 16 the configuration of the multilayer build-up wiring board 10 according to the second embodiment of the present invention will be described. The description will be made with reference to FIGS. 16, 17, and 18. FIG. 16
- FIG. 16 shows a cross-sectional view of the multilayer printed wiring board 10 before mounting the IC chip.
- FIG. 17 shows an IC chip 90 mounted on the multilayer printed wiring board 10 shown in FIG. , A state in which it is attached to the door board 94.
- a through-hole 36 is formed in the core board 30 and a power layer is formed on the surface (IC chip side) of the core board 30.
- a plane layer 34U is formed, and a plane layer 34D serving as a ground layer is formed on the back surface (the side of the dough board).
- a lower interlayer resin insulation layer 50 having via holes 60 and conductor circuits 58 formed thereon is provided.
- an upper interlayer resin insulation layer 150 having via holes 160 and conductor circuits 158 (only the back side is shown) is arranged.
- solder bumps 76 U for connecting to the lands 92 of the IC chip 90 are provided on the upper surface side of the multilayer printed wiring board.
- the solder bump 76 U is connected to the through hole 36 via the via hole 160 and the via hole 60.
- a solder bump 76 D for connecting to the land 96 of the dough board 94 is provided on the lower surface side.
- the solder bump 76 D is connected to a through hole 36 via a via hole 160 and a via hole 60.
- FIG. 18 shows a DD cross section of FIG. 17, that is, the plane of the plane layer 34 U formed on the surface of the core substrate 30.
- a cross section taken along line E--E in FIG. 18 corresponds to FIG.
- the plane layer 34 U has a region facing the region where the IC chip 90 in FIG. 17 is mounted via an interlayer insulating layer (hereinafter, referred to as “ Outside of C, mesh holes 35a with a diameter of 250 / xm are formed at intervals of P (560 urn).
- a gourd-shaped mesh hole 35b is formed inside the chip mounting area C. This mesh hole 35b is enlarged and shown in Fig. 18 (B).
- a land 36a of the through hole 36 and a via hole (bottom of the via hole) 60a are provided with a gap K of 5 to 50 / xm.
- This land 3 6a and via The pad to which the hole is connected is connected via a conductor circuit 34c.
- a mesh hole 35b is formed in the chip mounting area C of the plane layer 34U, and a through hole 36 is formed in the mesh hole 35b.
- the plane layer is formed at the gap K between the mesh holes 36b provided on the outer periphery of the land 36a and the pad 60a that connects to the via hole. Since the interlayer resin insulating layer 50 provided in the upper layer of the 34 U and the resin core substrate 30 provided in the lower layer are in direct contact, the adhesiveness can be improved.
- the land 36a and the via hole are connected in the hole.
- the pad 60a By arranging the pad 60a, it can be made flat.
- the pad to which the land 36a and the via hole are connected may be integrally formed into a gourd type, a daruma type, or a teardrop type.
- a manufacturing process of the multilayer build-up wiring board according to the second embodiment of the present invention will be described with reference to FIGS. 11 to 16.
- a multilayer build-up wiring board is formed by a semi-additive method.
- an 18 m copper foil 32 is laminated on both sides of a substrate 30 made of glass epoxy resin or BT (bismaleimide triazine) resin having a thickness of l mm.
- Copper-clad laminate 3OA was used as a starting material.
- the copper clad laminate 3OA is drilled, subjected to an electroless plating process, and etched in a pattern to form through holes 36 and plane layers 34U and 34D.
- mesh holes 35a and 35b are formed in plane layers 34U and 34D.
- the land 36a of the through hole 36, the conductor circuit 34c, and the bottom 60a of the via hole are provided in the mesh hole 35b in the chip mounting area C.
- Oxidation-reduction treatment using Na3 P04 (6 g / 1) and NaOH (10 g / l) and NaBH4 (6 g / l) as a reducing bath provides rough surfaces on the plain layers 34 U, 34 D and through holes 36.
- a chemical layer 38 was provided (see Fig. 11 (C)).
- the resin filler 40 obtained in the above (3) is applied to both sides of the substrate 30 within a period of 24 hours after the preparation by using an open-cut method, so that the mesh holes of the conductor circuit (plane layer) 34 are formed. Fill into 35a, 35b and through hole 36, dry at 70 ° C for 20 minutes, and apply resin filler 40 to mesh hole 35a or through hole 36 on the other side in the same manner. And dried by heating at 70 ° C. for 20 minutes (see FIG. 11 (D)).
- the interlayer resin insulating material (for lower layer) 44 obtained in (7) is applied to both surfaces of the substrate of (6), and then the photosensitive adhesive solution obtained in (7) is applied.
- (For the upper layer) 46 was applied to form an adhesive layer 50 ⁇ with a thickness of 35 m (see Fig. 12 (G)).
- a photomask film 51 (FIG. 13 (H)) on which a black circle 51 a is printed is brought into close contact with both surfaces of the substrate 30 on which the adhesive layer is formed in the above (8), and exposed to light.
- an interlayer resin insulating layer (two-layer structure) 50 having a thickness of 35 Aim having an opening (opening for forming a via hole) of 85 ⁇ ⁇ was formed (see FIG. 13 (I)).
- a tin plating layer (not shown) was partially exposed in the opening 48 to be a via hole.
- the substrate 30 in which the openings 48 are formed is immersed in chromic acid for 19 minutes to dissolve and remove the epoxy resin particles present on the surface of the interlayer resin insulating layer 50, thereby obtaining the surface of the interlayer resin insulating layer 50.
- was roughened see Fig. 13 (J)
- a neutralizing solution manufactured by Shipley
- an upper interlayer resin insulation layer (150), via holes (160), and conductor circuits (158) are formed to form a multilayer build-up wiring board. It is completed (see Fig. 14 (P)). Note that Sn was not replaced in the step of forming the upper conductor circuit.
- solder bumps are formed on the above-mentioned multilayer build-up wiring board.
- the same solder resist composition 70 ⁇ as in the first embodiment is applied to both sides of the substrate 30 obtained in (16) in a thickness of 45 m (FIG. 15 (Q)).
- exposure and development are performed to form a solder-resist layer (thickness 20 m) 70 having an opening (opening diameter 200 m) 71 in the solder pad portion (including the via hole and its land portion) (first step). (See Fig. 5 (R)).
- a nickel plating layer 72 was formed. Further, by forming a gold-plated layer 74 having a thickness of 0.03 m on the nickel plating layer, a solder pad 75 is formed in the via hole 160 and the conductor circuit 158 (only the back side is shown). (See Fig. 15 (S)).
- solder paste is printed on the opening 71 of the solder-resist layer 70 and reflowed at 200 ° C, so that solder bumps (solder bodies) 76 U, 76
- the pad 92 of the IC chip 90 is placed so as to correspond to the solder bump 76 U of the completed multilayer printed wiring board 10, and reflow is performed to mount the IC chip 90. Thereafter, an underfill 88 is filled between the IC chip 90 and the multilayer printed wiring board 10.
- the multilayer printed wiring board 10 on which the IC chip 90 is mounted is placed so as to correspond to the bump 96 on the side of the dough pad 94, reflowed, and attached to the dough board 94. Thereafter, an underfill 88 is filled between the multilayer printed wiring board 10 and the daughter board 94.
- FIG. 19 is a sectional view of a multilayer printed wiring board 110 of the first modification.
- the plane layers 34 U and 34 D are provided on both surfaces of the core substrate 30.
- an interlayer resin insulation layer is provided in the multilayer printed wiring board 110 of the first modification. Plane layers 58 U and 58 D are formed on 50.
- a conductor circuit 34 is formed on the front and back surfaces of the core substrate 30, and a lower interlayer resin insulation layer 50 is formed on the conductor circuit 34.
- the plane layers 58 U and 58 D are formed on the lower interlayer resin insulation layer 50.
- the plane layer 58 on the front side (IC chip side) is used as a power supply layer
- the plane layer 58 on the rear side (side of the board) is used as a ground layer.
- an upper interlayer resin insulation layer 150 is formed, and a via hole 160 and a conductor circuit 158 are provided.
- FIG. 20 (A) shows the FF cross section of FIG. 19, that is, the plane of the plane layer 58U formed on the surface of the interlayer resin insulating layer 50.
- the GG section of FIG. 20 (A) corresponds to FIG.
- a mesh hole 59a having a diameter of 200 m is formed in the plane layer 58U outside the chip mounting area C.
- a gourd-shaped mesh hole 59b is formed inside the chip mounting area C.
- FIG. 20 (B) shows the mesh hole 359b in an enlarged manner.
- the mesh hole 59 b there are provided tens of gaps K, and pads (via holes) connected to via holes 60 formed in the interlayer resin insulation layer 50 and via holes formed in the interlayer resin insulation layer 150.
- (Bottom of) 160a is provided. That is, the land 60 of the via hole and the pad 160a connected to the via hole are formed in a body.
- a mesh hole 59 b is formed in the chip mounting area C of the plane layer 58 U, and a land 60 0 of the via hole is formed in the mesh hole 59 b.
- the land 60 of the via hole and the mesh hole 59 provided on the outer periphery of the pad 160a for connecting the via hole 59 at the gap K between the 9b and the plane layer 5
- the interlayer resin insulation layer 150 provided above 8 U and the interlayer resin insulation layer 50 provided below Direct contact improves adhesiveness.
- the water absorbed by the interlayer resin insulation layers 150 and 50 passes through the gap K between the land 60 of the via hole and the mesh hole 59 b provided on the outer periphery of the pad 160 a connected to the via hole. Since the gas composed of components and the like can be diffused, the insulating properties of the interlayer resin insulating layers 50 and 150 can be improved, and the peeling of the interlayer resin insulating layers can be prevented. Furthermore, since land 60 of the via hole and pad 160a for connecting the via hole are formed in mesh hole 59b of chip mounting area C, no irregularities are formed, and the chip mounting area C is flattened. it can. As shown in FIG. 21 (C), the connection between the land 60 of the via hole and the pad 160a to which the via hole is connected may be eliminated so as to form a polished or teardrop shape.
- FIG. 21 is a plan view showing a plane layer 34U formed on the front surface side of the core substrate.
- the mesh holes 35 in which the lands 36 a of the through holes and the pads 60 to which the via holes are connected are arranged. b was drilled.
- not only the gourd-shaped mesh hole 35b but also a circular mesh hole 35c is provided in the chip mounting area C, and the mesh hole 35c is provided in the mesh hole 35c.
- a mesh hole 35c is formed in the chip mounting area C of the plane layer 34U, and the glass conductor layer 34d is formed in the mesh hole 35c.
- the interlayer resin insulation layer 50 provided above the plain layer 34 U and the lower layer provided between the mesh layers 35 c provided on the outer periphery of the cylindrical conductor layer 34 d and the gap between the mesh holes 35 c are provided below. Since the resin core substrate 30 to be formed is brought into direct contact with the resin core substrate 30, the adhesiveness can be improved.
- a gas consisting of moisture and the like absorbed by the interlayer resin insulating layer 50 and the core substrate 30 can be diffused through the gap of the mesh hole 35 c provided on the outer periphery of the cylindrical conductor layer 34 d. Therefore, it is possible to enhance the insulating properties of the interlayer resin insulating layer 50 and the core substrate 30 and to prevent the interlayer resin insulating layer from peeling off. Further, since the bare conductor layer 34 d is formed in the mesh hole 35 c of the chip mounting area C, no irregularities are formed, and the chip mounting area C can be flattened.
- FIG. 22 (A) is a plan view showing a plane layer 34U formed on the front surface side of the core substrate.
- the mesh hole in which the pad 36 to which the land 36 a of the through hole and the via hole are connected is disposed. 35 b was drilled.
- a circular mesh hole 35 d is provided in the chip mounting area C, and only a land 36 a of a through hole is provided in the mesh hole 35 d.
- the cross section of the interlayer resin insulating layer 50 and the core substrate 30 of the third modification is shown in FIG. 22 (B).
- a via hole 60 is formed just above the land 36 a of the through hole 36 formed in the core substrate 30.
- a mesh hole 35 d is formed in the chip mounting area C of the plane layer 34 U, and a land 36 a is provided in the mesh hole 35 d.
- the interlayer resin insulation layer 50 disposed on the upper layer of the plain layer 34 U and the resin core substrate disposed on the lower layer 30 between the mesh holes 35 d provided on the outer periphery of 36 a and the lower layer of the plane layer 34 U Is brought into direct contact, so that the adhesiveness can be improved.
- the gas consisting of the moisture absorbed into the interlayer resin insulating layer 50 and the core substrate 30 can be radiated through the gap of the mesh hole 35 d provided on the outer periphery of the land 36 a, It is possible to increase the edge of the interlayer resin insulating layer 50 and the core substrate 30 and to prevent peeling of the interlayer resin insulating layer.
- the land 36a is formed in the mesh hole 34d of the chip mounting area C, no irregularities are formed, and the chip mounting area C can be flattened. As shown in FIG. 22 (C), the connection may be made via a land 36a of the through hole, a via hole 60, and a conductor layer (cover) 36e covering the force through hole.
- FIG. 31 shows a cross section of a multilayer build-up wiring board (package substrate) 10 before mounting the integrated circuit chip 90
- FIG. 32 shows a multilayer build-up circuit board with the integrated circuit chip 90 mounted.
- 2 shows a cross section of the top wiring board 10.
- an integrated circuit chip 90 is mounted on the upper surface of the multilayer build-up self-wired board 10, and the lower surface is connected to a daughter pad 94.
- the configuration of the multilayer build-up wiring board will be described in detail with reference to FIG.
- build-up wiring layers 80 and 80 are formed on the front and back surfaces of the multilayer core substrate 30.
- the built-up layer 8 OA includes an interlayer resin insulation layer 50 having via holes 60 and conductor circuits 58 a and 58 b formed therein, via holes 16 A and 16 B, and conductor circuits 15 8 B It is composed of a layer 150 of resin thread formed between layers.
- the build-up 1H line layer 80 B is formed of an interlayer resin insulation layer 50 having via holes 60 and conductor circuits 58 a, 58 b, 58 formed therein, and via holes 160 A, 160 B.
- solder bumps 76 UA and 76 UB for connecting to lands 92 (see FIG. 32) of the integrated circuit chip 90 are provided.
- solder bumps 76 DA and 76 DB for connecting to lands 96 (see FIG. 32) of the daughter board (sub-board) 94 are provided.
- FIG. 33 (A) is a cross-sectional view taken along a line A—A in FIG. 31, that is, a plan view of an opening of a via hole 60 provided on the surface of the interlayer resin layer 50
- FIG. 33 (B) is an explanatory diagram showing a perspective view of the via hole 60
- FIG. 33 (C) is a cross-sectional view taken along the line CC of FIG. 31, and is a plan view of an opening of a through hole 36 disposed on the surface of the core substrate 30.
- FIG. 33 (D) is an explanatory view showing the through hole 36 in a perspective view.
- the via hole 60 is divided into two, and two wiring paths 61 a and 61 b are formed.
- the through-hole 36 is divided into two and two wiring paths 3 7a, 3 7b is formed, and semicircular through-hole land 39a, 39b are force-connected to the respective wiring paths 37a, 37b.
- the through-hole lands 39a, 39 are connected to the via hole wiring paths 61a, 61b described above.
- the solder bump 76 UA is connected to the wiring path 37 a of the through hole 36 via the wiring path 61 a of the via hole 16 O A and the via hole 60.
- the wiring path 37a is connected to the solder bump 76DA via the wiring path 61a of the via hole 60 and the via hole 16OA.
- the solder bump 76 UB is connected to the wiring path 37 b of the through hole 36 via the wiring path 61 b of the via hole 160 B and the via hole 60.
- the wiring path 37b is connected to the solder bump 76DB via the wiring path 61b of the via hole 60 and the via hole 160B.
- the lands 39a and 39b formed in the opening of the through hole 36 are formed in a semicircular shape as shown in FIGS. 33 (C) and 33 (D). Then, as shown in FIG. 31, they are connected to wiring paths 61 a and 61 b of via holes.
- the area immediately above the through hole 36 functions as an inner layer pad, eliminating dead space.
- the number of through holes 36 can be increased by increasing the arrangement density of the through holes 36 provided in the multilayer core substrate 30.
- two wiring paths 37a and 37b are provided for each through hole 36, a wiring path twice as large as the through hole can be passed through the core substrate 30.
- the via hole 60 disposed immediately above the through hole 36 is composed of two wiring paths 6 1 a and 6 lb, a wiring path twice as large as the via hole is formed in the interlayer resin layer 50. You can pass. For this reason, a multi-layer build buffer. @ It is possible to increase the density of the wiring on the self-made board. Further, since the via hole 60 is formed immediately above the through hole 36, the wiring length is shortened, and the speed of the multilayer build-up wiring board can be increased.
- the wirings of the plurality of bumps on the back surface are connected to the bumps on the front surface while being integrated, but in the present embodiment, the number of wirings that can pass through one through hole Buildings on the front and back sides by doubling In the wiring layers 90A and 90B, wiring can be integrated at the same pace.
- the number of build-up wiring layers 90 A and 90 B formed on the front side and the back side can be reduced.
- the wiring from the bumps on the front side (IC chip side) is connected to the bumps on the back side (mother board) while being integrated, so the number of bumps on the front side is smaller than the number of bumps on the back side. Many bumps are formed.
- the number of build-up wiring layers 90 A and 90 B formed on the front side and the back side can be made the same (minimum).
- FIGS. 34 and 34 (B) show the case where a build-up multilayer wiring layer is provided on one side.
- the conductor pin 230 is inserted into the through hole 36 and fixed with the solder 232.
- solder-resist 2 3 4 force S is provided on the back side.
- the conductor pin 230 is divided into two parts by an insulator 230c at the center, and the respective surfaces of the conductor pin 230 are connected to the divided wiring paths 37a and 37b of the through hole 36. Electrically connected.
- the wiring paths 37a and 37b are respectively connected to the wiring paths 61a and 61b of the via hole 60, and the wiring paths 61a and 61b force ⁇ via holes 160a and 16b. Connected to solder bumps 76 UA and 76 B via 0 B.
- FIG. 34 (B) shows an example in which solder bumps 76 DB, 76 DA for connection are formed on the side opposite to the side on which the build-up multilayer wiring layer is provided.
- the solder bumps 76DB and 76DA are electrically connected to the divided wiring paths 37a and 37b of the through hole 36.
- the wiring paths 37a and 37b are respectively connected to the wiring paths 61a and 61b of the via hole 60, and the wiring paths 61a and 61b are connected to the via holes 160A and 16b, respectively.
- 0 B is connected to solder bumps 76 UA and 76 B.
- the signal lines from the build-up multilayer wiring layer provided on one side of the core substrate can be directly drawn out to the rear side by the divided wiring paths 37a and 37b of the through hole 36, and the It is possible to improve the degree of freedom of wiring.
- the substrate 30 in which the through-hole 36 made of the electroless copper plating film in (1) is formed is washed with water, dried, and subjected to an oxidation-reduction treatment, and the entire conductor including the through-hole 36 is formed.
- a roughening layer 20 is provided on the surface (see Fig. 24 (D)).
- filler 22 containing copper particles with an average particle diameter of 10 m was printed by through-hole 36 screen printing. Filled, dried and cured (Fig. 24 (E)). Then, the filler 22 protruding from the roughened layer 20 and the through hole 36 on the upper surface of the conductor is removed by belt sanding using # 600 belt polishing paper (manufactured by Sankyo Rikagaku Co., Ltd.). The surface of the substrate 30 is flattened by puff polishing for removal (see FIG. 25 (F)).
- a palladium catalyst (manufactured by Atotech) is applied to the surface of the substrate 30 flattened in the above (3), and electroless copper plating is performed to form an electroless copper plating film 23 having a thickness of 0.6 m. (See Fig. 25 (G)).
- electrolytic copper plating is performed under the same conditions as in the first embodiment to form an electrolytic copper plating film 24 having a thickness of 15 m, and a conductor layer covering the filler 22 filled in the through hole 36. (It becomes a semicircular through-hole land) 26a is formed (Fig. 25 (H)).
- a part of the filler 22 in the through hole 36 is removed by irradiating a short pulse carbon dioxide gas laser of 2 ⁇ 10-4 seconds. Since the through hole 36 is covered with the conductor layer 26a, this serves as a laser mask, and the filler 22 is removed only in the uncovered portion. By removing the filler, the inner wall of the through-hole conductor 36 is exposed (Fig. 26 (K)).
- the same raw material composition for preparing a resin filler as in the first embodiment is mixed and kneaded to obtain a resin filler.
- the resin filler 40 is applied to both sides of the substrate 30 using a roll coater within 24 hours after preparation, and then the resin is applied to the surface of the inner layer copper pattern 34 and the lands 39 a and 39 b of the through hole 36. Polishing was performed so that the filler 40 did not remain, and then puff polishing was performed. (See Figure 26 (O)).
- a Cu—Sn substitution reaction is performed to provide a 0.3 mSn layer (not shown) on the surface of the roughened layer.
- a photomask film (not shown) on which a black circle is printed is brought into close contact with both surfaces of the substrate 30 on which the adhesive layer is formed in the above (15), developed and exposed, and an opening (an opening for forming a via hole) is formed.
- tin plating layer (not shown) is partially exposed in the opening 48 to be a via hole.
- the substrate 30 in which the opening 48 is formed is immersed in chromic acid for 19 minutes to dissolve and remove the epoxy resin particles present on the surface of the interlayer resin insulating layer 50, thereby forming the interlayer resin insulating layer 50. Roughen the surface (see Fig. 27 (S)), then immerse it in a neutralizing solution (manufactured by Shipley) and wash with water.
- the substrate is immersed in an electroless copper plating aqueous solution having the same composition as in the first embodiment to form a 0.6 m-thick electroless copper plating film 52 on the entire rough surface (FIG. 28).
- a commercially available photosensitive dry film is stuck on the electroless copper plating film 52 formed in the above (19), a mask (not shown) having a predetermined pattern is placed thereon, and exposure is performed with lOOmJZcm 2 .
- thickness 15 im A plating resist 54 is provided (see FIG. 28 (V)).
- a conductor circuit 158 and via holes 160A and 160B are formed after further providing an upper interlayer resin yarn edge layer 150 to obtain a multilayer wiring board. See Figure 30 (ZA)). However, Sn substitution is not performed on the roughened surface 62 formed on the surface of the conductor circuit 158 and the via holes 160A and 160B.
- solder resist composition described in the above D. is applied to both surfaces of the substrate 30 obtained in (24) in a thickness of 20 / im. Exposure and development to form a solder resist layer (thickness: 20 m) 70 with openings (opening diameter: 200 m) 71 in the solder pad area (including via holes and their lands) (Fig. 30 (ZB) reference). Further, a reinforcing layer 78 is formed on the solder resist layer 70.
- a nickel plating layer 72 having a thickness of 5 / m is formed in the opening 71 of the solder-resist layer 70. Further, by forming a gold plating layer 74 having a thickness of 0.03 m on the nickel plating layer 72, solder pads 75 are formed on the via holes 160A and 160B and the conductor circuit 158 (see FIG. 30 (ZC)).
- solder paste is printed on the opening 71 of the solder-resist layer 70 and reflowed at 200 ° C, so that solder bumps (solder bodies) 76UA, 7 6 UB, 76 DA, and 76 DB are formed to form a multilayer build-up wiring board 10 (see FIG. 31).
- FIG. 35 (A) is a cross-sectional view showing a configuration of a multilayer build-up wiring board according to a first modification
- FIG. 35 (B) is a through-hole of the multilayer build-up wiring board.
- FIG. 3 is a plan view for explaining the shape of a land 260.
- the through hole land 13 9 of the through hole 13 6 is formed in a circular shape, and pads 13 7 A and 13 7 B for via hole connection are added respectively. Have been.
- wiring paths 260a and 260b of two divided via holes 260 are provided, respectively.
- the wiring path 260a is connected to a pad 258A for connecting to an upper via hole 360 via a conductor circuit 258.
- the wiring path 260b is connected to a pad 258B for connecting to an upper via hole 360 through a conductor circuit 258.
- the wiring density in the interlayer resin insulating layer 350 provided with the via hole 260 can be increased by dividing the via hole 260.
- the via hole and the through hole of the multilayer build-up wiring board are divided into two to provide the wiring path.
- the wiring path may be further divided into three or more to further increase the wiring density. It is.
- the via hole is composed of a plurality of wiring paths, wiring paths several times as large as the dimensional holes can be passed through the interlayer resin insulating layer, and high-density wiring of the multilayer build-up wiring board can be achieved.
- FIG. 36 is a cross-sectional view schematically showing one embodiment of the wiring board of the fourth embodiment.
- a first metal film 222 formed of a thick film is formed on a substrate 221, and the first metal film 222 is formed on the first metal film 222.
- a second metal film 222 that is thinner than 222 is formed, and the side surface of the second metal film 222 protrudes outside the side surface of the first metal film 222 described above.
- the resin layer 224 is formed so as to cover these two-layered conductor layers, the effect of the fourth embodiment is exhibited.
- the material of the fiber substrate 222 is not particularly limited, and may be a substrate made of an inorganic material such as a ceramic or a substrate made of an organic material such as a resin.
- the conductor layer and the resin insulation layer having the structure shown in FIG. 36 may be formed by repeating several layers.
- the method for forming these two-layered conductor layers is not particularly limited, and examples thereof include the following methods.
- the first metal film 222 and the second metal A metal film 222 is formed.
- the first metal film 222 can be etched relatively easily as an etchant, and the second metal film 222 can hardly be etched.
- a conductor layer having a two-layer structure having a shape as shown in FIG. 36 can be formed.
- the above structure is obtained. Is formed.
- This method is a method used in a method for manufacturing a multilayer build-up wiring board according to a fourth embodiment described below.
- a first plating resist 232 is formed on a stripped board 231, etc. (see FIG. 37 (A)).
- the formation of the first plating resist 232 can be performed by using a normal photolithography method.
- a first metal film 233 is formed on a portion where the first plating resist 232 is not formed (see FIG. 37 (B)). Since the first metal film 233 is preferably a thick film, it is desirable to form the first metal film 233 by electroplating, and the thickness thereof is substantially the same as the thickness of the first plating resist 233. Is desirable.
- a second plating resist 234 is formed so as to have a slightly smaller area (see FIG. 37 (C)).
- a second metal film 235 is formed so as to fill the recesses formed by the second plating resist 234 (see FIG. 37 (D)).
- the second metal film 235 needs to be formed also on the first plating resist 232 which is not covered with the second plating resist 234, electroless plating is preferable.
- the multilayer build-up S-wire board of the fourth embodiment is a multilayer build-up wiring board having a structure in which a resin insulating layer and one or more conductor circuits are formed on a resin substrate, respectively.
- One side includes a conductor layer having a two-layer structure in which a second metal film thinner than the first metal film is laminated on the first metal film, and a side surface of the second metal film constituting the conductor layer Are protruding outside the side surfaces of the first metal film.
- a board having a conductor circuit force S formed directly on the resin board is used as the resin board, and a resin thread layer and a conductor circuit are provided thereon respectively. And two or more layers may be provided. Further, a resin substrate on which a conductor circuit is not formed may be used, and a resin insulating layer and a conductor circuit may be respectively provided on the resin substrate, or two or more layers may be provided thereon. Further, the resin edge layer and the conductor circuit may be provided on one surface of the resin substrate, or may be provided on both surfaces.
- a wiring board having a lower conductive circuit on the surface of a resin substrate is manufactured.
- etching is performed using an etching solution comprising a mixed solution of sulfuric acid and hydrogen peroxide or an aqueous solution of sodium persulfate, ammonium persulfate, etc.
- a through hole is formed in the resin substrate by a drill, and a through hole is formed by applying electroless plating to the wall surface of the through hole and the surface of the copper foil. Copper plating is preferred for electroless plating.
- electric plating may be performed for thickening the copper foil. Copper plating is preferable as the electric plating.
- the inner wall of the through hole and the surface of the electroplated film may be roughened. Examples of the roughening treatment include blackening (oxidation), monoreduction treatment, spray treatment with a mixed aqueous solution of an organic acid and a cupric complex, and treatment with Cu-N needle-like alloy plating. .
- a conductive paste may be filled in the through holes, and a conductive layer covering the conductive paste may be formed by electroless plating or electric plating.
- an opening for a via hole is formed by exposing and developing and then thermally curing.
- a via hole can be formed in the interlayer resin insulating layer by performing laser processing after forming the unified resin.
- the surface of the interlayer resin layer is roughened.
- the particles which are soluble in the acid or oxidizing agent present on the surface of the interlayer resin insulating layer are dissolved and removed with an acid or oxidizing agent, and the adhesive for electroless plating is used. Roughen the surface of the layer.
- a catalyst nucleus is applied to the wiring board whose surface is roughened. It is desirable to use a noble metal ion or a noble metal colloid for providing the catalyst nucleus. In general, palladium salt or a palladium colloid is used. It is desirable to perform a heat treatment to fix the catalyst core. Palladium is preferred as such a catalyst core.
- electroless plating is applied to the surface of the interlayer resin edge layer provided with the catalyst nucleus, and an electroless plating film is formed on the entire roughened surface.
- the thickness of the electroless plating film is preferably 0.5 to 5 m.
- a plating resist is formed on the electroless plating film.
- the nickel plating film is formed by electroless nickel plating. Form. This is because an alloy plating consisting of Cu—Ni—P tends to precipitate on the nickel plating film. Also, since the nickel plating film acts as a metal resist, there is an effect that excessive etching is prevented even in the subsequent etching step.
- the substrate from which the plating resist has been removed is etched by dipping in a mixed solution of sulfuric acid and hydrogen peroxide or an aqueous solution of sodium persulfate, ammonium persulfate, etc.
- the electroless plating film existing under the plating resist is removed to make an independent upper layer conductor circuit.
- the electroless nickel plating film is not etched, and the copper plating film is slightly etched.
- a conductor layer having a two-layer structure protruding outside the side surface of the electrolytic copper plating film is formed.
- the roughened layer of the P alloy is likely to precipitate on the nickel plating film, so that the corners become closer to a curved surface, so that stress is less likely to concentrate even when the conductor layer expands or contracts.
- Starting material is a copper-clad laminate in which a substrate made of glass epoxy resin or BT (pismaleimide-triazine) resin with a thickness of l mm is laminated with 18 11 m copper foil 32 on both sides. (See Fig. 38 (A)). First, the copper-clad laminate is drilled, a plating resist is formed, and then the substrate is subjected to an electroless copper plating process to form through holes 36, and further formed into a pattern according to a conventional method. The inner layer conductor circuit 32 is formed on both sides of the base by etching. Was.
- a resin filler 40 containing an epoxy resin as a main component was applied to both sides of the substrate by using a printing machine to fill the space between the inner-layer conductor circuits 34 or the inside of the through-holes 36, followed by heating and drying. That is, in this step, the resin filler 40 is filled between the inner conductor circuits 34 or in the through holes 36 (see FIG. 38 (C)).
- a 2 m-thick porous alloy roughened layer 42 of Cu—Ni—P having a thickness of 2 m was formed on the exposed land of the inner layer conductor circuit 34 and the through hole 36 according to the first embodiment.
- a Sn layer having a thickness of 0.05 m was formed on the surface of the roughened layer 42 in the same manner (see FIG. 39 (A)). However, the Sn layer is not shown.
- the substrate on which the holes for via holes 48 are formed is immersed in a chromic acid aqueous solution (700 g / ⁇ ) at 73 ° C for 20 minutes, and the epoxy resin particles present on the back surface of the interlayer insulating layer 50 are removed. Was dissolved and removed, and the surface was roughened to obtain a roughened surface. After that, they were immersed in a neutralizing solution (manufactured by Shipley) and washed with water (see Fig. 39 (D)).
- a neutralizing solution manufactured by Shipley
- a multilayer build-up wiring board was manufactured in the same manner as in the fourth embodiment except that the step (11) in the fourth embodiment was not performed and a nickel film was not formed.
- a heat cycle test was repeated 0 times. After the test, the multilayer build-up wiring board was cut with a wire saw, and the cross sections of the conductive circuit and the interlayer resin insulating layer were observed with an optical microscope.
- the wiring board of the fourth embodiment since the side surface of the second metal film constituting the conductor layer having the two-layer structure extends outside the side surface of the first metal film, Even when a resin insulating layer is formed on these conductor layers, even when a temperature change or the like occurs due to the structure of the overhanging portion, the corners of the conductor layers are not affected. Stress is not concentrated on the portion, and as a result, it is possible to prevent the occurrence of cracks in the resin insulating layer.
- a multilayer build-up according to the fourth embodiment According to the E-line plate, the side surface of the second metal film constituting the conductor layer of the two-layer structure projects outside the side surface of the first metal film. For this reason, even when a temperature change or the like occurs, stress does not concentrate on the corners of the conductor layer, and as a result, cracks can be prevented from being generated in the resin insulating layer.
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP99943231A EP1137333B1 (en) | 1998-09-17 | 1999-09-08 | Multilayer build-up wiring board |
KR1020017003399A KR20010085811A (ko) | 1998-09-17 | 1999-09-08 | 다층빌드업배선판 |
US09/787,321 US6613986B1 (en) | 1998-09-17 | 1999-09-08 | Multilayer build-up wiring board |
DE69942279T DE69942279D1 (de) | 1998-09-17 | 1999-09-08 | Vielschichtig aufgebaute leiterplatte |
US12/406,009 US7847318B2 (en) | 1998-09-17 | 2009-03-17 | Multilayer build-up wiring board including a chip mount region |
Applications Claiming Priority (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10/283437 | 1998-09-17 | ||
JP28343798A JP4127433B2 (ja) | 1998-09-17 | 1998-09-17 | 多層ビルドアップ配線板及び多層ビルドアップ配線板の製造方法 |
JP32453598A JP2000133941A (ja) | 1998-10-28 | 1998-10-28 | 多層ビルドアップ配線板 |
JP10/324535 | 1998-10-28 | ||
JP10/362961 | 1998-12-21 | ||
JP36296198A JP2000188447A (ja) | 1998-12-21 | 1998-12-21 | 配線基板およびプリント配線板 |
JP11/315 | 1999-01-05 | ||
JP00031599A JP4127440B2 (ja) | 1999-01-05 | 1999-01-05 | 多層ビルドアップ配線板 |
Related Child Applications (3)
Application Number | Title | Priority Date | Filing Date |
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US09787321 A-371-Of-International | 1999-09-08 | ||
US09/787,321 A-371-Of-International US6613986B1 (en) | 1998-09-17 | 1999-09-08 | Multilayer build-up wiring board |
US10/334,062 Division US7514779B2 (en) | 1998-09-17 | 2002-12-31 | Multilayer build-up wiring board |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2000018202A1 true WO2000018202A1 (fr) | 2000-03-30 |
Family
ID=27453142
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1999/004895 WO2000018202A1 (fr) | 1998-09-17 | 1999-09-08 | Tableau de connexions multicouche d'accumulation |
Country Status (8)
Country | Link |
---|---|
US (3) | US6613986B1 (ja) |
EP (2) | EP1868423A1 (ja) |
KR (4) | KR20090059173A (ja) |
CN (1) | CN1318274A (ja) |
DE (1) | DE69942279D1 (ja) |
MY (2) | MY141631A (ja) |
TW (1) | TW453146B (ja) |
WO (1) | WO2000018202A1 (ja) |
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1999
- 1999-09-08 WO PCT/JP1999/004895 patent/WO2000018202A1/ja active Application Filing
- 1999-09-08 CN CN99811085A patent/CN1318274A/zh active Pending
- 1999-09-08 US US09/787,321 patent/US6613986B1/en not_active Expired - Lifetime
- 1999-09-08 KR KR1020097011027A patent/KR20090059173A/ko active Search and Examination
- 1999-09-08 EP EP07115803A patent/EP1868423A1/en not_active Withdrawn
- 1999-09-08 KR KR1020017003399A patent/KR20010085811A/ko active Search and Examination
- 1999-09-08 KR KR1020087005013A patent/KR20080023369A/ko not_active Application Discontinuation
- 1999-09-08 EP EP99943231A patent/EP1137333B1/en not_active Expired - Lifetime
- 1999-09-08 KR KR1020087005014A patent/KR20080024239A/ko active Application Filing
- 1999-09-08 DE DE69942279T patent/DE69942279D1/de not_active Expired - Lifetime
- 1999-09-13 TW TW088115730A patent/TW453146B/zh not_active IP Right Cessation
- 1999-09-16 MY MYPI20044069A patent/MY141631A/en unknown
- 1999-09-16 MY MYPI99004017A patent/MY123224A/en unknown
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2002
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8161636B2 (en) | 2007-10-12 | 2012-04-24 | Fujitsu Limited | Circuit board and method of manufacturing the same |
US8186053B2 (en) | 2008-11-14 | 2012-05-29 | Fujitsu Limited | Circuit board and method of manufacturing the same |
Also Published As
Publication number | Publication date |
---|---|
KR20090059173A (ko) | 2009-06-10 |
US20030102151A1 (en) | 2003-06-05 |
CN1318274A (zh) | 2001-10-17 |
DE69942279D1 (de) | 2010-06-02 |
EP1868423A1 (en) | 2007-12-19 |
EP1137333A4 (en) | 2004-03-24 |
US7847318B2 (en) | 2010-12-07 |
US6613986B1 (en) | 2003-09-02 |
KR20080024239A (ko) | 2008-03-17 |
KR20080023369A (ko) | 2008-03-13 |
EP1137333B1 (en) | 2010-04-21 |
MY141631A (en) | 2010-05-31 |
KR20010085811A (ko) | 2001-09-07 |
US7514779B2 (en) | 2009-04-07 |
MY123224A (en) | 2006-05-31 |
US20090173523A1 (en) | 2009-07-09 |
TW453146B (en) | 2001-09-01 |
EP1137333A1 (en) | 2001-09-26 |
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