WO2001013428A1 - Method for fabrication of enlarged stacked dram capacitors - Google Patents

Method for fabrication of enlarged stacked dram capacitors Download PDF

Info

Publication number
WO2001013428A1
WO2001013428A1 PCT/US2000/020359 US0020359W WO0113428A1 WO 2001013428 A1 WO2001013428 A1 WO 2001013428A1 US 0020359 W US0020359 W US 0020359W WO 0113428 A1 WO0113428 A1 WO 0113428A1
Authority
WO
WIPO (PCT)
Prior art keywords
dielectric layer
holes
layer
forming
recited
Prior art date
Application number
PCT/US2000/020359
Other languages
French (fr)
Inventor
Young-Jin Park
Heon Lee
Original Assignee
Infineon Technologies North America Corp.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Infineon Technologies North America Corp. filed Critical Infineon Technologies North America Corp.
Publication of WO2001013428A1 publication Critical patent/WO2001013428A1/en

Links

Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B12/00Dynamic random access memory [DRAM] devices
    • H10B12/01Manufacture or treatment
    • H10B12/02Manufacture or treatment for one transistor one-capacitor [1T-1C] memory cells
    • H10B12/03Making the capacitor or connections thereto
    • H10B12/033Making the capacitor or connections thereto the capacitor extending over the transistor

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Semiconductor Memories (AREA)

Abstract

In accordance with the present invention, a method for expanding holes for the formation of stacked capacitors is described and claimed. The method includes the steps of providing a planarized dielectric layer (120) for forming bottom electrodes of the stacked capacitors, forming a first dielectric layer (130) on the planarized dielectric layer, forming a second dielectric layer (132) on the first dielectric layer. The second dielectric layer is selectively etchable relative to the first dielectric layer. The steps of etching the second dielectric layer to form holes (134) for forming the bottom electrodes and isotropically etching the second dielectric layer to expand the holes for forming the bottom electrodes are also included.

Description

METHOD FOR FABRICATION OF ENLARGED STACKED DRAM CAPACITORS
BACKGROUND
1. Technical Field
This disclosure relates to semiconductor memory fabrication and more particularly, to a method for fabricating enlarged stacked capacitors by employing isotropic etching.
2. Description of the Related Art
Semiconductor memory cells include capacitors accessed by transistors to store data. Data is stored as a high or low bit depending on the state of the capacitor cell. The capacitor's charge or lack of charge indicates a high or low when accessed to read data, and the capacitor is charged or discharged to write data from the capacitor through a bit- line sense amplifier circuit.
Stacked capacitors are among the types of capacitors used in semiconductor memories, for example, dynamic random access memories (DRAM). Stacked capacitors are typically located on top of the cell transistor used to access a storage node of the capacitor as opposed to trench capacitors which are buried in the substrate of the device. Higher cell capacitance is beneficial for improving data sensing margin in DRAM devices.
In semiconductor memories, such as dynamic random access memories (DRAM) which include stacked capacitors, an area for a memory cell is proportional to the size of a stacked capacitor. For sub-8F2 stacked capacitor DRAMs, i.e., DRAMs with memory cells occupying an area of less than 8F2 where F is a minium feature size of a given technology, the projected area of capacitor is drastically decreased. For example, only IF2 of area for a 4F2 cell is available for the stacked capacitor and only 2F2 of area for a 6F2 cell is available for the stacked capacitor, while 3F2 of area is available for the stacked capacitor in a 8F2 cell. Thus, cell capacitance is also drastically decreased with the decrease minimum feature size (F) and also the decrease of cells in a layout .
Referring to FIG. 1, a layout for 8F2 memory cells each having a stacked capacitor is shown. In the layout, stacked capacitors 10 are disposed in rows and columns. Active areas 12 are shown between pairs of stacked capacitors 10. Active areas 12 are surrounded by shallow trench isolation regions 14.
Referring to FIG. 2, a cross-sectional view is shown taken at section line 2-2 of FIG. 1. FIG. 2 illustratively depicts the major elements of the 8F2 memory cells. Stacked capacitors 10 are shown having a top electrode 16, a bottom electrode 18 and a capacitor dielectric layer 20 therebetween.
Bottom electrode 18 is connected to a plug 22 which extends down to a portion of active area 12. Active areas 12 form an access transistor for charging and discharging stacked capacitor 10 in accordance with data on a bitline 24. Bitline 24 is coupled to a portion of active area 12 (source or drain of the access transistor) by a contact 23. When a gate conductor 28 is activated the access transistor conducts and charges or discharges stacked capacitor 10. When F is reduced with each new generation of DRAM design, stacked capacitor 12 loses area thereby reducing the capacitors capabilities. A typical capacitor area for an 8F2 memory cell is equal to about 3F2.
Referring to FIG. 3, a layout for 6F2 memory cells each having a stacked capacitor is shown. In the layout, stacked capacitors 30 are disposed in rows and columns. Active areas 32 are shown between pairs of stacked capacitors 30, similar to FIG. 1. Active areas 32 are surrounded by narrower shallow trench isolation regions 34.
Referring to FIG. 4, a cross-sectional view is shown taken at section line 4-4 of FIG. 3. FIG. 4 illustratively depicts the major elements of the 6F2 memory cells. Stacked capacitors 30 are shown having a top electrode 36, a bottom electrode 38 and a capacitor dielectric layer 40 therebetween. Bottom electrode 38 is connected to a plug 42 which extends down to a portion of active area 32. Active areas 32 form an access transistor for charging and discharging stacked capacitor 30 in accordance with data on a bitline 44. Bitline 44 is coupled to a portion of active area 32 (source or drain of the access transistor) by a contact 43. When a gate conductor 48 is activated the access transistor conducts and charges or discharges stacked capacitor 30. Stacked capacitors 30 are smaller than those of the 8F2 memory cells. When F is reduced with each new generation of DRAM design, stacked capacitor 30 losses area thereby reducing the capacitors capabilities. A typical capacitor area for a 6F2 memory cell is equal to about 2F2.
Therefore, a need exists for a method for increasing or maintaining stacked capacitor area while reducing the size of memory cells.
SUMMARY OF THE INVENTION
In accordance with the present invention, a method for expanding holes for the formation of stacked capacitors includes the steps of providing a planarized dielectric layer for forming bottom electrodes of the stacked capacitors, forming a first dielectric layer on the planarized dielectric layer, forming a second dielectric layer on the first dielectric layer, the second dielectric layer being selectively etchable relative to the first dielectric layer, etching the second dielectric layer to form holes for forming the bottom electrodes and isotropically etching the second dielectric layer to expand the holes for forming the bottom electrodes .
A method for forming stacked capacitors for a semiconductor memory device, in accordance with the present invention, includes the steps of providing a substrate having a planarized dielectric layer formed on access transistors, the planarized dielectric layer having conductive plugs disposed therein for connecting to the access transistors, forming a first dielectric layer on a top surface of the planarized dielectric layer, forming a second dielectric layer which is selectively etchable relative to the first dielectric layer, patterning holes in the second dielectric layer by selectively etching the second dielectric layer relative to the first dielectric layer and isotropically etching the holes in the second dielectric layer to expand the holes to provide an increased surface area within the holes over a surface area formed by the selectively etching the second dielectric layer.
Another method for forming stacked capacitors for a dynamic random access memory device includes the steps of providing a substrate having a planarized glass layer formed on access transistors, the planarized glass layer having conductive plugs disposed therein for connecting to the access transistors, forming a nitride layer on a top surface of the planarized glass layer, forming an oxide layer which is selectively etchable relative to the nitride layer, depositing a resist layer on the oxide layer, patterning the resist layer by forming openings in the resist over locations for the conductive plugs, anisotropically etching holes in the oxide layer by selectively etching the oxide layer relative to the nitride layer, isotropically etching the holes in the oxide layer to expand the holes to provide an increased surface area within the holes over a surface area formed by the selectively etching the oxide layer, removing the resist layer, removing portions of the nitride layer in the holes to expose the conductive plugs, depositing a conductive layer in the holes to form a bottom electrode for the stacked capacitors, and depositing a capacitor dielectric layer on the conductive layer.
In alternate methods, the first dielectric layer may include a nitride (or aluminum oxide) and the second dielectric layer may include an oxide. The steps of removing portions of the first dielectric layer in the holes, depositing a conductive layer in the holes to form the bottom electrode and depositing a capacitor dielectric layer on the conductive layer are preferably included. The step of isotropically etching may include employing wet etching or chemical dry etching. The wet etch process may employ HF, diluted HF or BHF. The chemical dry etching may include CF4- 02, C2F6, CH4-I2 (Br2, Cl2), CH4-Br2(Cl2) , CBrF3, CF3C1, CF2C12, HC1 or NF3-He. Other etchants are also contemplated for both wet and dry etching. The step of isotropically etching may include the step of expanding the holes such that a surface area of the holes is increased by a factor greater than 1. The step of isotropically etching may include the step of expanding the holes such that lateral sidewalls of the second dielectric layer adjacent to the holes are recessed by a distance of at least about one third a minimum feature size for a given technology. The holes are preferably tapered. The step of isotropically etching may include the step of forming a stepped portion in the holes. A stacked capacitor formed in accordance with these methods is also included.
These and other objects, features and advantages of the present invention will become apparent from the following detailed description of illustrative embodiments thereof, which is to be read in connection with the accompanying drawings .
BRIEF DESCRIPTION OF DRAWINGS
This disclosure will present in detail the following description of preferred embodiments with reference to the following figures wherein:
FIG. 1 is a conventional layout for 8F2 memory cells; FIG. 2 is a cross-sectional view taken at section line 2-2 of FIG. 1 showing stacked capacitors in accordance with the prior art;
FIG. 3 is a conventional layout for 6F memory cells;
FIG. 4 is a cross-sectional view taken at section line 4-4 of FIG. 3 showing stacked capacitors in accordance with the prior art;
FIG. 5 is a layout for 4F2 memory cells;
FIG. 6 is a cross-sectional view taken at section line 6-6 of FIG. 5 showing stacked capacitors;
FIG. 7 is a cross-sectional view of a memory device having 6F2 memory cells and showing a planarized glass layer for employing the present invention;
FIG. 8 is a cross-sectional view of the memory device of FIG. 7 showing conductive plugs formed for use with the present invention;
FIG. 9 is a cross-sectional view of the memory device of FIG. 8 showing a first dielectric layer formed on a top surface of the glass layer for employing the present invention;
FIG. 10 is a cross-sectional view of the memory device of FIG. 9 showing a second dielectric layer formed on the first dielectric layer for employing the present invention; FIG. 11 is a cross-sectional view of the memory device of FIG. 10 showing the second dielectric layer having capacitor holes formed therein for employing the present invention;
FIG. 12 is a cross-sectional view of the memory device of FIG. 11 showing the second dielectric layer isotropically etched in accordance with the present invention;
FIG. 13 is a cross-sectional view of the memory device of FIG. 12 showing a bottom electrode layer and a capacitor dielectric layer deposited in accordance with the present invention;
FIG. 14 is a cross-sectional view of a 4F2 memory cell device showing a bottom electrode layer and a capacitor dielectric layer deposited on which the present invention may be employed;
FIG. 15 is a cross-sectional view of a 4F2 -memory cell device showing a bottom electrode layer and a capacitor dielectric layer deposited in accordance with the present invention;
FIG. 16 is a cross-sectional view of a memory device showing a dielectric layer having tapered capacitor holes formed therein for employing the present invention;
FIG. 17 is a cross-sectional view of the memory device of FIG. 16 showing the dielectric layer isotropically etched in accordance with the present invention; FIG. 18 is a cross-sectional view of the memory device of FIG. 17 showing a bottom electrode layer and a capacitor dielectric layer deposited in accordance with the present invention; and
FIG. 19 is a cross-sectional view of the memory device of FIG. 18 showing the memory device after a chemical mechanical polish process to isolate the bottom electrodes in accordance with the present invention.
DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS
The present invention relates to semiconductor memory fabrication and more particularly, to a method for fabricating enlarged stacked capacitors by employing isotropic etching. The present invention includes methods for increasing capacitor area, while satisfying other design rules for fabricating a semiconductor memory device. A projected area of a stacked capacitor is enlarged by employing an additional isotropic etch. In this way electrodes are formed in larger openings forming stacked capacitors with increased area. In one embodiment, the stacked capacitor has an area about 2 times greater than the prior art stacked capacitors in 4F cells employing the present invention.
Referring now in specific detail to the drawings in which like reference numerals identify similar or identical elements throughout the several views, and initially to FIG. 5, a layout for 4F2 memory cells each having a stack capacitor is shown. In the layout, stacked capacitors 50 are disposed in rows and columns. Active areas 52 are vertically disposed to provide vertical access transistors 53 (FIG. 6). The layout shown is described in detail in a commonly assigned U.S. Application entitled "METHOD FOR FABRICATING 4F2 MEMORY CELLS WITH IMPROVED GATE CONDUCTOR", Attorney Docket: 99E7510US (8706-289), filed concurrently herewith and incorporated herein by reference.
Referring to FIG. 6, a cross-sectional view is shown taken at section line 6-6 of FIG. 5. FIG. 6 illustratively depicts the major elements of the 4F2 memory cells. Stacked capacitors 50 are shown having a top electrode 58, a bottom electrode 60 and a capacitor dielectric layer 62 therebetween.
Bottom electrode 60 is connected to a plug 64 which extends down to a portion of active area 52. Active areas 52 form vertical access transistors 53 for charging and discharging stacked capacitor 50 in accordance with data on a buried bitline 58. Shallow trench isolation regions 54 isolate gate conductors 56 from buried bitline 58. When gate conductors 56 are activated vertical access transistor 53 conducts and charges or discharges stacked capacitor 50. Stacked capacitors 50 are smaller than those of the 6F2 memory cells. When F is reduced with each new generation of DRAM design, stacked capacitor 50 loses area thereby reducing the capacitors capabilities. A capacitor area for a 4F2 memory cell is equal to about IF2.
Referring to FIG. 7, the present invention will now be described for a semiconductor memory having 6F2 memory cells. The following description is applicable to 8F2 cells and other cell areas having similar structure. A semiconductor memory device 100, such as a dynamic random access memory, includes a substrate 102. Substrate 102 is preferably a monocrystalline silicon substrate. Other materials may be used as well, for example gallium arsenide, silicon on insulator, etc. Shallow trench isolation regions 104 are formed in substrate 102. Substrate 102 also includes doped regions or active areas 106 for forming an access transistor. A gate oxide layer 107 is formed over the surface of substrate 102.
Polysilicon or other conductive layers are deposited on substrate 102 for forming gate structures 108. Gate structures 108 preferably include a polysilicon layer 110 and a metal layer 112. Metal layer 112 may include tungsten, molybdenum, or their suicides. A cap 114 (nitride or oxide) and spacers 116 (nitride or oxide) are formed over polysilicon layer 110 and metal layer 112. A dielectric layer 120 is deposited over gate structures 108 to fill in gaps and planarized to prepare a top surface 122. Dielectric layer 120 preferably conforms to gate structures 108. In a preferred embodiment, dielectric layer 120 includes a glass, such as borophospho-silicate glass (BPSG) or high density plasma (HDP) oxide .
Referring to FIG. 8, dielectric layer 120 is etched to form contact holes 124 down to active areas 106 in substrate 102. A conductive material is deposited in contact holes 124 to form plugs 126. Conductive material preferably includes polysilicon. A top surface 128 of dielectric layer 120 is planarized to remove remaining conductive material and to smooth the surface.
Referring to FIG. 9, a dielectric layer 130 is deposited on top surface 128. Dielectric layer 130 preferably includes a nitride, such as silicon nitride. Dielectric layer 130 may include an oxide, such as silicon oxide, Aluminum oxide or silicon oxy-nitride. Dielectric layer 130 is deposited in accordance with the present invention to protect capacitor contacts during an isotropic etching which will be described in greater detail below. Dielectric layer 130 may be between about 50 A to about 200 A although other thicknesses may be employed.
Referring to FIG. 10, a dielectric layer 132 is deposited on dielectric layer 130. Dielectric layer 132 is selectably etchable relative to dielectric layer 130. In a preferred embodiment, an oxide, such as silicon oxide is used to form dielectric layer 132. Then, dielectric layer 130 is preferably a nitride (or Aluminum oxide) . However, if a nitride is used for dielectric layer 132, an oxide layer should be used for dielectric layer 130. Dielectric layer 132 is deposited with a thickness H. H is preferably between about IF to about 4F. Other thicknesses may be employed.
Referring to FIG. 11, dielectric layer 132 is patterned to form capacitor bottom electrode holes 134. A resist layer 133 is formed on dielectric layer 132, and patterned to expose portions of dielectric layer 132 to be removed. Etching holes 134 is preferably performed by an anisotropic etch process such as reactive ion etching (RIE) . In a preferred embodiment, the distance D between plugs 126 is preferably about one minimum feature size, F, although other distance may be formed, and dielectric layer 132 includes a portion 136 occupying this distance.
Referring to FIG. 12, an isotropic etch is performed to enlarge holes 134. This is performed while resist 133 is present to protect a top surface of dielectric layer 132 from the isotropic etch process. The isotropic etch step is included to enlarge a capacitor area by enlarging holes 134. Since the space between two adjacent capacitors is D, a distance of about D/3 is recessed back on each side of portions 136. This amount of material may be removed without causing any interference. More or less of portion 136 may be removed depending on design requirements. The isotropic etch process may include a wet or dry etch. The wet etch process may employ HF, diluted HF or BHF. The chemical dry etching may include CF4-02, C2F6, CH4-I2 (Br2, Cl2) , CH4-Br2 (Cl2) , CBrF3, CF3C1, CF2C12, HC1 or NF3-He.
Referring to FIG. 13, dielectric layer 130 is now etched selective to dielectric layer 132 and using dielectric layer 132 as an etch mask. Bottom electrodes 140 are formed by depositing a conductive material, such as platinum, to line the sides and bottom of enlarged holes 134. A chemical mechanical polish is performed to remove material form the top surface and to isolate bottom electrodes 140 from each other.
A capacitor dielectric layer 142 is formed on bottom electrodes 140. A top electrode (not shown) will be formed in later steps. Processing continues from this point as is known in the art .
Referring to FIG. 14, a cross-section of a stacked capacitor structure implemented with 4F2 memory cells is shown.
The layout shown is described in detail in the commonly assigned U.S. Application, Attorney Docket: 99E7510US (8706- 289), previously incorporated herein by reference. Stacked capacitor structures are shown having a bottom electrode 60 and a capacitor dielectric layer 62 formed. Bottom electrode 60 is connected to a plug 64 which extends down to a portion of active area 52. Active areas 52 form vertical access transistors 66 for charging and discharging the stacked capacitor in accordance with data on a buried bitline 58. Shallow trench isolation regions 54 isolate gate conductors 56 from buried bitline 58. When gate conductors 56 are activated vertical access transistor 66 conducts and charges or discharges the stacked capacitor. An oxide layer includes portions 72 between adjacent bottom electrodes 60. This distance is typically about F, the minimum feature size. An approximated calculation for capacitor area may be computed by determining the surface area of the bottom electrode 60. If the distance described for bottom electrode 60 is indeed F and a height h of the bottom electrode is given, the capacitor area may be calculated as follows:
Capacitor Area -4-F-h
If F is .15 microns and h is .4 microns than the capacitance area is about .2625 square microns.
Referring to FIG. 15, bottom electrodes 202 are shown in accordance with the present invention. Holes 204 for supporting bottom electrodes 202 have been isotropically etched in accordance with the present invention. Bottom electrodes 202 are deposited in holes 204. A stepped portion 203 is advantageously formed which increases capacitance area further. A dielectric layer 210 is formed over bottom electrodes 202.
The distance between bottom electrodes 202 has been decreased making a bottom portion 206 increased in area. In one illustrative embodiment, dimension "A" is about 5/3 F. Other increased dimensions are also contemplated. Using the 5/3 F dimension and h for the capacitor height, a calculation of capacitor area may be performed as before.
Capacitor Area = (25/9) F2 +4(5/3-F)-h
If F is .15 microns and h is .4 microns than the capacitance area is about .4625 square microns. This represents an increase in capacitor area of about 1.8 times. For 4 F2 memory cells, capacitor areas of about 2.8 F2 can be achieved. For 6F2 memory cells, capacitor areas of about 4.4 F2 can be achieved. For 8 F2 memory cells, capacitor areas of about 6.1 F2 can be achieved. These are significant improvements for capacitor areas which were about, I F2 , 2 F2 and 3 F2 , respectively.
Referring to FIG. 16, an alternate method for forming stacked capacitor structure using isotropic etching in accordance with the present invention is shown. The method is illustratively shown for 4F2 memory cells, however, this method is applicable to other types of memory cells. Since depositing bottom electrode materials is strongly dependent on the geometrical shape of the surface to be deposited on, a tapered trench structure 300 is preferable. Tapered holes 302 are etched into dielectric layers 304 and 305 which is preferably, an oxide. Tapered holes 302 are etched by an anisotropic process such as a dry etch process.
Referring to FIG. 17, after etching tapered holes 302, isotropic etching is performed in accordance with the invention. The isotropic etching includes the same processes as described above. The isotropic etch enlarges the area for the capacitor electrodes which will be formed in later steps.
Referring to FIGS. 18 and 19, a conductive layer 308 is deposited in tapered holes 302 on layer 304. As shown in FIG. 18, tips 312 are polished to isolate bottom electrodes 314. A chemical mechanical polish (CMP) may be employed to perform this. This is followed by a capacitor dielectric layer 310 deposition. Processing continues from this point as is known in the art.
Having described preferred embodiments for methods for fabrication of enlarged stacked capacitors using isotropic etching (which are intended to be illustrative and not limiting) , it is noted that modifications and variations can be made by persons skilled in the art in light of the above teachings. It is therefore to be understood that changes may be made in the particular embodiments of the invention disclosed which are within the scope and spirit of the invention as outlined by the appended claims. Having thus described the invention with the details and particularity required by the patent laws, what is claimed and desired protected by Letters Patent is set forth in the appended claims .

Claims

HAT IS CLAIMED IS:
1. A method for expanding holes for the formation of stacked capacitors comprising the steps of: providing a planarized dielectric layer for forming bottom electrodes of the stacked capacitors; forming a first dielectric layer on the planarized dielectric layer; forming a second dielectric layer on the first dielectric layer, the second dielectric layer being selectively etchable relative to the first dielectric layer; etching the second dielectric layer to form holes for forming the bottom electrodes; and isotropically etching the second dielectric layer to expand the holes for forming the bottom electrodes.
2. The method as recited m claim 1, wherein the first dielectric layer includes one of a nitride and Aluminum oxide and the second dielectric layer includes an oxide.
3. The method as recited in claim 1, further comprising the steps of: removing portions of the first dielectric layer in the holes; depositing a conductive layer m the holes to form the bottom electrode; and depositing a capacitor dielectric layer on the conductive layer.
4. The method as recited in claim 1, wherein the step of isotropically etching includes employing one of a wet etch and a chemical dry etch process.
5. The method as recited in claim 1, wherein the step of isotropically etching includes the step of expanding the holes such that a surface area of the holes is increased by a factor greater than 1.
6. The method as recited in claim 1, wherein the step of isotropically etching includes the step of expanding the holes such that lateral sidewalls of the second dielectric layer adjacent to the holes are recessed by a distance of at least about one third a minimum feature size for a given technology.
7. The method as recited in claim 1, wherein the holes are tapered.
8. The method as recited in claim 1, wherein the step of isotropically etching includes the step of forming a stepped portion in the holes.
9. A stacked capacitor formed in accordance with the method of claim 1.
10. A method for forming stacked capacitors for a semiconductor memory device comprising the steps of: providing a substrate having a planarized dielectric layer formed on access transistors, the planarized dielectric layer having conductive plugs disposed therein for connecting to the access transistors; forming a first dielectric layer on a top surface of the planarized dielectric layer; forming a second dielectric layer which is selectively etchable relative to the first dielectric layer; patterning holes in the second dielectric layer by selectively etching the second dielectric layer relative to the first dielectric layer; and isotropically etching the holes in the second dielectric layer to expand the holes to provide an increased surface area within the holes over a surface area formed by the selectively etching the second dielectric layer.
11. The method as recited in claim 10, wherein the first dielectric layer includes one of a nitride and Aluminum oxide and the second dielectric layer includes an oxide.
12. The method as recited in claim 10, further comprising the steps of: removing portions of the first dielectric layer in the holes to expose the conductive plugs; depositing a conductive layer in the holes to form a bottom electrode for the stacked capacitors; and depositing a capacitor dielectric layer on the conductive layer.
13. The method as recited in claim 10, wherein the step of isotropically etching includes employing one of a wet etch and a chemical dry etch process.
14. The method as recited in claim 10, wherein the step of isotropically etching includes the step of expanding the holes such that lateral sidewalls of the second dielectric layer adjacent to the holes are recessed by a distance of at least about one third a minimum feature size for a given technology.
15. The method as recited in claim 10, wherein the holes are tapered.
16. The method as recited in claim 10, wherein the step of isotropically etching includes the step of forming a stepped portion m the holes.
17. A stacked capacitor formed in accordance with the method of claim 10.
18. A method for forming stacked capacitors for a dynamic random access memory device comprising the steps of: providing a substrate having a planarized glass layer formed on access transistors, the planarized glass layer having conductive plugs disposed therein for connecting to the access transistors; forming a nitride layer on a top surface of the planarized glass layer; forming an oxide layer which is selectively etchable relative to the nitride layer; depositing a resist layer on the oxide layer; patterning the resist layer by forming openings m the resist over locations for the conductive plugs; anisotropically etching holes m the oxide layer by selectively etching the oxide layer relative to the nitride layer; isotropically etching the holes in the oxide layer to expand the holes to provide an increased surface area within the holes over a surface area formed by the selectively etching the oxide layer; removing the resist layer; removing portions of the nitride layer in the holes to expose the conductive plugs; depositing a conductive layer in the holes to form a bottom electrode for the stacked capacitors; and depositing a capacitor dielectric layer on the conductive layer.
19. The method as recited in claim 18, wherein the step of isotropically etching includes employing one of a wet etch and a chemical dry etch process.
20. The method as recited in claim 18, wherein the step of isotropically etching includes the step of expanding the holes such that lateral sidewalls of the second dielectric layer adjacent to the holes are recessed by a distance of at least about one third a minimum feature size for a given technology.
21. The method as recited in claim 18, wherein the holes are tapered.
22. The method as recited in claim 18, wherein the step of isotropically etching includes the step of forming a stepped portion in the holes.
PCT/US2000/020359 1999-08-16 2000-07-26 Method for fabrication of enlarged stacked dram capacitors WO2001013428A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/374,538 1999-08-16
US09/374,538 US6294436B1 (en) 1999-08-16 1999-08-16 Method for fabrication of enlarged stacked capacitors using isotropic etching

Publications (1)

Publication Number Publication Date
WO2001013428A1 true WO2001013428A1 (en) 2001-02-22

Family

ID=23477280

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2000/020359 WO2001013428A1 (en) 1999-08-16 2000-07-26 Method for fabrication of enlarged stacked dram capacitors

Country Status (2)

Country Link
US (1) US6294436B1 (en)
WO (1) WO2001013428A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1443617A1 (en) 2003-01-28 2004-08-04 Weidmüller Interface GmbH & Co. KG Support rail arrangement for electrical cabinets

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11251540A (en) * 1998-02-26 1999-09-17 Oki Electric Ind Co Ltd Semiconductor device and its manufacture
JP3287346B2 (en) * 1999-11-29 2002-06-04 カシオ計算機株式会社 Semiconductor device
US6486505B1 (en) * 2000-03-24 2002-11-26 Infineon Technologies, Ag Semiconductor contact and method of forming the same
JP4963750B2 (en) * 2000-08-10 2012-06-27 ルネサスエレクトロニクス株式会社 Semiconductor integrated circuit device
US6391711B1 (en) * 2000-10-03 2002-05-21 Vanguard International Semiconductor Corporation Method of forming electrical connection between stack capacitor and node location of substrate
US6545904B2 (en) * 2001-03-16 2003-04-08 Micron Technology, Inc. 6f2 dram array, a dram array formed on a semiconductive substrate, a method of forming memory cells in a 6f2 dram array and a method of isolating a single row of memory cells in a 6f2 dram array
JP3718458B2 (en) * 2001-06-21 2005-11-24 セイコーエプソン株式会社 Manufacturing method of semiconductor device
US8253183B2 (en) 2001-06-28 2012-08-28 Samsung Electronics Co., Ltd. Charge trapping nonvolatile memory devices with a high-K blocking insulation layer
US7253467B2 (en) * 2001-06-28 2007-08-07 Samsung Electronics Co., Ltd. Non-volatile semiconductor memory devices
US20060180851A1 (en) 2001-06-28 2006-08-17 Samsung Electronics Co., Ltd. Non-volatile memory devices and methods of operating the same
DE10228768A1 (en) * 2001-06-28 2003-01-16 Samsung Electronics Co Ltd Non-volatile floating trap storage device comprises a semiconductor substrate, a tunnel insulation layer on the substrate, a charge storage layer, a barrier insulation layer, and a gate electrode
US7473959B2 (en) * 2001-06-28 2009-01-06 Samsung Electronics Co., Ltd. Non-volatile semiconductor memory devices and methods of fabricating the same
TWI222720B (en) * 2003-09-19 2004-10-21 Promos Technologies Inc DRAM process and structure
US7476920B2 (en) * 2004-12-15 2009-01-13 Infineon Technologies Ag 6F2 access transistor arrangement and semiconductor memory device
KR101338158B1 (en) * 2007-07-16 2013-12-06 삼성전자주식회사 Non-volatile memory devices and methods of forming the same
US8030215B1 (en) * 2008-02-19 2011-10-04 Marvell International Ltd. Method for creating ultra-high-density holes and metallization
JP2009206418A (en) * 2008-02-29 2009-09-10 Elpida Memory Inc Nonvolatile memory device and manufacturing method for the same

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03174767A (en) * 1989-09-13 1991-07-29 Oki Electric Ind Co Ltd Manufacture of semiconductor memory device
US5332685A (en) * 1992-06-24 1994-07-26 Hyundai Electronics Industries Co., Ltd. Method of manufacturing a DRAM cell
US5497017A (en) * 1995-01-26 1996-03-05 Micron Technology, Inc. Dynamic random access memory array having a cross-point layout, tungsten digit lines buried in the substrate, and vertical access transistors
US5702974A (en) * 1994-07-18 1997-12-30 Hyundai Electronics Industries Co., Ltd. Method for fabricating capacitor of semiconductor device
DE19904781A1 (en) * 1998-02-06 1999-08-12 Sony Corp Dielectric capacitor especially a ferroelectric capacitor for a RAM

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63146461A (en) 1986-12-10 1988-06-18 Mitsubishi Electric Corp Semiconductor memory device
US5250458A (en) 1987-02-25 1993-10-05 Mitsubishi Denki Kabushiki Kaisha Method for manufacturing semiconductor memory device having stacked memory capacitors
US4855953A (en) 1987-02-25 1989-08-08 Mitsubishi Denki Kabushiki Kaisha Semiconductor memory device having stacked memory capacitors and method for manufacturing the same
US5623243A (en) * 1990-03-20 1997-04-22 Nec Corporation Semiconductor device having polycrystalline silicon layer with uneven surface defined by hemispherical or mushroom like shape silicon grain
DE4131078A1 (en) 1990-11-19 1992-05-21 Micron Technology Inc Capacitor structure for DRAM cell - has two types of spacers with two sides, supporting subsequently formed layers respectively
US5236860A (en) 1991-01-04 1993-08-17 Micron Technology, Inc. Lateral extension stacked capacitor
KR920018987A (en) 1991-03-23 1992-10-22 김광호 Manufacturing method of capacitor
DE4235996A1 (en) 1992-10-24 1994-04-28 Degussa Titanium dioxide mixed oxide produced by flame hydrolysis, process for its preparation and use
KR0132859B1 (en) * 1993-11-24 1998-04-16 김광호 Method for manufacturing capacitor of semiconductor
JPH1070252A (en) * 1996-08-27 1998-03-10 Mitsubishi Electric Corp Semiconductor device and method of fabricating the same
JP3466851B2 (en) * 1997-01-20 2003-11-17 株式会社東芝 Semiconductor device and manufacturing method thereof
KR100273987B1 (en) * 1997-10-31 2001-02-01 윤종용 Dynamic random access memory device and manufacturing method thereof
KR19990043605A (en) 1997-11-29 1999-06-15 이경하 Aromatic Amidine Derivatives Useful as Selective Thrombin Inhibitors
TW357457B (en) * 1998-02-21 1999-05-01 United Microelectronics Corp Manufacturing method for DRAM capacitors
US5879987A (en) 1998-02-21 1999-03-09 Wang; Chuan-Fu Method of fabricating dynamic random access memory having a stacked capacitor
US6077742A (en) * 1998-04-24 2000-06-20 Vanguard International Semiconductor Corporation Method for making dynamic random access memory (DRAM) cells having zigzag-shaped stacked capacitors with increased capacitance
US6037213A (en) * 1998-06-03 2000-03-14 Taiwan Semiconductor Manufacturing Company, Ltd. Method for making cylinder-shaped capacitors for dynamic random access memory
TW430981B (en) * 1999-03-30 2001-04-21 Taiwan Semiconductor Mfg Manufacture method of stack capacitor

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03174767A (en) * 1989-09-13 1991-07-29 Oki Electric Ind Co Ltd Manufacture of semiconductor memory device
US5332685A (en) * 1992-06-24 1994-07-26 Hyundai Electronics Industries Co., Ltd. Method of manufacturing a DRAM cell
US5702974A (en) * 1994-07-18 1997-12-30 Hyundai Electronics Industries Co., Ltd. Method for fabricating capacitor of semiconductor device
US5497017A (en) * 1995-01-26 1996-03-05 Micron Technology, Inc. Dynamic random access memory array having a cross-point layout, tungsten digit lines buried in the substrate, and vertical access transistors
DE19904781A1 (en) * 1998-02-06 1999-08-12 Sony Corp Dielectric capacitor especially a ferroelectric capacitor for a RAM

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
MORIHARA T ET AL: "DISK-SHAPED STACKED CAPACITOR CELL FOR 256 MB DYNAMIC RANDOM-ACCESSMEMORY", JAPANESE JOURNAL OF APPLIED PHYSICS,JP,PUBLICATION OFFICE JAPANESE JOURNAL OF APPLIED PHYSICS. TOKYO, vol. 33, no. 8, PART 01, 1 August 1994 (1994-08-01), pages 4570 - 4575, XP000595078, ISSN: 0021-4922 *
PATENT ABSTRACTS OF JAPAN vol. 015, no. 419 (E - 1126) 24 October 1991 (1991-10-24) *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1443617A1 (en) 2003-01-28 2004-08-04 Weidmüller Interface GmbH & Co. KG Support rail arrangement for electrical cabinets

Also Published As

Publication number Publication date
US6294436B1 (en) 2001-09-25

Similar Documents

Publication Publication Date Title
US6294436B1 (en) Method for fabrication of enlarged stacked capacitors using isotropic etching
US5491103A (en) Method for manufacturing a capacitor structure of a semiconductor memory device
US7888725B2 (en) Electronic devices including electrode walls with insulating layers thereon
US6165864A (en) Tapered electrode for stacked capacitors
US5770499A (en) Planarized capacitor array structure for high density memory applications
US6355520B1 (en) Method for fabricating 4F2 memory cells with improved gate conductor structure
US6696336B2 (en) Double sided container process used during the manufacture of a semiconductor device
JP2776331B2 (en) Semiconductor device and manufacturing method thereof
US5793077A (en) DRAM trench capacitor with recessed pillar
EP0682372A1 (en) DRAM device with upper and lower capacitor and production method
JP4282101B2 (en) Self-aligned multi-crown memory capacitor and manufacturing method thereof
US7078292B2 (en) Storage node contact forming method and structure for use in semiconductor memory
US20060199332A1 (en) Method of forming storage node of capacitor in semiconductor memory, and structure therefor
US6097055A (en) Capacitor and method for fabricating the same
KR19990078136A (en) Dram cell arrangement and process for producing thereof
US6188096B1 (en) DRAM cell capacitor having increased trench capacitance
US6150213A (en) Method of forming a cob dram by using self-aligned node and bit line contact plug
US5539230A (en) Chimney capacitor
US6607954B2 (en) Methods of fabricating cylinder-type capacitors for semiconductor devices using a hard mask and a mold layer
US6844229B2 (en) Method of manufacturing semiconductor device having storage electrode of capacitor
US6930345B2 (en) Increase in deep trench capacitance by a central ground electrode
US6011286A (en) Double stair-like capacitor structure for a DRAM cell
US6136716A (en) Method for manufacturing a self-aligned stacked storage node DRAM cell
KR100458988B1 (en) Memory cell unit and method of producing same
US6753252B2 (en) Contact plug formation for devices with stacked capacitors

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): CN JP KR

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: JP