WO2002004823A1

WO2002004823A1 - Coated contoured crushable structural members and methods for making the same

Info

Publication number: WO2002004823A1
Application number: PCT/US2001/021342
Authority: WO
Inventors: Dale Francis Obeshaw
Original assignee: Delphi Technologies, Inc.
Priority date: 2000-07-07
Filing date: 2001-07-05
Publication date: 2002-01-17
Also published as: US20020062546A1; WO2002004823A8; EP1301721A1; US20050019597A1; WO2002004823A9; JP2004506537A; EP1301721A4

Abstract

Coated cored contoured crushable structural members and methods for making the same are described. The contoured structural members comprise composite or metal materials sandwiching a support or stabilizing structure. The cored and contoured structure can be provided by tube rolling (or roll wrapping) the composite or metal materials and the support structure together and then, if necessary, bonding them or connecting them. The coating for the coated structure is provided in or on the materials making up the structural member. The structural members are made crushable by incorporating an initiator into the structural member. The structural member crushes at the location of the initiator by absorbing the energy of an exerting load. With a coated, contoured, crushable, and generally non-flat structure, applications and uses for the structural members of the present invention are nearly limitless.

Description

COATED CONTOURED CRUSHABLE STRUCTURAL MEMBERS AND METHODS FOR MAKING THE SAME

[01] REFERENCES TO RELATED APPLICATIONS

[02] This application claims priority from U.S. provisional patent application number

60/216,636, the entire disclosure of which is incorporated herein by reference.

[03] FIELD OF THE INVENTION

[04] The present invention relates to structural members and methods for making the

same. In particular, the present invention relates to cored crushable contoured structural

members and methods for making the same. Specifically, the present invention relates to

such structural members that are coated and methods for making the same.

[05] BACKGROUND OF THE INVENTION

[06] In recent years there has been an increasing emphasis on the use of lightweight

materials. One application, for example, has been their use to improve the efficiency of

motor vehicles. To that end, the United States Government and the U.S. Council for

Automotive Research (USCAR) — which represents Daimler Chrysler, Ford, and General

Motors have partnered to form the Partnership for a New Generation of Vehicles

(PNGN). One goal of PΝGN is to develop technology, such as composite technology,

that can be used to create environmentally friendly vehicles with up to triple the fuel

efficiency, while providing today's affordability, performance and safety. For example, PNGN wants to improve the fuel efficiency of today's vehicles from about 28 miles per

gallon (mpg) to about 83 mpg and a 40-60% decrease in the present curb weight (3200

pounds).

[07] One method to improve the fuel efficiency is to decrease the weight of today's

vehicles and use lighter weight materials. The materials used in today's vehicles, such as

steel and aluminum, are quite heavy relative to composite materials, but have been

necessary to provide sufficient structural properties, including tensile, compression,

flexural, interlaminar shear, and in-plane shear strengths and other mechanical and

material properties, to meet vehicle design requirements.

[08] Many other applications of lightweight materials have been made to supplement

or replace the use of structural materials, such as steel, cast iron, and aluminum. These

include buildings, bridges, recreational vehicles, aerospace, defense, and sporting goods,

as well as many other applications.

[09] As well, tubes of lightweight materials above have been used as structural

members to reduce the weight and increase the energy absorbing characteristics. The

structural characteristics, however, of such tubes containing such lightweight materials

are still fairly limited when compared to more traditional structural materials.

[10] One way to increase the structural properties of materials, particularly the

torsional or flexural strength, is to make them in a more structurally efficient form. In

one structurally efficient form, metals like aluminum and steel have been combined with

a supporting structure, such as a honeycomb core material, by sandwiching the honeycomb between panels of the metal. Examples of such combinations have been

described in U.S. Patent Nos. 4,291,205, 5,140,913, 5,192,623, 5,635,306, 5,875,596, and

5,899,037, the disclosures of which are incorporated herein by reference. In another

structurally efficient form, composite materials have been combined with a supporting

structure, such as a honeycomb or foam structure, by sandwiching the supporting

structure between panels of the composite material. Examples of such combinations have

been described in U.S. Patent Nos. 5,006,391, 5,195,779, 5,652,039, 5,834,082,

5,848,767, 5,849,122, and 5,875,609, the disclosures of which are incorporated herein by reference.

[11] Such combinations, however, have been generally limited to relatively flat

structures and so applications of such materials have been quite limited. As well, the

structural members have not contained additional components on their surface(s) that

would have enhanced their use for applications other than just solely as structural

members.

[12] SUMMARY OF THE INVENTION

[13] The present invention provides coated cored contoured crushable structural

members and methods for making the same. The contoured structural members comprise

composite or metal materials sandwiching a support or stabilizing structure. The cored

and contoured structure can be provided by tube rolling (or roll wrapping) the composite

or metal materials and the support structure together and then, if necessary, bonding them or connecting them. The coating for the coated structure is provided in or on the

materials making up the structural member. The structural members are made crushable

by incorporating an initiator into the structural members. The structural member crushes

at the location of the initiator by absorbing the energy of an exerting load. With a coated,

contoured, crushable, and generally non-flat structure, applications and uses for the

structural members of the present invention are nearly limitless.

[14] BRIEF DESCRIPTION OF THE DRAWINGS

[15] Figures 1-28 are views of various aspects of structural members and methods of

making the same according to the present invention. Figures 1-28 presented in

conjunction with this description are views of only particular — rather than complete —

portions of the structural members and methods of making the same.

[16] DETAILED DESCRIPTION OF THE INVENTION

[17] The following description provides specific details in order to provide a thorough

understanding of the present invention. The skilled artisan, however, would understand

that the present invention can be practiced without employing these specific details.

Indeed, the present invention can be practiced by modifying the illustrated structural

member and method and can be used in conjunction with apparatus and techniques

conventionally used in the industry. [18] Figure 1 illustrates one contoured structural member — a tubular member with a

substantially circular cross-section — according to the present invention, i the context of

the present invention, a "contoured" structural member is any shape, size, or

configuration where at least one portion of the outer or inner periphery of such member is

substantially non-flat, including curved, geometric or irregular. Preferably, the contoured

structural members have a closed surface configuration, such as a surface facilitating their

manufacture as explained below, hi the context of the present invention, a "closed"

structural member is one having any shape, size, or configuration where at least one

portion of the surface (inner and/or outer) of such member is a substantially closed or

substantially continuous. Examples of a closed configuration include a tubular,

substantially spherical, polygonal, conical, or other similar shape, as well as those

illustrated and described herein.

[19] The structural members of the present invention may have a cylindrical or a non-

cylindrical configuration such as cones, pyramid, pods, hemispheres or spheres. The

structural members of the present invention may also have a circular or a non-circular

cross-section such as rectangular, square, hexagonal, octagonal, or the like. They may

also comprise very irregular, non-closed, substantially planar surfaces. Indeed, the

structural members of the present invention could have any complex contoured shape or

combination of contoured shapes. The structural members of the present invention are

characterized by the fact that they are substantially non-flat and thereby distinguished

from known sheet-shaped cored composite structures. {2 } In Figure 1, tubular structural member 2 comprises inner section or portion 4,

intermediate section or portion 6, outer section or portion 8, and optional core region 10.

Inner portion 4, outer portion 8, and optional core region 10, can be made of any suitable

composite material as described below. Intermediate portion 6 is a "cored" structure that

attaches to and supports and/or stabilizes the inner and outer portions.

[21] Core region 10 is located in an inner section of structural member 2 and, as

described below, is about the size of the substrate or mandrel used in forming the

structural member. Core region 10 can be of any suitable size, shape, or configuration

depending primarily on the removable mandrel(s) in the manufacturing process used to

make structural member 2, the configuration of structural member 2, and the desired end

application of structural member 2.

[22] Core region 10 may be hollow, but may optionally be partially or completely filled

with any desired core material such as foam, plastic, conducting or insulating materials,

metals and/or the like, as well as the coating described below. Core region 10 containing

the core material may be a structural element. The core material may also be added after

structural member 2 is formed, or formed integrally into the structure. If the core material

is added after the formation of structural member 2, it may be attached to structural

member 2 using an adhesive or other suitable bonding means known in the art.

[23] The materials for inner section 4 and outer section 8 can be the same or different

materials. Preferably, inner portion 4 and outer portion 8 comprise the same material. hi

one aspect of the invention, the materials for the inner or outer portions comprise any suitable reinforced resin matrix material (RRMM), which is a resin matrix material

(RMM) with continuous or discontinuous reinforcement material embedded in the resin

matrix. In one aspect of the invention, the RMM is a organic resin matrix material

(ORMM). See, for example, U.S. Patent No. 5,725,920 and 5,309,620, the disclosures of

which are incorporated herein by reference.

[24] i one aspect of the invention, the ORMM can be a thermoset resin. Thermoset

resins are polymeric materials which set irreversibly when heated. Examples of

thermoset resins include epoxy, bismeleimide, polyester, phenolic, polyimide, melamine,

xylene, urethane, phenolic, furan, silicone, vinyl ester, and alkyd resins, or combinations

thereof. The thermoset resins can contain various additives as known in the art, such as

cross-linking agents, curing agents, fillers, binders, or ultraviolet inhibitors. Preferably,

epoxy, vinyl ester, or polyester resins are employed as the thermoset resin in the present

invention.

[25] hi another aspect of the invention, the ORMM can be a thermoplastic resin matrix

material. Thermoplastic resins are polymeric materials which do not set irreversibly

when heated, e.g., they soften when exposed to heat and then return to their original

condition when cooled. Examples of thermoplastic resins include polypropylene,

polyethelene, polyamides (nylons), polyesters (PET, PBT), polyether ketone (PEK),

polyether ether ketone(PEEK), polyphenylene sulfide (PPS), polyphenylene oxide (PPO)

and its alloys, and polyvinyl resins, or combinations thereof. The thermoplastic resins

can contain various additives as known in the art, such as cross-linking agents, curing agents, fillers, binders, or ultraviolet inhibitors. Preferably, polyamides (nylons),

polyester, polycarbonate and polypropylene resins are employed as the thermoplastic

resin in the present invention.

[26] The material used to reinforce the RMM of the present invention can be in any

form which reinforces the resin matrix. Examples of reinforcement forms include

unidirectional tape, multidirectional tapes, woven fabrics, roving fabrics, matt fabrics,

preforms, fibers, filaments, whiskers, and combinations thereof. The type of material

used to reinforce the RMM can be any type serving such a reinforcing function.

Preferably, the form of the reinforcement materials for the resin matrix is a fiberous

material, such as continuous or discontinuous fibers. Examples of materials that can be

employed in the present invention include glass-s, glass-e, aramid, graphite, carbon, ultra-

high molecular weight polyethylene, boron, silicon carbide, ceramic, quartz, metals,

isotropic metals (aluminum, magnesium and titanium), metal coated organic fibers,

CAMP, hybrids of these fibers, or combinations of these fibers. See, for example, U.S.

Patent No. 6,117,534, the disclosure of which is incorporated herein by reference.

[27] In yet another aspect of the invention, non- or partially-cured composite materials

are used as the material for the inner and/or outer sections. Composites are a mixture or

combination, on a macro scale, of two or more materials that are solid in the finished

state, are mutually insoluble, and differ in chemical nature. Any composites known in the

art such as laminar, particle, fiber, flake, and filled composites can be employed in the invention. The non- or partially-cured composite materials are a ORMM (thermoset or

thermoplastic resin) reinforced with a continuous fiber.

[28] Preferable composite materials used for inner section 4 and outer section 8 include

B-stage prepreg materials typically in the form of sheets or laminates, which can be

formed by impregnating a plurality of fiber reinforcement tows with a formulated resin.

Methods of making B-stage prepreg sheets and the sheets themselves are well known.

See, for example, those sheets described in U.S. Patent No. 4,495,017, the disclosure of

which is incorporated herein by reference. When cured, prepreg materials are generally

stronger and stiffer than metals while providing greater resistance to fatigue, chemicals,

wear and corrosion. Preferable reinforcement for prepregs include aramids, glass

materials, nickel carbide, silicone carbide, ceramic, carbons and ultra-high molecular

weight polyethylene, or a combination thereof. See, for example, U.S. Patent Nos.

4,968,545, 5,102,723, 5,499,661, 5,579,609, and 5,725,920, the disclosures of which are

incorporated herein by reference. Carbon, glass, metals and especially isotropic metals

like aluminum, magnesium and titanium, metal-coated organic fibers, and aramid fibers,

or a combination thereof, can also be employed as the fibers. See, for example, U.S.

Patent Nos. 5,601,892 and 5,624,115, the disclosures of which are incorporated herein by

reference. Preferably, carbon fibers, glass fibers, or aramid fibers and more preferably

Kevlar 29 or 49 fibers are employed in the present invention.

[29] The fiber volume in the prepregs may be varied so as to maximize the mechanical,

electrical, and thermal properties. See, for example, U.S. Patent No. 5,848,767, the disclosure of which is incorporated herein by reference. High fiber volume parts are

stiffer and, in the case of thermally conductive fibers, the parts are more thermally

conductive. Fiber volumes in the present invention can range from about 5% to about

95%, and preferably range from about 50% to about 65%. The fibers of the prepregs may

be oriented within the prepreg material in any desired direction as known in the art, such

as about 0 to about 90 degrees, including equal numbers of fibers balanced in opposing

directions. See, for example, U.S. Patent No. 4,946,721, the disclosure of which is

incorporated herein by reference.

[30] hi yet another aspect of the invention, sheet molding compounds (SMCs) can be

used as the materials for the inner or outer portion. SMCs are sheets made up of B-stage

thermoset resin reinforced with a discontinuous fiber. SMCs are fully formulated

ORMM compounds having discontinuous fiber reinforcement materials which are

typically formed into sheet, ply, or laminate — without additional preparation. See, for

example, U.S. Patent No. 6,103,032, the disclosure of which is incorporated herein by

reference. The resins that can be used in the SMCs of the present invention include any

of the thermoset resins listed above. Preferably, polyester, vinyl esters, or epoxy resins are

employed as the resin in SMCs of the present invention. The fibers that can be used in

the SMCs of the present invention include any of those listed above. Preferably, glass,

carbon, or aramid fibers, and more preferably Kevlar 29 or 49 fibers can be used as the

fibers in the SMCs. The fiber volume in the SMC may also be varied so as to maximize

the mechanical and thermal properties. [31] With an unsaturated resin system as its base, SMCs incorporate other materials for

desirable processing and molding characteristics and optimum physical and mechanical properties, such as mechanical strength, impact resistance, stiffness, and dimensional stability. These incorporated materials include polymers, fibers for reinforcement, resins, fillers, initiators to promote polymerization, viscosity agents, lubricants, mold release agents, catalysts, thickeners, pigments, polyethylene powders, flame retardants, ultraviolet absorbing agents, and other additives. Each of the additives can provide important

properties to the SMC, either during the processing or molding steps or in the finished parts, and can be incorporated in the SMCs of the present invention.

[32] hi one aspect of the invention, inner section 4 and outer section 8 contain at least

one layer of such ORMM materials. One layer is sufficient to form the respective inner or outer section and provide the desired structural characteristics for structural member 2. Additional layers can be added to improve the strength, stiffness, or other physical characteristics of structural member 2. It is possible to use a single layer with fibers having complementary orientations. It is preferred, however, to use a plurality of layers with complementary orientations to balance intrinsic stresses in the layers that make up the sections that result when, as described below, the B-stage materials are fully cured. To be complementary, the fibers in successive layers should be symmetric and balanced (e.g., by having the fibers offset from the sheet axis by equal and opposite amounts from

one layer to another) as shown in Figure 2. The fibers can also be oriented to meet the design parameters of the component into which they are being incorporated, e.g., to optimize the structural strength against the expected load. The fibers could be oriented at any suitable angle, including at angles ranging from 0 to about 90 degrees, including in ±15, ±30, ±45, ±60, and ±75 degrees, or as otherwise known in the art. See, for example,

U.S. Patent Nos. Re. 35,081 and 5,061,583, the disclosures of which are incorporated

herein by reference.

[33] hi yet another aspect of the invention, the materials for the inner or outer portions can comprise any suitable metal-containing materials, such as a light or heavy metal or

alloys thereof. Suitable light metals include magnesium, aluminum, titanium, zinc, molybdenum, or alloys thereof. Suitable heavy metals include iron, copper, nickel, carbon steel, stainless steel, alloy steel, tin, or alloys thereof.

[34] Since metal-containing materials comprise isotropic fibers, which exhibit similar strength characteristics in all directions, one layer of the metal-containing material is sufficient to form the respective inner or outer portion and provide the desired structural characteristics. Additional layers of the metal-containing material, depending on cost and structural considerations, can also be used to give the desired thickness of the inner or outer portion. Indeed, successive layers of different metal-containing materials may be employed as the inner and/or outer portion.

[35] The configuration of inner portion 4 and outer portion 8 can vary within structural member 2. For example, the materials used for the composite, the fiber orientation, and the curvature, thickness, shape and other characteristics of the inner and/or outer portions (4, 8) can differ along the length and width of structural member 2. See, for example,

U.S. Patent No. 5,718,212, the disclosure of which is incorporated by reference.

[36] Intermediate portion 6 of the structural member 2 of the present invention has any

structure which spaces and/or supports inner portion 4 and outer portion 8, as well as

enhances the structural properties of those two portions when placed therebetween.

Further, intermediate section 6 can be made of any suitable material which separates,

supports, stabilizes, couples and attaches inner portion 4 with respect to outer portion 8.

Interposing intermediate section 6 between inner section 4 and outer section 8 improves

the structural properties according to well-known principles of engineering mechanics

and mechanical engineering of structural member 2 over the properties of a member

comprising only appropriately shaped inner section 4 and outer section 8 bonded together.

Preferably, as illustrated in Figure 1, the intermediate portion is substantially contiguous

with the outer surface of inner section 4 and the inner surface of outer section 8, e.g., the

intermediate section 6 contacts the inner section 4 and/or the outer section 8 at discrete

points over most — if not all — of their surfaces.

[37] hi one aspect of the present invention, intermediate portion 6 has a ribbed

structure (RS), or a structure where any single member (rib) of that structure extends

continuously from a location proximate the inner (or outer) portion to a location

proximate the outer (or inner) portion. In another aspect of the invention, the RS is a

structure where any rib connects at one end to a location proximate the at least one layer

of the inner (or outer) portion and the other ends abuts or connects to another rib. Examples of RSs include corrugated materials, posts, curvilinear materials, honeycomb

cores, and the like. These structures, as well as other RSs, are illustrated in Figure 3.

[38] A RS is advantageous because, for the additional weight added, the structural

properties of the structural member are often substantially increased. The RSs contain

both "ribs" and a large volume of voids. The "ribs" of the RS enhance the structural

properties of the structural member while the voids are provided to minimize the weight

of the RS. The respective amounts of ribs and voids present in the RSs used in the

present invention depend on the configuration of the RS selected, e.g., which of those

illustrated in Figure 3 is selected. Preferably, the amount of voids should be maximized

and the amount of ribs minimized, thereby giving the minimum weight for the maximum

strength, provided the necessary (or desired) structural properties of the RS or the

structural member is obtained.

[39] The RSs employed in the present invention can be incorporated into the structural

member in any suitable manner, i one aspect of the invention, the RS can be

incorporated as a standalone "rib" extending from the at least one layer of the inner

portion to the at least one layer of the outer portion, such as the configurations illustrated

in Figure 3. In another aspect of the invention, the rib can be connected to a supporting

sheet(s) or another ri-b(s) where the sheet(s) or other rib(s) itself is connected to the at

least one layer of the inner or outer portion.

[40] If desired, additional materials can be incorporated into the ribbed structure.

Examples of additional materials that can be incorporated into the RS include be filled with materials other than air, such as resins, foams, insulating materials, or NVH (noise,

vibration, or harshness) damping materials, and/or the like, as well as the coating

materials described below.

[41] The RS need not be uniform in the structural member, hi one aspect of the

embodiment, the type of ribs in the RS can vary from location to location. Further,

multiples types of RSs can be combined in the at least one layer of the intermediate

portion. In another aspect of the invention, the periodicity and/or thickness of the ribs can

be changed in different areas of the at least one layer of the intermediate portion. In

another aspect of the invention, the strength and other physical properties of the ribs can

change from one location to another.

[42] The ribs of the RS can be made of any suitable material which exhibits the desired

structural properties. Suitable materials include any material known in the art to provide

such a function, including materials having individual cells like beads, corrugated

materials, thermoplastic molded materials, honeycomb materials, woods (balsas), and

foams such as rigid expanded plastic foams, polymer foams, metal components, flexible

metal (i.e., aluminum) foams, or any combination of these materials. See, for example,

U.S. Patent Nos. 5,344,038, 4,573,707, 5,562,981, 4,128,963, 4,968,545, and 5,894,045,

the disclosures of which are incorporated herein by reference.

[43] A preferred intermediate portion 6 may be formed using honeycomb materials

(also known as honeycomb cores). These materials usually comprise a thin sheet (or

sheets) of material, such as paper or aluminum foil, which is formed into a variety of random or geometric cellular configurations. See U.S. Patent No. 5,876,654, the

disclosure of which is incorporated herein by reference. Honeycomb cores, which have a

geometric cellular configuration, are known to have structural properties or characteristics

that are superior to most foam or solid cores with a comparable density. Honeycomb

cores can be made of various shapes and types of materials such as aluminum, aramid

materials such as Korex^®, nylon materials such as Nomex^®, plastic, reinforced phenols,

carbons, and fiberglass, or a combination thereof. Preferably, honeycombs made of

Nomex^® are employed as the material for intermediate portion 6.

[44] The material and configuration (width, length, and geometric shape) of the cells

can be optimized to provide the desired support and/or stabilization to the inner and outer

portions. For example, the cell size can range from about 1/8 to about 3/4 inches, and is

preferably about 3/16 inches.

[45] The cells of the honeycomb cores can be filled with materials other than air, such

as resins, foams, insulating materials, or NVH (noise, vibration, or harshness) damping

materials, and/or the like, as well as the coating materials described below. The type of

material used, the thickness, the cell configuration, and "fill-in" material for intermediate

portion 6 can vary along the length of structural member 2.

[46] The structural member of the present invention may, if desired, have additional

layers or portions on the outside of outer portion 8. In one example, a layer of metal,

insulation, another composite material, or honeycomb core material may be placed over

outer portion 8. Numerous additional portions or layers, including similar or different composite materials, could be added in a similar manner, hi addition, at least one

structural component, such as a bracket, coupler, cap, or the like could be located on the end(s) of structural member 2.

[47] h one aspect of the invention, the structural member 2 contains a coating 11 on one of its surfaces. As described herein, coating 11 can be located in or on the inner portion 4, in or on the intermediate portion 6, and/or in or on the outer portion 8. Any surface of the structural member — or a portion of such a surface — can include such a coating, including the inner surface (see Figure 17), the outer surface (see Figure 18), the surface between the inner portion and the intermediate portion (see Figure 19), the surface

between the intermediate portion and the outer portion (see Figure 20), the surface(s)

within the inner and/or outer portion (i.e., between the composite plies or between the metal sheets as depicted in Figure 21), and/or the surface(s) within the intermediate portion (see Figure 22). The location of the coating in the structural member depends on the modifications to the structural member 2 that are desired. For example, to decrease the friction of the structural member, a Teflon coating could be located on the outer surface of the structural member.

[48] The configuration, material, thickness, and number of layers comprising the coating 11 are selected for the desired ability of the coating. The coating 11 can have any configuration in the structural member accomplishing the desired function(s). In one

aspect of the invention, the coating 11 can be a continuous or substantially continuous layer(s) as illustrated in Figure 23. hi another aspect of the invention, the coating "layer" is not continuous, e.g., it maybe substantially contiguous at discrete points with inner

and/or outer portion as illustrated in Figure 24. Another example of the non-continuous

continuous "layer" is illustrated in Figures 25 and 26, where structural member 2 may

have sections with a coating and sections without a coating. Additional examples of the

patterns in non-continuous "layers" are illustrated in Figure 27, which can be configured

for the desired function.

[49] The thickness of the coating 11 can be selected to provide the desired function for

which the coating is incorporated into the structural member. To that end, multiple layers

can be provided at the same or different locations to give the desired thickness. In a

preferred aspect of the invention, when a substantially-continuous Teflon coating is

employed on the outer surface of the structural member, the thickness of the coating can

range from about 0.001 inch to about 0.125 inch.

[50] The coating(s) can have various functions and/or purposes. In one aspect of the

invention, the coating is added to modify — either increase or decrease — the friction of the

structural member when it abuts another surface. The inner surface and/or the outer

surface (or ends of the structural member) can be modified to change the friction

properties. For example, the structural member may be employed as in a steering column

system where the friction of the structural member should be decreased as the metal or

composite material of the structural member is not suitable.

[51] Any suitable coating materials known in the art to modify the friction properties

of the structural member can be employed in the present invention. Suitable coating materials include fluoropolymer-based fabrics, films, tapes or any similar fabrics, films,

tapes, etc.... hi one aspect of the invention, such coatings materials can also be coated

with fluoropolymeric resins such as teflon (PTFE), fluorinated ethylene propylene (FEP)

materials, partially-fluorinated resins such as polychlorotrifluoroethylene (PCTFE), or

any other family of fluoropolymer resins. Preferably, a porous, brominated, glass fabric

coated with Teflon, and/or a fabric made of teflon and/or decron (nylon) is employed as

the material for modifying the friction of structural member 2.

[52] In another aspect of the invention, the coating is added to structural member 2 to

modify — either increase or decrease — the magnetic properties of the structural member.

The inner surface and or the outer surface can be modified to change the magnetic

properties. As well, the surface(s) between the inner portion and/or outer portion and the

intermediate portion can be modified to change the magnetic properties of the structural

member. As well, the material comprising the inner, intermediate, and outer portion can

be modified to change their magnetic properties. For example, the magnetic-modifying

coating material can be located between successive composite plies (or metal sheets), hi

another example, the magnetic-modifying material can be incorporated in the voids of the

RS in the intermediate portion.

[53] Any suitable materials known in the art to modify the magnetic properties of the

can be employed in the present invention. Suitable materials include magnetic and

ferromagnetic materials, alloys of magnetic and ferromagnetic materials, cobalt, nickel, samarium, etc.... Preferably, a ferromagnetic, material is employed as the material for

modifying the magnetic properties of structural member 2.

{§4} In another aspect of the invention, the coating is added to structural member 2 to

modify the chemical properties — such as corrosion resistance — of the structural member.

The inner surface and/or the outer surface (or ends) can be modified to change the

chemical properties. For example, the structural member may be employed as a teflon

coated structural member in hydrolic power streering system where the surface of the

structural member should be changed as metal materials are not very resistant to

corrosion. Teflon coated composite tubes also provide anti-stick surface, low

permeability to liquids, gases and moisture, and high resistance to tearing. In one aspect

of the invention, the structural member can be configured as a composite rack and pinion

tube liner, bearingless steering shaft.

[55] Any suitable coating materials known in the art to modify the chemical properties

can be employed in the structural member of the present invention. Suitable coating

materials include fluoiOpolymer-based fabrics, films, tapes or any similar fabrics, films,

tapes, etc.... hi one aspect of the invention, such coating materials can be themselves

coated with fluoropolymeric resins such as teflon (PTFE), fluorinated ethylene propylene

(FEP), partially fluorinated resins such as polychlorotiifluoroethylene (PCTFE), or any

other family of fluoropolymer resins. Preferably, a specially-treated teflon or FEP

material is employed for modifying the corrosion resistance of structural member 2.

Other types of these materials can be used to modify other chemical properties. [56] In another aspect of the invention, the coating is added to structural member 2 to

modify — either increase or decrease — the conducting properties of the structural member.

These conducting properties include thermal conduction (or insulation), electrical

conduction (or-insulation), and optical conduction (or insulation). The inner surface

and/or the outer surface can be modified to change the conductive properties. As well,

the surface(s) between the inner portion and/or outer portion and the intermediate portion

can be modified to change the conductive properties of the structural member. In another

aspect of the invention, the material comprising the inner, intermediate, and outer portion

can be modified to change their conductive properties. For example, the conductive-

modifying material can be located between successive composite plies (or metal sheets).

hi another example, the conductive-modifying material can be incorporated in the voids

of the RS in the intermediate portion.

[57] Any suitable materials known in the art to modify the thermal conduction

properties of the structural member can be employed in the present invention. Suitable

materials include copper, aluminum, brass, steel, and alloys of ferrous materials.

Preferably, ferrous materials and/or aluminum is employed as the material for modifying

the thermal conduction properties of structural member 2.

[58] Any suitable materials known in the art to modify the thermal insulation

materials include glass fabrics, any form of glass materials, rubber materials, and

polymeric materials. Preferably, glass fabrics or silicone rubber materials can be employed as the material for modifying the thermal insulation properties of structural

member 2.

[59] Any suitable materials known in the art to modify the electrical conduction

materials include metals like copper and aluminum or metal alloys. Preferably, copper or

aluminum can be employed as the material for modifying the electrical conduction

properties of structural member 2.

[60] Any suitable materials known in the art to modify the electric insulation properties

of the structural members can be employed in the present invention. Suitable materials

include glass fabrics, any form of glass materials, rubber materials, and polymeric

materials. Preferably, glass fabric materials or silicone rubber materials can be employed

as the material for modifying the thermal insulation properties of structural member 2.

[61] Any suitable materials known in the art to modify the optical conduction (or

insulation) properties of the structural members can be employed in the present invention.

Suitable materials include coaxial fibers of high purity silica and its derivatives.

Preferably, high purity silica (more preferably in the shape of fibers or ribbon cable) is

employed as the material for modifying the optical conduction properties of structural

member 2.

[62] The structural member of the present invention may have any substantially non-

flat contour or configuration. Figure 4 illustrates several such configurations. The structural members illustrated in Figure 4 differ from the structural member illustrated in

Figure 1 in that the cross-section of the tube is not substantially circular.

[63] Structural member 2 can be made crushable by any manner in the art. In one

aspect of the invention, the structural members are made crushable by including at least

one crushing initiator (or initiator) adjacent to (or in) portion 4, portion 6, and/or portion

8. For example, as depicted in Figure 12, the at least one initiator 14 can be incorporated

in outer portion 8. However, the at least one initiator can be incorporated in inner portion

4, intermediate portion 6, and/or outer portion 8, as well as between these portions.

[64] The initiator controls the location where, when an external load is applied,

structural member 2 begins to deform. Often, the structural member resists impacts along

its longitudinal axis. By including an initiator, the structural member of the present

invention absorbs the energy of the load by undergoing a localized crush where the

initiator is located, in modes such as transverse shearing, lamina bending, or local

buckling like monocell buckling, face wrinkling, or core-shear instability. Thus, the

initiator leads to a localized crash of the member so the structural member does not fail at

other places. By incorporating at initiator, the preferred site of collapse of the structural

member can be selected before the expected load is applied.

[65] Any suitable initiator known in the art can be employed in the present invention,

including those described in U.S. Patent Nos. 4,742,889, 5,732,801, 5,895,699, and

5,914,163, the disclosures of which are incorporated herein by reference. The initiator

can be placed at any location of structural member 2 depending on the desired characteristics including the crushing strength and crushing length. Preferably, the

initiator is not located at the ends of structural member 2. More preferably, the initiator is

placed at least about Vi inch to about 2 inches away from any end of stractural member 2.

[66] Multiple initiators can be placed along separate portions of member 2 to deform

(and therefore crush) several locations. Multiple initiators can also be placed proximate

one another at a single portion of member 2 to deform that selected location. The number

of initiators can vary, depending on the desired crushing strength and desired crushing

length.

[67] The initiator(s) can be of various shapes, sizes, and configurations, but should be

substantially similar to the configuration of portion 4, intermediate portion 6, and/or

portion 8. The width of the initiator can vary depending on the expected load, the

desired crashing strength, and the desired crash length. For example, the width can range

from about 1/16 inches to about 1 inch, and is preferably about Vz inches. The shape of

the initiator can also vary depending on the expected load, the desired crushing strength,

and the desired crush length. Generally, the shape is similar to that portion of stractural

member 2 into which it is incorporated. Thus, the shape can vary from circular, to

rectangular or triangular, to any polygonal shape.

[68] When multiple initiators are employed, they can be located in any desired

location. In one aspect of the invention, the initiators can be either staggered or inline.

The initiators can be inline, meaning that multiple initiators are aligned along the length

or diameter of the stractural member. The initiators can also be semi-staggered or fully staggered. In a semi-staggered position, the initiators are only partially aligned along a

length or diameter of the stractural member, e.g., they have overlapping positions (as

illustrated in Figure 13). hi a fully staggered position, the initiators are not aligned along

the length or diameter of the stractural member, e.g., they have no overlapping positions

(as illustrated in Figure 14).

[69] Any suitable material can be used for the initiator(s) of the present invention.

Suitable materials used for the initiator can be any material which causes, as explained

below, the respective inner and/or outer portion to deform and do not adhere to the

materials used in the inner, intermediate, and/or outer portion. Examples of suitable

materials include as teflons, rubber bands, bromated films, release films, rubber films,

polytetrafluoroethylene (PTFE) tape, teflons, backing papers, or a combination thereof,

hi one aspect of the invention, bromated ("bromo") films are preferably employed as the

material for the initiator in the present invention.

[70] Bromo films are brominated PTFE coated fiber glass fabric films. Bromo films

are usually an impermeable layer that does not bond to the composite material during the

curing process (as described below). There are two types of bromo films that can be

employed as the initiator material: porous and non-porous. Preferably, a non-porous

bromo film is employed as the imtiator material, ensuring that there is an unbonded area

in any desired location that will cause the failure in that particular location. Numerous

bromo films are commercially available, including "Release Ease 234TFP" sold by Air

Tech Advanced Materials Group. [71] It is believed that the initiator works because, of the absence of a continuous layer

in the inner, intermediate, and/or outer portion. Thus, the initiator could also be a gap or

discontinuity (such as a stress riser) in the layer(s) of the inner, intermediate, and/or outer

portion. The discontinuity could be a singular discontinuity such as a fold or irregularity,

or plural discontinuities such as a row or column of cut-outs having any desired shape and

size. For example, as illustrated in Figure 15, a row of cut-outs can be located in a layer

of the inner and/or outer portion, as well as the intermediate portion, so that when

assembled, stractural member 2 contains at least one initiator 14. In addition, when the

impact load is an axial load, the initiator could be any material (or lack thereof) which

operates as a local stress riser.

[72] The present invention can be made by any suitable process which provides the

structure of structural member 2. Suitable process for making the composite layer(s)

include any processes known in the art, such as thermoforming, bladder or resin transfer

molding, or inflatable mandrel processes, as described in U.S. Patent Nos. 5,225,016,

5,192,384, 5,569,508, 4,365,952, 5,225,016, 5,624,519, 5,567,499, and 5,851,336, the

disclosures of which are incorporated herein by reference. Another suitable process is a

vacuum bagging process, such as described in U.S. Patent No. 5,848,767, the disclosure

of which is incorporated herein by reference. Other suitable processes are a filament

winding process or sheet or tube rolling (also known as roll wrapping). See, for example,

U.S. Patent Nos. 5,632,940, 5,437,450, 4,365,952, 5,624,529, 5,755,558, 4,885,865, 5,332,606, 5,540,877, 5,840,347, and 5,914,163, the disclosures of which are

incorporated herein by reference.

[73] hi the filament winding process, filaments of the desired material are dispersed in

a matrix of binder material and wound about any suitable substrate, such as a mandrel

assembly, with a shape generally corresponding to the desired shape (core region 10) of

structural member 2. Any suitable mandrel, including those described in U.S. Patent Nos.

5,795,524, 5,645,668, 5,192,384, 5,780,075, 5,632,940, 5,817,203, and 5,914,163, the

disclosures of which are incorporated by reference, can be employed in the present

invention. The substrate or mandrel must have sufficient strength, desired shape, and be

able to withstand the processing conditions for making the structural member. Suitable

mandrels include those made of metals like steel and aluminum, polycarbonate,

thermoplastic, or RRMM materials. The mandrels may be solid or hollow.

[74] The filaments are wound over the mandrel and are reciprocally displaced relative

to the mandrel along the longitudinal or winding axis of the mandrel to build portion 4.

Additional portions, structures, or layers, such as additional metal or composite layers or

coating 11, can be added as described herein or as known in the art.

[75] Preferably, the present invention employs a tube rolling (also known as roll

wrapping) process for making the structural member of the present invention. One

exemplary tube rolling process is illustrated in Figure 5. The tube rolling process

employs discrete sheet(s) of the metal-containing material or sheet(s) (or plies or

laminates) of the desired composite material rather than filaments. The sheet(s) is interleaved, wrapped, or rolled over a mandrel assembly such as at least one mandrel 20.

If desired, a release film can be applied to the mandrel prior to rolling any materials

thereon. When more than one sheet is employed, the sheets can be stacked as illustrated

in Figure 2 — prior to or during the rolling process — by hand or by any suitable

mechanical apparatus, with the fibers of the composite material oriented in the desired

orientation. When a continuous metal sheet is used, there is no need for such a stacking

operation. After forming inner portion 4, the material comprising intermediate portion 6

is placed, preferably by wrapping or rolling, on inner portion 4 by hand or mechanical

apparatus. The roll wrapping process is then resumed to apply the material of outer

portion 8. Further details about roll wrapping processes are described in Engineered

Materials Handbook, Volume 1: Composites, ASM International, pp. 569-574 (1987), the

disclosure of which is incorporated herein by reference. Additional layers or materials —

such as coating 11 — can be added over outer portion 8, if desired, in a similar manner or

as known in the art.

[76] The layers of the individual portions (inner, intermediate, and outer) can be cut

and/or patterned such that when roll wrapped, the ends of individual sheet(s) substantially

abut when rolled, thereby forming a butt joint 30. Preferably, the butt joint formed by the

ends of any single sheet is staggered from the butt joint formed by the ends of an adjacent

sheet, as illustrated in Figure 6. Of course, when a continuous metal sheet is rolled, no

butt joint occurs. [77] Inner portion 4 and outer portion 8 may be formed using different methods. For example, inner portion 4 can be formed by filament winding and outer portion 8 by roll

wrapping, or vice versa, hi this aspect of the invention, inner portion 4 may be fully cured prior to the application of intermediate portion 6. Similarly, inner portion 4 and intermediate portion 6 may be applied and cured together prior to the application of outer portion 8. Other methods known in the art, such as those described above, could also be combined with roll wrapping to make the stractural members by performing discrete steps by different methods. For example, inner portion 4 could be formed using the filament winding process, intermediate portion 6 and outer portion 8 could be formed using the roll wrapping process, and then this intermediate stracture could be constrained using a vacuum bagging process.

[78] If desired, a bonding agent can be placed between successive layers of portions 4,

6, and/or 8. The bonding agent can be placed on selected areas only, or in a pattern such as in rows and/or columns, or over entire areas of the layer(s)/portion(s). Any suitable agent which helps bond the layers and is compatible with all of the processes employed to make stractural member 2 can be employed, including glues, curing agents, adhesive materials, or a combination thereof. See, for example, U.S. Patent No. 5,635,306, the disclosure of which is incorporated herein by reference. The bonding agent can be

applied by hand or mechanical apparatus prior to, during, or after the assembly of the respective portion on the substrate. [79] Where portions 4, 6, and 8 are successively layed up in an uncured (e.g., B-stage

state), the stracture has outer portion 8 overlying intermediate portion 6, which overlies

inner portion 4, which overlies the mandrel. If necessary to better bond and connect inner

portion 4, intermediate portion 6, and outer portion 8 together, the intermediate stracture

formed by these portions can be constrained. The intermediate structure can be

constrained by applying a suitable compressive force. This can be done using any

suitable means including compressive dies or molds, vacuum bagging, or by using a

suitable constraining means, e.g., by placing it in a plastic or metal mold, or by applying a

suitable shrink-wrap tape(s) 22 or tube made of nylon, silicone, or polypropylene. During

the curing process described below, the compressive means (e.g., the shrink-wrap tape or

tube) applies suitable compressive force by physical or chemical change so that the

materials of stractural member 2 contact each other. When the RMM is used in the inner

and/or outer portion of the present invention, the compressive force squeezes out excess

resin during this curing process. See, for example, U.S. Patent Nos. 5,600,912 and

5,698,055, the disclosures of which are incorporated herein by reference.

[80] Moreover, if it is still necessary to better bond and connect the materials in the

intermediate stracture, they can undergo a suitable chemical reaction. For example, when

inner portion 4 and/or outer portion 8 comprise a curable material (e.g., B-stage epoxy

prepreg), the intermediate structure can be cured by any suitable means 24, such as an

oven curing by applying heat and/or pressure or using an ultraviolet (u.v.) or microwave

curing. The necessary heat and/or pressure depend on the size of the mandrel assembly and the materials used in structural member 2. During the curing process, the shrink-

wrap tape or tube applies suitable compressive force. When the RMM is used in the

inner and/or outer portion of the present invention, the compressive force squeezes out

excess resin during this curing process.

[81] The above process can be modified for structural members not having a

substantially circular cross-section, including those with outer diameters having at least

one flat area or area where the degree of curvature is substantially different from other

surfaces of structural member 2. Examples of such stractural members are illustrated in

Figure 4. As illustrated in Figure 7, where the outer diameter has at least one relatively

flat area, the shrink-wrap material (and accompanying compressive force) applied to the

intermediate structure may not be uniform. Thus, bonding and connecting the materials

to one another may not be uniform and, therefore, might impair the integrity of structural

member 2. To more uniformly bond and connect such materials, at least one pressure

distributor 26 is placed over the relatively flat areas of outer portion 8 prior to applying

the shrink-wrap material. The pressure distributors "distribute" the applied compressive

force more evenly to such flat areas, allowing a more uniform compressive force to all

areas of the intermediate structure.

[82] Any suitable shape of pressure distributors which evenly distribute the applied

compressive force to the intermediate structure can be employed in the present invention.

Exemplary shapes of the pressure distributors include substantially semicircular shapes

(which provide a substantially circular outer surface) and T-shaped distributors where the flat end of the "T" abuts (and matches in size) the flat area of the intermediate stracture

and the long-end of the "T" extends outwards. Other shapes and configurations,

including single components rather than plural components, could be employed provided they evenly distribute the compressive force over the flat area(s). For the structural member 2 like the one illustrated in Figure 4, substantially semicircular pressure distributors 26 are depicted in Figure 7. The pressure distributors of the present invention

can be made of any suitable material that will maintain its shape when subjected to the compressive force, such as aluminum, steel, and silicone. Preferably, aluminum is employed as the material for the pressure distributor.

[83] The shrink-wrap material can be placed under and/or over the pressure

distributor (s). The shrink-wrap materials underlying the pressure distributors pressurize the corners, as well as keeping the pressure distributors from sticking to the intermediate stracture. The shrink-wrap materials overlying the pressure distributors pressurize the flat areas.

[84] The above process can be also be modified for stractural members where the inner and outer portion do not have the same shape, such as those depicted in Figure 11. Any suitable process modification which manufactures differently-shaped inner and outer portions can be employed in the present invention. The following two modifications to the above process demonstrate this concept. Other modifications could be envisioned, even though not demonstrated below. [85] First, the inner portion can have a substantially circular cross-section and the outer

portion a non-circular cross-section, hi such an instance, and as shown in Figure 8, the

process for making a circular-shaped structural member is followed as described above.

To change the shape of the outer portion, a number of pressure distributors are placed

over the circular-shaped outer portion prior to the constraining and curing stages. The

number of pressure distributors used corresponds to the number of flat sides desired, e.g.,

four for a square, six for a hexagon, etc... The process as noted above is then continued

for the constraining and curing stages. During the constraining and curing process, the

circular outer shape is changed to flat sides of the desired polygonal shape by the pressure

exerted via the pressure distributors.

[86] Second, the inner portion can have a substantially polygonal shape (i.e, square)

and the outer portion a substantially circular shape. In this aspect of the invention as

depicted in Figure 9, the process for making a square-shaped stractural member is

followed as described above. To change the shape of the outer portion, the pressure

distributors which are normally placed over the outer portion prior to the constraining and

curing stages are omitted. Thus, the square-shaped outer portion is just wrapped with the

constraining means. The process as noted above is then continued for the constraining

and curing stages. During the constraining and curing process, the outer shape is changed

to a substantially circular shape by the pressure exerted via the constraining means.

[87] When used, the constraining means are then removed from the intermediate

stracture. For the plastic or metal mold, the mold is opened and removed. The shrink- wrap tape or tube may have reacted during the curing process to form a thin shell and, if

desired, may be removed by hand or by a mechanical apparatus. When used, the pressure

distributors are also removed.

fSS} In another aspect of the invention, the constraining means can be left on the outer

J portion either temporarily or permanently. For example, the shrink-wrap tape could be

left on the structural member in the form as a thin shell for protection during shipping and

then removed later, h another example, the shrink-wrap tape could be left on the

stractural member permanently as a protective coating.

[89] Through the constraining and curing processes described above, the inner portion

and the outer portion are chemically attached and/or or connected to the intermediate

portion. Preferably, the materials of the inner and outer portion both chemically bond to

the material of the intermediate portion, thus forming a substantially permanent physical

bond.

[90] Next, the substrate or mandrel may be removed from structural member 2 to form

core region 10. The mandrel may be removed by any suitable process, including any

known in the art which safely removes the mandrel without adversely impacting

stractural member 2, such as those disclosed in U.S. Patent No. 5,900,194 and 5,306,371,

the disclosures of which are incorporated herein by reference. If desired, core region 10

can be filled by any desired material as known in the art.

[91] The mandrel can be either a removable mandrel or an integral mandrel. A

removable mandrel is a mandrel that, as described above, is used in the roll wrapping process and then removed to create interior 10. An integral mandrel is a mandrel which

becomes part of stractural member 2 and is not removed. Thus, the mandrel remains in

core region 10 and becomes a part of stractural member 2.

[92] When using an integral mandrel, the stractural member 2 and the process for

making that member are modified from the above description. In this aspect of the

present invention, the intermediate portion is provided over the integral mandrel, and then

the outer portion is provided over the intermediate portion. The structural member then

follows the processing described above, with the exception that the integral mandrel is

not removed. Thus, the integral mandrel can serve as the inner portion. If desired, an

inner portion could still be included over the integral mandrel, yielding a structural

member with an integral mandrel, an inner portion, an intermediate portion, and an outer

portion.

[93] At least one initiator 14 may be included in the present invention by any suitable

method, including those known in the art. If only one layer is employed for portion 4,

intermediate portion 6, and/or portion 8, the initiator can be created under, in, or over that

single layer. When more than one layer is employed for such portions, such an initiator(s)

can, additionally or alternatively, be included between the layers making up the respective

portion.

[94] For example, when the initiator is a gap or discontinuity in portion 4, intermediate

portion 6, and/or portion 8, the desired section of that portion can be removed or altered.

Any gap or discontinuity is preferably, although not necessarily, formed in the material prior to the roll wrapping operation. The initiator can consist of rows or columns of cutouts of any desired shape and size, as exemplified in Figure 15, in the respective material which have been removed by any suitable process known in the art, such as stamping. The desired configuration for the initiator is selected, the desired location(s)

for deformation of the stractural member are determined, and the initiator(s) is then placed by creating a gap or discontinuity in the respective layer(s) of portion 4, portion 6,

and/or portion 8 either before or after the rolling operation.

[95] As another example, when the initiator is similar to that illustrated in Figure 12, the desired width of the initiator material can placed on the selected locations(s) of portion 4, intermediate portion 6, and/or portion 8. The initiator material could be placed

by rolling or wrapping the initiator material under or on the respective inner, intermediate, and/or outer portion. Alternatively, the initiator material could be placed in or on the sheet(s) prior to the rolling or wrapping process, e.g., by manufacturing the

sheet(s) with the initiator formed therein. The desired material and configuration for the initiator is selected, the desired location(s) for deformation of the structural member are

determined, and the initiator(s) is then placed under, over, or within the layer(s) of portion 4, 6, and/or 8 either before or after the rolling operation.

[96] Once formed, the stractural members of the present invention can be modified or cut for any desired use. For example, the structural members illustrated in Figures 5 and

7-9 have been cut in half along its length to provide two stractural members. Likewise,

the structural members could be cut along its length to provide any number of members with the desired length(s). Numerous shapes and configurations can be made using by

cutting along any dimension of the structural members, especially when combined with

the broadest aspects of the processes of the present invention. A few examples of such

shapes and configurations are shown in Figure 10. If desired, at least one stractural

component such as a bracket, fastener, coupler, cap, or the like, could be provided on

stractural member 2, for example, on the ends thereof.

[97] The coating of the present invention can be included in the structural member via

numerous methods. When the coating is located on the inner surface of the stractural

member, it can be applied to the substrate (mandrel) before the layer(s) of the inner

portion are applied. Alternatively, the coating can be applied to the surface of the layer(s)

of the inner portion that will abut the substrate. Thus, when such layer(s) are applied to

the substrate, the coating will be on the inner surface of the structural member.

[98] When the coating is located on the outer surface of the structural member, it can

be applied after the layer(s) of the outer portion are applied, but before the constraining

means mentioned above are used. Alternatively, the coating can be applied to the surface

of the layer(s) of the outer portion that will face the outside of the structural member.

Thus, when such layer(s) are applied to the intermediate portion, the coating will be on

the outer surface of the stractural member.

[99] When the coating is located between the inner portion and the intermediate

portion of the stractural member, it can be applied to top layer of the inner portion before

the layer(s) of the inner portion are applied to the substrate. Thus, when the inner portion is applied to the substrate, the coating is on the outer layer of the inner portion.

Alternatively, the coating can be applied to the inner surface of the layer(s) of the

intermediate portion. Thus, when such layer(s) are applied to the inner portion, the

coating will be on the inner surface of the intermediate portion.

[100] When the coating is located between the outer portion and the intermediate

portion of the structural member, it can be applied to bottom layer of the outer portion

before the layer(s) of the ouer portion are applied to the substrate. Thus, when the outer

portion is applied to the intermediate portion, the coating is on the inner layer of the outer

portion. Alternatively, the coating can be applied to the outer surface of the layer(s) of

the intermediate portion. Thus, when such layer(s) are applied to the inner portion, the

coating will be on the outer surface of the intermediate portion.

[101] When the coating is located between successive composite plies, the coating can

be incorporated between the plies before they are wrapped. For example, the coating

could be laid between successive plies when the plies are stacked together as described

above. When wrapped, the coating would be located between the layers of the sheet, as

depicted in Figure 28. Alternatively, when a single metal sheet is used, the coating could

be applied to desired portions of the sheet before the sheet is roll wrapped or could be

applied to the sheet while it is wrapped.

peg When the coating is incorporated in the layer(s) of the intermediate portion, the

material (such as the honeycomb core) can be manufactured with the coating material

already present in the voids. Alternatively, the material could be purchased and then the coating material incorporated into the voids. For example, when the coating material is a

rubber material, it could be applied to the honeycomb core in a liquid form such that

when it dries, it fills the cells in the honeycomb core.

fi S} Roll wrapping is the preferred method for making the structural members of the

present invention. The other methods described above, however, could be combined with

roll wrapping to make the stractural members by, in one aspect of the invention,

performing discrete steps by different methods. For example, inner portion 4 could be

formed using the filament winding process, the intermediate portion 6 and the outer

portion 8 could be formed using the roll wrapping process, and then the intermediate

structure could be constrained using the vacuum bagging process.

[104] The structural member of the present invention has numerous uses such as a tie,

torsion-bar, tube, beam, column, cylinder and the like and can be used in numerous

industries. Primarily, the stractural member can be used whenever a lightweight, strong,

cylindrical object is required. The stractural member of the present invention can be used

in the automotive, transportation, aerospace, and defense industries in applications such

as airplane components, vehicle components such as tracks, trains, shipping containers,

defense-related applications, recreational applications such as bikes, sail masts, shafts for

golf clubs and racquets, or commercial applications such as bridges and buildings.

The following non-limiting examples illustrate the present invention. [105] Example 1 (Hypothetical)

[106] A hollow, cylindrical structural member with a circular cross-section is made

according to following process. A thin coat of a release material (Frekote 700NC or Axel

EM606SL/SP) is applied to a 3 inch diameter aluminum mandrel with a length of 52

inches.

[107] Two metal (aluminum) sheets with preapplied adhesive and a thickness of about

0.001 inch are pattern cut with measurements of about 38 inches in width and about 48

inches in length. In both sheets, about 0.25 inch diameter holes, about 1 inch apart, are

punched about 2 inches away from the "side" end of the metal sheet. The holes are

punched, leaving the first 10 inches from the leading end of the sheet (that end first

wrapped onto the mandrel) without any holes and the remaining 28 inches with holes.

[108] One of the metal sheets is then roll wrapped by hand onto the aluminum mandrel

starting with the metal portion against the mandrel, e.g., so the adhesive material is on the

top. After rolling, the metal sheet of the inner portion is four layers "thick" on the

mandrel: the first layer contains those portions of the sheet with no punched holes and the

least three layers have the punched holes.

[109] Next, a honeycomb Hexcell Nomex^® core with hexagonal shaped cells and a

thickness of about 0.15 inches is measured and cut to dimensions of about 10 inches by

about 48 inches. About 0.25 inch diameter holes, about 1 inch apart, are punched about 2

inches away from the "side" end of the honeycomb. This honeycomb core is then roll wrapped by hand on the first metal sheet, with the honeycomb core adjacent to the adhesive of the last layer of the first metal sheet.

[110] The second metal sheet is then roll wrapped by hand starting with adhesive layer

first, e.g., so that adhesive layer is adjacent to the honeycomb core on the outer surface. After rolling, the metal sheet of the outer portion is four layers "thick" on the mandrel: the first three layers having the punched holes and the last layer contained no punched

holes. Both metal sheets are roll wrapped with the punched holes aligned.

[111] Next a thin layer of uncured silicone rubber sheet is roll wrapped over the second

metal sheet. The rubber sheet is cur to dimensions of about 0.100" thick about 10 inches by about 48 inches.

[l 12] Next, the resulting intermediate stracture is shrink-wrapped. One layer of polyethylene-based shrink-wrap tape is roll wrapped by a shrink-wrapping machine using

gauge number 150 on the resulting stracture. Two layers of nylon-based shrink-wrap tape

are then roll wrapped by a shrink-wrapping machine using gauge number 200.

[113] After this wrapping process, the final stracture is subjected to a curing process at about 250 degrees Fahrenheit for about 120 minutes during which the shrink-wrap tapes

applied compressive pressure to the intermediate stracture. After this curing process, the shell (formed by the shrink-wrap tapes during the curing process) is removed by hand with a knife. The mandrel is then removed from the center of the tube by hand and the tube is cut to the desired length. [114] Example 2 (Hypothetical)

[115] A hollow, cylindrical structural member with a square-shaped cross section is

made according to following process. A thin coat of a release material (Frekote 700NC

or Axel EM606SL/SP) is applied to a cylindrical aluminum mandrel with a 3.0 inch

square outer diameter and a length of 72 inches.

[116] One layer of Dacron/Teflon woven fabric is cut about 11.6 inches in width and 64

inches in length. An adhesive is then applied to the layer. The individual sheet was roll

wrapped over the mandrel so the adhesive is on the surface away from the mandrel.

[117] Four pairs of B-stage prepreg laminate sheets (8 individual sheets) containing

anisotropic Kevlar fibers in an epoxy-based resin are cut with measurements of about

11.6 to 13.4 inches in width and about 64 inches in length. The individual laminate

sheets are then overlaid so the fibers in successive sheets are symmetric and balanced at

angles of +15 degrees. The air between the stacked sheets is removed by using a roller or

other suitable device. Two pairs of the stacked prepreg sheets are then roll wrapped by

hand onto the aluminum mandrel.

[118] Then, Vz inch wide strips of bromo film are measured and cut to a length similar to

the outside diameter of the stacked sheets on the mandrel, e.g., \2^lA inches in length. The

strips are then roll wrapped over the prepreg sheets on the mandrel. The strips are located

such, that when the stractural member is cut as described below, the strips are about 2

inches away from any desired end of the structural member. [119] Next, a honeycomb Hexcell Nomex core with hexagonal shaped cells and a

thickness of about 0.2 inches is measured and cut to dimensions of about 13 inches by

about 64 inches. This honeycomb core is then roll wrapped by hand on the first set of

stacked prepreg sheets and strips of bromo film.

[120] Additional ^lA inch wide strips of bromo film are measured and cut to a length

similar to the outside diameter of the honeycomb core. The strips are then roll wrapped

over the honeycomb core to be aligned with the strips under the core. The other two pairs

of the stacked prepreg sheets are then roll wrapped onto the honeycomb core and the

strips of bromo film.

[121] Next, the resulting intermediate stracture is shrink-wrapped. One layer of

polyethylene-based shrink-wrap tape is roll wrapped by a shrink-wrapping machine using

gauge number 150 on the resulting stracture. Another layer of nylon-based shrink-wrap

tape is then roll wrapped by a shrink-wrapping machine using gauge number 200. Four

4-inch "T"-shaped pressure distributors made of aluminum are placed on four sides of the

resulting device. An additional, outer layer of nylon-based shrink-wrap tape is then roll

wrapped by a shrink-wrapping machine using gauge number 200 over the pressure

distributors.

[122] After this wrapping process, the final structure is subjected to a curing process at

about 250 degrees Fahrenheit for about 120 minutes during which the shrink-wrap tapes

applies compressive pressure to the intermediate stracture. After this curing process, the

outer shell (formed by the outer shrink-wrap tape during the curing process), the pressure distributors, and the inner shell (formed by the "inner" shrink-wrap tapes during the

curing process) are removed by hand with a knife. The mandrel is then removed from

the center of the tube by hand and the tube is cut to the desired length.

[123] Example 3

[124] A hollow, cylindrical stractural member with a hexagonal cross-section was made

EM606SL/SP) was applied to a 0.3395 inch diameter hexagonal aluminum mandrel with

a length of 48 inches.

[125] A single coating layer was prepared by laying a Decron Telfon woven fabric with

dimensions of 2.39" X 4.0" and a 7781 glass cloth with dimensions of 2.39" X 3.75" end

to end. Enough alternating pieces were layed end-to-end to make a 2.39" wide and 40 "

long layer. This layer was then roll wrapped over the mandrel.

[126] A single sheet of anisotropic carbon fibers in an epoxy-based resin was cut with

measurements of about 2.44 inches in width and about 40 inches in length. The individual

sheet was cut with a fiber angle of 90 degrees. The sheet was roll wrapped over the

coating layer.

[127] Fourteen pairs of B-stage prepreg laminate sheets (28 individual sheets)

containing anisotropic carbon fibers in an epoxy-based resin were cut then with

measurements of about 2.48 to 3.61 inches in width and about 40 inches in length. The

individual laminate sheets were overlaid so the fibers in successive sheets were symmetric and balanced at angles of +22 degrees. The air between the stacked sheets was

removed by using a roller. The fourteen pairs of the stacked prepreg sheets were then roll wrapped by hand onto the single sheet.

[128] Two pairs of B-stage prepreg laminate sheets (4 individual sheets) containing

anisotropic carbon fibers in an epoxy-based resin were cut with measurements of about 3.65 to 3.77 inches in width and about 40 inches in length. The individual laminate sheets were then overlaid so the fibers in successive sheets were symmetric and balanced at angles of 0 degrees. The air between the stacked sheets was removed by using a roller.

The two pairs of the stacked prepreg sheets were then roll wrapped by hand onto the fourteen pairs of prepreg sheets.

[129] The resulting stracture was then overwrapped. Two strips of B-stage prepreg laminate containing anisotropic carbon fibers in an epoxy-based resin were cut with

dimensions of 1.5" wide and 24" with a 0° fiber angle. Both strips were wrapped on each end of the resulting structure. Four additional strips with dimensions of 3.25" width and 24" length were then cut with a 0° fiber angle. All four strips were then wrapped in 7.25 " segments from the two strips located on the ends.

[130] Next, the resulting intermediate structure was shrink-wrapped. One layer of

polyethylene-based shrink-wrap tape was roll wrapped by a shrink-wrapping machine using gauge number 150 on the resulting structure. Two layers of nylon-based shrink- wrap tape were then roll wrapped by a shrink-wrapping machine using gauge number 200. [131] After this wrapping process, the final stracture was subjected to a curing process

at about 250 degrees Fahrenheit for about 120 minutes during which the shrink-wrap

tapes applied compressive pressure to the intermediate structure. After this curing

process, the shell (formed by the shrink-wrap tapes during the curing process) was

removed by hand with a knife. The mandrel was then removed from the center of the

tube by hand and the tube was cut into five 7.25" segments with a 1.5" overwrap on each

end.

[132] The tubes were then converted to an intermediate steering shaft by bonding using

Hysol adhesive a yoke stub shaft on each end where inner surface had glass section. The

other end (with teflon inner section) was left unbonded for a slip joint. The resulting

strucutal members were used as stroking intermediate steering shafts with satisfactory

results.

[133] Having described the preferred embodiments of the present invention, it is

understood that the invention defined by the appended claims is not to be limited by

particular details set forth in the above description, as many apparent variations thereof

are possible without departing from the spirit or scope thereof.

Claims

1. A contoured structural member (2), comprising: at least one contoured inner layer (4) comprising a composite material or a metal-

containing material; at least one contoured outer layer (8) comprising a composite material or a metal- containing material; at least one intermediate layer (6) having a ribbed structure connecting the at least one inner layer (4) and the art least one outer layer (8); and a coating (11).

2. The structural member of claim 1, wherein the stractural member has a closed configuration.

3. The structural member of claim 1, wherein the metal-containing material is a light metal or alloy thereof.

4. The stractural member of claim 1, wherein the metal-containing material is a heavy metal or alloy thereof.

5. The stractural member of claim 1, wherein the coating (11) is located on the outer surface, the inner surface, or both.

6. The structural member of claim 1 , wherein the coating (11) is located between the at least one inner layer (4) and the at least one intermediate layer (6), between the at least one

outer layer (8) ad the at least one intermediate layer (6), or both.

7. The stractural member of claim 1, wherein the coating (11) is incorporated within the at least one inner layer (4), within the at least one intermediate layer (6), within the at least one outer layer (8), or any combination thereof.

8. The stractural member of claim 1, wherein the coating (11) modifies the friction, magnetic, chemical properties, or conductivity properties of the at least one inner, at least one

intermediate layer (6), the at least one outer layer (8), of any combination thereof.

9. The stractural member of claim 1, wherein the coating (11) comprises Teflon.

10. The structural member of claim 1, wherein the ribbed stracture of the at least one intermediate layer (6) comprises a honeycomb stracture.

11. The structural member of claim 1, further comprising at least one initiator (14).

12. The structural member of claim 1, wherein the composite material is a reinforced resin matrix material.

13. The structural member of claim 12, wherein reinforced resin matrix material comprises at least one prepreg ply.

14. The stractural member of claim 1, wherein both the at least one inner layer (4) and the at least one outer layer (8) comprise a composite material.

15. The stractural member of claim 1, wherein both the at least one inner layer (4) and the at least one outer layer (8) comprise a metal-containing material.

16. The stractural member of claim 1, wherein the at least one inner layer (4)

comprises a composite material and the at least one outer layer (8) comprises a metal-containing material.

17. The structural member of claim 1, wherein the at least one inner layer (4) comprises a metal-containing material and the at least one outer layer (8) comprises a composite

material.

18. A contoured structural member (2), comprising: at least one contoured inner layer (4) comprising a composite material or a metal- containing material; at least one contoured outer layer (8) comprising a composite material or a metal-

containing material; at least one intermediate layer (6) having a honeycomb stracture connecting the at least one inner layer (4) and the art least one outer layer (8); and a coating (11) modifying the friction, magnetic, chemical resistance, or conductivity properties of the at least one inner layer (4), the at least one intermediate layer (6), the at least one outer layer (8), of any combination thereof.

19. A closed, contoured structural member (2), comprising: at least one contoured inner layer (4) comprising a composite material or a metal- containing material; at least one contoured outer layer (8) comprising a composite material or a metal- containing material; at least one intermediate layer (6) having a honeycomb structure connecting the at least one inner layer (4) and the art least one outer layer (8); and a coating (11) modifying the friction, magnetic, chemical resistance, or conductivity properties of the at least one inner layer (4), the at least one intermediate layer (6), the at least one

outer layer (8), of any combination thereof.

20. A closed, contoured stractural member (2), comprising:

at least one contoured inner layer (4) comprising a composite material or a metal-

containing material;

at least one contoured outer layer (8) comprising a composite material or a metal-

containing material;

at least one intermediate layer (6) having a honeycomb stracture being substantially

contiguous with the at least one inner layer (4) and the art least one outer layer (8); and

a coating (11) modifying the friction, magnetic, chemical resistance, or conductivity

properties of the at least one inner layer (4), the at least one intermediate layer (6), the at least one

outer layer (8), of any combination thereof.

21. A method for making a contoured structural member (2), comprising:

providing at least one inner layer (4) comprising a composite material or a metal-

containing material; roll wrapping at least one intermediate layer (6) over the at least one inner layer (4), the at

least one intermediate layer (6) having a ribbed structure;

providing at least one outer layer (8) over the at least one intermediate layer (6), the at

least one outer layer (8) comprising a composite material or a metal-containing material;

providing a coating (11) in or on the at least one inner layer (4), the at least one

intermediate layer (6), or the at least one outer layer (8); and connecting the at least one inner (4) and outer layer (8) to the at least one intermediate

layer (6);.

22. The method of claim 21 , including providing the at least one inner layer (4) by roll wrapping the at least one inner layer (4) over a substrate (20).

23. The method of claim 22, including providing the at least one outer layer (8) by roll wrapping the at least one outer layer (8) over the at least one intermediate layer (6).

24. The method of claim 23, further including removing the substrate (20).

25. The method of claim 24, including partially or completely filling the interior region (10) created by removing the substrate (20).

26. The method of claim 25, further including constraining the at least one outer layer (8) when connecting the at least one inner (4) and at least one outer layer (8) to the at least one intermediate layer (6) prior to removing the substrate (20).

27. The method of claim 26, including constraining the at least one outer layer (8) by roll wrapping at least one layer of a sMnk-wrap material (22) over the at least one outer layer

(8).

28. The method of claim 27, including removing the at least one layer of the shrink- wrap material (22) after the reaction.

29. The method of claim 27, further including providing at least one pressure distributor (26) over the at least one outer layer (8).

30. The method of claim 29, including providing a plurality of layers of shrink-wrap material (22) with the at least one pressure distributor (26) between two of said layers.

31. A method for making a contoured stractural member (2), comprising:

roll wrapping at least one inner layer (4) comprising a composite material or a metal- containing material over a substrate (20); roll wrapping at least one intermediate layer (6) over the at least one inner layer (4), the at least one intermediate layer (6) having a ribbed structure; and roll wrapping at least one outer layer (8) covering the at least one intermediate layer (6), the at least one outer layer (8) comprising a composite material or a metal-containing material; providing a coating (11) in or on the at least one inner layer (4), the at least one intermediate layer (6), or the at least one outer layer (8);

connecting the at least one inner (4) and outer layer (8) to the at least one intermediate layer (6); and removing the substrate (20).

32. The method of claim 31, including providing the coating (11) in or on the at least one inner layer (4), the at least one intermediate layer (6), or the at least one outer layer (8) before said layer is roll wrapped.

33. The method of claim 31, including providing the coating (11) on the at least one inner layer (4), the at least one intermediate layer (6), or the at least one outer layer (8) after said layer is roll wrapped.

34. A method for making a contoured stractural member (2), comprising:

roll wrapping at least one inner layer (4) comprising a composite material or a metal- containing material over a substrate (20); roll wrapping at least one intermediate layer (6) over the at least one inner layer (4), the at

least one intermediate layer (6) having a ribbed structure; and

roll wrapping at least one outer layer (8) covering the at least one intermediate layer (6),

the at least one outer layer (8) comprising a composite material or a metal-containing material;

intermediate layer (6), or the at least one outer layer (8);

constraining the outer portion with a shrink-wrap material (22);

connecting the at least one inner (4) and outer layer (8) to the at least one intermediate

layer (6); and

removing the shrink-wrap material (22) and the substrate (20).

35. A method for making a contoured structural member (2), comprising:

roll wrapping at least one inner layer (4) comprising a composite material or a metal-

containing material over a substrate (20);

roll wrapping at least one intermediate layer (6) having a honeycomb stracture to be

substantially contiguous with the at least one inner layer (4); and

roll wrapping at least one outer layer (8) to be substantially contiguous with the at least

one intermediate layer (6), the at least one outer layer (8) comprising a composite material or a

metal-containing material; providing a coating (11) in or on the at least one inner layer (4), the at least one

intermediate layer (6), or the at least one outer layer (8);

constraining the outer portion with a shrink-wrap material (22); connecting the at least one inner (4) and outer layer (8) to the at least one intermediate layer (6); and removing the shrink-wrap material (22) and the substrate (20).

36. A contoured stractural member (2) made by the method comprising: providing at least one inner layer (4) comprising a composite material or a metal- containing material;

roll wrapping at least one intermediate layer (6) over the at least one inner layer (4), the at least one intermediate layer (6) having a ribbed structure; providing at least one outer layer (8) over the at least one intermediate layer (6), the at least one outer layer (8) comprising a composite material or a metal-containing material; connecting the at least one inner (4) and outer layer (8) to the at least one intermediate layer (6); providing a coating (11) in or on the at least one inner layer (4), the at least one intermediate layer (6), or the at least one outer layer (8).

37. A contoured stractural member (2) made by the method comprising: roll wrapping at least one inner layer (4) comprising a composite material or a metal- containing material over a substrate (20);

roll wrapping at least one intermediate layer (6) over the at least one inner layer (4), the at least one intermediate layer (6) having a ribbed stracture; and

roll wrapping at least one outer layer (8) covering the at least one intermediate layer (6), the at least one outer layer (8) comprising a composite material or a metal-containing material; providing a coating (11) in or on the at least one inner layer (4), the at least one

intermediate layer (6), or the at least one outer layer (8); connecting the at least one inner (4) and outer layer (8) to the at least one intermediate layer (6); and removing the substrate (20).

38. A contoured stractural member (2) made by the method comprising: roll wrapping at least one inner layer (4) comprising a composite material or a metal- containing material over a substrate (20); roll wrapping at least one intermediate layer (6) over the at least one inner layer (4), the at least one intermediate layer (6) having a ribbed structure; and roll wrapping at least one outer layer (8) covering the at least one intermediate layer (6),

the at least one outer layer (8) comprising a composite material or a metal-containing material; providing a coating (11) in or on the at least one inner layer (4), the at least one intermediate layer (6), or the at least one outer layer (8); constraining the outer portion with a shrink-wrap material (22); connecting the at least one inner (4) and outer layer (8) to the at least one intermediate

layer (6); and removing the shrink-wrap material (22) and the substrate (20).

39. A contoured stractural member (2) made by the method comprising: roll wrapping at least one inner layer (4) comprising a composite material or a metal-

containing material over a substrate (20); roll wrapping at least one intermediate layer (6) having a honeycomb structure to be substantially contiguous with the at least one inner layer (4); and

roll wrapping at least one outer layer (8) to be substantially contiguous with the at least one intermediate layer (6), the at least one outer layer (8) comprising a composite material or a

metal-containing material; providing a coating (11) in or on the at least one inner layer (4), the at least one intermediate layer (6), or the at least one outer layer (8); constraining the outer portion with a shrink-wrap material (22); connecting the at least one inner (4) and outer layer (8) to the at least one intermediate layer (6); and removing the shrink-wrap material (22) and the substrate (20).