WO2002026677A3 - A methanol, olefin, and hydrocarbon synthesis process - Google Patents

A methanol, olefin, and hydrocarbon synthesis process Download PDF

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Publication number
WO2002026677A3
WO2002026677A3 PCT/US2001/028106 US0128106W WO0226677A3 WO 2002026677 A3 WO2002026677 A3 WO 2002026677A3 US 0128106 W US0128106 W US 0128106W WO 0226677 A3 WO0226677 A3 WO 0226677A3
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WIPO (PCT)
Prior art keywords
methanol
hydrocarbon synthesis
synthesis unit
olefin
integrates
Prior art date
Application number
PCT/US2001/028106
Other languages
French (fr)
Other versions
WO2002026677A2 (en
Inventor
Gary F Janda
Original Assignee
Exxonmobil Chem Patents Inc
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Publication date
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Priority to DE60119954T priority Critical patent/DE60119954D1/en
Priority to MXPA03002744A priority patent/MXPA03002744A/en
Priority to AU2001288901A priority patent/AU2001288901A1/en
Priority to CA002422844A priority patent/CA2422844A1/en
Priority to EP01968668A priority patent/EP1328497B1/en
Publication of WO2002026677A2 publication Critical patent/WO2002026677A2/en
Publication of WO2002026677A3 publication Critical patent/WO2002026677A3/en
Priority to NO20031381A priority patent/NO20031381L/en

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
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    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
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    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
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    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
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    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
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    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Abstract

An improved method for the production of methanol and hydrocarbons from a methane-containing gas, such as natural gas. The improved method integrates a hydrocarbon synthesis unit with a methanol synthesis unit without the need to recycle unreacted syngas exiting the methanol synthesis reactor. The invention combines a syngas stream and additional carbon dioxide from the hydrocarbon synthesis unit to form an optimal syngas composition for methanol and hydrocarbon synthesis. The invention also integrates other process parameters and process components of a methanol and hydrocarbon synthesis process plant to effectively convert most of the carbon in the natural gas to commercial-value products. The invention is also directed to a method of making olefin from the methanol produced by the process of the invention.
PCT/US2001/028106 2000-09-28 2001-09-06 A methanol, olefin, and hydrocarbon synthesis process WO2002026677A2 (en)

Priority Applications (6)

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DE60119954T DE60119954D1 (en) 2000-09-28 2001-09-06 METHOD FOR PRODUCING METHANOL, OLEFINES AND HYDROCARBONS
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US6444712B1 (en) 2002-09-03
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