WO2002067344A3 - Electrolytes with strong oxidizing additives for lithium/sulfur batteries - Google Patents

Electrolytes with strong oxidizing additives for lithium/sulfur batteries Download PDF

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Publication number
WO2002067344A3
WO2002067344A3 PCT/US2002/004274 US0204274W WO02067344A3 WO 2002067344 A3 WO2002067344 A3 WO 2002067344A3 US 0204274 W US0204274 W US 0204274W WO 02067344 A3 WO02067344 A3 WO 02067344A3
Authority
WO
WIPO (PCT)
Prior art keywords
lithium
battery
oxidizer
electrolytes
cell
Prior art date
Application number
PCT/US2002/004274
Other languages
French (fr)
Other versions
WO2002067344A2 (en
Inventor
May-Ying Chu
Yevgeniy S Nimon
Steven J Visco
Original Assignee
Polyplus Battery Co Inc
May-Ying Chu
Yevgeniy S Nimon
Steven J Visco
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Polyplus Battery Co Inc, May-Ying Chu, Yevgeniy S Nimon, Steven J Visco filed Critical Polyplus Battery Co Inc
Priority to AU2002306483A priority Critical patent/AU2002306483A1/en
Publication of WO2002067344A2 publication Critical patent/WO2002067344A2/en
Publication of WO2002067344A3 publication Critical patent/WO2002067344A3/en

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/06—Electrodes for primary cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/06—Electrodes for primary cells
    • H01M4/08—Processes of manufacture
    • H01M4/12—Processes of manufacture of consumable metal or alloy electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/381—Alkaline or alkaline earth metals elements
    • H01M4/382—Lithium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
    • H01M6/162—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
    • H01M6/162—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte
    • H01M6/168—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte by additives
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)

Abstract

Disclosed are oxidizer-treated lithium electrodes, battery cells containing such oxidizer-treated lithium electrodes, battery cell electrolytes containing oxidizing additives, and methods of treating lithium electrodes with oxidizing agents and battery cells containing such oxidizer-treated lithium electrodes. Battery cells containing SO2 as an electrolyte additive in accordance with the present invention exhibit higher discharge capacities after cell storage over cells not containing SO2. Pre-treating the lithium electrode with SO2 gas prior to battery assembly prevented cell polarization. Moreover, the SO2 treatment does not negatively impact sulfur utilization and improves the lithium's electrochemical function as the negative electrode in the battery cell.
PCT/US2002/004274 2001-02-20 2002-02-13 Electrolytes with strong oxidizing additives for lithium/sulfur batteries WO2002067344A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2002306483A AU2002306483A1 (en) 2001-02-20 2002-02-13 Electrolytes with strong oxidizing additives for lithium/sulfur batteries

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/789,379 US6632573B1 (en) 2001-02-20 2001-02-20 Electrolytes with strong oxidizing additives for lithium/sulfur batteries
US09/789,379 2001-02-20

Publications (2)

Publication Number Publication Date
WO2002067344A2 WO2002067344A2 (en) 2002-08-29
WO2002067344A3 true WO2002067344A3 (en) 2005-02-03

Family

ID=25147472

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2002/004274 WO2002067344A2 (en) 2001-02-20 2002-02-13 Electrolytes with strong oxidizing additives for lithium/sulfur batteries

Country Status (3)

Country Link
US (2) US6632573B1 (en)
AU (1) AU2002306483A1 (en)
WO (1) WO2002067344A2 (en)

Cited By (1)

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US9577289B2 (en) 2012-12-17 2017-02-21 Sion Power Corporation Lithium-ion electrochemical cell, components thereof, and methods of making and using same

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Also Published As

Publication number Publication date
US20040081894A1 (en) 2004-04-29
US6632573B1 (en) 2003-10-14
WO2002067344A2 (en) 2002-08-29
AU2002306483A1 (en) 2002-09-04

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