WO2002104072A3 - Emissive multichromophoric systems - Google Patents

Emissive multichromophoric systems Download PDF

Info

Publication number
WO2002104072A3
WO2002104072A3 PCT/US2002/005584 US0205584W WO02104072A3 WO 2002104072 A3 WO2002104072 A3 WO 2002104072A3 US 0205584 W US0205584 W US 0205584W WO 02104072 A3 WO02104072 A3 WO 02104072A3
Authority
WO
WIPO (PCT)
Prior art keywords
excited states
emissive
multichromophoric
multichromophoric systems
excited
Prior art date
Application number
PCT/US2002/005584
Other languages
French (fr)
Other versions
WO2002104072A2 (en
Inventor
Michael J Therien
Original Assignee
Univ Pennsylvania
Michael J Therien
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Pennsylvania, Michael J Therien filed Critical Univ Pennsylvania
Priority to CA002439060A priority Critical patent/CA2439060A1/en
Priority to EP02763188A priority patent/EP1363916A4/en
Priority to AU2002327166A priority patent/AU2002327166A1/en
Priority to JP2003506242A priority patent/JP2005503453A/en
Priority to US10/467,107 priority patent/US20040067198A1/en
Publication of WO2002104072A2 publication Critical patent/WO2002104072A2/en
Publication of WO2002104072A3 publication Critical patent/WO2002104072A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/22—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains four or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D519/00—Heterocyclic compounds containing more than one system of two or more relevant hetero rings condensed among themselves or condensed with a common carbocyclic ring system not provided for in groups C07D453/00 or C07D455/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B33/00—Electroluminescent light sources
    • H05B33/12—Light sources with substantially two-dimensional radiating surfaces
    • H05B33/14—Light sources with substantially two-dimensional radiating surfaces characterised by the chemical or physical composition or the arrangement of the electroluminescent material, or by the simultaneous addition of the electroluminescent material in or onto the light source
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/30—Coordination compounds
    • H10K85/361—Polynuclear complexes, i.e. complexes comprising two or more metal centers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10—Non-macromolecular compounds
    • C09K2211/1018—Heterocyclic compounds
    • C09K2211/1025—Heterocyclic compounds characterised by ligands
    • C09K2211/1029—Heterocyclic compounds characterised by ligands containing one nitrogen atom as the heteroatom
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/14—Macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/14—Macromolecular compounds
    • C09K2211/1408—Carbocyclic compounds
    • C09K2211/1416—Condensed systems
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/14—Macromolecular compounds
    • C09K2211/1408—Carbocyclic compounds
    • C09K2211/1425—Non-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/14—Macromolecular compounds
    • C09K2211/1441—Heterocyclic
    • C09K2211/1466—Heterocyclic containing nitrogen as the only heteroatom
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/18—Metal complexes
    • C09K2211/185—Metal complexes of the platinum group, i.e. Os, Ir, Pt, Ru, Rh or Pd
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/18—Metal complexes
    • C09K2211/188—Metal complexes of other metals not provided for in one of the previous groups
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • H10K71/10—Deposition of organic active material
    • H10K71/18—Deposition of organic active material using non-liquid printing techniques, e.g. thermal transfer printing from a donor sheet
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10—Organic polymers or oligomers
    • H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/30—Coordination compounds
    • H10K85/381—Metal complexes comprising a group IIB metal element, e.g. comprising cadmium, mercury or zinc
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/615—Polycyclic condensed aromatic hydrocarbons, e.g. anthracene

Abstract

Synthetic multichromophoric systems exhibiting low energy fluorescent excited states in which the transition dipoles of the pigment building blocks are correlated in defined phase relationships are provided. The polarized nature of these singlet excited states can be maintained over long (ns) timescales. In preferred embodiements ethyne- and butadiyne- bridged multiporphyrin species that manifest high excited-state anisotropies display exceptionally large emitting dipole strengths, establishing a new precedent for superradiant oligopigment assemblies.
PCT/US2002/005584 2001-02-26 2002-02-26 Emissive multichromophoric systems WO2002104072A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CA002439060A CA2439060A1 (en) 2001-02-26 2002-02-26 Emissive multichromophoric systems
EP02763188A EP1363916A4 (en) 2001-02-26 2002-02-26 Emissive multichromophoric systems
AU2002327166A AU2002327166A1 (en) 2001-02-26 2002-02-26 Emissive multichromophoric systems
JP2003506242A JP2005503453A (en) 2001-02-26 2002-02-26 Luminescent multicolor chromophore system
US10/467,107 US20040067198A1 (en) 2002-02-26 2002-02-26 Emissive multichromophoric systems

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US27152001P 2001-02-26 2001-02-26
US60/271,520 2001-02-26
US30650401P 2001-07-19 2001-07-19
US60/306,504 2001-07-19

Publications (2)

Publication Number Publication Date
WO2002104072A2 WO2002104072A2 (en) 2002-12-27
WO2002104072A3 true WO2002104072A3 (en) 2003-06-05

Family

ID=26954969

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2002/005584 WO2002104072A2 (en) 2001-02-26 2002-02-26 Emissive multichromophoric systems

Country Status (5)

Country Link
EP (1) EP1363916A4 (en)
JP (2) JP2005503453A (en)
AU (1) AU2002327166A1 (en)
CA (1) CA2439060A1 (en)
WO (1) WO2002104072A2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7682603B2 (en) * 2003-07-25 2010-03-23 The Trustees Of The University Of Pennsylvania Polymersomes incorporating highly emissive probes
US7378520B2 (en) * 2004-07-08 2008-05-27 North Carolina State University Synthesis of porphyrins designed for attachment to electroactive surfaces via one or more carbon tethers
DE102004044717B8 (en) * 2004-09-10 2010-12-16 BAM Bundesanstalt für Materialforschung und -prüfung Method and kit for calibrating a photoluminescence measuring system
US10510914B2 (en) 2013-03-21 2019-12-17 Board Of Trustees Of Michigan State University Transparent energy-harvesting devices

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5798306A (en) * 1996-04-17 1998-08-25 Corning Incorporated Rare earth doped oxyhalide laser glass
US5986090A (en) * 1992-08-14 1999-11-16 The Trustees Of The University Of Pennsylvania Metal-mediated cross-coupling with ring-metalated porphyrins

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07113031B2 (en) * 1989-12-15 1995-12-06 財団法人生産開発科学研究所 Porphyrin multimer and method for producing the same
US5599924A (en) * 1992-08-14 1997-02-04 Trustees Of The University Of Pennsylvania Electron-deficient porphyrins and processes and intermediates for preparing same
JP3150948B2 (en) * 1998-09-21 2001-03-26 科学技術振興事業団 Meso-position porphyrin polymer and method for producing the same
TW528789B (en) * 2000-12-22 2003-04-21 Koninkl Philips Electronics Nv Electroluminescent device comprising an electroluminescent material of at least two metal chelates

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5986090A (en) * 1992-08-14 1999-11-16 The Trustees Of The University Of Pennsylvania Metal-mediated cross-coupling with ring-metalated porphyrins
US5798306A (en) * 1996-04-17 1998-08-25 Corning Incorporated Rare earth doped oxyhalide laser glass

Also Published As

Publication number Publication date
CA2439060A1 (en) 2002-12-27
WO2002104072A2 (en) 2002-12-27
AU2002327166A1 (en) 2003-01-02
JP2007221168A (en) 2007-08-30
JP2005503453A (en) 2005-02-03
EP1363916A2 (en) 2003-11-26
EP1363916A4 (en) 2006-06-28

Similar Documents

Publication Publication Date Title
DE60329542D1 (en) Slot-fed microstrip patch antenna with high efficiency
EP1614189A4 (en) High efficiency crossed slot microstrip antenna
AU2002303385A1 (en) High luminescence phosphor particles
AU2001229538A1 (en) Low profile high polarization purity dual-polarized antennas
WO2003018653A1 (en) Phosphor light-emitting compound, phosphor light-emitting composition, and organic light emitting element
AU2002353064A1 (en) Multiple antenna diversity for wireless lan applications
AU2003273003A1 (en) Oxonitride phosphor and method for production thereof, and luminescent device using the oxonitride phosphor
AU2002249636A1 (en) Cold cathode fluorescent lamp
AU2003217075A1 (en) Crossed-field radio antenna
AU2003228312A1 (en) Multiband dual polarized adjustable beamtilt base station antenna
EP1418217A4 (en) Organo-electroluminescence element, luminescent material and organic compound
AU2003274044A1 (en) Multiband radio antenna
DE60208902D1 (en) MODULAR ANTENNA WITH DOUBLE POLARIZATION
AU2001243429A1 (en) High efficiency backwash shoe
AU2003243447A1 (en) Low profile, dual polarized antenna
AU2002359028A1 (en) Cold cathode type fluorescent lamp
WO2002104072A3 (en) Emissive multichromophoric systems
WO2001090147A3 (en) Long wavelength engineered fluorescent proteins
AU2003291185A8 (en) E-plane omni-directional antenna
AU2002364996A1 (en) Circular polarization antenna
AU2003206071A1 (en) Multiband microwave antenna
AU2002306620A1 (en) Fluorescent dye
AU2003242693A1 (en) BLUE EMITTING TRIS (8-OXOQUINOLINE) ALUMINUM (III) (AlQ3)
AU2002356814A1 (en) Antenna having cross polarization improvement using rotated antenna elements
HK1135794A1 (en) Field emission cold cathode

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PH PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 10467107

Country of ref document: US

WWE Wipo information: entry into national phase

Ref document number: 2439060

Country of ref document: CA

WWE Wipo information: entry into national phase

Ref document number: 2003506242

Country of ref document: JP

WWE Wipo information: entry into national phase

Ref document number: 2002763188

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 2002763188

Country of ref document: EP

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642