WO2003007067A1 - Electro-optic display and adhesive composition - Google Patents
Electro-optic display and adhesive composition Download PDFInfo
- Publication number
- WO2003007067A1 WO2003007067A1 PCT/US2002/020483 US0220483W WO03007067A1 WO 2003007067 A1 WO2003007067 A1 WO 2003007067A1 US 0220483 W US0220483 W US 0220483W WO 03007067 A1 WO03007067 A1 WO 03007067A1
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- WIPO (PCT)
- Prior art keywords
- electro
- optic
- volume resistivity
- filler
- adhesive
- Prior art date
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Classifications
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1334—Constructional arrangements; Manufacturing methods based on polymer dispersed liquid crystals, e.g. microencapsulated liquid crystals
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
- C09J9/02—Electrically-conducting adhesives
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/165—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on translational movement of particles in a fluid under the influence of an applied field
- G02F1/166—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on translational movement of particles in a fluid under the influence of an applied field characterised by the electro-optical or magneto-optical effect
- G02F1/167—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on translational movement of particles in a fluid under the influence of an applied field characterised by the electro-optical or magneto-optical effect by electrophoresis
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/165—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on translational movement of particles in a fluid under the influence of an applied field
- G02F1/1675—Constructional details
- G02F1/16757—Microcapsules
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
Definitions
- This invention relates to electro-optic displays and to adhesive compositions for use therein. More specifically, this invention relates to adhesive compositions having controlled volume resistivity, and to electro-optic displays incorporating such adhesive compositions. The adhesive compositions of the present invention may also be useful in applications other than electro-optic displays.
- Electro-optic displays comprise a layer of electro-optic material, a term which is used herein in its conventional meaning in the art to refer to a material having first and second display states differing in at least one optical property, the material being changed from its first to its second display state by application of an electric field to the material.
- the optical property is typically color perceptible to the human eye, but may be another optical property, such as optical transmission, reflectance, luminescence or, in the case of displays intended for machine reading, pseudo-color in the sense of a change in reflectance of electromagnetic wavelengths outside the visible range.
- electro-optic display is the rotating bichromal member type as described, for example, in U.S. Patents Nos. 5,808,783; 5,777,782 and 5.760,761 (this type of electro-optic medium is often referred to as a "rotating bichromal ball" medium, but the term "rotating bichromal member” is preferred since in some versions of the medium the rotating members are not spherical).
- electro-optic medium is an electrochromic medium, for example an electrochromic medium in the form of a nanochromic film comprising an electrode formed at least in part from a semi-conducting metal oxide and a plurality of dye molecules capable of reversible color change attached to the electrode; see, for example O'Regan, B., et al., Nature 1991, 353, 737; and Wood, D., Information Display, 18(3), 24 (March 2002). Nanochromic films of this type are also described, for example, in International Applications Publication Nos. WO 98/35267 and WO 01/27690.
- Electrophoretic display Another type of electro-optic display, which has been the subject of intense research and development for a number of years, is the particle-based electrophoretic display, in which a plurality of charged particles move through a suspending fluid under the influence of an electric field.
- Electrophoretic displays can have attributes of good brightness and contrast, wide viewing angles, state bistability, and low power consumption when compared with liquid crystal displays. Nevertheless, problems with the long-term image quality of these displays have prevented their widespread usage. For example, particles that make up electrophoretic displays tend to settle, resulting in inadequate service-life for these displays.
- encapsulated electrophoretic media comprise numerous small capsules, each of which itself comprises an internal phase containing electrophoretically-mobile particles suspended in a liquid suspension medium, and a capsule wall surrounding the internal phase.
- the capsules are themselves held within a polymeric binder to form a coherent layer positioned between two electrodes.
- Encapsulated media of this type are described, for example, in U.S. Patents Nos. 5,930,026
- An encapsulated, electrophoretic display typically does not suffer from the clustering and settling failure mode of traditional electrophoretic devices and provides further advantages, such as the ability to print or coat the display on a wide variety of flexible and rigid substrates.
- printing is intended to include all forms of printing and coating, including, but without limitation: pre-metered coatings such as patch die coating, slot or extrusion coating, slide or cascade coating, curtain coating; roll coating such as knife over roll coating, forward and reverse roll coating; gravure coating; dip coating; spray coating; meniscus coating; spin coating; brush coating; air knife coating; silk screen printing processes; electrostatic printing processes; thermal printing processes; ink jet printing processes; and other similar techniques.
- pre-metered coatings such as patch die coating, slot or extrusion coating, slide or cascade coating, curtain coating
- roll coating such as knife over roll coating, forward and reverse roll coating
- gravure coating dip coating
- spray coating meniscus coating
- spin coating spin coating
- brush coating air knife coating
- silk screen printing processes electrostatic printing processes
- electro-optic materials for example, liquid crystal, especially polymer-dispersed liquid crystal, may also be used in the displays of the present invention.
- an electro-optic display normally comprises at least two other layers disposed on opposed sides of the electro-optic material, one of these two layers being an electrode layer.
- both the layers are electrode layers, and one or both of the electrode layers are patterned to define the pixels of the display.
- one electrode layer may be patterned into elongate row electrodes and the other into elongate column electrodes running at right angles to the row electrodes, the pixels being defined by the intersections of the row and column electrodes.
- one electrode layer has the form of a single continuous electrode and the other electrode layer is patterned into a matrix of pixel electrodes, each of which defines one pixel of the display.
- electro-optic display which is intended for use with a stylus, print head or similar movable electrode separate from the display
- only one of the layers adjacent the electro-optic layer comprises an electrode, the layer on the opposed side of the electro-optic layer typically being a protective layer intended to prevent the movable electrode damaging the electro-optic layer.
- the manufacture of a three-layer electro-optic display normally involves at least one lamination operation.
- a process for manufacturing an encapsulated electrophoretic display in which an encapsulated electrophoretic medium comprising capsules in a binder is coated on to a flexible substrate comprising indium-tin-oxide or a similar conductive coating (which acts as an one electrode of the final display) on a plastic film, the capsules/binder coating being dried to form a coherent layer of the electrophoretic medium firmly adhered to the substrate.
- a backplane containing an array of pixel electrodes and an appropriate arrangement of conductors to connect the pixel electrodes to drive circuitry, is prepared.
- the substrate having the capsule/binder layer thereon is laminated to the backplane using a lamination adhesive.
- a lamination adhesive A very similar process can be used to prepare an electrophoretic display useable with a stylus or similar movable electrode by replacing the backplane with a simple protective layer, such as a plastic film, over which the stylus or other movable electrode can slide.
- the backplane is itself flexible and is prepared by printing the pixel electrodes and conductors on a plastic film or other flexible substrate.
- the obvious lamination technique for mass production of displays by the process described above is roll lamination using a lamination adhesive, which may be a pressure sensitive adhesive (PSA).
- a lamination adhesive which may be a pressure sensitive adhesive (PSA).
- PSA pressure sensitive adhesive
- lamination adhesives are of course readily available commercially, and several of these commercial materials have been found to meet the usual physico-chemical requirements for use in the roll lamination process described above, in that they provide a bond of sufficient strength and durability and are chemically compatible with the other components of the display, in that, for example they do not release any materials which interfere with the proper switching of the electrophoretic medium.
- any commercial pressure sensitive adhesive namely appropriate volume resistivity.
- the volume resistivity of the adhesive layer should not be too low, or lateral conduction of electric current through the continuous adhesive layer may cause undesirable cross-talk between adjacent electrodes.
- Encapsulated electrophoretic media typically have volume resistivities of the order of 5 x 10 10 ohm cm, and the volume resistivities of other electro-optic media are usually of the same order of magnitude.
- the volume resistivity of lamination adhesives used with such media should be around 10 10 ohm cm, whereas commercial PSA's have volume resistivities of about 10 12 to 10 15 ohm cm.
- volume resistivities of insulators can be decreased by blending a conductive filler (for example, silver flake, carbon black, polyaniline or poly(3,4-ethylenedioxythiophene)) with the insulator.
- a conductive filler for example, silver flake, carbon black, polyaniline or poly(3,4-ethylenedioxythiophene)
- the desired volume resistivity of about 10 1 ohm cm required for adhesives used in electro-optic displays typically falls in the middle of the very steep section of the composition/resistivity curve, where a very small change in the proportion of filler may cause an order of magnitude change in volume resistivity. It is difficult (and may be impracticable under mass production conditions) to control the proportion of filler with sufficient accuracy to maintain the volume resistivity desired in the adhesive. Furthermore, the variation of resistivity with proportion of filler at this point is so vertiginous that inevitable slight variations in the proportion of filler in particular areas of the display may cause undesirable effects in the display.
- volume resistivity of adhesives can be varied in a controlled manner to the range required for use in electro-optic displays be blending the adhesive with a filler having a controlled volume resistivity.
- the volume resistivity of this filler should not be lower that about two orders of magnitude less than the intended volume resistivity of the final blend. Desirably, the volume resistivity of the filler should be at least an order of magnitude less that the intended volume resistivity of the final blend.
- this invention provides an electro-optic display comprising first and second substrates, and an adhesive layer and a layer of electro-optic material disposed between the first and second substrates, the adhesive layer having a volume resistivity in the range of 10 9 to 10 11 ohm cm.
- the display of the present invention is characterized in that the adhesive layer comprises a mixture of an adhesive material having a volume resistivity of at least 5 x 10 ohm cm and a filler having a volume resistivity not less than 10 ohm cm, the filler being present in the mixture in a proportion above its percolation threshold in the adhesive material.
- This invention also provides an adhesive composition characterized in that it comprises a mixture of an adhesive material having a volume resistivity of at least 5 x 10 11 ohm cm and a filler having a volume resistivity not less than 10 7 ohm cm, the filler being present in the mixture in a proportion above its percolation threshold in the adhesive material.
- This invention also provides a method for the preparation of an adhesive composition having a volume resistivity of X (where X is an arbitrary number) starting from an adhesive material having a volume resistivity of at least 10X.
- This method is characterized by blending the adhesive material with a filler having a volume resistivity not greater than 0.1X but not less than 10 "3 X, the filler being blended with the adhesive material in a proportion above its percolation threshold in the adhesive material.
- Figure 1 of the accompanying drawings is a graph showing the change in volume resistivity of polyethylene upon addition of varying proportions of carbon black thereto;
- Figure 2 is a graph showing the variation in volume resistivity of GME-2417 (see below) upon addition of varying proportions of Soluol 105-304 (see below), as described in Example 1 below;
- Figure 3 is a graph showing the variation in volume resistivity of GME-2417 (see below) upon addition of varying proportions of NeoRez R 9320
- this invention provides an adhesive composition comprising a mixture of an adhesive material having a volume resistivity of at least 5 x 10 111 ohm cm and a filler having a volume resistivity not less than 10 7 ohm cm, the filler being present in the mixture in a proportion above its percolation threshold in the adhesive material, and an electro-optic display incorporating this adhesive composition.
- the volume resistivity of the present adhesive composition can be varied in a highly controllable manner by varying the proportion of the filler, thus allowing this volume resistivity to be adjusted to its optimum value for use with any specific electro-optic medium and other components of a display.
- the present invention is especially applicable to pressure sensitive adhesives, although it is also applicable to other types of adhesive, such as hot melt and heat-activated adhesives.
- the PSA's used in the present invention may be water-based, solvent-based or 100 per cent solids, such as ultra-violet curable
- PSA's may be, for example, acrylate, urethane or silicone-based PSA's.
- Specific commercial materials which have been found to be useful in the present invention include Gelva (Registered Trade Mark) multipolymer resin emulsion 2417 (usually known as GME-2417), an acrylic multipolymer emulsion available from Solutia Ine, 10300 Olive Boulevard, P.O. Box 66760, St. Louis MO 63166-
- the filler used in the present invention is typically a material having a volume resistivity in the range of about 10 8 to 5 x 10 9 ohm cm, and suitable materials include polyethylene glycol, urethane polymer dispersions, tailored acrylate polymers, diamond, zirconium oxide, silicon carbide and sodium-doped glass.
- suitable materials include polyethylene glycol, urethane polymer dispersions, tailored acrylate polymers, diamond, zirconium oxide, silicon carbide and sodium-doped glass.
- the presently preferred filler is Soluol 21-105HS, a polyurethane available from Soluol Chemical Co., Inc., P.O. Box 112, West Warwick RI 02893, United States of America; Soluol 105-304 from the same manufacturer has also been found useful.
- the percolation threshold for the filler varies widely, from greater than 20 to less than 2 per cent by volume, but can readily be determined empirically for any specific adhesive material/filler combination; as illustrated in the Examples below, the variation of volume resistivity with proportion of filler in the adhesive material/filler blend has the same general form as shown in Figure 1, with a sharp and characteristic decrease in volume resistivity at the percolation threshold.
- the proportion of filler in the adhesive layer will typically be in the range of 3 to 50 per cent by weight.
- the presently preferred blend for use in laminating electro-optic displays comprises 20 per cent by weight (calculated on dry weight) of Soluol 21-105HS filler and 80 per cent by weight Reichhold 97982-
- the electro-optic medium present in the displays of the present invention may be of any of the types previously discussed.
- the electro-optic medium may be a rotating bichromal member or electrochromic medium.
- the electro-optic medium be an electrophoretic medium comprising a plurality of capsules, each capsule comprising a capsule wall and an internal phase comprising electrically charged particles suspended in a suspending fluid and capable of moving through the fluid on application of an electric field to the electrophoretic medium.
- the electrophoretic medium comprises a polymeric binder within which the capsules are held.
- the display may be of any of the forms described in the aforementioned patents and applications.
- the display will comprise at least one electrode disposed between the electro-optic medium and one of the substrates, this electrode being arranged to apply an electric field to the electro-optic medium.
- the display will comprise two electrodes disposed on opposed sides of the electro-optic medium and between the electro-optic medium and the two substrates, at least one of the electrodes and the adjacent substrate being light-transmissive such that the electro-optic medium can be viewed through the light-transmissive substrate and electrode.
- Example 1 This Example illustrates the variation in volume resistivity achieved by adding the aforementioned Soluol 105-304 to the aforementioned GME-2417.
- Varying proportions of Soluol 105-304 were blended with GME- 2417 and the volume resistivities of films made from the resultant blends were calculated after measuring the current flow through a film of known dimensions on the application of a known voltage.
- the results are illustrated in Figure 2 of the accompanying drawings, which also shows theoretical results calculated assuming a percolation threshold for the Soluol 105-304 of 25% by volume.
- a simple model for percolation behavior assumes that for filler loadings below the percolation threshold the resistivity of a blend is given by the volume-fraction-weighted resistivity of the adhesive material in series with the filler. In other words, before percolation:
- Blends with a filler loading above the percolation threshold behave electrically as two resistors in parallel, and the film resistivity can be estimated by:
- NeoRez R 9320 a water-dispersible polyurethane available from NeoResins, 730 Main Street, Wilmington, MA 01887
- Varying proportions of NeoRez R 9320 were blended with GME-
- the volume resistivities of the resultant blends were measured in the same way as in Example 1 above.
- the results are illustrated in Figure 3 of the accompanying drawings, which also shows theoretical results calculated assuming a percolation threshold of 20 per cent by volume.
- the experimental results are a reasonably good fit to the model, displaying a sudden drop as the percolation threshold is passed and a slow decrease thereafter as the proportion of filler is increased.
- the blend has a volume resistivity of about 3 x 10 10 ohm cm, rendering it suitable for use in lamination of an electro-optic display.
- the electrophoretic media and displays of the present invention may employ the same components and manufacturing techniques as in the aforementioned MIT and E Ink patents and applications, to which the reader is referred for further information.
- the present invention provides for ready optimization of adhesive compositions used in electro-optic displays.
- the present can use readily available materials to achieve the desired adjustment of the volumes resistivity of adhesives, and requires only conventional apparatus and processing techniques which are familiar to those skilled in the manufacture of electro-optic displays.
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
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EP02742330A EP1407320B1 (en) | 2001-07-09 | 2002-06-28 | Electro-optic display and adhesive composition |
JP2003512774A JP2004535599A (en) | 2001-07-09 | 2002-06-28 | Electro-optical display and adhesive composition |
DE60216924T DE60216924T2 (en) | 2001-07-09 | 2002-06-28 | ELECTROOPTICAL DISPLAY AND ADHESIVE COMPOSITION |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US30401501P | 2001-07-09 | 2001-07-09 | |
US60/304,015 | 2001-07-09 |
Publications (1)
Publication Number | Publication Date |
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WO2003007067A1 true WO2003007067A1 (en) | 2003-01-23 |
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ID=23174659
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/US2002/020483 WO2003007067A1 (en) | 2001-07-09 | 2002-06-28 | Electro-optic display and adhesive composition |
Country Status (6)
Country | Link |
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US (1) | US6657772B2 (en) |
EP (1) | EP1407320B1 (en) |
JP (1) | JP2004535599A (en) |
AT (1) | ATE349028T1 (en) |
DE (1) | DE60216924T2 (en) |
WO (1) | WO2003007067A1 (en) |
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EP1616217A2 (en) * | 2003-03-27 | 2006-01-18 | E Ink Corporation | Electro-optic assemblies |
JP2007510956A (en) * | 2003-11-05 | 2007-04-26 | イー インク コーポレイション | Electro-optic display |
US20100303826A1 (en) * | 2003-07-31 | 2010-12-02 | Lfb Biotechnologies | Use of ADCC-Optimized antibodies for treating weak patients |
US8441432B2 (en) | 2005-09-23 | 2013-05-14 | Sipix Imaging, Inc. | Display cell structure and electrode protecting layer compositions |
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US7583251B2 (en) | 1995-07-20 | 2009-09-01 | E Ink Corporation | Dielectrophoretic displays |
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US7411719B2 (en) | 1995-07-20 | 2008-08-12 | E Ink Corporation | Electrophoretic medium and process for the production thereof |
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US7848006B2 (en) | 1995-07-20 | 2010-12-07 | E Ink Corporation | Electrophoretic displays with controlled amounts of pigment |
US8040594B2 (en) | 1997-08-28 | 2011-10-18 | E Ink Corporation | Multi-color electrophoretic displays |
DE69934618T2 (en) | 1998-07-08 | 2007-05-03 | E-Ink Corp., Cambridge | Improved colored microencapsulated electrophoretic display |
US7119772B2 (en) | 1999-04-30 | 2006-10-10 | E Ink Corporation | Methods for driving bistable electro-optic displays, and apparatus for use therein |
US7012600B2 (en) | 1999-04-30 | 2006-03-14 | E Ink Corporation | Methods for driving bistable electro-optic displays, and apparatus for use therein |
US8115729B2 (en) | 1999-05-03 | 2012-02-14 | E Ink Corporation | Electrophoretic display element with filler particles |
US8009348B2 (en) | 1999-05-03 | 2011-08-30 | E Ink Corporation | Machine-readable displays |
US7893435B2 (en) | 2000-04-18 | 2011-02-22 | E Ink Corporation | Flexible electronic circuits and displays including a backplane comprising a patterned metal foil having a plurality of apertures extending therethrough |
US6801001B2 (en) * | 2000-10-27 | 2004-10-05 | Science Applications International Corporation | Method and apparatus for addressing micro-components in a plasma display panel |
US7030854B2 (en) | 2001-03-13 | 2006-04-18 | E Ink Corporation | Apparatus for displaying drawings |
US8390918B2 (en) | 2001-04-02 | 2013-03-05 | E Ink Corporation | Electrophoretic displays with controlled amounts of pigment |
US7679814B2 (en) | 2001-04-02 | 2010-03-16 | E Ink Corporation | Materials for use in electrophoretic displays |
US20050156340A1 (en) | 2004-01-20 | 2005-07-21 | E Ink Corporation | Preparation of capsules |
US7535624B2 (en) | 2001-07-09 | 2009-05-19 | E Ink Corporation | Electro-optic display and materials for use therein |
US6982178B2 (en) | 2002-06-10 | 2006-01-03 | E Ink Corporation | Components and methods for use in electro-optic displays |
US6819471B2 (en) * | 2001-08-16 | 2004-11-16 | E Ink Corporation | Light modulation by frustration of total internal reflection |
US6825970B2 (en) * | 2001-09-14 | 2004-11-30 | E Ink Corporation | Methods for addressing electro-optic materials |
US8558783B2 (en) | 2001-11-20 | 2013-10-15 | E Ink Corporation | Electro-optic displays with reduced remnant voltage |
US7952557B2 (en) | 2001-11-20 | 2011-05-31 | E Ink Corporation | Methods and apparatus for driving electro-optic displays |
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JP2012108552A (en) * | 2003-11-05 | 2012-06-07 | E Ink Corp | Electro-optic display |
JP2015156035A (en) * | 2003-11-05 | 2015-08-27 | イー インク コーポレイション | Electro-optic display |
US8441432B2 (en) | 2005-09-23 | 2013-05-14 | Sipix Imaging, Inc. | Display cell structure and electrode protecting layer compositions |
Also Published As
Publication number | Publication date |
---|---|
ATE349028T1 (en) | 2007-01-15 |
DE60216924D1 (en) | 2007-02-01 |
EP1407320B1 (en) | 2006-12-20 |
DE60216924T2 (en) | 2007-04-05 |
US20030011867A1 (en) | 2003-01-16 |
JP2004535599A (en) | 2004-11-25 |
US6657772B2 (en) | 2003-12-02 |
EP1407320A1 (en) | 2004-04-14 |
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