WO2003081690A3 - Aqueous dispersions for antioxidants - Google Patents

Aqueous dispersions for antioxidants Download PDF

Info

Publication number
WO2003081690A3
WO2003081690A3 PCT/EP2003/002619 EP0302619W WO03081690A3 WO 2003081690 A3 WO2003081690 A3 WO 2003081690A3 EP 0302619 W EP0302619 W EP 0302619W WO 03081690 A3 WO03081690 A3 WO 03081690A3
Authority
WO
WIPO (PCT)
Prior art keywords
antioxidants
aqueous dispersions
relates
aqueous
polymer
Prior art date
Application number
PCT/EP2003/002619
Other languages
French (fr)
Other versions
WO2003081690A2 (en
Inventor
Daniel Thibaut
Original Assignee
Ciba Sc Holding Ag
Daniel Thibaut
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=28051877&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2003081690(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority to AU2003218751A priority Critical patent/AU2003218751A1/en
Priority to JP2003579294A priority patent/JP4399776B2/en
Priority to MXPA04009118A priority patent/MXPA04009118A/en
Priority to DE60303438T priority patent/DE60303438T3/en
Priority to DK03712000T priority patent/DK1485441T4/en
Application filed by Ciba Sc Holding Ag, Daniel Thibaut filed Critical Ciba Sc Holding Ag
Priority to SI200330188T priority patent/SI1485441T2/en
Priority to KR1020047014804A priority patent/KR101057745B1/en
Priority to US10/508,443 priority patent/US7205350B2/en
Priority to EP03712000A priority patent/EP1485441B2/en
Publication of WO2003081690A2 publication Critical patent/WO2003081690A2/en
Publication of WO2003081690A3 publication Critical patent/WO2003081690A3/en
Priority to US11/387,358 priority patent/US7323505B2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/205—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase
    • C08J3/21—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase the polymer being premixed with a liquid phase
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/06—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen
    • C09K15/08—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen containing a phenol or quinone moiety
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C08K5/134—Phenols containing ester groups
    • C08K5/1345—Carboxylic esters of phenolcarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/48—Stabilisers against degradation by oxygen, light or heat
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
    • C08J2329/02—Homopolymers or copolymers of unsaturated alcohols
    • C08J2329/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2429/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer

Abstract

The present invention relates to aqueous dispersions for solid phenolic antioxidants, wherein the antioxidants are dispersed in the aqueous phase with polyvinyl alcohol as dispersing agent. The invention also relates to a process, which comprises stabilising a polymer material against oxidative, thermal or light-induced degradation by adding to the polymer the aqueous dispersion.
PCT/EP2003/002619 2002-03-21 2003-03-13 Aqueous dispersions for antioxidants WO2003081690A2 (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
EP03712000A EP1485441B2 (en) 2002-03-21 2003-03-13 Aqueous dispersions for antioxidants
JP2003579294A JP4399776B2 (en) 2002-03-21 2003-03-13 Aqueous dispersions for antioxidants
MXPA04009118A MXPA04009118A (en) 2002-03-21 2003-03-13 Aqueous dispersions for antioxidants.
DE60303438T DE60303438T3 (en) 2002-03-21 2003-03-13 WAITER DISPERSIONS FOR ANTIOXIDANTS
DK03712000T DK1485441T4 (en) 2002-03-21 2003-03-13 Aqueous dispersions for antioxidants
AU2003218751A AU2003218751A1 (en) 2002-03-21 2003-03-13 Aqueous dispersions for antioxidants
SI200330188T SI1485441T2 (en) 2002-03-21 2003-03-13 Aqueous dispersions for antioxidants
KR1020047014804A KR101057745B1 (en) 2002-03-21 2003-03-13 Aqueous Dispersion for Antioxidants
US10/508,443 US7205350B2 (en) 2002-03-21 2003-03-13 Aqueous dispersions for antioxidants
US11/387,358 US7323505B2 (en) 2002-03-21 2006-03-23 Aqueous dispersions for antioxidants

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP02405218 2002-03-21
EP02405218.5 2002-03-21

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US10508443 A-371-Of-International 2003-03-13
US11/387,358 Continuation US7323505B2 (en) 2002-03-21 2006-03-23 Aqueous dispersions for antioxidants

Publications (2)

Publication Number Publication Date
WO2003081690A2 WO2003081690A2 (en) 2003-10-02
WO2003081690A3 true WO2003081690A3 (en) 2004-07-29

Family

ID=28051877

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2003/002619 WO2003081690A2 (en) 2002-03-21 2003-03-13 Aqueous dispersions for antioxidants

Country Status (14)

Country Link
US (2) US7205350B2 (en)
EP (1) EP1485441B2 (en)
JP (1) JP4399776B2 (en)
KR (1) KR101057745B1 (en)
CN (1) CN1290910C (en)
AT (1) ATE316996T1 (en)
AU (1) AU2003218751A1 (en)
DE (1) DE60303438T3 (en)
DK (1) DK1485441T4 (en)
ES (1) ES2256724T5 (en)
MX (1) MXPA04009118A (en)
SI (1) SI1485441T2 (en)
TW (1) TWI288775B (en)
WO (1) WO2003081690A2 (en)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006502302A (en) * 2002-10-04 2006-01-19 チバ　スペシャルティ　ケミカルズ　ホールディング　インコーポレーテッド Aqueous polymer dispersion, its manufacture and its use
JP2008507276A (en) * 2004-07-23 2008-03-13 ポルノクス コーポレーション Antioxidant macromonomer and antioxidant polymer, and method for producing and using the same
WO2006010718A1 (en) * 2004-07-27 2006-02-02 Ciba Specialty Chemicals Holding Inc. Process for preparing solid particles of phenolic antioxidants
CA2589883A1 (en) 2004-12-03 2006-06-08 Polnox Corporation Synthesis of aniline and phenol-based antioxidant macromonomers and corresponding polymers
CA2598703A1 (en) 2005-02-22 2006-08-31 Polnox Corporation Nitrogen and hindered phenol containing dual functional macromolecular antioxidants: synthesis , performances and applications
US7705185B2 (en) * 2005-03-25 2010-04-27 Polnox Corporation Alkylated and polymeric macromolecular antioxidants and methods of making and using the same
US7705176B2 (en) * 2005-10-27 2010-04-27 Polnox Corporation Macromolecular antioxidants based on sterically hindered phenols and phosphites
US20070106059A1 (en) * 2005-10-27 2007-05-10 Cholli Ashok L Macromolecular antioxidants and polymeric macromolecular antioxidants
EP1966293A1 (en) * 2005-10-27 2008-09-10 Polnox Corporation Stabilized polyolefin compositions
EP1963468A1 (en) 2005-12-02 2008-09-03 Polnox Corporation Lubricant oil compositions
US20090038701A1 (en) 2006-01-17 2009-02-12 Baxter International Inc. Device, system and method for mixing
WO2008005358A2 (en) * 2006-07-06 2008-01-10 Polnox Corporation Novel macromolecular antioxidants comprising differing antioxidant moieties: structures, methods of making and using the same
US7767853B2 (en) 2006-10-20 2010-08-03 Polnox Corporation Antioxidants and methods of making and using the same
CN101778893B (en) * 2007-08-01 2012-11-28 巴斯夫欧洲公司 Liquid antioxidant mixtures
KR20110042283A (en) * 2008-07-11 2011-04-26 바스프 에스이 Storage-stable aqueous emulsions and liquid blends with low viscosity as stabilizers
US8674810B2 (en) * 2009-04-22 2014-03-18 Franwell, Inc. Wearable RFID system
US8859235B2 (en) 2009-08-14 2014-10-14 Basf Se Methods in cell cultures, and related inventions, employing certain additives
CN101805458B (en) * 2010-04-07 2012-02-08 天津力生化工有限公司 Method for preparing emulsion composite antioxidant
CN102344581B (en) * 2011-06-14 2013-01-16 江苏飞亚化学工业有限责任公司 Preparation method of emulsion type low-particle-diameter high-efficiency antioxidant
US10294423B2 (en) 2013-11-22 2019-05-21 Polnox Corporation Macromolecular antioxidants based on dual type moiety per molecule: structures, methods of making and using the same
PL3102631T3 (en) * 2014-02-03 2019-01-31 Arlanxeo Deutschland Gmbh Stabilized rubbers
JP6510178B2 (en) * 2014-04-03 2019-05-08 株式会社クラレ Method of producing polyvinyl alcohol film
CN113336878A (en) 2015-11-19 2021-09-03 巴斯夫欧洲公司 Ammonia-based imide-containing resin cuttings of styrene-maleic acid resins
CN106589456A (en) * 2016-12-17 2017-04-26 大连大学 High-temperature stable antioxidant emulsion and preparation method thereof
US20180251695A1 (en) 2017-03-01 2018-09-06 Polnox Corporation Macromolecular Corrosion (McIn) Inhibitors: Structures, Methods Of Making And Using The Same
EP3666835A1 (en) * 2018-12-14 2020-06-17 Henkel AG & Co. KGaA Water based dispersion to make coatings with increased mvtr barrier properties out of it
CN114478841B (en) * 2021-12-29 2023-07-14 广东希必达新材料科技有限公司 Preparation method and application of emulsion type suspension termination liquid
WO2023202971A1 (en) * 2022-04-20 2023-10-26 Basf Se An aqueous antioxidant suspoemulsion and a process for preparing the same

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1366702A (en) * 1971-05-22 1974-09-11 Reynolds R J W Stabilisation of polymeric materials
EP0458509A1 (en) * 1990-05-15 1991-11-27 E.I. Du Pont De Nemours And Company Oxidation-resistant ethylene vinyl alcohol polymer compositions
EP0884352A1 (en) * 1997-06-11 1998-12-16 Kuraray Co., Ltd. Water-soluble film
EP1085069A1 (en) * 1999-09-14 2001-03-21 Ricoh Company, Ltd. Heat activatable adhesive composition and adhesive sheet having adhesive layer thereof
US6277910B1 (en) * 1996-01-18 2001-08-21 Akzo Nobel Industrial Coatings, Ab Water-borne hybrid binder composition and use thereof

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JPH0788401B2 (en) † 1987-03-06 1995-09-27 信越化学工業株式会社 Method for producing vinyl chloride polymer
JPH11349940A (en) † 1998-06-11 1999-12-21 Yoshitomi Fine Chemical Kk Antioxidant dispersion
JP2000290308A (en) † 1999-04-09 2000-10-17 Shin Etsu Chem Co Ltd Production of vinyl chloride polymer
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GB0004436D0 (en) * 2000-02-25 2000-04-12 Clariant Int Ltd Synergistic stabilizer compositions for thermoplastic polymers in prolonged contact with water
JP2002308917A (en) * 2001-04-17 2002-10-23 Shin Etsu Chem Co Ltd Method for producing vinyl polymer

Patent Citations (5)

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Publication number Priority date Publication date Assignee Title
GB1366702A (en) * 1971-05-22 1974-09-11 Reynolds R J W Stabilisation of polymeric materials
EP0458509A1 (en) * 1990-05-15 1991-11-27 E.I. Du Pont De Nemours And Company Oxidation-resistant ethylene vinyl alcohol polymer compositions
US6277910B1 (en) * 1996-01-18 2001-08-21 Akzo Nobel Industrial Coatings, Ab Water-borne hybrid binder composition and use thereof
EP0884352A1 (en) * 1997-06-11 1998-12-16 Kuraray Co., Ltd. Water-soluble film
EP1085069A1 (en) * 1999-09-14 2001-03-21 Ricoh Company, Ltd. Heat activatable adhesive composition and adhesive sheet having adhesive layer thereof

Also Published As

Publication number Publication date
DE60303438D1 (en) 2006-04-13
MXPA04009118A (en) 2004-12-07
SI1485441T2 (en) 2009-12-31
KR101057745B1 (en) 2011-08-19
US20050245654A1 (en) 2005-11-03
SI1485441T1 (en) 2006-06-30
KR20040094825A (en) 2004-11-10
DE60303438T2 (en) 2006-07-13
AU2003218751A1 (en) 2003-10-08
AU2003218751A8 (en) 2003-10-08
DK1485441T4 (en) 2009-11-23
CN1643099A (en) 2005-07-20
EP1485441B2 (en) 2009-08-05
DE60303438T3 (en) 2010-04-15
TW200400246A (en) 2004-01-01
ES2256724T5 (en) 2009-11-27
US7205350B2 (en) 2007-04-17
ES2256724T3 (en) 2006-07-16
JP2005520923A (en) 2005-07-14
CN1290910C (en) 2006-12-20
ATE316996T1 (en) 2006-02-15
EP1485441A2 (en) 2004-12-15
WO2003081690A2 (en) 2003-10-02
EP1485441B1 (en) 2006-02-01
US20060167152A1 (en) 2006-07-27
JP4399776B2 (en) 2010-01-20
TWI288775B (en) 2007-10-21
DK1485441T3 (en) 2006-04-24
US7323505B2 (en) 2008-01-29

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