WO2004035636A3 - Polymerized cycloolefins using transition metal catalyst and end products thereof - Google Patents

Polymerized cycloolefins using transition metal catalyst and end products thereof Download PDF

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Publication number
WO2004035636A3
WO2004035636A3 PCT/US2003/032474 US0332474W WO2004035636A3 WO 2004035636 A3 WO2004035636 A3 WO 2004035636A3 US 0332474 W US0332474 W US 0332474W WO 2004035636 A3 WO2004035636 A3 WO 2004035636A3
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WO
WIPO (PCT)
Prior art keywords
complex
transition metal
weakly coordinating
group
metal catalyst
Prior art date
Application number
PCT/US2003/032474
Other languages
French (fr)
Other versions
WO2004035636A2 (en
Inventor
Larry F Rhodes
Andrew Bell
R Ravikiran
John C Fondran
Saikumar Jayaraman
Brian L Goodall
Richard A Mimna
John-Henry Lipian
Original Assignee
Promerus Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Promerus Llc filed Critical Promerus Llc
Priority to AU2003287068A priority Critical patent/AU2003287068A1/en
Publication of WO2004035636A2 publication Critical patent/WO2004035636A2/en
Publication of WO2004035636A3 publication Critical patent/WO2004035636A3/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F32/00—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F32/00—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C08F32/08—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having two condensed rings
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics

Abstract

Articles. Especially in electronic, optical and opoelectronic applications, comprising an optical polymer containing polycyclic repeating units, said optical polymer being obtained through the addition polymerization of cycloolefins using a cationic group 10 metal complex and a weakly coordinating anion of the formula: [(R')ZM(L')X(L'')y]b [WCA]d wherein [(R')ZM(L')x(L'')y] is a cation complex where M represents a Group 10 transition metal; R' represents an anionic hydrocarbyl containing ligand; L' represents a Group 15 neutral electron donor ligand; L' represents a labile neutral electron donor ligand; x is 1 or 2; and y is 0, 1, 2, or 3; and z is 0 or 1, wherein the sum of x, y, and z is 4; and [WCA] represents a weakly coordinating counteranion complex; and b and d are numbers representing the number of times the cation complex and weakly coordinating counteranion complex are taken to balance the electronic charge on the overall catalyst complex.
PCT/US2003/032474 2002-10-15 2003-10-14 Polymerized cycloolefins using transition metal catalyst and end products thereof WO2004035636A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2003287068A AU2003287068A1 (en) 2002-10-15 2003-10-14 Polymerized cycloolefins using transition metal catalyst and end products thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/271,393 US6903171B2 (en) 1998-10-05 2002-10-15 Polymerized cycloolefins using transition metal catalyst and end products thereof
US10/271,393 2002-10-15

Publications (2)

Publication Number Publication Date
WO2004035636A2 WO2004035636A2 (en) 2004-04-29
WO2004035636A3 true WO2004035636A3 (en) 2005-01-13

Family

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Family Applications (1)

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PCT/US2003/032474 WO2004035636A2 (en) 2002-10-15 2003-10-14 Polymerized cycloolefins using transition metal catalyst and end products thereof

Country Status (3)

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US (2) US6903171B2 (en)
AU (1) AU2003287068A1 (en)
WO (1) WO2004035636A2 (en)

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Also Published As

Publication number Publication date
US7910674B2 (en) 2011-03-22
US20030181607A1 (en) 2003-09-25
WO2004035636A2 (en) 2004-04-29
US20040048994A1 (en) 2004-03-11
AU2003287068A1 (en) 2004-05-04
AU2003287068A8 (en) 2004-05-04
US6903171B2 (en) 2005-06-07

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