WO2004078654A3 - Free radical solution water - Google Patents

Free radical solution water Download PDF

Info

Publication number
WO2004078654A3
WO2004078654A3 PCT/US2003/006600 US0306600W WO2004078654A3 WO 2004078654 A3 WO2004078654 A3 WO 2004078654A3 US 0306600 W US0306600 W US 0306600W WO 2004078654 A3 WO2004078654 A3 WO 2004078654A3
Authority
WO
WIPO (PCT)
Prior art keywords
water
molecules
free radical
frs
free
Prior art date
Application number
PCT/US2003/006600
Other languages
French (fr)
Other versions
WO2004078654A2 (en
Inventor
Kenji Fukui
Kazunari Naya
Tim M Itamura
Original Assignee
Kenji Fukui
Kazunari Naya
Tim M Itamura
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kenji Fukui, Kazunari Naya, Tim M Itamura filed Critical Kenji Fukui
Priority to JP2004569169A priority Critical patent/JP2006513849A/en
Priority to PCT/US2003/006600 priority patent/WO2004078654A2/en
Priority to US10/547,722 priority patent/US20060263441A1/en
Priority to CNA038260689A priority patent/CN1784238A/en
Priority to AU2003223222A priority patent/AU2003223222A1/en
Priority to EP03719352A priority patent/EP1617851A4/en
Publication of WO2004078654A2 publication Critical patent/WO2004078654A2/en
Publication of WO2004078654A3 publication Critical patent/WO2004078654A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/4608—Treatment of water, waste water, or sewage by electrochemical methods using electrical discharges
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K33/00—Medicinal preparations containing inorganic active ingredients
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104—Devices therefor; Their operating or servicing
    • C02F1/4618—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00—Multistage treatment of water, waste water or sewage
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/30—Treatment of water, waste water, or sewage by irradiation
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/48—Treatment of water, waste water, or sewage with magnetic or electric fields
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
    • C02F2001/425—Treatment of water, waste water, or sewage by ion-exchange using cation exchangers
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104—Devices therefor; Their operating or servicing
    • C02F1/4618—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • C02F2001/46195—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water characterised by the oxidation reduction potential [ORP]
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/02—Non-contaminated water, e.g. for industrial water supply
    • C02F2103/026—Treating water for medical or cosmetic purposes
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/04—Oxidation reduction potential [ORP]
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/06—Controlling or monitoring parameters in water treatment pH
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/23—O3
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/02—Odour removal or prevention of malodour
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/04—Disinfection
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/18—Removal of treatment agents after treatment
    • C02F2303/185—The treatment agent being halogen or a halogenated compound
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00—Use of specific compounds during water treatment
    • C02F2305/02—Specific form of oxidant
    • C02F2305/023—Reactive oxygen species, singlet oxygen, OH radical

Abstract

Free Radical Solution functional (electrolyzed) water with high oxidation reduction potential of 900mV, and with a stable Hydrogen Ion Concentration (HIC) level of 6-8 pH is provided that cleans, deodorizes, and sterilizes without any chemicals. The FRS water is pollution free, non-chemical and water based solution. The original and the resulting end material (or component) in the process of producing FRS water is simply water (H20). Using transformation of water molecules by pretreatment and electrolysis processes, water is transformed to Free Radical Solution water wherein the free radicals in the FRS water solution add the very unique (physical) characteristics and functions that makes this water different from regular water (physically). The transformation is not chemical, but a physical change of atoms or molecules in water, i.e. the H20 molecules of water are transformed into different types of free radicals. The transformations are random, continuous, and repeat for at least two hours after production.
PCT/US2003/006600 2003-03-04 2003-03-04 Free radical solution water WO2004078654A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2004569169A JP2006513849A (en) 2003-03-04 2003-03-04 Water as a free radical solution
PCT/US2003/006600 WO2004078654A2 (en) 2003-03-04 2003-03-04 Free radical solution water
US10/547,722 US20060263441A1 (en) 2003-03-04 2003-03-04 Free radical solution water
CNA038260689A CN1784238A (en) 2003-03-04 2003-03-04 Free radical solution water
AU2003223222A AU2003223222A1 (en) 2003-03-04 2003-03-04 Free radical solution water
EP03719352A EP1617851A4 (en) 2003-03-04 2003-03-04 Free radical solution water

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2003/006600 WO2004078654A2 (en) 2003-03-04 2003-03-04 Free radical solution water

Publications (2)

Publication Number Publication Date
WO2004078654A2 WO2004078654A2 (en) 2004-09-16
WO2004078654A3 true WO2004078654A3 (en) 2005-09-15

Family

ID=32961108

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2003/006600 WO2004078654A2 (en) 2003-03-04 2003-03-04 Free radical solution water

Country Status (5)

Country Link
EP (1) EP1617851A4 (en)
JP (1) JP2006513849A (en)
CN (1) CN1784238A (en)
AU (1) AU2003223222A1 (en)
WO (1) WO2004078654A2 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1461474B1 (en) 2001-12-05 2011-11-30 Oculus Innovative Sciences, Inc. Method and apparatus for producing negative and positive oxidative reductive potential (orp) water
US9168318B2 (en) 2003-12-30 2015-10-27 Oculus Innovative Sciences, Inc. Oxidative reductive potential water solution and methods of using the same
BRPI0609429B8 (en) 2005-03-23 2021-07-20 Invekra S A P I De C V use of an aqueous solution with redox potential (ORP)
AU2006242175A1 (en) 2005-05-02 2006-11-09 Oculus Innovative Sciences, Inc. Method of using oxidative reductive potential water solution in dental applications
SI1945576T1 (en) 2005-10-28 2013-02-28 Apr Nanotechnologies S.A. Device comprising an electrode with nanocoating for preparing a highly stable aqueous solution and method for making this aqueous solution
US20070196357A1 (en) 2006-01-20 2007-08-23 Oculus Innovative Sciences, Inc. Methods of treating or preventing inflammation and hypersensitivity with oxidative reductive potential water solution
US8709495B2 (en) * 2007-04-25 2014-04-29 Apr Nanotechnologies S.A. Highly stable electrolytic water with reduced NMR half line width
WO2008139653A1 (en) * 2007-05-10 2008-11-20 Kurashiki Boseki Kabushiki Kaisha Method of washing and apparatus for use therein
JP6033082B2 (en) 2009-06-15 2016-11-30 オキュラス イノヴェイティヴ サイエンシズ、インコーポレイテッド Solution containing hypochlorous acid and method of using the same
ES2549913T3 (en) 2009-06-17 2015-11-03 Apr Nanotechnologies S.A. Methods of treatment of external ocular disorders using high ORP acid water and compositions thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5833831A (en) * 1994-03-25 1998-11-10 Nec Corporation Method and system for generating electrolyzed water
US6143163A (en) * 1997-08-06 2000-11-07 Permelec Electrode Ltd. Method of water electrolysis

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6426066B1 (en) * 2000-01-12 2002-07-30 California Pacific Labs, Inc. Use of physiologically balanced, ionized, acidic solution in wound healing

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5833831A (en) * 1994-03-25 1998-11-10 Nec Corporation Method and system for generating electrolyzed water
US6143163A (en) * 1997-08-06 2000-11-07 Permelec Electrode Ltd. Method of water electrolysis

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP1617851A4 *

Also Published As

Publication number Publication date
AU2003223222A1 (en) 2004-09-28
AU2003223222A8 (en) 2004-09-28
EP1617851A4 (en) 2011-09-21
CN1784238A (en) 2006-06-07
WO2004078654A2 (en) 2004-09-16
JP2006513849A (en) 2006-04-27
EP1617851A2 (en) 2006-01-25

Similar Documents

Publication Publication Date Title
Bilińska et al. Novel trends in AOPs for textile wastewater treatment. Enhanced dye by-products removal by catalytic and synergistic actions
Martín-Lara et al. New treatment of real electroplating wastewater containing heavy metal ions by adsorption onto olive stone
Li et al. Pretreatment of acrylic fiber manufacturing wastewater by the Fenton process
WO2004078654A3 (en) Free radical solution water
Naumczyk et al. Electrochemical treatment of tannery wastewater—Raw, coagulated, and pretreated by AOPs
CN105692861B (en) The advanced oxidization method of artificial sweetener in a kind of removal sewage
Pillai et al. Performance analysis of a continuous serpentine flow reactor for electrochemical oxidation of synthetic and real textile wastewater: Energy consumption, mass transfer coefficient and economic analysis
MX2009005627A (en) Removal of contaminants from a waste stream through production and utilization of oxyhydrogen gas.
CN105502739A (en) Method for synchronous complex breaking and heavy metal removal based on self-strengthening ozone
CN103819024B (en) Pretreatment method for fluorenone production wastewater
Wang et al. Synergistic removal of ammonia nitrogen by UV photo-electrocatalytic process: Heterogeneous reaction pathways and mechanism
CN102344225B (en) Processing method of salty wastewater in cellulose ether production
Perkowski et al. Application of Fenton’s reagent in detergent separation in highly concentrated water solutions
CN107721040A (en) A kind of garbage percolation liquid treating system and its method
Bustos et al. Treatment of industrial effluents by electrochemical generation of H2O2 using an RVC cathode in a parallel plate reactor
Khataee et al. Treatment of an Azo dye by citrate catalyzed photoelectro-Fenton process under visible light using carbon nanotube-polytetrafluoroethylene cathode
Bae et al. Evaluation of predominant reaction mechanisms for the Fenton process in textile dyeing wastewater treatment
Xie et al. Enhanced• Cl generation by introducing electrophilic Cu (II) in Co3O4 anode for efficient total nitrogen removal with hydrogen recovery in urine treatment
KR100713615B1 (en) Offensive odor treatment apparatus using chlorine dioxide
李天成 et al. Purification of Organic Wastewater Containing Cu^(2+) and Cr^(3+) by a Combined Process of Micro Electrolysis and Biofilm
CN105502855A (en) Method for performing combined treatment on TAIC industrial wastewater through alkaline demulsification and hydrolysis-contact oxidation system
Palahouanea et al. Remediation of post treated fluorinated photovoltaic wastewater by electrocoagulation
CN205115211U (en) Organic high ammonia -nitrogen concentration waste water treatment integration equipment
Satapathy et al. Surface modification of granular activated carbon by nitric acid for the enhancement of copper adsorption
Gutiérrez-Bouzán et al. Interaction between pH and Conductivity in the Indirect Electro-oxidation of Azo Dyes

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ OM PH PL PT RO RU SC SD SE SG SK SL TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 1020057016272

Country of ref document: KR

Ref document number: 20038260689

Country of ref document: CN

WWE Wipo information: entry into national phase

Ref document number: 2004569169

Country of ref document: JP

WWE Wipo information: entry into national phase

Ref document number: 2003719352

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 1020057016272

Country of ref document: KR

WWP Wipo information: published in national office

Ref document number: 2003719352

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2006263441

Country of ref document: US

Ref document number: 10547722

Country of ref document: US

WWP Wipo information: published in national office

Ref document number: 10547722

Country of ref document: US