WO2004093156A2

WO2004093156A2 - Method of fabricating a polymer matrix composite electromagnetic shielding structure

Info

Publication number: WO2004093156A2
Application number: PCT/US2004/009625
Authority: WO
Inventors: Edward W. Sheridan; Walter B. May; Gene P. Shumaker; Michael Griffith; Donald G. Rollin; Bobby G. Isler
Original assignee: Lockheed Martin Corporation
Priority date: 2003-03-31
Filing date: 2004-03-31
Publication date: 2004-10-28
Also published as: US20040188890A1; AU2004230038B2; EP1620261A2; DE602004019513D1; EP1620261B1; WO2004093156A3; EP1620261A4; ATE422998T1; AU2004230038A1; US7208115B2

Abstract

An exemplary method of manufacturing a polymer matrix composite electromagnetic shielding structure includes pretreating a dry fiber reinforcement with a composition including a carrier and a conductive element, laying out the pretreated reinforcement to form a pre-form structure, applying a resin to the pre-form structure, and curing the resin at room temperature. Another exemplary method of manufacturing a polymer matrix composite electromagnetic shielding structure includes laying out a plurality of dry fiber reinforcements, placing at least one ply between any two of the plurality of dry fiber reinforcements, the ply having a non-woven including a conductive material, applying a resin to the plurality of dry fiber reinforcements and the at least one ply, and curing the resin.

Description

METHOB OF FABRICATING A POLYMER MATRIX COMPOSITE ELECTROMAGNETIC SHIELDING STRUCTURE

BACKGROUND 0001 Polymer matrix composite structures can be modified to form electromagnetic interference (EMI) shielding materials. For example, EMI shielding in the form of metal-coated fibers forming a discontinuous phase in a continuous phase matrix material is disclosed in U.S. Pat. No. 4,935,296. Radar absorbing materials are described in U.S. Patent No. 5,661,484. Electrically conductive laminates, conductive coatings, conductive adhesives, conductive inks, conductive gaskets and conductive caulking and sealing compounds using metal coated fibers are disclosed in U.S. Patent No. 4,983,456. Electrically conductive bulk, granular or nodular molding compounds comprising a multi-component filler system of particulate carbon black, graphite and metal particles are disclosed in U.S. Patent No. 4,474,685.

0002 Polymer matrix composites can be been manufactured by several techniques, such as preimpregnated fabric hand lay-up (so called prepreg) techniques and by resin transfer molding (RTM) techniques. Prepreg techniques generally include depositing resin on structural supports, such as a cloth, fabric or fiberglass, stacking the structural supports, and heating the stacked structural supports in an external heat source, such as an oven, an autoclave, or a heat lamp. Similarly, RTM techniques assemble dry structural reinforcements in a specifically designed tool, pump resin using a positive displacement pump, and apply pressure and/or temperature to form the polymer matrix composite structure. 0003 With both prepreg and RTM methods, the resin flows during heating to penetrate throughout the structure and subsequently cures, thereby forming a unitary polymer matrix composite stracture. However, the flow of the resin can also cause portions of the structure in the structural support to shift position, thereby forming defects and/or voids within the polymer matrix composite. In addition, the flow of resin can be incomplete in that resin does not penetrate into certain areas of the structural support and/or penetrates nonuniformly. Incomplete resin flow can also contribute to the formation of defects and/or voids within the polymer matrix composite.

SUMMARY

0004 An exemplary method of manufacturing a polymer matrix composite electromagnetic shielding structure comprises pretreating a dry fiber reinforcement with a composition including a carrier and an electromagnetically active element, laying out the pretreated reinforcement to form a pre-form stracture, applying a resin to the pre-form structure, and curing the resin at room temperature.

0005 An exemplary method of manufacturing a polymer matrix composite electromagnetic shielding stracture comprises pretreating a dry fiber reinforcement with a composition including a carrier and an electromagnetically active element, laying out the pretreated reinforcement to form a pre-form stracture, applying a resin to the pre-foπn structure, the resin including at least one of a polyester-based resin, a vinyl ester-based resin, and an epoxy polyurethane-based resin, and curing the resin.

0006 An exemplary method of manufacturing a polymer matrix composite electromagnetic shielding stracture comprises laying out a plurality of dry fiber reinforcements, placing at least one ply between any two of the plurality of dry fiber reinforcements, the ply having a non-woven including an electromagnetically active element, applying a resin to the plurality of dry fiber reinforcements and the at least one ply, and curing the resin.

0007 An exemplary method of manufacturing a polymer matrix composite electromagnetic shielding stracture comprises laying out a plurality of resin impregnated reinforcements, placing at least one ply between any two of the plurality of resin impregnated reinforcements, the ply having a non- woven including an electromagnetically active element, and curing the resin impregnated reinforcement. 0008 An exemplary polymer matrix composite electromagnetic shielding structure comprises pretreating a dry fiber reinforcement with a composition including a carrier and an electromagnetically active element, laying out the pretreated reinforcement to form a pre-form stracture, applying at least one of a polyester-based resin, a vinyl ester-based resin, an epoxy polyurethane-based resin, and an epichlorohydrin resin, and curing the resin.

BRIEF DESCRIPTION OF THE DRAWING FIGURES

0009 The following detailed description of preferred embodiments can be read in connection with the accompanying drawings in which like numerals designate like elements and in which:

0010 FIG. 1 schematically illustrates an exemplary method of manufacturing a polymer matrix composite electromagnetic shielding structure.

0011 FIG. 2 shows an expanded view of an exemplary polymer matrix composite electromagnetic shielding structure in an exemplary manufacturing method.

0012 FIG. 3 schematically illustrates an exemplary method of manufacturing a polymer matrix composite electromagnetic shielding structure.

0013 FIG. 4 shows an expanded view of an exemplary polymer matrix composite electromagnetic shielding structure.

0014 Figure 5 schematically illustrates another exemplary method of manufacturing a polymer matrix composite electromagnetic shielding structure. DETALLED DESCRIPTION OF PREFERRED EMBODIMENTS

0015 Figure 1 schematically illustrates an exemplary method of manufacturing a polymer matrix composite electromagnetic shielding structure. The exemplary method 100 comprises pretreating a dry fiber reinforcement with a composition including a carrier and an electromagnetically active element 102, laying out the pretreated reinforcement to form a preform stracture 104, applying a resin to the preform structure 106, and curing the resin at room temperature 108.

0016 The dry fiber reinforcement in exemplary embodiments is formed of a non- conductive material. For example, the dry fiber reinforcement can include a cloth, a unidirectional tape, a felt of non-conductive fibrous material, a mat of non- conductive fibrous material, or combinations thereof. Non-conductive fibrous material can include glass, quartz, polyaramids, polyolefins, and combinations thereof. In one exemplary embodiment, the dry fiber reinforcement is fiberglass.

0017 The composition can include a carrier and an electromagnetically active element. In an exemplary embodiment, the carrier includes a solvent and a tackifier.

Any suitable solvent and tackifier can be used where the solvent and tackifier are compatible and the tackifier is compatible with the resin to be used in the composite, e.g. the solvent solvates the tackifier and the tackifier is dissolved by the resin. For example, the solvent can be toluene or styrene and the tackifier can be paraffin for use with polyester or vinyl ester resins at room temperature. In an exemplary composition, the carrier is composed of one gram of paraffin for every 18.75 grams of toluene.

0018 The behavior of the electromagnetically active elements are used to tailor the polymer matrix composite materials to produce high performance, broadband electromagnetic (EM) shielding and/or attenuating materials or stractures. Several parameters can be adjusted to obtain the desired shielding effect, including length, diameter, conductivity (or electrical resistance) of the electromagnetically active element and volume percent (vol. %) of electromagnetically active element per unit volume of stracture. For example, a length and an electrical resistance of the electromagnetically active element within the nonwoven ply is chosen to maximize a shielding effect at a frequency or f equencies. In addition, the type of electromagnetically active element contributes to the shielding response. For example, a Debye-type electromagnetically active element effects the complex permittivity of the shielding stracture through relaxation mechanisms; a Lorentx- type electromagnetically active element effects the complex permittivity of the shielding structure through resonance mechanisms. In addition, different conductivities of electromagnetically active element have different frequency responses, with higher conductivities having a greater impact on Lorentizian parameters of complex permittivity and lower conductivities having a greater impact on Debye parameters of complex permittivity. One or both of these types of electromagnetically active elements can be utilized to obtain a desired. The choice of electromagnetically active elements is within the design choice to obtain shielding at a particular frequency of electromagnetic radiation. 0019 In an exemplary method of selecting the type of electromagnetically active element and the characteristics of the electromagnetically active element and loading of electromagnetically active elements in a polymer matrix composite electromagnetic shielding structure, a physical model and corresponding computer . software can be used to predict the electrical characteristics of the polymer matrix composite materials with electromagnetically active elements. Models for selecting the properties of the electromagnetically active element were based upon the work of H. Wade Swinford, "Electromagnetic Behavior of Radar Absorbing Chaff (RAC)", Naval Weapons Center Technical Note 354-43 (1975) and Arthur Gauss, Jr., "RACO, A New Type of Radar Absorbing Coating", Technical Report ARBRL-TR- 02357 (1981). These references provide a Debye model (relaxation oscillator) for the cylindrical, electric dipoles dispersed in air (chaff). 0020 These models can be extended by accounting for dipoles dispersed in dielectric media other than air, an improved depolarization factor for the small cylinders and for multiple dipole species in the same dielectric media or binder system. In addition, a Lorentzian model can account for the use of a damped oscillator or resonant dipole in the polymer matrix composite material. This resonant dipole model can be implemented in computer software using an equivalent circuit model similar to that described by Arthur Gauss, Jr. Using these models provides considerable flexibility to tailor attenuation levels and operational frequency bandwidths for the polymer matrix composite materials.

0021 The electromagnetically active element of the composition can include an electromagnetically active fiber, filament, particle or a mixture thereof. For example, the electromagnetically active fiber, filament, or particle can have a composition including a carbon, a metal-plated carbon fiber, a metal or a mixture thereof. Examples of suitable carbon includes polyacrylonitrile (PAN) carbon, pitch carbon, graphite or mixtures thereof. Examples of suitable metal-coated carbon fibers include carbon fibers with chemical vapor deposition (CVD) physical vapor deposition (PND), or electrochemically plated metals, such as nickel-coated carbon. In addition to nickel, examples of suitable metals include aluminum, copper, stainless steel, iron, titanium, alloys thereof or mixtures thereof. Suitable electromagnetically active elements are also disclosed in U.S. Patent No. 5,400,043, the entire contents of which are incorporated herein by reference.

0022 The electromagnetically active element contributes to the electromagnetic shielding properties of the polymer matrix composite stracture. In an exemplary embodiment of a Lorentz-type absorber, the electromagnetically active element can have a length approximately equal to one-half of a wavelength of a predetermined threat frequency or frequencies, such as a radio frequency (RF) or a miUimeterwave frequency (MMW). Other electromagnetically active elements, such as Debye-type absorbers, can be used in the polymer matrix composite structure. These electromagnetically active elements include broadband absorbers, such as the broadband absorbers disclosed in U.S. Patent No. 5,661,484, the entire contents of which are incorporated herein by reference, conductive fibers, such as the conductive fibers disclosed in U.S. Patent No. 5,400,043, the entire contents of which are incorporated herein by reference, and/or frequency selective surfaces, such as the slot type openings disclosed in U.S. Patent No. 5,400,403, the entire contents of which are herein incorporated by reference.

0023 In another exemplary embodiment, electromagnetically active elements, e.g, conductive filaments or electric dipoles, are dispersed throughout the volume of a low loss dielectric binder to form a composite material whose frequency dependent, complex permittivity can be readily varied by adjusting the filament content, dimensions, and intrinsic conductivity. Small, cylindrical, electromagnetically active elements represent efficient electric dipoles at radio frequencies/millimeterwave frequencies (RF MMW) so that a very small number of electromagnetically active elements per unit volume (< 0.1%) yield a significant change in the macroscopic electrical properties of the polymer matrix composite material. Note that the magnetic properties of the electromagnetically active elements are the same as free space, e.g., no magnetic loss. 0024 hi an exemplary embodiment, the electromagnetically active element is present in an amount sufficient to achieve a desired shielding or to alter an electromagnetic impedance of the composite structure. For example, the electromagnetically active element can be present at less than 1 vol. %, but higher amounts of the electromagnetically active element can be used. 0025 Pretreating the dry fiber reinforcement can be by any suitable method. For example, the composition including a carrier and an electromagnetically active element can be formed such that it can be applied by suitable techniques. Suitable techniques can include, for example, spraying, curtain coating, or filtering. The composition can be formed to flow sufficiently to be applied by the selected technique. For example, the composition can be formed to flow sufficiently by controlling the viscosity, i one embodiment using carbon fibers as the electromagnetically active element, a minimum viscosity is based on preventing clumping of the carbon. 0026 In an exemplary embodiment, the dry fiber reinforcement can be pretreated during unrolling of a spool of dry fiber reinforcement. The pretreated material can be wound onto a spool for storage or used directly. A suitable method of pretreating is disclosed in U.S. Patent No. 5,721,019, the entire contents of which are herein incorporated by reference. U.S. Patent No. 5,721,019 discloses spray application with a smooth and unrestricted fluid transfer system. Controlled spraying resulting in uniform application of the fiber containing composition, a single pass method for spray depositing, and an air nozzle spray gun are also disclosed. Multiply pretreating operations can also be used. 0027 hi an exemplary method, laying out the pretreated reinforcements to form a pre-form stracture can be by any suitable method. For example, the pretreated dry fiber reinforcement can be cut or otherwise fashioned into the appropriate preform stracture by automated techniques. Alternatively, the pretreated reinforcement can be hand assembled to form the pre-form structure. Laying out can include, lay-up operations, layering, or other suitable shaping operations.

0028 In an exemplary method of manufacture, applying a resin to the pre-form stracture can be by any suitable method. For example, applying the resin can include a vacuum resin infusion process. The vacuum resin infusion process can comprise placing the pre-form stracture in a vacuum bag, evacuating the bag, and introducing the resin by vacuum drawing the resin into the vacuum bag so as to infuse the resin throughout the pre-form stracture. The infused resin can solvate a tackifier securing the conductive element in the pre-form structure, e.g., the infused resin can include a solvent compatible with the tackifier, such as toluene or styrene with paraffin, to dissolve the tackifier. The solvated tackifier is then dispersed within the infused resin or can be flushed from the vacuum bag.

0029 Curing the resin can occur at a room temperature. As used herein, room temperature is from 40° F to 100° F, preferably from 60° F to 80° F, of both the structure being manufactured and the environmental conditions in which the stracture is being manufactured. In an exemplary method, curing the resin at room temperature occurs without the application of an external source of heat. For example, ovens, autoclaves, heat lamps, and/or other heat sources can be eliminated from at least the curing process, preferably from the, entire manufacturing process. The elimination of ovens, autoclaves, heat lamps, and/or other heat sources can significantly reduce the costs involved in the fabrication of composite parts.

Generally, in resin curing systems cured at elevated temperatures, e.g., temperatures greater than 100° F, the shape and size of parts are limited by the shape and size of any external source of heat.

0030 Examples of room temperature curing resin systems include at least one of a polyester-based resin, a vinyl ester-based resin, and an epoxy polyurethane-based resin. For example, a suitable polyester-based resin includes Polylite® 33234-18, available from Reichhold, Inc. of Durham NC; a suitable vinyl ester-based resin includes CORNE 8440, available from Interplastic Corp. of St. Paul, MΝ; and a suitable epoxy polyurethane-based resin includes, as an epoxy, Resinfusion 8605 available from Nantico of East Lansing, MI and, as a polyurethane, Smooth Cast

326, available from Smooth-On, Inc. of Easton, PA.

0031 Figure 2 shows an expanded view of an exemplary polymer matrix composite electromagnetic shielding structure in an exemplary manufacturing method. In the exemplary manufacturing method 200, a preform structure 202 is positioned for infusion of resin on a support, such as a tool plate 204. The pre-form structure 202 is placed on a release film 206, which allows for subsequent removal of the impregnated pre-form stracture 202 from the system, e.g., to facilitate the release of the pre-form structure 202 such that it does not adhere to the tool plate 204. A porous release film 208 is positioned over the pre-form structure 202 and serves a similar function with respect to the elements placed on that side of the preform structure 202, except that the porous release film allows resin to flow through the film. A distribution media 210 and a release film 212 are also suitably arranged about the preform stracture 202. The distribution media 210 and the release film 212 are any suitable materials conventionally used for such purposes. The arrangement of porous and non-porous release films can be made to accommodate the infusion of resin through the porous release structure where desired.

0032 An inner vacuum bag 214 and an outer vacuum bag 216 form, with the tool plate 204, an inner volume occupied by at least the preform structure 202. The inner vacuum bag 214 is secured over the pre-form stracture 202 (and any attendant items, such as release films and distribution media) and attached to the tool plate 204 with an inner bag sealant tape 218. The outer vacuum bag 216 is positioned over the inner vacuum bag 214 and attached to the tool plate 204 by an outer bag sealant tape 220. The release film 212 assists in preventing the inner vacuum bag 214 from adhering to other structures due to the resin.

0033 Connections to supply resin, vacuum, pressure or other media are used during the exemplary manufacturing method 200. For example, a resin inlet 222 and resin outlet 224 are positioned with an opening within the volume space occupied by the pre-form structure 202. Thus, the resin inlet 222 can port resin into the volume area including the pre-form stracture 202 and the resin outlet 224 can port resin out of that same volume area. For example, the resin can be forced under pressure through the resin inlet 222, can be drawn through the resin inlet 222 by a vacuum applied to the resin outlet 224, or combinations of these methods. A pressure vacuum outlet 226 has an opening located between the inner vacuum bag 214 and the outer vacuum bag 216. The pressure vacuum outlet 226 can port a fluid medium, such as air or a liquid, to apply pressure and/or a vacuum to the space between the imier vacuum bag 214 and the outer vacuum bag 216.

0034 Figure 3 schematically illustrates an exemplary method of manufacturing a polymer matrix composite electromagnetic shielding structure. The exemplary method 300 comprises laying out a plurality of dry fiber reinforcements 302, placing at least one ply between any two of the plurality of dry fiber reinforcements, the ply comprising a non- oven including a conductive material 304, applying a resin to a plurality of dry fiber reinforcements and the at least one ply 306, and curing the resin 308. 0035 Laying out a plurality of dry fiber reinforcements can be by any suitable method. For example, the dry fiber reinforcements can be layered, multilayered, stacked, placed in a shell mold, and so forth to provide the desired shape for the polymer matrix composite electromagnetic shielding stracture. 0036 In an exemplary embodiment, the dry fiber reinforcement is formed of a non-conductive material. The dry fiber reinforcement can include a cloth, a unidirectional tape, a felt of non-conductive fibrous material, a mat of non- conductive fibrous material, or combinations thereof. Further, the non-conductive fibrous material can include glass, quartz, polyaramids, polyolefins, and combinations thereof. In an exemplary embodiment, the dry fiber reinforcement is fiberglass.

0037 The at least one ply placed between any two of the plurality of dry fiber reinforcements can be of any suitable form. In an exemplary embodiment, the ply comprises a non-woven including a conductive material. For example, the non- woven can be a prefabricated fibrous veil. Suitable prefabricated fibrous veils are available from Hollingsworth and Vose, located in East Walpole, Massachusetts, and are commercially available as advanced fiber non-wovens.

0038 In an exemplary embodiment, the non- woven has a desired electromagnetic energy absorption property. For example, the non- woven can have an isotropic electromagnetic energy absorption property. The electromagnetic energy can be, for example, a desired threat frequency or frequencies, such as a radio frequency (RF) and/or a specific RF energy and/or a miUimeterwave frequency (MMW)and/or a specific MMW energy. Multiple non-wovens each having a desired electromagnetic energy absorption property and collectively having a plurality of desired electromagnetic energy absorption properties can also be used to provide absorption of a broadband energy, such as a range of RF energy, MMW energy, and so forth.

0039 In an exemplary embodiment, the non- woven can also include an electromagnetically active fiber, filament, particle, or combinations thereof to form a loaded non-woven. The electromagnetically active fiber, filament, or particle can have, for example, a composition including a carbon, a metal-plated carbon fiber, a metal, or a mixture thereof. Examples of suitable electromagnetically active fibers, filaments, or particles include PAN carbon, pitch carbon, nickel-coated carbon, or mixtures thereof. Examples of suitable fibers, filaments, particles, or combinations thereof, are disclosed in U.S. Patent No. 5,400,043, the entire contents of which are herein incorporated by reference.

0040 The electromagnetically active fiber, filament, or particle in exemplary embodiments can be present in an amount effective to altar an electromagnetic impedance of the polymer matrix composite structure to a desired frequency or frequencies, such as a radio frequency and/or a miUimeterwave frequency. In exemplary embodiments, the electromagnetically active fiber, filament, or particle is arranged randomly and distributed homogeneously, e.g., without any polarization dependence, within the polymer matrix composite structure to alter the electromagnetic impedance of the polymer matrix composite stracture to a desired frequency or frequencies.

0041 In an exemplary method, the plurality of dry fiber reinforcements and the at least one ply form a pre-form stracture. In the exemplary method, placing at least one ply includes interleaving a plurality of plies throughout a thickness of the pre- form stracture, e.g., the ply can be placed alternately with one or more dry fiber reinforcements in a stacked arrangement, portions of the pre-foπn stracture can have increased or decreased numbers of plies between dry fiber reinforcements, or any other suitable arrangement of plies within the dry fiber reinforcement. The number and interleaved position of the ply within the polymer matrix composite structure alters an electromagnetic impedance of the polymer matrix composite structure to a desired frequency or frequencies, such as a radio frequency and/or a miUimeterwave frequency. The number and position of the ply, e.g., orientation and interleaved position, can be selected based on the physical model and corresponding computer software described herein in connection with predicting the electrical characteristics of the polymer matrix composite materials with electromagnetically active elements. In an exemplary embodiment, the at least one ply is in the interior of the pre-form structure.

0042 In the exemplary method, applying a resin to the plurality of dry fiber reinforcements and the at least one ply can be by any suitable method. For example, applying the resin can include hand lay-up fabrication, vacuum bagging, resin transfer molding, vacuum assisted resin transfer molding, resin infusion processing, vacuum assisted resin infusion processing, vacuum injection packaging, Seeman Composites Resin Infusion Molding Process (SCRIMP), or combinations thereof. 0043 In the exemplary manufacturing method, curing the resin can occur by any suitable method. For example, curing the resin can occur without heat, e.g., without ovens, autoclaves, heat lamps, and/or other heat sources. A non-heat induced resin curing system can include a room temperature curing resin system at room temperature, such as the room temperature curing resin system disclosed and described herein in connection with Figures 1 and 2. Alternately, curing the resin can occur at elevated temperatures in an oven, in an autoclave, with a heat lamp, and/or other heat sources in which an external heat source is used to cure the resin. Resin systems suitable for use as a resin that cures at elevated temperatures can be selected based on the structural requirements of the application, such as high temperature or low temperature working environment, aerospace applications and so forth. An example of a suitable elevated temperature curing resin system includes epichlorohydrin (Sara HI) available from Shell Oil Company as EPON® Resin 828, although any suitable resin can be used, such as aerospace or marine resins. 0044 Figure 4 shows an expanded view of an exemplary polymer matrix composite electromagnetic shielding stracture. hi the exemplary structure 400, dry fiber reinforcement 402 is shown in a stacked arrangement. The at least one ply, here shown as ply 404, is interleaved between single dry fiber reinforcements on the interior of the structure. Upon completion of the manufacturing method, the exemplary embodiment of the polymer matrix composite electromagnetic shielding structure shown in FIG. 4 has a multi-layer cross-section of alternating dry fiber reinforcement and ply, e.g., the nonwoven including a conductive material. 0045 Figure 5 schematically illustrates another exemplary method of manufacturing a polymer matrix composite electromagnetic shielding structure. The exemplary method 500 comprises laying out a plurality of resin impregnated reinforcement 502, placing at least one ply between any two of the plurality of resin impregnated reinforcements, the ply having a non-woven including an electromagnetically active element 504, and curing the resin impregnated reinforcement 506. 0046 Laying out a plurality of resin impregnated reinforcement can be by any suitable method. For example, the resin impregnated reinforcement can be layered, multilayered, stacked, placed in a shell mold, and so forth to provide the desired shape for the polymer matrix composite electromagnetic shielding structure.

0047 In an exemplary embodiment, the resin impregnated reinforcement is formed of a non-conductive material having a resin incorporated therein. The resin impregnated reinforcement can include a cloth, a unidirectional tape, a felt of non- conductive fibrous material, a mat of non-conductive fibrous material, or combinations thereof having a resin incorporated by entanglement, adhesion, or other suitable method. Further, the non-conductive fibrous material can include glass, quartz, polyaramids, polyolefϊns, and combinations thereof. In an exemplary embodiment, the resin impregnated reinforcement is fiberglass.

0048 The at least one ply placed between any two of the plurality of resin impregnated reinforcement can be of any suitable form. In an exemplary embodiment, the ply comprises a non-woven including a conductive material. For example, the non-woven can be a prefabricated fibrous veil. Suitable prefabricated fibrous veils are available from Hollingsworth and Nose, located in East Walpole, Massachusetts, and are commercially available as advanced fiber non-wovens.

0049 In an exemplary embodiment, the non-woven has a desired electromagnetic energy absorption property. For example, the non-woven can have an isotropic electromagnetic energy absorption property. The electromagnetic energy can be, for example, a desired tlireat frequency or frequencies, such as a radio frequency (RF) and/or a specific RF energy and/or a miUimeterwave frequency (MMW)and/or a specific MMW energy. Multiple non-wovens each having a desired electromagnetic energy absorption property and collectively having a plurality of desired electromagnetic energy absorption properties can also be used to provide absorption of a broadband energy, such as a range of RF energy, MMW energy, and so forth.

0050 hi an exemplary embodiment, the non- woven can also include an electromagnetically active fiber, filament, particle, or combinations thereof to form a loaded non-woven. The electromagnetically active fiber, filament, or particle can have, for example, a composition including a carbon, a metal-plated carbon fiber, a metal, or a mixture thereof. Examples of suitable electromagnetically active fibers, filaments, or particles include PAN carbon, pitch carbon, nickel-coated carbon, or mixtures thereof. Examples of suitable fibers, filaments, particles, or combinations thereof, are disclosed in U.S. Patent No. 5,400,043, the entire contents of which are herein incorporated by reference.

0051 The electromagnetically active fiber, filament, or particle in exemplary embodiments can be present in an amount effective to altar an electromagnetic impedance of the polymer matrix composite structure to a desired frequency or frequencies, such as a radio frequency and/or a miUimeterwave frequency. In exemplary embodiments, the electromagnetically active fiber, filament, or particle is arranged randomly and distributed homogeneously, e.g., without any polarization dependence, within the polymer matrix composite structure to alter the electromagnetic impedance of the polymer matrix composite stracture to a desired frequency or frequencies.

0052 In an exemplary method, the plurality of resin impregnated reinforcement and the at least one ply form a pre-form structure, hi the exemplary method, placing at least one ply includes interleaving a plurality of plies throughout a thickness of the pre-foπri structure, e.g., the ply can be placed alternately with one or more resin impregnated reinforcement in a stacked arrangement, portions of the pre-foπn structure can have increased or decreased numbers of plies between resin impregnated reinforcement, or any other suitable arrangement of plies within the dry fiber reinforcement. The number and interleaved position of the ply within the polymer matrix composite structure alters an electromagnetic impedance of the polymer matrix composite structure to a desired frequency or frequencies, such as a radio frequency and/or a miUimeterwave frequency. The number and position of the ply, e.g., orientation and interleaved position, can be selected based on the physical model and corresponding computer software described herein in connection with predicting the electrical characteristics of the polymer matrix composite materials with electromagnetically active elements. In an exemplary embodiment, the at least one ply is in the interior of the pre-form stracture.

0053 In the exemplary method, applying a resin to the plurality of resin impregnated reinforcement and the at least one ply can be by any suitable method.

For example, applying the resin can include hand lay-up fabrication, vacuum bagging, resin transfer molding, vacuum assisted resin transfer molding, resin infusion processing, vacuum assisted resin infusion processing, vacuum injection packaging, Seeman Composites Resin Infusion Molding Process (SCRIMP), or combinations thereof.

0054 In the exemplary manufacturing method, curing the resin can occur by any suitable method. For example, curing the resin can occur without heat, e.g., without ovens, autoclaves, heat lamps, and/or other heat sources. A non-heat induced resin curing system can include a room temperature curing resin system at room temperature, such as the room temperature curing resin system disclosed and described herein in connection with Figures 1 and 2. An example of a suitable resin system includes a polyester or a vinyl ester resin system. Alternatively, curing the resin can occur at elevated temperatures in an oven, in an autoclave, with a heat lamp, and/or other heat sources in which an external heat source is used to cure the resin. Resin systems suitable for use as a resin that cures at elevated temperatures can be selected based on the stractural requirements of the application, such as high temperature or low temperature working environment, aerospace applications and so forth. An example of a suitable resin system includes epichlorohydrin (Sara ID) available from Shell Oil Company as EPON® Resin 828, although any suitable resin can be used, such as aerospace or marine resins.

0055 While the present invention has been described by reference to the above- mentioned embodiments, certain modifications and variations will be evident to those of ordinary skill in the art. Therefore, the present invention is to be limited only by the scope and spirit of the appended claims.

Claims

WHAT IS CLAIMED IS:

1. A method of manufacturing a polymer matrix composite electromagnetic shielding stracture, the method comprising: pretreating a dry fiber reinforcement with a composition including a carrier and an electromagnetically active element; laying out the pretreated reinforcement to form a pre-form stracture; applying a resin to the pre-form stracture; and curing the resin at room temperature.

2. The method of claim 1 , wherein pretreating includes at least one of spraying, curtain coating, and filtering in which the composition is dispersed onto the dry fiber reinforcement.

3. The method of claim 1 , wherein the dry fiber reinforcement is formed of a non-conductive material.

4. The method of claim 1 , wherein the dry fiber reinforcement includes at least one of a cloth, a unidirectional tape, a felt of nonconductive fibrous material, and a mat of nonconductive fibrous material.

5. The method of claim 4, wherein the nonconductive fibrous material includes at least one of glass, quartz, polyaramids, and polyolefins.

6. The method of claim 1 , wherein the carrier includes a solvent and a tackifier, the solvent compatible with the tackifier to solvate the tackifier.

7. The method of claim 6, wherein the solvent includes at least one of toluene and styrene and the tackifier includes paraffin.

8. The method of claim 7, wherein a composition of the carrier is 1 gram of paraffin per 18.75 grams of toluene or styrene.

9. The method of claim 6, comprising evaporating the solvent.

10. The method of claim 1 , wherein the electromagnetically active element includes at least one of a fiber, a filament, and a particle, at least one of the fiber, filament and particle including at least one of carbon, a metal-coated carbon fiber, and a metal.

11. The method of claim 10, wherein the metal includes at least one of aluminum, copper, stainless steel, iron, titanium, nickel, and alloys or mixtures thereof.

12. The method of claim 10, wherein a metal in the metal-coated carbon fiber includes at least one of aluminum, copper, stainless steel, iron, titanium, nickel, and alloys or mixtures thereof.

13. The method of claim 1 , wherein the electromagnetically active element has a length approximately equal to one-half of a wavelength of a predetermined threat frequency.

14. The method of claim 1 , wherein the electromagnetically active element is present in an amount effective to alter an electromagnetic impedance of the composite stracture.

15. The method of claim 1, wherein a length and an electrical resistance of the electromagnetically active element within the nonwoven ply is chosen to maximize a shielding effect at a frequency or frequencies.

16. The method of claim 1 , wherein applying a resin includes a vacuum resin infusion process, the vacuum resin infusion process comprising placing the pre-form stracture in a vacuum bag, evacuating the bag, and introducing the resin by vacuum drawing the resin into the vacuum bag to infuse the resin throughout the pre-form structure.

17. The method of claim 16, wherein the infused resin solvates a tackifier securing the electromagnetically active element in the pre-form structure.

18. The method of claim 17, wherein the solvated tackifier disperses within the infused resin or is flushed from the vacuum bag.

19. The method of claim 1 , wherein room temperature is from 40 ° F to

100° F.

20. The method of claim 19, wherein room temperature is from 60 to

80° F.

21. The method of claim 1 , wherein the resin inlcudes at least one of a polyester-based resin, a vinyl ester-based resin, and an epoxy polyurethane-based resin.

22. A method of manufacturing a polymer matrix composite electromagnetic shielding stracture, the method comprising: pretreating a dry fiber reinforcement with a composition including a carrier and an electromagnetically active element; laying out the pretreated reinforcement to form a pre-form structure; applying a resin to the pre-form stracture, the resin including at least one of a polyester-based resin, a vinyl ester-based resin, and an epoxy polyurethane-based resin; and curing the resin.

23. The method of claim 22, wherein curing the resin occurs at room temperature

24. The method of claim 23 , wherein room temperature is from 40 ° F to 100° F.

25. The method of claim 24, wherein room temperature is from 60 to 80° F.

26. A method of manufacturing a polymer matrix composite electromagnetic shielding structure, the method comprising: laying out a plurality of dry fiber reinforcements; placing at least one ply between any two of the plurality of dry fiber reinforcements, the ply having a non-woven including an electromagnetically active element; applying a resin to the plurality of dry fiber reinforcements and the at least one ply; and curing the resin.

27. The method of claim 26, wherein the dry fiber reinforcement is formed of a non-conductive material.

28. The method of claim 26, wherein the dry fiber reinforcement includes at least one of a cloth, a unidirectional tape, a felt of nonconductive fibrous material, and a mat of nonconductive fibrous material.

29. The method of claim 28, wherein the nonconductive fibrous material includes at least one of glass, quartz, polyaramids, and polyolefins.

30. The method of claim 26, wherein the non-woven is a prefabricated fibrous veil.

31. The method of claim 26, wherein the non- woven has an isotropic electromagnetic energy absorption property.

32. The method of claim 31 , where the electromagnetic energy is at least one of a radio frequency energy and a miUimeterwave energy.

33. The method of claim 26, wherein the non- woven includes at least one of an electromagnetically active fiber, filament, and particle.

34. The method of claim 33, wherein at least one of the electromagnetically active fiber, filament, and particle has a composition including at least one of PAN carbon, pitch carbon, metal-coated carbon, and a metal.

35. The method of claim 34, wherein a metal in the metal-coated carbon includes at least one of aluminum, copper, stainless steel, iron, titanium, nickel, and alloys or mixtures thereof.

36. The method of claim 34, wherein a metal includes at least one of aluminum, copper, stainless steel, iron, titanium, nickel, and alloys or mixtures thereof.

37. The method of claim 33, wherein at least one of the electromagnetically active fiber, filament, and particle is present in an amount effective to alter an electromagnetic impedance of the polymer matrix composite stracture to a desired frequency or frequencies.

38. The method of claim 37, wherein the desired frequency is at least one of a radio frequency and a miUimeterwave frequency.

39. The method of claim 33, wherein at least one of the electromagnetically active fiber, filament, and particle is arranged within the polymer matrix composite stracture to alter an electromagnetic impedance of the polymer matrix composite stracture at a desired frequency or frequencies.

40. The method of claim 39, wherein the desired frequency is at least one of a radio frequency and a miUimeterwave frequency.

41. The method of claim 26, wherein applying a resin includes at least one of hand lay-up fabrication, vacuum bagging, resin transfer molding, vacuum assisted resin transfer molding, resin infusion processing, vacuum assisted resin infusion processing, and vacuum injection packaging, SCRIMP.

42. The method of claim 26, wherein curing the resin occurs at room temperature.

43. The method of claim 42, wherein room temperature is from 40 ° F to 100° F.

44. The method of claim 43, wherein the resin including at least one of a polyester-based resin, a vinyl ester-based resin, and an epoxy polyurethane-based resin.

45. The method of claim 26, wherein the plurality of dry fiber reinforcements and the at least one ply form a pre-form stracture, and wherein placing at least one ply includes interleaving a plurality of plies throughout a thickness of the pre-form stracture.

46. The method of claim 45, wherein a number and an interleaved position of the ply within the polymer matrix composite structure alters an electromagnetic impedance of the polymer matrix composite stracture to a desired frequency or frequencies.

47. The method of claim 46, wherein the desired frequency is at least one of a radio frequency and a miUimeterwave frequency.

48. The method of claim 26, wherein the plurality of dry fiber reinforcements and the at least one ply form a pre-form stracture, and wherein the at least one ply is in an interior of the pre-form stracture.

49. The method of claim 26, wherein the resin is at least one of a polyester-based resin, a vinyl ester-based resin, an epoxy polyurethane-based resin and an epichlorohydrin resin.

50. A method of manufacturing a polymer matrix composite electromagnetic shielding structure, the method comprising: laying out a plurality of resin impregnated reinforcements; placing at least one ply between any two of the plurality of resin impregnated reinforcements, the ply having a non- woven including an electromagnetically active element; and curing the resin impregnated reinforcement.

51. The method of claim 50, wherein the resin impregnated reinforcements are formed of a non-conductive material.

52. The method of claim 50, wherein the resin impregnated reinforcements includes at least one of a cloth, a unidirectional tape, a felt of nonconductive fibrous material, and a mat of nonconductive fibrous material.

53. The method of claim 52, wherein the nonconductive fibrous material includes at least one of glass, quartz, polyaramids, and polyolefins.

54. The method of claim 50, wherein the non-woven is a prefabricated fibrous veil.

55. The method of claim 50, wherein the non-woven has an isotropic electromagnetic energy absorption property.

56. The method of claim 55, where the electromagnetic energy is at least one of a radio frequency energy and a miUimeterwave energy.

57. The method of claim 50, wherein the non- woven includes at least one of an electromagnetically active fiber, filament, and particle.

58. The method of claim 57, wherein at least one of the electromagnetically active fiber, filament, and particle has a composition including at least one of PAN carbon, pitch carbon, metal-coated carbon, and a metal.

59. The method of claim 58, wherein a metal in the metal-coated carbon includes at least one of aluminum, copper, stainless steel, iron, titanium, nickel, and alloys or mixtures thereof.

60. The method of claim 58, wherein a metal includes at least one of aluminum, copper, stainless steel, iron, titanium, nickel, and alloys or mixtures thereof.

61. The method of claim 57, wherein at least one of the electromagnetically active fiber, filament, and particle is present in an amount effective to alter an electromagnetic impedance of the polymer matrix composite structure to a desired frequency or frequencies.

62. The method of claim 61 , wherein the desired frequency is at least one of a radio frequency and a miUimeterwave frequency.

63. The method of claim 57, wherein at least one of the electromagnetically active fiber, filament, and particle is arranged within the polymer matrix composite structure to alter an electromagnetic impedance of the polymer matrix composite stracture at a desired frequency or frequencies.

64. The method of claim 63, wherein the desired frequency is at least one of a radio frequency and a miUimeterwave frequency.

65. The method of claim 50, wherein applying a resin includes at least one of hand lay-up fabrication, vacuum bagging, resin transfer molding, vacuum assisted resin transfer molding, resin infusion processing, vacuum assisted resin infusion processing, and vacuum injection packaging, SCRIMP.

66. The method of claim 50, wherein curing the resin occurs at room temperature.

67. The method of claim 50, wherein room temperature is from 40° F to 100° F.

68. The method of claim 67, wherein room temperature is from 60 to 80° F.

69. The method of claim 50, wherein the plurality of resin impregnated reinforcements and the at least one ply form a pre-form structure, and wherein placing at least one ply includes interleaving a plurality of plies throughout a thickness of the pre-form stracture.

70. The method of claim 69, wherein a number and an interleaved position of the ply within the polymer matrix composite structure alters an electromagnetic impedance of the polymer matrix composite stracture to a desired frequency or frequencies.

71. The method of claim 70, wherein the desired frequency is at least one of a radio frequency and a miUimeterwave frequency.

72. The method of claim 50, wherein the plurality of resin impregnated reinforcements and the at least one ply form a pre-form structure, and wherein the at least one ply is in an interior of the pre-form stracture.

73. The method of claim 50, wherein the resin is at least one of a polyester-based resin, a vinyl ester-based resin, an epoxy polyurethane-based resin, and an epichlorohydrin resin.

74. A method of manufacturing a polymer matrix composite electromagnetic shielding structure, the method comprising: pretreating a dry fiber reinforcement with a composition including a carrier and an electromagnetically active element; laying out the pretreated reinforcement to form a pre-form stracture; applying at least one of a polyester-based resin, a vinyl ester-based resin, an epoxy polyurethane-based resin, and an epichlorohydrin resin; and curing the resin.

75. The method of claim 74, wherein curing the resin occurs at room temperature

76. The method of claim 75, wherein room temperature is from 40° F to 100° F.

77. The method of claim 76, wherein room temperature is from 60 to

80° F.