WO2005016480A3 - Removing nitrogen oxides during a lean-burn engine cold start - Google Patents

Removing nitrogen oxides during a lean-burn engine cold start Download PDF

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Publication number
WO2005016480A3
WO2005016480A3 PCT/US2004/020404 US2004020404W WO2005016480A3 WO 2005016480 A3 WO2005016480 A3 WO 2005016480A3 US 2004020404 W US2004020404 W US 2004020404W WO 2005016480 A3 WO2005016480 A3 WO 2005016480A3
Authority
WO
WIPO (PCT)
Prior art keywords
lnt
coupled
close
nox
main
Prior art date
Application number
PCT/US2004/020404
Other languages
French (fr)
Other versions
WO2005016480A2 (en
Inventor
Wei Li
David R Monroe
Original Assignee
Gen Motors Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gen Motors Corp filed Critical Gen Motors Corp
Priority to DE112004001449.2T priority Critical patent/DE112004001449T5/en
Publication of WO2005016480A2 publication Critical patent/WO2005016480A2/en
Publication of WO2005016480A3 publication Critical patent/WO2005016480A3/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0828Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents characterised by the absorbed or adsorbed substances
    • F01N3/0842Nitrogen oxides
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • F01N13/0093Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series the purifying devices are of the same type
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0814Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with catalytic converters, e.g. NOx absorption/storage reduction catalysts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/22Control of additional air supply only, e.g. using by-passes or variable air pump drives
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2570/00Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
    • F01N2570/14Nitrogen oxides
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Abstract

An apparatus and method for removing NOx from an exhaust stream of a lean-­burn engine during an engine cold start is provided. The apparatus includes a close-­coupled LNT coupled to a main LNT by a hollow conduit. NOx from the cold exhaust is initially stored on the close-coupled LNT. As the engine exhaust warms up, the close-­coupled LNT reaches its operating temperature and reduces the stored NOx to N2. When the temperature of the close-coupled LNT reaches approximately 350 °C, NOx is released from the close-coupled LNT, is absorbed on the main LNT, and is converted to N2 during fuel-rich conditions. The close-coupled LNT can be regenerated after the engine is turned off by providing heat. The released NOx during the regeneration of the closed-coupled LNT is absorbed by the main LNT. The stored NOx on the main LNT can be reduced to N2 during the next vehicle operation.
PCT/US2004/020404 2003-08-07 2004-06-24 Removing nitrogen oxides during a lean-burn engine cold start WO2005016480A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE112004001449.2T DE112004001449T5 (en) 2003-08-07 2004-06-24 Elimination of nitrogen oxides during a cold start of a lean-burn engine

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/636,676 US6938412B2 (en) 2003-08-07 2003-08-07 Removing nitrogen oxides during a lean-burn engine cold start
US10/636,676 2003-08-07

Publications (2)

Publication Number Publication Date
WO2005016480A2 WO2005016480A2 (en) 2005-02-24
WO2005016480A3 true WO2005016480A3 (en) 2005-08-11

Family

ID=34116456

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2004/020404 WO2005016480A2 (en) 2003-08-07 2004-06-24 Removing nitrogen oxides during a lean-burn engine cold start

Country Status (5)

Country Link
US (1) US6938412B2 (en)
KR (1) KR100801675B1 (en)
CN (1) CN100529339C (en)
DE (1) DE112004001449T5 (en)
WO (1) WO2005016480A2 (en)

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US7673445B2 (en) * 2004-11-09 2010-03-09 Ford Global Technologies, Llc Mechanical apparatus having a catalytic NOx storage and conversion device
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US20060168949A1 (en) * 2005-02-02 2006-08-03 Lifeng Xu Alumina-based lean NOx trap system and method of use in dual-mode HCCI engines
US20060168948A1 (en) * 2005-02-02 2006-08-03 Lifeng Xu Alumina-based lean NOx trap system and method of use
US7644578B2 (en) * 2005-11-07 2010-01-12 Delphi Technologies, Inc. Vehicle exhaust aftertreatment system
US20080072575A1 (en) * 2006-09-21 2008-03-27 Eaton Corporation Catalyst to improve low temperature deNOx activity in a reformer-LNT exhaust aftertreatment system
JP4420048B2 (en) * 2007-03-20 2010-02-24 トヨタ自動車株式会社 Exhaust gas purification device for internal combustion engine
US7950226B2 (en) * 2007-05-14 2011-05-31 Eaton Corporation LNT-SCR system optimized for thermal gradient
US20090199547A1 (en) * 2008-02-08 2009-08-13 Gm Global Technology Operations, Inc. Method and apparatus for exhaust aftertreatment in a spark-ignition direct-injection internal combustion engine
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FR2959277A3 (en) * 2010-04-27 2011-10-28 Renault Sa Method for controlling e.g. oil engine of vehicle, involves allowing internal combustion heat engine to take two operating modes, where emission rate of nitrogen oxides is greater than and lower than predetermined thresholds, respectively
US8661797B2 (en) * 2010-11-15 2014-03-04 GM Global Technology Operations LLC NOx adsorber regeneration system and method
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US9003792B2 (en) * 2012-04-05 2015-04-14 GM Global Technology Operations LLC Exhaust aftertreatment and exhaust gas recirculation systems
US9574971B2 (en) * 2014-06-23 2017-02-21 GM Global Technology Operations LLC Monitoring cold start emission reduction strategy
DE102015206838A1 (en) 2015-04-16 2016-10-20 Ford Global Technologies, Llc Method for operating an exhaust aftertreatment device of a motor vehicle
DE102015219113A1 (en) * 2015-10-02 2017-04-06 Volkswagen Ag Method and device for exhaust aftertreatment of an internal combustion engine
DE102016222012B4 (en) 2015-12-18 2022-09-29 Ford Global Technologies, Llc Method for controlling a NOx storage catalyst
US10378404B2 (en) * 2016-04-27 2019-08-13 Ford Global Technologies, Llc Methods and systems for an engine after-treatment system
US20180058286A1 (en) * 2016-08-31 2018-03-01 GM Global Technology Operations LLC METHOD AND APPARATUS TO MINIMIZE DEACTIVATION OF A LOW TEMPERATURE NOx ADSORBER IN AN EXHAUST AFTERTREATMENT SYSTEM
BR112019008207A2 (en) * 2016-10-24 2019-07-09 Basf Corp exhaust gas treatment systems, method for treating an exhaust stream and catalytic article
JP6551426B2 (en) * 2017-01-13 2019-07-31 トヨタ自動車株式会社 Exhaust purification system for internal combustion engine
CN107261842B (en) * 2017-06-30 2020-04-21 浙江大学 Device for eliminating yellow smoke emitted from chimney at initial starting stage of combustion engine
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Also Published As

Publication number Publication date
DE112004001449T5 (en) 2014-04-17
CN1829856A (en) 2006-09-06
KR20060076273A (en) 2006-07-04
US6938412B2 (en) 2005-09-06
US20050028518A1 (en) 2005-02-10
KR100801675B1 (en) 2008-02-11
CN100529339C (en) 2009-08-19
WO2005016480A2 (en) 2005-02-24

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