WO2005058468A3 - Desulfurization and sorbents for same - Google Patents

Desulfurization and sorbents for same Download PDF

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Publication number
WO2005058468A3
WO2005058468A3 PCT/US2004/041617 US2004041617W WO2005058468A3 WO 2005058468 A3 WO2005058468 A3 WO 2005058468A3 US 2004041617 W US2004041617 W US 2004041617W WO 2005058468 A3 WO2005058468 A3 WO 2005058468A3
Authority
WO
WIPO (PCT)
Prior art keywords
sorbent
nickel
promoter
sorbents
desulfurization
Prior art date
Application number
PCT/US2004/041617
Other languages
French (fr)
Other versions
WO2005058468A2 (en
Inventor
Edward L Sughrue
Marvin M Johnson
Glenn W Dodwell
Larry E Reed
Joseph E Bares
Jason J Gislason
Robert W Morton
James L Malandra
Byron G Johnson
Original Assignee
Conocophillips Co
Edward L Sughrue
Marvin M Johnson
Glenn W Dodwell
Larry E Reed
Joseph E Bares
Jason J Gislason
Robert W Morton
James L Malandra
Byron G Johnson
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Conocophillips Co, Edward L Sughrue, Marvin M Johnson, Glenn W Dodwell, Larry E Reed, Joseph E Bares, Jason J Gislason, Robert W Morton, James L Malandra, Byron G Johnson filed Critical Conocophillips Co
Publication of WO2005058468A2 publication Critical patent/WO2005058468A2/en
Publication of WO2005058468A3 publication Critical patent/WO2005058468A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/024—Compounds of Zn, Cd, Hg
    • B01J20/0244—Compounds of Zn
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03

Abstract

Attrition resistant, sorbent compositions for the removal of elemental sulfur and sulfur compounds, such as hydrogen sulfide and organic sulfides, from cracked-gasoline and diesel fuels are prepared by the impregnation of a sorbent support comprising zinc oxide, expanded perlite, and alumina with a promoter such as nickel, nickel oxide or a precursor of nickel oxide followed by reduction of the valence of the promoter metal in the resulting promoter metal sorbent support composition.
PCT/US2004/041617 2003-12-17 2004-12-13 Desulfurization and sorbents for same WO2005058468A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/738,141 2003-12-17
US10/738,141 US20040140244A1 (en) 2000-05-30 2003-12-17 Desulfurization and sorbents for same

Publications (2)

Publication Number Publication Date
WO2005058468A2 WO2005058468A2 (en) 2005-06-30
WO2005058468A3 true WO2005058468A3 (en) 2005-10-06

Family

ID=34700464

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2004/041617 WO2005058468A2 (en) 2003-12-17 2004-12-13 Desulfurization and sorbents for same

Country Status (2)

Country Link
US (1) US20040140244A1 (en)
WO (1) WO2005058468A2 (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2005323528B2 (en) * 2005-01-06 2010-02-25 Research Triangle Institute Zinc oxide-based sorbents and processes for preparing and using same
US7597798B2 (en) * 2005-06-17 2009-10-06 Exxonmobil Research And Engineering Company Method for reducing the amount of high molecular weight organic sulfur picked-up by hydrocarbon streams transported through a pipeline
JP2007184847A (en) * 2006-01-10 2007-07-19 Nec Electronics Corp Clock and data recovery circuit and serdes circuit
US20070289900A1 (en) * 2006-06-14 2007-12-20 Alvarez Walter E Hydrogenation of polynuclear aromatic compounds
US7833316B2 (en) * 2007-05-01 2010-11-16 Auburn University Doped supported zinc oxide sorbents for regenerable desulfurization applications
US20080283446A1 (en) 2007-05-01 2008-11-20 Auburn University Silver-based sorbents
US7682424B2 (en) * 2008-01-31 2010-03-23 Conocophillips Company Contaminant removal from a gas stream
US7931739B2 (en) * 2008-04-08 2011-04-26 China Petroleum & Chemical Corporation Agglomerate removal system
US7776138B2 (en) * 2008-06-12 2010-08-17 Conocophillips Company Removal of contaminants from gas streams
US7951740B2 (en) * 2008-09-11 2011-05-31 China Petroleum & Chemical Corporation Method of inhibiting in situ silicate formation in desulfurization sorbents
WO2010061986A1 (en) * 2008-11-26 2010-06-03 Sk Energy Co., Ltd. Process for the preparation of clean fuel and aromatics from hydrocarbon mixtures catalytic cracked on fluid bed
US8268745B2 (en) * 2009-01-08 2012-09-18 China Petroleum & Chemical Corporation Silicate-resistant desulfurization sorbent
US20100314297A1 (en) * 2009-06-16 2010-12-16 Exxonmobil Research And Engineering Company Cyclic petroleum refining
AU2018312487B2 (en) 2017-08-01 2024-03-14 Research Triangle Institute Zinc oxide-based sorbents using alkali metal hydroxides and processes for preparing and using same

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6087544A (en) * 1998-05-07 2000-07-11 Exxon Research And Engineering Co. Process for the production of high lubricity low sulfur distillate fuels
US6150575A (en) * 1998-11-12 2000-11-21 Mobil Oil Corporation Diesel fuel
US6461497B1 (en) * 1998-09-01 2002-10-08 Atlantic Richfield Company Reformulated reduced pollution diesel fuel
US6610265B2 (en) * 2001-07-31 2003-08-26 Utc Fuel Cells, Llc Method and system for desulfurizing gasoline or diesel fuel for use in a fuel cell power plant

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE562617A (en) * 1956-11-27
US4221677A (en) * 1979-03-19 1980-09-09 Standard Oil Company (Indiana) Catalytic cracking with reduced emission of noxious gases
US4260471A (en) * 1979-07-05 1981-04-07 Union Oil Company Of California Process for desulfurizing coal and producing synthetic fuels
US4442221A (en) * 1982-04-09 1984-04-10 Chevron Research Company Process for regenerating a spent copper composite sulfur sorbent
US5157201A (en) * 1990-06-22 1992-10-20 Exxon Chemical Patents Inc. Process for adsorbing sulfur species from propylene/propane using regenerable adsorbent
US5897768A (en) * 1997-02-28 1999-04-27 Exxon Research And Engineering Co. Desulfurization process for removal of refractory organosulfur heterocycles from petroleum streams

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6087544A (en) * 1998-05-07 2000-07-11 Exxon Research And Engineering Co. Process for the production of high lubricity low sulfur distillate fuels
US6461497B1 (en) * 1998-09-01 2002-10-08 Atlantic Richfield Company Reformulated reduced pollution diesel fuel
US6150575A (en) * 1998-11-12 2000-11-21 Mobil Oil Corporation Diesel fuel
US6610265B2 (en) * 2001-07-31 2003-08-26 Utc Fuel Cells, Llc Method and system for desulfurizing gasoline or diesel fuel for use in a fuel cell power plant

Also Published As

Publication number Publication date
WO2005058468A2 (en) 2005-06-30
US20040140244A1 (en) 2004-07-22

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