WO2006036359A2 - Magnesium chloride support - Google Patents
Magnesium chloride support Download PDFInfo
- Publication number
- WO2006036359A2 WO2006036359A2 PCT/US2005/029350 US2005029350W WO2006036359A2 WO 2006036359 A2 WO2006036359 A2 WO 2006036359A2 US 2005029350 W US2005029350 W US 2005029350W WO 2006036359 A2 WO2006036359 A2 WO 2006036359A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- magnesium chloride
- support
- inorganic oxide
- transition metal
- catalyst
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/14—Methods for preparing oxides or hydroxides in general
- C01B13/145—After-treatment of oxides or hydroxides, e.g. pulverising, drying, decreasing the acidity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/021—After-treatment of oxides or hydroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
Definitions
- the invention relates to a support for olefin polymerizations and a method of making the support.
- U.S. Pat. No. 4,421 ,674 discloses a spray drying method and compares it with several other methods. They are able to prepare small particle size magnesium chloride by heating a concentrated solution of magnesium chloride in ethanol and spray drying the solution with a stream of hot nitrogen. Spray drying has advantages versus other techniques that can give low particle size such as milling. Unfortunately, milling yields irregular particles. When these particles are treated with titanium tetrachloride, the catalysts have lower activity than titanium tetrachloride supported on spray- dried magnesium chloride.
- the '674 patent also teaches to dissolve commercially available flake magnesium chloride with an average particle size of from 0.1 to 2 mm in anhydrous ethanol and heat to concentrate the solution.
- the magnesium chloride precipitates as elongated needles with an average size of 30 microns. This is treated with titanium tetrachloride, but again gives poorer results than those obtained by using spray-dried magnesium chloride. Spray drying requires extra equipment and it would be desirable to have a simpler process.
- U.S. Pat. No. 5,173,465 there are difficulties and complications inherent in the spray drying operation. They attempt to overcome these difficulties by impregnating porous silica having a mean particle size of between 10 and 100 microns.
- the silica is slurried in an ethanol solution of magnesium chloride to impregnate the porous silica and then the slurry is heated to remove the ethanol to a level of between 1.5 to 4 moles ethanol per mole magnesium chloride.
- the silica represents 50 - 90% by weight of the solid catalyst component with the remaining 50-10% containing titanium, magnesium, chlorine, and alkoxy groups. Even at 50%, this doubles the weight of solid that must be added to the polymerization.
- Magnesium chloride has been used for more than 20 years and the concept of seeding to influence crystallization has been known for more than 100 years. However, there remains a need to make magnesium chloride of uniform and small particle size without the complications of spray drying.
- the invention relates to supports comprising inorganic oxide nanoparticles coated with magnesium chloride and a method for making them.
- the nanoparticles are used as seeds to crystallize magnesium chloride from solution.
- the magnesium chloride-coated inorganic oxide nanoparticles are useful for supporting transition metal compounds.
- the supported transition metal compounds can be used to catalyze olefin polymerizations.
- the support of the invention comprises inorganic oxide nanoparticles coated with magnesium chloride.
- nanoparticles we mean particles having a mean particle diameter less than 5 microns.
- the inorganic oxide nanoparticles preferably have a mean particle diameter of less than 1 micron, a nd more preferably less than 0.1 micron.
- the size of the inorganic oxide is a more critical parameter than the exact choice of inorganic oxide.
- Suitable inorganic oxides include, for example, oxides of aluminum, silicon, antimony, cerium, copper, indium, iron, titanium, tin, yttrium, and zinc. Mixtures of inorganic oxides may be used.
- the inorganic oxide should be insoluble in the solvent used to crystallize the magnesium chloride. Suitable inorganic oxides are commercially available from a variety of companies.
- Magnesium chloride can initially be of any size or shape.
- the magnesium chloride has a water content less than 10% by weight, more preferably, less than 0.5%.
- One preferred method of coating the inorganic oxide with magnesium chloride is to slurry the inorganic oxide in a solution of magnesium chloride dissolved in ethanol and then crystallize the magnesium chloride by cooling or concentrating the solvent.
- the slurry is stirred during crystallization.
- Alcohols, especially ethanol, are preferred solvents.
- the solvent has a water content less than 5% by weight.
- the solid particles are separated from excess solvent by any of several techniques.
- One preferred technique is to filter and then vacuum-dry the solid.
- drying is not exhaustive and a small amount of the solvent remains with the solid.
- ethanol used as a solvent
- the drying is preferably done until from 1 - 6 moles of ethanol per mole magnesium chloride remain.
- the weight ratio of magnesium chloride to inorganic oxide nanoparticles is preferably from about 100:1 to about 100,000:1 , more preferably, from about 1,000:1 to about 10,000:1. If the weight ratio is too high, the particle size of the crystals can be variable and too large. If the weight ratio is too low, it can add to the cost unnecessarily.
- the inorganic oxide nanoparticles coated with magnesium chloride can be used as a support material for an olefin polymerization catalyst.
- the olefin polymerization catalyst is a metallocene, non-metallocene single-site, or Ziegler-Natta catalyst comprising a Group 4-10 transition metal compound.
- Metallocene catalysts include those containing substituted and unsubstituted cyclopentadienyl, fluorenyl, or indenyl ligands, or the like, such as those described in U.S. Pat. Nos. 4,791 ,180 and 4,752,597.
- Non-metallocene single-site catalysts include the so-called "constrained geometry" catalysts (see, e.g., U.S. Pat. No. 5,064,802) and catalysts containing one or more heteroatomic ring ligands such as boraaryl, pyrrolyl, indolyl, indenoindolyl, quinolinyl, pyridinyl, and azaborolinyl as described in U.S. Pat. Nos . 5,554,775, 5,539,124, 5,637,660, 5,902,866, and 6,232,260.
- the olefin polymerization catalyst is a Ziegler-Natta catalyst. They include titanium halides, titanium alkoxides, vanadium halides, and mixtures thereof, especially, TiCb, TiCI 4 , mixtures of VOCI3 with TiCU, and mixtures of VCI 4 with TiCI 4 .
- Other suitable Ziegler-Natta catalysts appear in U.S. Pat. No. 4,483,938 and in Eur. Pat. No. 222,504.
- the olefin polymerization catalyst is TiCI 4 .
- a Lewis base is also added to the supported transition metal compound.
- Preferred Lewis bases are C 3 -C 24 esters such as butyl acetate, diethyl phthalate, trimethyl trimellitate, and diethyl adipate and C 4 -Ci 6 ethers such as dibutyl ether, glyme, and diglyme. More preferred Lewis bases are C 9 - C 24 esters such as diethyl phthalate, dioctyl isophthalate, and 1 ,6-hexanediol bisbenzoate.
- the supported transition metal compounds are useful as olefin polymerization catalysts.
- the polymerization is conducted in the presence of the supported transition metal compound and an aluminum compound such as methylalumoxane, diethyl aluminum chloride, triethyl aluminum, and triisobutyl aluminum.
- the transition metal compound is a Ziegler-Natta catalyst and the alu minum compound is a dialkyl aluminum halide or a trialkyl aluminum compound.
- the olefin is an alpha-olefin. More preferably, the olefin is selected from the group consisting of ethylene, propylene, 1-butene, 1 -hexene, 1 -octene, and mixtures thereof. Most preferably, the olefin is ethylene or ethylene with a second olefin.
- Magnesium chloride powder (100 g; water content ⁇ 5%; available from
- the magnesium chloride coated on aluminum oxide is filtered and dried for 1 hour at 40°C under vacuum. The particles are expected to be uniform and to have a large surface area.
- Example 2 The magnesium chloride coated on inorganic oxide prepared in Example 1 (1 g) is placed in a glass tube and exposed to a stream of titanium tetrachloride in nitrogen for 2 hours to support the titanium tetrachloride.
- a 2-L stainless steel polymerization reactor is pressure purged with dry nitrogen three times at 70°C. After completely venting the reactor, hydrogen is added as a 1.7 MPa pressure drop from a 7-mL vessel.
- a solution of 1-hexene (100 mL) and triisobutyl aluminum (1 mmol) in isobutane (1 L) is added to the reactor followed by the supported titanium tetrachloride. Ethylene is added to give a total reactor pressure of 2.4 MPa.
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05803946A EP1802666A2 (en) | 2004-09-23 | 2005-08-16 | Magnesium chloride support |
JP2007532339A JP2008513570A (en) | 2004-09-23 | 2005-08-16 | Magnesium chloride carrier |
MX2007003163A MX2007003163A (en) | 2004-09-23 | 2005-08-16 | Magnesium chloride support. |
CA002581560A CA2581560A1 (en) | 2004-09-23 | 2005-08-16 | Magnesium chloride support |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/947,721 US7402546B2 (en) | 2004-09-23 | 2004-09-23 | Magnesium chloride support |
US10/947,721 | 2004-09-23 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2006036359A2 true WO2006036359A2 (en) | 2006-04-06 |
WO2006036359A3 WO2006036359A3 (en) | 2006-05-26 |
Family
ID=35840439
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2005/029350 WO2006036359A2 (en) | 2004-09-23 | 2005-08-16 | Magnesium chloride support |
Country Status (8)
Country | Link |
---|---|
US (1) | US7402546B2 (en) |
EP (1) | EP1802666A2 (en) |
JP (1) | JP2008513570A (en) |
KR (1) | KR20070067156A (en) |
CN (1) | CN101027329A (en) |
CA (1) | CA2581560A1 (en) |
MX (1) | MX2007003163A (en) |
WO (1) | WO2006036359A2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009025296A1 (en) | 2007-08-23 | 2009-02-26 | Sysmex Corporation | Method of detecting methylated cytosine |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BRPI0915034B1 (en) * | 2008-06-11 | 2019-06-18 | Lummus Novolen Technology Gmbh | HIGH-ACTIVITY ZIEGLER-NATTA CATALYSTS, PROCESS FOR PRODUCTION OF CATALYSTS AND USE OF THE SAME |
CN101554595B (en) * | 2009-05-18 | 2011-02-02 | 中国石油化工股份有限公司 | Catalyst support used for olefinic polymerization as well as preparation method and application thereof |
CN103073660B (en) * | 2011-10-26 | 2015-04-29 | 中国石油化工股份有限公司 | Magnesium halide carrier and application thereof, and olefin polymerization catalyst, olefin polymerization catalyst system, and olefin polymerization method |
CA2760264C (en) | 2011-12-05 | 2018-08-21 | Nova Chemicals Corporation | Passivated supports for use with olefin polymerization catalysts |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0654444A1 (en) * | 1992-05-08 | 1995-05-24 | Fina Research S.A. | Process for the production of magnesium chloride powder |
WO2004074329A1 (en) * | 2003-02-24 | 2004-09-02 | China Petroleum & Chemical Corporation | Complex support suitable for propylene polymerization catalyst, a catalyst component and catalyst containing the same |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3953574A (en) * | 1974-11-25 | 1976-04-27 | N L Industries, Inc. | Process for purifying molten magnesium chloride |
US4076602A (en) * | 1975-04-14 | 1978-02-28 | Wheeler Roger M | Method of producing magnesium metal and chlorine from MgCl2 containing brine |
JPS54112396A (en) * | 1978-02-22 | 1979-09-03 | Ube Ind Ltd | Production of high purity anhydrous magnesium chloride |
CA1171065A (en) * | 1981-01-06 | 1984-07-17 | Vaclav G. Zboril | Process for the preparation of polymers of alpha- olefins at high temperatures |
IT1136627B (en) * | 1981-05-21 | 1986-09-03 | Euteco Impianti Spa | SUPPORTED CATALYST FOR THE POLYMERIZATION OF ETHYLENE |
CA1257863A (en) | 1985-10-17 | 1989-07-25 | Vaclav G. Zboril | SOLUTION PROCESS FOR THE PREPARATION OF POLYMERS OF .alpha.-OLEFINS |
US4752597A (en) * | 1985-12-12 | 1988-06-21 | Exxon Chemical Patents Inc. | New polymerization catalyst |
US4791180A (en) * | 1985-12-12 | 1988-12-13 | Exxon Chemical Patents Inc. | New polymerization catalyst |
US5064802A (en) * | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
IT1248981B (en) * | 1990-06-22 | 1995-02-11 | Enichem Anic Spa | PROCEDURE FOR THE PREPARATION OF A SOLID CATALYST COMPONENT FOR THE (CO) POLYMERIZATION OF ETHYLENE |
TW400342B (en) * | 1994-09-06 | 2000-08-01 | Chisso Corp | A process for producing a solid catalyst component for olefin polymerization and a process for producing an olefin polymer |
US5539124A (en) * | 1994-12-19 | 1996-07-23 | Occidental Chemical Corporation | Polymerization catalysts based on transition metal complexes with ligands containing pyrrolyl ring |
US5554775A (en) * | 1995-01-17 | 1996-09-10 | Occidental Chemical Corporation | Borabenzene based olefin polymerization catalysts |
US5637660A (en) * | 1995-04-17 | 1997-06-10 | Lyondell Petrochemical Company | Polymerization of α-olefins with transition metal catalysts based on bidentate ligands containing pyridine or quinoline moiety |
KR19990008050A (en) * | 1995-04-25 | 1999-01-25 | 폰티노트제이.릭 | Azaborolinyl Metal Complexes as Olefin Polymerization Catalyst |
US6232260B1 (en) * | 1999-10-14 | 2001-05-15 | Equistar Chemicals, L.P. | Single-site catalysts for olefin polymerization |
US7071137B2 (en) * | 2004-08-25 | 2006-07-04 | Novolen Technology Holdings, C.V. | Method of making a ziegler-natta catalyst |
-
2004
- 2004-09-23 US US10/947,721 patent/US7402546B2/en not_active Expired - Fee Related
-
2005
- 2005-08-16 WO PCT/US2005/029350 patent/WO2006036359A2/en active Application Filing
- 2005-08-16 KR KR1020077009018A patent/KR20070067156A/en not_active Application Discontinuation
- 2005-08-16 CN CNA2005800321497A patent/CN101027329A/en active Pending
- 2005-08-16 CA CA002581560A patent/CA2581560A1/en not_active Abandoned
- 2005-08-16 EP EP05803946A patent/EP1802666A2/en not_active Withdrawn
- 2005-08-16 JP JP2007532339A patent/JP2008513570A/en not_active Withdrawn
- 2005-08-16 MX MX2007003163A patent/MX2007003163A/en unknown
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0654444A1 (en) * | 1992-05-08 | 1995-05-24 | Fina Research S.A. | Process for the production of magnesium chloride powder |
WO2004074329A1 (en) * | 2003-02-24 | 2004-09-02 | China Petroleum & Chemical Corporation | Complex support suitable for propylene polymerization catalyst, a catalyst component and catalyst containing the same |
Non-Patent Citations (1)
Title |
---|
MISHAKOV, BEDILO, RICHARDS, CHESNOKOV, VOLODIN,ZAIKOVSKII,BUYANOV,KLABUNDE: "Nanocrystalline MgO as Dehydrohalogenation Catalyst" JOURNAL OF CATALYSIS, vol. 206, 11 March 2002 (2002-03-11), - 11 March 2003 (2003-03-11) pages 40-48, XP002369880 USA * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009025296A1 (en) | 2007-08-23 | 2009-02-26 | Sysmex Corporation | Method of detecting methylated cytosine |
Also Published As
Publication number | Publication date |
---|---|
CN101027329A (en) | 2007-08-29 |
JP2008513570A (en) | 2008-05-01 |
MX2007003163A (en) | 2007-05-16 |
US20060063664A1 (en) | 2006-03-23 |
CA2581560A1 (en) | 2006-04-06 |
WO2006036359A3 (en) | 2006-05-26 |
US7402546B2 (en) | 2008-07-22 |
EP1802666A2 (en) | 2007-07-04 |
KR20070067156A (en) | 2007-06-27 |
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