WO2006036748A3 - Heterocycle-amine ligands, compositions, complexes, and catalysts, and methods of making and using the same - Google Patents

Heterocycle-amine ligands, compositions, complexes, and catalysts, and methods of making and using the same Download PDF

Info

Publication number
WO2006036748A3
WO2006036748A3 PCT/US2005/034009 US2005034009W WO2006036748A3 WO 2006036748 A3 WO2006036748 A3 WO 2006036748A3 US 2005034009 W US2005034009 W US 2005034009W WO 2006036748 A3 WO2006036748 A3 WO 2006036748A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalysts
heterocycle
compositions
complexes
making
Prior art date
Application number
PCT/US2005/034009
Other languages
French (fr)
Other versions
WO2006036748A2 (en
Inventor
Gary Diamond
Anne M Lapointe
Margarete K Leclerc
James Longmire
Victor Nava-Salgado
James A W Shoemaker
Pu Sun
Original Assignee
Symyx Technologies Inc
Gary Diamond
Anne M Lapointe
Margarete K Leclerc
James Longmire
Victor Nava-Salgado
James A W Shoemaker
Pu Sun
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Symyx Technologies Inc, Gary Diamond, Anne M Lapointe, Margarete K Leclerc, James Longmire, Victor Nava-Salgado, James A W Shoemaker, Pu Sun filed Critical Symyx Technologies Inc
Priority to EP05800266A priority Critical patent/EP1794196A2/en
Publication of WO2006036748A2 publication Critical patent/WO2006036748A2/en
Publication of WO2006036748A3 publication Critical patent/WO2006036748A3/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/003Compounds containing elements of Groups 4 or 14 of the Periodic System without C-Metal linkages
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/28Titanium compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

Abstract

Ligands, compositions, and metal-ligand complexes that incorporate heterocycle-­amine compounds are disclosed that are useful in the catalysis of transformations such as the polymerization of monomers into polymers. The catalysts have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts also polymerize propylene to form isotactic polypropylene.
PCT/US2005/034009 2004-09-22 2005-09-21 Heterocycle-amine ligands, compositions, complexes, and catalysts, and methods of making and using the same WO2006036748A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP05800266A EP1794196A2 (en) 2004-09-22 2005-09-21 Heterocycle-amine ligands, compositions, complexes, and catalysts, and methods of making and using the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US61194304P 2004-09-22 2004-09-22
US60/611,943 2004-09-22

Publications (2)

Publication Number Publication Date
WO2006036748A2 WO2006036748A2 (en) 2006-04-06
WO2006036748A3 true WO2006036748A3 (en) 2006-07-27

Family

ID=35539370

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2005/034009 WO2006036748A2 (en) 2004-09-22 2005-09-21 Heterocycle-amine ligands, compositions, complexes, and catalysts, and methods of making and using the same

Country Status (3)

Country Link
US (3) US7387980B2 (en)
EP (1) EP1794196A2 (en)
WO (1) WO2006036748A2 (en)

Families Citing this family (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006066126A2 (en) * 2004-12-16 2006-06-22 Symyx Technologies, Inc. Phenol-heterocyclic ligands, metal complexes, and their uses as catalysts
WO2006096881A1 (en) * 2005-03-09 2006-09-14 Exxonmobil Chemical Patents Inc. Methods for oligomerizing olefins
US7414006B2 (en) * 2005-03-09 2008-08-19 Exxonmobil Chemical Patents Inc. Methods for oligomerizing olefins
WO2007026831A1 (en) * 2005-08-31 2007-03-08 Inter-University Research Institute Corporation National Institutes Of Natural Sciences Zirconium-borane complex and method for producing siloxanes using such complex
US8076524B2 (en) * 2006-02-03 2011-12-13 Exxonmobil Chemical Patents Inc. Process for generating alpha olefin comonomers
US8003839B2 (en) * 2006-02-03 2011-08-23 Exxonmobil Chemical Patents Inc. Process for generating linear apha olefin comonomers
US7982085B2 (en) * 2006-02-03 2011-07-19 Exxonmobil Chemical Patents Inc. In-line process for generating comonomer
US20090306318A1 (en) * 2006-05-05 2009-12-10 Boone Harold W Ortho-metallated hafnium complexes of imidazole ligands
ES2560247T3 (en) * 2006-05-05 2016-02-18 Dow Global Technologies Llc Hafnium complexes of heterocyclic organic ligands
WO2007130305A2 (en) * 2006-05-05 2007-11-15 Dow Global Technologies Inc. Hafnium complexes of carbazolyl substituted imidazole ligands
KR20090009946A (en) * 2006-05-05 2009-01-23 다우 글로벌 테크놀로지스 인크. Improved hafnium complexes of heterocyclic organic ligands
US8404915B2 (en) * 2006-08-30 2013-03-26 Exxonmobil Chemical Patents Inc. Phosphine ligand-metal compositions, complexes, and catalysts for ethylene trimerizations
EP2114974A1 (en) * 2007-01-08 2009-11-11 ExxonMobil Chemical Patents Inc. Methods for oligomerizing olefins with chromium pyridine ether catalysts
EP2121183A1 (en) * 2007-01-08 2009-11-25 ExxonMobil Chemical Patents Inc. Chromium complexes of pyridine bis (oxazoline)-ligands for ethylene dimerization
WO2008085658A1 (en) * 2007-01-08 2008-07-17 Exxonmobil Chemical Patents Inc. Methods for oligomerizing olefins with chromium pyridine thioether catalysts
US8138348B2 (en) * 2007-01-08 2012-03-20 Exxonmobil Chemical Patents Inc. Methods for oligomerizing olefins with chromium pyridine mono-oxazoline catalysts
CN101711258B (en) 2007-03-07 2012-07-04 陶氏环球技术有限责任公司 Tethered supported transition metal complex
US8431660B2 (en) * 2007-12-05 2013-04-30 Lg Chem, Ltd. Non-metallocene catalysts having tetrazol group for olefin polymerization and polymerizing method of olefin using the same
WO2010102163A2 (en) * 2009-03-06 2010-09-10 Dow Global Technologies Inc. Catalysts, processes for making catalysts, processes for making polyolefin compositions and polyolefin compositions
EP2430053A1 (en) 2009-05-14 2012-03-21 Univation Technologies, LLC Mixed metal catalyst systems having a tailored hydrogen response
US8389660B1 (en) 2009-06-10 2013-03-05 The Florida State University Research Foundation Polyolefins having reduced crystallinity
US8907031B2 (en) 2011-04-20 2014-12-09 Chevron Phillips Chemical Company Lp Imino carbene compounds and derivatives, and catalyst compositions made therefrom
WO2013036546A2 (en) 2011-09-07 2013-03-14 Dow Corning Corporation Titanium containing complex and condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
US9228061B2 (en) 2011-09-07 2016-01-05 Dow Corning Corporation Zirconium containing complex and condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
US9139699B2 (en) 2012-10-04 2015-09-22 Dow Corning Corporation Metal containing condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
TWI485145B (en) 2012-10-26 2015-05-21 Ind Tech Res Inst P-type organic semiconductor material and optoelectronic device utilizing the same
US9260552B2 (en) 2013-11-15 2016-02-16 Exxonmobil Chemical Patents Inc. Process to produce polymers from pyridyldiamido transition metal complexes and use thereof
US9290519B2 (en) 2013-11-15 2016-03-22 Exxonmobil Chemical Patents Inc. Pyridyldiamido transition metal complexes, production and use thereof
US9315593B2 (en) 2013-11-15 2016-04-19 Exxonmobil Chemical Patents Inc. Catalyst systems comprising pyridyldiamido transition metal complexes and chain transfer agent and use thereof
KR101725949B1 (en) 2014-01-08 2017-04-11 주식회사 엘지화학 The post metallocene catalyst based on thiophene
KR101703155B1 (en) 2014-02-18 2017-02-06 주식회사 엘지화학 The post metallocene catalyst having diaryl ether backbone
CN105503763B (en) * 2014-10-17 2020-11-03 上海中科康润新材料科技有限公司 Polyolefin oil catalyst and application thereof
CA2978823C (en) 2014-12-29 2023-10-10 The United States Of America, As Represented By The Secretary, Department Of Health And Human Services Small molecule inhibitors of lactate dehydrogenase and methods of use thereof
US10618988B2 (en) 2015-08-31 2020-04-14 Exxonmobil Chemical Patents Inc. Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof
US10676547B2 (en) 2015-08-31 2020-06-09 Exxonmobil Chemical Patents Inc. Aluminum alkyls with pendant olefins on clays
WO2017039995A1 (en) 2015-08-31 2017-03-09 Exxonmobil Chemical Patents Inc. Aluminum alkyls with pendant olefins for polyolefin reactions
US9982067B2 (en) 2015-09-24 2018-05-29 Exxonmobil Chemical Patents Inc. Polymerization process using pyridyldiamido compounds supported on organoaluminum treated layered silicate supports
US10414887B2 (en) 2015-10-02 2019-09-17 Exxonmobil Chemical Patents Inc. Supported catalyst systems and methods of using same
US9982076B2 (en) 2015-10-02 2018-05-29 Exxonmobil Chemical Patents Inc. Supported bis phenolate transition metals complexes, production and use thereof
US10000593B2 (en) 2015-10-02 2018-06-19 Exxonmobil Chemical Patents Inc. Supported Salan catalysts
US9994657B2 (en) 2015-10-02 2018-06-12 Exxonmobil Chemical Patents Inc. Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports
US9994658B2 (en) 2015-10-02 2018-06-12 Exxonmobil Chemical Patents Inc. Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports
US9975973B2 (en) 2015-10-02 2018-05-22 Exxonmobil Chemical Patents Inc. Asymmetric fluorenyl-substituted salan catalysts
US10562987B2 (en) 2016-06-30 2020-02-18 Exxonmobil Chemical Patents Inc. Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents
US10626200B2 (en) 2017-02-28 2020-04-21 Exxonmobil Chemical Patents Inc. Branched EPDM polymers produced via use of vinyl transfer agents and processes for production thereof
WO2018160278A1 (en) 2017-03-01 2018-09-07 Exxonmobil Chemical Patents Inc. Branched ethylene copolymers produced via use of vinyl transfer agents and processes for production thereof
EP3762475A1 (en) 2018-03-08 2021-01-13 ExxonMobil Chemical Patents Inc. Ethylene-propylene branched copolymers as viscosity modifiers with enhanced fuel economy
CN112513110B (en) 2018-03-08 2023-10-27 埃克森美孚化学专利公司 Ethylene-propylene linear copolymers as viscosity modifiers
WO2020028240A1 (en) * 2018-07-31 2020-02-06 Dow Global Technologies Llc Bidentate azolylamido metal-ligand complexes and olefin polymerization catalysts
US20220289882A1 (en) 2019-08-27 2022-09-15 Chevron Oronite Company Llc Ethylene copolymers and use as viscosity modifiers
CN113667042B (en) * 2021-08-28 2022-02-11 潍坊驼王实业有限公司 Preparation method of melt-blown non-woven fabric

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999001460A1 (en) * 1997-07-02 1999-01-14 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
US20030232717A1 (en) * 2002-04-12 2003-12-18 Symyx Technologies, Inc. Ethylene-styrene copolymers and phenol-triazole type complexes, catalysts, and processes for polymerizing

Family Cites Families (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4297465A (en) 1980-10-29 1981-10-27 Eastman Kodak Company Catalysts for polymerizing propylene in a high temperature solution process
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5384299A (en) 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
ZA882999B (en) 1987-05-04 1988-11-01 Shell Oil Company Preparation of olefin polymerization catalyst component
US5093415A (en) 1987-05-19 1992-03-03 Union Carbide Chemicals & Plastics Technology Corporation Process for producing stereoregular polymers having a narrow molecular weight distribution
JPH01122339A (en) * 1987-11-05 1989-05-15 Mitsubishi Electric Corp Commutator for starting motor
US4971936A (en) 1989-07-10 1990-11-20 Shell Oil Company Catalyst component for making primarily isotactic elastomeric polypropylene or polybutene
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
ES2085000T3 (en) 1990-12-27 1996-05-16 Exxon Chemical Patents Inc A TRANSITIONAL AMIDO-METAL COMPOUND AND A CATALYTIC SYSTEM FOR THE PRODUCTION OF ISOTACTIC POLYPROPYLENE.
JPH04272907A (en) 1991-02-27 1992-09-29 Mitsubishi Petrochem Co Ltd Production of olefin polymer
KR100262023B1 (en) 1992-01-06 2000-07-15 그레이스 스티븐 에스. Improved catalyst composition
CA2121721C (en) 1993-04-29 2004-11-23 Giampiero Morini Crystalline propylene polymers having high melt flow rate values and a narrow molecular weight distribution
TW354792B (en) 1993-08-13 1999-03-21 Mitsui Petrochemical Ind Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer
US5527929A (en) 1994-08-02 1996-06-18 The Dow Chemical Company Zwitterionic biscyclopentadienyl complexes
US6030917A (en) 1996-07-23 2000-02-29 Symyx Technologies, Inc. Combinatorial synthesis and analysis of organometallic compounds and catalysts
US5985356A (en) 1994-10-18 1999-11-16 The Regents Of The University Of California Combinatorial synthesis of novel materials
JPH11514012A (en) 1996-07-23 1999-11-30 サイミックス・テクノロジーズ Combinatorial synthesis and analysis of organometallic compounds and catalysts
US6720186B1 (en) 1998-04-03 2004-04-13 Symyx Technologies, Inc. Method of research for creating and testing novel catalysts, reactions and polymers
IL122115A (en) 1997-07-27 2007-06-17 Technion Res & Dev Foundation Process for polymerizing alpha-olefins and polymers, copolymers and elastomers prepared thereby
EP1000069B1 (en) 1997-08-01 2003-03-12 Dow Global Technologies Inc. Catalyst activator
EP0938509B1 (en) 1997-09-03 2002-11-20 Basell Poliolefine Italia S.p.A. Components and catalysts for the polymerization of olefins
JP4722287B2 (en) 1998-02-20 2011-07-13 ダウ グローバル テクノロジーズ インコーポレーテッド Catalyst activators containing expanded anions
US6034240A (en) 1998-03-09 2000-03-07 Symyx Technologies, Inc. Substituted aminomethylphosphines, coordination complexes of aminomethylphosphines and their synthesis
US6406632B1 (en) 1998-04-03 2002-06-18 Symyx Technologies, Inc. Rapid characterization of polymers
US6175409B1 (en) 1999-04-02 2001-01-16 Symyx Technologies, Inc. Flow-injection analysis and variable-flow light-scattering methods and apparatus for characterizing polymers
US6294388B1 (en) 1998-04-03 2001-09-25 Symyx Technologies, Inc. Indirect calibration of polymer characterization systems
US6260407B1 (en) 1998-04-03 2001-07-17 Symyx Technologies, Inc. High-temperature characterization of polymers
US6455316B1 (en) 1998-08-13 2002-09-24 Symyx Technologies, Inc. Parallel reactor with internal sensing and method of using same
US6306658B1 (en) 1998-08-13 2001-10-23 Symyx Technologies Parallel reactor with internal sensing
US6548026B1 (en) 1998-08-13 2003-04-15 Symyx Technologies, Inc. Parallel reactor with internal sensing and method of using same
US6436292B1 (en) 1999-04-02 2002-08-20 Symyx Technologies, Inc. Parallel high-performance liquid chromatography with post-separation treatment
US6296771B1 (en) 1999-04-02 2001-10-02 Symyx Technologies, Inc. Parallel high-performance liquid chromatography with serial injection
US7078164B1 (en) 2000-06-19 2006-07-18 Symyx Technologies, Inc. High throughput screen for identifying polymerization catalysts from potential catalysts
WO2002046249A2 (en) 2000-11-07 2002-06-13 Symyx Technologies, Inc. Methods of copolymerizing ethylene and isobutylene and polymers made thereby
WO2002085820A2 (en) 2001-04-20 2002-10-31 Indiana University Chiral organic compounds and metal coordination complexes thereof
SG147306A1 (en) 2001-11-06 2008-11-28 Dow Global Technologies Inc Isotactic propylene copolymers, their preparation and use
US7256296B2 (en) * 2004-09-22 2007-08-14 Symyx Technologies, Inc. Heterocycle-amine ligands, compositions, complexes, and catalysts

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999001460A1 (en) * 1997-07-02 1999-01-14 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
US20030232717A1 (en) * 2002-04-12 2003-12-18 Symyx Technologies, Inc. Ethylene-styrene copolymers and phenol-triazole type complexes, catalysts, and processes for polymerizing

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
HUANG, JI-LING ET AL HUANG, JI-LING ET AL: "Syntheses of some new group 4 non-cp complexes bearing Schiff-base, thiophene diamide ligands respectively, and their catalytic activities for .alpha.-olefin polymerization", CHINESE JOURNAL OF CHEMISTRY, 22(6), 577-584, 2004, XP008058752 *

Also Published As

Publication number Publication date
US20090131619A1 (en) 2009-05-21
US7387980B2 (en) 2008-06-17
US20090143222A1 (en) 2009-06-04
US7642216B2 (en) 2010-01-05
WO2006036748A2 (en) 2006-04-06
US20060094839A1 (en) 2006-05-04
EP1794196A2 (en) 2007-06-13
US7642324B2 (en) 2010-01-05

Similar Documents

Publication Publication Date Title
WO2006036748A3 (en) Heterocycle-amine ligands, compositions, complexes, and catalysts, and methods of making and using the same
WO2006066126A3 (en) Phenol-heterocyclic ligands, metal complexes, and their uses as catalysts
AU2003225156A1 (en) Bridged bi-aromatic ligands, complexes, catalysts and processes for polymerizing and poymers therefrom
WO2002038628A3 (en) Substituted pyridyl amine ligands, complexes and catalysts therefrom; processes for producing polyolefins therewith
WO2007037944A3 (en) High activity, low molecular weight olefin polymerization process
MX2007011340A (en) Catalyst composition comprising shuttling agent for regio-irregular multi-block copolymer formation.
JP5763312B2 (en) Method for producing polar group-containing allyl monomer copolymer
SG158923A1 (en) Catalyst composition comprising shuttling agent for tactic/ atactic multi- block copolymer formation
SG151302A1 (en) Catalyst composition comprising shuttling agent for higher olefin multi- block copolymer formation
ZA200607170B (en) Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
SG156614A1 (en) Catalytic olefin block copolymers via polymerizable shuttling agent
WO2001092342A3 (en) Catalysts for olefin polymerization
SG151301A1 (en) Catalyst composition comprising shuttling agent for ethylene multi- block copolymer formation
WO2005058916A3 (en) Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and preparation of polyolefins
JP2005503417A5 (en)
SG151310A1 (en) Catalyst composition comprising shuttling agent for ethylene copolymer formation
MX2008002573A (en) Polymerization catalysts and process for producing bimodal polymers in a single reactor.
EP1803742A4 (en) Process for producing propylene polymer
WO2011129593A3 (en) Method for preparing polypropylene using a transition metal compound containing thiophene-fused cyclopentadienyl ligands
WO2009045300A3 (en) Polymerization catalysts for producing polymers with high comonomer incorporation
SG158131A1 (en) Solid catalyst component and catalyst for olefin polymerization, and process for producing olefin polymer or copolymer
MXPA03006297A (en) Copolymers of olefins and vinyl- and allylsilanes.
WO2007076231A3 (en) Bridged phenol-heterocyclic ligands, metal complexes, and their uses as catalysts
WO2009072833A3 (en) Non-metallocene catalysts having tetrazol group for olefin polymerization and polymerizing method of olefin using the same
TW200615288A (en) ANSA-metallocene compound, process of preparing the same, and process of preparing polyolefin using the same

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KM KP KR KZ LC LK LR LS LT LU LV LY MA MD MG MK MN MW MX MZ NA NG NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SM SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GM KE LS MW MZ NA SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LT LU LV MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2005800266

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 2005800266

Country of ref document: EP