WO2006066126A3 - Phenol-heterocyclic ligands, metal complexes, and their uses as catalysts - Google Patents

Phenol-heterocyclic ligands, metal complexes, and their uses as catalysts Download PDF

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Publication number
WO2006066126A3
WO2006066126A3 PCT/US2005/045766 US2005045766W WO2006066126A3 WO 2006066126 A3 WO2006066126 A3 WO 2006066126A3 US 2005045766 W US2005045766 W US 2005045766W WO 2006066126 A3 WO2006066126 A3 WO 2006066126A3
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WO
WIPO (PCT)
Prior art keywords
catalysts
phenol
metal complexes
heterocyclic ligands
styrene
Prior art date
Application number
PCT/US2005/045766
Other languages
French (fr)
Other versions
WO2006066126A2 (en
Inventor
Margarete K Leclerc
Xiahong Bei
James Longmire
Gary M Diamond
James A W Shoemaker
Anne M Lapointe
Lily Ackerman
Original Assignee
Symyx Technologies Inc
Margarete K Leclerc
Xiahong Bei
James Longmire
Gary M Diamond
James A W Shoemaker
Anne M Lapointe
Lily Ackerman
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Symyx Technologies Inc, Margarete K Leclerc, Xiahong Bei, James Longmire, Gary M Diamond, James A W Shoemaker, Anne M Lapointe, Lily Ackerman filed Critical Symyx Technologies Inc
Publication of WO2006066126A2 publication Critical patent/WO2006066126A2/en
Publication of WO2006066126A3 publication Critical patent/WO2006066126A3/en

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D271/00—Heterocyclic compounds containing five-membered rings having two nitrogen atoms and one oxygen atom as the only ring hetero atoms
    • C07D271/02—Heterocyclic compounds containing five-membered rings having two nitrogen atoms and one oxygen atom as the only ring hetero atoms not condensed with other rings
    • C07D271/06—1,2,4-Oxadiazoles; Hydrogenated 1,2,4-oxadiazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
    • C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D277/22—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic System without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Abstract

Ligands, compositions, and metal-ligand complexes that incorporate phenol-heterocyclic compounds are disclosed that are useful in the catalysis of transformations such as the polymerization of monomers into polymers. The catalysts have high performance characteristics, including high comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts particularly polymerize styrene to form polystyrene.
PCT/US2005/045766 2004-12-16 2005-12-16 Phenol-heterocyclic ligands, metal complexes, and their uses as catalysts WO2006066126A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US63655504P 2004-12-16 2004-12-16
US60/636,555 2004-12-16

Publications (2)

Publication Number Publication Date
WO2006066126A2 WO2006066126A2 (en) 2006-06-22
WO2006066126A3 true WO2006066126A3 (en) 2006-08-24

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US (2) US7705157B2 (en)
WO (1) WO2006066126A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7196197B2 (en) 2018-04-26 2022-12-26 エクソンモービル ケミカル パテンツ インコーポレイテッド Non-coordinating anionic activators containing cations with long-chain alkyl groups

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100249161A1 (en) * 2006-11-15 2010-09-30 Anders Klarskov Petersen 2- ( 2 -hydroxyphenyl) -quinazolin-4-ones useful for treating obesity and diabetes
US8022066B2 (en) * 2006-11-15 2011-09-20 High Point Pharmaceuticals, Llc 2-(2-hydroxyphenyl) benzothiadiazines useful for treating obesity and diabetes
WO2008059023A1 (en) * 2006-11-15 2008-05-22 High Point Pharmaceuticals, Llc New haloalkylsulfone substituted compounds useful for treating obesity and diabetes
WO2008059026A1 (en) * 2006-11-15 2008-05-22 High Point Pharmaceuticals, Llc Novel 2-(2-hydroxyphenyl)benzimidazoles useful for treating obesity and diabetes
AU2007334436A1 (en) 2006-12-15 2008-06-26 Abbott Laboratories Novel oxadiazole compounds
US8242237B2 (en) 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
US8431660B2 (en) * 2007-12-05 2013-04-30 Lg Chem, Ltd. Non-metallocene catalysts having tetrazol group for olefin polymerization and polymerizing method of olefin using the same
US20090286944A1 (en) * 2008-05-15 2009-11-19 Symyx Technologies, Inc. Select phenol-heterocycle ligands, metal complexes formed therefrom, and their uses as catalysts
CA2786286C (en) 2008-12-31 2017-03-14 Symyx Solutions, Inc. Method for producing very-high or ultra-high molecular weight polyethylene
JP5709389B2 (en) 2009-03-20 2015-04-30 株式会社半導体エネルギー研究所 Oxadiazole derivative, light-emitting element, light-emitting device, and electronic device
EP2430053A1 (en) * 2009-05-14 2012-03-21 Univation Technologies, LLC Mixed metal catalyst systems having a tailored hydrogen response
JP5539687B2 (en) * 2009-09-10 2014-07-02 東レ・ダウコーニング株式会社 Method for producing alkyl-modified polydimethylsiloxane purified product, cosmetic raw material containing the purified product, and cosmetic
US8541522B2 (en) * 2009-10-28 2013-09-24 Exxonmobil Chemical Patents Inc. Catalyst compounds and use thereof
CN102597015A (en) * 2009-10-28 2012-07-18 埃克森美孚化学专利公司 Catalyst compounds and use thereof
WO2011056432A2 (en) 2009-10-28 2011-05-12 Exxonmobil Chemical Patents Inc. Catalyst compounds and use thereof
WO2011056431A2 (en) * 2009-10-28 2011-05-12 Exxonmobil Chemical Patents Inc. Catalyst compounds and use thereof
US8557936B2 (en) * 2009-10-28 2013-10-15 Exxonmobil Chemical Patents Inc. Catalyst compounds and use thereof
US9228061B2 (en) 2011-09-07 2016-01-05 Dow Corning Corporation Zirconium containing complex and condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
WO2013036546A2 (en) 2011-09-07 2013-03-14 Dow Corning Corporation Titanium containing complex and condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
US9139699B2 (en) 2012-10-04 2015-09-22 Dow Corning Corporation Metal containing condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
CN111362885A (en) * 2020-03-06 2020-07-03 华东理工大学 Benzothiazole ring substituted aminophenol oxygen radical zinc complex and preparation method and application thereof
WO2021242801A1 (en) 2020-05-29 2021-12-02 Dow Global Technologies Llc Attenuated hybrid catalysts
WO2021242800A1 (en) 2020-05-29 2021-12-02 Dow Global Technologies Llc Attenuated post-metallocene catalysts
RU2748114C1 (en) * 2020-09-11 2021-05-19 Публичное акционерное общество "Нефтяная компания "Роснефть" (ПАО "НК "Роснефть") Method of producing a {2,4-di-tert-butyl-6-[(tert-butylimino)methyl]phenolate} pre-catalyst for vanadium(v) oxodichloride for the synthesis of epdm/epm ethylene-propylene rubbers

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000030864A (en) * 1998-07-14 2000-01-28 Minolta Co Ltd Organic electroluminescence element
WO2000037512A2 (en) * 1998-12-18 2000-06-29 Univation Technologies, Llc Olefin polymerization catalysts, their production and use
JP2001271063A (en) * 2000-03-27 2001-10-02 Toyo Ink Mfg Co Ltd Material for organic electroluminescent device and organic electroluminescent device using the same material
WO2002006358A1 (en) * 2000-07-17 2002-01-24 Univation Technologies, Llc A catalyst system and its use in a polymerization process
WO2002046250A2 (en) * 2000-12-04 2002-06-13 Univation Technologies, Llc Catalyst composition, method of polymerization and polymer therefrom
US20030165711A1 (en) * 1998-06-23 2003-09-04 Youngkyoo Kim Novel organometallic luminescent materials and organic electroluminescent device containing same
WO2006036748A2 (en) * 2004-09-22 2006-04-06 Symyx Technologies, Inc. Heterocycle-amine ligands, compositions, complexes, and catalysts, and methods of making and using the same

Family Cites Families (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4297465A (en) * 1980-10-29 1981-10-27 Eastman Kodak Company Catalysts for polymerizing propylene in a high temperature solution process
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5384299A (en) * 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
ZA882999B (en) 1987-05-04 1988-11-01 Shell Oil Company Preparation of olefin polymerization catalyst component
US5093415A (en) * 1987-05-19 1992-03-03 Union Carbide Chemicals & Plastics Technology Corporation Process for producing stereoregular polymers having a narrow molecular weight distribution
US4971936A (en) * 1989-07-10 1990-11-20 Shell Oil Company Catalyst component for making primarily isotactic elastomeric polypropylene or polybutene
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
ES2085000T3 (en) * 1990-12-27 1996-05-16 Exxon Chemical Patents Inc A TRANSITIONAL AMIDO-METAL COMPOUND AND A CATALYTIC SYSTEM FOR THE PRODUCTION OF ISOTACTIC POLYPROPYLENE.
JPH04272907A (en) * 1991-02-27 1992-09-29 Mitsubishi Petrochem Co Ltd Production of olefin polymer
KR100262023B1 (en) * 1992-01-06 2000-07-15 그레이스 스티븐 에스. Improved catalyst composition
CA2121721C (en) 1993-04-29 2004-11-23 Giampiero Morini Crystalline propylene polymers having high melt flow rate values and a narrow molecular weight distribution
TW354792B (en) * 1993-08-13 1999-03-21 Mitsui Petrochemical Ind Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer
US5527929A (en) 1994-08-02 1996-06-18 The Dow Chemical Company Zwitterionic biscyclopentadienyl complexes
US6030917A (en) * 1996-07-23 2000-02-29 Symyx Technologies, Inc. Combinatorial synthesis and analysis of organometallic compounds and catalysts
US5985356A (en) * 1994-10-18 1999-11-16 The Regents Of The University Of California Combinatorial synthesis of novel materials
US5637660A (en) * 1995-04-17 1997-06-10 Lyondell Petrochemical Company Polymerization of α-olefins with transition metal catalysts based on bidentate ligands containing pyridine or quinoline moiety
JP3653825B2 (en) * 1995-10-23 2005-06-02 東洋インキ製造株式会社 Organic electroluminescent device material and organic electroluminescent device using the same
JPH11514012A (en) 1996-07-23 1999-11-30 サイミックス・テクノロジーズ Combinatorial synthesis and analysis of organometallic compounds and catalysts
US6720186B1 (en) * 1998-04-03 2004-04-13 Symyx Technologies, Inc. Method of research for creating and testing novel catalysts, reactions and polymers
TWI246520B (en) * 1997-04-25 2006-01-01 Mitsui Chemicals Inc Processes for olefin polymerization
IL122115A (en) 1997-07-27 2007-06-17 Technion Res & Dev Foundation Process for polymerizing alpha-olefins and polymers, copolymers and elastomers prepared thereby
EP1000069B1 (en) 1997-08-01 2003-03-12 Dow Global Technologies Inc. Catalyst activator
EP0938509B1 (en) * 1997-09-03 2002-11-20 Basell Poliolefine Italia S.p.A. Components and catalysts for the polymerization of olefins
JP4722287B2 (en) 1998-02-20 2011-07-13 ダウ グローバル テクノロジーズ インコーポレーテッド Catalyst activators containing expanded anions
US6410660B1 (en) * 1998-03-27 2002-06-25 E. I. Du Pont De Nemours And Company Polymerization of olefins
US6175409B1 (en) * 1999-04-02 2001-01-16 Symyx Technologies, Inc. Flow-injection analysis and variable-flow light-scattering methods and apparatus for characterizing polymers
US6294388B1 (en) * 1998-04-03 2001-09-25 Symyx Technologies, Inc. Indirect calibration of polymer characterization systems
US6260407B1 (en) * 1998-04-03 2001-07-17 Symyx Technologies, Inc. High-temperature characterization of polymers
US6406632B1 (en) * 1998-04-03 2002-06-18 Symyx Technologies, Inc. Rapid characterization of polymers
KR100342541B1 (en) 1998-04-16 2002-06-28 나까니시 히로유끼 Olefin polymerization catalyst and polymerization process
US6306658B1 (en) * 1998-08-13 2001-10-23 Symyx Technologies Parallel reactor with internal sensing
US6759014B2 (en) * 2001-01-26 2004-07-06 Symyx Technologies, Inc. Apparatus and methods for parallel processing of multiple reaction mixtures
US6455316B1 (en) * 1998-08-13 2002-09-24 Symyx Technologies, Inc. Parallel reactor with internal sensing and method of using same
DE69900946T2 (en) 1998-10-19 2002-06-27 Symyx Technologies Inc DESIGN OF COMBINATIONAL MATERIAL LIBRARIES
JP4221129B2 (en) * 1999-02-15 2009-02-12 富士フイルム株式会社 Nitrogen-containing heterocyclic compound, organic light emitting device material, organic light emitting device
JP4045684B2 (en) * 1999-03-01 2008-02-13 コニカミノルタホールディングス株式会社 Organic electroluminescence device
US6436292B1 (en) * 1999-04-02 2002-08-20 Symyx Technologies, Inc. Parallel high-performance liquid chromatography with post-separation treatment
US6296771B1 (en) * 1999-04-02 2001-10-02 Symyx Technologies, Inc. Parallel high-performance liquid chromatography with serial injection
US6507945B1 (en) * 1999-05-05 2003-01-14 Symyx Technologies, Inc. Synthesizing combinatorial libraries of materials
JP2001040346A (en) * 1999-07-30 2001-02-13 Fuji Photo Film Co Ltd Luminescent element material and luminescent element using same
JP3938263B2 (en) * 1999-11-09 2007-06-27 独立行政法人科学技術振興機構 Method for producing metal complex
US7078164B1 (en) 2000-06-19 2006-07-18 Symyx Technologies, Inc. High throughput screen for identifying polymerization catalysts from potential catalysts
US7018589B1 (en) * 2000-07-19 2006-03-28 Symyx Technologies, Inc. High pressure parallel reactor
WO2002046249A2 (en) 2000-11-07 2002-06-13 Symyx Technologies, Inc. Methods of copolymerizing ethylene and isobutylene and polymers made thereby
GB0028317D0 (en) * 2000-11-21 2001-01-03 South Bank Univ Entpr Ltd Electroluminescent device incorporating polyaniline
JP3949391B2 (en) * 2001-05-14 2007-07-25 富士フイルム株式会社 Light emitting element
SG147306A1 (en) 2001-11-06 2008-11-28 Dow Global Technologies Inc Isotactic propylene copolymers, their preparation and use
AU2003221701A1 (en) * 2002-04-12 2003-10-27 Dow Global Technologies Inc. Low molecular weight copolymer of ethylene and vinyl aromatic monomer and uses thereof
US6794514B2 (en) * 2002-04-12 2004-09-21 Symyx Technologies, Inc. Ethylene-styrene copolymers and phenol-triazole type complexes, catalysts, and processes for polymerizing
AU2003225156A1 (en) 2002-04-24 2003-11-10 Symyx Technologies, Inc. Bridged bi-aromatic ligands, complexes, catalysts and processes for polymerizing and poymers therefrom
US7160513B2 (en) 2002-12-20 2007-01-09 Symyx Technologies, Inc. Batch reactor with injection system
DE10309837A1 (en) 2003-03-05 2004-09-16 Basf Ag Catalysts for the polymerization of styrene

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030165711A1 (en) * 1998-06-23 2003-09-04 Youngkyoo Kim Novel organometallic luminescent materials and organic electroluminescent device containing same
JP2000030864A (en) * 1998-07-14 2000-01-28 Minolta Co Ltd Organic electroluminescence element
WO2000037512A2 (en) * 1998-12-18 2000-06-29 Univation Technologies, Llc Olefin polymerization catalysts, their production and use
JP2001271063A (en) * 2000-03-27 2001-10-02 Toyo Ink Mfg Co Ltd Material for organic electroluminescent device and organic electroluminescent device using the same material
WO2002006358A1 (en) * 2000-07-17 2002-01-24 Univation Technologies, Llc A catalyst system and its use in a polymerization process
WO2002046250A2 (en) * 2000-12-04 2002-06-13 Univation Technologies, Llc Catalyst composition, method of polymerization and polymer therefrom
WO2006036748A2 (en) * 2004-09-22 2006-04-06 Symyx Technologies, Inc. Heterocycle-amine ligands, compositions, complexes, and catalysts, and methods of making and using the same

Non-Patent Citations (22)

* Cited by examiner, † Cited by third party
Title
ANTHONY K ET AL: "Solid-state fluorescent photophysics of some 2-substituted benzothiazoles", JOURNAL OF THE CHEMICAL SOCIETY, PERKIN TRANSACTIONS 2, no. 12, 1984, pages 2111 - 2117, XP009011528, ISSN: 1472-779X *
BACH T ET AL: "Synthesis of 2-(o-hydroxyaryl)-4-arylthiazoles by regioselective Pd(0)-catalyzed cross-coupling", TETRAHEDRON LETTERS, vol. 41, no. 11, March 2000 (2000-03-01), pages 1707 - 1710, XP004202254, ISSN: 0040-4039 *
BEHER J ET AL: "O- und N-alkylsubstituierte 2-(2'-hydroxyphenyl)- benzimidazole und -1,3,4-oxadiazole als Komplexbildner und Extractionsmittel für Kupfer-II-ionen - O- and N-alkyl substituted 2-(2'-hydroxyphenyl)- benzimidazoles and -1,3,4-oxadiazoles and their use as complexants and extractants for copper(II) ions", JOURNAL FÜR PRAKTISCHE CHEMIE, vol. 325, no. 5, 1983, pages 708 - 718, XP009066580 *
BENISVY L ET AL: "A phenol-imidazole pro-ligand that can exist as a phenoxyl radical, alone and when complexed to copper (II) and zinc (II)", DALTON TRANSACTIONS, no. 10, 2003, pages 1975 - 1985, XP002382183 *
CALHORDA M J ET AL: "Bis(eta-cyclopentadienyl)molybdenum (and -tungsten or -titanium) complexes with chelate imidazole derivatives and realted ligands", JOURNAL OF THE CHEMICAL SOCIETY, DALTON TRANSACTIONS, no. 8, 1980, pages 1443 - 1447, XP009066562, ISSN: 0300-9246 *
CARVALHO C ET AL: "Excited-state acidity of bifunctional compounds. Part 5. 5-(2- hydroxyphenyl)-3-phenyl-1,2,4-oxadiazole and 3-(2-hydroxyphenyl)-5-phenyl-1,2,4- oxadiazole", JOURNAL OF THE CHEMICAL SOCIETY, FARADAY TRANSACTIONS, vol. 93, no. 18, 21 September 1997 (1997-09-21), pages 3325 - 3329, XP000697790, ISSN: 0956-5000 *
COOK A H ET AL: "Experiments in the triazine and the glyoxaline series", JOURNAL OF THE CHEMICAL SOCIETY, 1941, pages 278 - 282, XP009017853, ISSN: 0368-1769 *
COUSIN ET AL: "Sur les nitriles salicyliques - Salicic nitriles", BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, vol. 4, no. 15, 1914, pages 414 - 421, XP009066572 *
COZZI P G ET AL: "(Hydroxyphenyl)oxazoline: a novel and remarkably facile entry into the area of chiral cationic alkylzirconium complexes which serve as polymerization catalysts", ORGANOMETALLICS, vol. 14, no. 11, 1995, pages 4994 - 4996, XP000909157, ISSN: 0276-7333 *
COZZI P G ET AL: "Bis(hydroxyphenyloxazolinato)-titanium(IV) and -zirconium(IV) triflates as novel transition metal-base Lewis acids", JOURNAL OF THE CHEMICAL SOCIETY, PERKIN TRANSACTIONS 1, no. 20, 1995, pages 2557 - 2563, XP009066567 *
COZZI P G ET AL: "Oxazoline early transition metal complexes: functionalisable achiral titanium(IV), titanium(III), zirconium(IV), vanadium(III) and chiral zriconium (IV) bis(oxazoline) complexes", INORGANIC CHEMISTRY, vol. 34, no. 11, 24 May 1995 (1995-05-24), pages 2921 - 2930, XP002382175, ISSN: 0022-1669 *
DELIWALA C V ET AL: "Chemotherapy of tuberculosis. Part III. Preparation of 5:5'dichlorosalicil and heterocyclic derivatives from dichlorosalicil and related alpha-diketones", PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES, SECTION A, vol. 31, 1950, pages 107 - 116, XP009066816 *
FUKATA G ET AL: "Cyclodienones. 9. Reaction of 4-halo-2,4,6-tri-tert-butyl-2,5-cyclohexadien-1-ones with pyrazoles and preparation of 1-(2-hydroxyphenyl)- and 1-(4-hydroxyphenyl)pyrazoles", HETEROCYCLES, vol. 19, no. 8, 1982, pages 1487 - 1495, XP009066593 *
MAURYA M R ET AL: "Oxo, dioxo and oxoperoxo complexes of molybdenum and tungsten with 2-(2-hydroxyphenyl)benzimidazole", JOURNAL OF CHEMICAL RESEARCH (SYNOPSES), no. 8, 1996, pages 390 - 391, XP009066565 *
MISHRA A ET AL: "Rare earth complexes with N,O-donor ligands - part I. Nitrato-complexes of terpositive yttrium and lighter lanthanides with 2-(2'-hydroxyphenyl) benzimidazole", JOURNAL OF THE INDIAN CHEMICAL SOCIETY, vol. 57, no. 3, March 1980 (1980-03-01), pages 249 - 251, XP009066564, ISSN: 0019-4522 *
MISHRA A ET AL: "Rare earth complexes with N,O-donor ligands - part II. Complexes of Gd(III), Tb(III), Dy(III) and Ho(III) with 2-(2'-hydroxyphenyl) benzimidazole", JOURNAL OF THE INDIAN CHEMICAL SOCIETY, vol. 58, no. 12, December 1981 (1981-12-01), pages 1197 - 1198, XP009066563, ISSN: 0019-4522 *
PATENT ABSTRACTS OF JAPAN vol. 2000, no. 04 31 August 2000 (2000-08-31) *
PATENT ABSTRACTS OF JAPAN vol. 2002, no. 02 2 April 2002 (2002-04-02) *
PLA-DALMAU A: "2-(2'-hydroxyphenyl)benzothiazoles, -benzoxazoles, and -benzimidazoles for plastic scintillation applications", JOURNAL OF ORGANIC CHEMISTRY, vol. 60, no. 17, 25 September 1995 (1995-09-25), pages 5468 - 5473, XP002382177, ISSN: 0022-3263 *
RYABUKHIN Y A ET AL: "Synthesis of bis(o-hydroxyphenyl)-1,3,5-triazines, 1,2,4-triazoles, and oxadiazole by recyclisation of the o-hydroxyphenyl-4-oxo-1,3-benzoxazinium cation", CHEMISTRY OF HETEROCYCLIC COMPOUNDS, vol. 19, no. 3, 1983, pages 332 - 336, XP009066578, ISSN: 0009-3122 *
RYABUKHIN Y I ET AL: "Synthesis and study of the structure of o-hydroxy-1,2,4-oxadiazoles", CHEMISTRY OF HETEROCYCLIC COMPOUNDS, vol. 28, no. 4, 1992, pages 454 - 463, XP009066577 *
WEIDNER-WELLS M A ET AL: "Amidino benzimidazole inhibitors of bacterial two-component systems.", BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, vol. 11, no. 12, 18 June 2001 (2001-06-18), pages 1545 - 1548, XP002382176, ISSN: 0960-894X *

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JP7196197B2 (en) 2018-04-26 2022-12-26 エクソンモービル ケミカル パテンツ インコーポレイテッド Non-coordinating anionic activators containing cations with long-chain alkyl groups

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