WO2007075867A3 - Composite solid electrolyte for protection of active metal anodes - Google Patents

Composite solid electrolyte for protection of active metal anodes Download PDF

Info

Publication number
WO2007075867A3
WO2007075867A3 PCT/US2006/048755 US2006048755W WO2007075867A3 WO 2007075867 A3 WO2007075867 A3 WO 2007075867A3 US 2006048755 W US2006048755 W US 2006048755W WO 2007075867 A3 WO2007075867 A3 WO 2007075867A3
Authority
WO
WIPO (PCT)
Prior art keywords
solid electrolyte
active metal
composite solid
porosity
architecture
Prior art date
Application number
PCT/US2006/048755
Other languages
French (fr)
Other versions
WO2007075867A2 (en
Inventor
Steven J Visco
Jonghe Lutgard C De
Yevgeniy S Nimon
Original Assignee
Polyplus Battery Co Inc
Steven J Visco
Jonghe Lutgard C De
Yevgeniy S Nimon
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Polyplus Battery Co Inc, Steven J Visco, Jonghe Lutgard C De, Yevgeniy S Nimon filed Critical Polyplus Battery Co Inc
Publication of WO2007075867A2 publication Critical patent/WO2007075867A2/en
Publication of WO2007075867A3 publication Critical patent/WO2007075867A3/en

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/122Ionic conductors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566Liquid materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00Hybrid cells; Manufacture thereof
    • H01M12/04Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00Hybrid cells; Manufacture thereof
    • H01M12/08Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • H01M4/0402Methods of deposition of the material
    • H01M4/0416Methods of deposition of the material involving impregnation with a solution, dispersion, paste or dry powder
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/06Electrodes for primary cells
    • H01M4/08Processes of manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134Electrodes based on metals, Si or alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/24Electrodes for alkaline accumulators
    • H01M4/242Hydrogen storage electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/24Electrodes for alkaline accumulators
    • H01M4/32Nickel oxide or hydroxide electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/38Selection of substances as active materials, active masses, active liquids of elements or alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/38Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/383Hydrogen absorbing alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/38Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/383Hydrogen absorbing alloys
    • H01M4/385Hydrogen absorbing alloys of the type LaNi5
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/46Separators, membranes or diaphragms characterised by their combination with electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/04Cells with aqueous electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/14Cells with non-aqueous electrolyte
    • H01M6/16Cells with non-aqueous electrolyte with organic electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/14Cells with non-aqueous electrolyte
    • H01M6/18Cells with non-aqueous electrolyte with solid electrolyte
    • H01M6/181Cells with non-aqueous electrolyte with solid electrolyte with polymeric electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/14Cells with non-aqueous electrolyte
    • H01M6/18Cells with non-aqueous electrolyte with solid electrolyte
    • H01M6/185Cells with non-aqueous electrolyte with solid electrolyte with oxides, hydroxides or oxysalts as solid electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/14Cells with non-aqueous electrolyte
    • H01M6/18Cells with non-aqueous electrolyte with solid electrolyte
    • H01M6/188Processes of manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/24Cells comprising two different electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/30Deferred-action cells
    • H01M6/32Deferred-action cells activated through external addition of electrolyte or of electrolyte components
    • H01M6/34Immersion cells, e.g. sea-water cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/08Fuel cells with aqueous electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00Hybrid cells; Manufacture thereof
    • H01M12/04Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
    • H01M12/06Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/026Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027Negative electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0002Aqueous electrolytes
    • H01M2300/0005Acid electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0068Solid electrolytes inorganic
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0068Solid electrolytes inorganic
    • H01M2300/0071Oxides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0082Organic polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0085Immobilising or gelification of electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0088Composites
    • H01M2300/0091Composites in the form of mixtures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/38Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/387Tin or alloys based on tin
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

A composite solid electrolyte include a monolithic solid electrolyte base component that is a continuous matπx of an inorganic active metal ion conductor and a filler component used to eliminate through porosity in the solid electrolyte In this way a solid electrolyte produced by any process that yields residual through porosity can be modified by the incorporation of a filler to form a substantially impervious composite solid electrolyte and eliminate through porosity in the base component Methods of making the composites is also disclosed The composites are generally useful in electrochemical cell structures such as battery cells and in particular protected active metal anodes, particularly lithium anodes, that are protected with a protective membrane architecture incorporating the composite solid electrolyte The protective architecture prevents the active metal of the anode from deleteπous reaction with the environment on the other (cathode) side of the architecture.
PCT/US2006/048755 2005-12-19 2006-12-19 Composite solid electrolyte for protection of active metal anodes WO2007075867A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US75225505P 2005-12-19 2005-12-19
US60/752,255 2005-12-19

Publications (2)

Publication Number Publication Date
WO2007075867A2 WO2007075867A2 (en) 2007-07-05
WO2007075867A3 true WO2007075867A3 (en) 2008-06-12

Family

ID=38218598

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/048755 WO2007075867A2 (en) 2005-12-19 2006-12-19 Composite solid electrolyte for protection of active metal anodes

Country Status (2)

Country Link
US (3) US8182943B2 (en)
WO (1) WO2007075867A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108878751B (en) * 2018-07-03 2021-07-30 宁德卓高新材料科技有限公司 Conductive ceramic composite diaphragm and solid-state battery

Families Citing this family (231)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7247408B2 (en) * 1999-11-23 2007-07-24 Sion Power Corporation Lithium anodes for electrochemical cells
US20110165471A9 (en) * 1999-11-23 2011-07-07 Sion Power Corporation Protection of anodes for electrochemical cells
US7771870B2 (en) 2006-03-22 2010-08-10 Sion Power Corporation Electrode protection in both aqueous and non-aqueous electrochemical cells, including rechargeable lithium batteries
US7645543B2 (en) 2002-10-15 2010-01-12 Polyplus Battery Company Active metal/aqueous electrochemical cells and systems
US20080057386A1 (en) * 2002-10-15 2008-03-06 Polyplus Battery Company Ionically conductive membranes for protection of active metal anodes and battery cells
US7491458B2 (en) 2003-11-10 2009-02-17 Polyplus Battery Company Active metal fuel cells
US10629947B2 (en) 2008-08-05 2020-04-21 Sion Power Corporation Electrochemical cell
US9368775B2 (en) 2004-02-06 2016-06-14 Polyplus Battery Company Protected lithium electrodes having porous ceramic separators, including an integrated structure of porous and dense Li ion conducting garnet solid electrolyte layers
US7282295B2 (en) * 2004-02-06 2007-10-16 Polyplus Battery Company Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture
US8679674B2 (en) 2005-03-25 2014-03-25 Front Edge Technology, Inc. Battery with protective packaging
US7846579B2 (en) 2005-03-25 2010-12-07 Victor Krasnov Thin film battery with protective packaging
WO2007062220A2 (en) * 2005-11-23 2007-05-31 Polyplus Battery Company Li/air non-aqueous batteries
WO2007075867A2 (en) 2005-12-19 2007-07-05 Polyplus Battery Company Composite solid electrolyte for protection of active metal anodes
US8012633B2 (en) * 2006-10-13 2011-09-06 Ceramatec, Inc. Advanced metal-air battery having a ceramic membrane electrolyte
JP5110850B2 (en) * 2006-10-31 2012-12-26 株式会社オハラ Lithium ion conductive solid electrolyte and method for producing the same
EP2102924B1 (en) 2006-12-04 2018-03-28 Sion Power Corporation Separation of electrolytes in lithium batteries
US8673477B2 (en) 2008-06-16 2014-03-18 Polyplus Battery Company High energy density aqueous lithium/air-battery cells
US8771879B2 (en) 2007-09-05 2014-07-08 Ceramatec, Inc. Lithium—sulfur battery with a substantially non-porous lisicon membrane and porous lisicon layer
US20100239893A1 (en) * 2007-09-05 2010-09-23 John Howard Gordon Sodium-sulfur battery with a substantially non-porous membrane and enhanced cathode utilization
US20090123846A1 (en) * 2007-11-12 2009-05-14 Kyushu University All-solid-state cell
US20090123847A1 (en) * 2007-11-12 2009-05-14 Kyushu University All-solid-state cell
US8012621B2 (en) 2007-11-26 2011-09-06 Ceramatec, Inc. Nickel-metal hydride battery using alkali ion conducting separator
US9209445B2 (en) 2007-11-26 2015-12-08 Ceramatec, Inc. Nickel-metal hydride/hydrogen hybrid battery using alkali ion conducting separator
US8088270B2 (en) * 2007-11-27 2012-01-03 Ceramatec, Inc. Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides
WO2009070600A2 (en) 2007-11-27 2009-06-04 Ceramatec, Inc. Substantially solid, flexible electrolyte for alkili-metal-ion batteries
US20090136839A1 (en) * 2007-11-28 2009-05-28 Front Edge Technology, Inc. Thin film battery comprising stacked battery cells and method
US20090189567A1 (en) * 2008-01-30 2009-07-30 Joshi Ashok V Zinc Anode Battery Using Alkali Ion Conducting Separator
US10320033B2 (en) 2008-01-30 2019-06-11 Enlighten Innovations Inc. Alkali metal ion battery using alkali metal conductive ceramic separator
WO2010054261A1 (en) 2008-11-07 2010-05-14 Seeo, Inc Multiple electrolyte electrochemical cells
US9893337B2 (en) 2008-02-13 2018-02-13 Seeo, Inc. Multi-phase electrolyte lithium batteries
JP5358825B2 (en) * 2008-02-22 2013-12-04 国立大学法人九州大学 All solid battery
JP5300502B2 (en) * 2008-03-13 2013-09-25 株式会社東芝 Battery active material, non-aqueous electrolyte battery and battery pack
WO2009120812A2 (en) * 2008-03-25 2009-10-01 A123 Systems, Inc. High energy high power electrodes and batteries
US8349498B2 (en) * 2010-01-12 2013-01-08 Sisom Thin Films, Llc Method of forming solid state electrolyte having high lithium ion conduction and battery incorporating same
FR2931298B1 (en) * 2008-05-13 2010-09-03 Electricite De France LITHIUM MEDIUM-TO-AIR STORAGE BATTERY
US9099758B2 (en) * 2008-06-20 2015-08-04 University Of Dayton Lithium-air cell incorporating lithium aluminum germanium phosphate cathode
US9178255B2 (en) * 2008-06-20 2015-11-03 University Of Dayton Lithium-air cells incorporating solid electrolytes having enhanced ionic transport and catalytic activity
CN101325094B (en) * 2008-07-25 2013-04-03 清华大学 Lithium lanthanum titanium oxygen LLTO composite solid-state electrolyte material and synthesizing method thereof
WO2010016881A1 (en) 2008-08-05 2010-02-11 Sion Power Corporation Application of force in electrochemical cells
US8940443B2 (en) * 2008-08-13 2015-01-27 Greatbatch Ltd. Polyvinylpyridine additives for nonaqueous electrolytes activating lithium rechargeable electrochemical cells
US8163434B2 (en) 2008-08-28 2012-04-24 General Electric Company Barrier coatings for interconnects; related devices, and methods of forming
US8178241B2 (en) * 2008-08-28 2012-05-15 3M Innovative Properties Company Electrode including current collector with nano-scale coating and method of making the same
US8323817B2 (en) * 2008-09-12 2012-12-04 Ceramatec, Inc. Alkali metal seawater battery
US9475998B2 (en) 2008-10-09 2016-10-25 Ceramatec, Inc. Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides
JP4728385B2 (en) * 2008-12-10 2011-07-20 ナミックス株式会社 Lithium ion secondary battery and manufacturing method thereof
US9923231B2 (en) 2009-08-14 2018-03-20 Seeo, Inc. High energy lithium battery with separate anolyte and catholyte layers
WO2011028251A2 (en) 2009-08-24 2011-03-10 Sion Power Corporation Release system for electrochemical cells
WO2011057135A2 (en) 2009-11-05 2011-05-12 Ceramatec, Inc Solid-state sodium-based secondary cell having a sodium ion conductive ceramic separator
EP2360772A1 (en) * 2010-02-12 2011-08-24 Fortu Intellectual Property AG Rechargeable and electrochemical cell
US9209458B2 (en) 2010-02-10 2015-12-08 Alevo Research Ag Rechargeable electrochemical battery cell
US8865354B2 (en) * 2010-03-30 2014-10-21 West Virginia University Inorganic solid electrolyte glass phase composite and a battery containing an inorganic solid electrolyte glass phase composite
CN102948000B (en) 2010-06-14 2016-05-18 株式会社Lg化学 Electrolyte used for electrochemical equipment, prepare described electrolytical method and comprise described electrolyte electrochemical device
KR101311494B1 (en) 2010-06-14 2013-09-25 주식회사 엘지화학 Electrolyte for electrochemical device, the preparation method thereof and electrochemical device comprising the same
US8758914B2 (en) 2010-06-18 2014-06-24 Polyplus Battery Company Li-Ion/polysulfide flow battery
US9147920B2 (en) 2010-07-01 2015-09-29 Ford Global Technologies, Llc Metal oxygen battery containing oxygen storage materials
US20110143226A1 (en) * 2010-07-01 2011-06-16 Ford Global Technologies, Llc Metal Oxygen Battery Containing Oxygen Storage Materials
US8658319B2 (en) * 2010-07-01 2014-02-25 Ford Global Technologies, Llc Metal oxygen battery containing oxygen storage materials
US8968942B2 (en) * 2010-07-01 2015-03-03 Ford Global Technologies, Llc Metal oxygen battery containing oxygen storage materials
US9209503B2 (en) * 2010-07-01 2015-12-08 Ford Global Technologies, Llc Metal oxygen battery containing oxygen storage materials
US8771855B2 (en) 2010-08-11 2014-07-08 Ceramatec, Inc. Alkali metal aqueous battery
KR101394624B1 (en) * 2010-08-13 2014-05-14 에스케이이노베이션 주식회사 Pore-Protected Multi-layered Composite Separator and the Method for manufacturing the same
WO2012034042A2 (en) 2010-09-09 2012-03-15 California Institute Of Technology Electrochemical energy storage systems and methods
CA2724307A1 (en) * 2010-12-01 2012-06-01 Hydro-Quebec Lithium-air battery
WO2012075079A2 (en) 2010-12-01 2012-06-07 Ceramatec, Inc. Moderate temperature sodium battery
US9305716B2 (en) * 2010-12-03 2016-04-05 Imra America, Inc. Rechargeable electrochemical energy storage device
JP5556797B2 (en) * 2010-12-17 2014-07-23 トヨタ自動車株式会社 Secondary battery
US9246188B2 (en) * 2011-02-14 2016-01-26 Los Alamos National Security, Llc Anti-perovskite solid electrolyte compositions
US8999563B2 (en) * 2011-04-07 2015-04-07 Samsung Sdi Co., Ltd. Secondary battery
KR20120122674A (en) * 2011-04-29 2012-11-07 삼성전자주식회사 Negative electrode for lithium secondary battery, method of preparing the same, and lithium secondary battery employing the same
CN103718371A (en) * 2011-05-23 2014-04-09 国立大学法人名古屋工业大学 Production method for material employed in energy device and/or electrical storage device, and material employed in energy device and/or electrical storage device
KR101807911B1 (en) 2011-06-17 2017-12-11 시온 파워 코퍼레이션 Plating technique for electrode
EP2732487A4 (en) 2011-07-11 2015-04-08 California Inst Of Techn Novel separators for electrochemical systems
US9379368B2 (en) 2011-07-11 2016-06-28 California Institute Of Technology Electrochemical systems with electronically conductive layers
CN102916199B (en) * 2011-08-05 2014-12-10 清华大学 Preparation method of fuel cell membrane electrode
WO2013028574A2 (en) 2011-08-19 2013-02-28 Polyplus Battery Company Aqueous lithium air batteries
WO2013033126A1 (en) * 2011-09-02 2013-03-07 Seeo, Inc. Microsphere composite electrolyte
JP2013073907A (en) * 2011-09-29 2013-04-22 Toyota Motor Corp Method for manufacturing electrode mixture
KR101905233B1 (en) * 2011-10-13 2018-10-05 시온 파워 코퍼레이션 Electrode structure and method for making the same
US8865340B2 (en) 2011-10-20 2014-10-21 Front Edge Technology Inc. Thin film battery packaging formed by localized heating
US8828573B2 (en) 2011-11-15 2014-09-09 Polyplus Battery Company Electrode structures for aqueous electrolyte lithium sulfur batteries
US8828575B2 (en) * 2011-11-15 2014-09-09 PolyPlus Batter Company Aqueous electrolyte lithium sulfur batteries
US9660265B2 (en) 2011-11-15 2017-05-23 Polyplus Battery Company Lithium sulfur batteries and electrolytes and sulfur cathodes thereof
US8828574B2 (en) 2011-11-15 2014-09-09 Polyplus Battery Company Electrolyte compositions for aqueous electrolyte lithium sulfur batteries
US10411288B2 (en) * 2011-11-29 2019-09-10 Corning Incorporated Reactive sintering of ceramic lithium-ion solid electrolytes
DE102011121236A1 (en) 2011-12-12 2013-06-13 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Solid electrolyte for use in lithium-air or lithium-water storage batteries
DE102011088910A1 (en) * 2011-12-16 2013-06-20 Robert Bosch Gmbh Lithium sulfur cell separator with polysulfide barrier
DK2794475T3 (en) 2011-12-21 2020-04-27 Univ California Connected corrugated carbon-based network
US9887429B2 (en) 2011-12-21 2018-02-06 Front Edge Technology Inc. Laminated lithium battery
WO2013093044A1 (en) 2011-12-22 2013-06-27 Cic Energigune Electrochemical energy storage device
US8864954B2 (en) 2011-12-23 2014-10-21 Front Edge Technology Inc. Sputtering lithium-containing material with multiple targets
US10355305B2 (en) 2012-01-16 2019-07-16 Enlighten Innovations Inc. Alkali metal intercalation material as an electrode in an electrolytic cell
JP6315769B2 (en) * 2012-01-27 2018-04-25 国立大学法人東京工業大学 Solid ion capacitor and method of using solid ion capacitor
CN104321914B (en) * 2012-03-01 2019-08-13 约翰逊Ip控股有限责任公司 High capacity solid union anode, solid union barrier film, solid state rechargeable lithium battery and its manufacturing method
CN104541349A (en) 2012-03-05 2015-04-22 加州大学评议会 Capacitor with electrodes made of an interconnected corrugated carbon-based network
WO2013140574A1 (en) * 2012-03-22 2013-09-26 株式会社 東芝 Solid electrolyte material, solid electrolyte, and cell
US9257695B2 (en) 2012-03-29 2016-02-09 Front Edge Technology, Inc. Localized heat treatment of battery component films
US9077000B2 (en) 2012-03-29 2015-07-07 Front Edge Technology, Inc. Thin film battery and localized heat treatment
EP2834866A4 (en) * 2012-04-02 2016-01-20 Ceramatec Inc Battery with non-porous alkali metal ion conductive honeycomb structure separator
US8932771B2 (en) 2012-05-03 2015-01-13 Polyplus Battery Company Cathode architectures for alkali metal / oxygen batteries
US8535851B1 (en) 2012-06-19 2013-09-17 ZAF Energy Systems, Incorporated Metal-air battery and gas impermeable anodic conductive matrix
KR101417302B1 (en) * 2012-07-19 2014-07-08 현대자동차주식회사 Materials for regulating electronic conductivity of lithium secondary battery and manufacturing method for electrode of lithium secondary battery using the same
EP2883269B1 (en) * 2012-08-10 2019-05-08 Robert Bosch GmbH Controlling the location of product distribution and removal in a metal/oxygen cell
US9478782B2 (en) * 2012-09-07 2016-10-25 Uchicago Argonne, Llc Lithium air battery having a cross-linked polysiloxane separator
JP6164812B2 (en) * 2012-09-19 2017-07-19 株式会社オハラ All solid lithium ion secondary battery
US9159964B2 (en) 2012-09-25 2015-10-13 Front Edge Technology, Inc. Solid state battery having mismatched battery cells
US8753724B2 (en) 2012-09-26 2014-06-17 Front Edge Technology Inc. Plasma deposition on a partially formed battery through a mesh screen
US9356320B2 (en) 2012-10-15 2016-05-31 Front Edge Technology Inc. Lithium battery having low leakage anode
US9005311B2 (en) 2012-11-02 2015-04-14 Sion Power Corporation Electrode active surface pretreatment
EP2965379B1 (en) * 2013-03-04 2020-07-08 Enlighten Innovations Inc. Alkali metal intercalation material as an electrode in an electrolytic cell
AU2014248900C1 (en) 2013-03-12 2017-06-08 Apple Inc. High voltage, high volumetric energy density Li-ion battery using advanced cathode materials
WO2014151385A1 (en) 2013-03-15 2014-09-25 Sion Power Corporation Protected electrode structures and methods
US10862105B2 (en) 2013-03-15 2020-12-08 Sion Power Corporation Protected electrode structures
KR102443148B1 (en) 2013-05-15 2022-09-13 퀀텀스케이프 배터리, 인코포레이티드 Solid state catholyte or electrolyte for battery
GB2514821A (en) 2013-06-06 2014-12-10 Leclanch S A Electrochemical cells with glass containing separators
US9905860B2 (en) 2013-06-28 2018-02-27 Polyplus Battery Company Water activated battery system having enhanced start-up behavior
CN105706274B (en) * 2013-07-03 2019-03-08 锡安能量公司 Ceramic/polymer matrix for the guard electrode in the electrochemical cell for including lithium rechargeable battery
JP6629200B2 (en) 2013-08-08 2020-01-15 シオン・パワー・コーポレーション Self-healing electrode protection in electrochemical cells
KR20180101729A (en) * 2013-08-30 2018-09-14 로베르트 보쉬 게엠베하 Li-ION BATTERY WITH COATED ELECTROLYTE
DE102013219602A1 (en) * 2013-09-27 2015-04-16 Robert Bosch Gmbh Production method for lithium cell functional layer
DE102013220785A1 (en) * 2013-10-15 2015-04-16 Robert Bosch Gmbh Lithium electrode for a lithium-ion battery and method for its production
JP2015088391A (en) * 2013-10-31 2015-05-07 セイコーエプソン株式会社 Solid electrolyte, method for manufacturing solid electrolyte, and lithium ion battery
US10714724B2 (en) 2013-11-18 2020-07-14 California Institute Of Technology Membranes for electrochemical cells
WO2015074037A2 (en) 2013-11-18 2015-05-21 California Institute Of Technology Separator enclosures for electrodes and electrochemical cells
DE102013224302A1 (en) * 2013-11-27 2015-06-11 Robert Bosch Gmbh Electrochemical cell and method for producing an electrochemical cell
US9368847B2 (en) * 2014-01-08 2016-06-14 Toyota Motor Engineering & Manufacturing North America, Inc. Rechargeable metal nitric oxide gas battery
KR102316170B1 (en) 2014-02-19 2021-10-21 시온 파워 코퍼레이션 Electrode protection using a composite comprising an electrolyte-inhibiting ion conductor
US10490796B2 (en) 2014-02-19 2019-11-26 Sion Power Corporation Electrode protection using electrolyte-inhibiting ion conductor
CN107078326B (en) 2014-05-12 2021-07-06 乔纳·莱迪 Electrochemical lanthanide and actinide
JP6044588B2 (en) * 2014-05-15 2016-12-14 トヨタ自動車株式会社 Sulfide solid electrolyte material, battery, and method for producing sulfide solid electrolyte material
JP6044587B2 (en) * 2014-05-15 2016-12-14 トヨタ自動車株式会社 Sulfide solid electrolyte material, battery, and method for producing sulfide solid electrolyte material
CN105226323B (en) 2014-06-09 2017-12-01 宁德新能源科技有限公司 Battery core and preparation method thereof
JP2017522725A (en) 2014-06-16 2017-08-10 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア Hybrid electrochemical cell
WO2015195595A1 (en) 2014-06-17 2015-12-23 Medtronic, Inc. Semi-solid electrolytes for batteries
US9716265B2 (en) 2014-08-01 2017-07-25 Apple Inc. High-density precursor for manufacture of composite metal oxide cathodes for Li-ion batteries
KR102563670B1 (en) 2014-09-09 2023-08-03 시온 파워 코퍼레이션 Protective layers in lithium-ion electrochemical cells and associated electrodes and methods
KR102493741B1 (en) 2014-10-23 2023-01-30 시온 파워 코퍼레이션 Ion-conductive composite for electrochemical cells
US10333173B2 (en) 2014-11-14 2019-06-25 Medtronic, Inc. Composite separator and electrolyte for solid state batteries
EA038167B1 (en) 2014-11-18 2021-07-19 Дзе Риджентс Оф Дзе Юниверсити Оф Калифорния Porous interconnected corrugated carbon-based network (iccn) composite
US11749834B2 (en) 2014-12-02 2023-09-05 Polyplus Battery Company Methods of making lithium ion conducting sulfide glass
US10147968B2 (en) 2014-12-02 2018-12-04 Polyplus Battery Company Standalone sulfide based lithium ion-conducting glass solid electrolyte and associated structures, cells and methods
US10601071B2 (en) 2014-12-02 2020-03-24 Polyplus Battery Company Methods of making and inspecting a web of vitreous lithium sulfide separator sheet and lithium electrode assemblies
US10164289B2 (en) 2014-12-02 2018-12-25 Polyplus Battery Company Vitreous solid electrolyte sheets of Li ion conducting sulfur-based glass and associated structures, cells and methods
US9722279B2 (en) 2014-12-24 2017-08-01 Toyota Motor Engineering & Manufacturing North America, Inc. All-solid-state metal-metal battery comprising ion conducting ceramic as electrolyte
US10008739B2 (en) 2015-02-23 2018-06-26 Front Edge Technology, Inc. Solid-state lithium battery with electrolyte
WO2016160703A1 (en) 2015-03-27 2016-10-06 Harrup Mason K All-inorganic solvents for electrolytes
DE102015208435A1 (en) * 2015-05-06 2016-11-10 Robert Bosch Gmbh Separator for a battery cell and battery cell
KR102364845B1 (en) * 2015-05-18 2022-02-18 삼성전자주식회사 Lithium air battery and preparation method thereof
JP6964003B2 (en) 2015-05-20 2021-11-10 シオン・パワー・コーポレーション Protective layer for electrodes
KR20180021797A (en) 2015-06-24 2018-03-05 콴텀스케이프 코포레이션 Composite electrolyte
WO2017048341A1 (en) * 2015-09-14 2017-03-23 Nanotek Instruments, Inc. Alkali metal or alkali-ion batteries having high volumetric and gravimetric energy densities
US9735445B2 (en) 2015-09-14 2017-08-15 Nanotek Instruments, Inc. Alkali metal or alkali-ion batteries having high volumetric and gravimetric energy densities
WO2017058650A1 (en) 2015-09-30 2017-04-06 Hongli Dai Cathode-active materials, their precursors, and methods of preparation
EP3368640B1 (en) * 2015-10-26 2019-06-26 Shell International Research Maatschappij B.V. Fluid comprising methane and a tracer, and processes for producing it and the use thereof
WO2017091341A1 (en) 2015-11-24 2017-06-01 Sion Power Corporation Ionically conductive compounds and related uses
WO2017096258A1 (en) 2015-12-02 2017-06-08 California Institute Of Technology Three-dimensional ion transport networks and current collectors for electrochemical cells
US10163540B2 (en) 2015-12-03 2018-12-25 Nanotek Instruments, Inc. Production process for highly conducting and oriented graphene film
EP3384548A4 (en) 2015-12-04 2019-07-24 QuantumScape Corporation Lithium, phosphorus, sulfur, and iodine including electrolyte and catholyte compositions, electrolyte membranes for electrochemical devices, and annealing methods of making these electrolytes and catholytes
JP6763965B2 (en) 2015-12-21 2020-09-30 ジョンソン・アイピー・ホールディング・エルエルシー Solid-state batteries, separators, electrodes and manufacturing methods
JP7176735B2 (en) 2015-12-22 2022-11-22 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア cellular graphene membrane
US10218044B2 (en) 2016-01-22 2019-02-26 Johnson Ip Holding, Llc Johnson lithium oxygen electrochemical engine
CN108475590B (en) 2016-01-22 2021-01-26 加利福尼亚大学董事会 High voltage device
WO2017160856A1 (en) 2016-03-14 2017-09-21 Apple Inc. Cathode active materials for lithium-ion batteries
AU2017238201B2 (en) 2016-03-23 2022-01-27 Nanotech Energy, Inc. Devices and methods for high voltage and solar applications
US10587005B2 (en) 2016-03-30 2020-03-10 Wildcat Discovery Technologies, Inc. Solid electrolyte compositions
KR101926784B1 (en) * 2016-03-31 2018-12-07 코오롱인더스트리 주식회사 Ion exchanging membrane, method for manufacturing the same and energy storage system comprising the same
US10622163B2 (en) 2016-04-01 2020-04-14 The Regents Of The University Of California Direct growth of polyaniline nanotubes on carbon cloth for flexible and high-performance supercapacitors
KR102601602B1 (en) * 2016-04-11 2023-11-14 삼성전자주식회사 Composite solid electrolyte, protected anode and lithium battery including the same, and method of preparing the composite solid electrolyte
US10818909B2 (en) 2016-05-09 2020-10-27 Demaray, Llc Energy storage device with a first metal layer formed from a precursor layer upon charge and diffused into a cathode during discharge
WO2017197039A1 (en) * 2016-05-10 2017-11-16 Polyplus Battery Company Solid-state laminate electrode assemblies and methods of making
CN107365151B (en) * 2016-05-12 2021-01-01 中国科学院宁波材料技术与工程研究所 Dense submicron crystal beta' -Al2O3Article, method of making and use thereof
JP7049269B2 (en) 2016-05-20 2022-04-06 シオン・パワー・コーポレーション Protective layer for electrodes and electrochemical battery
US11097951B2 (en) 2016-06-24 2021-08-24 The Regents Of The University Of California Production of carbon-based oxide and reduced carbon-based oxide on a large scale
CN106025402B (en) * 2016-07-07 2018-09-07 苏州氢洁电源科技有限公司 A kind of on-line detecting system of bipolar plates leakproofness
KR101984722B1 (en) * 2016-07-21 2019-05-31 주식회사 엘지화학 Lithium Secondary Battery containing Cathod Active Material Synthesizing Lithium Cobalt Oxide, Manufacturing Method Thereof
US9972838B2 (en) 2016-07-29 2018-05-15 Blue Current, Inc. Solid-state ionically conductive composite electrodes
CN110462889A (en) * 2016-07-29 2019-11-15 麻省理工学院 Lithium ion thin film micro cell and its manufacturing method
KR102626915B1 (en) 2016-08-02 2024-01-18 삼성전자주식회사 Composite membrane, preparing method thereof, and lithium secondary battery including the anode structure
WO2018044952A1 (en) 2016-08-29 2018-03-08 Quantumscape Corporation Catholytes for solid state rechargeable batteries, battery architectures suitable for use with these catholytes, and methods of making and using the same
EA201990587A1 (en) 2016-08-31 2019-07-31 Дзе Риджентс Оф Дзе Юнивёрсити Оф Калифорния DEVICES CONTAINING CARBON-BASED MATERIALS AND THEIR PRODUCTION
US10804563B2 (en) 2016-09-08 2020-10-13 Iowa State University Research Foundation, Inc. Oxy-thio-nitride mixed network former solid electrolytes
WO2018052371A1 (en) * 2016-09-13 2018-03-22 National University Of Singapore Solid electrolyte
WO2018057584A1 (en) 2016-09-20 2018-03-29 Apple Inc. Cathode active materials having improved particle morphologies
KR102223565B1 (en) 2016-09-21 2021-03-04 애플 인크. Surface-stabilized cathode material for lithium-ion battery and method for its synthesis
US10707531B1 (en) 2016-09-27 2020-07-07 New Dominion Enterprises Inc. All-inorganic solvents for electrolytes
KR20190055842A (en) 2016-10-07 2019-05-23 더 리젠츠 오브 더 유니버시티 오브 미시건 Stabilizing Coatings for Solid State Batteries
EP3529847A1 (en) 2016-10-21 2019-08-28 QuantumScape Corporation Electrolyte separators including lithium borohydride and composite electrolyte separators of lithium-stuffed garnet and lithium borohydride
WO2018081224A1 (en) * 2016-10-26 2018-05-03 The Regents Of The University Of Michigan Metal infiltrated electrodes for solid state batteries
WO2018081808A1 (en) 2016-10-31 2018-05-03 The Regents Of The University Of California Lithium and sodium superionic conductors
CA3043171A1 (en) * 2016-11-08 2018-05-17 Fisker Inc. All-solid-state li ion batteries comprising mechanically flexible ceramic electrolytes and manufacturing methods for the same
CN108258305B (en) 2016-12-28 2020-08-18 财团法人工业技术研究院 Electrolyte and battery
DE102016226291A1 (en) * 2016-12-29 2018-07-05 Robert Bosch Gmbh Protective layer with improved contacting for lithium cells and / or lithium batteries
US20180254518A1 (en) 2017-03-03 2018-09-06 Blue Current, Inc. Polymerized in-situ hybrid solid ion-conductive compositions
US10457781B2 (en) 2017-03-03 2019-10-29 Blue Current, Inc. Polymerized in-situ hybrid solid ion-conductive compositions
CN108630894A (en) * 2017-03-23 2018-10-09 株式会社东芝 Secondary cell, battery pack and vehicle
JP7326163B2 (en) 2017-05-24 2023-08-15 シオン・パワー・コーポレーション Ionically conductive compound and related uses
US10868293B2 (en) 2017-07-07 2020-12-15 Polyplus Battery Company Treating sulfide glass surfaces and making solid state laminate electrode assemblies
US10629950B2 (en) 2017-07-07 2020-04-21 Polyplus Battery Company Encapsulated sulfide glass solid electrolytes and solid-state laminate electrode assemblies
KR102563188B1 (en) 2017-07-14 2023-08-02 더 리전트 오브 더 유니버시티 오브 캘리포니아 A Simple Route from Carbon Nanoparticles to Highly Conductive Porous Graphene for Supercapacitor Applications
US10862171B2 (en) 2017-07-19 2020-12-08 Polyplus Battery Company Solid-state laminate electrode assembly fabrication and making thin extruded lithium metal foils
JP6833648B2 (en) * 2017-09-20 2021-02-24 株式会社東芝 Rechargeable batteries, battery packs and vehicles
WO2019150083A1 (en) * 2018-02-01 2019-08-08 Thermal Ceramics Uk Limited Energy storage device and ionic conducting composition for use therein
US10957886B2 (en) 2018-03-14 2021-03-23 Front Edge Technology, Inc. Battery having multilayer protective casing
EP3776692A4 (en) * 2018-04-06 2021-12-29 Celgard, LLC Solid state batteries, sse batteries, lithium metal batteries with solid state electrolytes, hsse, separators, and/or coatings, and/or related methods
US11695108B2 (en) 2018-08-02 2023-07-04 Apple Inc. Oxide mixture and complex oxide coatings for cathode materials
US11167375B2 (en) 2018-08-10 2021-11-09 The Research Foundation For The State University Of New York Additive manufacturing processes and additively manufactured products
US11749799B2 (en) 2018-08-17 2023-09-05 Apple Inc. Coatings for cathode active materials
JP7033041B2 (en) * 2018-09-27 2022-03-09 太陽誘電株式会社 All-solid-state battery and its manufacturing method
CN109301316B (en) * 2018-09-28 2020-12-08 苏州清陶新能源科技有限公司 Organic-inorganic composite electrolyte, preparation method thereof and application thereof in solid lithium ion secondary battery
US11453772B2 (en) 2018-09-30 2022-09-27 Robert Bosch Gmbh Polymer compositions based on PXE
US11658336B2 (en) 2018-11-30 2023-05-23 Samsung Electronics Co., Ltd. Lithium-ion solid state conductor containing a compound of Li1+(4-a)αHf2-αMaα(PO4-δ)3, Electrode and battery including the conductor, and methods of manufacture thereof
CN109742357B (en) * 2019-01-03 2021-12-10 浙江锋锂新能源科技有限公司 Composite anode material, preparation method thereof and anode plate containing anode material
US11581570B2 (en) 2019-01-07 2023-02-14 Blue Current, Inc. Polyurethane hybrid solid ion-conductive compositions
EP3942631A1 (en) 2019-03-20 2022-01-26 FMC Lithium USA Corp. Battery utilizing printable lithium
CN110707268B (en) * 2019-04-24 2022-01-11 中南大学 SiO 2-polymer composite water-based battery diaphragm material and preparation method and application thereof
CN110137566B (en) * 2019-05-21 2021-06-08 哈尔滨工业大学 Method for inhibiting lithium dendrite on solid electrolyte interface and application
CN110247112A (en) * 2019-06-25 2019-09-17 哈尔滨工业大学 A kind of high wettability sulfide based composite electrolyte and the preparation method and application thereof of " sandwich " structure
CN114342146A (en) * 2019-07-01 2022-04-12 A123系统有限责任公司 System and method for a composite solid state battery cell with an ion conducting polymer electrolyte
US11063271B2 (en) 2019-07-31 2021-07-13 Nissan North America, Inc. Electrolyte with embedded metal for solid oxide electrochemical devices
US11757096B2 (en) 2019-08-21 2023-09-12 Apple Inc. Aluminum-doped lithium cobalt manganese oxide batteries
US10938032B1 (en) 2019-09-27 2021-03-02 The Regents Of The University Of California Composite graphene energy storage methods, devices, and systems
US11929523B2 (en) 2019-11-19 2024-03-12 Sion Power Corporation Batteries, and associated systems and methods
US11791511B2 (en) 2019-11-19 2023-10-17 Sion Power Corporation Thermally insulating compressible components for battery packs
CN112909327A (en) * 2019-12-04 2021-06-04 中国科学院宁波材料技术与工程研究所 Ultrathin sulfide electrolyte sheet supported by porous ceramic, and preparation method and application thereof
CN115336039A (en) 2019-12-20 2022-11-11 蓝色电流股份有限公司 Composite electrolyte with binder
US11394054B2 (en) 2019-12-20 2022-07-19 Blue Current, Inc. Polymer microspheres as binders for composite electrolytes
US11631889B2 (en) 2020-01-15 2023-04-18 Polyplus Battery Company Methods and materials for protection of sulfide glass solid electrolytes
KR20220144387A (en) 2020-02-19 2022-10-26 리벤트 유에스에이 코포레이션 Fast Charge Pre-Lithium Silicon Anode
US11923495B2 (en) 2020-03-13 2024-03-05 Sion Power Corporation Application of pressure to electrochemical devices including deformable solids, and related systems
US20220115693A1 (en) * 2020-10-08 2022-04-14 Ut-Battelle, Llc Method of manufacturing a thin film composite solid electrolyte
KR20220089368A (en) * 2020-12-21 2022-06-28 삼성전자주식회사 A cathode material, cathode including the same, and lithium air battery including the same
CN112899746B (en) * 2021-02-05 2022-04-08 南京理工大学 Method for reducing electrostatic sensitivity of cuprous azide film

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040191617A1 (en) * 2002-10-15 2004-09-30 Polyplus Battery Company Ionically conductive membranes for protection of active metal anodes and battery cells
US6835492B2 (en) * 2001-05-31 2004-12-28 Samsung Sdi Co., Ltd. Method for forming lithium metal anode protective layer for lithium battery and lithium battery having such protective layer
US20050175894A1 (en) * 2004-02-06 2005-08-11 Polyplus Battery Company Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture

Family Cites Families (146)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3528856A (en) 1966-08-29 1970-09-15 Energy Conversion Devices Inc Thermoelectric device and method of manufacture
US3607417A (en) 1967-12-04 1971-09-21 Ionics Battery cell
US3615835A (en) 1969-01-16 1971-10-26 Energy Conversion Devices Inc Generation of dc voltage
US3625769A (en) 1969-03-21 1971-12-07 Gulton Ind Inc Fuel cell
US3912536A (en) 1971-03-27 1975-10-14 Montedison Spa Negative electrode for solid electrolyte cells
US3703415A (en) 1971-06-01 1972-11-21 Gen Electric Primary sodium-water battery
US3976509A (en) 1975-04-04 1976-08-24 Lockheed Missiles & Space Company, Inc. Electrolyte compositions
US4007057A (en) 1975-12-29 1977-02-08 Lockheed Missiles & Space Company, Inc. Cell comprising an alkali metal and aqueous electrolyte
US4091182A (en) 1976-03-01 1978-05-23 General Electric Company Sealed lithium electrochemical cell with sodium beta-alumina electrolyte
US4162202A (en) 1976-03-08 1979-07-24 P. R. Mallory & Co. Inc. Means for improving contact between Li and the anode current collector
US4163084A (en) 1978-07-27 1979-07-31 Lockheed Missiles & Space Company, Inc. Electrochemically stable cathode
US4210707A (en) 1978-11-20 1980-07-01 General Electric Company Sealed lithium-type electrochemical cell
DE2930056A1 (en) 1979-07-25 1981-02-12 Varta Batterie GALVANIC PRIME ELEMENT
US4248682A (en) 1979-09-27 1981-02-03 Prototech Company Carbon-cloth-based electrocatalytic gas diffusion electrodes, assembly and electrochemical cells comprising the same
US4405416A (en) 1980-07-18 1983-09-20 Raistrick Ian D Molten salt lithium cells
US4402995A (en) 1982-01-28 1983-09-06 Ray-O-Vac Corporation Treatment of lithium anodes
JPS5931573A (en) 1982-08-16 1984-02-20 Nippon Telegr & Teleph Corp <Ntt> Negative electrode for lithium battery
US4414293A (en) 1982-09-20 1983-11-08 The United States Of America As Represented By The United States Department Of Energy Parasitic corrosion resistant anode for use in metal/air or metal/O2 cells
DE3244824C2 (en) 1982-12-03 1985-10-24 Chamotte- u. Tonwerk Kurt Hagenburger, 6719 Hettenleidelheim Pouring device for pouring molten metal and method for pouring the same
US4440836A (en) 1982-12-14 1984-04-03 Union Carbide Corporation Nonaqueous cell employing an anode having a boron-containing surface film
US4981672A (en) 1983-06-27 1991-01-01 Voltaix, Inc. Composite coating for electrochemical electrode and method
US5591315A (en) 1987-03-13 1997-01-07 The Standard Oil Company Solid-component membranes electrochemical reactor components electrochemical reactors use of membranes reactor components and reactor for oxidation reactions
US4828942A (en) 1987-08-27 1989-05-09 Massachusetts Institute Of Technology Polysulfide battery
US4833048A (en) 1988-03-31 1989-05-23 The United States Of America As Represented By The United States Department Of Energy Metal-sulfur type cell having improved positive electrode
US4916036A (en) 1988-10-20 1990-04-10 Dreisbach Electromotive, Inc. Continuous consumable anode
US4985317A (en) 1988-11-30 1991-01-15 Japan Synthetic Rubber Co., Ltd. Lithium ion-conductive solid electrolyte containing lithium titanium phosphate
US5108856A (en) 1989-03-13 1992-04-28 Westinghouse Electric Corp. Electrolyte compositions and methods
US4917974A (en) 1989-04-14 1990-04-17 The United States Of America As Represented By The Department Of Energy Lithium/organosulfur redox cell having protective solid electrolyte barrier formed on anode and method of making same
US5162175A (en) 1989-10-13 1992-11-10 Visco Steven J Cell for making secondary batteries
US5035963A (en) 1990-09-11 1991-07-30 The United States Of America As Represented By The Secretary Of The Army High temperature rechargeable molten salt battery
US5427873A (en) 1990-09-14 1995-06-27 Westinghouse Electric Corporation Lithium-water battery
US5525442A (en) 1990-09-14 1996-06-11 Westinghouse Electric Corporation Alkali metal battery
US5166011A (en) 1990-11-07 1992-11-24 Alupower, Inc. Process for forming an argentic oxide containing bipolar electrode and product produced thereby and deferred actuated battery assembly employing same
US5100523A (en) 1990-12-17 1992-03-31 Ford Motor Company Use of amorphous carbon to promote adhesion between electroactive polymer films and conductive substrates
JP2535748B2 (en) 1991-03-04 1996-09-18 工業技術院長 Lithium recovery method
US5213908A (en) 1991-09-26 1993-05-25 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Alkali metal carbon dioxide electrochemical system for energy storage and/or conversion of carbon dioxide to oxygen
US5336384A (en) 1991-11-14 1994-08-09 The Dow Chemical Company Membrane-electrode structure for electrochemical cells
US5696201A (en) 1992-04-06 1997-12-09 Matec Holding Ag Sound and heat insulation having little odor
US5338625A (en) 1992-07-29 1994-08-16 Martin Marietta Energy Systems, Inc. Thin film battery and method for making same
CA2110097C (en) 1992-11-30 2002-07-09 Soichiro Kawakami Secondary battery
US5413881A (en) 1993-01-04 1995-05-09 Clark University Aluminum and sulfur electrochemical batteries and cells
US5409786A (en) 1993-02-05 1995-04-25 Eveready Battery Company, Inc. Inactive electrochemical cell having an ionically nonconductive polymeric composition activated by electrolyte salt solution
EP0614239A3 (en) 1993-03-01 1996-10-16 Tadiran Ltd Non-aqueous safe secondary cell.
US5342710A (en) 1993-03-30 1994-08-30 Valence Technology, Inc. Lakyer for stabilization of lithium anode
US5387479A (en) 1993-06-16 1995-02-07 Valence Technology, Inc. Electrodes for rechargeable lithium batteries
US5314765A (en) 1993-10-14 1994-05-24 Martin Marietta Energy Systems, Inc. Protective lithium ion conducting ceramic coating for lithium metal anodes and associate method
US5569520A (en) 1994-01-12 1996-10-29 Martin Marietta Energy Systems, Inc. Rechargeable lithium battery for use in applications requiring a low to high power output
US5961672A (en) 1994-02-16 1999-10-05 Moltech Corporation Stabilized anode for lithium-polymer batteries
US5648187A (en) 1994-02-16 1997-07-15 Moltech Corporation Stabilized anode for lithium-polymer batteries
ES2080686B1 (en) 1994-02-16 1996-10-16 S E De Carburos Metalicos S A ELECTROLYTIC DEPURATION PROCESS AND EQUIPMENT IN CONTAMINATED WASTEWATER USING OXYGEN CATODES.
IL109845A (en) 1994-06-01 1998-08-16 Tadiran Ltd Rechargeable electrochemical cell
US5516598A (en) 1994-07-28 1996-05-14 Polyplus Battery Company, Inc. Secondary cell using organosulfur/metal charge transfer materials as positive electrode
US5571600A (en) 1994-11-07 1996-11-05 Clark University Sulfur/aluminum electrochemical batteries
US6376123B1 (en) 1994-11-23 2002-04-23 Polyplus Battery Company Rechargeable positive electrodes
US6025094A (en) 1994-11-23 2000-02-15 Polyplus Battery Company, Inc. Protective coatings for negative electrodes
US5814420A (en) 1994-11-23 1998-09-29 Polyplus Battery Company, Inc. Rechargeable positive electrodes
US6358643B1 (en) 1994-11-23 2002-03-19 Polyplus Battery Company Liquid electrolyte lithium-sulfur batteries
US6017651A (en) 1994-11-23 2000-01-25 Polyplus Battery Company, Inc. Methods and reagents for enhancing the cycling efficiency of lithium polymer batteries
US5523179A (en) 1994-11-23 1996-06-04 Polyplus Battery Company Rechargeable positive electrode
US5686201A (en) 1994-11-23 1997-11-11 Polyplus Battery Company, Inc. Rechargeable positive electrodes
US6030720A (en) 1994-11-23 2000-02-29 Polyplus Battery Co., Inc. Liquid electrolyte lithium-sulfur batteries
US5582623A (en) 1994-11-23 1996-12-10 Polyplus Battery Company, Inc. Methods of fabricating rechargeable positive electrodes
US5510209A (en) 1995-01-05 1996-04-23 Eic Laboratories, Inc. Solid polymer electrolyte-based oxygen batteries
US5792335A (en) 1995-03-13 1998-08-11 Magnesium Technology Limited Anodization of magnesium and magnesium based alloys
DE69630298T2 (en) 1995-05-03 2004-09-02 Pinnacle Vrb Limited, Melbourne METHOD FOR PRODUCING A VANADIUM ELECTROLYTE FOR WHOLE VANADIUM REDOX CELLS AND BATTERIES WITH HIGH ENERGY DENSITY
US5665481A (en) 1995-11-14 1997-09-09 Northrop Grumman Corporation Metal-air battery
US5652068A (en) 1995-11-14 1997-07-29 Northrop Grumman Corporation Metal-air battery with improved air supply
US7211532B2 (en) 1995-11-15 2007-05-01 Kabushiki Kaisha Ohara Alkali ion conductive glass-ceramics and electric cells and gas sensors using the same
US5702995A (en) 1995-11-15 1997-12-30 Kabushiki Kaisha Ohara Lithium ion conductive glass-ceramics
US6315881B1 (en) 1995-11-15 2001-11-13 Kabushiki Kaisha Ohara Electric cells and gas sensors using alkali ion conductive glass ceramic
US6306509B2 (en) * 1996-03-21 2001-10-23 Showa Denko K.K. Ion conductive laminate and production method and use thereof
WO1997048145A1 (en) 1996-06-14 1997-12-18 Moltech Corporation Composition useful in electrolytes of secondary battery cells
CN1204636C (en) 1996-10-21 2005-06-01 日本电池株式会社 Battery electrode and manufacture method thereof
EP1029828B1 (en) 1996-10-28 2003-02-26 Kabushiki Kaisha Ohara Lithium ion conductive glass-ceramics and electric cells and gas sensors using the same
US5882812A (en) 1997-01-14 1999-03-16 Polyplus Battery Company, Inc. Overcharge protection systems for rechargeable batteries
IL120557A (en) 1997-03-31 2000-07-16 Licht Stuart Zinc sulfur battery
JPH10302794A (en) 1997-04-30 1998-11-13 Matsushita Electric Ind Co Ltd Lithium secondary battery
KR100378004B1 (en) * 1997-06-10 2003-06-09 삼성에스디아이 주식회사 Glass-polymer composite electrolyte and method for producing the same
US6096447A (en) 1997-11-05 2000-08-01 Wilson Greatbatch Ltd. Phosphonate additives for nonaqueous electrolyte in alkali metal electrochemical cells
US6068950A (en) 1997-11-19 2000-05-30 Wilson Greatbatch Ltd. Organic phosphate additives for nonaqueous electrolyte in alkali metal electrochemical cells
US6402795B1 (en) 1998-02-18 2002-06-11 Polyplus Battery Company, Inc. Plating metal negative electrodes under protective coatings
IL124007A (en) * 1998-04-08 2001-08-26 Univ Ramot Long cycle-life alkali metal battery
US6214061B1 (en) 1998-05-01 2001-04-10 Polyplus Battery Company, Inc. Method for forming encapsulated lithium electrodes having glass protective layers
KR20010083043A (en) 1998-06-08 2001-08-31 추후제출 Multifunctional reactive monomers for safety protection of nonaqueous electrochemical cells
JP4745472B2 (en) 1998-07-16 2011-08-10 株式会社オハラ Lithium ion conductive glass ceramic, battery using the same, and gas sensor
US6200704B1 (en) 1998-09-01 2001-03-13 Polyplus Battery Company, Inc. High capacity/high discharge rate rechargeable positive electrode
US6210832B1 (en) 1998-09-01 2001-04-03 Polyplus Battery Company, Inc. Mixed ionic electronic conductor coatings for redox electrodes
US6537701B1 (en) 1998-09-03 2003-03-25 Polyplus Battery Company, Inc. Coated lithium electrodes
US6955866B2 (en) 1998-09-03 2005-10-18 Polyplus Battery Company Coated lithium electrodes
US6198701B1 (en) 1998-09-03 2001-03-06 Polyplus Battery Company, Inc. Electrochemical timer
US6110236A (en) 1998-09-11 2000-08-29 Polyplus Battery Company, Inc. Method of preparing electrodes having evenly distributed component mixtures
US6203942B1 (en) 1998-10-22 2001-03-20 Wilson Greatbatch Ltd. Phosphate additives for nonaqueous electrolyte rechargeable electrochemical cells
US6146787A (en) 1998-11-11 2000-11-14 Bechtel Bwxt Idaho, Llc Solid polymer battery electrolyte and reactive metal-water battery
US6194098B1 (en) 1998-12-17 2001-02-27 Moltech Corporation Protective coating for separators for electrochemical cells
US6200701B1 (en) 1999-01-25 2001-03-13 Wilson Greatbatch Ltd. Phosphonate additives for nonaqueous electrolyte in rechargeable cells
US6495285B2 (en) 1999-01-25 2002-12-17 Wilson Greatbatch Ltd. Phosphonate additives for nonaqueous electrolyte in rechargeable electrochemical cells
US6225002B1 (en) 1999-02-05 2001-05-01 Polyplus Battery Company, Inc. Dioxolane as a proctector for lithium electrodes
US6358651B1 (en) 1999-02-26 2002-03-19 Reveo, Inc. Solid gel membrane separator in rechargeable electrochemical cells
US6228527B1 (en) 1999-03-02 2001-05-08 The United States Of America As Represented By The Secretary Of The Navy Magnesium solution phase catholyte seawater electrochemical system
JP3643289B2 (en) 1999-04-30 2005-04-27 株式会社オハラ Glass ceramic composite electrolyte and lithium secondary battery
US6489055B1 (en) 1999-06-25 2002-12-03 Sanyo Electric Co., Ltd. Lithium secondary battery
DE19940069A1 (en) * 1999-08-24 2001-03-08 Basf Ag Process for the electrochemical production of an alkali metal from an aqueous solution
US6413284B1 (en) 1999-11-01 2002-07-02 Polyplus Battery Company Encapsulated lithium alloy electrodes having barrier layers
US6413285B1 (en) 1999-11-01 2002-07-02 Polyplus Battery Company Layered arrangements of lithium electrodes
US7771870B2 (en) 2006-03-22 2010-08-10 Sion Power Corporation Electrode protection in both aqueous and non-aqueous electrochemical cells, including rechargeable lithium batteries
US7247408B2 (en) 1999-11-23 2007-07-24 Sion Power Corporation Lithium anodes for electrochemical cells
US6797428B1 (en) 1999-11-23 2004-09-28 Moltech Corporation Lithium anodes for electrochemical cells
US6733924B1 (en) 1999-11-23 2004-05-11 Moltech Corporation Lithium anodes for electrochemical cells
US6296958B1 (en) 2000-03-08 2001-10-02 Metallic Power, Inc. Refuelable electrochemical power source capable of being maintained in a substantially constant full condition and method of using the same
MY158895A (en) 2000-05-19 2016-11-30 Monsanto Technology Llc Potassium glyphosate formulations
JP4626013B2 (en) 2000-06-08 2011-02-02 住友電気工業株式会社 Lithium secondary battery negative electrode
KR100366346B1 (en) 2000-06-16 2002-12-31 삼성에스디아이 주식회사 Negative active material for lithium secondary battery and method of preparing same
JP3988374B2 (en) 2000-10-06 2007-10-10 ソニー株式会社 Non-aqueous electrolyte secondary battery
US20020068220A1 (en) 2000-12-05 2002-06-06 Wyler Mark D. Electrochemical cell and negative electrode therefor
US6511772B2 (en) 2001-01-17 2003-01-28 Wilson Greatbatch Ltd. Electrochemical cell having an electrode with a phosphate additive in the electrode active mixture
US6632573B1 (en) 2001-02-20 2003-10-14 Polyplus Battery Company Electrolytes with strong oxidizing additives for lithium/sulfur batteries
US6537698B2 (en) 2001-03-21 2003-03-25 Wilson Greatbatch Ltd. Electrochemical cell having an electrode with a phosphonate additive in the electrode active mixture
US7070632B1 (en) 2001-07-25 2006-07-04 Polyplus Battery Company Electrochemical device separator structures with barrier layer on non-swelling membrane
US6766817B2 (en) 2001-07-25 2004-07-27 Tubarc Technologies, Llc Fluid conduction utilizing a reversible unsaturated siphon with tubarc porosity action
US6991662B2 (en) 2001-09-10 2006-01-31 Polyplus Battery Company Encapsulated alloy electrodes
KR100477744B1 (en) 2001-10-31 2005-03-18 삼성에스디아이 주식회사 Organic electrolytic solution and lithium secondary battery adopting the same
US6911280B1 (en) 2001-12-21 2005-06-28 Polyplus Battery Company Chemical protection of a lithium surface
GB2386126B (en) * 2002-03-06 2006-03-08 Ceres Power Ltd Forming an impermeable sintered ceramic electrolyte layer on a metallic foil substrate for solid oxide fuel cell
CA2424725A1 (en) 2002-04-08 2003-10-08 David D. Rendina Renewable, energetic, nanodimensional dispersion
US20080057386A1 (en) 2002-10-15 2008-03-06 Polyplus Battery Company Ionically conductive membranes for protection of active metal anodes and battery cells
US7645543B2 (en) 2002-10-15 2010-01-12 Polyplus Battery Company Active metal/aqueous electrochemical cells and systems
US7282302B2 (en) 2002-10-15 2007-10-16 Polyplus Battery Company Ionically conductive composites for protection of active metal anodes
US7282296B2 (en) 2002-10-15 2007-10-16 Polyplus Battery Company Ionically conductive composites for protection of active metal anodes
KR100590376B1 (en) 2003-03-20 2006-06-19 마쯔시다덴기산교 가부시키가이샤 An integrated battery
US7211351B2 (en) 2003-10-16 2007-05-01 Cymbet Corporation Lithium/air batteries with LiPON as separator and protective barrier and method
US7608178B2 (en) 2003-11-10 2009-10-27 Polyplus Battery Company Active metal electrolyzer
US7491458B2 (en) 2003-11-10 2009-02-17 Polyplus Battery Company Active metal fuel cells
US7691536B2 (en) 2004-02-20 2010-04-06 Excellatron Solid State, Llc Lithium oxygen batteries and method of producing same
WO2006025662A1 (en) * 2004-09-02 2006-03-09 Lg Chem, Ltd. Organic/inorganic composite porous film and electrochemical device prepared thereby
US20060063051A1 (en) 2004-09-20 2006-03-23 Jang Bor Z Metal-air battery with ion-conducting inorganic glass electrolyte
US7947405B2 (en) * 2004-09-29 2011-05-24 Giner Electrochemical Systems, Llc Solid polymer electrolyte composite membrane comprising porous ceramic support
US20060078790A1 (en) 2004-10-05 2006-04-13 Polyplus Battery Company Solid electrolytes based on lithium hafnium phosphate for active metal anode protection
US8129052B2 (en) 2005-09-02 2012-03-06 Polyplus Battery Company Polymer adhesive seals for protected anode architectures
US9580320B2 (en) 2005-10-13 2017-02-28 Ohara Inc. Lithium ion conductive solid electrolyte and method for manufacturing the same
US7771880B2 (en) 2005-11-21 2010-08-10 University Of Dayton Solid composite electrolyte membrane and method of making
WO2007062220A2 (en) 2005-11-23 2007-05-31 Polyplus Battery Company Li/air non-aqueous batteries
WO2007075867A2 (en) 2005-12-19 2007-07-05 Polyplus Battery Company Composite solid electrolyte for protection of active metal anodes
US20070231704A1 (en) 2006-03-30 2007-10-04 Ohara Inc. Lithium ion conductive solid electrolyte and production process thereof
US7807296B2 (en) 2006-08-23 2010-10-05 Roval, Inc. Copper-manganese mixed oxide cathode material for use in alkaline cells having high capacity
US20080124433A1 (en) * 2006-11-27 2008-05-29 Synrad, Inc. Food processing using laser radiation
US8673477B2 (en) 2008-06-16 2014-03-18 Polyplus Battery Company High energy density aqueous lithium/air-battery cells

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6835492B2 (en) * 2001-05-31 2004-12-28 Samsung Sdi Co., Ltd. Method for forming lithium metal anode protective layer for lithium battery and lithium battery having such protective layer
US20040191617A1 (en) * 2002-10-15 2004-09-30 Polyplus Battery Company Ionically conductive membranes for protection of active metal anodes and battery cells
US20050175894A1 (en) * 2004-02-06 2005-08-11 Polyplus Battery Company Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108878751B (en) * 2018-07-03 2021-07-30 宁德卓高新材料科技有限公司 Conductive ceramic composite diaphragm and solid-state battery

Also Published As

Publication number Publication date
US8652686B2 (en) 2014-02-18
US20120270112A1 (en) 2012-10-25
US20130344397A1 (en) 2013-12-26
US8182943B2 (en) 2012-05-22
US8334075B2 (en) 2012-12-18
WO2007075867A2 (en) 2007-07-05
US20070172739A1 (en) 2007-07-26

Similar Documents

Publication Publication Date Title
WO2007075867A3 (en) Composite solid electrolyte for protection of active metal anodes
WO2005083829A3 (en) Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture
WO2010005686A3 (en) Aqueous lithium/air battery cells
WO2005038953A3 (en) Active metal/aqueous electrochemical cells and systems
WO2018218057A3 (en) Ionically conductive compounds and related uses
WO2004036669A3 (en) Ionically conductive composites for protection of active metal anodes
WO2005038962A3 (en) Ionically conductive membranes for protection of active metal anodes and battery cells
WO2009097445A3 (en) Zinc anode battery using alkali ion conducting separator
EP1843416A4 (en) Fuel cell
WO2005048385A3 (en) Active metal fuel cells
DE602006019554D1 (en) Implantierbare batterie mit thermoabschaltseparator
WO2009085327A3 (en) Protective and precipitation layers for pem fuel cell
WO2006064344A3 (en) Lithium-ion battery and method for its manufacture
WO2005124916A3 (en) Processing techniques for the fabrication of solid acid fuel cell membrane electrode assemblies
WO2007062220A3 (en) Li/air non-aqueous batteries
WO2006105130A3 (en) Novel electrolytes to enhance oxygen reduction reaction (orr) in the cathode layer of pem fuel cell
WO2006088861A3 (en) Intercalation anode protection for cells with dissolved lithium polysulfides
EP2763211A3 (en) Notebook computer or personal computer comprising a lithium secondary battery with an organic/inorganic composite microporous membrane
WO2013087348A3 (en) Separator having a polysulphide barrier layer for lithium‑sulphur cells
WO2010071387A3 (en) High-power lithium secondary battery
WO2008036734A3 (en) Forming solid electrolyte interface layer on lithium-ion polymer battery electrode
WO2007116363A3 (en) Lithium rechargeable electrochemical cell
WO2004021486A3 (en) Fuel cell electrode
WO2004102694A3 (en) Polyimide based electrolyte and improved batteries therefrom
WO2008009992A3 (en) Fuel cells

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application
NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 06847902

Country of ref document: EP

Kind code of ref document: A2