WO2010090712A1 - Aliphatic polyester coating compositions containing tetramethyl cyclobutanediol - Google Patents
Aliphatic polyester coating compositions containing tetramethyl cyclobutanediol Download PDFInfo
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- WO2010090712A1 WO2010090712A1 PCT/US2010/000213 US2010000213W WO2010090712A1 WO 2010090712 A1 WO2010090712 A1 WO 2010090712A1 US 2010000213 W US2010000213 W US 2010000213W WO 2010090712 A1 WO2010090712 A1 WO 2010090712A1
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- C08G18/78—Nitrogen
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- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
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- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
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- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
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- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
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- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
- C08G18/4238—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
- C08G18/4241—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols from dicarboxylic acids and dialcohols in combination with polycarboxylic acids and/or polyhydroxy compounds which are at least trifunctional
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- C08K5/34—Heterocyclic compounds having nitrogen in the ring
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- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
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- C08L33/04—Homopolymers or copolymers of esters
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Definitions
- Coatings with high hardness typically exhibit high gloss, good distinctness of image (DOI), fast dry-times, scratch, stain, chemical, and humidity resistance, and outdoor durability.
- DOI good distinctness of image
- Aliphatic polyesters are frequently used to reduce viscosity and increase solids for thermosetting acrylic (abbreviated herein as "TSA”) coatings. Aliphatic polyesters also are useful as a primary film former in high solids coatings because of their ability to reduce volatile organic compound (“VOC”) emissions. Coatings made from aliphatic polyesters are generally flexible but tend to be soft, which results in poor resistance to solvents and chemicals, poor humidity resistance and poor outdoor durability.
- Hardness and hardness-related properties of aliphatic polyester resins sometimes can be improved with the addition of 1,4-cyclohexanedimethanol (abbreviated herein as "CHDM”) and hydrogenated bisphenol A (abbreviated herein as "HBPA”).
- CHDM 1,4-cyclohexanedimethanol
- HBPA hydrogenated bisphenol A
- TSA resins are widely used in industrial coatings. They can be formulated to a high glass transition temperature (Tg) and exhibit excellent light stability and hydrolysis resistance. These properties result in coatings with the desirable characteristics of high hardness; fast dry times; resistance to stains, chemicals and humidity; and good outdoor durability. Consequently, TSA resins often serve as the primary film-former in coatings for demanding applications that include transportation, maintenance, marine and building/construction markets.
- TSA resins exhibit many desirable properties, they often lack flexibility and require more solvent in the coating formulation to achieve a practical application viscosity.
- the higher solvent requirement for TSA resins makes it difficult to achieve high solids coatings with reduced VOC content as mandated by various federal and state air quality organizations.
- aliphatic polyester resins can be blended with TSA resins.
- Tg glass transition temperature
- the lower Tg of the blend has an adverse impact on the desirable characteristics that the TSA resin imparts to the coating.
- the present invention provides curable, aliphatic polyesters prepared from 2,2,4, 4-tetramethyl-l,3-cyclobutanediol.
- one embodiment of our invention is a curable, aliphatic polyester, comprising: i. diacid residues, comprising at least 90 mole percent, based on the total moles of diacid residues, of the residues of at least one aliphatic dicarboxylic acid, the aliphatic dicarboxylic acid comprising 50 to 100 mole percent of a cycloaliphatic dicarboxylic acid; ii.
- diol residues comprising 50 to 100 mole percent, based on the total moles of diol residues, of the residues of 2,2,4, 4-tetramethyl-l,3-cyclobutanediol; and iii. 2 to 40 mole percent of the residues of at least one polyol, based on the total moles of diol and polyol residues; wherein the curable, aliphatic polyester has a number average molecular weight of 300 to 10,000 daltons, a glass transition temperature of -35 0 C to 35°C, a hydroxyl number of 20 to 450 mg KOH/ g of polyester, and an acid number of 0 to 80 mg KOH / g of polyester.
- thermosetting coating composition comprising:
- diol residues comprising 50 to 100 mole percent, based on the total moles of diol residues, of the residues of 2,2,4,4-tetramethyl-l,3- cyclobutanediol; and iii. 2 to 40 mole percent of the residues of at least one polyol, based on the total moles of diol and polyol residues; wherein the curable, aliphatic polyester has a number average molecular weight of 300 to 10,000 daltons, a glass transition temperature of -35 0 C to 35°C, a hydroxyl number of 20 to 450 mg KOH/ g of polyester, and an acid number of 0 to 80 mg KOH / g of polyester;
- the aliphatic polyesters may be blended with acrylics or serve as the primary film former to formulate factory and field-applied coatings used in auto OEM, auto refinish, transportation, aerospace, maintenance, marine, machinery and equipment, general metal, appliance, metal furniture, plastic and building / construction applciations.
- TSA thermosetting acrylic
- curable, aliphatic polyesters that contain 2,2,4,4- tetramethyl-l,3-cyclobutanediol (abbreviated herein as "TMCD”) can be used to prepare solvent-borne, high-solids, thermosetting coatings that exhibit high gloss, good hardness and flexibility; and solvent and chemical resistance.
- TMCD 2,2,4,4- tetramethyl-l,3-cyclobutanediol
- TSA thermosetting acrylic resins
- diacid residues comprising at least 90 mole percent, based on the total moles of diacid residues, of the residues of at least one aliphatic dicarboxylic acid, the aliphatic dicarboxylic acid comprising 50 to 100 mole percent of a cycloaliphatic dicarboxylic acid; ii. diol residues, comprising 50 to 100 mole percent, based on the total moles of diol residues, of the residues of 2,2,4, 4-tetramethyl-l,3-cyclobutanediol; and iii.
- the curable, aliphatic polyester has a number average molecular weight of 300 to 10,000 daltons, a glass transition temperature of -35 0 C to 35°C, a hydroxyl number of 20 to 450 mg KOH/ g of polyester, and an acid number of 0 to 80 mg KOH / g of polyester.
- Another aspect of the invention is a solvent borne thermosetting coating formulation comprising the above aliphatic polyester resin.
- the coating formulation may, optionally, comprise a crosslinker, various additives and pigments.
- a range associated with chemical substituent groups such as, for example, "Ci to C 5 diols", is intended to specifically include and disclose C x and C 5 diols as well as C 2 , C 3 , and C 4 diols.
- curable, aliphatic polyester is synonymous with the term “resin” and is intended to mean a thermosetting surface coating polymer prepared by the polycondensation of one or more acid components, diol components, and polyol components.
- the curable, aliphatic polyester of the present invention is a thermoset polymer and is suitable as a resin for solvent-based coatings. This polyester has a low molecular weight, typically 300 to 10,000 daltons, and would not be suitable for the fabrication films, sheets, and other shaped objects by extrusion, casting, blow molding, and other thermoforming processes commonly used for high molecular weight thermoplastic polymers.
- the polyester has a reactive functional group, typically a hydroxyl group or carboxyl group for the purpose of later reacting with a crosslinker in a coating formulation.
- the functional group is controlled by having either excess diol or acid (from dicarboxylic acid or tricarboxylic acid) in the polyester resin composition.
- the desired crosslinking pathway will determine whether the polyester resin will be hydroxyl- terminated or carboxylic acid-terminated. This concept is known to those skilled in the art and described, for example, in Organic Coatings Science and Technology, 2nd ed., p. 246-257, by Z. Wicks, F. Jones, and S. Pappas, Wiley, New York, 1999.
- the acid component comprises at least one dicarboxylic acid and may, optionally, include mono- and polybasic carboxylic acids.
- the curable, aliphatic polyester may be prepared from an acid component comprising an aliphatic or cycloaliphatic dicarboxylic acid such as, for example, adipic acid or 1,3- cyclohexanedicarboxylic acid, or a mixture of one or more aliphatic and cycloaliphatic acids.
- the diol component may comprise one or more cycloaliphatic diols such as, for example, 2,2,4, 4-tetramethyl-l,3-cyclobutanediol, either alone or in combination with one or more linear or branched aliphatic diols such as, for example, neopentyl glycol. Catalysts may be used to accelerate the rate of the polycondensation reaction. Additional examples of each of the components of the curable, aliphatic polyester include those known in the art including, but not limited to, those discussed below, and in various documents known in the art such as, for example, in Resins for Surface Coatings, Vol. Ill, p. 63-167, ed. by P.K.T. Oldring and G. Hayward, SITA Technology, London, UK, 1987.
- cycloaliphatic diols such as, for example, 2,2,4, 4-tetramethyl-l,3-cyclobutanediol, either alone or in
- residue means any organic structure incorporated into a polymer through a polycondensation or ring opening reaction involving the corresponding monomer. It will also be understood by persons having ordinary skill in the art, that the residues associated within the various curable polyesters of the invention can be derived from the parent monomer compound itself or any derivative of the parent compound.
- the dicarboxylic acid residues referred to in the polymers of the invention may be derived from a dicarboxylic acid or its associated acid halides, esters, salts, anhydrides, or mixtures thereof.
- dicarboxylic acid is intended to include dicarboxylic acids and any derivative of a dicarboxylic acid, including its associated acid halides, esters, half-esters, salts, half-salts, anhydrides, mixed anhydrides, or mixtures thereof, useful in a polycondensation process with a diol to make a curable, aliphatic polyester.
- aliphatic is intended to have its common meaning as would be understood by persons having ordinary skill in the art, that is, acyclic or cyclic, saturated or unsaturated carbon compounds, excluding benzenoid or other aromatic systems.
- cycloaliphatic as used herein, is intended to mean an aliphatic, cyclic compound.
- aliphatic polyester as used herein, is understood to mean a polyester that contains 90 or greater mole percent aliphatic diacid or diol residues, based on the total moles of diacid or diol residues. Small amounts (i.e., 10 mole percent or less) of aromatic dicarboxylic acids or aromatic diols also may be present.
- the curable, aliphatic polyester comprises diacid residues, that comprise at least 90 mole percent, based on the total moles of diacid residues, of the residues of at least one aliphatic dicarboxylic acid which, in turn, comprises 50 to 100 mole percent of a cycloaliphatic dicarboxylic acid.
- aliphatic and cycloaliphatic dicarboxylic acids include, but are not limited to, adipic acid, dodecanedioic acid, sebacic acid, azelaic acid, 1,4-cyclohexanedicarboxylic acid, 1,3-cyclohexanedicarboxylic acid, hexahydrophthalic anhydride, tetrahydrophthalic anhydride succinic acid, glutaric acid, and combinations thereof.
- the curable, aliphatic polyester can comprise 50 mole percent of the residues of 1,4-cyclohexanedicarboxylic acid and 50 mole percent of the residues of adipic acid, based on the total moles of diacid residues.
- the curable, aliphatic polyester can contain 50 mole percent of the residues of hexahydrophthalic anhydride and 50 mole percent of the residues of adipic acid.
- diacid component of the curable, aliphatic polyester are as follows: (a) 50 to 85 mole percent of the residues of at least one diacid chosen from 1,4-cyclohexanedicarboxylic acid, 1,3- cyclohexanedicarboxylic acid, hexahydrophthalic anhydride, and combinations thereof; and 15 to 50 mole percent of the residues of at least one alicyclic aliphatic dicarboxylic acid having from 4 to 10 carbon atoms; (b) 50 to 85 mole percent of the residues of at least one diacid chosen from 1,4-cyclohexanedicarboxylic acid, hexahydrophthalic anhydride, and combinations thereof; and 15 to 50 mole percent of the residues of at least one diacid chosen from adipic acid, succinic acid, and glutaric acid; (c) 50 to 75 mole percent of the residues of at least one diacid chosen from 1,
- the diacid residues may further comprise from 0 to 10 mole percent of the residues of at least one aromatic dicarboxylic acid chosen from phthalic acid, terephthalic acid, isophthalic acid, 2,6-naphthalenedicarboxylic acid, and combinations thereof.
- the acid component of our inventive polyester composition may further comprise the residues of a monocarboxylic acid or a polybasic acid containing more that 2 carboxylic acid groups.
- the curable, aliphatic polyester may comprise residues of at least one monocarboxylic acid or a polybasic acid chosen from benzoic acid, acetic acid, 2-ethyl- hexanoic acid, propionic acid, tert-butyl benzoic acid, and butanoic acid; trimellitic anhydride; or a mixture thereof.
- the acid component can comprise the residues of at least one aliphatic tricarboxylic acid such as, for example, 1,2,4- cyclohexanetricarboxylic acid, 1,3,4-butanetricarboxylic acid, 1,2,5-hexanetricarboxylic acid, and mixtures of one or more of these acids.
- aliphatic tricarboxylic acid such as, for example, 1,2,4- cyclohexanetricarboxylic acid, 1,3,4-butanetricarboxylic acid, 1,2,5-hexanetricarboxylic acid, and mixtures of one or more of these acids.
- the curable, aliphatic polyester also comprises the residues of 2,2,4,4- tetramethyl-l,3-cyclobutanediol ("TMCD").
- TMCD 2,2,4,4- tetramethyl-l,3-cyclobutanediol
- the curable, aliphatic polyester can comprise 50 to 100 mole percent TMCD, based on the total moles of diol residues.
- Other representative examples of TMCD concentrations are 75 to 100 mole percent, and 85 to 100 mole percent.
- aliphatic diols in addition to TMCD, can be used to prepare the curable, aliphatic polyester of the instant invention.
- Representative examples of aliphatic diols include, but are not limited to, neopentyl glycol, ethylene glycol, propylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, pentaethylene glycol, hexaethylene glycol, heptaethylene glycol, octaethylene glycol, nonaethylene glycol, decaethylene glycol, 1,3-propanediol, 2,4-dimethyl-2-ethyl-hexane-l,3-diol, 2,2- dimethyl-l,2-propanediol, 2-ethyl-2-butyl-l,3-propanediol, 2-ethyl-2-isobutyl-l,3- propanediol, 1,2-butanediol, 1,3-
- the curable, aliphatic polyester resins comprise a combination of the residues of neopentyl glycol and TMCD.
- the diols listed above may be used in any combination with TMCD and the aforementioned diacid components and in any amount within the ranges described hereinabove [0026]
- the curable, aliphatic polyester can comprise (i) diacid residues comprising 50 to 85 mole percent of the residues of at least one c ⁇ cloaliphatic dicarboxylic acid chosen from 1,4-cyclohexanedicarboxylic acid, 1,3- cyclohexanedicarboxylic acid, hexahydrophthalic anhydride, and 15 to 50 mole percent of the residues at least one acylic aliphatic dicarboxylic acid chosen from dodecanedioic acid, adipic acid, sebacic acid, azelaic acid, maleic acid, fumaric
- the curable aliphatic polyester can comprise (i) diacid residues comprising 50 to 85 mole percent of the residues of 1,4- cyclohexanedicarboxylic acid, hexahydrophthalic anhydride, or a mixture thereof, and 15 to 50 mole percent of the residues of adipic acid; and (ii) diol residues comprising 50 to 100 mole percent of the residues of TMCD and 50 to 0 mole percent of the residues of neopentyl glycol.
- the curable, aliphatic polyester can comprise (i) diacid resides comprising 50 mole percent of the residues of hexahydrophthalic anhydride and 50 mole percent of the residues of adipic acid; and (ii) diol residues comprising 75 to 100 mole percent of the residues of 2,2,4, 4-tetramethyl-l,3- cyclobutanediol, and 25 to 0 mole percent of the residues of neopentyl glycol.
- the curable, aliphatic polyester comprises 2 to 40 mole percent of the residues of at least one polyol, based on the total moles of diol and polyol residues.
- polyols may include aliphatic, alicyclic, and cyclic alkyl polyols.
- polyols include, but are not limited to, trimethylolpropane (abbreviated herein as "TMP), pentaerythritol (abbreviated herein as “PE”), trimethylolethane (abbreviated herein as “TME”), erythritol, threitol, dipentaerythritol, sorbitol, glycerine, and the like.
- TMP trimethylolpropane
- PE pentaerythritol
- TME trimethylolethane
- erythritol erythritol
- threitol dipentaerythritol
- sorbitol glycerine
- the curable, aliphatic polyester can comprise 3 to 30 mole percent of the residues of at least one polyol selected from trimethylolpropane, pentaerythritol, trimethylolethane, erythritol, threitol, dipentaerythritol, sorbitol, and glycerine.
- the curable, aliphatic polyester comprises trimethylolpropane.
- the curable, aliphatic polyester of this invention has a hydroxyl number of 20 to 450 mg KOH/g resin. Further examples of hydroxyl number are 25 to 300, and 30 to 250.
- the curable, aliphatic polyester has an acid number of 0 to 80 mg KOH/g polyester or, in other examples, 2 to 25 mg KOH/g polyester, and 2 to 15 mg KOH/g polyester.
- the number average molecular weight of the curable, aliphatic polyester is 300 daltons to 10,000 daltons. Additional examples of molecular weight ranges are 400 to 7000, and 500 to 5000.
- the curable, aliphatic polyester has a glass transition temperature (abbreviated herein as "Tg") of -35 to 35°C.
- Tg ranges for the curable, aliphatic polyester are -35 to 30 0 C, -35 to 25°C, -35 to less than 20, -35 to 19 0 C, -35 to 18 0 C, -35 to 17 0 C, -35 to 16 0 C, -35 to 15 0 C, -35 to 1O 0 C.
- the curable, aliphatic polyester can have a hydroxyl number of 30 to 250 mg potassium hydroxide per gram of polyester, an acid number of 2 to 15 mg potassium hydroxide per gram of polyester, and a number average molecular weight of 700 to 7000 daltons, and a Tg of -20 to 2O 0 C.
- a further aspect of the invention is a curable, aliphatic polyester, consisting essentially of: i. diacid residues, consisting essentially of the residues of at least one aliphatic dicarboxylic acid, the aliphatic dicarboxylic acid comprising 50 to 100 mole percent, based on the total moles of diacid residues, of a cycloaliphatic dicarboxylic acid selected from residues of 1,4-cyclohexanedicarboxylic acid, hexahydrophthalic anhydride, or a mixture thereof; ii.
- diol residues consisting essentially of 75 to 100 mole percent, based on the total moles of diol residues, of the residues of 2,2,4,4-tetramethyl-l,3-cyclobutanediol; iii. 2 to 40 mole percent of the residues of at least one polyol, based on the total moles of diol and polyol residues; wherein the curable, aliphatic polyester has a number average molecular weight of 300 to 10,000 daltons, a glass transition temperature of -35 0 C to 35°C, a hydroxyl number of 20 to 450 mg KOH/ g of polyester, and an acid number of 0 to 80 mg KOH / g of polyester.
- the phrase "consisting essentially of”, as used herein is intended to encompass curable polyesters having components (i)-(iii) listed above and is understood to exclude any elements that would substantially alter the essential properties of the polyester to which the phrase refers.
- the diacid and diol residues may include other components that do not alter the solubility of the curable, aliphatic polyester and its compatibility with TSA resins.
- any combination of diol, diacid, and polyol monomers that would produce a resin having a Tg greater than 45 0 C would be understood in the art to reduce that solubility of a polyester polymer would be excluded from this embodiment.
- diacids and diols that would be expected to increase Tg and reduce solubility include, but are not limited to, cycloaliphatic diol or diacid components, and polycycloaliphatic diacids or diols.
- diacid and diol components that would be excluded from this embodiment are hydrogenated bisphenol A at 50 mole percent or greater and tetrahydrophthalic acid or anhydride at 25 mole percent or greater. All mole percentages are based upon the total moles of diacid or diol residues.
- compositions that would be included in the above embodiment are those, for example, in which the aliphatic polyester consists essentially of (i) diacid residues consisting essentially of 50 to 85 mole percent of the residues of at least one cycloaliphatic dicarboxylic acid chosen from 1,4- cyclohexanedicarboxylic acid, hexahydrophthalic anhydride, and 50 to 15 mole percent of the residues at least one acyclic aliphatic dicarboxylic acid chosen from adipic acid, dodecanedioic acid, sebacic acid, azelaic acid, maleic acid, fumaric acid, succinic acid, and glutaric acid; and (ii) diol residues consisting essentially of 75 to 100 mole percent of the residues of 2,2,4,4-tetramethyl-l,3-cyclobutanediol and 25 to 0 mole percent of the residues of at least one diol
- the curable aliphatic polyester consists essentially of (i) diacid residues consisting essentially of 50 to 85 mole percent of the residues of 1,4- cyclohexanedicarboxylic acid, hexahydrophthalic anhydride, or a mixture thereof, and 15 to 50 mole percent of the residues of adipic acid; and (ii) diol residues consisting essentially of 75 to 100 mole percent of the residues of TMCD and 25 to 0 mole percent of the residues of neopentyl glycol.
- the curable, aliphatic polyester can consist essentially of (i) diacid resides consisting essentially of 50 mole percent of the residues of hexahydrophthalic anhydride and 50 mole percent of the residues of adipic acid; and (ii) diol residues consisting essentially of 75 to 100 mole percent of the residues of 2,2,4,4-tetramethyl-l,3-cyclobutanediol, and 25 to 0 mole percent of the residues of neopentyl glycol.
- the curable, aliphatic polyester has a glass transition temperature (abbreviated herein as "Tg") of -35 to 35 0 C.
- Tg ranges for the curable, aliphatic polyester are -35 to 30 0 C, -35 to 25°C, -35 to less than 20, -35 to 19 0 C, -35 to 18 0 C, -35 to 17 0 C, -35 to 16 0 C, -35 to 15 0 C, -35 to 10 0 C.
- the curable, aliphatic polyester can be prepared by heating the reactants until the desired molecular weight, acid number, or hydroxyl number is reached.
- the reaction can be monitored by the collection of water (when diacids are used as starting materials) or alcohol (when diesters are used).
- the polyester typically can be prepared at a temperature range of 150 to 250 0 C and at atmospheric pressure or under vacuum. In one embodiment, for example, the diacid and diol components of the polyester may be partially reacted before the polyol is added. Once the polyol is added to the reaction mixture, heating is continued until a target acid number is satisfied.
- the curable, aliphatic polyester can be prepared in the presence of a process solvent to help remove the water or alcohol by-products of the reaction and to promote the synthesis of the polyester resin.
- the process solvent may be any solvent known in the art as useful for the preparation of polyester polymers.
- the process solvent can be a hydrocarbon solvent.
- the process solvent can comprise an aromatic hydrocarbon such as, for example, xylene.
- the xylene can be a pure isomer, or a mixture of ortho, meta, and para isomers.
- the amount of process solvent may be determined by routine experimentation as understood by those skilled in the art.
- the process solvent can be added in amounts ranging from 0.5 to 5 weight percent, based on the total weight of reaction mixture.
- a catalyst may be used to promote the synthesis of the polyester.
- the catalyst may be any catalyst known in the art to be useful for the formation of polyester resins.
- the catalyst can be a tin catalyst, such as, for example, FASCATTM 4100 (available from Arkema Corporation).
- the catalyst increases the rate of the polyester resin reaction, as described above, and its amount may be determined by routine experimentation as understood by those skilled in the art. Ordinarily, the catalyst is added in amounts ranging from 0.01 to 1.00 weight percent based on the total weight of the reactants.
- Our invention also provides a coating composition comprising the various embodiments of the curable, aliphatic polyester resin containing 2,2,4,4-tetramethyl-l,3- cyclobutanediol (TMCD) as described above.
- TMCD 2,2,4,4-tetramethyl-l,3- cyclobutanediol
- another aspect of the present invention is a thermosetting coating composition, comprising: (A). 50 to 90 weight percent, based on the total weight of (A) and (B) of at least one curable, aliphatic polyester, comprising i.
- diacid residues comprising at least 90 mole percent, based on the total moles of diacid residues, of the residues of at least one aliphatic dicarboxylic acid, the aliphatic dicarboxylic acid comprising 50 to 100 mole percent of a cycloaliphatic dicarboxylic acid; ii. diol residues, comprising 50 to 100 mole percent, based on the total moles of diol residues, of the residues of 2,2,4, 4-tetramethyl-l,3- cyclobutanediol; and iii.
- the curable, aliphatic polyester has a number average molecular weight of 300 to 10,000 daltons, a glass transition temperature of -35 0 C to 35°C, a hydroxyl number of 20 to 450 mg KOH/ g of polyester, and an acid number of 0 to 80 mg KOH / g of polyester;
- B 10 to 50 weight percent, based on the total weight of (A) and (B) of a crosslinker comprising at least one compound reactive with a carboxylic acid or a hydroxyl group;
- C 10 to 60 weight percent, based on the total weight of (A), (B), and (C) of at least one nonaqueous solvent.
- the curable, aliphatic polyester component of coating composition may include any combination of the various embodiments of diacids, diols, polyols, acid and hydroxyl numbers, and glass transition temperatures described hereinabove in accordance with the present invention.
- the curable, aliphatic polyester can comprise 50 mole percent of the residues of 1,4-cyclohexanedicarboxylic acid and 50 mole percent of the residues of adipic acid, based on the total moles of diacid residues.
- the curable, aliphatic polyester can contain 50 mole percent of the residues of hexahydrophthalic anhydride and 50 mole percent of the residues of adipic acid.
- diacid component of curable, aliphatic polyester are as follows: (a) 50 to 85 mole percent of the residues of at least one diacid chosen from 1,4-cyclohexanedicarboxylic acid, 1,3-cyclohexanedicarboxylic acid, hexahydrophthalic anhydride, and combinations thereof; and 15 to 50 mole percent of the residues of at least one alicyclic aliphatic dicarboxylic acid having from 4 to 10 carbon atoms; (b) 50 to 85 mole percent of the residues of at least one diacid chosen from 1,4-cyclohexanedicarboxylic acid, hexahydrophthalic anhydride, and combinations thereof; and 15 to 50 mole percent of the residues of at least one diacid chosen from adipic acid, succinic acid, and glutaric acid; (c) 50 to 75 mole percent of the residues of one or diacids chosen from 1,4-cyclohex
- the diacid residues may further comprise from 0 to 10 mole percent of the residues of at least one aromatic dicarboxylic acid chosen from phthalic acid, terephthalic acid, isophthalic acid, 2,6-naphthalenedicarboxylic acid, and combinations thereof.
- the acid component of our inventive polyester composition may further comprise the residues of a monocarboxylic acid or a polybasic acid containing more that 2 carboxylic acid groups, such as, for example, the residues of at least one monobasic or polybasic carboxylic acid chosen from benzoic acid, acetic acid, 2-ethylhexanoic acid, propionic acid, tert-butyl benzoic acid, butanoic acid; trimellitic acid; 1,2,4-cyclohexanetricarboxylic acid, 1,3,4-butanetricarboxylic acid, and 1,2,5-hexanetricarboxylic acid.
- a monocarboxylic acid or a polybasic acid containing more that 2 carboxylic acid groups such as, for example, the residues of at least one monobasic or polybasic carboxylic acid chosen from benzoic acid, acetic acid, 2-ethylhexanoic acid, propionic acid, tert-butyl benzoic
- the curable, aliphatic polyester of the coating composition can comprise from 0 to 50 mole percent of at least one aliphatic diol.
- aliphatic diols include, but are not limited to, neopentyl glycol, ethylene glycol, propylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, pentaethylene glycol, hexaethylene glycol, heptaethylene glycol, octaethylene glycol, nonaethylene glycol, decaethylene glycol, 1,3-propanediol, 2,4-dimethyl-2-ethyl-hexane- 1,3-diol, 2,2-dimethyl-l,2-propanediol, 2-ethyl-2-butyl-l,3-propanediol, 2-ethyl-2- isobutyl-l,3-propanediol, 1,2-butane
- the curable, aliphatic polyester resins comprise a combination of the residues or neopentyl glycol and TMCD. It should be understood that the diols listed above may be used in any combination with TMCD and the diacid components and in any amount within the ranges described hereinabove.
- the curable, aliphatic polyester can comprise (i) diacid residues comprising 50 to 85 mole percent of the residues of at least one cycloaliphatic dicarboxylic acid chosen from 1,4-cyclohexanedicarboxylic acid, 1,3- cyclohexanedicarboxylic acid, hexahydrophthalic anhydride, and 15 to 50 mole percent of the residues at least one acylic aliphatic dicarboxylic acid chosen from adipic acid, dodecanedioic acid, sebacic acid, azelaic acid, maleic acid, fumaric acid, succinic acid, and glutaric acid; and (ii) diol residues comprising 50 to 100 mole percent of the residues of TMCD and 50 to 0 mole percent of the residues of at least one diol chosen from neopentyl glycol, ethylene glycol, propylene glycol, diethylene glycol,
- the curable aliphatic polyester can comprise (i) diacid residues comprising 50 to 85 mole percent of the residues of 1,4- cyclohexanedicarboxylic acid, hexahydrophthalic anhydride, or a mixture thereof, and 15 to 50 mole percent of the residues of adipic acid; and (ii) diol residues comprising 50 to 100 mole percent of the residues of TMCD and 50 to 0 mole percent of the residues of neopentyl glycol.
- the curable, aliphatic polyester can comprise (i) diacid resides comprising 50 mole percent of the residues of hexahydrophthalic anhydride and 50 mole percent of the residues of adipic acid; and (ii) diol residues comprising 75 to 100 mole percent of the residues of 2,2,4,4-tetramethyl-l,3- cyclobutanediol, and 25 to 0 mole percent of the residues of neopentyl glycol.
- the curable, aliphatic polyester of the coating composition comprises 2 to 40 mole percent of the residues of at least one polyol, based on the total moles of diol and polyol residues.
- polyols may include aliphatic, alicyclic, and cyclic alkyl polyols.
- polyols include, but are not limited to, trimethylolpropane (abbreviated herein as "TMP), pentaerythritol (abbreviated herein as “PE”), trimethylolethane (abbreviated herein as “TME”), erythritol, threitol, dipentaerythritol, sorbitol, glycerine, and the like.
- TMP trimethylolpropane
- PE pentaerythritol
- TME trimethylolethane
- erythritol erythritol
- threitol dipentaerythritol
- sorbitol glycerine
- the curable, aliphatic polyester can comprise 3 to 30 mole percent of the residues of at least one polyol selected from trimethylolpropane, pentaerythritol, trimethylolethane, erythritol, threitol, dipentaerythritol, sorbitol, and glycerine.
- the curable, aliphatic polyester comprises trimethylolpropane.
- the curable, aliphatic polyester of this invention has a hydroxyl number of 20 to 450 mg KOH/g resin. Further examples of hydroxyl number are 25 to 300, and 30 to 250.
- the curable, aliphatic polyester has an acid number of 0 to 80 mg KOH/g polyester or, in other examples, 2 to 25 mg KOH/g polyester, and 2 to 15 mg KOH/g polyester.
- the number average molecular weight of the curable, aliphatic polyester is 300 daltons to 10000 daltons. Additional examples of molecular weight ranges are 400 to 7000, and 500 to 5000.
- the curable, aliphatic polyester has a glass transition temperature (abbreviated herein as "Tg") of -35 to 35 0 C.
- Tg glass transition temperature
- Some additional, representative examples of Tg ranges for the curable, aliphatic polyester are -35 to 30 0 C, -35 to 25°C, -35 to less than 20, -35 to 19 0 C, -35 to 18 0 C, -35 to 17 0 C, -35 to 16 0 C, -35 to 15 0 C, -35 to 1O 0 C.
- the curable, aliphatic polyester can have a hydroxyl number of 30 to 250 mg potassium hydroxide per gram of polyester, an acid number of 2 to 15 mg potassium hydroxide per gram of polyester, and a number average molecular weight of 700 to 7000 daltons, and a Tg of -20 to 20 0 C.
- the curable, aliphatic polyester resin comprises a reactive functional group, typically a hydroxyl group or carboxyl group for the purpose of later reacting with a crosslinker in a coating formulation.
- the functional group is controlled by having either excess diol or acid (from dicarboxylic acid or tricarboxylic acid) in the polyester resin composition.
- the desired crosslinking pathway will determine whether the polyester resin will be hydroxyl-terminated or carboxylic acid-terminated.
- the concept is known to those skilled in the art and described in Organic Coatings Science and Technology, 2nd ed., p. 246-257, by Z. Wicks, F. Jones, and S. Pappas, Wiley, New York, 1999.
- the thermosetting coating composition may further contain 10 to 50 weight percent of at least one crosslinker, based on the combined weight of the polyester and the crosslinker.
- the crosslinker will be a compound, generally known in the art, that can react with either the carboxylic acid-terminated or hydroxyl-terminated polyester resin.
- the crosslinker can comprise at least one compound chosen from epoxides, melamines, hydroxy alkyl amides, and isocyanates.
- epoxide crosslinkers will react with a carboxylic acid-terminated polyester resin, whereas melamines, isocyanates, and isocyanurates will react with a hydroxyl-terminated polyesters.
- the coating composition of the present invention can comprise at least one melamine compound chosen from hexamethoxymethylmelamine, tetramethoxymethylbenzoguanamine, tetramethoxy- methylurea, and mixed butoxy/methoxy substituted melamines.
- melamine crosslinkers include the CYMELTM300 series and CYMELTM 1100 series melamine crosslinkers, available from Cytec Surface Specialties.
- the polyester to melamine weight ratio is typically 50:50 to 90:10.
- polyeste ⁇ melamine weight ratios are 60:40 to 85:15 and 65:35 to 80:20.
- isocyanates and isocyanurates can be used as crosslinkers in accordance with the invention.
- isocyanates and isocyanurates include, but are not limited to, toluene diisocyanate, isocyanurates of toluene diisocyanate, diphenylmethane 4,4'-diisocyanate, isocyanurates of 4,4'- diisocyanate, methylenebis-4,4'-isocyanatocyclohexane, isophorone diisocyanate, isocyanurates of isophorone diisocyanate, the biuret of 1,6-hexamethylene diisocyanate, 1,6-hexamethylene diisocyanate, isocyanurates of 1,6-hexamethylene diisocyanate, 1,4- cyclohexane diisocyanate, p-phenylene diisocyanate, and triphenylmethane 4,4',4"- triisocyanate, tetramethyl xylene diisocyanate, metaxylene diisocyanate, polyisocyan
- the coating composition also can comprise isocyanate-terminated adducts of diols and polyols, such as ethylene glycol, 1,4-butylene glycol, trimethylol propane, etc., as crosslinkers.
- These crosslinkers are formed by reacting more than one equivalent of a diisocyanate, such as those mentioned above, with one equivalent of a diol or polyol to form a higher molecular weight isocyanate prepolymer with a isocyanate functionality of 2 to 3.
- Some commercial examples of isocyanate-terminated adducts include isocyanate crosslinkers under the DESMODURTM and MONDURTM trademarks available from Bayer Material Science and under the TOLONATETM trademark from Perstorp Corporation.
- the crosslinker comprises at least one aliphatic isocyanate, which can provide good outdoor durability and color stability in the cured coating.
- aliphatic isocyanates include 1,6-hexamethylene diisocyanate, 1,4-butylene diisocyanate, methylene bis(4-cyclohexyl isocyanate), isophorone diisocyanate, and combinations thereof. Mixtures of isocyanate crosslinkers can also be employed.
- the crosslinker can comprise isocyanurates of 1,6-hexamethylene diisocyanate, the biuret of 1,6-hexamethylene diisocyanate, or a mixture thereof.
- NCO:OH ratios can be used; for example, it may be desirable to vary the NCO to OH ratio to less than 1:1 to improve flexibility or greater than 1:1 to produce harder, more chemical resistant, and more weather resistant coatings.
- the solvent borne, thermosetting coating composition has an NCO:OH ratio, on an equivalent basis, of 0.9:1.0 to 1.5:1.0. Examples of other NCO:OH ratios are 0.95:1.0 to 1.25:1.0 and 0.95:1.0 to 1.1:1.0.
- the thermosetting coating composition also comprises 10 to 60 weight percent, based on the total weight of components (A), (B), and (C) of a solvent.
- solvents include, but are not limited to, benzene, xylene, mineral spirits, naptha, toluene, acetone, methyl ethyl ketone, methyl n-amyl ketone, methyl isoamyl ketone, n- butyl acetate, isobutyl acetate, t-butyl acetate, n-propyl acetate, isopropyl acetate, ethyl acetate, methyl acetate, ethanol, n-propanol, isopropanol, n-butanol, sec-butanol, isobutanol, ethylene glycol monobutyl ether, propylene glycol n-butyl ether, propylene glycol methyl ether, propylene glycol monopropyl ether, dipropylene glycol methyl ether, diethylene glycol monobutyl ether, trimethylpentanediol
- the coating composition may also comprise reactive solvents such as, for example, diallyl phthalate, SANTOUNKTM XI-100 polyglycidyl ally! ether (available from Cytec), and others as described, for example, in U.S. Patent No's 5,349,026 and 5,371,148.
- reactive solvents such as, for example, diallyl phthalate, SANTOUNKTM XI-100 polyglycidyl ally! ether (available from Cytec), and others as described, for example, in U.S. Patent No's 5,349,026 and 5,371,148.
- the coating composition can further comprise at least one crosslinking catalyst.
- Representative crosslinking catalysts include carboxylic acids, sulfonic acids, tertiary amines, tertiary phosphines, tin compounds, or combinations of these compounds.
- Some specific examples of crosslinking catalysts are at least one compound chosen from p-toluenesulfonic acid, dodecylbenzene sulfonic acid, dinonylnaphthalene sulfonic acid, and dinonylnaphthalene disulfonic acid, benzoic acid, triphenylphosphine, dibutyltindilaurate, and dibutyltindiacetate.
- crosslinking catalyst typically depends on the type of crosslinker that is used in the coating composition.
- the crosslinker can comprise a melamine or "amino" crosslinker and the crosslinking catalyst can comprise p-toluenesulfonic acid, unblocked and blocked dodecylbenzene sulfonic (abbreviated herein as "DDBSA”), dinonylnaphthalene sulfonic acid (abbreviated herein as "DNNSA”) and dinonylnaphthalene disulfonic acid (abbreviated herein as "DNNDSA”).
- DBSA unblocked and blocked dodecylbenzene sulfonic
- DNNSA dinonylnaphthalene sulfonic acid
- DNNDSA dinonylnaphthalene disulfonic acid
- the curable, aliphatic polyester can comprise hydroxyl- terminated end groups and the crosslinker can comprise an isocyanate.
- the coating composition also can comprise at least one isocyanate crosslinking catalyst such as, for example, FASCATTM 4202 (dibutyltindilaurate), FASCATTM 4200 (dibutyltindiacetate, both available from Arkema), DABCOTM T-12 (available from Air Products) and K-KATTM 348, 4205, 5218, XC-6212TM non-tin catalysts (available from King Industries), and tertiary amines.
- isocyanate crosslinking catalyst such as, for example, FASCATTM 4202 (dibutyltindilaurate), FASCATTM 4200 (dibutyltindiacetate, both available from Arkema), DABCOTM T-12 (available from Air Products) and K-KATTM 348, 4205, 5218, XC-6212TM non-tin catalysts (available from King Industries), and tertiary amines.
- thermosetting coating composition can comprise 25 to 35 weight percent solvent, 20 to 35 weight percent of a melamine crosslinker, and a crosslinking catalyst comprising p-toluenesulfonic acid.
- thermosetting coating composition comprises 25 to 35 weight percent solvent and 20 to 35 weight percent hexamethoxy-methylmelamine.
- the coating composition of the instant invention may further contain at least one coating additive known in the art.
- coating additives include, but are not limited to, leveling, rheology and flow control agents such as silicones, fluorocarbons or cellulosics; extenders; plasticizers; flatting agents; pigment wetting and dispersing agents; ultraviolet (UV) absorbers; UV light stabilizers; defoaming and antifoaming agents; anti-settling, anti-sag and bodying agents; anti-skinning agents; anti-flooding and anti-floating agents; and corrosion inhibitors.
- leveling, rheology and flow control agents such as silicones, fluorocarbons or cellulosics; extenders; plasticizers; flatting agents; pigment wetting and dispersing agents; ultraviolet (UV) absorbers; UV light stabilizers; defoaming and antifoaming agents; anti-settling, anti-sag and bodying agents; anti-skinning agents; anti-flooding and
- additives can be found in the Raw Material Index and Buyer's Guide, published by the National Paint & Coatings Association, 1500 Rhode Island Avenue, N.W., Washington., DC 20005. Further examples of such additives may be found in U.S. Patent No. 5,371,148.
- flatting agents include, but are not limited to, synthetic silica, available from the Davison Chemical Division of W. R. Grace & Company as SYLOIDTM; polypropylene, available from Hercules Inc., as HERCOFLATTM; and synthetic silicate, available from J. M. Huber Corporation, as ZEOLEXTM.
- dispersing agents include, but are not limited to, sodium bis(tridecyl) sulfosuccinate, di(2-ethyl hexyl) sodium sulfosuccinate, sodium dihexylsulfosuccinate, sodium dicyclohexyl sulfosuccinate, diamyl sodium sulfosuccinate, sodium dusobutyl sulfosuccinate, disodium isodecyl sulfosuccinate, disodium ethoxylated alcohol half ester of sulfosuccinic acid, disodium alkyl amido polyethoxy sulfosuccinate, tetra-sodium N-(l,2- dicarboxyethyl)-N-octadecyl sulfosuccinamate, disodium N-octasulfosuccinamate, sulfated ethoxylated
- viscosity, suspension, and flow control agents include, but are not limited to, polyaminoamide phosphate, high molecular weight carboxylic acid salts of polyamine amides, and alkylene amine salts of an unsaturated fatty acid, all available from BYK Chemie USA as ANTI TERRATM. Further examples include, but are not limited to, polysiloxane copolymers, polyacrylate solution, cellulose esters, hydroxyethyl cellulose, hydroxypropyl cellulose, polyamide wax, polyolefin wax, hydroxypropyl methyl cellulose, polyethylene oxide, and the like.
- BUBREAKTM available from Buckman Laboratories Inc.
- BYKTM available from BYK Chemie
- DREWPLUSTM available from the Drew Industrial Division of Ashland Chemical Company
- TROYSOLTM and TROYKYDTM available from Troy Chemical Corporation
- SAGTM available from Union Carbide Corporation.
- UV absorbers examples include, but are not limited to, substituted benzophenone, substituted benzotriazoles, hindered amines, hindered benzoates, phenols, and phosphites, some of which are available from Cytec Specialty Chemicals as CYASORB ® UV, and from Ciba Specialty Chemicals as TINUVIN ® , CHIMASSORB ® , IRGANOX ® and IRGAFOS ® ; diethyl-3-acetyl-4-hydroxy-benzyl- phosphonate, 4-dodecyloxy-2-hydroxy benzophenone, and resorcinol monobenzoate.
- the thermosetting coating compositon can contain IRGANOX ® 1010 antioxidant, available from Ciba Specialty Chemicals.
- IRGANOX ® 1010 antioxidant available from Ciba Specialty Chemicals.
- Such paint or coating additives as described above form a relatively minor proportion of the coating composition, generally 0.05 weight percent to 5.00 weight percent.
- a coating composition optionally may contain at least one of the above-described additives and at least one pigment.
- the solvent borne thermosetting coating composition also may comprise at least one pigment.
- the pigment is present in an amount of 20 to 60 weight percent, based on the total weight of the composition.
- examples of pigments include those generally recognized by persons of ordinary skill in the art of surface coatings.
- the pigment may be a typical organic or inorganic pigment, especially those set forth by the Colour Index, 3rd ed., 2nd Rev., 1982, published by the Society of Dyers and Colourists in association with the American Association of Textile Chemists and Colorists.
- suitable pigments include, but are not limited to, titanium dioxide, barytes, clay, calcium carbonate, Cl Pigment White 6 (titanium dioxide), Cl Pigment Red 101 (red iron oxide), Cl Pigment Yellow 42, Cl Pigment Blue 15,15:1,15:2,15:3,15:4 (copper phthalocyanines); Cl Pigment Red 49:1 and Cl Pigment Red 57:1. Colorants such as, for example, phthalocyanine blue, molybdate orange, or carbon black also may be added to the coating composition.
- the solvent borne, thermosetting coating formulations can contain titanium dioxide as the pigment.
- the thermosetting coating composition of this invention may optionally comprise a TSA resin.
- Thermosetting acrylic ("TSA") resins are prepared by free radical polymerization in bulk or in a solvent.
- Initiators are of the free radical type and are usually organic peroxides or azo compounds, such as benzoyl peroxide, t-butyl hydroperoxide, t-butyl peroxide, t-butyl peroxybenzoate, azobisisobutyronitrile, and 2,2'- azobis(2,4-dimethyl)-valeronitrile.
- the reaction is preferably carried out at the reflux temperature of the solvent used, which is generally higher than the thermal decomposition temperature of the initiator employed.
- the acrylic resin is composed of ethylenically unsaturated monomers that include acrylate, methacrylate, styrene, (meth) acrylic acid, and vinyl esters. They further contain hydroxyl, epoxy, carboxyl, blocked- phenol and/or acetoacetoxy functional groups. Suitable examples of preparation methods and components of the acrylic resin include those known in the art including, but not limited to, those described above, and in Resins for Surface Coatings, Vol. II, p. 121-210, ed. by P.K.T. Oldring and G. Hayward, SITA Technology, London, UK, 1987.
- hydroxyl functional TSA resins include the MACRYNALTM series, available from Cytec Surface Specialties; the ACRYLOIDTM series, available from Rohm and Haas; and the JONCRYLTM series, available from BASF Corporation.
- MACRYNALTM SM 515/70BAC available from Cytec Surface Specialties.
- the curable, aliphatic polyester and the TSA resin can be blended together.
- the weight percent of polyester in the blend is 5 to 50 wt. percent preferably 10 to 40 weight percent, and most preferably 15 to 30 weight percent.
- thermosetting coating composition and additives can be formulated into coating that contains 40 to 90% non-volatiles.
- the coating composition can be applied to a substrate or article.
- a further aspect of the present invention is a shaped or formed article that has been coated with the coating compositions of the present invention.
- the substrate can be any common substrate such as paper; polymer films such as polyethylene or polypropylene; wood; metals such as aluminum, steel or galvanized sheeting; glass; urethane elastomers; primed (painted) substrates; and the like.
- the coating composition can be coated onto a substrate using techniques known in the art, for example, by spraying, draw-down, roll-coating, etc., 0.5 to 4 mils of wet coating onto a substrate.
- the coating can be cured at ambient (room) temperature or heated in a forced air oven to a temperature of 50 0 C to 175°C, for a time period that typically ranges 5 to 90 minutes and allowed to cool. Further examples of typical application and curing methods can be found in US patent no. 1 S 4,737,551 and 4,698,391 and 3,345,313.
- the invention is further illustrated by the following examples.
- the resins were prepared using a solvent process to help remove the water of esterification.
- the resins were prepared in a two-liter reaction kettle equipped with a heating mantle, mechanical stirrer, thermocouple, nitrogen blanket (0.6 scfh), oil-heated partial condenser (103°C-105°C), condensate trap, and water-cooled total condenser (15°C).
- the condensate trap, kettle top and adapter from the kettle to the column were insulated by aluminum foil and fiberglass tape to facilitate water removal.
- Stage 1 raw materials were charged to the reactor. Additional xylene (approximately 3Og) was used to fill the condensate trap.
- the temperature was then increased from room temperature to 150 0 C over ninety minutes to form a homogenous melt. Agitation (300 rpm) was started and the temperature increased to a maximum of 230 0 C over 240 minutes. The Stage 2 TMP was added when half the theoretical condensate was collected. The reaction mixture was held at 230°C until a final acid number of 6 ⁇ 2 mg KOH/g resin was obtained. The resins were then poured into a metal paint can.
- the acid number (abbreviated "AN”), hydroxyl number (abbreviated “OH#”), number average molecular weight (abbreviated “Mn”) and glass transition temperature (abbreviated “Tg”) of the polyesters are shown in Table 1.
- Acid number was determined using ASTM method D 1639. Hydroxyl number was determined by esterifying the resin by reaction with excess acetic anhydride in pyridine and then decomposing the unreacted anhydride with water. The resulting acetic acid is then titrated with a standard solution of KOH. The number of milligrams KOH which are equivalent to one gram of resin sample is reported as the hydroxyl number. Number average molecular weight was determined by gel permeation chromatography using a refractive index detector with polystyrene standards.
- Residual xylene remaining in the resin from solvent processing could artificially lower the Tg measurement.
- a resin sample was first subjected to preconditioning in a TGA (thermal gravimetric analysis) instrument. It was placed into a stainless steel DSC pan and heated under nitrogen atmosphere from room temperature to 150 0 C at a rate of 5°C/min. The sample was then transferred to a differential scanning calorimeter with modulating capability (TA Instruments Q2000 MDSC with Universal software V4.3A). On the first heating cycle, the sample was heated under nitrogen atmosphere from -120 0 C to 125°C at a rate of 5°C/min. modulating at ⁇ 0.796°C/min.
- TGA thermo gravimetric analysis
- the sample was heated under the same conditions as those used in the first heating cycle.
- the midpoint of the second heating cycle is reported as the Tg of the sample.
- Clarity of the solutions was measured with a BYK-Gardner haze-gard plus instrument according to ASTM method D 1003, Method A, and is reported as percent haze.
- Solution viscosity was determined using a Brookfield Model LV DV 11+ Pro viscometer. Viscosity was measured in a 4 oz. jar at 100 rpm using spindle #63. Viscosity readings below 1000 centipoise are considered to be very low.
- polyesters P2, P3, and P4 have low color, good clarity and low viscosity. All are suitable for blending with a TSA resin and formulating into a high solids, solvent borne thermosetting coating.
- TSA/Aliphatic Polyester Blends Examples B3, B4, B5, B7, B8, B9, BIl, B12, and B13 illustrate blends of a TSA with the aliphatic polyesters of the invention, while examples Bl, B2, B6, and BlO are comparative examples.
- the properties of the TSA/aliphatic polyester blends are listed in Table 2.
- the aliphatic polyester resins were evaluated for compatibility with a commercially available TSA resin, MACRYNALTM SM 515/70BAC (available from Cytec Surface Specialties).
- MACRYNALTM SM 515 is a hydroxy functional acrylic that is crosslinkable with aliphatic polyisocyanates. This TSA resin is suggested for use by the manufacturer in air-drying and forced drying two pack high solids thermosetting coatings.
- TSA/polyester resin blends were evaluated at 70 weight percent solids in n- butyl acetate at TSA:polyester weight ratios of 85:15, 75:25 and 65:35.
- MACRYNALTM SM 515 was supplied as a 70 weight percent solution in n-butyl acetate, and all of the polyester resins were reduced to 70 weight percent solids in n-butyl acetate.
- the appropriate amount of acrylic and polyester resin solutions were combined in a 4 oz. jar as indicated in Table 2. The solutions were then rolled at room temperature for 24 hours to thoroughly mix the components.
- the viscosity of the TSA/polyester blends was determined using a Brookfield Model LV DV 11+ Pro viscometer. Viscosity was measured in the 4 oz. jar at 20 rpm using spindle #63 and is reported in centipoise. A portion of each TSA/polyester blend was cast as a 10 mil wet film onto glass and force-dried for 7 hrs. at 80 0 C (176°F) then dried at room temperature drying for 4 days before evaluation.
- the Tg of the blends was determined on samples of the dried cast films using a differential scanning calorimeter with modulating capability (TA Instruments Q2000 MDSC with Universal software V4.3A).
- TA Instruments Q2000 MDSC with Universal software V4.3A On the first heating cycle, the sample was heated under helium atmosphere from -120 0 C to 125°C at a rate of 5°C/min. and modulating at ⁇ 0.531°C/40 sec. The sample then was quench-cooled with liquid nitrogen to -120°C.
- the sample was heated under the same conditions as those used in the first heating cycle. The midpoint of the second heating cycle is reported as the Tg of the sample.
- the compatibility of the aliphatic polyester with the TSA resin was determined by measuring the percent haze of the dried films according to ASTM method D 1003, Method A, using a BYK-Gardner HAZE-GARD PLUSTM instrument.
- Table 2 shows that the viscosity of the TSA resin was lowered when blended with any of the polyesters. Viscosity decreases as the polyester content increases.
- comparative examples B2, B6, and BlO show the greatest reduction in Tg from the TSA alone, especially as the polyester content increases.
- Example blends B3, B4, B5, B7, B8, B9, BIl, B12 and B13 have less impact on Tg.
- Example blend B13 made from polyester P4 experienced only a 7°C drop from the original Tg of the TSA versus a 35°C drop for Comparative blend BlO containing polyester Pl.
- the compatibility of Example polyesters P2, P3 and P4 with the TSA, as indicated by percent haze were similar to blends made from Comparative polyester Pl and the TSA alone.
- Part A aliphatic polyester and pigment were added to a 500-mL stainless steel beaker.
- a cowles disperser was used to grind the resin and pigment to a 7+ Hegman for about 5 min. at 5000 rpm.
- the flow aid then was added and thoroughly mixed for a few minutes.
- the catalyst and solvent blend were added and thoroughly mixed.
- the total Part A mixture was transferred into a glass jar and rolled until needed.
- the Part B crosslinker was added to Part A and thoroughly mixed with a wooden tongue depressor then filtered through a Hayward PE 100 PN 164 300M felt paint filter inside a medium mesh paper filter.
- Coating viscosity was determined with a Gardco mini Ford dip cup #4. The initial viscosity measurement was made after combining and thoroughly mixing Part B with Part A. Viscosity was then measured every two hours thereafter and is shown in Table 3.
- a wire wound rod was used to apply the coating to glass microscope slides and polished cold rolled steel test panels with Bonderite 1000 pretreatment.
- the rod was selected to achieve a 1.5 ⁇ 0.2 mil dry film thickness.
- the coatings were force-dried 30 minutes at 250 0 F (121.1°C). With the exception of K ⁇ nig pendulum hardness, all of the coating mechanical properties were determined after 21 days ambient aging. Specular gloss, distinctness of image, reflectance, color, hardness, flexibility, solvent resistance, chemical resistance and accelerated weathering (UVA and constant humidity) resistance of the coatings were determined and reported in Tables 4 - 9.
- DFT Dry film thickness
- Fischerscope MMS Multi Measuring System permascope Fischer Technology
- Specular gloss was measured with a BYK-Gardner micro-TRI-gloss meter in accordance with ASTM method D 523.
- Distinctness of image was measured with a BYK-Gardner wave-scan DOI instrument according to ASTM method E 430.
- the test was run to a maximum of 300 double rubs with observations made on the left, middle and right side of the rubbed path.
- Hardness was determined by three methods: a BYK-Gardner pendulum hardness tester using ASTM method D 4366; by pencil test using ASTM method D 3363; and with an lnstron Wilson-Wolpert Tukon 2100B indentation hardness tester using
- KPH K ⁇ nig method
- Flexibility was measured as impact resistance with a Gardco Model 172 universal impact tester in accordance with ASTM method D 2794. The values reported are the last impact to not produce any crack in the coating film or delamination of the coating from the substrate.
- the coatings were placed in a Cleveland condensing type humidity cabinet (Q-Lab Model QCT/ADO) for continuous 60 0 C misting with deionized water. The edges and back of the test panels were taped to protect against rust formation. They were rotated after each observation interval. The coatings were evaluated for gloss retention (20° and 60° per ASTM D 523) and degree of blistering (using ASTM method D 714). The results are shown in Tables 7, 8 and 9.
- Table 3 shows that example coatings C2 and C3 show similar pot lives as comparative example Cl (based on NPG glycol as the diol). Coating mechanical properties are presented in Table 4.
- Examples C2 and C3 exhibit higher gloss, DOI, and reflectance than comparative example Cl. Color is relatively similar for all of the coatings. Examples C2 and C3 also have a more uniform and brilliant appearance as indicated by the higher gloss, DOI and reflectance values.
- MEK double rub solvent resistance was higher across the coating surface for examples C2 and C3 than comparative example Cl.
- the combination of TMCD/CHDA in example C2 showed no breakthrough of the coating to the substrate.
- Hardness, as measured by pencil, Tukon and Konig pendulum tests, is greater for examples C2 and C3.
- examples C2 and C3 display similar flexibility to comparative example Cl. Examples C2 and C3 were unaffected after 36 days exposure to H 2 SO 4 solution, whereas comparative example Cl blistered.
- examples C2 and C3 had greater gloss retention than comparative example Cl (see Table 5). Gloss retention of examples C2 and C3 was about 4.5 times longer. Examples C2 and C3 also exhibited a Hunter ⁇ E* shift and Yellow Index shift of only one unit over the entire test period (see Table 6).
- Examples C2 and C3 had greater gloss retention with little or no blister development than comparative example Cl when subjected to Cleveland humidity testing (see Tables 7, 8 and 9). In particular, example C3 retained 73% of its original 20° gloss after 10,000 hours exposure with no blister formation.
- Polyester resin (70 wt. % in n-BuOAc) 76.23 76.23 76.45
- Fascat 4202(c) catalyst (1 wt. % in n-BuOAc) 0.82 0.82 0.82
- Solvent blend (45/45/10 Xylene/MAK/EEP) 40.99 40.99 40.99 40.94
- Polyester Formulation from Example 1 Pl P3 P4 Mole % TMCD in Polyester 0 100 100 blistering.
Abstract
Description
Claims
Priority Applications (6)
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CA2750516A CA2750516A1 (en) | 2009-02-06 | 2010-01-27 | Aliphatic polyester coating compositions containing tetramethyl cyclobutanediol |
CN201080006610.2A CN102307928B (en) | 2009-02-06 | 2010-01-27 | Aliphatic polyster coating compositions containing tetramethyl cyclobutanediol |
MX2011007470A MX2011007470A (en) | 2009-02-06 | 2010-01-27 | Aliphatic polyester coating compositions containing tetramethyl cyclobutanediol. |
JP2011549145A JP5462285B2 (en) | 2009-02-06 | 2010-01-27 | Aliphatic polyester coating composition containing tetramethylcyclobutanediol |
EP10703372A EP2393865A1 (en) | 2009-02-06 | 2010-01-27 | Aliphatic polyester coating compositions containing tetramethyl cyclobutanediol |
BRPI1007304A BRPI1007304A2 (en) | 2009-02-06 | 2010-01-27 | curable aliphatic polyester, thermocure coating composition, and coated molded object |
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US12/367,190 US9029461B2 (en) | 2009-02-06 | 2009-02-06 | Aliphatic polyester coating compositions containing tetramethyl cyclobutanediol |
US12/367,190 | 2009-02-06 |
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EP (1) | EP2393865A1 (en) |
JP (1) | JP5462285B2 (en) |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3760658A1 (en) | 2019-07-03 | 2021-01-06 | Covestro Deutschland AG | Resistant 2k-pur coatings |
Families Citing this family (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8163850B2 (en) * | 2009-02-06 | 2012-04-24 | Eastman Chemical Company | Thermosetting polyester coating compositions containing tetramethyl cyclobutanediol |
US9029461B2 (en) * | 2009-02-06 | 2015-05-12 | Eastman Chemical Company | Aliphatic polyester coating compositions containing tetramethyl cyclobutanediol |
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KR20140048854A (en) | 2011-02-07 | 2014-04-24 | 발스파 소싱 인코포레이티드 | Coating compositions for containers and other articles and methods of coating |
CA2879424C (en) | 2012-08-09 | 2020-06-30 | Valspar Sourcing, Inc. | Compositions for containers and other articles and methods of using same |
US8623483B1 (en) * | 2012-10-23 | 2014-01-07 | Eastman Chemical Company | Copolyesters containing neopentyl glycol and 2,2,4,4-tetraalkyl 1,3-cyclobutanediol |
RU2658035C2 (en) * | 2014-01-02 | 2018-06-19 | Эмерелд Калама Кемикл, Ллк | Plasticizers based on complex polyesters with terminal blocking benzoic acid groups |
CN106536624B (en) | 2014-04-14 | 2019-11-19 | 宣伟投资管理有限公司 | Preparation is used for the method for the composition of container and other products and the method using the composition |
WO2016069572A1 (en) * | 2014-10-27 | 2016-05-06 | Eastman Chemical Company | Resole phenolic resins curable with functional polyesters |
US20160115345A1 (en) * | 2014-10-27 | 2016-04-28 | Eastman Chemical Company | Curable polyesters and thermosetting compostions containing resole phenolic resins |
US9598602B2 (en) | 2014-11-13 | 2017-03-21 | Eastman Chemical Company | Thermosetting compositions based on phenolic resins and curable poleyester resins made with diketene or beta-ketoacetate containing compounds |
US9650539B2 (en) | 2014-10-27 | 2017-05-16 | Eastman Chemical Company | Thermosetting compositions based on unsaturated polyesters and phenolic resins |
US9487619B2 (en) | 2014-10-27 | 2016-11-08 | Eastman Chemical Company | Carboxyl functional curable polyesters containing tetra-alkyl cyclobutanediol |
JP6085627B2 (en) * | 2015-02-14 | 2017-02-22 | 三菱樹脂株式会社 | Laminated polyester film |
US20160340471A1 (en) * | 2015-05-19 | 2016-11-24 | Eastman Chemical Company | Aliphatic polyester coating compositions containing tetramethyl cyclobutanediol |
CN107709395B (en) * | 2015-06-09 | 2020-08-11 | Ppg工业俄亥俄公司 | Stain resistant coating compositions and coatings formed therefrom |
PL3307802T3 (en) * | 2015-06-09 | 2020-05-18 | Ppg Industries Ohio, Inc. | Stain resistant, soft touch coating compositions and coatings formed therefrom |
US20170088665A1 (en) | 2015-09-25 | 2017-03-30 | Eastman Chemical Company | POLYMERS CONTAINING CYCLOBUTANEDIOL AND 2,2 BIS(HYDROXYMETHYL) AlKYLCARBOXYLIC ACID |
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US9988553B2 (en) | 2016-02-22 | 2018-06-05 | Eastman Chemical Company | Thermosetting coating compositions |
US11168174B2 (en) | 2016-02-23 | 2021-11-09 | Eastman Chemical Company | Isocyanate-modified rigid thermoplastic polymer compositions |
US11208520B2 (en) | 2016-02-23 | 2021-12-28 | Eastman Chemical Company | Isocyanate-modified rigid thermoplastic polymer compositions |
US10011737B2 (en) * | 2016-03-23 | 2018-07-03 | Eastman Chemical Company | Curable polyester polyols and their use in thermosetting soft feel coating formulations |
US11732165B2 (en) | 2017-06-13 | 2023-08-22 | Eastman Chemical Company | Low-temperature curable compositions |
WO2019147458A1 (en) * | 2018-01-23 | 2019-08-01 | Eastman Chemical Company | Novel polyesteramides, processes for the preparation thereof, and polyesteramide compositions |
WO2020076663A1 (en) * | 2018-10-11 | 2020-04-16 | Eastman Chemical Company | Coatings with improved scratch resistance |
CN112789332A (en) * | 2018-10-11 | 2021-05-11 | 伊士曼化工公司 | Thermosetting coating composition with improved scratch resistance |
US20210380835A1 (en) * | 2018-10-11 | 2021-12-09 | Eastman Chemical Company | Scratch resistant thermosetting coating compositions |
EP3891205A4 (en) * | 2018-12-06 | 2022-05-25 | Eastman Chemical (China) Co., Ltd. | Polyesters comprising 2, 2, 4, 4-tetraalkyl-1, 3-cyclobutanediol |
EP3894509B1 (en) * | 2018-12-11 | 2024-03-20 | Eastman Chemical Company | Self-curable and low temperature curable coating compositions |
US11820923B2 (en) | 2018-12-11 | 2023-11-21 | Eastman Chemical Company | Controlled cure for compositions comprising acetoacetylated resins |
CN113993977A (en) | 2019-05-24 | 2022-01-28 | 伊士曼化工公司 | Mixing a small amount of pyrolysis oil into the liquid flow entering the gas cracker for processing |
WO2021021855A1 (en) * | 2019-07-29 | 2021-02-04 | Eastman Chemical Company | Recycle content cyclobutane diol polyester |
US11945998B2 (en) | 2019-10-31 | 2024-04-02 | Eastman Chemical Company | Processes and systems for making recycle content hydrocarbons |
US11319262B2 (en) | 2019-10-31 | 2022-05-03 | Eastman Chemical Company | Processes and systems for making recycle content hydrocarbons |
CN116348384A (en) * | 2020-10-27 | 2023-06-27 | 伊士曼化工公司 | Coating composition comprising TMCD polyester and modified polyester |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3345313A (en) | 1963-02-20 | 1967-10-03 | Trojan Powder Co | Alkyd resins and their preparation from reaction mixtures comprising a polymethylolalkanoic acid |
US4698391A (en) | 1986-07-30 | 1987-10-06 | Eastman Kodak Company | Crosslinked polymers with lowered resistivity and materials and methods for their preparation |
US4737551A (en) | 1986-06-23 | 1988-04-12 | E. I. Dupont De Nemours And Company | Coating composition of a hydroxy group-containing modified polyester with polymerized lactone monomers |
US5097006A (en) * | 1990-11-21 | 1992-03-17 | U C B S.A. | Weatherable powder coating compositions |
US5349026A (en) | 1992-11-20 | 1994-09-20 | Rohm And Haas Company | Reactive coalescents |
US5371148A (en) | 1993-06-23 | 1994-12-06 | Union Carbide Chemicals & Plastics Technology Corporation | Reactive polymers having pendant flexible side chains prepared from ethylenically unsaturated carbodiimides |
US5596037A (en) * | 1992-03-16 | 1997-01-21 | U C B S.A. | Carboxyl-terminated polyesters for the preparation of powder coating compositions |
US20070232778A1 (en) * | 2006-03-28 | 2007-10-04 | Leslie Shane Moody | Certain polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and high trans-cyclohexanedicarboxylic acid |
Family Cites Families (95)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2891930A (en) | 1957-03-25 | 1959-06-23 | Eastman Kodak Co | Fiber-forming polyesters from trans-1, 4-cyclohexanedicarboxylic compounds and 1, 1-cyclohexane dimethanol |
FR83790E (en) | 1959-12-18 | 1964-10-09 | Kodak Pathe | New polymers derived from 2, 2, 4, 4-tetraalkyl-1, 3-cyclobutanediols and their industrial applications |
US3313777A (en) | 1959-12-18 | 1967-04-11 | Eastman Kodak Co | Linear polyesters and polyester-amides from 2, 2, 4, 4-tetraalkyl-1, 3-cyclobutanediols |
BE615850Q (en) | 1960-12-16 | 1962-07-16 | Eastman Kodak Co | New polymers derived from 2,2,4,4-tetraalkyl-1,3-cyclobutanediols and their industrial applications |
US3227764A (en) | 1960-12-30 | 1966-01-04 | Eastman Kodak Co | Separation of cis and trans isomers of tetraalkyl - 1,3 - cyclobutanediols and novel compound obtained thereby |
FR1456345A (en) | 1964-12-07 | 1966-10-21 | Eastman Kodak Co | New process for the preparation of polyesters and new products obtained |
US3484339A (en) | 1966-05-02 | 1969-12-16 | Eastman Kodak Co | Blends of polyesters containing free carboxyl groups and laminate thereof |
US3502620A (en) | 1967-05-11 | 1970-03-24 | Eastman Kodak Co | Branched polyesters containing terminal carboxyl groups |
US3538187A (en) | 1969-03-04 | 1970-11-03 | Atlas Chem Ind | Polyester resin from a mixture of dihydric alcohols |
US3789044A (en) | 1971-01-26 | 1974-01-29 | Ashland Oil Inc | Novel cured compositions prepared from the reaction of a polyisocyanate and a hydroxybenzoic acid capped epoxide-containing material |
US3856830A (en) | 1971-12-23 | 1974-12-24 | Atlas Chem Ind | Polymerizable urethane compounds |
US4076766A (en) | 1975-03-27 | 1978-02-28 | E. I. Du Pont De Nemours And Company | Flexible thermosetting acrylic enamels |
US4074061A (en) | 1976-10-26 | 1978-02-14 | Eastman Kodak Company | Unsaturated polyester containing formal linkages |
US4322508A (en) | 1978-03-20 | 1982-03-30 | Ford Motor Company | High solids paint composition comprising hydroxy functional oligoesters and hydroxy functional copolymers |
US4267279A (en) * | 1979-07-27 | 1981-05-12 | Koppers Company, Inc. | Polyester composition stabilized against gel-time drift with amine salt and method for making same |
US4299933A (en) | 1980-06-02 | 1981-11-10 | Eastman Kodak Company | Polyester adhesives |
US4581093A (en) | 1980-12-15 | 1986-04-08 | Whittaker Corporation | Branched polyester adhesive compositions and method employing same |
US4350807A (en) | 1981-02-09 | 1982-09-21 | Eastman Kodak Company | Copolyester compositions |
US4338379A (en) | 1981-02-13 | 1982-07-06 | E. I. Du Pont De Nemours And Company | High-solids thermosetting enamel coating composition |
US4363908A (en) | 1981-08-31 | 1982-12-14 | Eastman Kodak Company | Polyester modified with alkyl- or alkenylsuccinic anhydrides |
US4397989A (en) | 1982-02-08 | 1983-08-09 | E. I. Du Pont De Nemours & Co. | High solids coating composition of an acrylic polymer a polyester polyol and an alkylated melamine crosslinking agent |
US4525544A (en) | 1982-04-12 | 1985-06-25 | The Dow Chemical Company | Vinyl ester resin composition |
US4480077A (en) | 1982-10-12 | 1984-10-30 | Dow Chemical Co | Heat resistant vinyl ester resin composition |
US5023367A (en) | 1982-12-27 | 1991-06-11 | King Industries, Inc. | Linear, low-molecular-weight polyester-based polyol |
US4525504A (en) | 1983-10-24 | 1985-06-25 | Eastman Kodak Company | Stabilized polyester compositions suitable for outdoor applications |
US4585854A (en) | 1984-04-16 | 1986-04-29 | The Goodyear Tire & Rubber Company | Polyester composition |
US4724173A (en) | 1986-01-29 | 1988-02-09 | The Board Of Governors For Higher Education, State Of Rhode Island | Method of preventing gel coat blistering in fiber glass reinforced polymers |
US4751267A (en) | 1986-03-06 | 1988-06-14 | The Glidden Company | Acrylic polyester high solids coatings |
US4716200A (en) | 1986-03-06 | 1987-12-29 | The Glidden Company | Acrylic polyester high solids coatings |
US4859760A (en) | 1987-12-07 | 1989-08-22 | Eastman Kodak Company | Polyurethane powder coating compositions |
FR2635716B1 (en) | 1988-08-24 | 1990-11-02 | Beneteau Sa Chantiers | METHOD OF PROTECTING AGAINST WATER OF A LAMINATED RESIN WALL AND WALL OF PROTECTED LAMINATED RESIN THUS OBTAINED |
US4910292A (en) | 1988-10-14 | 1990-03-20 | Eastman Kodak Company | Water-dissipatable polyester resins and coatings prepared therefrom |
US4939233A (en) | 1988-12-05 | 1990-07-03 | Eastman Kodak Company | Aqueous polymer compositions and methods for their preparation |
JPH0338281A (en) | 1989-07-04 | 1991-02-19 | Nippon Steel Metal Prod Co Ltd | Preparation of precoated metal plate |
US5017679A (en) | 1989-08-30 | 1991-05-21 | Eastman Kodak Company | Polyesters terminated with carboxycyclohexanecarboxylate groups |
US6184311B1 (en) * | 1990-03-26 | 2001-02-06 | Courtaulds Coatings (Holdings) Limited | Powder coating composition of semi-crystalline polyester and curing agent |
US5124388A (en) | 1990-05-07 | 1992-06-23 | Eastman Kodak Company | Films and containers of heat resistant copolyesters |
DE4024204A1 (en) | 1990-07-31 | 1992-02-06 | Basf Lacke & Farben | COATING AGENTS BASED ON HYDROXYL GROUPS OF POLYCONDENSATION AND POLYADDITION PRODUCTS AND THEIR USE |
US5025086A (en) | 1990-11-13 | 1991-06-18 | Eastman Kodak Company | Trifunctional monomer compounds, polyesters derived therefrom and thermosetting coating compositions containing the polyesters |
US5160792A (en) | 1991-02-04 | 1992-11-03 | Eastman Kodak Company | Thermosetting powder coating compositions |
US5254637A (en) | 1991-06-03 | 1993-10-19 | Eastman Kodak Company | Thermosetting coating compositions |
US5256759A (en) | 1991-06-10 | 1993-10-26 | Eastman Kodak Company | Thermosetting coating compositions |
US5245002A (en) | 1991-06-10 | 1993-09-14 | Eastman Kodak Company | Thermosetting coating compositions |
US5256761A (en) | 1991-09-23 | 1993-10-26 | Eastman Kodak Company | Polyester coatings containing covalently-bound mesogenic monomers |
ATE154380T1 (en) | 1992-07-06 | 1997-06-15 | Eastman Chem Co | HEAT CURING POWDER COATING COMPOSITIONS |
CZ138993A3 (en) * | 1992-07-15 | 1994-02-16 | Herberts & Co Gmbh | Aqueous, thermosetting coating composition, process of its preparation and use |
US5350830A (en) | 1992-11-27 | 1994-09-27 | Eastman Chemical Company | Thermosetting coating compositions |
US5344872A (en) | 1993-02-19 | 1994-09-06 | Eastman Chemical Company | Ink compositions containing certain methacrylates |
GB9304940D0 (en) | 1993-03-11 | 1993-04-28 | Ucb Sa | Thermosetting powder compositions based on polyesters and acrylic copolymers |
CA2166306A1 (en) * | 1993-07-01 | 1995-01-12 | Robert B. Barbee | Powder coating compositions |
US5393840A (en) * | 1993-11-01 | 1995-02-28 | Eastman Chemical Company | Thermosetting coating compositions |
US5416187A (en) | 1994-04-04 | 1995-05-16 | Eastman Chemical Company | Process for the preparation of phenol-functional polyester resins |
ES2163457T3 (en) | 1994-04-06 | 2002-02-01 | Ppg Ind Ohio Inc | COATING COMPOSITIONS THAT INCLUDE 1,4-CYCLOHEXAN DIMETHANOL. |
US5393609A (en) | 1994-06-13 | 1995-02-28 | Eastman Chemical Company | Weatherable powder coatings |
JPH0873781A (en) | 1994-09-12 | 1996-03-19 | Sumitomo Metal Ind Ltd | Production of glaze-skinned decorative metallic sheet excellent in staining resistance |
US5498668A (en) | 1994-10-31 | 1996-03-12 | Eastman Chemical Company | Blends of certain polyesters with acrylics |
DE19500358A1 (en) | 1995-01-09 | 1996-07-11 | Bayer Ag | Polyester polyols and their use in two-component polyurethane coatings |
US5554701A (en) | 1995-03-24 | 1996-09-10 | Eastman Chemical Company | Crosslinked polyesters made from decahydronaphthalene dimethanol |
US5464909A (en) | 1995-03-24 | 1995-11-07 | Eastman Chemical Company | Powder coating having good UV resistance |
JP2001527586A (en) | 1995-04-19 | 2001-12-25 | エクソン ケミカル カンパニー | Polymer vehicle containing polyol, phenol ester alcohol and isocyanate compound |
US5681906A (en) | 1995-04-19 | 1997-10-28 | Exxon Chemical Patents Inc. | Thermoset coating compositions having improved hardness |
EP0745628B1 (en) * | 1995-05-31 | 2002-04-03 | Shell Internationale Researchmaatschappij B.V. | Copolyester composition |
JPH093341A (en) | 1995-06-15 | 1997-01-07 | Nippon Oil & Fats Co Ltd | Thermosetting composition, coating and finishing method and coated article, and moding method and molded article |
US5646237A (en) | 1995-08-15 | 1997-07-08 | Eastman Chemical Company | Water-dispersible copolyester-ether compositions |
JPH09111183A (en) | 1995-10-20 | 1997-04-28 | Kansai Paint Co Ltd | Coating composition and one-coat steel sheet |
JP2914297B2 (en) * | 1996-05-29 | 1999-06-28 | 日本電気株式会社 | PLL frequency synthesizer |
DE19629823A1 (en) | 1996-07-24 | 1998-01-29 | Basf Lacke & Farben | Coating composition based on a branched hydroxyl-containing, polyester-modified polyacrylate resin and its use in processes for producing a multicoat paint system |
US5955565A (en) | 1996-12-28 | 1999-09-21 | Eastman Chemical Company | Polyesters from terephthalic acid, 2,2,4,4-tetramethyl-1,3-cyclobutanediol and ethylene glycol |
NL1005809C2 (en) | 1997-04-14 | 1998-10-19 | Dsm Nv | Powder paint binder composition. |
US6887937B1 (en) | 1997-05-21 | 2005-05-03 | Akzo Nobel Nv | Coating composition based on a hydroxy group-containing film forming polymer, a polyisocyanate compound, and a diol |
US6248843B1 (en) | 1998-09-18 | 2001-06-19 | Mcwhorter Technologies, Inc. | Powder coatings based on branched oligoesters and triazole blocked polyisocyanates |
US20010051706A1 (en) | 1998-12-03 | 2001-12-13 | Scott E. George | Terephthalate-based sulfopolyesters |
US6265072B1 (en) | 1999-04-27 | 2001-07-24 | Eastman Chemical Company | UV-stabilized polymeric structures |
WO2001059020A1 (en) | 2000-02-08 | 2001-08-16 | The C.P. Hall Company | Low voc, nonlinear polyester polyol resin-based compositions |
US6808821B2 (en) | 2000-09-05 | 2004-10-26 | Dainippon Ink And Chemicals, Inc. | Unsaturated polyester resin composition |
JP2002235038A (en) | 2001-02-08 | 2002-08-23 | Mitsubishi Electric Corp | Powder coating material composition dispersed in nonaqueous medium |
TWI237052B (en) | 2001-07-26 | 2005-08-01 | Surface Specialties Sa | Radiation curable powder coating compositions |
TW591341B (en) | 2001-09-26 | 2004-06-11 | Shipley Co Llc | Coating compositions for use with an overcoated photoresist |
US7087672B2 (en) | 2002-05-08 | 2006-08-08 | E. I. Du Pont De Nemours And Company | Non-yellowing polyester coating composition |
WO2003106560A1 (en) | 2002-06-13 | 2003-12-24 | 大日本インキ化学工業株式会社 | Water base resin composition |
US20040087736A1 (en) | 2002-11-04 | 2004-05-06 | Bin Wu | Powder coating compositions containing anhydride end-capped crystalline polyesters |
US20060079650A1 (en) | 2004-10-12 | 2006-04-13 | Stevenson Thomas A | Flexible, super durable powder coating composition |
WO2006083343A1 (en) | 2005-02-01 | 2006-08-10 | Henkel Corporation | Vinyl ether/acrylate block resins, compositions and methods of making same |
JP2006233068A (en) | 2005-02-25 | 2006-09-07 | Nippon Ester Co Ltd | Copolyester |
US7807775B2 (en) | 2005-06-17 | 2010-10-05 | Eastman Chemical Company | Point of purchase displays comprising polyester compositions formed from 2,2,4,4-tetramethyl-1, 3,-cyclobutanediol and 1,4-cyclohexanedimethanol |
US7375144B2 (en) | 2005-06-16 | 2008-05-20 | Eastman Chemical Company | Abrasion resistant coatings |
US7470500B2 (en) | 2005-07-19 | 2008-12-30 | Az Electronic Materials Usa Corp. | Organic bottom antireflective polymer compositions |
US8586701B2 (en) | 2005-10-28 | 2013-11-19 | Eastman Chemical Company | Process for the preparation of copolyesters based on 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
US20080139687A1 (en) | 2005-11-10 | 2008-06-12 | Henkel Corporation | Vinyl Ether/Acrylate Block Resins, Compositions and Methods of Making Same |
US7915319B2 (en) | 2005-12-19 | 2011-03-29 | Henkel Corporation | Visible light curing systems, methods for reducing health risks to individuals exposed to systems designed to cure curable compositions by exposure to radiation, methods for bonding substrates and visible light curing compositions |
US8163850B2 (en) | 2009-02-06 | 2012-04-24 | Eastman Chemical Company | Thermosetting polyester coating compositions containing tetramethyl cyclobutanediol |
US8168721B2 (en) | 2009-02-06 | 2012-05-01 | Eastman Chemical Company | Coating compositions containing tetramethyl cyclobutanediol |
US9029460B2 (en) * | 2009-02-06 | 2015-05-12 | Stacey James Marsh | Coating compositions containing acrylic and aliphatic polyester blends |
US9029461B2 (en) * | 2009-02-06 | 2015-05-12 | Eastman Chemical Company | Aliphatic polyester coating compositions containing tetramethyl cyclobutanediol |
US8324316B2 (en) | 2009-02-06 | 2012-12-04 | Eastman Chemical Company | Unsaturated polyester resin compositions containing 2,2,2,4-tetramethyl-1,3-cyclobutanediol and articles made therefrom |
-
2009
- 2009-02-06 US US12/367,190 patent/US9029461B2/en active Active
-
2010
- 2010-01-27 BR BRPI1007304A patent/BRPI1007304A2/en not_active IP Right Cessation
- 2010-01-27 EP EP10703372A patent/EP2393865A1/en not_active Withdrawn
- 2010-01-27 WO PCT/US2010/000213 patent/WO2010090712A1/en active Application Filing
- 2010-01-27 CN CN201080006610.2A patent/CN102307928B/en active Active
- 2010-01-27 CA CA2750516A patent/CA2750516A1/en not_active Abandoned
- 2010-01-27 MX MX2011007470A patent/MX2011007470A/en active IP Right Grant
- 2010-01-27 JP JP2011549145A patent/JP5462285B2/en not_active Expired - Fee Related
- 2010-01-27 KR KR1020117020262A patent/KR20110127171A/en not_active Application Discontinuation
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- 2014-06-16 US US14/305,411 patent/US20140296407A1/en not_active Abandoned
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3345313A (en) | 1963-02-20 | 1967-10-03 | Trojan Powder Co | Alkyd resins and their preparation from reaction mixtures comprising a polymethylolalkanoic acid |
US4737551A (en) | 1986-06-23 | 1988-04-12 | E. I. Dupont De Nemours And Company | Coating composition of a hydroxy group-containing modified polyester with polymerized lactone monomers |
US4698391A (en) | 1986-07-30 | 1987-10-06 | Eastman Kodak Company | Crosslinked polymers with lowered resistivity and materials and methods for their preparation |
US5097006A (en) * | 1990-11-21 | 1992-03-17 | U C B S.A. | Weatherable powder coating compositions |
US5596037A (en) * | 1992-03-16 | 1997-01-21 | U C B S.A. | Carboxyl-terminated polyesters for the preparation of powder coating compositions |
US5349026A (en) | 1992-11-20 | 1994-09-20 | Rohm And Haas Company | Reactive coalescents |
US5371148A (en) | 1993-06-23 | 1994-12-06 | Union Carbide Chemicals & Plastics Technology Corporation | Reactive polymers having pendant flexible side chains prepared from ethylenically unsaturated carbodiimides |
US20070232778A1 (en) * | 2006-03-28 | 2007-10-04 | Leslie Shane Moody | Certain polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and high trans-cyclohexanedicarboxylic acid |
Non-Patent Citations (8)
Title |
---|
"Colour Index", 1982, SOCIETY OF DYERS |
"Organic Coatings Science and Technology", 1999, WILEY, pages: 246 - 257 |
"Raw Material Index and Buyer's Guide", NATIONAL PAINT & COATINGS ASSOCIATION |
"Resins for Surface Coatings", vol. 111, 1987, SITA TECHNOLOGY, pages: 63 - 167 |
"Resins for Surface Coatings", vol. II, 1987, SITA TECHNOLOGY, pages: 121 - 210 |
"Technical Publication", 2005, BAYER MATERIAL SCIENCE, article "The Chemistry of Polyurethane Coatings", pages: 20 |
See also references of EP2393865A1 |
Z. WICKS; F. JONES; S. PAPPAS: "Organic Coatings Science and Technology", 1999, WILEY, pages: 246 - 257 |
Cited By (2)
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EP3760658A1 (en) | 2019-07-03 | 2021-01-06 | Covestro Deutschland AG | Resistant 2k-pur coatings |
WO2021001270A1 (en) | 2019-07-03 | 2021-01-07 | Covestro Intellectual Property Gmbh & Co. Kg | Resistant 2k-pur coatings |
Also Published As
Publication number | Publication date |
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MX2011007470A (en) | 2011-08-03 |
CN102307928A (en) | 2012-01-04 |
EP2393865A1 (en) | 2011-12-14 |
US20140296407A1 (en) | 2014-10-02 |
US20100204401A1 (en) | 2010-08-12 |
US9029461B2 (en) | 2015-05-12 |
JP5462285B2 (en) | 2014-04-02 |
CN102307928B (en) | 2014-05-07 |
JP2012517497A (en) | 2012-08-02 |
BRPI1007304A2 (en) | 2016-02-10 |
CA2750516A1 (en) | 2010-08-12 |
KR20110127171A (en) | 2011-11-24 |
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