WO2011049929A3 - High performance guar for hydraulic fracturing and other applications - Google Patents
High performance guar for hydraulic fracturing and other applications Download PDFInfo
- Publication number
- WO2011049929A3 WO2011049929A3 PCT/US2010/053163 US2010053163W WO2011049929A3 WO 2011049929 A3 WO2011049929 A3 WO 2011049929A3 US 2010053163 W US2010053163 W US 2010053163W WO 2011049929 A3 WO2011049929 A3 WO 2011049929A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- guar
- produced
- less
- hydraulic fracturing
- applications
- Prior art date
Links
- 244000007835 Cyamopsis tetragonoloba Species 0.000 title abstract 9
- 229920002907 Guar gum Polymers 0.000 abstract 2
- 229960002154 guar gum Drugs 0.000 abstract 2
- 235000010417 guar gum Nutrition 0.000 abstract 2
- 239000000665 guar gum Substances 0.000 abstract 2
- 238000010008 shearing Methods 0.000 abstract 2
- 239000005997 Calcium carbide Substances 0.000 abstract 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 abstract 1
- 230000036571 hydration Effects 0.000 abstract 1
- 238000006703 hydration reaction Methods 0.000 abstract 1
- 238000011068 loading method Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 238000002791 soaking Methods 0.000 abstract 1
- CLZWAWBPWVRRGI-UHFFFAOYSA-N tert-butyl 2-[2-[2-[2-[bis[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]amino]-5-bromophenoxy]ethoxy]-4-methyl-n-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]anilino]acetate Chemical compound CC1=CC=C(N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)C(OCCOC=2C(=CC=C(Br)C=2)N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)=C1 CLZWAWBPWVRRGI-UHFFFAOYSA-N 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/62—Compositions for forming crevices or fractures
- C09K8/70—Compositions for forming crevices or fractures characterised by their form or by the form of their components, e.g. foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/006—Heteroglycans, i.e. polysaccharides having more than one sugar residue in the main chain in either alternating or less regular sequence; Gellans; Succinoglycans; Arabinogalactans; Tragacanth or gum tragacanth or traganth from Astragalus; Gum Karaya from Sterculia urens; Gum Ghatti from Anogeissus latifolia; Derivatives thereof
- C08B37/0087—Glucomannans or galactomannans; Tara or tara gum, i.e. D-mannose and D-galactose units, e.g. from Cesalpinia spinosa; Tamarind gum, i.e. D-galactose, D-glucose and D-xylose units, e.g. from Tamarindus indica; Gum Arabic, i.e. L-arabinose, L-rhamnose, D-galactose and D-glucuronic acid units, e.g. from Acacia Senegal or Acacia Seyal; Derivatives thereof
- C08B37/0096—Guar, guar gum, guar flour, guaran, i.e. (beta-1,4) linked D-mannose units in the main chain branched with D-galactose units in (alpha-1,6), e.g. from Cyamopsis Tetragonolobus; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L5/00—Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/62—Compositions for forming crevices or fractures
- C09K8/66—Compositions based on water or polar solvents
- C09K8/68—Compositions based on water or polar solvents containing organic compounds
- C09K8/685—Compositions based on water or polar solvents containing organic compounds containing cross-linking agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/84—Compositions based on water or polar solvents
- C09K8/86—Compositions based on water or polar solvents containing organic compounds
- C09K8/88—Compositions based on water or polar solvents containing organic compounds macromolecular compounds
- C09K8/90—Compositions based on water or polar solvents containing organic compounds macromolecular compounds of natural origin, e.g. polysaccharides, cellulose
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2305/00—Characterised by the use of polysaccharides or of their derivatives not provided for in groups C08J2301/00 or C08J2303/00
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH DRILLING; MINING
- E21B—EARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/25—Methods for stimulating production
- E21B43/26—Methods for stimulating production by forming crevices or fractures
- E21B43/2607—Surface equipment specially adapted for fracturing operations
Abstract
A process and the guar produced thereby, the guar having superior performance in hydraulic fracturing applications. The guar is produced by first washing, soaking, and prehydrating guar gum splits in hot water. Calcium carbide which is then added to the mixture results in the production of acetylene gas, forcing the guar cells to open during shearing. Shearing the guar gum splits produces flakes, which are then ground and sieved. The fine guar particles produced are spherical in shape, with improved hydration viscosity, and better cross-linking performance than guars presently available. An operator can use twenty-percent (20%) less guar to create the same fracturing geometry, resulting in less formation damage. The improved guar can even be used at ultra low loadings. Further, it leaves less residue after break.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/589,316 US20110092696A1 (en) | 2009-10-21 | 2009-10-21 | High performance low residue guar for hydraulic fracturing and other applications |
US12/589,316 | 2009-10-21 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2011049929A2 WO2011049929A2 (en) | 2011-04-28 |
WO2011049929A3 true WO2011049929A3 (en) | 2011-06-09 |
Family
ID=43759945
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2010/053163 WO2011049929A2 (en) | 2009-10-21 | 2010-10-19 | High performance guar for hydraulic fracturing and other applications |
Country Status (2)
Country | Link |
---|---|
US (1) | US20110092696A1 (en) |
WO (1) | WO2011049929A2 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9194223B2 (en) * | 2009-12-18 | 2015-11-24 | Baker Hughes Incorporated | Method of fracturing subterranean formations with crosslinked fluid |
US8371383B2 (en) * | 2009-12-18 | 2013-02-12 | Baker Hughes Incorporated | Method of fracturing subterranean formations with crosslinked fluid |
WO2019236071A1 (en) | 2018-06-05 | 2019-12-12 | Economy Mud Products Company | Process for making and using a composition of matter |
CN109233782B (en) * | 2018-10-08 | 2021-06-08 | 中国石油集团渤海钻探工程有限公司 | Fracturing fluid suitable for hot water preparation and preparation method thereof |
CN109722235B (en) * | 2018-10-17 | 2021-09-28 | 中国石油天然气股份有限公司 | Guanidine gum fracturing fluid system prepared from thickened oil hot water and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4269975A (en) * | 1980-03-10 | 1981-05-26 | National Starch And Chemical Corporation | Preparation of guar gum |
US20060068994A1 (en) * | 2004-09-30 | 2006-03-30 | Subramanian Kesavan | Fast hydrating guar powder, method of preparation, and methods of use |
US20070123432A1 (en) * | 2005-11-30 | 2007-05-31 | Halliburton Energy Services, Inc. | Compositions and methods for producing guar gum and for using the guar gum in treating a subterranean formation |
US20080203199A1 (en) * | 2007-02-07 | 2008-08-28 | Imation Corp. | Processing of a guar dispersion for particle size reduction |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3303074A (en) * | 1965-12-06 | 1967-02-07 | Trojan Powder Co | Aqueous explosives slurries containing sulfur compounds having a low coefficient of expansion |
US3912713A (en) * | 1973-08-29 | 1975-10-14 | Scholten Honig Research Nv | Guar gum derivatives and process for preparation |
US4514309A (en) * | 1982-12-27 | 1985-04-30 | Hughes Tool Company | Cross-linking system for water based well fracturing fluids |
US5681796A (en) * | 1994-07-29 | 1997-10-28 | Schlumberger Technology Corporation | Borate crosslinked fracturing fluid and method |
AU751713B2 (en) * | 1997-05-27 | 2002-08-22 | Bj Services Company | Improved polymer expansion for oil and gas recovery |
US20030008780A1 (en) * | 2000-02-09 | 2003-01-09 | Economy Mud Products Company | Method and product for use of guar powder in treating subterranean formations |
US20030017952A1 (en) * | 2000-02-09 | 2003-01-23 | Chowdhary Manjit S. | Hydration of guar gum powder |
US20030054963A1 (en) * | 2000-02-09 | 2003-03-20 | Economy Mud Products Company | Method and product for use of guar powder in treating subterranean formations |
US6844296B2 (en) * | 2001-06-22 | 2005-01-18 | Bj Services Company | Fracturing fluids and methods of making and using same |
US6810959B1 (en) * | 2002-03-22 | 2004-11-02 | Bj Services Company, U.S.A. | Low residue well treatment fluids and methods of use |
US7637322B2 (en) * | 2005-01-13 | 2009-12-29 | Halliburton Energy Services, Inc. | Methods and compositions for enhancing guar hydration rates and performing guar derivitization reactions |
US7585819B2 (en) * | 2006-10-05 | 2009-09-08 | Halliburton Energy Services, Inc. | Methods for producing a guar gum comprising undehusked guar and for using the guar gum in treating a subterranean formation |
US7790774B1 (en) * | 2007-03-16 | 2010-09-07 | Benchmark Energy Products, LLC | Preparation of guar suspension from guar splits |
-
2009
- 2009-10-21 US US12/589,316 patent/US20110092696A1/en not_active Abandoned
-
2010
- 2010-10-19 WO PCT/US2010/053163 patent/WO2011049929A2/en active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4269975A (en) * | 1980-03-10 | 1981-05-26 | National Starch And Chemical Corporation | Preparation of guar gum |
US20060068994A1 (en) * | 2004-09-30 | 2006-03-30 | Subramanian Kesavan | Fast hydrating guar powder, method of preparation, and methods of use |
US20070123432A1 (en) * | 2005-11-30 | 2007-05-31 | Halliburton Energy Services, Inc. | Compositions and methods for producing guar gum and for using the guar gum in treating a subterranean formation |
US20080203199A1 (en) * | 2007-02-07 | 2008-08-28 | Imation Corp. | Processing of a guar dispersion for particle size reduction |
Also Published As
Publication number | Publication date |
---|---|
US20110092696A1 (en) | 2011-04-21 |
WO2011049929A2 (en) | 2011-04-28 |
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