WO2011056938A1 - Laundry scent additive - Google Patents
Laundry scent additive Download PDFInfo
- Publication number
- WO2011056938A1 WO2011056938A1 PCT/US2010/055398 US2010055398W WO2011056938A1 WO 2011056938 A1 WO2011056938 A1 WO 2011056938A1 US 2010055398 W US2010055398 W US 2010055398W WO 2011056938 A1 WO2011056938 A1 WO 2011056938A1
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- WO
- WIPO (PCT)
- Prior art keywords
- composition
- perfume
- weight
- pastilles
- polyethylene glycol
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/08—Liquid soap, e.g. for dispensers; capsuled
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/40—Products in which the composition is not well defined
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
Definitions
- the present invention relates to products to freshen laundry.
- An embodiment of the invention can be a composition consisting essentially of: (a) from about 80 % to about 91 % by weight of the composition of polyethylene glycol, wherein the polyethylene glycol has a molecular weight from about 5,000 to about 11,000; (b) from about 2 % to about 12 % by weight of the composition free perfume; and (c) from about 2 % to about 12 % by weight of the composition of friable perfume microcapsule, wherein the perfume microcapsule comprises encapsulated perfume; wherein the composition is shaped in a pastille having a mass from about 0.95 mg to about 2 g.
- An additional embodiment of the invention can be a unit dose of a fabric treatment composition comprising a plurality of pastilles, wherein each pastille comprises: (a) from about 80 % to about 91 % by weight of the composition of polyethylene glycol, wherein the polyethylene glycol has a molecular weight from about 5,000 to about 11,000; (b) from about 2 % to about 12 % by weight of the composition free perfume; and (c) from about 2 % to about 12 % by weight of the composition of friable perfume microcapsule, wherein the perfume microcapsule comprises encapsulated perfume; wherein each pastille has a mass from about 0.95 mg to about 2 g; and wherein the plurality of pastilles has a mass from about 13 g to about 27 g to comprise the unit dose.
- An additional embodiment of the invention can be a composition consisting essentially of: (a) from about 80 % to about 91 % by weight of the composition of polyethylene glycol, wherein the polyethylene glycol has a molecular weight from about 5,000 to about 11,000; and (b) from about 9 % to about 20 wt% of friable perfume microcapsule, wherein the perfume microcapsule comprises encapsulated perfume; wherein the composition is essentially free of free perfume; and wherein the composition is shaped in a pastille having a mass from about 0.95 mg to about 2 g.
- An additional embodiment of the invention can be a composition consisting essentially of: (a) from about 80 % to about 91 % by weight of the composition of polyethylene glycol, wherein the polyethylene glycol has a molecular weight from about 5,000 to about 11,000; and
- composition (b) from about 9 % to about 20 % by weight of the composition free perfume; wherein the composition is essentially free of a perfume carrier; and wherein the composition is shaped in a pastille having a mass from about 0.95 mg to about 2 g.
- An additional embodiment of the invention can be a method of making a composition comprising the steps of: providing a viscous material having a glass transition temperature ,the viscous material comprising: (a) from about 80 % to about 91 % by weight of the composition of polyethylene glycol, wherein the polyethylene glycol has a molecular weight from about 5,000 to about 11,000; (b) from about 2 % to about 12 % by weight of the composition free perfume; and
- FIG. 1 is a schematic of a pastillation apparatus.
- compositions of the present invention may comprise: polyethylene glycol; free perfume and/or perfume microcapsules; and optionally a dye.
- the composition is essentially free of detergent surfactants and/or fabric softening actives.
- Polyethylene glycol has a relatively low cost, may be formed into many different shapes and sizes, minimizes free perfume diffusion, and dissolves well in water. PEG comes in various molecular weights.
- a suitable molecular weight range of PEG for the purposes of freshening laundry includes from about 3,000 to about 13,000, from about 4,000 to about 12,000, alternatively from about 5,000 to about 11,000, alternatively from about 6,000 to about 10,000, alternatively from about 6,000 to about 10,000, alternatively from about 7,000 to about 9,000, alternatively combinations thereof.
- PEG is available from BASF, for example PLURIOL E 8000.
- compositions of the present invention may comprise from about 65 % to about 99 % by weight of the composition of PEG.
- the composition can comprise from about 80 % to about 91 %, alternatively from about 85 % to about 91 %, more than about 75 %, alternatively from about 70 % to about 98 %, alternatively from about 80 % to about 95 %, alternatively combinations thereof, of PEG by weight of the composition.
- compositions of the present invention may comprise a free perfume and/or a perfume microcapsule.
- Perfumes are generally described in U.S. Patent No. 7,186,680 at column 10, line 56, to column 25, line 22.
- the composition comprises free perfume and is essentially free of perfume carriers, such as a perfume microcapsule.
- the composition comprises perfume carrier materials (and perfume contained therein). Examples of perfume carrier materials are described in U.S. Patent No. 7,186,680, column 25, line 23, to column 31, line 7. Specific examples of perfume carrier materials may include cyclodextrin and zeolites.
- the composition comprises free (neat) perfume but is free or essentially free of a perfume carrier.
- the composition may comprise less than about 20%, alternatively less than about 25 %, alternatively from about 9% to about 20%, alternatively from about 10% to about 18%, alternatively from about 11% to about 13%, alternatively combinations thereof, of free perfume by weight of the composition.
- the composition consists essentially of: (a) from about 80 % to about 91 % by weight of the composition of polyethylene glycol, wherein the polyethylene glycol has a molecular weight from about 5,000 to about 11,000; and (b) from about 9% to about 20% by weight of the composition free perfume; wherein the composition is essentially free of a perfume carrier; and wherein the composition is shaped in a pastille having a mass from about 0.95 mg to about 2 g.
- the composition consists essentially of: (a) more than about 75 % by weight of the composition of polyethylene glycol, wherein the polyethylene glycol has a molecular weight from about 5,000 to about 11,000; and (b) less than about 25 % by weight of the composition free perfume; wherein the composition is essentially free of a perfume carrier; and wherein the composition is shaped in a pastille having a mass from about 0.95 mg to about 2 g.
- the composition comprises free perfume and perfume microcapsules.
- the composition may comprise from about 2 % to about 12 %, alternatively from about 1 % to about 10 %, alternatively from about 3 % to about 8 %, alternatively from about 4 % to about 7 %, alternatively from about 5 % to about 7 %, alternatively combinations thereof, of the free perfume by weight of the composition.
- the composition comprises free (neat) perfume and a perfume microcapsule but is free or essentially free of other perfume carriers.
- compositions of the present invention can comprise perfume oil encapsulated in a perfume microcapsule (PMC).
- PMC perfume microcapsule
- the PMC can be a friable PMC.
- PMC and “perfume microcapsule” are used interchangeably and refers to a plurality of perfume microcapsules.
- Suitable perfume microcapsules and perfume nanocapsules can include: U.S. Patent Publication Nos. 2003215417 Al; 2003216488 Al; 2003158344 Al; 2003165692 Al; 2004071742 Al; 2004071746 Al; 2004072719 Al; 2004072720 Al; 2003203829 Al; 2003195133 Al;
- the term "perfume microcapsules" or “PMC” describes both perfume microcapsules and perfume nanocapsules.
- the PMCs can be friable (verses, for example, moisture activated PMCs).
- the PMCs can be moisture activated.
- the PMC comprises a melamine/formaldehyde shell.
- Encapsulated perfume and/or PMC may be obtained from Appleton, Quest International, or International Flavor & Fragrances, or other suitable source.
- the PMC shell is coated with polymer to enhance the ability of the PMCs to adhere to fabric, as describe in U.S. Patent Nos. 7,125,835; 7,196,049; and 7,119,057.
- the composition comprises a PMC but is free or essentially free or free of (neat) perfume.
- the composition may comprise less than about 20 %, alternatively less than about 25 %, alternatively from about 9% to about 20%, alternatively from about 9 % to about 15 %, alternatively from about 10 % to about 14 %, alternatively from about 11 % to about 13 %, alternatively combinations thereof, of PMC (including the encapsulated perfume) by weight of the composition.
- the perfume encapsulated by the PMC may comprise from about 0.6 % to about 4 % of perfume by weight of the composition.
- the composition consists essentially of: (a) from about 80 % to about 91 % by weight of the composition of polyethylene glycol, wherein the polyethylene glycol has a molecular weight from about 5,000 to about 11,000; and (b) from about 9 % to about 20 % by weight of the composition of a friable perfume microcapsule, wherein the perfume microcapsule comprises encapsulated perfume; wherein the composition is essentially free of free perfume; and wherein the composition is shaped in a pastille having a mass from about 0.95 mg to about 2 g.
- the perfume encapsulated by the PMC may comprise from about 0.6 % to about 4 % of perfume by weight of the composition.
- the composition comprises PMC and free perfume.
- the composition may comprise from about 1 % to about 10 %, alternatively from about 2 % to about 12 %, alternatively from about 2 % to about 8 %, alternatively from about 3 % to about 8 %, alternatively from about 4 % to about 7 %, alternatively from about 5 % to about 7 %, alternatively combinations thereof, of PMC (including the encapsulated perfume) by weight of the composition.
- the perfume encapsulated by the PMC may comprise from about 0.6 % to about 4 % of perfume by weight of the composition.
- the composition may consist essentially of: (a) from about 80 % to about 91 % by weight of the composition of polyethylene glycol, wherein the polyethylene glycol has a molecular weight from about 5,000 to about 11,000; (b) from about 2 % to about 12 % by weight of the composition free perfume; and (c) from about 2 % to about 12 % by weight of the composition of friable perfume microcapsule, wherein the perfume microcapsule comprises encapsulated perfume; wherein the composition is shaped in a pastille having a mass from about 0.95 mg to about 2 g.
- the perfume encapsulated by the PMC may comprise from about 0.6 % to about 4 % of perfume by weight of the composition.
- the composition comprises (a) from about 80 % to about 91 % by weight of the composition of polyethylene glycol, wherein the polyethylene glycol has a molecular weight from about 5,000 to about 11,000; (b) from about 2 % to about 12 % by weight of the composition free perfume; and (c) from about 2 % to about 12 % by weight of the composition of a friable perfume microcapsule, wherein the perfume microcapsule comprises encapsulated perfume; wherein the composition is shaped in a pastille, each of the pastilles has a mass from about 0.95 mg to about 2 g.
- a formulation is thought to provide for a balanced scent experience to the user of the composition.
- the about 2% to about 12% by weight of the composition of free perfume can provide for a pleasant scent experience to the user upon opening of the package containing the composition and as the user pours the composition into a dosing device and transfers the composition to her washing machine. That is the user can experience the scent at an appreciably detectable level but is not overwhelmed by the scent.
- the about 2% to about 12% by weight of the composition of friable perfume microcapsule can provide physical and/or chemical stability of the pastille and for a sufficient quantity of friable perfume microcapsule to deposit on a user' s clothing during washing when the pastilles are applied in the wash in a unit dose.
- compositions can be beneficial for the composition to consist essentially of the above ingredients at the prescribed levels as additional components might interfere with the physical and/or chemical stability of the pastilles and recognizing that other components, such as surfactants, fabric softeners, or other such ingredients, might be delivered by other mechanisms, such as the detergent or dryer added product, and there would be the potential that the user might over apply such ingredients during washing and/or drying.
- additional components such as surfactants, fabric softeners, or other such ingredients
- the composition can comprise perfume microcapsule but is free or essentially free of other perfume carriers and/or free (neat) perfume.
- the composition may comprise a formaldehyde scavenger.
- the scent of the present composition is coordinated with scent(s) of other fabric care products (e.g., laundry detergent, fabric softener). This way, consumers who like APRIL FRESH scent, may use a pastille having an APRIL FRESH scent, thereby coordinating the scent experience of washing their laundry with their scent experience from using APRIL FRESH.
- the pastilles of the present invention may be sold as a product array (with laundry detergent and/or fabric softener) having coordinated scents.
- the composition may comprise dye.
- the dye may include those that are typically used in laundry detergent or fabric softeners.
- the composition may comprises from about 0.001 % to about 0.1 %, alternatively from about 0.01 % to about 0.02 %, alternatively combinations thereof, of dye by weight of the composition.
- An example of a dye includes LIQUITINT BLUE BL from Millikin Chemical., Free of Laundry Actives and Softeners
- the composition may be free of laundry active and/or fabric softener actives.
- one aspect of the invention may include compositions that are free or essentially free of laundry actives and/or fabric softener actives.
- the composition comprises less than about 3 %, alternatively less than about 2 % by weight of the composition, alternatively less than about 1 % by weight of the composition, alternatively less than about 0.1 % by weight of the composition, alternatively are about free, of laundry actives and/or fabric softener actives (or combinations thereof).
- a laundry active includes: detergent surfactants, detergent builders, bleaching agents, enzymes, mixtures thereof, and the like. It is appreciated that a non-detersive level of surfactant may be used to help solubilize perfume contained in the composition.
- the composition of the present invention may be formed into pastilles by those methods known in the art, including methods disclosed in U.S. Patent Nos. 5,013,498 and 5,770,235.
- the composition of the present invention may be prepared in either batch or continuous mode.
- batch mode molten PEG is loaded into a mixing vessel having temperature control.
- PMC is then added and mixed with PEG until homogeneous.
- Perfume is then added to the vessel and the components are further mixed for a period of time until the entire mixture is homogeneous.
- molten PEG is mixed with perfume and PMC in an in-line mixer such as a static mixer or a high shear mixer and the resulting homogeneous mixture is then used for pastillation.
- PMC and perfume can be added to PEG in any order or simultaneously and dye can be added at a step prior to pastillation.
- the pastilles may be formed into different shapes include tablets, pills, spheres, and the like.
- a pastille can have a shape selected from the group consisting of spherical, hemispherical, compressed hemispherical, lentil shaped, and oblong.
- Lentil shaped refers to the shape of a lentil bean.
- Compressed hemispherical refers to a shape corresponding to a hemisphere that is at least partially flattened such that the curvature of the curved surface is less, on average, than the curvature of a hemisphere having the same radius.
- a compressed hemispherical pastille can have a ratio of height to diameter of from about 0.01 to about 0.4, alternatively from about 0.1 to about 0.4, alternatively from about 0.2 to about 0.3.
- Oblong shaped refers to a shape having a maximum dimension and a maximum secondary dimension orthogonal to the maximum dimension, wherein the ratio of maximum dimension to the maximum secondary dimension is greater than about 1.2.
- An oblong shape can have a ratio of maximum dimension to maximum secondary dimension greater than about 1.5.
- An oblong shape can have a ratio of maximum dimension to maximum secondary dimension greater than about 2.
- Oblong shaped particles can have a maximum dimension from about 2 mm to about 6 mm, a maximum secondary dimension of from about 2 mm to about 4 mm.
- each individual pastille can have a mass from about 0.95 mg to about 2 g, alternatively from about 10 mg to about 1 g, alternatively from about 10 mg to about 500 mg, alternatively from about 10 mg to about 250 mg, alternatively from about 0.95 mg to about 125 mg, alternatively combinations thereof.
- individual pastilles can have a shape selected from the group consisting of spherical, hemispherical, compressed hemispherical, lentil shaped, and oblong.
- An individual pastille may have a volume from about 0.003 cm 3 to about 0.15 cm 3 .
- a plurality of pastilles may collectively comprise a unit dose for dosing to a laundry washing machine or laundry was basin.
- a single unit dose of the pastilles may comprise from about 13 g to about 27 g, alternatively from about 14 g to about 20 g, alternatively from about 15 g to about 19 g, alternatively from about 16 g to about 18 g, alternatively combinations thereof.
- the individual pastilles forming the plurality of pastilles that make up the unit dose can each have a mass from about 0.95 mg to about 2 g.
- the plurality of pastilles can be made up of pastilles of different size, shape, and/or mass.
- the pastilles in a unit dose can have a maximum dimension less than about 1 centimeter.
- the composition may be manufactured by a pastillation process.
- a schematic of a pastillation apparatus 100 is illustrated in FIG. 1.
- the steps of manufacturing according to such process can comprise providing the desired formulation as a viscous material 50.
- the viscous material 50 can comprise or consists of any of the possible formulations disclosed herein.
- the viscous material 50 comprises: (a) from about 80 % to about 91 % by weight of the composition of polyethylene glycol, wherein the polyethylene glycol has a molecular weight from about 5,000 to about 11,000; (b) from about 2 % to about 12 % by weight of the composition free perfume; and (c) from about 2 % to about 12 % by weight of the composition of friable perfume microcapsule, wherein the perfume microcapsule comprises encapsulated perfume.
- the viscous material 50 can be provided at a processing temperature less than about 20 degrees Celsius above the onset of solidification temperature as determined by differential scanning calorimetry.
- the PMC can be added as a slurry to the polyethylene glycol and free perfume to form the viscous material 50.
- the PMC can be added as a powder to the
- the viscous material 50 is passed through small openings 10 and onto a moving conveyor surface 20 upon which the viscous material 50 is cooled below the glass transition temperature to form a plurality of pastilles 30.
- the small openings 10 can be on a rotatable pastillation roll 5.
- Viscous material 50 can be distributed to the small openings 10 by a viscous material distributor 40.
- Pastilles can be formed on a ROTOFORMER, available from Sandvik Materials Technology.
- a unit dose or a plurality of unit doses may be contained in a package.
- the package may be a bottle, bag, or other container.
- the package is a bottle, preferably a PET bottle comprising a translucent portion to showcase the pastilles to a viewing consumer.
- the package comprises a single unit dose (e.g., trial size sachet); or multiple unit doses (e.g., from about 15 unit doses to about 30 unit doses).
- the aforementioned package may comprise a dosing means for dispensing the pastilles from the package to a laundry washing machine (or laundry wash basin in hand washing applications).
- the user may use the dosing means to meter the recommended unit dose amount or simply use the dosing means to meter the pastilles according to the user's own scent preference.
- Examples of a dosing means may be a dispensing cap, dome, or the like, that is functionally attached to the package.
- the dosing means can be releasably detachable from the package and re-attachable to the package, such as for example, a cup mountable on the package.
- the dosing means may be tethered (e.g., by hinge or string) to the rest of the package (or alternatively un-tethered).
- the dosing means may have one or more demarcations (e.g., fill-line) to indicate a recommend unit dose amount.
- the packaging may include instructions instructing the user to open the removable opening of the package, and dispense (e.g., pour) the pastilles contained in the package into the dosing means. Thereafter, the user may be instructed to dose the pastilles contained in the dosing means to a laundry washing machine or laundry wash basin.
- the pastille of the present invention may be used to add freshness to laundry.
- the package including the dosing means may be made of plastic.
- One embodiment can be a unit dose of a fabric treatment composition comprising a plurality of pastilles, wherein each pastille comprises: (a) from about 80 % to about 91 % by weight of the composition of polyethylene glycol, wherein the polyethylene glycol has a molecular weight from about 5,000 to about 11,000; (b) from about 2 % to about 12 % by weight of the composition free perfume; and (c) from about 2 % to about 12 % by weight of the composition of friable perfume microcapsule, wherein the perfume microcapsule comprises encapsulated perfume; wherein each pastille has a mass from about 0.95 mg to about 2 g; and wherein the plurality of pastilles has a mass from about 13 g to about 27 g to comprise the unit dose.
- the pastilles of the present invention can be administered to a laundry machine as used during the "wash cycle" of the washing machine (but a "rinse cycle” may also be used).
- the pastilles of the present invention are administered in a laundry wash basin - during washing and/or rinsing laundry.
- the pastille may further comprise an "antifoam agent" such as those available from Wacker. Antifoam agents (suds suppressing systems) are described in U.S. Patent Publication No. 20030060389 at 65 - 77.
- PMC is a friable PMC with a urea-formaldehyde shell from Appleton. About 50% water by weight of the PMC (including encapsulated perfume) is assumed.
Abstract
Description
Claims
Priority Applications (23)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2012537983A JP5485409B2 (en) | 2009-11-05 | 2010-11-04 | Laundry fragrance additive |
EP10779153.5A EP2496679B1 (en) | 2009-11-05 | 2010-11-04 | Laundry scent additive |
PL10779153T PL2496679T3 (en) | 2009-11-05 | 2010-11-04 | Laundry scent additive |
MX2012005260A MX2012005260A (en) | 2009-11-05 | 2010-11-04 | Laundry scent additive. |
CN2010800506935A CN102597204A (en) | 2009-11-05 | 2010-11-04 | Laundry scent additive |
BR112012010572A BR112012010572A2 (en) | 2009-11-05 | 2010-11-04 | aromatic laundry additive. |
KR1020127011519A KR101442508B1 (en) | 2009-11-05 | 2010-11-04 | Laundry scent additive |
US13/462,157 US8476219B2 (en) | 2009-11-05 | 2012-05-02 | Laundry scent additive |
US13/908,514 US9708574B2 (en) | 2009-11-05 | 2013-06-03 | Laundry scent additive |
US14/876,249 US9453189B2 (en) | 2009-11-05 | 2015-10-06 | Laundry scent additive |
US15/626,482 US10167441B2 (en) | 2009-11-05 | 2017-06-19 | Laundry scent additive |
US16/201,596 US11142728B2 (en) | 2009-11-05 | 2018-11-27 | Laundry scent additive |
US17/471,590 US11608481B2 (en) | 2009-11-05 | 2021-09-10 | Laundry scent additive |
US18/109,621 US11859159B2 (en) | 2009-11-05 | 2023-02-14 | Laundry scent additive |
US18/122,378 US20230287309A1 (en) | 2009-11-05 | 2023-03-16 | Laundry scent additive |
US18/122,851 US20230295536A1 (en) | 2009-11-05 | 2023-03-17 | Laundry scent additive |
US18/122,797 US20230295535A1 (en) | 2009-11-05 | 2023-03-17 | Laundry scent additive |
US18/127,878 US20230287310A1 (en) | 2009-11-05 | 2023-03-29 | Laundry scent additive |
US18/143,330 US11834637B2 (en) | 2009-11-05 | 2023-05-04 | Laundry scent additive |
US18/484,094 US20240034964A1 (en) | 2009-11-05 | 2023-10-10 | Laundry scent additive |
US18/378,833 US20240034963A1 (en) | 2009-11-05 | 2023-10-11 | Laundry scent additive |
US18/488,460 US20240043776A1 (en) | 2009-11-05 | 2023-10-17 | Laundry scent additive |
US18/538,837 US20240110133A1 (en) | 2009-11-05 | 2023-12-13 | Laundry scent additive |
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CA2682636A CA2682636C (en) | 2009-11-05 | 2009-11-05 | Laundry scent additive |
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US13/462,157 Continuation US8476219B2 (en) | 2009-11-05 | 2012-05-02 | Laundry scent additive |
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EP (1) | EP2496679B1 (en) |
JP (1) | JP5485409B2 (en) |
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CN (2) | CN106987461A (en) |
BR (1) | BR112012010572A2 (en) |
CA (1) | CA2682636C (en) |
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KR20120080232A (en) | 2012-07-16 |
CA2682636A1 (en) | 2010-01-11 |
CA2682636C (en) | 2010-06-15 |
MX2012005260A (en) | 2012-06-14 |
CN106987461A (en) | 2017-07-28 |
EP2496679B1 (en) | 2014-10-29 |
US7871976B1 (en) | 2011-01-18 |
KR101442508B1 (en) | 2014-09-22 |
CN102597204A (en) | 2012-07-18 |
PL2496679T3 (en) | 2015-03-31 |
JP5485409B2 (en) | 2014-05-07 |
EP2496679A1 (en) | 2012-09-12 |
US7867968B1 (en) | 2011-01-11 |
JP2013509508A (en) | 2013-03-14 |
BR112012010572A2 (en) | 2016-03-22 |
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