WO2011072665A1 - Burner for a turbine - Google Patents
Burner for a turbine Download PDFInfo
- Publication number
- WO2011072665A1 WO2011072665A1 PCT/DE2010/050074 DE2010050074W WO2011072665A1 WO 2011072665 A1 WO2011072665 A1 WO 2011072665A1 DE 2010050074 W DE2010050074 W DE 2010050074W WO 2011072665 A1 WO2011072665 A1 WO 2011072665A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- burner
- fuel
- fuel supply
- oxidant
- combustion chamber
- Prior art date
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
- F23R3/02—Continuous combustion chambers using liquid or gaseous fuel characterised by the air-flow or gas-flow configuration
- F23R3/04—Air inlet arrangements
- F23R3/10—Air inlet arrangements for primary air
- F23R3/12—Air inlet arrangements for primary air inducing a vortex
- F23R3/14—Air inlet arrangements for primary air inducing a vortex by using swirl vanes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
- F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
- F23R3/28—Continuous combustion chambers using liquid or gaseous fuel characterised by the fuel supply
- F23R3/286—Continuous combustion chambers using liquid or gaseous fuel characterised by the fuel supply having fuel-air premixing devices
Definitions
- the invention relates to a burner for a turbine, and more particularly to a device for premixing oxidant and fuel
- turbines such as e.g.
- Premix burner Gas turbines called "premix burner” or “Premix Burner” used.
- premix burner gas turbines
- Premix Burner By using premix technology, the mixing process of
- Fuel and oxidants such as air are decoupled from the actual combustion process, i. preceded by this. This allows the peak combustion temperatures to be lowered. At the same time, the residence time of the fuel-oxidant mixture (e.g., fuel-air mixture) in the reaction zone may be shortened. In particular, this reduces the formation of NOx (especially thermal NOx).
- fuel-oxidant mixture e.g., fuel-air mixture
- Fuel injection should be carefully selected.
- the burner for a turbine provided with a device for premixing air and fuel.
- the burner has a cylindrical combustion chamber for gaseous or liquid fuel and a Haupindindüsung.
- the combustion chamber is in an Axialnchtung of the burner bounded on one side by a burner bottom and radially by a flame tube.
- the main injection is used to inject a premixed fuel-air mixture.
- the injection takes place radially to a burner longitudinal axis via main nozzles, which open into a radial swirl generator.
- the radial swirler is disposed between the burner bottom and the flame tube and causes the fuel-air mixture to be impinged with a swirl pulse and swirl into the combustion chamber.
- Fuel burners are described in DE 198 59 210 A1 and in DE 38 19 898 A1.
- the invention has for its object to provide a burner for a turbine, in a simple and cost-effective manner an extremely homogeneous premix of a in a combustion chamber of the burner
- Fuel-air mixture is achieved.
- a burner for a turbine comprises: a flame tube, in which a combustion chamber is formed, a jacket, which surrounds the flame tube from radially outside with a predetermined distance thereof, so that an oxidant collecting space is formed between flame tube and jacket, a combustor bottom defining the oxidizer plenum and combustion chamber at an axial end of the combustor, and a swirler axially disposed between the combustor tube and the burner floor axially adjacent the combustor bottom and radially adjacent to the oxidant plenum for supplying a fuel oxidant; Mixture in the combustion chamber, the
- air is provided as the oxidizing agent, which is fed at atmospheric or elevated pressure into the oxidant collecting space.
- Fuel supply pipes an optimal premix of fuel (eg fuel gas) and oxidizing agents (eg air) can be achieved. If the As fuel composition changes, the fuel delivery ports may be adjusted in size and shape.
- fuel eg fuel gas
- oxidizing agents eg air
- all inlet passages are each provided with a fuel feed pipe.
- At least one of the fuel supply pipes is arranged in the respective intake passage.
- At least one of the fuel supply tubes is in the oxidant flow direction directly in front of the respective inlet passage, i. at the beginning of Einlasströmungs Kunststoffs arranged.
- This embodiment of the invention represents a further advantageous variant for the arrangement of one or more or all Brennstoffzuzanrohre, wherein the mixing length or mixing distance of fuel and oxidant is maximally extended.
- at least one of the fuel supply pipes is relative to a longitudinal center axis of the respective one
- Inlet passage arranged off-center in the respective intake passage.
- This embodiment of the invention represents yet another advantageous variant for the arrangement of one or more or all fuel supply pipes, wherein the respective off-center position in the inlet passage transversely to their
- At least one of the fuel supply pipes or a plurality or all of the fuel supply pipes is arranged centrally in the respective intake passage with respect to the longitudinal central axis of the respective intake passage.
- At least one of the fuel supply pipes has a plurality of fuel discharge openings spaced along the length of the fuel supply pipe.
- the homogeneous mixing of fuel and oxidant can be further improved.
- the fuel supply pipes each having a plurality of along the length of the BrennstoffzuWORKe each with a distance from each other
- At least one of the Brennstoffzu classifiedrohre two fuel discharge openings which are arranged with respect to the length of the Brennstoffzu Technologyrohrs at the same position, so that these two fuel discharge openings fuel with two opposite direction components of the
- Fuel supply tube can be dispensed.
- the oxidant flow on both sides of the fuel supply pipe is utilized for fluidizing the fuel, thereby further improving homogeneous mixing of fuel and oxidant.
- Fuel supply tube are arranged at the same position, so that these two fuel discharge openings fuel with two each other
- the two fuel discharge openings are diametrically opposed to each other or include respective longitudinal center axes of the two fuel discharge openings at an obtuse angle.
- Fuel supply pipes each have a cylindrical cross section or a wing-shaped cross-section or other suitable for optimum turbulence cross-sections. According to the invention, all
- Fuel supply tubes have the same cross-sectional shape.
- the airfoil shape may prove advantageous for reducing direct mixing in the pipe wake, which may be particularly necessary with reactive fuels (such as hydrogen).
- the fuel supply tubes are each detachably mounted so that each is arranged in a predetermined manner
- the fuel feed configuration formed fuel supply tube is individually replaceable with a fuel supply tube according to another predetermined fuel mixing configuration.
- the burner according to the invention is suitable for the use of fuel gas as fuel.
- the burner according to the invention can also be operated with liquid fuel, wherein, if necessary, special nozzles should be inserted into the fuel discharge openings.
- Fuel gas) and oxidizing agent e.g., air. This can be low
- Emission values can be achieved. At the same time can by the individual
- FIG. 1 shows a schematic longitudinal sectional view of the structure of a
- Burner of a gas turbine according to an embodiment of the invention.
- FIG. 2 shows a schematic cross-sectional view of a part of the burner of FIG. 1, seen along a line A-A in FIG.
- FIG. 3 shows in enlarged partial views of an inlet passage of the burner of Figure 2 three possible configuration variants of a
- FIG. 4 shows two possible configuration variants of a fuel feed tube in an inlet passage of the burner according to the invention, as seen along a line B-B in FIG.
- FIG. 1 shows the structure of a burner 1 of a gas turbine (not completely shown) according to an embodiment of the invention.
- the burner 1 has a flame tube 10, in which a combustion chamber 1 1 is formed, and a tubular shell 20, the flame tube 10 from radially outward encloses it with a predetermined distance, so that between
- Flame tube 10 and shell 20 an oxidant-collecting space 21 is formed.
- Oxidizing agent for the fuel gas is provided atmospheric air, which is compressed by a compressor (not shown) and then the
- Oxidant collecting space 21 is supplied.
- the burner 1 further has a burner bottom 30 defining the Oxidationsffen- collecting space 21 and the combustion chamber 1 1 at an axial end of the burner 1, and a swirl generator 40, the axially adjacent to the burner bottom 30 and radially to the oxidant collecting space 21 axially between the flame tube 10 and the burner bottom 30 is arranged, for supplying a
- Fuel-oxidizer mixture BOG in the combustion chamber 1 1.
- the swirl generator 40 has a plurality of circumferentially spaced apart UR of the burner 1 (FIG. here eight) of vanes 41.
- the guide vanes 41 are each shaped and arranged such that the respective distances between the guide vanes 41 form a plurality (in this case eight) of radial inlet passages 42 each having a tangential component in their course toward the combustion chamber 11.
- a fuel supply pipe 43a, 43b, 43c, 43d each having a length in an axial direction AR (see FIG 1) of the burner 1 and extends transversely to an oxidant flow direction OR through the respective inlet passage 42 therethrough.
- Fuel supply pipe 43a, 43b, 43c, 43d may also be provided in more or less or in all inlet passages 42 respective fuel supply pipes 43a, 43b, 43c, 43d.
- each fuel supply pipe 43a, 43b, 43c, 43d has in its wall at least one fuel discharge port 44, 45 radial with respect to the fuel supply pipe 43a, 43b, 43c, 43d, over which
- each fuel dispensing opening 44, 45 is formed as a bore or as a nozzle insert.
- Inlet passages 42 may be arranged. As also seen from FIG. 2, the fuel supply pipes 43a, 43b, 43d may be disposed within the respective intake passages 42 at different positions along the length of the respective ones
- Inlet passages 42 may be arranged.
- Inlet passages 42 (ie at the entrance of the respective inlet passages 42 partially or completely in the oxidant collecting space 21) may be arranged.
- one, several or all fuel supply pipes 43 a, 43 b, 43 c may be arranged centrally in the respective intake passages 42 with respect to longitudinal center axes L of the respective intake passages 42.
- one, several or all of the fuel supply pipes 43d may be off-center with respect to the longitudinal center axes L of the respective ones
- Inlet passages 42 may be arranged in these.
- one or more, or all can
- Fuel supply pipes 43 a, 43 b, 43 c, 43 d a plurality of
- one, several or all fuel supply pipes 43a, 43b, 43c, 43d may have only a single fuel discharge opening 44, 45 with respect to the respective length of the fuel supply pipes 43a, 43b, 43c, 43d [variant b) in Fig. 4].
- one, several or all of the central fuel supply pipes 43a, 43b, 43c (designated by 43a-c in FIG. 3) and also one, several or all off-center fuel supply pipes 43d (not in FIG shown) have two fuel discharge openings 44, 45, which are arranged at the same position with respect to the length of the Brennstoffzu Glassrohrs, so that these two fuel discharge openings 44, 45 fuel BS with two opposite direction components (as shown by the
- Fuel supply pipe 43 a, 43 b, 43 c, 43 d seen diametrically
- Fuel discharge openings 44, 45 is arranged.
- the fuel supply pipes 43a, 43b, 43c, 43d each have a cylindrical cross section.
- the fuel supply pipes 43a, 43b, 43c, 43d may also have a wing-shaped cross-section or other suitable for homogeneous mixing of oxidant and fuel
- a hydrofoil shape is for example in
- Each of fuel supply pipes 43a, 43b, 43c, 43d is detachably mounted in the burner 1 such that each of fuel supply pipes 43a, 43b, 43c formed according to a predetermined fuel mixing configuration (position of the fuel supply pipe in the intake passage, number and arrangement of the fuel discharge ports, cross sectional shape of the fuel supply pipe); 43d is individually replaceable with a fuel supply pipe 43a, 43b, 43c, 43d, if necessary, according to another predetermined fuel mixing configuration.
- the fuel supply pipes 43a, 43b, 43c, 43d (designated 43a-d in Fig. 4) are detachably inserted into corresponding openings in the burner bottom 30, as shown in Fig. 4, with each fuel supply pipe 43a, 43b, 43c, 43d a longitudinal end of a flange or head portion 46, 47th which, on the side facing away from the swirl generator 40 of the
- Burner bottom 30 abuts this and e.g. by means of screws (not shown) screwed to the burner bottom 30.
- each fuel delivery tube 43a, 43b, 43c, 43d is naturally connected via respective conduits and control valves (both not shown) to a fuel source (not shown), such as a fuel source.
- Fuel gas tank fluid-connected.
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP10786994.3A EP2513562B1 (en) | 2009-12-15 | 2010-09-28 | Burner for a turbine |
US13/509,329 US20120227407A1 (en) | 2009-12-15 | 2010-09-28 | Burner for a turbine |
JP2012543473A JP2013517440A (en) | 2009-12-15 | 2010-09-28 | Turbine burner |
CA2782196A CA2782196C (en) | 2009-12-15 | 2010-09-28 | Burner for a turbine |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102009054669A DE102009054669A1 (en) | 2009-12-15 | 2009-12-15 | Burner for a turbine |
DE102009054669.3 | 2009-12-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2011072665A1 true WO2011072665A1 (en) | 2011-06-23 |
Family
ID=43568285
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/DE2010/050074 WO2011072665A1 (en) | 2009-12-15 | 2010-09-28 | Burner for a turbine |
Country Status (6)
Country | Link |
---|---|
US (1) | US20120227407A1 (en) |
EP (1) | EP2513562B1 (en) |
JP (1) | JP2013517440A (en) |
CA (1) | CA2782196C (en) |
DE (1) | DE102009054669A1 (en) |
WO (1) | WO2011072665A1 (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9581333B2 (en) * | 2012-05-01 | 2017-02-28 | Aerco International, Inc. | Igniter assembly and method for operating |
US9677766B2 (en) * | 2012-11-28 | 2017-06-13 | General Electric Company | Fuel nozzle for use in a turbine engine and method of assembly |
KR102184778B1 (en) * | 2013-12-19 | 2020-11-30 | 한화에어로스페이스 주식회사 | Swirler for gas turbine |
JP6602004B2 (en) * | 2014-09-29 | 2019-11-06 | 川崎重工業株式会社 | Fuel injector and gas turbine |
EP3098514A1 (en) * | 2015-05-29 | 2016-11-30 | Siemens Aktiengesellschaft | Combustor arrangement |
US10215415B2 (en) * | 2015-09-23 | 2019-02-26 | General Electric Company | Premix fuel nozzle assembly cartridge |
EP3236157A1 (en) | 2016-04-22 | 2017-10-25 | Siemens Aktiengesellschaft | Swirler for mixing fuel with air in a combustion engine |
JP6995696B2 (en) * | 2018-05-28 | 2022-01-17 | 三菱重工業株式会社 | Fuel injection system and gas turbine |
CN113310071B (en) * | 2021-06-16 | 2022-11-15 | 哈尔滨工程大学 | Coaxial staged combustor for low-pollution combustion chamber of gas fuel gas turbine |
CN113834094B (en) * | 2021-09-15 | 2022-11-01 | 中国船舶重工集团公司第七0三研究所 | Nozzle with tangential rotational flow structure |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3819898A1 (en) | 1988-06-11 | 1989-12-14 | Daimler Benz Ag | Combustion chamber for a thermal turbo-engine |
US5394688A (en) * | 1993-10-27 | 1995-03-07 | Westinghouse Electric Corporation | Gas turbine combustor swirl vane arrangement |
EP0762057A1 (en) * | 1995-09-01 | 1997-03-12 | Mtu Motoren- Und Turbinen-Union MàNchen Gmbh | Mixing device for fuel and air for gas turbine combustors |
DE19859210A1 (en) | 1997-12-19 | 1999-07-01 | Alstom Gas Turbines Ltd | Fuel-air mixing arrangement for combustion devices |
EP0982545A2 (en) * | 1998-08-21 | 2000-03-01 | Rolls-Royce Plc | A combustion chamber |
EP2093488A2 (en) * | 2008-02-20 | 2009-08-26 | Ingersoll-Rand Energy Systems Corporation | Air-Cooled swirlerhead |
DE102008019117A1 (en) | 2008-04-16 | 2009-10-22 | Man Turbo Ag | Method for operating a premix burner and a premix burner for carrying out the method |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0169431B1 (en) * | 1984-07-10 | 1990-04-11 | Hitachi, Ltd. | Gas turbine combustor |
US5117637A (en) * | 1990-08-02 | 1992-06-02 | General Electric Company | Combustor dome assembly |
US5450724A (en) * | 1993-08-27 | 1995-09-19 | Northern Research & Engineering Corporation | Gas turbine apparatus including fuel and air mixer |
EP0747635B1 (en) * | 1995-06-05 | 2003-01-15 | Rolls-Royce Corporation | Dry low oxides of nitrogen lean premix module for industrial gas turbine engines |
US5647215A (en) * | 1995-11-07 | 1997-07-15 | Westinghouse Electric Corporation | Gas turbine combustor with turbulence enhanced mixing fuel injectors |
GB2333832A (en) * | 1998-01-31 | 1999-08-04 | Europ Gas Turbines Ltd | Multi-fuel gas turbine engine combustor |
GB2334087A (en) * | 1998-02-03 | 1999-08-11 | Combustion Technology Internat | Combustor restrictor |
FR2824625B1 (en) * | 2001-05-10 | 2003-08-15 | Inst Francais Du Petrole | DEVICE AND METHOD FOR INJECTING A LIQUID FUEL INTO AN AIRFLOW FOR A COMBUSTION CHAMBER |
US6691515B2 (en) * | 2002-03-12 | 2004-02-17 | Rolls-Royce Corporation | Dry low combustion system with means for eliminating combustion noise |
US7093445B2 (en) * | 2002-05-31 | 2006-08-22 | Catalytica Energy Systems, Inc. | Fuel-air premixing system for a catalytic combustor |
US6786047B2 (en) * | 2002-09-17 | 2004-09-07 | Siemens Westinghouse Power Corporation | Flashback resistant pre-mix burner for a gas turbine combustor |
US6868676B1 (en) * | 2002-12-20 | 2005-03-22 | General Electric Company | Turbine containing system and an injector therefor |
GB2435508B (en) * | 2006-02-22 | 2011-08-03 | Siemens Ag | A swirler for use in a burner of a gas turbine engine |
US20070220898A1 (en) * | 2006-03-22 | 2007-09-27 | General Electric Company | Secondary fuel nozzle with improved fuel pegs and fuel dispersion method |
GB2437977A (en) * | 2006-05-12 | 2007-11-14 | Siemens Ag | A swirler for use in a burner of a gas turbine engine |
GB2443431B (en) * | 2006-11-02 | 2008-12-03 | Siemens Ag | Fuel-injector nozzle |
US20080163627A1 (en) * | 2007-01-10 | 2008-07-10 | Ahmed Mostafa Elkady | Fuel-flexible triple-counter-rotating swirler and method of use |
EP1970629A1 (en) * | 2007-03-15 | 2008-09-17 | Siemens Aktiengesellschaft | Burner fuel staging |
JP4906689B2 (en) * | 2007-11-29 | 2012-03-28 | 株式会社日立製作所 | Burner, combustion device, and method for modifying combustion device |
EP2107300A1 (en) * | 2008-04-01 | 2009-10-07 | Siemens Aktiengesellschaft | Swirler with gas injectors |
EP2230458A1 (en) * | 2009-03-17 | 2010-09-22 | Siemens Aktiengesellschaft | Burner assembly for fluid fuels and method for producing a burner assembly |
DE102009045950A1 (en) * | 2009-10-23 | 2011-04-28 | Man Diesel & Turbo Se | swirl generator |
-
2009
- 2009-12-15 DE DE102009054669A patent/DE102009054669A1/en not_active Withdrawn
-
2010
- 2010-09-28 EP EP10786994.3A patent/EP2513562B1/en active Active
- 2010-09-28 CA CA2782196A patent/CA2782196C/en active Active
- 2010-09-28 WO PCT/DE2010/050074 patent/WO2011072665A1/en active Application Filing
- 2010-09-28 JP JP2012543473A patent/JP2013517440A/en active Pending
- 2010-09-28 US US13/509,329 patent/US20120227407A1/en not_active Abandoned
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3819898A1 (en) | 1988-06-11 | 1989-12-14 | Daimler Benz Ag | Combustion chamber for a thermal turbo-engine |
US5394688A (en) * | 1993-10-27 | 1995-03-07 | Westinghouse Electric Corporation | Gas turbine combustor swirl vane arrangement |
EP0762057A1 (en) * | 1995-09-01 | 1997-03-12 | Mtu Motoren- Und Turbinen-Union MàNchen Gmbh | Mixing device for fuel and air for gas turbine combustors |
DE19859210A1 (en) | 1997-12-19 | 1999-07-01 | Alstom Gas Turbines Ltd | Fuel-air mixing arrangement for combustion devices |
EP0982545A2 (en) * | 1998-08-21 | 2000-03-01 | Rolls-Royce Plc | A combustion chamber |
EP2093488A2 (en) * | 2008-02-20 | 2009-08-26 | Ingersoll-Rand Energy Systems Corporation | Air-Cooled swirlerhead |
DE102008019117A1 (en) | 2008-04-16 | 2009-10-22 | Man Turbo Ag | Method for operating a premix burner and a premix burner for carrying out the method |
Also Published As
Publication number | Publication date |
---|---|
CA2782196A1 (en) | 2011-06-23 |
JP2013517440A (en) | 2013-05-16 |
CA2782196C (en) | 2014-07-29 |
US20120227407A1 (en) | 2012-09-13 |
EP2513562A1 (en) | 2012-10-24 |
DE102009054669A1 (en) | 2011-06-16 |
EP2513562B1 (en) | 2018-07-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2513562B1 (en) | Burner for a turbine | |
EP1802915B1 (en) | Gas turbine burner | |
EP1864056B1 (en) | Premix burner for a gas turbine combustion chamber | |
DE102005024062B4 (en) | Burner tube and method of mixing air and gas in a gas turbine engine | |
DE102009044136B4 (en) | Tubular fuel injectors for secondary fuel nozzles | |
EP0276696B1 (en) | Hybrid burner for premix operation with gas and/or oil, particularly for gas turbine plants | |
DE2143012C3 (en) | Burner arrangement in a gas turbine combustor | |
EP0902233B1 (en) | Combined pressurised atomising nozzle | |
EP2156095B1 (en) | Swirling-free stabilising of the flame of a premix burner | |
EP1754002B1 (en) | Staged premix burner with an injector for liquid fuel | |
DE60037850T2 (en) | Liquid fuel injector for gas turbine burners | |
EP1828684A1 (en) | Premix burner comprising a mixing section | |
EP2116766A1 (en) | Fuel lance | |
EP1436546B1 (en) | Burner for synthesis gas | |
DE102009003572A1 (en) | Combustion chamber cap with rim-shaped openings | |
EP0777081B1 (en) | Premix burner | |
EP1504222B1 (en) | Premix burner | |
EP1734306B1 (en) | Burner for premix-type combustion | |
EP0193838A2 (en) | Burner disposition for combustion installations, especially for combustion chambers of gas turbine installations, and method for its operation | |
DE19750310A1 (en) | Gas turbine drive unit | |
DE10104695B4 (en) | Premix burner for a gas turbine | |
EP1359376B1 (en) | Combustion chamber for gas turbine with precise fuel injection to increase the homogeneity of the air-fuel mixture | |
DE102004049491A1 (en) | premix | |
CH703230B1 (en) | Gas turbine with single-stage fuel injection. | |
DE2116429A1 (en) | Combustion chamber for gas turbine engines |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 10786994 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2010786994 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 13509329 Country of ref document: US |
|
ENP | Entry into the national phase |
Ref document number: 2782196 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2012543473 Country of ref document: JP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1120100048142 Country of ref document: DE |