WO2011147573A3 - Process for preparing a supported catalyst system for olefin polymerization, the catalyst system and its use - Google Patents

Process for preparing a supported catalyst system for olefin polymerization, the catalyst system and its use Download PDF

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Publication number
WO2011147573A3
WO2011147573A3 PCT/EP2011/002612 EP2011002612W WO2011147573A3 WO 2011147573 A3 WO2011147573 A3 WO 2011147573A3 EP 2011002612 W EP2011002612 W EP 2011002612W WO 2011147573 A3 WO2011147573 A3 WO 2011147573A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst system
preparing
olefin polymerization
supported catalyst
support component
Prior art date
Application number
PCT/EP2011/002612
Other languages
French (fr)
Other versions
WO2011147573A2 (en
Inventor
Fabiana Fantinel
Shahram Mihan
Rainer Karer
Volker Fraaije
Original Assignee
Basell Polyolefine Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine Gmbh filed Critical Basell Polyolefine Gmbh
Priority to CN201180026560.9A priority Critical patent/CN102939311B/en
Priority to US13/700,098 priority patent/US8999875B2/en
Priority to EP11727642.8A priority patent/EP2576642B1/en
Priority to KR1020127031201A priority patent/KR101805945B1/en
Publication of WO2011147573A2 publication Critical patent/WO2011147573A2/en
Publication of WO2011147573A3 publication Critical patent/WO2011147573A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61925—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Abstract

The invention refers to a process for preparing a supported catalyst system for the polymerization of olefins comprising at least one active catalyst component on a support, the process comprising A) impregnating a dry porous support component with a mixture comprising at least one precatalyst, at least one cocatalyst, and a first solvent, such that the total volume of the mixture is from 0.8 to 2.0 times the total pore volume of the support component, and B) thereafter, adding a second solvent in an amount of more than 1.5 times the total pore volume of the support component. The invention refers further to a catalyst system made by this process and the use of this catalyst system for polymerization or copolymerization of olefins.
PCT/EP2011/002612 2010-05-28 2011-05-26 Process for preparing a supported catalyst system for olefin polymerization, the catalyst system and its use WO2011147573A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN201180026560.9A CN102939311B (en) 2010-05-28 2011-05-26 The method for preparing the load type catalyst system for olefinic polymerization, the catalyst system and application thereof
US13/700,098 US8999875B2 (en) 2010-05-28 2011-05-26 Process for preparing a supported catalyst system for olefin polymerization, the catalyst system and its use
EP11727642.8A EP2576642B1 (en) 2010-05-28 2011-05-26 Process for preparing a supported catalyst system for olefin polymerization, the catalyst system and its use
KR1020127031201A KR101805945B1 (en) 2010-05-28 2011-05-26 Process for preparing a supported catalyst system for olefin polymerization, the catalyst system and its use

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
EP10005630 2010-05-28
EP10005630.8 2010-05-28
EP10006346.0 2010-06-17
EP10006346 2010-06-17
US39836810P 2010-06-24 2010-06-24
US61/398,368 2010-06-24

Publications (2)

Publication Number Publication Date
WO2011147573A2 WO2011147573A2 (en) 2011-12-01
WO2011147573A3 true WO2011147573A3 (en) 2012-12-06

Family

ID=45004472

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2011/002612 WO2011147573A2 (en) 2010-05-28 2011-05-26 Process for preparing a supported catalyst system for olefin polymerization, the catalyst system and its use

Country Status (5)

Country Link
US (1) US8999875B2 (en)
EP (1) EP2576642B1 (en)
KR (1) KR101805945B1 (en)
CN (1) CN102939311B (en)
WO (1) WO2011147573A2 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013096815A1 (en) * 2011-12-21 2013-06-27 Swaminathan Ramesh Method for recycling a plastic
CN103772568B (en) * 2014-01-14 2016-01-20 浙江大学 A kind of method regulating vapor phase process polyhutadiene product vinyl structure content
SG11201606539RA (en) 2014-02-11 2016-09-29 Univation Tech Llc Method to prepare ethylene copolymers
SG11201701266TA (en) 2014-08-19 2017-03-30 Univation Tech Llc Fluorinated catalyst supports and catalyst systems
CA2957809C (en) 2014-08-19 2023-01-03 Univation Technologies, Llc Fluorinated catalyst supports and catalyst systems
US10189917B2 (en) 2014-08-19 2019-01-29 Univation Technologies, Llc Fluorinated catalyst supports and catalyst systems
WO2019070329A1 (en) 2017-10-06 2019-04-11 Exxonmobil Chemical Patents Inc. Polyethylene extrudates and methods of making the same
CN109894151B (en) * 2017-12-07 2022-02-18 万华化学集团股份有限公司 Supported metallocene catalyst and preparation method and application thereof
WO2022076216A1 (en) 2020-10-08 2022-04-14 Exxonmobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof

Citations (4)

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WO1996011961A1 (en) * 1994-10-13 1996-04-25 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US6194341B1 (en) * 1996-06-17 2001-02-27 Exxon Chemical Patents Inc. Mixed transition metal catalyst systems for olefin polymerization
US20030228971A1 (en) * 2002-06-06 2003-12-11 Equistar Chemicals L.P. Prealkylated olefin polymerization catalysts and olefin polymerization employing such catalysts
US7671148B2 (en) * 2004-04-26 2010-03-02 Basell Polyolefine Gmbh Catalyst system for olefin polymerization, its production and use

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US3248179A (en) 1962-02-26 1966-04-26 Phillips Petroleum Co Method and apparatus for the production of solid polymers of olefins
US5602067A (en) 1992-12-28 1997-02-11 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
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CN1112370C (en) 1994-06-24 2003-06-25 埃克森美孚化学专利公司 Polymerization catalyst systems, their production and use
DE69620760T2 (en) 1995-07-06 2002-12-05 Exxonmobil Chem Patents Inc METHOD FOR PRODUCING POLYMERIZED SUPPORTED METALLOCENE CATALYST SYSTEMS
FI104826B (en) 1996-01-30 2000-04-14 Borealis As Heteroatom-substituted metallose compounds for catalytic systems in olefin polymerization and process for their preparation
KR20000005128A (en) 1996-03-29 2000-01-25 그레이스 스티븐 에스. Metallocene cocatalyst
EP1327636B1 (en) 1996-11-15 2006-01-11 Basell Polyolefine GmbH Heterocyclic metallocenes and polymerisation catalysts
EP0931099A1 (en) 1997-03-07 1999-07-28 Basell Polyolefine GmbH Method for producing olefin polymers with a higher melting point
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Patent Citations (4)

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US6194341B1 (en) * 1996-06-17 2001-02-27 Exxon Chemical Patents Inc. Mixed transition metal catalyst systems for olefin polymerization
US20030228971A1 (en) * 2002-06-06 2003-12-11 Equistar Chemicals L.P. Prealkylated olefin polymerization catalysts and olefin polymerization employing such catalysts
US7671148B2 (en) * 2004-04-26 2010-03-02 Basell Polyolefine Gmbh Catalyst system for olefin polymerization, its production and use

Also Published As

Publication number Publication date
WO2011147573A2 (en) 2011-12-01
KR20130079415A (en) 2013-07-10
CN102939311A (en) 2013-02-20
US20130072652A1 (en) 2013-03-21
EP2576642A2 (en) 2013-04-10
CN102939311B (en) 2017-10-24
KR101805945B1 (en) 2017-12-06
US8999875B2 (en) 2015-04-07
EP2576642B1 (en) 2017-08-16

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