WO2013086080A3 - Process for dispersing cellulose esters into elastomeric compositions - Google Patents

Process for dispersing cellulose esters into elastomeric compositions Download PDF

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Publication number
WO2013086080A3
WO2013086080A3 PCT/US2012/068088 US2012068088W WO2013086080A3 WO 2013086080 A3 WO2013086080 A3 WO 2013086080A3 US 2012068088 W US2012068088 W US 2012068088W WO 2013086080 A3 WO2013086080 A3 WO 2013086080A3
Authority
WO
WIPO (PCT)
Prior art keywords
cellulose ester
cellulose esters
elastomeric compositions
concentrate
dispersing cellulose
Prior art date
Application number
PCT/US2012/068088
Other languages
French (fr)
Other versions
WO2013086080A2 (en
Inventor
Marcus David Shelby
Michael Eugene Donelson
Jeff Scott Howell
Soumendra Kumar Basu
Bradley James Helmer
Matthew Davie Wood
Chris Stanley Dagenhart
Original Assignee
Eastman Chemical Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/690,981 external-priority patent/US20130150498A1/en
Priority claimed from US13/690,890 external-priority patent/US20130150500A1/en
Application filed by Eastman Chemical Company filed Critical Eastman Chemical Company
Publication of WO2013086080A2 publication Critical patent/WO2013086080A2/en
Publication of WO2013086080A3 publication Critical patent/WO2013086080A3/en

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08Cellulose derivatives
    • C08L1/10Esters of organic acids, i.e. acylates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0016Plasticisers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08Cellulose derivatives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08Cellulose derivatives
    • C08L1/10Esters of organic acids, i.e. acylates
    • C08L1/14Mixed esters, e.g. cellulose acetate-butyrate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08Cellulose derivatives
    • C08L1/26Cellulose ethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00Compositions of unspecified rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/02Homopolymers or copolymers of unsaturated alcohols
    • C08L29/04Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L31/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
    • C08L31/02Homopolymers or copolymers of esters of monocarboxylic acids
    • C08L31/04Homopolymers or copolymers of vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10Homopolymers or copolymers of methacrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L39/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions of derivatives of such polymers
    • C08L39/04Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
    • C08L39/06Homopolymers or copolymers of N-vinyl-pyrrolidones
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L59/00Compositions of polyacetals; Compositions of derivatives of polyacetals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02Polyalkylene oxides

Abstract

In one embodiment of the present invention, a cellulose ester concentrate is provided. The cellulose ester concentrate comprises at least one non-nitrile carrier elastomer and at least one non-fibril cellulose ester. The Tg of the cellulose ester is greater than the Tg of the carrier elastomer. The cellulose ester concentrate comprises at least 15 weight percent of the cellulose ester. In another embodiment of the present invention, a process to produce a cellulose ester concentrate is provided. The process comprises mixing at least one cellulose ester with one or more carrier elastomers to produce the cellulose ester concentrate. At least a portion of the mixing occurs at a temperature that exceeds the Tg of the cellulose ester.
PCT/US2012/068088 2011-12-07 2012-12-06 Process for dispersing cellulose esters into elastomeric compositions WO2013086080A2 (en)

Applications Claiming Priority (34)

Application Number Priority Date Filing Date Title
US201161567950P 2011-12-07 2011-12-07
US201161567953P 2011-12-07 2011-12-07
US201161567948P 2011-12-07 2011-12-07
US201161567951P 2011-12-07 2011-12-07
US61/567,951 2011-12-07
US61/567,950 2011-12-07
US61/567,948 2011-12-07
US61/567,953 2011-12-07
US13/690,981 US20130150498A1 (en) 2011-12-07 2012-11-30 Cellulose esters in pneumatic tires
US13/690,944 2012-11-30
US13/690,890 US20130150500A1 (en) 2011-12-07 2012-11-30 Process for dispersing cellulose esters into elastomeric compositions
US13/690,930 2012-11-30
US13/690,935 2012-11-30
US13/690,945 2012-11-30
US13/690,919 US20130150492A1 (en) 2011-12-07 2012-11-30 Process for dispersing cellulose esters into elastomeric compositions
US13/690,919 2012-11-30
US13/690,935 US9708473B2 (en) 2011-12-07 2012-11-30 Cellulose esters in pneumatic tires
US13/690,968 US9708475B2 (en) 2011-12-07 2012-11-30 Cellulose esters in highly-filled elastomeric systems
US13/691,007 US20130150499A1 (en) 2011-12-07 2012-11-30 Cellulose esters in highly-filled elastomeric systems
US13/690,909 2012-11-30
US13/690,944 US20130150484A1 (en) 2011-12-07 2012-11-30 Cellulose esters in pneumatic tires
US13/690,937 2012-11-30
US13/690,909 US9708472B2 (en) 2011-12-07 2012-11-30 Cellulose esters in highly-filled elastomeric systems
US13/690,958 2012-11-30
US13/690,930 US20130150493A1 (en) 2011-12-07 2012-11-30 Process for dispersing cellulose esters into elastomeric compositions
US13/690,968 2012-11-30
US13/690,953 US9273195B2 (en) 2010-06-29 2012-11-30 Tires comprising cellulose ester/elastomer compositions
US13/690,981 2012-11-30
US13/690,937 US20130150495A1 (en) 2011-12-07 2012-11-30 Process for dispersing cellulose esters into elastomeric compositions
US13/690,958 US9708474B2 (en) 2011-12-07 2012-11-30 Cellulose esters in pneumatic tires
US13/690,890 2012-11-30
US13/691,007 2012-11-30
US13/690,953 2012-11-30
US13/690,945 US20130150501A1 (en) 2011-12-07 2012-11-30 Cellulose esters in highly-filled elastomaric systems

Publications (2)

Publication Number Publication Date
WO2013086080A2 WO2013086080A2 (en) 2013-06-13
WO2013086080A3 true WO2013086080A3 (en) 2016-04-07

Family

ID=48574854

Family Applications (13)

Application Number Title Priority Date Filing Date
PCT/US2012/068102 WO2013086091A1 (en) 2011-12-07 2012-12-06 Cellulose esters in pneumatic tires
PCT/US2012/068109 WO2013086095A1 (en) 2011-12-07 2012-12-06 Process for dispersing cellulose esters into elastomeric compositions
PCT/US2012/068097 WO2013086086A1 (en) 2011-12-07 2012-12-06 Cellulose esters in pneumatic tires
PCT/US2012/068131 WO2013086108A1 (en) 2011-12-07 2012-12-06 Cellulose esters in highly-filled elastomeric systems
PCT/US2012/068114 WO2013086097A1 (en) 2011-12-07 2012-12-06 Cellulose esters in highly-filled elastomeric systems
PCT/US2012/068140 WO2013086114A1 (en) 2011-12-07 2012-12-06 Process for dispersing cellulose esters into elastomeric compositions
PCT/US2012/068100 WO2013086089A1 (en) 2011-12-07 2012-12-06 Cellulose esters in pneumatic tires
PCT/US2012/068088 WO2013086080A2 (en) 2011-12-07 2012-12-06 Process for dispersing cellulose esters into elastomeric compositions
PCT/US2012/068096 WO2013086085A1 (en) 2011-12-07 2012-12-06 Cellulose esters in highly-filled elastomeric systems
PCT/US2012/068093 WO2013122661A1 (en) 2011-12-07 2012-12-06 Cellulose esters in pneumatic tires
PCT/US2012/068086 WO2013086079A1 (en) 2011-12-07 2012-12-06 Cellulose ester/elastomer compositions
PCT/US2012/068147 WO2013086120A1 (en) 2011-12-07 2012-12-06 Process for dispersing cellulose esters into elastomeric compositions
PCT/US2012/068124 WO2013086104A1 (en) 2011-12-07 2012-12-06 Cellulose esters in highly-filled elastomeric systems

Family Applications Before (7)

Application Number Title Priority Date Filing Date
PCT/US2012/068102 WO2013086091A1 (en) 2011-12-07 2012-12-06 Cellulose esters in pneumatic tires
PCT/US2012/068109 WO2013086095A1 (en) 2011-12-07 2012-12-06 Process for dispersing cellulose esters into elastomeric compositions
PCT/US2012/068097 WO2013086086A1 (en) 2011-12-07 2012-12-06 Cellulose esters in pneumatic tires
PCT/US2012/068131 WO2013086108A1 (en) 2011-12-07 2012-12-06 Cellulose esters in highly-filled elastomeric systems
PCT/US2012/068114 WO2013086097A1 (en) 2011-12-07 2012-12-06 Cellulose esters in highly-filled elastomeric systems
PCT/US2012/068140 WO2013086114A1 (en) 2011-12-07 2012-12-06 Process for dispersing cellulose esters into elastomeric compositions
PCT/US2012/068100 WO2013086089A1 (en) 2011-12-07 2012-12-06 Cellulose esters in pneumatic tires

Family Applications After (5)

Application Number Title Priority Date Filing Date
PCT/US2012/068096 WO2013086085A1 (en) 2011-12-07 2012-12-06 Cellulose esters in highly-filled elastomeric systems
PCT/US2012/068093 WO2013122661A1 (en) 2011-12-07 2012-12-06 Cellulose esters in pneumatic tires
PCT/US2012/068086 WO2013086079A1 (en) 2011-12-07 2012-12-06 Cellulose ester/elastomer compositions
PCT/US2012/068147 WO2013086120A1 (en) 2011-12-07 2012-12-06 Process for dispersing cellulose esters into elastomeric compositions
PCT/US2012/068124 WO2013086104A1 (en) 2011-12-07 2012-12-06 Cellulose esters in highly-filled elastomeric systems

Country Status (9)

Country Link
US (1) US9273195B2 (en)
EP (3) EP2788421A4 (en)
JP (3) JP6196229B2 (en)
KR (3) KR20140105531A (en)
CN (3) CN103958588B (en)
BR (2) BR112014013559A2 (en)
CA (3) CA2856855A1 (en)
MX (3) MX2014005803A (en)
WO (13) WO2013086091A1 (en)

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