WO2017046139A1 - Pre-treating aluminum surfaces with zirconium- and molybdenum-containing compositions - Google Patents
Pre-treating aluminum surfaces with zirconium- and molybdenum-containing compositions Download PDFInfo
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- WO2017046139A1 WO2017046139A1 PCT/EP2016/071657 EP2016071657W WO2017046139A1 WO 2017046139 A1 WO2017046139 A1 WO 2017046139A1 EP 2016071657 W EP2016071657 W EP 2016071657W WO 2017046139 A1 WO2017046139 A1 WO 2017046139A1
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/40—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates
- C23C22/44—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates containing also fluorides or complex fluorides
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/73—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/73—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
- C23C22/76—Applying the liquid by spraying
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/78—Pretreatment of the material to be coated
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/78—Pretreatment of the material to be coated
- C23C22/80—Pretreatment of the material to be coated with solutions containing titanium or zirconium compounds
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/82—After-treatment
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/12—Light metals
- C23G1/125—Light metals aluminium
Definitions
- the invention relates to a method for the pretreatment of workpieces with a surface made of aluminum or aluminum alloys for non-cutting forming and / or joining by welding or gluing with similarly pretreated or otherwise otherwise precoated workpieces or with optionally pretreated parts made of steel and / or galvanized and / or alloy-galvanized steel, and for subsequent corrosion-protective treatment by phosphating, by chromium-free conversion treatment, by primer application or by painting.
- the method of EP-B-700 452 envisages contacting surfaces of aluminum or its alloys with an aqueous solution prior to a second permanent anticorrosion treatment for pretreatment, comprising complex fluorides of the elements boron, Contain silicon, titanium, zirconium or hafnium individually or in admixture with each other in concentrations of the fluoro-anions of 100 to 4000 mg / l and have a pH of 0.3 to 3.5.
- the parts made of aluminum or its alloys are subjected to a chipless and / or cutting deformation process, and / or connected to one another or to parts made of steel and / or galvanized and / or alloy-galvanized steel by gluing and / or welding.
- the application of the optionally polymers containing certain state of the art solution can be done by spraying, dipping or no-rinse method, wherein in the case of the no-rinse method, the wet film amount between 2 to 10, preferably between 4 and 6 ml / m 2 metal surface should. Regardless of the form of application of the solution, it is advantageous to dry at temperatures between 40 and 85 ° C.
- the parts made of aluminum or its alloys are acid or alkaline cleaned prior to the first conversion treatment, and cleaning steps and intermediate rinses with water and / or activating rinsing baths preferably take place before the permanent corrosion-protective treatment.
- the object of the invention is a method for the pretreatment of workpieces with a surface made of aluminum or aluminum alloys for non-cutting forming and / or joining by welding or gluing, in particular for bonding by gluing, with similarly pretreated or otherwise otherwise precoated workpieces or with Parts made of steel and / or galvanized and / or alloy galvanized steel, in particular with similarly pretreated workpieces, and to provide a permanent corrosion protection treatment by phosphating and / or by a chrome-free conversion treatment and by primer application and / or painting, in particular by phosphating and a Chrome-free conversion treatment as well as varnishing, which regularly leads to workpieces with a sufficiently low volume resistance and at the same time good phosphatability and adhesive adhesion.
- the method according to the invention should moreover lead to good temporary corrosion protection values and be largely insensitive to bath contamination by aluminum ions.
- the object is achieved, on the one hand, by configuring the method according to the invention in such a way that the workpieces a) are immersed in a dipping or spraying with a mineral acid-containing aqueous, acidic solution,
- aqueous, acidic solution which is chromium-free and contains Zr as complex fluoride and Mo as molybdate in a weight ratio (calculated as Zr / Mo metal) of Zr: Mo of 15: 1 to 3.5: 1, brought by dipping or spraying application in contact, so that after the subsequent drying a coating weight of 2 to 15 mg / m 2 of Zr and Mo results, the Solution contains 100 to 800 mg / l Zr and 30 to 100 mg / l Mo (calculated as Zr / Mo metal) and has a pH of 2.5 to 4.5.
- the aqueous, acidic solution in step c) preferably contains Zr and Mo in a weight ratio of 15: 1 to 5: 1, more preferably from 13: 1 to 7: 1 and very particularly preferably from 1: 1 by immersion or spraying : 1 to 9: 1.
- a coating weight of 2 to 12 mg / m 2 , particularly preferably 2 to 10 mg / m 2 and very particularly preferably 2 to 8 mg / m 2 of Zr and Mo preferably results in the case of immersion or spray application ,
- the aqueous solution contains 250 to 700 mg / l Zr and 30 to 80 mg / l Mo, more preferably 400 to 600 mg / l Zr and 40 to 60 mg / l Mo and most preferably 475 in the case of immersion or spray application to 525 mg / l Zr and 45 to 55 mg / l Mo.
- the aqueous solution in the case of immersion or spray application preferably has a pH of from 3.1 to 4.3 and more preferably from 3.6 to 4.0 and preferably a temperature of from 20 to 50 ° C. and more preferably from 20 to 30 ° C on.
- the object is achieved by the method of the type mentioned according to the invention is designed such that the workpieces a) with a mineral acid-containing aqueous, acidic solution in the dipping or spraying,
- roller coating method brings into contact, so that after the subsequent drying, a coating weight of 2 to 15 mg / m 2 of Zr and Mo results, the solution 0.4 to 7.5 g / l Zr and 0.4 to 7.5 contains g / l Mo (calc. as Zr / Mo metal) and has a pH of 1.0 to 3.0.
- the aqueous solution when applied by roller coating 1, 0 to 6.0 g / l Zr and 1, 0 to 6.0 g / l Mo, more preferably 2.0 to 4.0 g / l Zr and 2.0 to 4 , 0 g / l Mo and most preferably 2.8 to 3.2 g / l Zr and 2.8 to 3.2 g / l Mo.
- the aqueous solution preferably has a pH of from 1.4 to 2.7, and particularly preferably from 1.8 to 2.5, when applied by the roller application method on.
- the aqueous, acidic solution in step c) can by prior dilution of a corresponding concentrate, preferably by a factor of 1: 30 to 1: 100, more preferably by a factor of about 1:50, preferably with water and optionally adjusting the pH value can be provided.
- the workpieces are pickled with a mineral acid-containing aqueous, acidic solution by dipping or spraying.
- Alkaline cleaning results in the formation of zirconium / molybdenum layers with poor volume resistivity values.
- the compound of the invention pretreated workpieces can be pre-coated with similar pretreated or possibly otherwise, for.
- phosphated workpieces done with surfaces of aluminum or its alloys. If intended to be joined to steel and / or galvanized and / or alloy galvanized steel parts, these parts may have bare or precoated surfaces.
- a suitable pre-coating can, for. Example, a phosphate layer with a maximum coating weight of 2 g / m 2 or a layer of a conductive primer.
- the pickling process must be preceded by a cleaning / degreasing stage or the pickling process must be carried out in such a way that simultaneous cleaning / degreasing takes place.
- the latter can be done by adding surfactant to the pickling solution.
- Phosphatier alliance are those who work with solutions based on zinc phosphate, in particular according to the low-zinc technology, or with alkali metal phosphate in the foreground.
- the solutions may be modified by the addition of further small amounts of polyvalent cations, such as calcium, magnesium, nickel, copper or manganese.
- chromium-free conversion treatment in particular acid solutions of the fluoro complexes of titanium, zirconium, hafnium, but also silicon, optionally containing organic polymer, are used.
- These acidic solutions may additionally contain at least one organosilane and / or at least one hydrolysis product thereof and / or at least one condensation product thereof.
- the at least one organosilane preferably has at least one amino group. Particularly preferably it is one which can be hydrolyzed to an aminopropylsilanol and / or to 2-aminoethyl-3-amino-propyl-silanol and / or a bis (trimethoxysilylpropyl) amine.
- reaction primer so-called reaction primer or primer can be applied.
- the pre-treatment of the workpieces according to the invention ensures adequate, temporary corrosion protection for longer storage times. During this time, there is no negative influence on the weldability, in particular the electrical resistance welding, or the bondability. Also, with regard to the weldability, it is ensured that the volume resistance is practically the same on all surface areas of the workpiece.
- Workpieces in the context of the present invention are tape, sheet metal and individual parts, such as profiles.
- the application of the solution according to step c) can be done by spraying or dipping each with or without water rinse. When applied without water rinse, it is advantageous to remove excess treatment solution by squeezing rollers. In the treatment of sheet or strip, the application of the treatment solution by the roll coater method is particularly advantageous. It allows a defined setting of the desired wet film thickness in one operation.
- the workpiece is dried or the solution is dried.
- Object temperatures of 30 to 90 ° C are particularly advantageous.
- Concentrates which are diluted with low-salt water, preferably demineralized water, to the concentrations to be respectively adjusted are usually used to prepare the treatment liquids.
- low-salt water preferably demineralized water
- concentrations to be respectively adjusted are usually used to prepare the treatment liquids.
- the molybdate is advantageously introduced as ammonium heptamolybdate and / or sodium heptamolybdate, preferably as ammonium heptamolybdate and particularly preferably as ammonium heptamolybdate x 7 H 2 O.
- molybdate also includes protonated forms, in particular molybdic acid.
- the pickling of the workpieces is done with a mineral acid-containing aqueous, acidic solution. It can be carried out electrolytically or chemically. In the case of electrolytic pickling, phosphoric acid is particularly suitable as the mineral acid.
- the pickling by chemical means which is given preference because of the apparatus less laborious procedure in the rule, can be made with nitric acid or nitric acid / hydrofluoric acid.
- the workpieces are pickled with a solution by spraying or dipping containing surfactant, sulfuric acid and a compound selected from the group consisting of hydrofluoric acid, phosphoric acid and iron (III) sulfate, preferably hydrogen fluoride, wherein solutions, containing 3 to 8 g / l of sulfuric acid, 50 to 150 mg / l of non-complexed free fluoride and 1 to 3 g / l of nonionic surfactant have been found to be particularly suitable.
- Nonionic surfactants are ethylene oxide Adducts to fatty alcohols and, for example, abietic acid are particularly suitable.
- the measurement of the free fluoride was carried out with a fluoride-sensitive electrode, wherein the calibration of the electrode was carried out with solutions whose pH was identical to that of the solution to be tested.
- the pickling process should be carried out in such a way that a metal removal of about 0.1 to 0.6 g / m 2 workpiece surface is obtained.
- the subsequent to the pickling of the workpieces flushing - according to step b) - is preferably carried out in several rinsing stages, and it is particularly advantageous to perform the rinse water cascade-like the workpiece in the opposite direction.
- the last rinse step should be carried out with demineralized water.
- the subsequent to the pickling and rinsing step treatment according to step c) prevents the re-growth of an oxide layer occurs on the workpieces with a surface made of aluminum or aluminum alloy.
- the solution used in step c) additionally contains at least one polymer selected from the group consisting of poly (meth) acrylic acid, (meth) acrylic acid copolymers, polyvinylphosphonic acid, vinylphosphonic acid copolymers and maleic acid copolymers.
- the (meth) acrylic acid copolymers used are preferably (meth) acrylic acid / maleic acid copolymers and the vinylphosphonic acid copolymers vinylphosphonic acid / acrylic acid copolymers.
- polymers in particular polyacrylic acid and acrylic acid copolymers and in the latter especially acrylic acid-maleic acid copolymers are suitable.
- the poly (meth) acrylic acid used has a number average molecular weight (MW) in the range from 4,000 to 300,000 g / mol, more preferably from 50,000 to 250,000 g / mol and most preferably from 100,000 up to 250,000 g / mol.
- MW number average molecular weight
- the (meth) acrylic acid copolymer used has a number average molecular weight (MW) in the range from 4,000 to 100,000 g / mol and particularly preferably from 60,000 to 80,000 g / mol.
- MW number average molecular weight
- the polyvinylphosphonic acid or vinylphosphonic acid copolymer used preferably has a number average molecular weight (MW) in the range from 4,000 to 70,000 g / mol and particularly preferably in the range from 10,000 to 30,000 g / mol.
- MW number average molecular weight
- the concentration of the at least one polymer is between 100 and 600 mg / l, preferably between 100 and 400 mg / l, more preferably between 135 and 290 mg / l and most preferably between 170 and 180 mg / l.
- a coating weight of Zr and Mo which is more independent of the injection time and preferably largely independent of coating weight in the target range of 2 to 15 mg / m 2 can be achieved in spray application. This is particularly advantageous because even at different tape speeds similar coating weights can be achieved. Negative effects on the volume resistivity, however, are not observed by the polymer content.
- a further advantageous embodiment of the invention provides to apply a lubricant to the workpieces.
- a lubricant are in particular mineral oil-based forming oils, which may be fully synthetic or native, or dry lubricants based on polyethylene / polyacrylate.
- workpieces with layers are regularly obtained which permit perfect deformation and / or gluing or, as a result of the small electrical resistance which is uniform over the workpiece surface, a perfect and trouble-free welding.
- the workpieces are ideally suited for a subsequent permanent corrosion-protective treatment.
- the pickling process was carried out in such a way that the pickling rate for the alloy AA 5754 was 0.05 to 0.2 g / m 2 and for the alloy AA 61 1 1 0.05 to 0.4 g / m 2 . For this treatment times between 5 and 20 seconds were required.
- the volume resistances measured on the single sheet were about 60 ⁇ -ohms for the AA 5754 alloy and about 13 ⁇ -ohms for the AA 61 1 1 alloy.
- the polymers A to D in Table 1 were the following:
- A: polyacrylic acid, MW about 60,000 g / mol in colloidal solution,
- Adhesive adhesion was determined using a modified APGE (Arizona Proving Ground Equivalent) test. To this end, two test slides (each 56.25 x 25 x 0.25 mm) were coated with a dry lubricant customary in the industry and bonded using a suitable industrial adhesive. Six such test plate pairs were then bolted at their respective ends to a chain which was subjected to a tensile stress of 2400 N. The following climate program was used per test week:
- a sequence of steps 1. to 3. represents a cycle by definition. One cycle was passed if the adhesive bond between all of the test slides on the chain withstood. The test was passed as a whole, if at least 45 cycles were passed.
- the phosphatability was determined by scanning electron microscope images. Thus, a "+" - in Table 3, a closed, finely crystalline phosphate layer, an "o” a closed, coarsened phosphate layer (crystals with> 20 ⁇ edge length) and a "-" a non-closed to nonexistent phosphate layer.
- Comparative Example VB1 reveals that owing to an excessively high Zr support weight, the layer obtained in the treatment according to step c) (37 mg / m 2 at AA 5754 and 26 mg / m 2 at AA 61 1 1) has very high volume resistivities - in particular a storage of 30 days - be obtained (100 ⁇ -ohms for AA 5754 and 38 ⁇ -ohms for AA 61 1 1).
- examples B1 to B7 show that, in compliance with the conditions essential to the invention, with regard to the type of pickling treatment, the Zr / Mo ratio, the produced coating weight, the respective Concentration and pH ranges of the treatment solutions layers with extremely good volume resistances at the same time good adhesive properties are obtained.
- the pretreated test slides of Examples B6 and B7 and a non-pretreated bare test slide VB6 were further subjected to a multistage anticorrosive treatment consisting of the following steps: i) Alkaline purification (60 ° C., 180 s)
- the corrosion protection of B6 and B7 is similar to that of VB6.
- the pretreatment according to the invention therefore does not adversely affect the protection subsequently achieved by a corrosion-protective treatment.
Abstract
Description
Claims
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2996465A CA2996465A1 (en) | 2015-09-15 | 2016-09-14 | Pre-treating aluminum surfaces with zirconium- and molybdenum-containing compositions |
JP2018513833A JP2018527467A (en) | 2015-09-15 | 2016-09-14 | Method for pretreating an aluminum surface with a composition containing zirconium and molybdenum |
RU2018113309A RU2750923C1 (en) | 2015-09-15 | 2016-09-14 | Pretreatment of aluminum surfaces with compounds containing zirconium and molybdenum |
CN201680051452.XA CN108350579A (en) | 2015-09-15 | 2016-09-14 | With the composition pre-treating aluminium surface containing zirconium and molybdenum |
MX2018003246A MX2018003246A (en) | 2015-09-15 | 2016-09-14 | Pre-treating aluminum surfaces with zirconium- and molybdenum-containing compositions. |
KR1020187007023A KR20180053306A (en) | 2015-09-15 | 2016-09-14 | Pretreatment of aluminum surfaces with zirconium- and molybdenum-containing compositions |
US15/759,870 US20180237919A1 (en) | 2015-09-15 | 2016-09-14 | Pre-treating aluminum surfaces with zirconium-and molybdenum-containing compositions |
EP16770231.5A EP3350357A1 (en) | 2015-09-15 | 2016-09-14 | Pre-treating aluminum surfaces with zirconium- and molybdenum-containing compositions |
ZA2018/02301A ZA201802301B (en) | 2015-09-15 | 2018-04-09 | Pre-treating aluminum surfaces with zirconium- and molybdenum-containing compositions |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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DE102015217585 | 2015-09-15 | ||
DE102015217585.5 | 2015-09-15 |
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WO2017046139A1 true WO2017046139A1 (en) | 2017-03-23 |
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PCT/EP2016/071657 WO2017046139A1 (en) | 2015-09-15 | 2016-09-14 | Pre-treating aluminum surfaces with zirconium- and molybdenum-containing compositions |
Country Status (11)
Country | Link |
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US (1) | US20180237919A1 (en) |
EP (1) | EP3350357A1 (en) |
JP (1) | JP2018527467A (en) |
KR (1) | KR20180053306A (en) |
CN (1) | CN108350579A (en) |
CA (1) | CA2996465A1 (en) |
DE (1) | DE102016217507A1 (en) |
MX (1) | MX2018003246A (en) |
RU (1) | RU2750923C1 (en) |
WO (1) | WO2017046139A1 (en) |
ZA (1) | ZA201802301B (en) |
Cited By (5)
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WO2019053023A1 (en) * | 2017-09-14 | 2019-03-21 | Chemetall Gmbh | Method for pretreating aluminum materials, particularly aluminum wheels |
WO2022090388A1 (en) | 2020-10-29 | 2022-05-05 | Chemetall Gmbh | Zr, mo and acid-functional polymer containing aqueous compositions for treatment of metallic surfaces |
WO2022101191A1 (en) | 2020-11-10 | 2022-05-19 | Chemetall Gmbh | Treatment of metallic surfaces by copolymer containing acidic aqueous compositions |
WO2022101192A1 (en) | 2020-11-10 | 2022-05-19 | Chemetall Gmbh | Treatment of metallic surfaces by oh-functional copolymer containing acidic aqueous compositions |
RU2778535C2 (en) * | 2017-09-14 | 2022-08-22 | Хеметалл Гмбх | Method for pre-processing of aluminum materials, especially aluminum discs |
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PL3545118T3 (en) | 2016-11-23 | 2021-02-08 | Chemetall Gmbh | Composition and method for the chromium-free pretreatment of aluminium surfaces |
JP6846558B1 (en) | 2019-09-27 | 2021-03-24 | 株式会社Uacj | Aluminum alloy material and its manufacturing method |
CN111020551B (en) * | 2019-12-30 | 2022-02-08 | 郑州大学 | Using ZrO2/MoO3Method for protecting irony cultural relics by composite nano film layer |
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- 2016-09-14 WO PCT/EP2016/071657 patent/WO2017046139A1/en active Application Filing
- 2016-09-14 EP EP16770231.5A patent/EP3350357A1/en active Pending
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WO2019053023A1 (en) * | 2017-09-14 | 2019-03-21 | Chemetall Gmbh | Method for pretreating aluminum materials, particularly aluminum wheels |
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JP7330952B2 (en) | 2017-09-14 | 2023-08-22 | ケメタル ゲゼルシャフト ミット ベシュレンクテル ハフツング | How to pretreat aluminum materials, especially aluminum wheels |
WO2022090388A1 (en) | 2020-10-29 | 2022-05-05 | Chemetall Gmbh | Zr, mo and acid-functional polymer containing aqueous compositions for treatment of metallic surfaces |
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Also Published As
Publication number | Publication date |
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DE102016217507A1 (en) | 2017-03-16 |
RU2750923C1 (en) | 2021-07-06 |
CN108350579A (en) | 2018-07-31 |
MX2018003246A (en) | 2018-05-17 |
KR20180053306A (en) | 2018-05-21 |
ZA201802301B (en) | 2019-07-31 |
CA2996465A1 (en) | 2017-03-23 |
US20180237919A1 (en) | 2018-08-23 |
EP3350357A1 (en) | 2018-07-25 |
JP2018527467A (en) | 2018-09-20 |
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