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INVENTOR

WAVELENGTH (NANOMETERS) FREDERICK W. SCHMIDTS

WILLIAM P. HAMILTON

ATTORNEY

3,731,612

1 2

PHOTOGRAPHIC DEVELOPING DEVICE 15 in which the radiation source 12 is supported. One

The invention herein described was made under a suitable source of radiation is a 650 watt DVY

contract with the United States Air Force. Quartzline (Registered Trademark) sun gun. Vertical

This invention relates to a cold red light source of il- sidewalls 16 may enclose a square, rectangular, oval or

lumination to be used in photochemical development 5 cylindrical or other configured space. Adjacent to the

of non-silver organic free radical films, as described in f,im ^ positioned between the film plane and the

U.S. Pat. No. 3,510,300 and in 3,573,046 and is an im- iower end of enclosure 10 is a support or shelf 18 for

provement of the photochemical developing apparatus one or more Wratten type fllters or other transmission

described in U.S. Pat. No. 3,573,046 and in U.S. Pat. filters 20.

application Ser. No. 766,160, filed Oct. 9, 1968, now 10 In ,ine with the axis passing through the radiation

Pat. No. 3,618,504 the disclosures of which are m- source and preferably at an angle of 45° to the plane of

tended to be incorporated herein by reference. filter 2Q is the first series of dichroic fllters 26, 28.

Free radical photographic systems have the unique To ... a substantial portion of the heat and to

advantage that the latent image can be developed by ... ^ ^ 2Q from overheating and fracturing) a

flooding the entire film with radiative energy in the red fon ^ ^ kioned in an Q ; in wa16 Fan 24 ex.

or infrared region. A latent image dye is formed from i u * J • r *u i I«j i

f , ... .... pels heated air from the enclosure 10 and sucks air into

its precursors by the original exposure to visible or near , . „ „, , , „ , .

, J\. _, , the enclosure from the filter end thereof, thereby ef

ultraviolet light. It appears that the dye, m turn, has the . . _ . . , , „ „„ „,

....^ ,, •. ,. . . , , ^ , fectmg a flow of air along the surfaces of filters 20,26,

ability to absorb red and/or infrared photons and use 7 . , , ,

them to form additional dye molecules from neighbor- 20 28 Fan 24 also sucks a,r into the ^osure past the

ing dye precursors. Less light of shorter wavelengths sou'ce 12 and ultimately all the air IS expelled from the

& n C* i l T*^

during development allows more development before

the fog level reaches the maximum allowable. Less As shown ln FIG- 11 is Purred to utilize two

radiation of longer wavelengths reduces thermal fog. - dichroic fllters 26,28, one of which serves to determine

In order to obtain optimum results in the develop- the short wavelength cutoff and the other of which can

ment of free radical films, it is necessary to utilize a be used to determine the long wavelength cutoff. A

high intensity source for the radiation provided for third dichroic, if used, may be the same as the first or

development and such sources usually provide a large last filter, depending on which end of the waveband is

amount of heat in addition to the desired radiation. The 30 intended to have the sharpest cutoff,

heat may be considered "noise", and in contrast to the It is also possible to provide only one dichroic filter

desired actinic radiation which is "signal". which will provide a gradual cut off and cut on of the

One object of the invention is to provide develop- wavelengths of the radiation from the source 12.

ment radiation having a high signal-to-noise ratio of ac- As shown in FIG. 1, the radiation passed by the

tinic to visible intensities and actinic to infrared intensi- 35 dichroics can be further modified by the use of one or

ties. more of the usual Wratten fllters, disposed to receive

Another object of the invention is to provide the red radiation from which most of the IR and heat have been

and near-infrared radiation for development of organic removed. The relatively delicate Wratten filter 20 is

free radical films in a manner that is more effective and positioned downstream from the dichroics 26, 28.

more uniform than has heretofore been possible. 40 Heretofore, the Wratten filters were not usable in a

Another object of the invention is to provide a sim- practical sense because of the heat generated and

pier and more versatile apparatus than the prior art ap- pasSed from the previously used radiation sources,

paratus noted above. -rj,e apparatus includes means for positioning a film

Still a further object is to provide an apparatus in to be phot0chemically developed into the path of the

which the peak sens.tivity of the developing radiation is 45 radiation passed by tne tram of fllters. Any suitable

readily changed to accomodate ^ sens.tiv.- ... may bg provided for bringing individual expo.

^ J?^.!?16 PaTl*cu^T fi'm_ eing processe . sures or a reel may be passed out intermittently by any

Still another obiect is elimination of the water niter, . . c ...

. J „ . , , . conventional film feeding means,

and mechanical drive of previously known units and to ,. , . . ■ . f ,„ rwi/

, - , , . • ■ en The dichroic unit consists of a 650 watt GE DVY

provide an apparatus for simultaneously achieving ■ c 1 • c o . • i_ ■

v . . , _ , Z tungsten lamp in a Sylvania Super 8 sun gun which is a

greater intensity, more uniformity, better control of ° . . r v. .. ..

0 w t. „. , .,. well optimized tungsten source for radiometric intensi

waveband, higher signal-to-noise ratio, operating with , \ , ...

Iower wattage and less heat output, thereby yielding *tm the red' and c°»ect.on for projection through a

higher photo speeds, more latitude for gamma control relat.vely small aperture. The halogen cycle, however,

and better general appearance of the free radical films 55 insures relatively constant color temperature until a

developed. relatively sudden burn out.

These and other objects are accomplished by the use A fan 24 is positioned to cool both the lamp from

of the method and apparatus hereinafter described back to front and the dichroics and cut-off filter by

taken in connection with the drawings in which: pulling air into the apparatus. The filters are positioned

FIG. 1 is a schematic plan view of a preferred ap- 60 to prevent any stray light from the lamp house from by

paratus; and passing both dichroics and still hitting the film platen

FIG. 2 is a graphical representation showing the directly,

radiation provided by the apparatus of FIG. 1. Utilizing Kodak No. 301 dichroics in the apparatus

Briefly, the apparatus includes an enclosure 10 hav- ^ described has been found to effectively dump the heat

ing a source of radiation 12 mounted at one end of the beyond 700 nm so that glass filters, especially the ab

apparatus, opposite the end at which a film F is exposed sorbing type, no longer break from its absorption

to the radiation. The enclosure comprises an upper well beyond 900 nm.

[blocks in formation]

FIG. 2 shows the opening of the red/IR window of the Kodak No. 301 SWP (changing these dichroics optimizes the unit for other films) dichroic and the cutoffs of the red filters of interest. The curves are plots of relative intensity vs. wavelength. The dichroic was 5 placed in the light path at a 45° angle. Moving it away from the 45° angle shifts the reflection cutoff to shorter or longer wavelengths, since the effective depth of optical coatings is increased or decreased. The curves are empirical measurements of the radiation that actually '° floods the film, and can thereby be directly related with the film results experienced.

We claim:

1. An apparatus for photochemically developing visible images from latent images existing in non-silver free 15 radical photographic film which comprises:

an enclosure having an opening at one end wall thereof;

means for positioning a film bearing a latent image adjacent to said opening; 2°

a high intensity light source positioned adjacent to the other end wall of said enclosure, for illuminating said film bearing the latent image which is to be developed;

means disposed in said enclosure between said light source and said film, for filtering a substantial portion of the visible and infrared radiation emitted by said light source from the radiation delivered to the photographic film to be developed, said means comprising at least two dichroic filters supported so that they are parallel to each other and so that each of them is inclined 45° to the path of the radiation delivered by said light source to said film.

2. The apparatus of claim 1 including, in addition, at least one means for effecting a movement of cool air along the surface of said dichroic filters.

3. The apparatus of claim 1 including, in addition, at least one transmission filter positioned downstream from said dichroic filters.

*****

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