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United States Patent m

Hayafuji

[li] Patent Number: [45] Date of Patent:

4,592,799 Jun. 3, 1986

[54] METHOD OF RECRYSTALLIZING A

POLYCRYSTALLINE, AMORPHOUS OR
SMALL GRAIN MATERIAL

[75] Inventor: Yoshinori Hayafuji, Tokyo, Japan

[73] Assignee: Sony Corporation, Tokyo, Japan

[21] Appl. No.: 492,800

[22] Filed: May 9, 1983

[51] Int. Q.4 C30B1/08

[52] U.S. CI 156/617 R; 156/DIG. 73;

156/DIG. 102; 427/43.1; 427/86; 148/1.5

[58] Field of Search 156/617 R, DIG. 102,

156/DIG. 73, DIG. 80; 148/1.5; 29/576 B, 576 T; 427/43.1, 86; 250/492.3, 492.2; 219/121 EB;

357/23 TF

[56] References Cited

U.S. PATENT DOCUMENTS

2,729,748 1/1956 Robinson .

3,144,552 8/1964 Schonberg et al 250/49.5

3,193,717 7/1965 Nunan 313/76

3,600,237 8/1971 Davis et al 156/617

3,614,423 10/1971 Heymick et al 250/49.5 C

3,702,412 11/1972 Quintal 313/299

3,745,396 7/1973 Quintal et al 313/37

3,769,600 10/1973 Denholm et al 328/233

3,780,308 12/1973 Nabco 250/492

3,780,334 12/1973 Leboutet 313/299

4,035,829 7/1977 Ipri et al 357/23 TF

4,061,944 12/1977 Gay 313/420

4,131,909 12/1978 Matsude et al 357/23 TF

4,151,422 4/1979 Geto et al 250/492 A

4,199,384 4/1980 Hsu 357/23 TF

4,258,266 3/1981 Robinson et al 250/492 A

4,301,369 11/1981 Matsno 250/423 R

4,309,225 1/1982 Fan et al 156/DIG. 80

4,322,881 4/1982 Enomoto et al 148/1.5

4,323,417 4/1982 Lam 156/613

4,330,363 5/1982 Biegesen et al 156/620

4,358,326 11/1982 Doo 427/86

4,371,421 2/1983 Fan et al 156/624

4,375,993 3/1983 Mori et al 148/1.5

4,382,186 5/1983 Denholm et al 250/492.2

4,448,632 5/1984 Akaska 156/603

FOREIGN PATENT DOCUMENTS

11414 5/1980 European Pat. Off. .

2146941 9/1971 Fed. Rep. of Germany .

2228294 12/1972 Fed. Rep. of Germany .

57-21834 2/1982 Japan 29/576 T

420395 3/1967 Switzerland .

1032071 6/1966 United Kingdom .

OTHER PUBLICATIONS

H. Schaber, D. Cutter, and W. M. Werner, Laser Annealing Study of the Grain Size Effect in Polycrystalline Silicon Schottky Diodes, J. Appl. Phys. 53 (12), Dec. 1982, pp. 8827-8834.

Primary Examiner—David L. Lacey

Attorney, Agent, or Firm—Lewis H. Eslinger; Alvin

Sinderbrand

[57] ABSTRACT

For recrystallizing a layer of polysilicon extending over a layer of silicon dioxide on a substrate of silicon single crystal, the silicon dioxide layer is interrupted at seeding locations which are spaced apart in at least one direction and at which the polysilicon layer comes into contact with the substrate, an electron beam of generally strip-shaped cross section is impacted on the polysilicon layer where the beam is focused into a fine impact line of intense energy extending transverse to the one direction in which the seeding locations are spaced apart, the substrate and electron beam are relatively displaced in a direction transverse to the impact line so that the impact line of the beam relatively scans at least a portion of the polysilicon layer transversely to the direction in which the seeding locations are spaced apart, and the speed with which the impact line relatively scans the polysilicon layer is determined so that the polysilicon layer is subjected to zone melting at the impact line of the electron beam for growing silicon single crystals by lateral epitaxial recrystallization of the polysilicon from the seeding locations.

43 Claims, 14 Drawing Figures

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