United States Patent m
Smalley
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US005591312A Patent Number: 5,591,312 Date of Patent: Jan. 7, 1997
[54] PROCESS FOR MAKING FULLERENE FIBERS
[75] Inventor: Richard E. Smalley, Houston, Tex. [73] Assignee: William Marsh Rice University, Tex.
[21] Appl. No.: 441,432
[22] Filed: May 15,1995
Related U.S. Application Data
[63] Continuation of Ser. No. 958,929, Oct. 9, 1992, abandoned.
[51] Int. CI.6 D01F 9/12
[52] U.S. CI 204/157.41; 423/447.3;
423/445 B; 204/157.47; 204/173
[58] Field of Search 423/445 B, 447.3,
423/DIG. 39, DIG. 40; 204/157.47, 173,
157.41
[56] References Cited
U.S. PATENT DOCUMENTS
4,014,980 3/1977 Fujimaki et al 423/447.3
4,435,375 3/1984 Tamura et al 423/447.3
4,663,230 5/1987 Tennent 428/367
4,816,289 3/1989 Komatsu et al 423/447.3
5,227,038 7/1993 Smalley 204/173
FOREIGN PATENT DOCUMENTS
60-199921 10/1985 Japan 423/447.3
3-019919 1/1991 Japan 423/447.3
1469930 4/1977 United Kingdom 423/447.3
OTHER PUBLICATIONS
Bauerle, Chemical Processing with Lasers, pp. 5-7 (1986). Haufler Et Al., Journ. Phys. Chem., 94(24) pp. 8634-36, Nov. 29, 1990.
Koch Et AL, Journ. Org. Chem., 56(14), pp. 4543^5, Jul. 5, 1991.
Haufler Et Al., Mat. Res. Soc. Symp. Proc, vol. 206, pp. 627-37, Aug. 9, 1991.
Patent Abstracts of Japan for Kokai 58-104,095, first published Juh. 21, 1983.
M. Jose-Yacaman, et al. "Catalytic Growth of Carbon Microtubules with Fullerene Structure", Applied Physics Letters, vol. 62, #6, 08 Feb. 1993, pp. 657-659. Bacon, Roger, "Growth, Structure and Properties of Graph- ite Whiskers," J. Appl. Phys., vol. 31, No. 2, Feb., 1960, pp. 283-290.
"Needles In A Carbon Haystack," News And Views Section, Nature, vol. 354, Nov. 7, 1991, p. 18. Iijima, Sumio, "Helical Microtubes Of Graphitic Carbon," Nature, vol. 354, Nov. 7, 1991, pp. 56-58. "Buckytubes," Scientific American, Dec, 1991, p. 14. Jin, Changming, et al., "Fullerene Nanowires," Proc. of 1st Italian Workshop on Fullerenes, Bologna, Italy, Feb. 6-7, 1992.
Dresselhaus, M. S., "Down The Straight And Narrow," News and Views Section, Nature, vol. 358, Jul. 16,1992, pp. 195-196.
Ebbesen, T. M., et al., "Large Scale Synthesis Of Carbon Nanotubes," Nature, vol. 358, Jul. 16, 1992, pp. 220-222.
Primary Examiner—Wayne Langel
Assistant Examiner—Peter Di Mauro
Attorney, Agent, or Firm—Baker & Botts, L.L.P.
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