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United States Patent m

Smalley

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US005591312A Patent Number: 5,591,312 Date of Patent: Jan. 7, 1997

[54] PROCESS FOR MAKING FULLERENE FIBERS

[75] Inventor: Richard E. Smalley, Houston, Tex. [73] Assignee: William Marsh Rice University, Tex.

[21] Appl. No.: 441,432

[22] Filed: May 15,1995

Related U.S. Application Data

[63] Continuation of Ser. No. 958,929, Oct. 9, 1992, abandoned.

[51] Int. CI.6 D01F 9/12

[52] U.S. CI 204/157.41; 423/447.3;

423/445 B; 204/157.47; 204/173

[58] Field of Search 423/445 B, 447.3,

423/DIG. 39, DIG. 40; 204/157.47, 173,

157.41

[56] References Cited

U.S. PATENT DOCUMENTS

4,014,980 3/1977 Fujimaki et al 423/447.3

4,435,375 3/1984 Tamura et al 423/447.3

4,663,230 5/1987 Tennent 428/367

4,816,289 3/1989 Komatsu et al 423/447.3

5,227,038 7/1993 Smalley 204/173

FOREIGN PATENT DOCUMENTS

60-199921 10/1985 Japan 423/447.3

3-019919 1/1991 Japan 423/447.3

1469930 4/1977 United Kingdom 423/447.3

OTHER PUBLICATIONS

Bauerle, Chemical Processing with Lasers, pp. 5-7 (1986). Haufler Et Al., Journ. Phys. Chem., 94(24) pp. 8634-36, Nov. 29, 1990.

Koch Et AL, Journ. Org. Chem., 56(14), pp. 4543^5, Jul. 5, 1991.

Haufler Et Al., Mat. Res. Soc. Symp. Proc, vol. 206, pp. 627-37, Aug. 9, 1991.

Patent Abstracts of Japan for Kokai 58-104,095, first published Juh. 21, 1983.

M. Jose-Yacaman, et al. "Catalytic Growth of Carbon
Microtubules with Fullerene Structure", Applied Physics
Letters, vol. 62, #6, 08 Feb. 1993, pp. 657-659.
Bacon, Roger, "Growth, Structure and Properties of Graph-
ite Whiskers," J. Appl. Phys., vol. 31, No. 2, Feb., 1960, pp.
283-290.

"Needles In A Carbon Haystack," News And Views Section,
Nature, vol. 354, Nov. 7, 1991, p. 18.
Iijima, Sumio, "Helical Microtubes Of Graphitic Carbon,"
Nature, vol. 354, Nov. 7, 1991, pp. 56-58.
"Buckytubes," Scientific American, Dec, 1991, p. 14.
Jin, Changming, et al., "Fullerene Nanowires," Proc. of 1st
Italian Workshop on Fullerenes, Bologna, Italy, Feb. 6-7,
1992.

Dresselhaus, M. S., "Down The Straight And Narrow," News and Views Section, Nature, vol. 358, Jul. 16,1992, pp. 195-196.

Ebbesen, T. M., et al., "Large Scale Synthesis Of Carbon Nanotubes," Nature, vol. 358, Jul. 16, 1992, pp. 220-222.

Primary Examiner—Wayne Langel

Assistant Examiner—Peter Di Mauro

Attorney, Agent, or Firm—Baker & Botts, L.L.P.

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