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Effect of an oil heat treatment on the teachability and biological resistance of boric acid impregnated wood

Impact d’un traitement oléothermique sur la durabilité du bois imprégné à l’acide borique

Abstract

Vegetable oils provide boron retention of about 30% of initial amount depending on oil drying properties. Linseed oil is the most efficient, followed by soybean oil and rapeseed oil. Durability of C. japonica and F. crenata wood specimens has been enhanced by application of linseed oil alone but not enough to reduce termite’s attack of Coptotermes formosanus. Treating wood with a 1.0% w/w boric acid solution prior to oil treatment protects C. japonica from termite and fungi degradations. Efficiency against termites is mainly due to boron retention by oil but hydrophobic oil also forms a barrier decreasing fungi penetration. Boron efficacy threshold around 0.7 kg/m3BAE, lower than classical boron treatments thresholds indicates that oil water-repellence reinforces boron biostatic effect.

Résumé

La recherche en préservation du bois se tourne à présent vers des produits à faibles impacts environnementaux. Nous avons étudié l’opportunité d’associer borates et huiles végétales pour accroître la rétention du bore ainsi que la résistance du bois aux termites et aux champignons xylophages. Les huiles végétales permettent de retenir environ 30 % du bore initial selon leurs propriétés de séchage. Ainsi, l’huile de lin est plus efficace que les huiles de soja et de colza. La durabilité d’éprouvettes d’aubier de C. japonica et F. crenata est améliorée par l’ajout d’huile de lin mais trop peu pour éviter les attaques de termites Coptotermes formosanus. En revanche, la combinaison d’une imprégnation par une solution d’acide borique à 1.0 % m/m suivi d’une traitement à l’huile protège efficacement C. japonica contre les termites et les champignons. Alors que son efficacité contre les termites semble principalement due à la rétention du bore, l’huile semble former une barrière efficace contre la pénétration des champignons xylophages. Les seuils d’efficacité d’environ 0.7 kg/m3BAE, plus faible que ceux enregistrés pour les traitements classiques au bore indique que l’huile renforce l’effet biostatique du bore.

References

  1. Aucejo A., Ferrer J., Gabaldón C., Marzal P., Seco A., Diagnosis of boron, fluorine, lead, nickel and zinc toxicity in citrus plantations in Villareal, Spain, Water Air Soil Pollut. 14 (1997) 349–360.

    Google Scholar 

  2. Bérard P., Valorisation des taillis de châtaignier en bois ronds pour usage extérieur : étude et optimisation d’un traitement oléo thermique pour améliorer l’aspect et la durée de vie du produit, Thèse de doctorat, Montpellier, France, 2003.

  3. Cockroft R., Levy J.F., Bibliography on the use of boron compounds in the preservation of wood, J. Inst. Wood Sci. 33 (1973) 28–37.

    Google Scholar 

  4. Dumonceaud O., Petits bois naturellement durables dans des usages extérieurs en vue de limiter l’emploi des traitements par les pesticides : problèmes posés par l’utilisation du châtaignier (Castanea sativa Mill.) et intérêt d’un traitement de type friture à basse température, Thèse de doctorat, Montpellier, France, 2001.

  5. Grace J.K., Yamamoto R.T., Repeated exposure of borate-treated Douglas-fir lumber to Formosan subterranean termites in an accelerated field test, For. Prod. J. 44 (1994) 65–67.

    CAS  Google Scholar 

  6. Grace J.K., Yamamoto R.T., Tamashiro M., Resistance of borate-treated Douglas-fir lumber to formosan subterranean termites, For. Prod. J. 42 (1992) 61–65.

    CAS  Google Scholar 

  7. Hamilton S.J., Buhl K.J., Acute toxicity of boron, molybdenum and selenium to fry of Chinook salmon and Coho salmon, Arch. Environ. Contam. Toxicol. 19 (1990) 366–373.

    Article  PubMed  CAS  Google Scholar 

  8. Jansen J.A., Andersen J., Shou J.S., Boric acid single dose pharmacokinetics after intravenous administration to man, Arch. Toxicol. 55 (1984) 64–67.

    Article  PubMed  CAS  Google Scholar 

  9. Kartal S.N., Imamura Y., Effects of N’-N-(l, 8-Naphthalyl) hydroxylamine (NHA-Na) and hydroxynaphthalimide (NHA-H) on boron teachability and biological degradation of wood, Holz Roh werkst, 62 (2004) 378–385.

    Article  CAS  Google Scholar 

  10. Lloyd J.D., Manning M.J., Developments in borate preservation technology, Annual convention of the British wood preserving and damp-proofing association, 1995, 7.

  11. Lloyd J.D., The mechanisms of action of boron containing wood preservatives, Ph.D. thesis, Imperial College of Science, Technology and Médecine, London, UK, 1993.

    Google Scholar 

  12. Lyon F., Pizzi A., Imamura Y., Thevenon M.F., Kartal N., Gril J., Leachability and termite resistance of wood treated with a new preservative: Boric acid ammonium oleate, Holz Roh Werkst (in press).

  13. Maier K.J., Knight A.W., The toxicity of waterborne boron to Daphnia magnia and Chironomus decorus and the effect of water hardness and sulphate on boron toxicity, Arch. Environ. Contam. Toxicol. 20 (1991) 282–287.

    Article  PubMed  CAS  Google Scholar 

  14. Megnis M., Olsson T., Varna J., Lindberg H., Mechanical performance of linseed oil impregnated pine as correlated to the uptake level, Wood Sci. Technol. 36 (2002) 1–18.

    Article  CAS  Google Scholar 

  15. Militz H., Thermal treatment of wood: European processes and their background, The International Research Group on Wood Preservation, Doc No. IRG/WP 02-40241, IRG Secretariat Stockholm, Sweden, 2002.

    Google Scholar 

  16. Mohareb A., Van Acker J., Stevens M., Effect of protective additives on leachability and efficacy of borate treated wood, The International Research Group on Wood Preservation, Doc. No. IRG/WP 02-30290, IRG Secretariat Stockholm, Sweden, 2002.

    Google Scholar 

  17. Mohareb A., Van Acker J., Stevens M., Leachability and efficacy of fatty acid derived boron esters as wood preservatives, The International Research Group on Wood Preservation, Doc. No. IRG/WP 04-30351, IRG Secretariat Stockholm, Sweden, 2004.

    Google Scholar 

  18. Olsson T., Marklund B., Lindberg H., Characterisation of linseed oil impregnated pine exposed for biological degradation-A case study, Proceeding of Cost Action E 22, Reinbek, Germany, 2001.

  19. Paajanen L., Ritschkofft A.-C., Effect of crude tall oil, linseed oil and rapeseed oil on the growth of the decay fungi, The International Research Group on Wood Preservation, Doc. No. IRG/WP 02-30299, IRG Secretariat Stockholm, Sweden, 2002.

    Google Scholar 

  20. Petric M., Pavlic M., Cadez F., Leaching of the new boron based biocide from coated wood. The International Research Group on Wood Preservation, Doc. No. IRG/WP 01-30267, IRG Secretariat Stockholm, Sweden, 2001.

    Google Scholar 

  21. Peylo A., Willeitner H., Leaching of boron more than 3 years after exposure. The International Research Group on Wood Preservation, Doc. No. IRG/WP 97-30143, IRG Secretariat Stockholm, Sweden, 1997.

    Google Scholar 

  22. Pizzi A., A new approach to non-toxic, wide-spectrum, ground-contact wood preservatives. Part 1: Approach and reaction mechanisms, Holzforschung 47 (1993) 253–260.

    Article  CAS  Google Scholar 

  23. Pizzi A., A new approach to non-toxic, wide-spectrum, ground-contact wood preservatives. Part 2: Accelerated and field biological tests, Holzforschung 47 (1993) 343–348.

    Article  CAS  Google Scholar 

  24. Pizzi A., Baecker A.W., A new boron fixation mechanism for non-toxic wood preservatives, Holzforschung 50 (1996) 507–510.

    Article  CAS  Google Scholar 

  25. Rapp A.O., Sailer M., Oil treatment of wood in Germany, Proceeding of Cost Action E 22, Reinbek, Germany, 2001.

  26. Sailer M., Rapp A.O., Leithoff H., Improved resistance of Scots pine and spruce by application of an oil-heat treatment, The International Research Group on Wood Preservation, Doc. No. IRG/WP 00-40162, IRG Secretariat, Stockholm, Sweden, 2000.

    Google Scholar 

  27. Sailer M., Rapp A.O., Use of vegetables oils for wood protection, Proceeding of Cost Action E 22, Reinbek, Germany, 2001.

  28. Tartari G., Camusso M., Boron contents in fresh water of northern Italy, Water Air, Soil Pollut. 38 (1988) 409–417.

    CAS  Google Scholar 

  29. Teshima D., Taniyama D., Oishi R., Usefulness of forced diuresis for acute boric acid poisoning in an adult, J. Clin. Pharm. Ther. 26 (2001) 387–390.

    Article  PubMed  CAS  Google Scholar 

  30. Thévenon M.F., Environmental optimization of wood protection: state of the art in France; State of the art reviews, Cost Action E22 Workshop, Environment optimization of wood protection, EUR 19859, ISBN 92-894-1371-9 (2000) 47–59.

  31. Thévenon M.-F., Pizzi A., Haluk J.P., Non-toxic albumin and soja protein borates as ground-contact wood preservatives, Holz Roh-Werkst. 55 (1997) 293–296.

    Article  Google Scholar 

  32. Tsunoda K., Preservative properties of vapour-boron-treated wood and wood-based composites, J. Wood Sci. 47 (2001) 149–153.

    Article  CAS  Google Scholar 

  33. Usuda K., Kono K., Orita Y., Dote T., Iguchi K., Nishiura H., Tominaga M., Tagawa T., Goto E., Shirai Y., Serum and urinary boron levels in rats after single administration of sodium tetraborate, Arch. Toxicol. 72 (1998) 468–474.

    Article  PubMed  CAS  Google Scholar 

  34. Welzbacher C.R., Rapp A.O., Comparison of thermally wood originating from four industrial scale processes-durability, The International Research Group on Wood Preservation, Doc. No. IRG/WP 02-40229, IRG Secretariat Stockholm, Sweden, 2002.

    Google Scholar 

  35. Japanese industrial Standard (JIS) K 1571, Qualitative standards and testing methods for wood preservatives, JIS, 2004.

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Correspondence to Florent Lyon.

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Tables I to III are only available in electronic form at http://www.afs-journal.org.

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Lyon, F., Thevenon, MF., Hwang, WJ. et al. Effect of an oil heat treatment on the teachability and biological resistance of boric acid impregnated wood. Ann. For. Sci. 64, 673–678 (2007). https://doi.org/10.1051/forest:2007046

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  • DOI: https://doi.org/10.1051/forest:2007046